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  • Life and Medical Sciences  (779)
  • Chemical Engineering  (418)
  • GEOPHYSICS
  • 1995-1999  (1,197)
  • 1997  (1,197)
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  • 1995-1999  (1,197)
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  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 43 (1997), S. 104-117 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Computational fluid dynamics methods are used to provide three-dimensional simulations of a low-density polyethylene (LDPE) autoclave reactor under normal operating conditions. For the conditions used, the reactor is not very well mixed; thus, the common model approximation of a perfectly stirred reactor is not warranted. The simulations verify the sensitive nature of the polymerization reactors and indicate a need for optimizing operating parameters.
    Additional Material: 21 Ill.
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 43 (1997), S. 118-126 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A rigorous approach was developed for the simulation of the decoking of an industrial cracking furnace. A one-dimensional heterogeneous reactor model, which accounts for the interfacial gradients between the process gas and the coke surface, was used to simulate reactor coils. Both the combustion and steam gasification of the coke layer were taken into account. The reactor model for the decoking was coupled with a detailed firebox simulation model. The initial profile of the coke layer thickness, required for the decoking calculations, was obtained by a run-length simulation. The evolution with time of the temperature distribution inside the cracking coil and in the furnace was generated simultaneously, which made it possible to understand the decoking operation in detail and to predict its duration accurately.
    Additional Material: 15 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 43 (1997), S. 157-165 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A semibatch flow scheduling strategy proposed by Teymour and Ray (1989, 1996) is evaluated for a polymerization reaction conducted in a pilot-plant reactor. The reaction used is the free radical terpolymerization of styrene, α-methyl styrene, and acrylic acid monomers initiated by an organic peroxide initiator and carried out in the presence of a reactive glycol ether solvent. This strategy was tested in both single batch and sequential semibatch modes. The process was shown to produce polymer of constant molecular weight properties and composition as inferred from acid number and monomer conversion measurements. This process could be used for obtaining polymer products from a semibatch reactor that are of comparable quality to CSTR products. Results indicate success of this process at meeting this objective; however, practical considerations relating to agitation and temperature control need to be properly addressed to ensure this success.
    Additional Material: 13 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 43 (1997), S. 127-134 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The steady-state simulation of a cocurrently cooled autothermal fixed-bed reactor was carried out using a 2-D heterogeneous mathematical model. The ammonia synthesis was chosen as a case study. Unlike the not-autothermal cocurrent reactor, which is unconditionally stable, the autothermal cocurrent reactor shows multiple steady states within a broad range of operating conditions. This finding, not reported in the literature, is explained through the mass transport from the bottom to the top of the reactor, associated with a feedback of energy. The feedback of heat, which is inherent to autothermal reactors, leads to an ignition-extinction phenomenon similar to that found in the countercurrent configuration. The influence of different parameters on the stability of the autothermal cocurrent reactor was analyzed. The regions where steady-state multiplicity occurs were compared with those presented by the autothermal countercurrent reactor. The influence of an additional heat exchanger on the reactor stability was considered.
    Additional Material: 11 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 43 (1997), S. 277-280 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 43 (1997), S. 265-267 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 43 (1997), S. 268-272 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 4 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 43 (1997), S. 339-344 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An experimental investigation was conducted to determine the boiling heat-transfer characteristics in a thermosyphon condenser-reboiler of air-separation plants. The test section was a plate-fin heat exchanger of practical size of 0.106 m width and 2.56 m length. The testing fluid was nitrogen. Experiments were carried out within a range of pressure from 150 to 300 kPa, submergence from 1.95 to 2.80 m, and heat flux up to 11 kW/m2 under constant wall-temperature condition. The liquid superheat at the onset of boiling was rather significant. The boiling heat-transfer coefficients obtained agreed well with Chen's correlation modified by Colburn's J factor within a mean deviation of 9.3%.
    Additional Material: 7 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 43 (1997) 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 10
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 43 (1997), S. 440-447 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The concept of robust design involves identification of design settings that make the product performance less sensitive to the effects of seasonal and environmental variations. This concept is discussed in this article in the context of batch distillation column design with feed stock variations, and internal and external uncertainties. Stochastic optimization methods provide a general approach to robust/parameter design as compared to conventional techniques. However, the computational burden of these approaches can be extreme and depends on the sample size used for characterizing the parametric variations and uncertainties. A novel sampling technique is presented that generates and inverts the Hammersley points (an optimal design for placing n points uniformly on a k-dimensional cube) to provide a representative sample for multivariate probability distributions. The example of robust batch-distillation column design illustrates that the new sampling technique offers significant computational savings and better accuracy.
    Additional Material: 8 Ill.
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