ALBERT

Description: This study focuses on the effects of summertime stratocumulus over the eastern Pacific. This cloud is linked to the semi-permanent sub-tropical highs that dominate the low-level circulation over the Pacific and Atlantic. Subsidence on the eastern flank of these highs creates an inversion based about 800 m above sea level that caps moist air near the surface. This air overlies cool waters driven by upwelling along the coastal regions of North America. Strong surface north-westerlies mix the boundary layer enough to saturate the air just below the capping inversion. Widespread stratocumulus is thus formed. All calculations were carried out using the GENESIS general circulation model that was run at MSFC. Among the more important properties of the model is that it includes radiative forcing due to absorption of solar radiation and the emission of infrared radiation, interactive clouds (both stratocumulus and cumulus types), exchanges of heat and moisture with the lower boundary. Clouds are interactive in the sense that they impact the circulation by modifying the fields of radiative heating and turbulent fluxes of heat and moisture in the boundary layer. In turn, clouds are modified by the winds through the advection of moisture. In order to isolate the effects of mid- and high-latitude stratocumulus, two runs were made with the model: one with and the other without stratocumulus. The runs were made for a year, but with perpetual July conditions, i.e., solar forcing was fixed. The diurnal solar cycle, however, was allowed for. The sea surface temperature distribution was fixed in both runs to represent climatological July conditions. All dependent variables were represented at 12 surfaces of constant sigma = p/p(sub O), where p is pressure and p(sub O) is surface pressure. To facilitate analysis, model output was transformed to constant pressure surfaces. Structures no smaller in size than 7.5 degrees longitude and 4.5 degrees in latitude were resolved. Smaller features of the circulation were parameterized. The model thus captures synoptic- and planetary-scale circulation features.

Description: Research was conducted to use the KSC Lightning Detection and Ranging (LDAR) system, together with companion data, in four subprojects: weather forecasting and advisory applications of LDAR, LDAR in relation to field mill readings, lightning flash and stroke detection using LDAR, and LDAR in relation to radar reflectivity patterns and KSC wind profiler vertical velocities. The research is aimed at developing rules, algorithms, and training materials that can be used by the operational weather forecasters who issue weather advisories for daily ground operations and launches by NASA and the United States Air Force. During the summer of 1993, LDAR data was examined on an hourly basis from 14 thunderstorm days and compared to ground strike data measured by the Lightning Location and Protection (LLP) system. These data were re-examined during 1994 to identify, number, and track LDAR-detected storms continually throughout the day and avoid certain interpretation problems arising from the use of hourly files. An areal storm growth factor was incorporated into a scheme to use current mappings of LDAR-defined thunderstorms to predict future ground strikes. During the summer of 1994, extensive sets of LDAR and companion data have been collected for 16 thunderstorm days, including a variety of meteorological situations. Detailed case studies are being conducted to relate the occurence of LDAR to the radar structure and evolution of thunderstorms. Field mill (LPWS) data are being examined to evaluate the complementary nature of LDAR and LPLWS data in determining the time of beginning and ending of the ground strike threat at critical sites. A computerized lightning flash and stroke discrimination algorithm has been written that can be used to help locate the points of origin of the electrical discharges, help distinguish in-cloud, cloud-ground, and upward flashes, and perhaps determine when the threat of ground strikes has ceased. Surface wind tower (mesonet), radar, sounding, and KSC wind profiler data will be used to develop schemes to help anticipate the timing and location of new thunderstorm development. Analysis of this data will continue in graduate student research projects.

Description: In a previous study, we used a modified two-space scatterer formalism of Twersky to establish for a cloud modeled as a statistically homogeneous distribution of spherical water droplets, the dispersion relations that determine its bulk propagation numbers and bulk indexes of refraction in terms of the vector equivalent scattering amplitude and the dyadic scattering amplitude of the single water droplet in isolation. The results were specialized to the forward direction of scattering while demanding that the scatterers preserve the incident polarization. We apply this approach to obtain specific numerical values for the macroscopic parameters of the cloud. We work with a cloud of density rho = 100 cm(exp -3), a wavelength lambda = 0.7774 microns, and with spherical water droplets of common radius alpha = 10 microns. In addition, the scattering medium is divided into three parts, the medium outside the cloud, moist air (the medium inside the cloud but outside the droplets), and the medium inside the spherical water droplets. The results of this report are applicable to a cloud of any geometry since the boundary does not interfere with the calculations. Also, it is important to notice the plane wave nature of the incidence wave in the moist atmosphere.

Description: In this paper the data simulation and data inversion studies for stellar occultation measurements are discussed. The specific application is the Global Ozone Monitoring by Occultation of Stars (GOMOS) instrument which has been proposed for the first European Platform, Polar Orbiting Earth Mission (POEM-1).

Description: Accurate, detailed maps of total ozone were not available until the launch of the Total Ozone Mapping Spectrometer (TOMS) in late 1978. However, the Scanning Radiometer (SR), an instrument on board the NOAA series satellites during the 1970s, had a visible channel that overlapped closely with the Chappuis absorption band of ozone. We are investigating whether data from the SR can be used to map Antarctic ozone prior to 1978. The method is being developed with 1980s data from the Advanced Very High Resolution Radiometer (AVHRR), which succeeded the SR on the NOAA polar-orbiting satellites. Visible-derived total ozone maps can then be compared able on the NOAA satellites, which precludes the use of a differential absorption technique to measure ozone. Consequently, our method works exclusively over scenes whose albedos are large and unvarying, i.e. scenes that contain ice sheets and/or uniform cloud-cover. Initial comparisons of time series for October-December 1987 at locations in East Antarctica show that the visible absorption by ozone in measurable and that the technique may be usable for the 1970s, but with much less accuracy than TOMS. This initial test assumes that clouds, snow, and ice all reflect the same percentage of visible light towards the satellite, regardless of satellite position or environmental conditions. This assumption is our greatest source of error. To improve the accuracy of ozone retrievals, realistic anisotropic reflectance factors are needed, which are strongly influenced by cloud and snow surface features.

Description: Comparisons of satellite-derived temperatures with correlative temperatures indicate that the LIMS temperatures are accurate and contain more of the needed vertical resolution for calculating a residual mean circulation for transporting tracer-like species. Generally, the LIMS temperatures are accurate to at least 2 K. Other satellite data sets are comprised of temperatures with coarser vertical resolution, leading to biases that occur with an error pattern that is characteristic of their resolution. Their biases exceed 2 K at some altitudes. Retrievals of species using an infrared limb emission technique are sensitive to any temperature bias. Generally, the IMS comparisons with other data sets for ozone and water vapor are good to better than 20 percent; this represents an independent confirmation of the quality of LIMS and temperatures. Zonal mean comparisons between LIMS and SAMS temperatures also indicate agreement to better than 2 K from about 7 to 2hPa. Therefore, we are confident that SAMS N2O and CH4 are relatively free of temperature bias in that region. These factors support the generally good agreement in G90 between model N2O transported using a LIMS-derived RMC and the N2O contours from SAMS.

Description: Differences in wavelength pair ozone values determined from Backscattered Ultraviolet (BUV) instrument measurements are directly correlated with scene reflectivity which, in turn, is a function of scene cloudiness. At low solar zenith angles (overhead sun), maximum discrepancies between pair values of 2 to 3 percent. These discrepancies are believed to be due to algorithmic behavior and imply a mean error in the final derived ozone of approximately 5 percent for cases of 50 percent reflectivity. Results using a new algorithm show a significant decrease in pair discrepancy and, therefore, in the error of the final derived ozone.

Description: Total ozone operational algorithms use climatological mean ozone profiles. When the actual ozone profiles have significantly different shapes versus the climatology and the solar zenith angles are large, retrieved total ozone will have an error. Recalibrated SBUV profiles are used to estimate this error. Preliminary results suggest that, on the average, the change and variation in significant profiles shapes can to a large degree be estimated by the SBUV derived profiles. Preliminary results suggest the average error in the report algorithm ozone trend (trend in reported ozone) from profile shape is relatively small during the north hemisphere winter (less than 2 percent) for solar zenith angles less than 82 degrees (for 60 degrees North Latitude).

Description: An asymptotic approach to solution of the inverse problems of remote sensing is presented. It consists in changing integral operators characteristic of outgoing radiation into their asymptotic analogues. Such approach does not add new principal uncertainties into the problem and significantly reduces computation time that allows to develop the real (or about) time algorithms for interpretation of satellite measurements. The asymptotic approach has been realized for estimating vertical ozone distribution from satellite measurements of backscatter solar UV radiation in the Earth's atmosphere.

Description: The difference in the vertical ozone profile at Syowa between 1966-1981 and 1982-1988 is shown. The month-height cross section of the slope of the linear regressions between ozone partial pressure and 100-mb temperature is also shown. The vertically integrated values of the slopes are in close agreement with the slopes calculated by linear regression of Dobson total ozone on 100-mb temperature in the period of 1982-1988.

Description: An ozone lidar system was installed at the National Institute for Environmental Studies (NIES) in Tsukuba, Japan in March 1988 and has been measuring vertical profiles of ozone (15 - 45 km) since September 1988. The lidar system consists of a XeCl (308 nm) excimer laser, its deuterium Raman shifter (339 nm), a XeF excimer laser (351 nm), a 2 m telescope, a receiving system and a data processing system. The precision of the derived ozone concentration is about 10 percent of an altitude of 40 km for a 4 hr observation. Temperature profiles (30 - 80 km) are also obtained from the Rayleigh scattering signals at 351 nm. Approximate 50 ozone measurements are carried out in a year and variations of vertical profiles of ozone such as seasonal variations and shorter-term variations are observed. Systematic errors due to aerosols had been negligible until the arrival of the stratospheric aerosols injected by the eruption of Mt. Pinatubo. Effects of the volcanic aerosols on ozone measurements depend on the differences between wavelengths used as the on- and off-resonance.

Description: A vertical ozone profile obtained by an in situ ozone sonde from 16 km to 45 km, has allowed to observe local ozone concentration variations. These variations can be observed, thanks to a fast measurement system based on a UV absorption KrF excimer laser beam in a multipass cell. Ozone standard deviation versus altitude calculated from the mean is derived. Ozone variations or fluctuations are correlated with the different dynamic zones of the stratosphere.

Description: Ozone data recorded by balloon-borne sondes released at various sites around the world revealed that frequently the vertical ozone distribution in the stratosphere is remarkably laminated. Recently, measurements of ozone profiles near the winter polar vortex have shown strong laminae close to the vortex boundary. Also, a statistical study published recently has shown that laminae are most commonly found between 12 and 18 km at high latitudes in winter and spring in both hemispheres but they are not found in the tropics and are rarely observed in the subtropics. Ozonesonde ascents performed in Athens (37.9 deg N, 23.8 deg E) during the winter 1991-1992 in the framework of the European Arctic Stratospheric Ozone Experiment (EASOE) have shown that the lamination phenomenon was very frequently present in our region which is in contradiction with previous measurements at our latitudes. The characteristic minimum of ozone at 15 km has been also detected. Finally, the correlation of the occurrence of these two phenomena in relation with the circulation of air masses showed that the laminated profiles are connected in the lower stratosphere while the appearance of the ozone minimum around 15 km is connected with the influence of the subtropical jet-stream.

Description: Results obtained with experimental balloon electrochemical and chemiluminescent ozonesondes are summarized and estimated as quite satisfactory. The average normalization factor for the electrochemical ozonesonde obtained in 1991 at four Soviet balloon routine network stations is 1.069+.073 (in 17 flights). Some ozone profiles obtained in summer 1991 at Volgograd are discussed together with corresponding meteorological data.

Description: Vertical distribution profiles of N2O and CH4 have been measured from Hyderabad, India using a balloon-borne cryogenic air sampler. The samples have been analyzed using gas chromatographic techniques. Results for two balloon flights made in 1987 and 1990 show effects of tropical characteristics like higher tropopause and upwelling motion due to Hadley circulation. These profiles also exhibit perturbations around 25 km height, which are likely to be due to dynamical effects. A comparison with the SAMS data show that the SAMS values for both these gases are higher by a factor of about 1.5 to 2 around 30 km height.

Description: The WMO ozone sonde intercomparison was held at Vanscoy, Saskatchewan from May 13 to May 24, 1991. The purpose of the intercomparison is to evaluate the performance of various ozone sonde types used operationally in the Global Ozone Observing System and to ensure that the accuracy and precision of the measurements are sufficient to detect long-term trends in stratospheric ozone. The intercomparison was sponsored by WMO and hosted by the Atmospheric Environment Service (AES) of Canada. It was attended by scientists from six countries: Canada, Finland, Germany, India, Japan and USA. A total of 10 balloon payloads were launched each carrying 7 or 8 sondes for a total of 67 successful ozone sonde flights. The payloads were carried to altitudes between 35 and 40 km where the flights terminated by balloon burst. Results of the profile measurements made during the series of the profile measurements made during the series of flight are used to determine statistically meaningful evaluations of the different sonde types. A description of the payload and the different ozone sondes is given. Preliminary results of the profile measurements and an evaluation of the performance of the sonde types are presented.

Description: The Ozone Watch, initiated in March, 1992, is a weekly bulletin describing the state of the ozone layer over Canada. The UV-B advisory program, which started in May, 1992, produces daily forecasts of clear-sky UV-B radiation. The forecast procedures use daily ozone measurements from the eight-station monitoring network, the output from the Canadian operational forecast model and a UV-B algorithm based on three years of spectral UV-B measurements with the Brewer spectrophotometer.

Description: This paper compares results of lidar and Umkehr measurements, made during 1985-1991, which include 110 coincidences. The Umkehr ozone profiles were retrieved using the conventional Umkehr method (Gotz et al., 1934; Mateer and Dutsch, 1964), the short Umkehr method (De Luisi, 1979), and the recently developed new-conventional Umkehr method (Mateer and De Luisi, 1992) in which the conventional method is referred to as the '1964 algorithm' and the new-conventional method as the '1991 algorithm'. Results obtained show good agreement between the ozone profiles derived using the new-conventional Umkehr method and lidar ozone profiles, emphasizing the influence of the temperature dependence of the ozone cross-sections on the Umkehr ozone retrievals.

Description: A comparison of 1262 cases of coincident ozone profiles derived from 666 Umkehrs at 17 different stations and 901 SAGE 2 profiles within 1000 km and 12 hours between October 1984 and April 1989 indicates the following layer percentage differences with 2-sigma error bars: layer three 14.6 plus/minus 3.3 percent, layer four 17.6 plus/minus 1.1 percent, layer five -1.3 plus/minus 0.5 percent, layer six -5.7 plus/minus 0.7 percent, layer seven -1.0 plus/minus 0.7 percent, layer eight 4.2 plus/minus 0.7 percent, and layer nine 6.8 plus/minus 1.2 percent. Comparing SAGE 2-Umkehr differences to SAGE 1 version 5.5-Umkehr differences shows SAGE 2 higher than or equal to SAGE 1 relative to Umkehr in all layers except layer three. Adjustment for this bias would produce trends derived from SAGE 2-SAGE 1 differences and Umkehr observations in the 1980s more nearly equal to each other in layers six, seven, and eight. A possible explanation of these differences is a systematic shift in the reference altitude between SAGE 1 and SAGE 2, but there is no independent evidence of this. While the shape of the vertical profile of differences at 17 individual Umkehr stations (mostly in mid-latitudes) is generally consistent at all stations except at Poker Flat, Seoul, and Lauder, significant variation does exists among the stations. The profile of mean difference is similar to previously observed differences between Umkehr and both SAGE 2 and SBUV and also to an eigenvector analysis, but with site-dependent amplitude discrepancies. Because of the close correspondence of stratospheric aerosol optical depth at the SAGE 2-measured 0.525 micron wavelength and the extrapolated 0.32 Umkehr wavelength determined in this study, we use the 0.525 micron data to determine the aerosol effect of Umkehr profiles. The aerosol errors to the Umkehr ozone amounts in percent ozone amount per 0.01 stratospheric aerosol optical depth range from plus 2 percent in layer six to minus 3 percent in layer nine. These results agree with previous theoretical and empirical studies within their respective error bounds in layers nine, eight, and five. The result in layer six differs significantly from previous works. In view of the fact that SAGE 2 and Umkehr produce different ozone retrievals in layers eight and nine and because the intra-layer correlation of SAGE 2 ozone and aerosol in layers eight and nine in non-zero, one must exercise some caution in attributing the entire SAGE 2-Umkehr differences in the upper layers to an aerosol effect.

Description: Studies of the depletion of ozone which have been conducted from the TOMS instrument on the NIMBUS 7 satellite indicate that total ozone has declined by 5 percent over the last 12 years at most mid-latitudes in the Northern Hemisphere typical of southern Ontario. The measurement of the actual resultant increases in UVB is now important. A monitoring program of UVB (biologically active solar ultraviolet radiation) has been conducted for the last 24 months at a site near Bolton, Ontario. The sunburn time varies from less than 17 minutes in late July, to over 4 hours in December on clear days. The levels depend on solar insolation and total ozone column. The ultraviolet levels are strongly affected by cloud and sky conditions. The implications of present and future depletion on the sunburn time are discussed.

Description: Results of field tests on a group of broadband UV-B pyranometers are presented. A brief description of the instrument is given. The effects of ambient temperature on thermally unregulated fluorescent phosphor (Robertson type) meters are presented and compared with the performance of thermally stabilized instruments. Means for correcting data from thermally unregulated instruments, where the prevailing ambient temperatures are known, are outlined.

Description: The monitoring of vertical profiles of ozone and related minor constituents in the atmosphere are of great significance to understanding the complex interaction between atmospheric dynamics, chemistry and radiation budget. An ultra high spectral resolution tunable CO2 laser heterodyne radiometer has been designed, developed and set up at the National Physical Laboratory, New Delhi to obtain vertical profiles of various minor constituents the characteristic absorption lines in 9 to 11 micron spectral range. Due to its high spectral resolution the lines can be resolved completely and data obtained are inverted to get vertical profiles using an inversion technique developed by the author. In the present communication the salient features of the laser heterodyne system and the results obtained are discussed in detail.

Description: In the present study the standard retrieval Umkehr method to estimate the vertical distribution of ozone was updated using a statistical approach to the mathematical inversion scheme. The vertical ozone profile covariance matrix was used as a priori information for the inverse problem. A new method of the ozonesonde data organization according to air mass types helped to improve the covariance matrix quality. A retrieval method was developed using eigenvector technique. An optimal vertical ozone profile resolution was determined from the mathematical inversion scheme analysis based on the same technique. The sun radiation transfer was accounted for multiple scattering and atmospheric sphericity in this calculation. The retrievals using actual Umkehr Dobson spectrophotometer observations were also performed to provide the comparison of the standard and updated methods with concurrent ozone sound data at Boulder U.S. The comparison has revealed that the present method has some advantages in both resolution and accuracy, as compared to the standard one, especially for the atmospheric layers below ozone maximum.

Description: The results of systematic perennial measurements of the total ozone (since 1979) and nitrogen dioxide column (since 1983) in the atmosphere in the European-Asian continent center above the mountainmass of the Tien Shan are given. This region is distinguished by a great number of sunny days during a year. The observation station is at the Northern shore of Issyk Kul Lake (42.56 N 77.04 E 1650 m above the sea level). The measurement results are presented as the monthly averaged atmospheric total ozone and NO2 stratospheric column abundances (morning and evening). The peculiarities of seasonal variations of ozone and nitrogen dioxide atmospheric contents, their regular variances with a quasi-biennial cycles and trends have been noticed. Irregular variances of ozone and nitrogen dioxide atmospheric contents, i.e. their positive and negative anomalies in the monthly averaged contents relative to the perennial averaged monthly means, have been analyzed. The synchronous and opposite in phase anomalies in variations of ozone and nitrogen dioxide atmospheric contents were explained by the transport and zonal circulation in the stratosphere (Kamenogradsky et al., 1990).

Description: Regular spectral UV-B measurements with a Brewer spectrophotometer have been performed at Hohenpeissenberg since 1990. Intercomparison of the Brewer instrument with other UV-B monitoring devices have shown agreement to within plus or minus 10 percent. Comparisons of UV-B spectra measured on fair weather days reveal the well known increasing influence of ozone on UV-B irradiance with decreasing wavelengths. The integral amplification factor the erythemal irradiance reaches values up to 2.8, which can be diminished by increasing turbidity. The influence of cirrus cloud on the UV-B is also shown.

Description: A MKII Brewer ozone spectrometer was used in Beijing from Oct. 1990 to June 1991 to measure O3, SO2 and UVB radiation. And since Nov. 1991 a new MKIV Brewer spectrometer, which can take the measurements of O3, SO2, NO2 and UVB radiation, has been set up in Beijing. The MKII Brewer spectrometer was moved to Qinghai baseline station which is on the Qinghai-tibetean plateau in the northwestern part of China. Both the data in Beijing and Qinghai baseline station has been analyzed and some results will be shown here along with the ozone profiles botained through the Umkehr program given by AES of Canada for the Brewer ozone spectrometer.

Description: Presented are the experimental data on the total ozone content obtained during continuous measurements (day-night-...-night-day) by Brewer 044 spectrophotometer near the Issyk Kul Lake (42.59N, 77.04W) at 1650 m above the sea level at full moon from 13 to 18 October 1989 under anomalously high transparent atmospheric conditions (the horizontal visibility range exceeded 50 km). At night the total O3 content decreased regularly to about 20 percent of the average daytime values. The minimum values at night were observed in 1-2 hours after the maximum solar dip below the horizon. In the daytime the measurements were carried out from direct Sun, at night - from the Moon. The values of the total ozone content for adjacent measurements from the Sun and from the Moon in the evening as well as in the morning are in good agreement.

Description: Measurements of the total column of ozone and NO2 were obtained by a SAOZ UV/Visible spectrometer at Aberystwyth (52.4 deg N, 4.1 deg W) and Lerwick (60.1 deg N, 1.2 deg W) during the period March 1991 - April 1992. NO2 measurements show a marked decrease in 1992 compared with 1991, due to the effect of aerosols from Mt. Pinatubo. Ozone measurements appear to have been affected by the aerosols - comparisons with both Dobson and TOMS measurements are presented.

Description: Total ozone observations of two Dobson instruments (D15 and D101, C- and AD wavelength pair observations) and of two Brewer instruments (Br40 and Br72) are currently performed at the LKO at Arosa. A quality control concept is presented in order to make best use of the large number of quasi-simultaneous measurements. The longest ozone series of the world is mainly based on the measurements of the Dobson instrument D15 (wavelength pair C). Since the last years D15 has suffered from instrumental problems. The transformation of the longterm series to the measurements of D101(AD) is described.

Description: GASCOD, a near-ultraviolet and visible differential optical spectrometer, was developed at CNR's FISBAT Institute in Bologna, Italy, and first tested at Terra Nova Bay station in Antarctica (74.6 deg S, 164.6 deg E) during the summer expeditions 1988-1990 of PNRA (PNRA is the national research program in Antarctica, 'Programma Nazionale di Ricerche in Atartide'). A comparison with coincident O3 total column measurements taken in the same Antarctic area is presented, as is another comparison performed in Italy. Also introduced is an updated model for solar zenith measurements taken from a ground-based, upward-looking GASCOD spectrometer, which was employed for the 1991-92 winter campaign at Aer-Ostersund in Sweden (63.3 deg N, 13.1 deg E) during AESOE (European Arctic Stratospheric Ozone Experiment). The GASCOD can examine the spectra from 300 to 700 nm, in 50 nm steps, by moving the spectrometer's grating. At present, it takes measurements of solar zenith radiation in the 310-342 nm range for O3 and in the 405-463 nm range for NO2.

Description: In May of 1991 a tunable diode laser heterodyne spectrometer built by the National Physical Laboratory was operated at the International Scientific Station of the Jungfraujoch (46.5 deg N, 8.0 deg E, altitude 3.56 km). Nitric acid spectra in the region of 868 wavenumbers were recorded at sunset and sunrise on two separate days at a resolution of 0.0013 wavenumbers with a signal-to-noise ratio of approximately 130:1. A vertical column amount of HNO3 of 1.61 x 10(exp 16) molecules/sq cm was determined using an atmospheric transmission model developed at the University of Denver. The mean of a number of mid-latitude, northern hemisphere profiles was used as the initial profile for the inversion. A comparison of different initial profiles provides information on the sensitivity of the retrieved column amount of 1.61 x 10(exp 16) molecules/sq cm lies within the range of values published in the World Meteorological Organization Report no. 16 (1986), but is considerably larger than the value of (0.99 - 1.29) x 10(exp 16) reported by Rinsland et al. (1991) for June during the period 1986 to 1990.

Description: Total ozone and NO2 were measured aboard a ship in the 40S - 40N latitude band in the Atlantic Ocean in the second half of May 1988. The main features of the latitudinal distributions of total NO2 and ozone are similar. There is seen an increase of total ozone and NO2 from the tropical to subtropical latitudes, strongest in the region of the subtropical jet stream. The fine structure has been revealed in the total ozone and NO2 latitudinal distributions, connected most likely with stratosphere-troposphere exchange processes in the tropopause folding zone.

Description: Absorption spectrum in 436 to 448 nm wavelength region gives NO2 and O3 column densities. This spectrum can also give H2O column density. The spectrum in the range of 655 to 667 nm contains absorption due to NO3 and H2O. Combining the absorption spectra in the wavelength ranges of 436 to 448 and 655 to 667 nm, water vapor absorption cross-sections in this range comes out to be of the order of 2.0 x 10(exp -24) cm(exp -2).

Description: The present study concentrates on measurements of NO2 and NO3. NO2 has been measured during twilight period using zenith sky absorption spectrometric technique in the 436 to 448 nm region. NO3 has been measured during night time using direct moon as a source of light in the 655 to 667 nm region. These measurements have been taken at low latitude station, Ahmedabad (23 deg N, 76 deg E), India for the past two years.

Description: In the last years much progress has been made in the field of the detection of stratospheric trace constituents. However, only few techniques are suitable to detect ClO, one of the key constituents in ozone depletion chemistry. One of these techniques is mm-wave radiometry. This work presents the first measurements performed by a new 204 GHz radiometer at the Jungfraujoch Alpine Station.

Description: The degree of polarization of skylight at the zenith during twilight depends on the aerosol content in the atmosphere. The long-term observations at the high-mountain research station 'Kislovodsk' (North Caucasus) have shown that the variation of the degree of polarization after the eruption of the El Chichon volcano can serve as the effective parameter characterizing the vertical aerosol stratification in the atmosphere. The results of the measurements are confirmed by the numerical calculations. The algorithm of the retrieval of the vertical aerosol distribution on the base of the measurements of the degree of polarization is proposed. This method can be applied for the increasing of the precision of O3, NO2, and other gas content measurements.

Description: The results of the measurements of the NO2 total content at the 'Kislovodsk' observatory (North Caucasus 2070 m a.s.l.) in 1979-1990 are presented. The measurements were based on the absorption of the direct sunlight in the visible region of the spectrum. The variation of the NO2 content from the morning to the evening and the seasonal and year to year variations are analyzed. The less amplitude of the daily variations of the NO2 total content in comparison with the variations of the stratospheric NO2 content says about the significant insert of the tropospheric and lower stratospheric NO2 in its total content. The year to year variations of NO2 and ozone are in antiphase. Their values depends on the regional features of the atmospheric circulation. The quasibiennial oscillations of the total NO2 content are picked out.

Description: Presented are the experimental data on the daytime course of the total O3 and SO2 content obtained by Brewer 044 spectrophotometer in the tropics (Thumba, India, 8.53 N, 76.87 W, March-May 1990) and at middle latitudes (Obninsk, Russia, 55.12 N, 36.6 W, May-October 1991) of the Northern Hemisphere. The analysis showed that under fine warm weather conditions without precipitation (air mass change and frontal passage were not observed during several days) in days with well-developed convective clouds (cloudless morning, convective clouds in the daytime, no clouds in the evening) there is a typical nearly symmetric (with respect to local noon) course of the total O3 (with the minimum at about local noon) and SO2 (with the maximum at about local noon) content. The minimum depth is about 2-5 percent of the average daytime values of the total ozone content. The synchronous measurements of pressure pulsations with microbarograph (they are the indicator of convective and turbulent motion development in the lower subcloud atmospheric layer) showed that during these days there is a nearly symmetric course of pressure pulsations with the maximum at about local noon.

Description: Under the auspices of the World Meteorological Organization, Environment Canada hosted an international comparison of visible light spectrophotometers at Mt. Kobau, British Columbia in August of 1991. Instruments from four countries were involved. The intercomparison results have indicated that some significant differences exist in the responses of the various instruments, and have provided a basis for the comparison of the historical data sets which currently exist as a result of the independent researches carried out in the past in the former Soviet Union, New Zealand, and Canada.

Description: For many years the airmass dependence of total ozone measurements at Belsk has been observed to vary noticeably from one day to another. Series of AD wavelength pairs measurements taken out to high airmass were analyzed and compared with the two parameter stray light model presented by Basher. The analysis extended to the series of CD measurements indicates the role of atmospheric attenuation in appearing the airmass dependence. The minor noon decline of total ozone has been observed in the CD measurement series similarly as in those of the AD wavelength pairs. Such errors may seriously affect the accuracy of CD measurements at high latitude stations and the observations derived in winter at middle latitude stations.

Description: The Japan Meteorological Agency started the spectral observation of solar ultraviolet (UV) irradiance on 1 January 1990 at Tateno, Aerological Observatory in Tsukuba (35 deg N, 140 deg E). The observation has been carried out using the Brewer spectrophotometer for the wavelengths from 290 to 325 nm with a 0.5 nm interval every hour from 30 minutes before sunrise to 30 minutes after sunset throughout a year. Because of remarkable similarity within observed spectra, an observed spectrum can be expressed by a simple combination of a reference spectrum and two parameters expressing the deformation of the observed spectrum from the reference. By use of the relation between one of the deformation parameters and the total ozone simultaneously observed with the Dobson spectrophotometer, the possible increase of UV irradiance due to ozone depletion is estimated. For damaging UV, the irradiance possibly increases about 19 percent with the ozone depletion of 10 percent at noon throughout the year in the northern midlatitudes. DUV at noon on the summer solstice possibly increases about 5.6 percent with the ozone depletion of 10 m atm-cm for all latitudes in the Northern Hemisphere.

Description: An overview of two years of data obtained with a ground-based microwave instrument is given. Intercomparisons with data obtained by the co-located JPL lidar and by SAGE 2 during near overpasses of the site are discussed, as are comparisons with mesospheric data taken earlier by SME and LIMS. Observations of diurnal variations of mesospheric ozone are shown.

Description: Absolute measurements of UV-irradiances in Germany and New Zealand are used to determine the total amounts of ozone. UV-irradiances measured and calculated for clear skies and for solar zenith angles less than 60 deg generally show a good accordance. The UVB-irradiances, however, show that the actual Dobson values are about 5 percent higher in Germany and about 3 percent higher in New Zealand compared to those obtained by our method. Possible reasons for these deviations are discussed.

Description: Important changes in the ozone vertical profile over South Pole, Antarctica have occurred both during the recent period of measurements, 1986-1991, and since an earlier set of soundings was carried out from 1967-1971. From the onset of the 'ozone hole' over Antarctica in the early 1980s, there has been a tendency for years with lower spring ozone amounts to alternate with years with somewhat higher (although still depleted) ozone amounts. Beginning in 1989 there have been three consecutive years of strong depletion although the timing of the breakdown of the vortex has varied from year to year. Comparison of the vertical profiles between the two periods of study reveals the dramatic decreases in the ozone amounts in the stratosphere between 15-21 km during the spring. In addition, it appears that summer values are also now much lower in this altitude region.

Description: The column amounts of NO2 and ozone have been measured using visible spectroscopy at Syowa Base (69 deg S) since March 1990. Ozone was also measured at the same location with a Dobson spectrometer as well as ozonesondes being flown regularly. The characteristic features of the seasonal and diurnal variations of NO2 are presented. The column ozone values from the visible spectrometers are compared with the Dobson data. The very low values of NO2 in midwinter and early spring are consistent with the conditions predicted to be needed for heterogeneous ozone destruction in early spring. In late spring and summer of 1991, NO2 amounts were considerably smaller than in 1990, presumably due to the effect of Mt. Pinatubo eruption.

Description: Two FTIR spectrometers were employed in the late winters 1990 and 1991 in Esrange, North Sweden, and in Ny Aalesund, Spitsbergen to detect zenith column amounts of several trace gases. Time series of column amounts of the trace gases O3, N2O, CH4, HNO3, NO2, CHl, and HF have been derived from the measured spectra. Additionally, some information on the vertical distribution of HCl could be obtained by analyzing the spectral line shapes. The results are interpreted in terms of dynamical and chemical processes.

Description: This paper compares coincident ozone profile measurements by electrochemical sondes and lidar performed at Ny-Alesund/Spitsbergen. A detailed height dependent statistical analysis of the differences between these complementary methods was performed for the overlapping altitude region (13-35 km). The data set comprises ozone profile measurements conducted between Jan. 1989 and Jan. 1991. Differences of up to 25 percent were found above 30 km altitude.

Description: Ozone sonde data of the winters 1988/89, 1989/90, and 1990/91 from a group of Arctic stations are used in this study. The ozone mixing ratio on several isentropic surfaces is correlated to the potential vorticity (P). The P is based on the initialized analysis data from the European Center for Medium-Range Weather Forecasts. Similar investigations were made by Lait et al. (Geophys. Res. Lett., 17, 521-524, March Supplement 1990) for the AASE campaign (January and February 1989), showing how the ozone mixing ratio varies with the distance to the edge of the vortex. Their findings are confirmed and extended to the following two winters. Furthermore we have studied the temporal development of the P-ozone correlations during these winters in order to recognize any chemical ozone depletion.

Description: Balloon measurements of the vertical distribution of ozone and aerosol were made at Dickson Island (73 deg N, 81 deg E), Kiruna (68 deg N, 20 deg E) and Heiss Island (81 deg N, 58 deg E) from December 1991 to March 1992. To acquire data on the seasonal variability of the vertical ozone distribution, electrochemical ozonesondes ECC-4A were flown three times a week. With ozonesondes on the same balloons, backscattersondes were flown on the average of two or three times per month. Using these instruments, altitude profiles of backscatter ratio were measured at two wavelengths centered at 490 nm and 940 nm. Additionally, at Heiss Island, Dickson, and Yakutsk (63 deg N, 130 deg E) regular total ozone measurements were obtained using Brewer spectrophotometers. Based on measurements of backscatter ratio it was found that after the Pinatubo eruption in June 1991 significant amount of stratospheric aerosols were formed and transported to the Arctic before the polar vortex was well developed. Analysis of ozone data has shown a deep decrease of ozone concentration in the lower stratosphere in times of intensive transportation of air masses from low latitudes to the polar region in the second half of January and also for some periods in February and March of 1992. When the values of backscatter ratio beta were more than 8-10 at a wavelength of 940 nm strong anticorrelation occurred between aerosol loading and ozone concentration in the lower stratosphere. At 50-70 deg N, the mean monthly values of total ozone in winter-spring 1992 proved to be much lower than the climatic mean values.

Description: A three-dimensional chemical transport model (CTM) (Kaminski, 1992) has been used to study the evolution of the Arctic ozone during the winter of 1992. The continuity equation has been solved using a spectral method with Rhomboidal 15 (R15) truncation and leap-frog time stepping. Six-hourly meteorological fields from the Canadian Meteorological Center global objective analysis routines run at T79 were degraded to the model resolution. In addition, they were interpolated to the model time grid and were used to drive the model from the surface to 10 mb. In the model, processing of Cl(x) occurred over Arctic latitudes but some of the initial products were still present by mid-January. Also, the large amounts of ClO formed in the model in early January were converted to ClNO3. The results suggest that the model resolution may be insufficient to resolve the details of the Arctic transport during this time period. In particular, the wind field does not move the ClO(x) 'cloud' to the south over Europe as seen in the MLS measurements.

Description: Ultraviolet absorption cross-section of six alternative hydrochlorofluorocarbons (HCFC-21 HCFC-22, HCFC-123, HCFC-124, HCFC-141b and HCFC-142b1) have been measured between 170 and 260 nm for temperature ranging from 210 to 295 K. These data are compared with other available determinations performed at room temperature and their temperature dependence is discussed. Photodissociation coefficients are estimated and their temperature dependence is discussed. Impact of the photodissociation on the total atmospheric destruction of these compounds is illustrated.

Description: An international comparison of Dobson ozone spectrophotometers, organized and partially funded by the World Meteorological Organization (WMO), was held at the Lichtklimatisches Observatorium (LKO) in Arosa, Switzerland, July-August 1990. Countries participating with a total of 18 Dobson instruments were Belgium, Czechoslovakia, Denmark, Germany, Greece, Hungary, Iceland, Norway, Poland, Portugal, Rumania, Spain, Switzerland, the United Kingdom, the United States, and the United Soviet Socialist Republics. The reference standard instrument for the comparison was U.S.A. Secondary Standard Dobson Spectrophotometer 65 maintained by the NOAA Climate and Monitoring and Diagnostics Laboratory, Boulder, Colorado. The mean difference in ozone obtained with the Dobson instruments relative to Dobson instrument 65, calculated from ADDSGQP observations in the air mass range 1.15-3.2, was minus 1.0 plus or minus 1.2 (1 sigma) percent. The WMO Standard Brewer Spectrometer 39 also participated. In the mean, the Brewer instrument measured 0.6 plus or minus 0.2 (1 sigma) percent more ozone than did Dobson instrument 65. Results are presented, also, of ozone vertical profile measurements made with the Dobson instruments, two Brewer spectrometers, a LIDAR, a balloon ozonesonde flown from Hohenpeissenberg, Germany, and balloon ozonesondes flown from Payerne, Switzerland.

Description: During deliberations of the International Ozone Trends Panel (IOTP) it became obvious that satellite determinations of global ozone amounts by themselves could not provide the necessary confidence in the measured trends. During the time of the deliberations of the IOTP, Bojkov re-examined the records of serveral North American Dobson stations and Degorska re-examined the records of the Belsk station. They were able to improve the quality of the data sets, thus improving the precision of their total ozone data sets. These improvements showed the greater potential of the world-wide Dobson total ozone data set in two primary areas. Firstly, the improvements showed that the existing data set when evaluated will become more valuable for comparisons with satellite determinations of total ozone. Secondly, the Dobson data set covers a greater period of time than the satellite data sets thus offering the possibility of extending improved information on ozone trends further back in time. An International Dobson Workshop was convened in September, 1991, under the auspices of the NOAA Climate and Global Change Program. It was part of the Information Management element of the C&GC Program. Further, it was considered as a 'data archaeology' project under the above. Clearly if the existing Dobson data set can be improved by re-evaluating all data records, we will be able to uncover the 'true' or 'best' data and fulfill the role of archaeologists.

Description: Long-term column ozone density measurements have been carried out in Norway and USSR. Data from Tromso and two meridional chains in USSR are analyzed, and most of the stations show that no significant decreasing trend in ozone has occurred during the last two decades.

Description: Total ozone measurements with the Dobson No. 104 (D 104) have been performed at the Meteorological Observatory Hohenpeissenberg since 1967. A critical review of this time series and the comparison with other instruments like TOMS or Brewer spectrophotometer revealed some intervals with uncertainties. Especially in the early eighties a monthly mean bias of about minus 3 percent to TOMS-data with annual variations depending on the mean sun-height exists. An extreme amplitude of 5.6 percent occurs in 1980 with minus 0.76 percent (February) and minus 6.36 percent (July). Two different methods were applied to reprocess the Dobson data set. A comparison of the differently recalculated data showed, that the application of N-corrections by means of the standard-lamp tests starting from the reference values of the Arosa Intercomparison 1986 yields better results than the N-corrections based on a Langley-pilot of the Arosa Intercomparison 1978. The extreme amplitude of the year 1980 is now reduced to 3.02 percent. There is still a slight drift in the monthly and yearly mean differences between TOMS and revised Dobson data. It cannot be excluded, that the satellite data may be responsible for the trend.

Description: The reevaluated Dobson total ozone data from Hradec Kralove, Czechoslovakia were compared with independent Total Ozone Mapping Spectrophotometer (TOMS) 'version 6' data set. The comparison was performed by means of the parallel daily averages of ground-based and satellite total ozone pairs of the period November 1978 to December 1990. The comparison showed slight differences between both data series. Their average relative difference is 0.48 percent. The similar results have been reached for subsets of direct sun and zenith types of measurements as well. Their relative differences are 0.61 percent and 0.11 percent respectively. These facts indicate not only good mutual relation of both data sources but also reliability and accuracy of the zenith charts of the spectrophotometer No. 74 used at Hradec Kralove. Preliminary assessment of seasonal MU-dependence of the differences between Dobson and TOMS data was made while using total ozones of winter and summer months representing values of MU=2.70-5.20 and MU = 1.12-1.30 respectively. The results did not show systematic underestimation or overestimation of total ozone due to MU-dependence of the instrument at Hradec Kralove in both seasons.

Description: Backward reevaluation of long-term total ozone measurements from the Solar and Ozone Observatory of Czech Hydrometeorological Institute at Hradec Kralove, Czechoslovakia, was performed for the period 1962-1990. The homogenization was carried out with respect to the calibration level of the World Primary Standard Spectrophotometer No. 83 - WPSS by means of day-by-day recalculations of more than 25,000 individual measurements using the R-N tables reconstructed after international comparisons and regular standard lamp tests of the Dobson spectrophotometer No. 74. The results showed significant differences among the recalculated data and those original ones published in the bulletins Ozone Data for the World. In the period 1962-1979 they reached 10-19 D.U. (3.0-5.5%) for annual averages and even 26 D.U. (7.0%) for monthly averages of total ozone. Such differences exceed several times accuracy of measuring and can significantly influence character of trends of total ozone in Central Europe. Therefore the results from Hradec Kralove support the calls for reevaluation of all historical Dobson total ozone data sets at individual stations of Global Ozone Observing System.

Description: To investigate total ozone behavior in different time intervals for the 40 deg - 52 deg N and 53 deg - 64 deg N latitudinal bands sliding 11 year linear trends with the first interval from 1959 to 1969 and the final one from 1980 to 1990 were computed. The most recent 11-year trends are negative and have larger absolute values than in the past. The trend values in the period from 1980 to 1990 in the 53 deg - 64 deg N band are minus 4.3 percent (winter), minus 3.2 percent (summer), and minus 3.8 percent (annual) per decade, and in the 40 deg - 52 deg N band they are minus 5.9 percent (winter), minus 2.7 percent (summer), and minus 3.6 percent (annual) per decade.

Description: The total ozone quantity has been obtained since September 1983 at O.H.P. using the conventional AD wavelength technique. An average of 180 measurements per year is obtained with the Dobson n deg 85. Each of these daily total quantities is in fact an average of at least 5 measurements. The preliminary comparison with TOMS data show good agreement. We discuss systematic daily and monthly comparisons.

Description: Ozone measurements from the Total Ozone Mapping Spectrometer on the Nimbus 7 satellite are compared with ground-based measurements from five Dobson stations at northern latitudes to evaluate the accuracy of the TOMS data, particularly in regions north of 50 deg N. The measurements from the individual stations show mean differences from -2.5 percent up to plus 8.3 percent relative to TOMS measurements and two of the ground stations, Oslo and Longyearbyen, show a significant drift of plus 1.2 percent and plus 3.7 percent per year, respectively. It can be shown from nearly simultaneous measurements in two different wavelength double pairs at Oslo that at least 2 percent of the differences result from the use of the CC' wavelength double pair instead of the standard AD wavelength double pair. Since all Norwegian stations used the CC' wavelength double pair exclusively a similar error can be assumed for Tromso and Longyearbyren. A comparison between the tropospheric ozone content in TOMS data and from ECC ozonesonde measurements at Ny-Alesund and Bear Island shows that the amount of tropospheric ozone in the standard profiles used in the TOMS algorithm is too low, which leads to an error of about 2 percent in total ozone. Particularly at high solar zenith angles (greater than 80 deg), Dobson measurements become unreliable. They are up to 20 percent lower than TOMS measurements averaged over solar zenith angles of 88 deg to 89 deg.

Description: The total ozone amount over Oslo has been measured with the Dobson spectrophotometer No 56. The instrument was modified, calibrated, and intercompared in 1977 in Boulder. A new intercomparison was made in 1986 in Arosa. Much work has been done to make the zenith charts reliable. A new method has been introduced where one takes into account the change in the shape of the zenith chart curves which is caused by a change of the ozone profile when the ozone amount changes. According to the conclusion derived from the intercomparison in Arosa 1986, the instrument has not been stable. The R-N tables had to be altered, but not the Q-tables. We have tried to account for this change in our handling of the observation data. No statistical analyses of these data has yet been made, but the monthly averages of the raw data show a negative linear trend of about 4 percent for the whole period.

Description: The daily averages of total column amount of ozone taken in the period 1964-1988 at a network of 24 Dobson stations have been analyzed. Year-round data as well as summer data (May - Aug.) and winter data (Dec. - March) have been examined in the following regions: latitude bands (30 deg N - 39 deg N, 40 deg N - 52 deg N, 30 deg N - 60 deg N), North America, Europe, and Japan. To find year-to-year changes in the shape of the annual statistical distribution of total ozone (ASDTO) for these regions, we analyze trends in the following statistic characteristics of ASDTO: mean, standard deviation, median, and 10 and 90 percentiles. Time series of the statistical characteristics for the selected regions have been combined by averaging the individual stations values of these characteristics. The trends have been calculated by the multiple regression model adjusted for: the 11-year solar cycle, the Southern Oscillations effects, and for serial correlations. We have found that: a) in all regions (excluding Japan, North America), the shape of ASDTO has been drifting towards low ozone values. The drift seems to be not accompanied with a transformation in the shape of ASDTO. The drift speed (the rate of decrease in the annual means of total ozone) is of order 1-3 percent per decade (in the period 1970-1988). b) In Japan, the interannual changes in the shape of ASDTO have not been revealed. c) In North America, the drift of the year-round ASDTO (the year-round ASDTO comprises all the daily means of total ozone in a given year) has been accompanied with a transformation in the shape. The shape of the year round ASDTO becomes narrower. d) In all regions, except Japan and the band 30 deg - 39 deg N, the winter ASDTO (the winter ASDTO comprises the data taken in the period December in a given year through March next year) moves faster towards low ozone values than the summer ASDTO (the summer ASDTO comprises the data taken in the period May through August in a given year).

Description: A Brewer Ozone Spectrophotometer has been in service at the Canadian ozone monitoring station at Stony Plain (53.55 deg N, 114.10 deg W), near Edmonton, Alberta, since 1984. During that time, the instrument has been operated in a fully automated mode that includes the collection of morning and evening Umkehr observations. Some 197 Umkehr observations have been analyzed to make an estimate of the temporal trend in ozone amount at high altitude over the station during the last 8 years. This work has shown that at 40 km the trend in the ozone concentration has been observed to be 0.14 plus or minus 0.10 percent per year.

Description: Annual extremes of total column amount of ozone (in the period 1964-1988) from a network of 29 Dobson stations have been examined using the extreme value analysis. The extremes have been calculated as the highest deviation of daily mean total ozone from its long-term monthly mean, normalized by the monthly standard deviations. The extremes have been selected from the direct-Sun total ozone observations only. The extremes resulting from abrupt changes in ozone (day to day changes greater than 20 percent) have not been considered. The ordered extremes (maxima in ascending way, minima in descending way) have been fitted to one of three forms of the Fisher-Tippet extreme value distribution by the nonlinear least square method (Levenberg-Marguard method). We have found that the ordered extremes from a majority of Dobson stations lie close to Fisher-Tippet type III. The extreme value analysis of the composite annual extremes (combined from averages of the annual extremes selected at individual stations) has shown that the composite maxima are fitted by the Fisher-Tippet type III and the composite minima by the Fisher-Tippet type I. The difference between the Fisher-Tippet types of the composite extremes seems to be related to the ozone downward trend. Extreme value prognoses for the period 1964-2014 (derived from the data taken at: all analyzed stations, the North American, and the European stations) have revealed that the prognostic extremes are close to the largest annual extremes in the period 1964-1988 and there are only small regional differences in the prognoses.

Description: Ozone trends for 1979-1991, determined from Dobson spectrophotometer observations made at eight stations in the United States, are augmented with trend data from four foreign cooperative stations operated by NOAA/CMDL. Results are based on provisional data archived routinely throughout the years at the World Ozone Data Center in Toronto, Canada, with calibration corrections applied to some of the data. Trends through 1990 exhibit values of minus 0.3 percent to minus 0.5 percent yr(exp -1) at mid-to-high latitudes in the northern hemisphere. With the addition of 1991 data, however, the trends become less negative, indicating that ozone increased in many parts of the world during 1991. Stations located within the plus or minus 20 deg N-S latitude band exhibit no ozone trends. Early 1992 data show decreased ozone values at some of the stations. At South Pole, Antarctica, October ozone values have remained low during the past 3 years.

Description: Trend analyses, assuming a linear trend which started at 1970, were performed from total ozone measurements from Arosa (Switzerland, 1926-1991). Decreases in monthly mean values were statistically significant for October through April showing decreases of about 2.0-4 percent per decade. For the period 1947-91, total ozone trends were further investigated using a multiple regression model. Temperature of a mountain peak in Switzerland (Mt. Santis), the F10.7 solar flux series, the QBO series (quasi biennial oscillation), and the southern oscillation index (SOI) were included as explanatory variables. Trends in the monthly mean values were statistically significant for December through April. The same multiple regression model was applied to investigate the ozone trends at various altitudes using the ozone balloon soundings from Payerne (1967-1989) and the Umkehr measurements from Arosa (1947-1989). The results show four different vertical trend regimes: On a relative scale changes were largest in the troposphere (increase of about 10 percent per decade). On an absolute scale the largest trends were obtained in the lower stratosphere (decrease of approximately 6 per decade at an altitude of about 18 to 22 km). No significant trends were observed at approximately 30 km, whereas stratospheric ozone decreased in the upper stratosphere.

Description: At most of the German ozone recording stations which have records over a sufficiently long period, the results of the summer months of 1989 showed the highest values since the beginning of the measurements. One of the reasons for this phenomenon was the high duration of sunshine in that summer; for example, in Potsdam near Berlin in May 1989 the sunshine duration was the highest in May since the beginning of the records in 1893. For that reason we selected this summer for a case study. The basis for the study was mainly the ozone measuring stations of the network of Lower Saxony and the Federal Office of Environment (Umweltbundesamt). The results of these summer measurements point to intense sources of ozone, probably in form of gaseous precursors, in the Middle German industrial areas near Leipzig and Halle and in Northwestern Czechoslovakia, with coal-mining, chemical and petrochemical industries, coking plants and others. The maps of average ozone concentrations, number or days with high ozone maxima, ozone-windroses of the stations, etc., suggest that these areas could be a main source of precursors and of photochemical ozone production in summer smog episodes in Central Europe. Stations on the North Sea coast, at which early ozone measurements were made by our institute in 1973/74 are compared with similarly located stations of the Lower Saxon network in 1989 and the results show a reversal of the ozone-windroses. In 1973/74, the highest ozone concentrations were correlated with wind directions from the sea while in 1989 these concentrations were correlated with directions from the continent. In the recent years, photochemical ozone production on the continent is probably predominant, while in former years the higher ozone content of the maritime subpolar air masses has been explained by stratospheric-tropospheric exchange.

Description: Several years of satellite observations indicate the presence of enhanced amounts of tropospheric ozone over the tropical South Atlantic during the austral springs. Wide-spread biomass burning is prevalent over Africa and South America during the same time of the year. Another recent satellite technique has identified the locations of fires over the continents. In this study, we present an analysis of the prevailing meteorological conditions when the highest amounts of tropospheric ozone are present.

Description: The first Intensive Observation Period (IOP) of the Swiss air pollution experiment POLLUMET took place in 1990 in the Aare River Valley between Bern and Zurich. During the IOP, fast response measurements of meteorological variables and ozone concentration were made within the boundary layer aboard a motorglider. In addition, mean values of meteorological variables and the concentrations of ozone and other trace species were measured using other aircraft, pilot balloons, tethersondes, and ground stations. Turbulent flux profiles of latent and sensible heat and ozone are calculated from the fast response data. Terms in the ozone mean concentration budget (time rate of change of mean concentration, horizontal advection, and flux divergence) are calculated for stationary time periods both before and after the passage of a cold front. The source/sink term is calculated as a residual in the budget, and its sign and magnitude are related to the measured concentrations of reactive trace species within the boundary layer. Relationships between concentration ratios of trace species and ozone concentration are determined in order to understand the influence of complex terrain on the processes that produce and destroy ozone.

Description: Variations in the concentration of surface ozone measured at a pollution-free mountain site from March 1991 to March 1992 are reported and discussed. Two of the ozone-transport episodes are presented in this case study: a stratospheric intrusion recorded in November 1991 and a horizontal transport in August 1991.

Description: The results of the surface ozone observations at the Observatory 'Kislovodsk', situated in the North Caucasus at the altitude 2070 m a.s.l., are given. The observatory is in the background conditions and the variations of the surface ozone are determined by the natural dynamic and photochemical processes. The mean value of the concentration and its seasonal variations are very near to those obtained at the high-mountain stations in Alps. The daily variations have the features, which remain stable during all warm period of the year (April-October). These features, including the minimum of the surface ozone at noon, are formed by the mountain-valley circulation. The significant variations of the surface ozone are connected with the unstationary lee waves.

Description: Extratropical cyclones are able to transport trace gases through the whole troposphere and lower stratosphere. At mid-latitudes most of the ozone transport from the lower stratosphere down into the troposphere is accomplished by depressions. The changing the total ozone contents, associated with the variable tropopause heights, are shown to be clearly visible in satellite ozone data.

Description: The seasonal budgets and evolution of photochemical oxidants reported for greater Ravenna's urban-industrial area in the present study were calculated using the combined data from on-site systematic surveys (1978-1989) and from the monitoring network of the local environmental authorities. The notable differences in the concentrations of ozone and nitrogen oxides depended on season, and meteorological variables showed a marked correlation to the seasonal budget of trace constituents. The weak local circulation, the land-sea breeze system, and high solar radiation in summer, which may persist at length because of the anticyclonic conditions, can produce episodes of intense photochemical reactions. In winter, by contrast, low solar radiation and the absence of the breeze system results in very different evolutions of both pollutant concentrations and their seasonal budget.

Description: Over a period of more than two years (March 1989 till June 1991) ozone and nitrogen dioxide have been monitored along twelve alpine hillsides in the Austrian alps. The profiles had a height-resolution of 100 m and cover a range between 400 m and 1800 m asl, that is 100 m to 1100 m above the bottom of the valleys. They were situated in remote rural areas as well as in the vicinity of polluted urban and industrial areas. Both trace gases were monitored by means of integral chemical (SAM-surface active monitor) methods with a measuring cycle of two weeks. The concentration of ozone exhibits a substantial annual variation over the entire height range. In summer, highest ozone levels are observed near the ground and at the top of the mountains, whereas in winter the maxima are found mainly in the crest regions. The overall ozone burden shows a relative maximum near the temperature inversion layer in the valleys and an absolute maximum at the crest.

Description: Total ozone and the vertical distribution of ozone were measured at Pretoria between 1965 and 1968. Total ozone measurements recommenced in Pretoria in August 1989, and measurements of the vertical distribution of ozone near Pretoria recommenced in July 1990. Relative to the earlier data, mean monthly total ozone values are significantly higher in all months, with a mean annual relative increase of 12 percent. The recent profiles show a significant increase in the mean monthly concentration of ozone in the lowest 12 km. Concurrent to this increase a relative decrease in ozone concentration is shown between 12 and 42 km. The increased ozone concentration in the lower troposphere may be related to urbanization and the increase in ozone-forming nitrogen oxides over the last two decades. It is suggested that the decreased ozone concentration in the stratosphere and upper troposphere is evidence of the global decrease in the mid-latitudes of the Southern Hemisphere.

Description: An analysis of specific features of space-time variations of ozone in the tropical areas which has been performed on the basis of processing of the results of special expedition studies in the Atlantic and Pacific in 1987-1990 and the data of observations at the stations of the world ozonometric network over the 25-year period. The existence of a cause-and-effect relation has been revealed between the processes determining tropical cyclone (TC) development, and specific features of variations of the total content of ozone (TCO) and the vertical distribution of ozone (VDO) in the regions of TC action. Characteristic features of day-to-day and daily variations of TCO during TC development have been found. On the periphery of a developing TC, 1-4 days before it reaches the stage of storm, TCO increases, on average, by 5-8 percent, and a substantial increase in the concentration of ozone occurs in the middle and upper troposphere. The most probable physical mechanisms relating the observed specific features of ozone variations to TC evolution have been suggested. A hypothesis of the possibility of using ozone as an indicator for early prediction of TC development has been substantiated.

Description: It has been suggested that surface ozone concentrations in rural areas of Europe have been increasing at a rate of 1 to 3 percent per year over the past two to three decades, presumably due to human influences (Feister and Warmbt, 1987; Bojkov, 1988; Penkett, 1989). Recently, we have analyzed surface ozone data from 20 European stations of differing character (remote, rural, suburban and urban) for a common period of 1978-1988 (Low et al., 1992). It was found that there were pronounced annual and seasonal variations in the linear trends in different areas, and there was no dominant region-wide trend. In spring and, most notably, summer, stations on the maritime fringe of the network generally exhibited negative trends whilst those located further into the continental interior exhibited positive trends. In winter, most of the stations in the network exhibited positive trends. Relatively few of these trends were statistically significant. This paper updates our earlier analysis by extending the data sets of the network up to the year 1990. The spatial variations in surface ozone trends over the extended period 1978-1990 are examined and discussed in comparison to the 1978-1988 patterns. The update confirms the overall conclusions of the earlier analysis, specifically that caution should be exercised in interpreting the results of trend analyses based on station data representative of a limited period of time and/or geographical area.

Description: This study examines the influence of ambient vertical wind shear on microburst intensity, asymmetry, and translation. Results show that microburst asymmetry is influenced by the magnitude of the low-level ambient vertical shear. The microburst outflow elongates in the direction of the shear vector (which is not necessarily in the direction of translation), and generates the greatest hazard (for commercial jet transports) along paths orthogonal to the shear vector. The model results also show that the asymmetry increases with increasing shear magnitude. One implication of these results concerns the detection of a microburst by a ground-based doppler systems. These systems may underestimate the hazard for landing and departing aircraft that are on trajectories orthogonal to both the sensor beam and shear vector, especially if the magnitude of the shear is large. Another implication is that microburst are more likely to be asymmetrical in regions (seasons) where there is climatologically a significant low-level shear. The model results also show that the rotor microbursts and severe wind damage can be a product of the microburst interaction with strong ambient wind shear.

Description: On 8 July 1989, a very strong microburst was detected by the Low-Level Windshear Alert system (LLWAS), within the approach corridor just north of Denver Stapleton Airport. The microburst was encountered by a Boeing 737-200 in a 'go-around' configuration which was reported to have lost considerable air speed and altitude during penetration. Data from LLWAS revealed a pulsating microburst with an estimated peak velocity change of 48 m/s. Wilson et al. reported that the microburst was accompanied by no apparent visible clues such as rain or virga, although blowing dust was present. Weather service hourly reports indicated virga in all quadrants near the time of the event. A National Center for Atmospheric Research (NCAR) research Doppler radar was operating; but according to Wilson et al., meaningful velocity could not be measured within the microburst due to low radar-reflectivity factor and poor siting for windshear detection at Stapleton. This paper presents results from the three-dimensional numerical simulation of this event, using the Terminal Area Simulation System (TASS) model. The TASS model is a three-dimensional nonhydrostatic cloud model that includes parameterizations for both liquid and ice phase microphysics, and has been used in investigations of both wet and dry microburst case studies. The focus of this paper is the pulsating characteristic and the very-low radar reflectivity of this event. Most of the surface outflow contained no precipitation. Such an event may be difficult to detect by radar.

Description: The objective of this study was to assess the ability of simple vertical wind models to improve the hazard prediction capability of an airborne Doppler sensor in a realistic microburst environment. The results indicate that in the altitude region of interest (at or below 300 meters), both the linear and empirical vertical wind models improved the hazard estimate. The radar simulation study showed that the magnitude of the performance improvement was altitude dependent. The altitude of maximum performance improvement occurred at about 300 meters. At the lower altitudes the percent improvement was minimized by the diminished contribution of the vertical wind. The vertical hazard estimate errors from flight tests were less than those of the radar simulation study.

Description: If the average power at the receiver is substantially reduced by heavy rain, the AGC (automatic gain control) circuit of the rain gauge will try to compensate this reduction by increasing the gain. If this happens, then the pulses created by rain drops are amplified more than they should be and the rainfall rate may be overestimated. If the effective diameter (blocking efficiency) of a particle is 2 mm and if the beam width is 2 cm, each particle will reduce the received power by 10 percent when it crosses the beam. Since the beam is blocked by water drops 75 percent of the total time according to the above calculation, the total received power may be reduced by 7.5 percent. To compensate this reduction to the reference value, the gain of amplifier will be increased by 8.1 percent. This increase of gain will increase all pulse sizes by the same fraction and result in the overestimate of the rainfall rate.

Description: Prior to the Tropical Oceans Global Atmosphere-Coupled Ocean Atmosphere Response Experiment (TOGA-COARE), 42 Model 100 series optical gauges were tested in the rain simulator facility at Wallops Island before shipment to the field. Baseline measurements at several rain rates were made simultaneously with collector cans, tipping bucket, and a precision weighing gauge and held for post-COARE evaluation with a repeat set of measurements that were to be recorded after the instruments were returned. This was done as a means of detecting any calibration changes that might have occurred while deployed. Although it was known that the artificial rain in the simulator did not contain the required exponential distribution for accurate optical rain gauge rate measurements, use of the facility was necessary because it was the only means available for taking controlled observations with instruments that were received, tested, and shipped out in groups over a period of months. At that point, it was believed that these measurements would be adequately precise for detecting performance changes over time. However, analysis of the data by STI now indicates that this may not be true. Further study of the data will be undertaken to resolve this.

Description: Limited analysis of optical rain gauge (ORG) data from shipboard and ground based sensors has shown the existence of spikes, possibly attributable to sensor vibration, while rain is occurring. An extreme example of this behavior was noted aboard the PRC#5 on the evening of December 24, 1992 as the ship began repositioning during a rain event in the TOGA/COARE IFA. The spikes are readily evident in the one-second resolution data, but may be indistinguishable from natural rain rate fluctuations in subsampled or averaged data. Such spikes result in increased rainfall totals.

Description: A comparison between rain gauge data and radar data from the Tropical Oceans Global Atmosphere/Coupled Ocean Atmosphere Response Experiment (TOGA/COARE) was studied. The rain gauge data from an echo that passed over the Xiangyanghong #5 on December 24, 1992 was compared to what the MIT radar saw at this location from the R/V Vickers, 103.4 km to the east. The precipitation measured by the rain gauge peaked at 108 mm/hr 92 seconds into the period before tapering off 11 1/2 minutes later. This sharp gradient was evident in a PPI plot of the radar reflectivities and the percentage area-rainfall for the radar data statistics. The percentage area curve was converted to rain rates using a GATE Z-R and compared to a percentage time curve of rain rates according to the rain gauge. A four minute running average applied to the rain gauge rates improved the comparison of peak rates between the rain gauge and radar. Differences in peaks between rain rates observed by the rain gauge and reflectivities observed by the radar could be due to variations in rainfall rates within a single radar data bin. For example, two measurements of reflectivity such as 37 and 47 dBZ within the same bin would result in a 44 dBZ average. This range in rates from 12 mm/hr to 74 mm/hr is observed in 30 seconds by the rain gauges within the first two minutes of the radar echo passage.

Description: The Ocean Acoustics Division (OAD) of the Atlantic Oceanographic and Meteorological Laboratory (AOML), in cooperation with NOAA/NESDIS and NASA, has deployed six rain gauges for calibration and intercomparison purposes. These instruments include: (1) a weighing rain gauge, (2) a RM Young Model 50202 capacitance rain gauge, (3) a ScTI ORG-705 (long path) optical rain gauge, (4) a ScTI ORG-105 (mini-ORG) optical rain gauge, (5) a Belfort Model 382 tipping bucket rain gauge, and (6) a Distromet RD-69 disdrometer. The system has been running continuously since July 1993. During this time period, roughly 150 events with maximum rainfall rate over 10 mm/hr and 25 events with maximum rainfall rates over 100 mm/hr have been recorded. All rain gauge types have performed well, with intercorrelations 0.9 or higher. However, limitations for each type of rain gauge have been observed.

Description: This study is intended to examine the impact of the synthetic relative humidity on the model simulation of mesoscale convective storm environment. The synthetic relative humidity is derived from the National Weather Services surface observations, and non-conventional sources including aircraft, radar, and satellite observations. The latter sources provide the mesoscale data of very high spatial and temporal resolution. The synthetic humidity data is used to complement the National Weather Services rawinsonde observations. It is believed that a realistic representation of initial moisture field in a mesoscale model is critical for the model simulation of thunderstorm development, and the formation of non-convective clouds as well as their effects on the surface energy budget. The impact will be investigated based on a real-data case study using the mesoscale atmospheric simulation system developed by Mesoscale Environmental Simulations Operations, Inc. The mesoscale atmospheric simulation system consists of objective analysis and initialization codes, and the coarse-mesh and fine-mesh dynamic prediction models. Both models are a three dimensional, primitive equation model containing the essential moist physics for simulating and forecasting mesoscale convective processes in the atmosphere. The modeling system is currently implemented at the Applied Meteorology Unit, Kennedy Space Center. Two procedures involving the synthetic relative humidity to define the model initial moisture fields are considered. It is proposed to perform several short-range (approximately 6 hours) comparative coarse-mesh simulation experiments with and without the synthetic data. They are aimed at revealing the model sensitivities should allow us both to refine the specification of the observational requirements, and to develop more accurate and efficient objective analysis schemes. The goal is to advance the MASS (Mesoscal Atmospheric Simulation System) modeling expertise so that the model output can provide reliable guidance for thunderstorm forecasting.

Description: In March 1990, a zenith-sky UV-visible spectrometer of the design 'Systeme Automatique d'Obervation Zenithal' (SAOZ) was installed at Faraday in Antarctica (66.3 deg S, 64.3 deg W). SAOZ records spectra between 290 and 600 nm during daylight. Its analysis program fits laboratory spectra of constituents, at various wavelengths, to the differential of the ratio of the observed spectrum and a reference spectrum. The least-squares fitting procedure minimizes the sum-of-squares of residuals. Ozone is deduced from absorption in its visible bands between 500 and 560 nm. The fortunate colocation of this SAOZ with the well-calibrated Dobson at Faraday has allowed us to examine the calibration of the zero of the SAOZ, difficult at visible wavelengths because of the small depth of absorption. Here we describe recent improvements and limitations to this calibration, and discuss SAOZ measurements of ozone during winter in this important location at the edge of the Antarctic vortex.

Description: The study presents the statistical analysis of ozone sonde data obtained at Sodankyla (67.4 deg N, 26.6 deg E) from the beginning of the sounding program on March 1988 to the end of December 1991. The Sodankyla sounding data offers the longest continuous record of the ozone vertical distribution in the European Arctic. In this paper, we present the average ozone partial pressures within each 1 km column obtained for different seasons during the almost four year long period. We believe that the data represented here are useful as an interim reference ozone atmosphere, especially considering the fact that northern Scandinavia has become a popular campaign site for the big international ozone experiments.

Description: The diurnally mean total ozone X from the Northern Hemisphere ground based 90 stations for 1975-1990 are averaged over the Arctic (bar X (sub A)) Intermediate (bar X (sub I)) and Tropical (bar X (sub T)) air mass areas, divided by the jet stream axes on the isobaric surfaces 300 and 200 mb. The mean square variations of the so averaged X are considerably smaller than of the X, averaged over the corresponding zonal belts. This property allows one to improve considerably the statistical significance of X trends and changes over various time periods, taking into account the time correlation of data for adjacent time intervals. Bar X (sub A), bar X (sub I), and bar X (sub T) trends are estimated over the periods of solar activity rise and fall in its 21st and rise in its 22nd 11 year cycles and over the periods of west and east phases of the known over the periods of west and east phases of the known quasibiennial oscillation (QBO). Solar activity variations affect mostly bar X (sub T), bar X (sub I) trends in summer months, while QBO phases influence the X changes mostly during the cold half year. X are lower in the west QBO phase and their trend is negative during almost all periods considered. The anthropogenic effects on the X is also estimated.

Description: The quasi-biennial oscillation (QBO) in total ozone (TO) is studied on the basis of TO measurements at the world ground-ased ozone network during 1972-1988. The TO content is on the whole greater in the tropical belt and smaller in high latitudes during the westerly phase of the QBO of the equatorial stratospheric 50 mb wind than during the easterly phase in all seasons. The appropriate TO difference (westerly category minus easterly category) displays certain space structures changing during a year. There are regions with the peculiar annual evolution of this difference, particularly in the Arctic and Antarctic. Spectral analysis reveals bimodality of TO power spectra in the frequency range of QBO periods, with spectral maxima corresponding to 17-23 months and 28-35 months. The large period oscillations are predominant on the whole. The small period oscillations are likely the consequence of interaction between an annual cycle and QBO.

Description: The correlation coefficients of temperature and geopotential heights at various levels with total ozone and its vertical distribution have been analyzed, using the ground based and ozone sounding data. Two independent groups of factors affect total ozone. The first group - the geopotential values of the troposphere - stratosphere border (100-500 mb) manifest themselves most of all in the middle latitudes. Pertaining to this group is the total ozone correlation with the tropopause height and temperature at 500 mb. The correlation coefficients are negative (-0.55 -0.65) and little depend on the season. Related to this factor is a high (up to 0.8) correlation of ozone partial pressure with the temperature in the lower stratosphere. The second group is the geopotential and temperature values at the 10-30 mb coefficients (up to 0.6) are observed in winter in the subpolar latitudes. In summer they are substantially lower - about 0.1.

Description: The relationship between patterns of total ozone and day-to-day weather was explored over South Africa for the period 1987 to 1988. Generally, there was a fairly poor relationship (variance less than 20 percent) between total ozone and the heights of the 100, 300 and 500 hPa geopotential heights at 5 South African stations. However, over a shorter period, October to December 1988, fluctuations in the height of the 300 hPa surface accounted for 53 percent of the variance in total ozone at Cape Town. High ozone amounts are associated with the lowering of the 300 hPa surface in the presence of an upper-air trough. The role of the mid-latitude westerly waves in this respect is discussed.

Description: The distribution of total column ozone is investigated, using data from the TOMS (Total Ozone Mapping Spectrometer) experiment aboard the US Nimbus 7 satellite. The region of interest extends from 60 North to 60 South, encircling the earth. Data for several years have been used in order to assess the long-term variations in the distribution of total column ozone. First results are presented on the seasonal variability of total column ozone in each hemisphere. The effects of the seasons are strongest at the highest latitudes but can still be discerned at the equator. While the variations are similar in the two hemispheres, ozone levels in the north are larger than in the south. Strong similarities are also found in the drift patterns of total column ozone in the two hemispheres. These drift patterns are compared to meteorological phenomena. We find an almost stationary ozone distribution drifts eastward in both hemispheres and this drift shows a seasonal variation. At very high latitudes (70 deg and higher) during spring in the southern hemisphere the ozone distribution is once again almost stationary, indicating that these regions are inside the polar vortex.

Description: A rigorous mathematical proof is presented for multiline representation on the equivalent width of a molecular band which consists in the general case of n overlapping spectral lines. The multiline representation includes a principal term and terms of minor significance. The principal term is the equivalent width of the molecular band consisting of the same n nonoverlapping spectral lines. The terms of minor significance take into consideration the overlapping of two, three and more spectral lines. They are small in case of the weak overlapping of spectral lines in the molecular band. The multiline representation can be easily generalized for optically inhomogeneous gas media and holds true for combinations of molecular bands. If the band lines overlap weakly the standard formulation of line-by-line method becomes too labor-consuming. In this case the multiline representation permits line-by-line calculations to be performed more effectively. Other useful properties of the multiline representation are pointed out.

Description: A world wide interest in protecting ozone layer against manmade effects is now increasing. Assessment of the ozone depletion due to these activities depends on how successfully we can separate the natural variabilities from the data. The monthly mean values of total ozone over Cairo (30 05N) for the period 1968-1988, have been analyzed using the power spectral analysis technique. The technique used in this analysis does not depend on a pre-understanding of the natural fluctuations in the ozone data. The method depends on increasing the resolution of the spectral peaks in order to obtain the more accurate sinusoidal fluctuations with wavelength equal to or less than record length. Also it handles the possible sinusoidal fluctuations with wavelength equal to or less than record length. The results show that it is possible to detect some of the well known national fluctuations in the ozone record such as annual, semiannual, quasi-biennial and quasi-quadrennial oscillations. After separating the natural fluctuations from the ozone record, the trend analysis of total ozone over Cairo showed that a decrease of about -1.2% per decade has occurred since 1979.

Description: Visible spectrometers SAOZ have been developed at Service d'Aeronomie for permanent ground-based ozone monitoring at all latitudes up to the polar circle in winter. Observations are made by looking at the sunlight scattered at zenith in the visible range, twice a day, at sunrise and sunset. Compared to ozone observations in the UV generally in use, visible observations in the small Chappuis bands at twilight have the advantages of being independent of stratospheric temperature, little contaminated by tropospheric ozone and multiple scattering, and of permitting observations even in winter at the polar circle. SAOZ instruments have been installed since 1988 at several stations in the Antarctic and the Arctic. More than four years data at Dumont d'Urville in Terre Adelie (67 deg S) are now available. The station is generally located at the edge of the vortex in spring and therefore the ozone hole is seen there only occasionally. The lowest values (140 DU) were reported in early October 1991. According to these first regular observations throughout the whole winter ozone seems to increase in late autumn and winter. Its decay does not start before the end of August. Although of smaller amplitude than with the previous version five data, the ratio between the groundbased and satellite/TOMS measurements displays a systematic seasonal variation correlated partly to the sun zenith angle of observations from orbit and partly to the temperature of the stratosphere. Since ground-based measurements are always made at 90 deg SZA, the SZA dependence must come from the satellite data interpretation (TOMS observations are between 43 to 88 deg SZA). The temperature dependence could be partly due to variations of ozone absorption cross-sections in the ultraviolet used by the satellite spectrometer, and partly to a systematic seasonal cycle of the air mass factor use in the interpretation of the ground based observations. However, the last contribution appears to be too small to compensate the ozone increase in winter reported by SAOZ, which is then real.

Description: The ozone Dobson measurements obtained in Antarctica at the Belgian 'Base Roi Baudouin' (70 deg 26 min S, 24 deg 19 min E) in 1965 and 1966 were retrieved from the KNMI (Royal Netherlands Meteorological Institute) archives in De Bilt. Despite excellent treatment at the time by the meteorologists in charge at the KNMI (Wisse and Meerburg, 1969), a study of the original observers notes was made in order to check possible seasonal ozone phenomena. No systematic anomaly in the first analysis was found; meteorological data from the site together with Brewer-Mast ozone soundings concur that the conditions did not correspond either in 1965 nor 1966 to the current ozone hole (Farman et al., 1985) situation, however, the data yields excellent correlation with stratospheric temperature and shows in 1966 a clear November maximum in opposition to an October value around 344 Dobson units.

Description: The total ozone mapping spectrometer (TOMS) and stratospheric aerosol and gas experiment (SAGE) measurements show a significant reduction in the stratospheric ozone over the middle and high latitudes of both hemispheres between the years 1979 and 1991 (WMO, 1992). This change in ozone will effect both the solar and longwave radiation with climate implications. However, recent studies (Ramaswamy et al., 1992; WMO, 1992) indicate that the net effect depends not only on latitudes and seasons, but also on the response of the lower stratospheric temperature. In this study we use a general circulation model (GCM) to calculate the climatic effect due to stratospheric ozone depletion and compare the effect with that due to observed increases of trace gases CO2, CH4, N2O, and CFC's for the period 1980-1990. In the simulations, we use the observed changes in ozone derived from the TOMS data. The GCM used is a version of the NCAR community climate model referenced in Wang et al. (1991). For the present study we run the model in perpetual January and perpetual July modes in which the incoming solar radiation and climatological sea surface temperatures are held constant.

Description: A fundamental problem in the study of the terrestrial middle atmosphere is to calculate accurately the local heating due to the absorption of solar radiation. Knowledge of the heat budget is essential to understanding the atmospheric thermal structure, atmospheric motions, atmospheric chemistry, and their coupling. The evaluation of heating rates is complicated (especially above the stratopause) by the fact that the heating is not a simple one-step process. That is, the absorbed solar energy does not all immediately appear as heat. Rather, substantial portions of the incident energy may appear as internal energy of excited photolysis products (e.g., O(1D) or O2(1 delta)) or as chemical potential energy of product species such as atomic oxygen. The ultimate disposition of the internal and chemical energy possessed by the photolysis products determines the efficiency and thus the rate at which the middle atmosphere is heated. In studies of the heat budget, it is also vitally important to consider transport of long lived chemical species such as atomic oxygen above approximately 80 km. In such cases, the chemical potential energy may be transported great distances (horizontally or vertically) before undergoing a reaction to release the heat. Atomic oxygen influences the heating not only by reactions with itself and with O2 but also by reactions with odd-hydrogen species, especially those involving OH (Mlynczak and Solomon, 1991a). Consequently, absorbed solar energy may finally by converted to heat a long time after and at a location far from the original deposition. The purpose of this paper is to examine the solar and chemical heating processes and to present parameterizations for the heating efficiencies readily applicable for use in numerical models and heat budget studies. In the next two sections the processes relevant to the heating efficiencies for ozone and molecular oxygen will be reviewed. In section 4 the processes for the exothermic reactions will be reviewed and parameterizations for the heating efficiencies for both the solar and chemical processes will be presented in Section 5.

Description: The total ozone amount is sensitive to the general circulation changes in the lower stratosphere due to the photochemically inactive nature of ozone there. In the equatorial region, such circulation changes arise from the quasi-biennial oscillation (QBO) of the stratospheric zonal wind and the El Nino/Southern Oscillation (ENSO). In the first half of this study we present observational results of the long-term variations in the equatorial ozone field using the 11 year Total Ozone Mapping Spectrometer (TOMS) data, by paying special attention to the longitudinal structure. In the latter half we try to understand quantitatively these variations by using a simple mechanistic relationship. We hypothesis that the ozone modulating processes are attributable to two dynamical effects, the advection effect and tropopause effect, owing to the strong vertical stratification of ozone existing just above the tropopause. The advection effect comes from the vertical motion which maintains the temperature structure, compensating for the radiative damping. The tropopause effect is associated with the altitude change of the tropopause. The total ozone variations in the tropics is discussed in terms of these two dynamical processes with the aid of mechanistic equations combined with the wind and sea surface temperature (SST) observations. The interactions between tropical and extratropical latitudes are beyond the scope of this study. Photochemical effects are also neglected. Details of this study are given by Shiotani (1992) and Hasebe (1992).