ISSN:
1572-8854
Keywords:
Crystal structure
;
pinacol
;
reductive dimerization
Source:
Springer Online Journal Archives 1860-2000
Topics:
Geosciences
,
Physics
Notes:
Abstract The pinacol resulting from sodium promoted reductive coupling of pentacyclo[5.4.0.02,6.-03,10.05,9]undecane-8,11-dione monoethylene ketal possesses a conformation, dictated by intramolecular hydrogen bonding, that lies midway between eclipsed and staggered. The C−C and C−O distances in the pinacol unit are, respectively, longer and shorter than usual, and all parameters are as expected.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF01665710
Permalink