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  • Springer  (14)
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  • 2000-2004
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  • 1
    Digitale Medien
    Digitale Medien
    Springer
    Surveys in geophysics 16 (1995), S. 5-36 
    ISSN: 1573-0956
    Schlagwort(e): continental crust ; electrical conductivity ; high pressure ; high temperature
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Geologie und Paläontologie , Physik
    Notizen: Abstract Great strides have been made in understanding the upper part of the crust by in-situ logging in, and laboratory experiments on core recovered from super-deep bore-holes such as the KTB. These boreholes do not extend into the lower crust, and can contribute little to the elucidation of mechanisms that produce the high electrical conductivities that are commonly observed therein by magneto-telluric (MT) methods. Laboratory studies at simulated lower crustal conditions of temperature, pressure and saturation, on electrolyte saturated rocks thought to have been derived from the lower crust, have not been possible up until now due to their experimental difficulty. It is necessary to subject electrolyte-saturated rock samples to independently controlled confining and pore-fluid pressure, which implies that the rock be sleeved in some impermeable but deformable material, that can withstand the very high temperatures required. Metals are the only materials capable of being used, but these cause great difficulties for cell sealing and conductivity measurement. In this paper we describe recent breakthroughs in experimental work, specifically the development of two new types of sophisticated metal/ceramic seal, and a conductivity measurement technique that enables the measurement of saturated rock conductivity in the presence of a highly conducting metallic sleeve. The advances in experimental technique have enabled us to obtain data on the electrical conductivity of brine saturated basic, acidic and graphite-bearing rocks at lower crustal temperatures and raised pressures. These data have facilitated the comparison of MT derived crustal electrical conductivity profiles with profiles obtained from laboratory experiments for the first time. Initial modelling shows a good agreement between laboratory derived and MT derived profiles only if the mid-crust is composed of amphibolite pervaded by aqueous fluids, and the lower crust is composed of granulite that is saturated with aqueous fluids and/or contains interconnected grain surface films of graphite. The experimental data are consistent with a three layer crust consisting of an aqueous fluid saturated acidic uppermost layer, above an aqueous fluid saturated amphibolite mid-crust, and a granulite lowermost crust, which may or may not be saturated with aqueous fluids, but if not, requires the presence of an additional conduction mechanism such as conduction through thin graphite films.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    Springer
    International journal of thermophysics 16 (1995), S. 133-143 
    ISSN: 1572-9567
    Schlagwort(e): high pressure ; refrigerants ; vibrating wire ; viscosity
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract A recently modified vibrating-wire instrument was employed to measure the liquid viscosity of a wide selection of new refrigerants under pressure. Calibration of the viscometer with water over the range of measurements confirmed that the estimated uncertainty of the measurements is 0.5%, while the precision is 0.3%. With this instrument, the viscosity of chlorofuorocarbons (CFC's) and alternative refrigerants. R11. R12. R22, R32. R124, R125. 11134a. R 141 b, and R152a, was measured over the temperature range from 270 to 340 K, from just above the saturation pressure up to 211 M Pa. The experimental data, represented by polynomial functions of temperature and pressure, are used in a comparative examination of other recently reported experimental measurements of the viscosity of all these refrigerants. to investigate the uncertainty with which the viscosity is known.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 3
    Digitale Medien
    Digitale Medien
    Springer
    International journal of thermophysics 16 (1995), S. 655-662 
    ISSN: 1572-9567
    Schlagwort(e): acoustic resonance spectroscopy ; diffusion kinetics ; high pressure ; methane ; liquid hydrocarbons
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract A novel cylindrical acoustic resonance method for the measurement of gas diffusion into liquids at high pressures is described. The measurements were per formed in a vertically oriented cylindrical acoustic resonator containing both the liquid solvent and gaseous diffusant while under high-precision isothermal and isobaric control. Individual resonance modes of the liquid column, the gas column, and the two-phase coupled fluid are resolved in the fast Fourier trans form acoustic-resonance spectrum (FFT-ARS). High-resolution acoustic spectra measured at frequent time intervals reveal the changes which accompany the diffusion fusion of gas into the liquid phase. One change, namely, the growth in length of the liquid column, results in a systematic shift to higher frequencies of axial modes in the gas column. The temporal behavior of this moving boundary, together with quantitative measurement of the flow to the gas column required to sustain the constant pressure, permits determination of the gas-into-liquid diffusion coefficient. Diffusion coefficients were determined from the change in frequency as a function of time of axial resonance modes in the gas-phase virtual cylinder as the surface of the underlying liquid phase advanced due to gas absorption. Measurements of the systems methane/n-octane, methane/n-nonane, and methane/n-decane were performed as a function of temperature at a pressure of 250 psia. Comparisons is made to results obtained elsewhere and by other methods but at the same temperatures and pressure.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 4
    Digitale Medien
    Digitale Medien
    Springer
    International journal of thermophysics 16 (1995), S. 399-411 
    ISSN: 1572-9567
    Schlagwort(e): density ; high pressure ; high temperature ; magnetic suspension balance ; single-sinker densitometer
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract A new apparatus for density measurements of fluids in the entire range from gas to liquid densities is presented. The instrument is a single-sinker buoyancy densitometer designed in a completely new way. The buoyancy force exerted by the sample fluid on an immersed sinker (buoy) is transferred by a new type of magnetic suspension coupling to an analytical balance. In order to reduce drastically the linearity error of the (commercial) balance. a special basic load compensation is applied which also avoids any buoyancy ellèct of the laboratory air on the balance. The new single-sinker densitometer covers a density range from 10 to 200(1 kg - m ' at temperatures from 233 to 523 K and pressures up to 30 MPa. A special compact version of such a single-sinker densitometer can even he used at temperatures from 80 to 523 K at pressures up to 100 MPa. Test measurements on densities of carbon dioxide at 233, 360, and 523 K at pressures up to 30 MPa show that the estimated total uncertainty of ±0.02% to ±0.03% in density is clearly met.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 5
    Digitale Medien
    Digitale Medien
    Springer
    International journal of thermophysics 16 (1995), S. 1009-1026 
    ISSN: 1572-9567
    Schlagwort(e): Anderson-Grüneisen ; bulk modulus ; equation of state ; expansivity ; high pressure ; Murnaghan equation
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract In the Murnaghan approximation, an isothermal relation between pressure (P) and volume (V) for solids is derived from the assumption that the isothermal bulk modulus (B) is a linear function ofP. This paper presents a thermodynamic analysis of a generalized form of the equation, based on treating all its various parameters [viz., V, B, and (∂B/∂P) T atP=0] as functions of temperature. Extending a previous study, the effect ofT upon (∂B/∂P) T is accounted for by using a dimensionless parameter introduced by us, which is used in formulating general expressions for the volume dependence of various thermophysical quantities,viz., the thermal expansion coefficient (α), the productαB, and the Grüneisen and Anderson-Grüneisen parameters. Some combinations of these parameters are identified, which show a simple dependence uponP. The new expressions are used in analyzing current approximations and the behavior of the solid in the low-compression range. In particular, an expression forα at highP is reported which generalizes the Anderson equation and previous results by us.
    Materialart: Digitale Medien
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  • 6
    Digitale Medien
    Digitale Medien
    Springer
    International journal of thermophysics 16 (1995), S. 761-772 
    ISSN: 1572-9567
    Schlagwort(e): density ; high pressure ; refrigerants ; Tail equation ; thermal conductivity ; viscosity
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract A recently developed scheme, based on considerations of hard-sphere theory, is used for the simultaneous correlation of the coefficients of viscosity and thermal conductivity for the refrigerants R11, R12, R22, R32. R124, R125, R134a, R141b, and R152a in excellent agreement with experiment, over extended temperature and pressure ranges. Values for the roughness factors and correlations for the characteristic volume are presented. The overall average absolute deviations of the experimental viscosity and thermal conductivity measurements from those calculated by the correlation are 2.1 and 2.3%, respectively, over a temperature range from 200 to about 10 K below the critical temperature and a pressure range from saturation to about 40 MPa. Since the proposed scheme is based on recent and accurate density values, a Tail-type equation was also employed to correlate successfully the density of the refrigerants. The overall average absolute deviation of the experimental density measurements from those calculated by the correlation is ±0.08%.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 7
    Digitale Medien
    Digitale Medien
    Springer
    International journal of thermophysics 16 (1995), S. 851-865 
    ISSN: 1572-9567
    Schlagwort(e): high pressure ; refrigerants ; R32 ; R124 ; R125 ; R141b ; thermal conductivity ; transient hot-wire technique
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract This paper reports measurements of the thermal conductivity of refrigerants R32, R124, R125, and R141b in the liquid phase. The measurements, covering a temperature range from 253 to 334 K and pressure up to 20 MPa, have been performed in a transient hotwire instrument employing two anodized tantalum wires. The uncertainty of the present thermal-conductivity data is estimated to be ±0.5%. The experimental data have been represented by polynomial functions of temperature and pressure for the purposes of interpolation. A comparison with other recent measurements is also included.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 8
    Digitale Medien
    Digitale Medien
    Springer
    International journal of thermophysics 16 (1995), S. 965-971 
    ISSN: 1572-9567
    Schlagwort(e): concentration fluctuations ; critical line broadening ; high pressure ; hydrogen-helium ; mixtures ; Raman spectroscopy
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract We investigated the vibrational Raman spectrum of H2 in the binary mixture He-H2. The Q1-line was measured between 150 and 350 K for two isobars in the gigapascal region in a mixture of critical composition. The results indicate a broadening of the spectrum due to critical concentration fluctuations.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 9
    Digitale Medien
    Digitale Medien
    Springer
    International journal of thermophysics 16 (1995), S. 1213-1224 
    ISSN: 1572-9567
    Schlagwort(e): alkanes ; diffusion ; high pressure ; mixtures
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract The interdiffusion coefficient,D 12, has been measured by Mach-Zehnder interferometry for liquid mixtures of methane andn-decane at 303 K. The mole fraction of methane was from 0.11 to 0.96 and the pressure was from 30 to 60 MPa. This includes measurements in the critical region, the critical locus being approached from supercritical pressures to within 0.4 MPa. The accuracy inD 12 is estimated to be from 3 to 10%, depending on the composition. Our data are compared with the Sigmund correlation, which is widely used to estimate diffusion coefficients in hydrocarbons at high pressures. The deviation between estimate and measurement is one order of magnitude for some of the states. We have also compared with a more recent correlation used by Erkey, but this one is not found to be applicable to the compositions studied in the present work. Our data were related to recently measured intradiffusion coefficients,D 1 andD 2, at the same state points. On this basis, we have evaluated different mixing rules for obtaining the interdiffusion coefficient from intradiffusion coefficients, both close to and away from the critical region. It is found that the so-called Darken and Adamson relations have the right qualitative behavior.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 10
    Digitale Medien
    Digitale Medien
    Springer
    International journal of thermophysics 16 (1995), S. 1309-1334 
    ISSN: 1572-9567
    Schlagwort(e): density ; high pressure ; hydrocarbons ; mixtures ; viscosity
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract The dynamic viscosityη and densityρ of 10 pure substances and three binary systems were measured as a function of temperatureT (298.15, 313.15, 333.15, 353.15, and 363.15 K.) and pressureP (⩽100 MPa). The pure substances were toluene,p-xylene,m-xylene,o-xylene, methylcyclohexane, methylnaphthalene, decahydronaphthalene, phenyldodecane, heptamethylnonane, and tetramethylpentadecane (pristane). The three binaries were toluene + tetramethylpentadecane, toluene + methylnaphthalene, and toluene + heptamethylnonane, for molar fractionsx of toluene ranging between 0 and 1. The three binaries are highly “contrasted” systems, i.e., systems in which the viscosities of the pure components are very different for eachP, T pair. In all, 547 experimental determinations were carried out (279 experimental data for viscosity of the pure substances and 268 data concerning the mixtures: x⊋0 and 1).
    Materialart: Digitale Medien
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  • 11
    Digitale Medien
    Digitale Medien
    Springer
    International journal of thermophysics 16 (1995), S. 585-598 
    ISSN: 1572-9567
    Schlagwort(e): concentration fluctuations ; critical broadening ; high pressure ; line shape ; line shift ; local composition ; mixtures ; nitrogen-helium ; Raman spectroscopy
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract Vibrational Raman spectroscopy is a very usful technique for studying the dynamical behavior of a system, in particular in the critical region. In a mixture, composition fluctuations play an important role and on the basis of the results for pure substances one would expect an increase of the linewidth in approaching the critical point. However, in previous experiments such an effect was not detected. The reasons for this failure will be discussed. Recently, we have observed a considerable broadening of the linewidth in approaching the critical point in the system helium-nitrogen under high pressure. However, it is well-known that broadening may occur through various other mechanisms such as changes in density, composition fluctuations far from the critical point, aggregation, etc. On the basis of the helium-nitrogen data the pitfalls in the experimental determination of critical broadening are discussed. The data analysis takes into account the contribution of noncritical effects. Consequences are drawn for the interpretation of spectroscopic data in terms of concentration of species in supercritical solvents. Moreover, we discuss the possibility of a difference between the local composition and the bulk composition and demonstrate from our line shift data that this is not a critical effect.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 12
    Digitale Medien
    Digitale Medien
    Springer
    International journal of thermophysics 16 (1995), S. 957-963 
    ISSN: 1572-9567
    Schlagwort(e): Gibbs free energy ; high pressure ; Monte Carlo ; nitrogen ; phase transition
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract Monte Carlo simulations that utilize an (N, P, T) ensemble with periodic deformable boundary conditions cannot describe phase transitions properly when a large potential barrier is involved. An alternative method is to calculate the Gibbs free energy difference between phases; the transition occurs when the difference is equal to zero. The Gibbs free-energy difference can be calculated using a generalized free-energy method. This method is used to determine theβ-δ phase transition of solid nitrogen at room temperature. The Gibbs freeenergy difference between theβ and theδ phase was obtained at 4.0 GPa. The difference at other pressures could be determined with the equation of state. The transition pressure was found at about 6.2 GPa, 1.3 GPa above the experimental pressure.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 13
    Digitale Medien
    Digitale Medien
    Springer
    International journal of thermophysics 16 (1995), S. 145-153 
    ISSN: 1572-9567
    Schlagwort(e): carbon dioxide ; high pressure ; low temperature ; liquid ; viscosity coellicient
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract The viscosity coellicient of carbon dioxide in the liquid phase has been measured by means of a vibrating-wire viscometer at temperatures of 220, 230, 240, 2411, 260, and 380 K. The measurements extended beyond both phase transition lines into the coexistence region (superheated liquid) and into the solid range (undercooled liquid). At 3811 K. the measurements extended only to 3511 MPa since no density data are available for high pressures. The accuracy of the measurements is estimated to be I % The agreement with the data of Ulybin and Makarushkin is rather good, but our values are in general a few percent lower than those of Diller and Ball. The results show, for the most part, a linear pressure dependence for the various isotherms, with a common intersection with the negative pressure axis of 113.7 MPa. The fluidity, the reciprocal of the viscosity, shows a linear dependence of the molar volume in adjacent density ranges. After reduction of the molar volume with the volumes of close packing, two sets of linear functions result, with common intersections of the axis forV/V 0=1.31 andV/V 0=1.40.
    Materialart: Digitale Medien
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  • 14
    Digitale Medien
    Digitale Medien
    Springer
    International journal of thermophysics 16 (1995), S. 877-882 
    ISSN: 1572-9567
    Schlagwort(e): high pressure ; toluene ; viscosity
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract This paper reports new measurements on the viscosity of toluene at pressures up to 500 MPa at 299 K and pressures up to 435 MPa at 323 K. The results are in close agreement with recent viscosity measurements from a vibrating-wire viscometer at pressures up to 250 MPa but confirm earlier measurements from a falling-body viscometer which show that the recently recommended polynomial expression for the representation of the pressure dependence of the viscosity of toluene up to 250 MPa underestimates the viscosity if applied at 500 MPa by about 30%. Modification of this polynomial expression by inclusion of one additional term is found to represent the data satisfactorily over the whole pressure range.
    Materialart: Digitale Medien
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