ALBERT

Description: Within the framework of the EU-funded BENGAL programme, the effects of seasonality on biogenic silica early diagenesis have been studied at the Porcupine Abyssal Plain (PAP), an abyssal locality located in the northeast Atlantic Ocean. Nine cruises were carried out between August 1996 and August 1998. Silicic acid (DSi) increased downward from 46.2 to 213 µM (mean of 27 profiles). Biogenic silica (BSi) decreased from ca. 2% near the sediment-water interface to 〈1% at depth. Benthic silicic acid fluxes as measured from benthic chambers were close to those estimated from non-linear DSi porewater gradients. Some 90% of the dissolution occurred within the top 5.5 cm of the sediment column, rather than at the sediment-water interface and the annual DSi efflux was close to 0.057 mol Si/m**2/yr. Biogenic silica accumulation was close to 0.008 mol Si/m**2/yr and the annual opal delivery reconstructed from sedimentary fluxes, assuming steady state, was 0.065 mol Si/m**2/yr. This is in good agreement with the mean annual opal flux determined from sediment trap samples, averaged over the last decade (0.062 mol Si/m**2/yr). Thus ca. 12% of the opal flux delivered to the seafloor get preserved in the sediments. A simple comparison between the sedimentation rate and the dissolution rate in the uppermost 5.5 cm of the sediment column suggests that there should be no accumulation of opal in PAP sediments. However, by combining the BENGAL high sampling frequency with our experimental results on BSi dissolution, we conclude that non-steady state processes associated with the seasonal deposition of fresh biogenic particles may well play a fundamental role in the preservation of BSi in these sediments. This comes about though the way seasonal variability affects the quality of the biogenic matter reaching the seafloor. Hence it influences the intrinsic dissolution properties of the opal at the seafloor and also the part played by non-local mixing events by ensuring the rapid transport of BSi particles deep into the sediment to where saturation is reached.

Description: The upper water column in the Fram Strait and the outer Laptev Sea was sampled for water column isotopes and living planktic foraminifer species Neogloboquadrina pachyderma (sinistral coiling) (Ehrenberg), 1861 and Turborotalita quinqueloba (Natland),1938. Their shell delta18O and delta13C values are compared to water oxygen and dissolved inorganic carbon isotope data to determine the environmental influence on the foraminifers' isotopic ratio. Major controls on the oxygen isotope composition of both species are the shallow depth habitat under permanent ice coverage, the low salinity surface layer, and the rate of metabolic activity. None of the specimens precipitated its shell in isotopic equilibrium with the ambient sea water. They are all depleted in 13C and 18O, attributed to a species-specific vital effect. For nonencrusted N. pachyderma (sin.) in the 125-250 µm size class, this vital effect amounts to 1.3 per mil in delta18O and 2.0 per mil in delta13C. It increases to higher values in waters under permanent ice cover. T. quinqueloba reveals a mean vital effect of about 1.3 per mil in delta18O and 2.6 per mil in delta13C. The general isotopic trends are similar for N. pachyderma (sin.) and T. quinqueloba. Differences in the species' isotope ratio at the same sites are caused by different calcification depths and metabolic activity. The oxygen isotope composition of N. pachyderma (sin.) shows a relationship to salinity measurements and indicates that it is a good quantitative proxy for salinity reconstructions, while no relationship exists in this region between N. pachyderma (sin.) oxygen isotopes and water temperature.

Description: The timing and magnitude of sea-surface temperature (SST) changes in the tropical southern South China Sea (SCS) during the last 16,500 years have been reconstructed on a high-resolution, 14C-dated sediment core using three different foraminiferal transfer functions (SIMMAX28, RAM, FP-12E) and geochemical (Uk'37) SST estimates. In agreement with CLIMAP reconstructions, both the FP-12E and the Uk'37 SST estimates show an average late glacial-interglacial SST difference of 2.0°C, whereas the RAM and SIMMAX28 foraminiferal transfer functions show only a minor (0.6°C) or no consistent late glacial-interglacial SST change, respectively. Both the Uk'37 and the FP-12E SST estimates, as well as the planktonic foraminiferal delta18O values, indicate an abrupt warming (ca. 1°C in 〈200 yr) at the end of the last glaciation, synchronous (within dating uncertainties) with the Bølling transition as recorded in the Greenland Ice Sheet Project 2 (GISP2) ice core, whereas the RAM-derived deglacial SST increase appears to lag during this event by ca. 500 yr. The similarity in abruptness and timing of the warming associated with the Bølling transition in Greenland and the southern SCS suggest a true synchrony of the Northern Hemisphere warming at the end of the last glaciation. In contrast to the foraminiferal transfer function estimates that do not indicate any consistent cooling associated with the Younger Dryas (YD) climate event in the tropical SCS, the Uk'37 SST estimates show a cooling of ca. 0.2-0.6°C compared to the Bølling-Allerød period. These Uk'37 SST estimates from the southern SCS argue in favor of a Northern Hemisphere-wide, synchronous cooling during the YD period.

Description: Organic carbon fluxes through the sediment/water interface in the high-latitude North Atlantic were calculated from oxygen microprofiles. A wire-operated in situ oxygen bottom profiler was deployed, and oxygen profiles were also measured onboard (ex situ). Diffusive oxygen fluxes, obtained by fitting exponential functions to the oxygen profiles, were translated into organic carbon fluxes and organic carbon degradation rates. The mean Corg input to the abyssal plain sediments of the Norwegian and Greenland Seas was found to be 1.9 mg C/m**2/d. Typical values at the seasonally ice-covered East Greenland continental margin are between 1.3 and 10.9 mg C/m**2/d (mean 3.7 mg C/m**2/d), whereas fluxes on the East Greenland shelf are considerably higher, 9.1-22.5 mg C/m**2/d. On the Norwegian continental slope Corg fluxes of 3.3-13.9 mg C/m**2/d (mean 6.5 mg C/m**2/d) were found. Fluxes are considerably higher here compared to stations on the East Greenland slope at similar water depths. By repeated occupation of three sites off southern Norway in 1997 the temporal variability of diffusive O2 fluxes was found to be quite low. The seasonal signal of primary and export production from the upper water column appears to be strongly damped at the seafloor. Degradation rates of 0.004-1.1 mg C/cm**3/a at the sediment surface were calculated from the oxygen profiles. First-order degradation constants, obtained from Corg degradation rates and sediment organic carbon content, are in the range 0.03-0.6/a. Thus, the corresponding mean lifetime of organic carbon lies between 1.7 and 33.2 years, which also suggests that seasonal variations in Corg flux are small. The data presented here characterize the Norwegian and Greenland Seas as oligotrophic and relatively low organic carbon deep-sea environments.

Description: On the basis of various lithological, mircopaleontological and isotopic proxy records covering the last 30,000 calendar years (cal kyr) the paleoenvironmental evolution of the deep and surface water circulation in the subarctic Nordic seas was reconstructed for a climate interval characterized by intensive ice-sheet growth and subsequent decay on the surrounding land masses. The data reveal considerable temporal changes in the type of thermohaline circulation. Open-water convection prevailed in the early record, providing moisture for the Fennoscandian-Barents ice sheets to grow until they reached the shelf break at ~26 cal. kyr and started to deliver high amounts of ice-rafted debris (IRD) into the ocean via melting icebergs. Low epibenthic delta18O values and small-sized subpolar foraminifera observed after 26 cal. kyr may implicate that advection of Atlantic water into the Nordic seas occurred at the subsurface until 15 cal. kyr. Although modern-like surface and deep-water conditions first developed at ~13.5 cal. kyr, thermohaline circulation remained unstable, switching between a subsurface and surface advection of Atlantic water until 10 cal. kyr when IRD deposition and major input of meltwater ceased. During this time, two depletions in epibenthic delta13C are recognized just before and after the Younger Dryas indicating a notable reduction in convectional processes. Despite an intermittent cooling at ~8 cal. kyr, warmest surface conditions existed in the central Nordic seas between 10 and 6 cal. kyr. However, already after 7 cal. kyr the present day situation gradually evolved, verified by a strong water mass exchange with the Arctic Ocean and an intensifying deep convection as well as surface temperature decrease in the central Nordic seas. This process led to the development of the modern distribution of water masses and associated oceanographic fronts after 5 cal. kyr and, eventually, to today's steep east-west surface temperature gradient. The time discrepancy between intensive vertical convection after 5 cal. kyr but warmest surface temperatures already between 10 and 6 cal. kyr strongly implicates that widespread postglacial surface warming in the Nordic seas was not directly linked to the rates in deep-water formation.

Description: Geochemical and clay mineral parameters of a high accumulation marine sediment core from the Chilean continental slope (41°S) provide a 7700 yr record of rainfall variability in southern Chile related to the position of the Southern Westerlies. We especially use the iron content, measured with a time-resolution of ca. 10 yr on average, of 14C-accelerator mass spectrometry dated marine sediments as a proxy for the relative input of iron-poor Coastal Range and iron-rich Andean source rocks. Variations in this input are most likely induced by rainfall changes in the continental hinterland of the core position. Based on these interpretations, we find a pronounced rainfall variability on multi-centennial to millennial time-scales, superimposed on generally more arid conditions during the middle Holocene (7700 to 4000 cal yr B.P.) compared to the late Holocene (4000 to present). This variability and thus changes in the position of the Southern Westerlies are first compared to regional terrestrial paleoclimate data-sets from central and southern Chile. In order to derive possible wider implications and forcing mechanisms of the Holocene latitudinal shifts of the Southern Westerlies, we then compare our data to ice-core records from both tropical South America and coastal Antarctica. These records show similar bands of variability centered at ca. 900 and 1500 yr. Comparisons of band pass filters suggest a close connection of shifts of the Southern Westerlies to changes within the tropical climate system. The correlation to climate conditions in coastal Antarctica shows a more complicated picture with a phase shift at the beginning of the late Holocene coinciding with the onset of the modern state of El Niño-Southern Oscillation system. The presented data provide further evidence that the well known millennial-scale climate variability during the last glacial continued throughout the Holocene.