ALBERT

Beschreibung: The Cenozoic sediments sampled in ODP Leg 104 on the Vøring Plateau show a distinct variability of the total organic carbon content (TOC) and the accumulation rates of TOC. Based on the geochemical and organic-petrographic characterization of the sedimentary organic matter (OM), the allochthonous and autochthonous proportion of the OM could be quantified. The results clearly demonstrate that high TOC percentages and TOC accumulation rates in Cenozoic sediment sections display a generally high input of allochthonous organic matter. Oxidized and partly well-rounded organic particles built up the main portion of OM within the Miocene, TOC-rich sediments. The most probable source of this oxidized OM are reworked sediments from the Scandinavian shelf. Changes in the input of these organic particles are to some degree correlative with sea-level changes. The Cenozoic accumulation of autochthonous OM is low and does not reveal a clear variation during the Miocene and early Pliocene. In spite of a high accumulation rate of biogenic opal during the Early Miocene, the accumulation rate of autochthonous TOC is low. The autochthonous particle assemblage is dominated by relatively inert OM, like dinoflagellate cysts. This points to an intensive biological and/or early diagenetic degradation of the marine OM under well oxidized bottom water conditions during the last 23 Myr. Nevertheless, a continuation of marine OM degradation during later stages of diagenesis cannot be excluded. A prominent dominance of allochthonous OM over autochthonous is documented with the beginning of the Pliocene. At 2.45 Ma the episodic occurrence of ice-rafted, thermally mature OM reflects the onset of the glacial erosion of Mesozoic, coal and black shale bearing sediments on the Scandinavian and Barents Sea shelves. The first occurrence of these, in view of the actual burial depth, thermally overmature OM particles is, therefore, a marker for the beginning of the strong Scandinavian glaciation and the advance of the glacial front toward the shelves.

Beschreibung: Over the past decade an increasing body of evidence has accumulated indicating that much, perhaps most, of the deep sea floor is an environment of substantial temporal variability (Smith and Baldwin, 1984 doi:10.1038/307624a0; Smith, 1987; Deuser and Ross, 1980 doi:10.1038/283364a0; Thiel et al., 1988). This variability is driven largely by seasonal changes of processes occurring in the surface waters (Smith, 1987; Deuser and Ross, 1980; Billett et al., 1983 doi:10.1038/302520a0). The coupling of the deep sea floor environment to the surface waters is the result of rapid vertical transport of particulate matter through the water column (Honjo, 1982 doi:10.1126/science.218.4575.883; Deuser et al., 1986 doi:10.1016/0198-0149(86)90120-2; Lampitt, 1985 doi:10.1016/0198-0149(85)90034-2), affording only limited time for degradation before arrival at the sea floor. Studies in the Pacific Ocean have indicated that temporal variations in particulate organic carbon fluxes to the sea floor are accompanied by temporal variability in sediment oxygen demand by as much as a factor of four (Smith and Baldwin, 1984; Smith, 1987). We report here time-series studies of oxygen fluxes into the sediments of the oligotrophic Atlantic near Bermuda which contrast sharply with these previous reports. At the Bermuda site, despite large seasonal variations in particulate organic carbon fluxes, in situ measured sediment oxygen consumption does not vary significantly. These results imply that large areas of the sea floor may be characterized by seasonally invariant sediment oxygen demand.