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  • Articles  (411)
  • Chemical Engineering  (348)
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  • Articles  (411)
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  • 1
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 33 (1993), S. 393-399 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The univariant element, Q1 P0, and the multivariant elements, Q1+P0 and R2+ P0, are compared for the numerical simulation of the flow in extrusion dies. The pressure distribution obtained by using the Q1 P0 element was found to be afflicted with the checkerboard pressure mode. On the other hand, the multivariant elements, Q1+ P0 and R2+ P0, gave accurate and physically reasonable velocity and pressure distributions. The computed values of the pressure drop across extrusion dies matched well with the pressure drop determined experimentally.
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  • 2
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 33 (1993), S. 377-382 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The viscoelastic responses of some molten polymers, and particularly of low density polyethylene (LDPE), are known to vary with processing history. Reasons for the variations include the effects of shear history on morphological states of the polymer, or on its molecular weight parameters. A typical low density polyethylene has been used to test the shear-history dependence concept following a variety of processing steps. The polymer was sheared in single-screw and twin-screw extruders, and in a high speed melter / mixer (Gelimat). Samples also were precipitated from very dilute solutions in trichlorobenzene and in p-xylene. GPC analyses showed that, in general, these procedures did not affect the various moments of molecular weight. An exception was the Gelimat-mixed sample, for which mild reductions in Mn and Mw were noted. In contrast, melt viscosity and elasticity readings, the former from low shear evaluations and the latter from extrudate swelling, were affected by the various procedures. A drop in melt viscosity and in elasticity was observed, being most pronounced for precipitated and twin-screw extruded versions of the LDPE. Reductions also were observed in the specimen sheared in the Gelimat instrument. Following conditioning at the test extrusion temperature (170°C), viscous and elastic responses tended to revert to those of the unsheared control sample, the exception again being the sample sheared in the Gelimat melter / mixer. Of the various mechanisms proposed in the literature to account for transient property changes such as those reported, temporary changes in the degree of chain entanglement appear the most satisfactory explanation. Irreversible alterations in viscoelastic properties may be associated with changes in molecular weights due to processing at high shear.
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  • 3
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 33 (1993), S. 400-409 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A model for the filling stage of injection molding of viscoelastic thermoplastics in cavities of complex shape is presented. The model considers two-dimensional melt flow, with converging and diverging flow patterns induced by complex boundary shape and by the presence of an obstacle. The model is non-isothermal (with the melt loosing heat to the mold walls as it travels into the cavity) and handles a viscoelastic (following the White-Metzner model) material with properties that vary with temperature, shear rate, and pressure. The numerical method is based on finite differences, with boundary fitted curvilinear coordinates used in the mapping of the flow field (which has an arbitrary shape that evolves with time) into a time invariant rectangle. The numerical results reveal geometry-induced asymmetries in the flow and thermal fields as well as the effect of various process parameters on the pressure and temperature profiles in the cavity. The model admits variable cavity thickness, thus allowing for a treatment of the cavity thickness as a process parameter in the simulations.
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  • 4
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 33 (1993), S. 497-500 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The use of polymeric materials in building or construction applications is steadily increasing. Therefore, the potential for these materials to be exposed to fire is also increased. The understanding of the pyrolysis characteristics of these materials is thus a necessity. There are many standard tests used to evaluate materials. Unfortunately, the correlation between these tests and large scale fire is less than desirable. A new bench scale rate of heat release apparatus, the Cone Calorimeter, is now being used more frequently in pyrolysis testing of polymeric materials. This apparatus has been shown to correlate much better between room scale testing and large scale fire testing. The cone Calorimeter provides a pyrolysis profile of a material under ambient oxygen conditions. Characteristics such as ignition time, total heat release, maximum rate of heat release, mass loss during pyrolysis, CO2, CO, and smoke production are determined. In this work several almost neat polymers are examined and the general pyrolysis characteristics of these polymers are discussed. The objective of this work is to provide information of basic polymeric pyrolysis properties of these materials. Variations in the material, i.e., molecular weight, polydispersity, and residual catalysis, along with changes in testing procedures, can have dramatic effects on results. Obviously the addition of flame retardant and flame retardant packages to any of these materials will have dramatic effects on results.
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  • 5
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 33 (1993) 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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  • 6
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 33 (1993), S. 513-521 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The overall isothermal crystallization kinetics for nucleated and non-nucleated isotactic polypropylene (iPP)-dotriacontane systems was investigated. Adipic acid was used as the nucleating agent. Half-time was determined via differential scanning calorimetry as a function of the experimentally controlled variables dilution, crystallization temperature, and the addition of nucleating agent. The influence of these variables on crystallization mechanism and spherulitic structure, as implied by the Avrami analysis, was determined. The influence of these variables on fold surface energy was examined by the Lauritzen and Hoffman analysis.
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  • 7
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The overall non-isothermal crystallization kinetics for nucleated and non-nucleated isotactic polypropylene (iPP) in dotriacontane systems was investigated. Adipic acid was used as the nucleating agent. Crystallization peak temperature was determined via differential scanning calorimetry as a function of the experimentally controlled variables iPP concentration, cooling rate, and nucleating agent concentration. The influence of these variables on crystallization mechanism and spherulitic structure as implied by the Ozawa and Ziabicki analyses was determined. The non-isothermal crystallization kinetics presented here are the first for iPP-diluent systems with and without nucleating agent.
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  • 8
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 33 (1993), S. 543-548 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The static shear strength and static friction of three thermoplastics have been investigated for the case of contact between a bulk plastic sample and a very smooth metallic plate. The minimum tangential force required to shear the interfacial adhesion bonds between the two surfaces was measured and defined as the adhesion component of friction Fa. Experimental results showed that Fa is large when the surface energy is high or the interfacial energy is small and that a correlation may exist between this force and the work of adhesion evaluated from Dupré equation. The real area of contact Ar was also measured using an optical device designed to handle samples and experimental conditions similar to the static friction tests. It was found that Ar is proportional to Pa0.9 where Pa is the apparent pressure of contact and an increase of Fa with Pr was observed. The static shear strength τ has been evaluated as the ratio Fa/Ar, and its relationships with the real contact pressure P approximated by linear functions. It was concluded that τ increases at high P, although it has not been verified for ultra-high-molecular-weight polyethylene. An attempt has been made to explain the observed break in the data. The results indicated that (τ/τb) = κ′(τa/Pa) where b refers to bulk, a to apparent values, and κ′ is a proportionality constant that depends on the plastic material.
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  • 9
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 33 (1993), S. 549-558 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A variety of different styrene monomers [styrene (S), p-fluorostyrene (p-FS), pentafluorostyrene (PFS), p-chlorostyrene (p-ClS), p-bromostyrene (p-BrS), p-methylstyrene (p-MS), p-tert-butylstyrene (p-tBS), p-methoxystyrene (p-MOS), p-ethoxystyrene (p-EOS), and p-propoxystyrene (p-POS)] have been polymerized by radical and cationic mechanisms. Copolymers of S/PFS, S/p-ClS, S/2-vinyl-naphthalene (2-VN), and S/p-phenylstyrene (p-PhS) were prepared by radical polymerization. All polymers were fully amorphous and transparent and exhibited only one glass transition temperature in the temperature range 77 to 141°C. Thin films of the polymers were subjected to external electrical partial discharges (PD). Typically, 20 PD experiments were conducted for each polymer and the data for the time to breakdown were adapted to the two-parameter Weibull distribution function. The resistance towards PD of the various polymers was found to depend strongly on the monomeric structure. Complementary PD experiments on a series of narrow molecular mass polystyrenes confirmed that the minor variation in molecular mass between the different styrene polymers is of no importance for the PD resistance. The PD resistance of the homopolymers decreased in the following order: PS ≍ P(p-MS) 〉 P(p-tBS) ≍ P(p-BrS) 〉 P(p-POS) 〉 P(p-ClS) ≍ P(p-MOS) 〉 P(p-EOS) ≍ P(p-FS) 〉 P(PFS). The time to breakdown for copolymers of S and PFS decreased monotonously with increasing PFS content. Styrene copolymers with low molar contents of 2- VN and p-PhS exhibited a higher resistance towards PD than PS. The results are discussed with reference to various properties of the studied polymers, such as segmental mobility, ionization potential, resonance stabilization, and reactivity of the radicals formed.
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  • 10
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 33 (1993) 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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  • 11
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 33 (1993), S. 614-621 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The glass transition temperatures in bismaleimide-based resins were investigated using different stoichiometric ratios of 1, 1′-(methylenedi-4, 1-phenylene)bismaleimide (BMI) and 4, 4′-methylenedianiline (MDA). The resin cure involves a low temperature primary amine addition to the maleimide double bonds and a high temperature homopolymerization of the maleimide double bonds. The network topology and the glass transition temperature changes with resin composition and curing conditions were determined using differential scanning calorimetry (DSC). An empirical model was used to relate the glass transition temperature to the extents of the amine addition and the homopolymerization reactions in 1:1 and 2:1 BMI:MDA resins. The changes in thermal properties with resin post-cure were also examined.
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  • 12
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 33 (1993), S. 640-644 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Dynamic mechanical properties, tensile properties, and scanning electron microscopy of blends of poly(methyl methacrylate) and polycarbonate were investigated after phase separation above their cloud point temperature by annealing in a hot press. The dynamic mechanical properties show that phase separation proceeds more distinctly for the blends annealed at higher temperature and for longer time. The scanning electron micrographs show that the morphology of phase separated blends varies with the conditions of heat treatment. The tensile properties of phase separated blends deteriorate on account of the coarsening of the brittle dispersed phase over the optimum size and the occurrence of voiding during the heat treatment.
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  • 13
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 33 (1993), S. 665-674 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The packing stage starts at the end of mold filling. During this stage, additional material is forced into the mold to compensate for the shrinkage during subse-quent cooling. Underpacking results in molded parts with dimensional variation. Overpacking causes flash at the parting lines, stick during ejection, and excess residual stresses resulting in warpage. The packing stage is thus extremely important in the determination of the final quality of the product. Despite its importance, analysis of the packing stage has been relatively ignored, particularly the viscoelastic effect. In this work, the analysis of the isothermal packing stage is presented for a Maxwell fluid. A set of governing equations is derived for a two-dimensional mold and solved using the Galerkin finite element method. In addition to the distribution of velocity and pressure, the model predicts the stresses in the planar direction, which could be used for subsequent calculation of the residual stresses.
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  • 14
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    Polymer Engineering and Science 33 (1993), S. 675-685 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The objective this work was to determine the effects of selected polyester catalysts on the reaction of a polyester with epoxy functional polymers. Polyesters containing various catalyst metals were melt blended with either an ethylene-co-glycidyl methacrylate or a styrene-co-glycidyl methacrylate copolymer. The viscosities of the blends were monitored as a function of mixing time using torque rheometry. In addition, the molecular weight distributions of selected samples were analyzed using gel permeation chromatography. Both the torque rheometry and the gel permeation chromatography results indicate that the polyester reacts with epoxy functional polymers. This reaction occurs under conditions and at processing times which are readily obtainable in conventional melt processing equipment. Furthermore, the reaction kinetics of polyesters with glycidyl methacrylate copolymers are dramatically affected by the nature of the catalyst system used to prepare the polyester. Under the conditions used, antimony catalysts are particularly effective at promoting the reaction between polyesters and the epoxy functionality and the activity of the catalysts studied appears to decrease in the following order: antimony 〉 gallium 〉 tin ≃ titanium 〉 germanium. Manipulation of the polyester catalyst system may offer a method to control the extent of reaction obtained in reactive processing of polyesters with epoxy functional compounds.
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  • 15
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    Polymer Engineering and Science 33 (1993), S. 709-715 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The flow kinematics of power-law fluids in fishtail dies is studied. A general isothermal three-dimensional finite element code developed by the authors is used for the flow analysis purpose. The basic geometry of the fishtail die is defined by simple super-elliptical curves, which allows a smooth transition from a circle to a slit. The three-dimensional path line and the residence time distribution (RTD) are calculated from the velocity field obtained from the finite element solution of the conservation equations. The effects of the rheological properties and the die geometry on the path line pattern and the residence time distribution are investigated. The results indicate that as both the length of the transition zone and the fishtail angle increases, the residence time distribution becomes more uniform. However, the power-law index does not affect the residence time distribution significantly.
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  • 16
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    Polymer Engineering and Science 33 (1993), S. 736-741 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The polymers of the aromatic nitrogen compounds N-methyl-pyrrole (P-N-Me-PPY), carbazole (PCarb), and aniline (PANI) have been investigated with electro-optical and surface analytical methods. The in-situ reflection spectra indicate the formation of polarons or bipolarons during electrochemical oxidation, depending on polymer type. The absorption bands can be attributed to changes in the electronic structure with regard to the applied potential. Photocurrent spectra of P-N-Me-PPY and PCarb show a p-type semiconducting behaviour for the polymers in the reduced state. The transition to the oxidized state with quasi-metallic properties is indicated by a significant shift in the Fermi level energy and can be followed with XPS and UPS measurements.
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  • 17
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    Polymer Engineering and Science 33 (1993), S. 838-844 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Extruded films of liquid crystalline polymer (LCP)/fluoropolymer blends were melt drawn to develop uniaxial orientation of a microfibrillar dispersed LCP phase. The anisotropy of the films increased with increasing draw and LCP content in the blend. Laminated composite plates were prepared using the extruded sheets as prepreg. The mechanical properties and coefficient of thermal expansion (CTE) of the prepreg and laminates agreed well with predictions from composite lamination theories. The potential for replacing glass fiber reinforced fluoropolymers with LCP/fluoropolymer blends in applications such as microwave circuit boards is discussed.
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  • 18
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    Polymer Engineering and Science 33 (1993) 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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  • 19
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    Polymer Engineering and Science 33 (1993), S. 865-876 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: This review presents a general picture of suspension, dispersion, and interfacial polycondensation processes employed for the preparation of beaded resins, dry powders, and high solid dispersions. The polymer systems covered include polyamides, polyesters, polycarbonates, polyurethanes, and phenol-formaldehyde and urea-formaldehyde resins. Basic features of heterogeneous polycondensation processes are outlined, and different mechanisms of particle formation in suspension, dispersion, and interfacial polycondensation are discussed. Effects of manufacturing parameters such as feed ratio, droplet/particle stabilizer, and stirrer speed on product characteristics are also briefly covered.
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  • 20
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    Polymer Engineering and Science 33 (1993), S. 781-788 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The extrudate swell and the dynamic rheological properties of poly(butylene terephthalate) (PBT) and polyamide 6 (PA6) binary blends were investigated at 240°C. The extrudate swell of the blend varies with the viscosity ratio and composition of constituents, and it is several times larger than that of homopolymers when the viscosity ratio of constituents is around unity. The dynamic oscillatory data could be interpreted by Oldroyd's emulsion model proposed by Graebling, et al. These results suggest that the extrudate swell is caused by the shape recovery of the dispersed particles. A semi-empirical method to estimate the terminal relaxation time with experimental data was introduced, and a clear correlation between the extrudate swell and the terminal relaxation time was obtained.
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  • 21
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    Polymer Engineering and Science 33 (1993), S. 819-826 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Much work in recent years had focused on the improvements of the impact properties of engineering thermoplastics by the addition of a low modulus modifier that contains polar moieties as a result of polymerization or that has been modified to contain polar moieties as a result of various grafting techniques. Styrenic block copolymers (styrene-ethylene/butylene-styrene) functionalized with maleic anhydride have proved useful as impact modifiers and compatibilizers in blends with engineering thermoplastics. This paper focuses on the use of these functionalized elastomers to modify nylon 6. In such compositions, a nylon material with unique mechanical performance may be achieved using the functionalized elastomer either alone or in combination with an unfunctionalized styrenic block copolymer. The optimization of performance in these rubber toughened polyamide blends using various types of styrenic block copolymers is discussed. The morphology as it pertains to performance is also reviewed. The information contained herein may prove useful in obtaining a better understanding of the mechanisms of compatibilization and modification of nylon 6 systems.
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  • 22
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    Polymer Engineering and Science 33 (1993), S. 827-837 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Oriented blends of poly(ethylene terephthalate) (PET) and high density polyethylene (HDPE) with and without compatibilizing agent have been studied with regard to orientation temperature, stretch rate, extension ratio, mode of orientation, and blend composition. These oriented blends have been characterized using infrared spectroscopy and differential scanning calorimetry. The tensile and tensile impact properties were also investigated. The results show that blends with compatibilizer show strain hardening upon orientation, whereas the blend without compatibilizer does not strain harden upon orientation. The blends with less PET content have been difficult to orient. The morphology of these blends show fibril structure, highly oriented in the direction of stretch. Infrared measurements show that PET within the blend has undergone strain induced crystallization upon orientation. It has also been observed that the mechanical properties, such as the modulus and ultimate stress, show improvement upon orientation. Simultaneously stretched blends show better physical properties than sequentially oriented blends.
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  • 23
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    Polymer Engineering and Science 33 (1993), S. 895-900 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: This paper illustrates the factors that control brittle failure under fatigue loading for test specimens cut from medium-density polyethylene pipes for gas distribution. A square bar specimen cut from a pipe with a notch was made and a fatigue test was conducted to cause a brittle failure. To obtain the correlation among stress range, frequency, temperature, and cycles to failure in this fatigue test, Coffin-Manson's frequency-modified fatigue life equation was adopted and the material constants were determined. By gradually lowering the frequency, the resistance to creep can be estimated because cycles to failure - indicating the fatigue damage - decreased, and the actual loading time - indicating the creep damage - increased.
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  • 24
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    Polymer Engineering and Science 33 (1993), S. 923-930 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The interfacial tension, phase morphology, and phase growth was determined for four polymer blend systems: polyethylene/polystyrene, polyethylene/polyamide-6, polystyrene/polyamide-6, and polystyrene/poly(ethylene terephthalate). Generally, high interfacial tension correlates with coarse phase morphology and rapid phase coalescence. The addition of various potential compatibilizing agents to these binary blend systems results in lowered interfacial tension, finer and stabilized phase morphologies. The characteristics of different compatibilizing agents were compared for several of the blend systems. We also look at the influences of compatibilizing agents on mechanical properties of the blend systems. Some compatibilizing agents are able to produce substantial improvements in ultimate properties.
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  • 25
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    Polymer Engineering and Science 33 (1993), S. 937-943 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Unidirectional sheets were extruded of an in-situ composite of thermotropic liquid crystalline Vectra B950 in a matrix of polyphenylene-ether and polystyrene. Three important processing parameters were systematically varied: draw-ratio, slit opening and extruder throughput. Morphology and mechanical properties of these films were determined, and qualitatively related to the processing conditions.
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  • 26
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    Polymer Engineering and Science 33 (1993), S. 959-970 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: It is of great importance to accurately measure or predict the Residence Time Distribution (RTD) in designing extruders and/or in setting up a proper operating condition, because chemical reactions depend significantly on the RTD and temperature when chemical reactions take place during the extrusion process. A previous method to predict the RTD can analytically determine RTD, Residence Time Distribution Function f(t) and Cumulative Residence Time Distribution Function F(t), based on a simplified two-dimensional velocity field in an extruder. However, this previous method cannot accurately take into account the three-dimensional circulatory flow inside the extruder. The present paper suggests a new method to accurately determine the RTD taking into account the three-dimensional circulatory flow and presents a new formula derived to calculate f(t). In order to demonstrate the applicability of the new method including the circulatory flow effect, RTD, f(t) and F(t) were calculated based on a three-dimensional velocity field obtained via a quasi-three-dimensional finite element analysis. It was found that the previous method has a tendency to underestimate the RTD, owing to the neglect of the three-dimensional circulatory flow in comparison with the new method.
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  • 27
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    Polymer Engineering and Science 33 (1993), S. 980-988 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Experimental data confirm the utility of the following simple equation in predicting the spin coating behavior of polyimide precursor solutions: \documentclass{article}\pagestyle{empty}\begin{document}$$ {\rm h} = {\rm c\beta }_{\rm 0} {\rm k}^{{\rm \beta }_{\rm 1} } {\rm \omega }^{{\rm \beta }_{\rm 2} } {\rm t}^{{\rm \beta }_{\rm 3} } \quad\quad\quad\quad{\rm (1)} $$\end{document} in which \documentclass{article}\pagestyle{empty}\begin{document}$$ \begin{array}{*{20}c} {c = {\rm polymer\, solution\, solid\, weight\, fraction;}} \\ {\beta _i = {\rm fitted\, coefficient\, (Greek\, letter\, beta)};} \\ \quad{h = {\rm film\, thickness\, after\, cure\, or\, solvent\, removal};} \\ \quad{k = {\rm polymer\, solution\, kinematic\, viscosity, centistokes};} \\ {t = {\rm time},{\rm and;}} \\ \quad{\omega = {\rm wafer\, spin\, speed, rpm (Greek\, letter\, omega)}.} \\ \end{array} $$\end{document}.
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  • 28
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Ternary systems consisting of polypropylene (PP), ethylene-propylene-dieneterpolymer (EPDM) and different types of inorganic fillers (kaolin, BaSO4) have been investigated with respect to their mechanical behavior. On the basis of an Interphase model, it was possible using the modified van der Poel equation to describe the temperature dependence of the storage modulus G′(T) and the loss modulus G″(T). The interphase properties G′(T) and G″(T) could be calculated.
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  • 29
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    Polymer Engineering and Science 33 (1993), S. 1251-1260 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Signal deterioration of optical discs depends strongly on the substrate surface roughness. Characteristics of surface roughness of the molded substrate have been studied in order to clarify the transcription mechanism of smooth surfaces in injection molding of polycarbonate resin. When the melt temperature, mold temperature, and injecting rate are low, microscopic flow marks more than 5 nm deep are observed on the surface. These flow marks are formed when the melted resin near the mold wall is cooled to the no-flow temperature of resin before it comes into contact with the mold wall. Molding transcription improves by optimizing the molding conditions for preventing these flow marks. As a result, the surface roughness of the molded substrate obtained is 3.2 nm in maximum height Rmax, which is nearly equal to that of the mold stamper at 2.7 nm in Rmax.
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  • 30
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    Polymer Engineering and Science 33 (1993), S. 1279-1287 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A finite element numerical analysis of preform inflation associated with the injection blow molding process has been developed using a neo-Hookean constitutive model. The analysis is capable of predicting final wall thickness distributions for axisymmetric mold geometries. Experimental studies were conducted on a Uniloy injection blow molding machine (Model 189-3 and Model 122). A twelve ounce (355 mL) cylindrical bottle mold was instrumented with contact sensors, thermocouples, and pressure transducers. Visualization studies of the inflation process were performed using specialized tooling and high-speed video cameras. The experimental studies provide justification for analyzing the deformation by means of a static elastic approach. The predicted wall thickness distribution is in reasonable agreement with the experimental data. Nonuniformities in the temperature distribution in the preform were found to have the most significant impact on the inflation behavior and the resulting wall thickness.
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  • 31
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    Polymer Engineering and Science 33 (1993), S. 1301-1307 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Dielectric α-relaxation of a bisphenol-A type epoxide oligomer has been investigated in the vicinity of the glass transition temperature (Tg) by the direct current (DC) transient method. The logarithm of the DC transient current for the oligomer was well approximated by the third order function of the logarithm of time. The complex dielectric constant was calculated through the Fourier transformation of that approximation function according to Simpson's integration rule in a frequency range of 10-5 - 1 Hz. At the temperature around the Tg (45°C), the dielectric α-relaxation process of the oligomer was found to be governed by the Havriliak-Negami equation. The relationship between the DC conductivity (σ) and the dielectric relaxation time (τ), σ·τm = const, is valid near and above the Tg of the oligomer. The DC transient current method combined with the DC conduction and the dielectric bridge measurements is considered to be a practical tool for analyzing the dielectric α-relaxation process of the epoxide oligomer over a wide frequency and temperature range.
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  • 32
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    Polymer Engineering and Science 33 (1993), S. 1329-1335 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: In this study, styrene-(ethylene-co-butylene)-styrene (SEBS) triblock copolymer (Kraton G-1652) was modified with maleic anhydride (MA). The maleated SEBS was used as compatibilizer for the blends of Nylon 6 (PA6) and SEBS. The morphology and impact strength of the blends were measured as functions of concentration and MA graft ratio of maleated SEBS. The compatibility and fracture mechanism of the blends were evaluated from the SEM micrographs of the xylene-etched surfaces and of fractured surfaces. Some of the blends exhibited an impact strength up to about 30 fold greater than neat PA6. The fracture involved both both cavitation and shear yielding. The mechanism of compatibilization of maleated SEBS in the ternary components blends was proposed.
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  • 33
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    Polymer Engineering and Science 33 (1993), S. 1341-1351 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: This paper reports on the theoretical and experimental studies of structure formation and strengthening (stiffening) of flexible-chain polymers. Two techniques of strengthening relying on the melt extrusion, i.e., orientational crystallization (crystallization initiated by melt extension) and drawing (uniaxial stretching of a crystallized polymer) are analysed by theory. The experiments involved preparation and study of melt extruded films and film fibers of linear polyethylene formed by the two techniques mentioned above. The effect of the degree of orientation and other parameters of the formation processes on the mechanical characteristics and the factors limiting the ultimate values of these characteristics are discussed. It is shown that multistage drawing succeeds in achieving a higher tensile strength and elastic modulus (1.2 and 35 GPa, respectively) than the orientational crystallization, which gives 0.8 and 15 GPa. The strengthening by drawing is accompanied by microcrack formation. In contrast, no discontinuities are observed in orientationally crystallized samples up to their ultimate extension.
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  • 34
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    Polymer Engineering and Science 33 (1993), S. 1370-1371 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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  • 35
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    Polymer Engineering and Science 33 (1993), S. 1381-1389 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Because of the inability of existing automotive bumpers to absorb energy during impacts over the supports, energy absorbers have to be used to make bumpers effective in barrier impacts. A parametric analysis of a novel double-beam bumper concept has shown that its performance, in terms of energy absorption and impact forces, is insensitive to the location of the point of impact. Physical realizations of this concept, which may not require more material than existing designs, and which are particularly suited to thermoplastic materials, have been developed.
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  • 36
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    Polymer Engineering and Science 33 (1993), S. 1270-1278 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Flow in a three-dimensional channel with a sinusoidally-wavy, vertical wall is examined for the case of applied down- and cross-channel velocity components. An important parameter for the analysis of the nature of laminar mixing in the flow field occurs when the changes in the downstream direction can be decoupled from the changes in the cross-channel direction, thereby allowing for a two-dimensional solution of the system of equations. This paper shows the effect on the nature of laminar mixing when the decoupling of the momentum equations from a fully three-dimensional case to one where a two-dimensional solution can be performed. Experiments are performed on a channel with sinusoidally varying vertical walls that cover the range of decoupling criteria. Silicone pigmented either white or black was run in the apparatus, cured, and cross-sectioned. The cross sections embody a local, detailed history of the state of mixing as it proceeds down the mixer. The amount of mixing is presented as a function of position at each cross section for the different channel configurations. The nature of mixing changes from a linear growth rate in the amount of interfacial area to an exponential rate as the amplitude of the wave is increased. Results demonstrate the existence of chaos, islands, and the factors affecting the mixing behavior.
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  • 37
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    Particle and Particle Systems Characterization 10 (1993), S. 7-10 
    ISSN: 0934-0866
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An image analysis system for extracting on-line quantitative geometric and densitometric information from images of ore samples is described. The apparatus employs a pulsed semiconductor laser as the light source for illuminating of a flowing stream of particles and a non-interlaced solid-state TV camera as size measurement device in a shadowgraph imaging system. The problem of the sampling volume is discussed and several size distributions of solid particulates are presented. The particle size measurement range is 2-400 μm.
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  • 38
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    Particle and Particle Systems Characterization 10 (1993), S. 11-18 
    ISSN: 0934-0866
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Accurate information on the size distribution of fly ash is needed to determine its role in the radiation transfer process in pulverized coal combustors. The Coulter Multisizer was used to determine the size distribution in the particle diameter range 1-200 μm. To size over such large diameter ranges, data must be obtained using several orifices, and then combined. In order to use the smaller orifices, the larger particles have to be removed from the sample. A wet-sieving apparatus, designed for accurate separation of the particles by size, is described. A scheme for combining data obtained using orifices of different diameters is presented. It appears from this study that the lower limit of size measurement using an orifice is set by sensitivity, rather than by signal/noise. A lognormal distribution function, truncated outside the measurement limits, fits the size distribution data well. This function allows detailed size information to be stored compactly using four parameters. Size parameters for six fly ashes representative of U. S. coals are presented.
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  • 39
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    Particle and Particle Systems Characterization 10 (1993), S. 38-38 
    ISSN: 0934-0866
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
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  • 40
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    Particle and Particle Systems Characterization 10 (1993), S. 26-32 
    ISSN: 0934-0866
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
    Notes: It is often necessary to estimate the properties of particle size distributions from limited samples taken from large populations. When the distributions are broad, and higher order moments required, as in the case of volume based particle size distributions, the inferred parameters d3,50 (volume median diameter) and GSD (geometric standard deviation) can have high intrinsic errors not immediately obvious to the measuring scientist. We show that there is a critical number of particles, Ncrit, which must be counted or else the error may blow up catastrophically. Ncrit is very sensitive to the width of the distribution, and is approximately proportional to GSD11 We develop formulae to estimate the random sampling error inherent in measured values of the d3,50 and GSD for the log-normal distribution; compare the predictions to a typical experimental particle size measurement; and then generalize to the median of any arbitrary moment, dr, 50.
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  • 41
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    Particle and Particle Systems Characterization 10 (1993) 
    ISSN: 0934-0866
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
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  • 42
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    Particle and Particle Systems Characterization 10 (1993), S. 48-55 
    ISSN: 0934-0866
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The working principle of the single-fibre reflection (SFR) probe is that light emitted by a laser diode is guided into the measuring volume by the same fibre which receives the proportion of light reflected by the particles in the vicinity of the probe tip and transmits it back to a photosensitive element. In contrast to other configurations of fibre optical probes, the SFR probe is characterized by an unambiguous calibration graph over the entire range of solid volume concentration values. SFR probes have been successfully applied to different kinds of multiphase flow systems, e.g. fluidized beds, pneumatic conveying lines, elutriators and thickeners.A particular question for the interpretation of measurements has always been the effective size of the measuring volume, which is mainly determined by the solid volume concentration. In this paper a simplified mathematical model of the signal generation by backscattering of the emitted light at the particle surfaces is given. The theory takes into account the average optical properties of the solids and their particle size distributions.The particle properties are determined on the basis of this model, which finally delivers the shape, size and depth of the effective measuring volume. For particle sizes between 30 and 120 μm the depth of the measuring volume of a 600-μm fibre probe is between 0.2 mm for solid concentrations near the fixed-bed state and approximately 4 mm for solid volume concentrations as low as 0.1 vol.-%.
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  • 43
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    Particle and Particle Systems Characterization 10 (1993), S. 86-91 
    ISSN: 0934-0866
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
    Notes: To produce disperse products, the characterization of the disperse state and a knowledge of the property function are essential. Property functions are applied not only to characterize the quality of an end product, but also to determine the influence of different processing steps on its state. Hence it is necessary to know the property and process functions for quality assurance of the products and for safety of the processes.Good laboratory particle measuring technologies are available for investigating property and process functions. On the basis of these functions, process control takes place. On-line or, better, in-line measuring techniques are necessary to enable the accompanying process information to be obtained.
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  • 44
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    Particle and Particle Systems Characterization 10 (1993), S. 79-85 
    ISSN: 0934-0866
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The paper discusses the interest in conventional triaxial tests widely used in soil mechanics for a better understanding of both the mechanical behaviour and flow characteristics of granular bulk materials. It proposes a rheological characterization of granular foodstuffs on diverse types of stress path using a conventional triaxial cell. The characteristic state concept, defining the disaggregation threshold of the granular structure, is found to be suitable and even indispensible for examining the mechanical behaviour and the flowability of stored bulk materials. The experimental results readily suggest, as an indicator of the arching effect, a rheological index that characterizes the particle interlocking breakdown and hence the flowability of the stored materials. In addition, this study offers a realistic physical meaning for parameters in use in constitutive models (yield conditions and flow rules) when describing granular flow in various hopper geometries. The case of silos equipped with vibrating hoppers necessitates additionally the study of the rheological behaviour of materials under cyclic and vibratory loadings in order to analyse the processes of densification or disaggregation conditioning the flowability of the stored materials during emptying operations.
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  • 45
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    Particle and Particle Systems Characterization 10 (1993), S. 111-117 
    ISSN: 0934-0866
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The Extended Boundary Condition Method (EBCM), also known as the T-matrix method, is used to compute exactly the scattered intensities from homogeneous isotropic circular cylinders characterized by relative refractive index N, diameter D and length L. The domain of convergence of the method regarding the parameters N, D, L is established. The effect of the geometry of the fiber ends on the scattered intensities is considered. The incident field is assumed to be a linearly polarized plane harmonic wave.
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    Particle and Particle Systems Characterization 10 (1993), S. 252-261 
    ISSN: 0934-0866
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A review of existing and developing process tomographic instrumentation suitable for characterising dry and wet particulate systems is presented. Factors governing the selection of sensing techniques appropriate for static and dynamic imaging of a wide range of single and multiphase particulate processes are discussed. The paper presents a systematic comparison of different image reconstruction methods. Examples of existing, developing and proven applications are cited. Future needs and ways in which these needs can be met are suggested, including the use of multi-modality methods in which different types of sensing methods are embodied in a single tomographic instrument.
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    Particle and Particle Systems Characterization 10 (1993), S. 266-270 
    ISSN: 0934-0866
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
    Notes: On-line characterization of powder and droplets during gas atomization of molten metals and alloys offers extensive opportunities for real-time process monitoring and control. The capability to make on-line measurements can significantly reduce tedious and costly powder classification, which, currently, is always carried out subsequent to the atomization process. Two laser-based particle sizing instruments, the EPCS (ensemble instrument) and PCSV (single particle instrument), were used during gas atomization of zinc with a double Coanda nozzle configuration. The laser instruments were positioned in the duct leading from the bottom of the atomization tower to the powder collection cyclone. The effect of gas to metal ratio on particle size was studied by varying the atomization gas pressure from 0.69 MPa to 1.03 MPa. Air was used as the atomizing gas for some of the 0.69 MPa runs, while nitrogen was used for all of the higher-pressure runs. Experimental apparatus and procedures for atomization and on-line powder sizing with the EPCS and PCSV are described. EPCS and PCSV measurements, which were compared with standard sieve analyses, indicate that the ensemble instrument is a good candidate for on-line process monitoring and control.
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    Particle and Particle Systems Characterization 10 (1993), S. 290-293 
    ISSN: 0934-0866
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
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    Particle and Particle Systems Characterization 10 (1993) 
    ISSN: 0934-0866
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
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    Particle and Particle Systems Characterization 10 (1993), S. 246-251 
    ISSN: 0934-0866
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A method for the rapid on-line determination of surface area and solids content in flowing concentrated slurries using low field NMR spin-lattice relaxation measurements has been developed and demonstrated. The relationship between flow and spin-lattice relaxation time (T1) of protons in water at 20 MHz was examined using aqueous copper sulfate solutions. The ability to measure surface area and solids concentration in both stagnant (stopped flow) and flowing systems via NMR was demonstrated using several different concentrated aqueous titania and glass slurries (20 to 80 weight percent) for which the dried powder surface area was previously determined via nitrogen adsorption/BET analysis and the solids content determined gravimetrically. Surface areas were also calculated from particle size analysis and found to vary by up to an order of magnitude from the adsorption and NMR results.
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  • 51
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    Particle and Particle Systems Characterization 10 (1993), S. 239-245 
    ISSN: 0934-0866
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Aggregates formed from colloidal particles will vary in shape according to the aggregation regime prevalent. Compact structures are formed when the aggregation is slow, whilst loose tenuous structures are formed when rapid (or diffusion limited) aggregation prevails. These structures can be fractal in nature, that is, there is a relationship between porosity and the number of primary particles making up the aggregate, and is described by the fractal dimension, dF. Fractal dimensions of hematite aggregates have been measured experimentally using the static light scattering technique. Fractal dimensions varied with aggregation regimes; for the rapid aggregation regime, dF was found to be 2.8, whilst for conditions in which aggregation was slow (retardation forces prevail), dF's of 2.3 were measured. For conditions which lead to aggregation in which both diffusion and retardation forces play a part, structures with fractal dimensions such that 2.3 〈 dF 〈 2.8 were found.The effects of adsorbed fulvic acid, a naturally occuring organic acid, on the kinetics of hematite aggregation and on the resulting structure of hematite aggregates were also investigated. The study of aggregate structure shows that the fractal dimensions of hematite aggregates which are partially coated with fulvic acid molecules are higher than those obtained with no adsorbed fulvic acid. The scattering exponents obtained from static light scattering experiments of these aggregates range from 2.83 ± 0.08 to 3.42 ± 0.1. The scattering exponents of greater than 3 indicate that the scattering is the result of objects that contains pores which are bounded by surfaces with a fractal structure, and can be related only to surface fractal dimension. The high fractal dimensions are due to restructuring within the aggregates, which only occured at low coverage by the organic acid.
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    Particle and Particle Systems Characterization 10 (1993), S. 234-238 
    ISSN: 0934-0866
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
    Notes: This work on imaging of particulate processes using electrical charge tomography uses two basic techniques: the multi-sensing of electrical charge in a cross-section of the flow pipe and a neural network based flow regime identification system to aid in the image reconstruction process.A measurement system, consisting of sixteen sensors, placed at equal distance from each other around the boundary of a circular 100 mm bore pipe, is used to determine the voltage profile of the flow for several artificially produced flow regimes: full, annular, core, half and stratified. A sand flow system is used to produce these different flow regimes, which are created artificially by using baffles of different shapes that obstruct the sand flow.The voltage profile from the sixteen sensors gives spatial information of the flow regime. These profiles are normalised and formed into patterns that are presented to a Kohonen neural network for classification. Two regime classification between clearly distinct regimes gives an accuracy of identification of 85%. Classification of closely similar patterns show much less accuracy of 30%.
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  • 53
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    Particle and Particle Systems Characterization 10 (1993), S. 262-265 
    ISSN: 0934-0866
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
    Notes: In-process measurement of particle size and concentration distributions provides continuous analysis and quality control of a product stream. Elimination of sample handling and operator manipulation is now possible for most pneumatic flows using optical methods which are properly interfaced with the process stream.The EPCS (Ensemble Particle Concentration & Size) described in the following has been used to obtain detailed size distribution measurements in powder production facilities at two second intervals, and has been successfully used for automatic feedback control.
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    Particle and Particle Systems Characterization 10 (1993), S. 271-274 
    ISSN: 0934-0866
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The paper discusses the application of image analysis to multiphase mineral particles. The emphasis is on the development of automatic and routine methods which provide reliable data for the process engineer. Optical systems are discussed briefly, but electron beam instruments are shown to offer many advantages for the identification and discrimination of mineral species. Image capture and analysis procedures are described together with the application of the measured data to aid our understanding of the processing properties of particles of complex structure. Examples are given from studies of beach sands, silver minerals, flyashes, ore characterisation, flotation of base metals, grinding and liberation.
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    Particle and Particle Systems Characterization 10 (1993), S. 279-289 
    ISSN: 0934-0866
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The response of the Partec laser backscatter particle size analyzer has been tested under a variety of conditions. Various materials posessing different light scattering characteristics have been examined and the response of the Partec instrument has been evaluated. In particular the system response to transparent particle systems (e.g. oil in water emulsions) tas been studied. It has been found that the Partec laser backscatter instrument provides reasonably accurate and reproducible results when used to characterize opaque, highly reflective particles such as hydrated alumina, but suffers from a lack of sensitivity to fine transparent particles such as oil droplets. The instrument does, however, readily detect the presence of opaque particle contaminants in oil-water emulsions.
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    Particle and Particle Systems Characterization 10 (1993), S. 357-363 
    ISSN: 0934-0866
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Concrete quality is influenced to a high degree by the granulometry of the aggregates used. In the construction industry, the grain size coefficient of K-coefficient is used as a quantity for the characterization of granulometry. In practice, this quantity is determined experimentally, and it is therefore a random variable influenced by material heterogeneity and errors in sampling, sample preparation and size analysis. Depending on the final use, in concrete production often an aggregate is required, the grain size coefficient of which can be adjusted to a given value Krequ with a prescribed precision. For this reason, continuous supervision of the aggregate quality is necessary using, e. g., automatic sampling and opto-electronic measuring equipment. In order to determine the optimum conditions for the installation of such equipment, the variances of the possible errors must be established. Further, methods for their restriction are necessary. In this paper, investigations involving hand sampling and hand sieving and on the example of a reference gravel plant are reported. The investigations reveal that, for the materials involved, primary samples of at least 1600 g were necessary, which then could be reduced to 200 g by sample splitting, in order to obtain the accuracy desired.
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    Particle and Particle Systems Characterization 10 (1993), S. 40-40 
    ISSN: 0934-0866
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
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    Particle and Particle Systems Characterization 10 (1993), S. 1-6 
    ISSN: 0934-0866
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
    Notes: This paper describes preliminary work carried out on the applicability of fractal geometry in describing the products of comminution events.A nickel sulphide ore was subjected to two comminution events, impact shattering and ball milling. Fractal analysis was performed on samples of the resulting comminution products.Two differing fractal populations resulted, with the impact sample exhibiting particles having higher boundary fractal dimensions than the milled sample. The fractal dimension of the impact fragments increased with decreasing size, whereas the milled particles displayed a more complex distribution.The under-fractal distributions, of the two populations of fragments, generate straight lines when plotted on Gaussian probability paper. This leads to the possibility of being able to predict the distribution of fragments, in fractal terms, of a particular material when subjected to comminution.
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    Particle and Particle Systems Characterization 10 (1993), S. 19-25 
    ISSN: 0934-0866
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The angular patterns of the polarization ratio were calculated for droplets with diameters between 0.020 and 50 μm at 500 nm wavelength. It was observed that the patterns for droplets slightly smaller than 1 μm were dominated by a backward peak belonging to the glory. The peak was successfully used to characterize aerosols of light and heavy oils with a Junge-like size distribution. Experiments conducted with heavy oil sprays produced by air-assisted atomization presented the same feature. A quantitative comparison of the experimental results with the Lorenz-Mie theory showed that the size distribution of these sprays was bimodal.
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    Particle and Particle Systems Characterization 10 (1993) 
    ISSN: 0934-0866
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
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    Particle and Particle Systems Characterization 10 (1993), S. 33-37 
    ISSN: 0934-0866
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A scattered light photometer which monitors the particle number concentration of aerosols is described. The photometer measures the scattered light from illuminated submicron particle clouds with known material properties at certain scattering angles. Intensity ratios in combination with the degree of polarization are used to determine the mean particle diameter and the geometric standard deviation of an assumed log-normal particle size distribution. The determination of the particle size distribution is based on an algorithm which compares the measured and calculated (Mie theory) relative intensity quantities described. Furthermore, the particle number concentration is monitored from a single absolute intensity measurement at one scattering angle. In order to obtain quantitative results a spherical particle shape is required.
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    Particle and Particle Systems Characterization 10 (1993), S. 41-47 
    ISSN: 0934-0866
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A laser-Doppler instrument has been used to measure the migration velocity of NaCl particles in an electrohydrodynamic flow field of an electrical precipitator. The measured average migration velocity of 1.40-μm particles (number distribution median with a geometric standard devitation of 1.46) is approximately five to six times higher than the calculated steady-state velocity for a 1.40-μm particle, provided there is a saturation charge of at least 90f%. Further, the particle velocities in the main flow direction are also influenced by the electrical operation conditions. Both observations demonstrate the important role of the state of the electrohydrodynamic flow field (superposition of moving gas ions and neutral gas molecules) on the particle transport, characterized by the dimensionless electrohydrodynamic number NEHD. A comparison between six different electrohydrodynamic states revealed that NEHD ≍ 1 is a critical value for the mutual interactions between the gas ions and the neutral gas phase. Whereas for NEHD values 〉 1 the stochastic particle motion is chiefly determined by the nonsteady-state character of the negative corona, for NEHD values 〈 1 the particle velocity fluctuations are governed by the turbulence level of the neutral fluid. These finding might be helpful in adjusting the operating conditions in electrical precipitators for and optimized particle separation.
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    Particle and Particle Systems Characterization 10 (1993), S. 62-69 
    ISSN: 0934-0866
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Two undesirable effects occur in particle sizing by dynamic light scattering; statistical noise, and distortion of correlation data. Statistical noise in the correlation data, caused by estimating the autocorrelation of scattered laser light by a time average, leads to non-physical artifacts in the resulting linewidth distribution. These may be removed by regularization, computer modeling, or other techniques. The regularized kernel function for inverting the Laplace transform is calculated, and used to illustrate the problem of noise. Correct choice of the regularization parameter gives the minimum overall error. It is found that excessive error occurs unless the linewidth distribution is modeled over a finite range. Analytical models for the linewidth with finite range, based on the beta distribution of probability theory, are given.Distortion of correlation data may occur in three ways, through a focused or otherwise nonuniform laser beam in the optical system, by insufficient bit resolution in the quantized detection of scattered laser light, or by calculating a first order field autocorrelation from a second order intensity autocorrelation. Unlike noise, distortion cannot be removed by any known methods, since the exact nature of the distortion is unknown. Several examples illustrate how distortion can lead to artifacts in the linewidth distribution which could easily be misinterpreted as segments of a size distribution, not present in the physical sample.
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    Particle and Particle Systems Characterization 10 (1993), S. 70-73 
    ISSN: 0934-0866
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Sampling powder flows in industrial grinding circuits are discussed. Work was done with different types of sampler and with different minerals and sampling objectives. It was found that all the samplers showed marked autocorrelation in sample mass for all the minerals ground. Typical autocorrelation could be found at both high (1 · 10-3-15 · 10-3 Hz) and low (1 · 10-4 - 4 · 10-4 Hz) frequencies. Higher frequencies were attributed to powder transport and low frequencies to mill circuit variations. The effects of the found autocorrelation on systematic errors and on industrial sampling schemes are discussed. Systematic sampling produced large errors if operated at sampling intervals that were high-frequency autocorrelation frequencies or small multiples of these. Low-frequency autocorrelation was less detrimental to the sampling results.
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    Particle and Particle Systems Characterization 10 (1993), S. 129-137 
    ISSN: 0934-0866
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Laser Doppler anemometry (LDA) is one of the most advanced optical measuring techniques for flow velocities and is widely used in industrial and academic laboratories. Based on numerous applications in the past, there is no doubt that LDA is one of the most accurate flow measuring techniques. However, recent investigations have shown that the period lengths of LDA signal bursts are not as constant as one might expect within the individual burst. This can induce an additional scatter in the signal frequency and in the determination of flow velocity from individual bursts. This paper describes experimental investigations which show qualitatively and quantitatively that the particle passage through the laser beams shortly before the point of intersection, i. e. the LDA measuring volume, yields a distorted LDA fringe pattern. The latter results in a scatter of the measured velocity data for those particles passing the center of the measuring volume at the same time.
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    Particle and Particle Systems Characterization 10 (1993), S. 146-151 
    ISSN: 0934-0866
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
    Notes: This paper is devoted to the description of the interaction between a spherical particle and a laser sheet beam (Gaussian beam focused by a cylindrical lens) by using the generalized Lorenz-Mie theory (GLMT). Comparisons between the scattering properties of laser sheet, Gaussian beam and plane wave are carried out.
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    Particle and Particle Systems Characterization 10 (1993), S. 152-155 
    ISSN: 0934-0866
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Various methods are available for reducing or ceasing growth of aggregating suspensions including the addition of highly charged adsorbents (such as gelatin), reduction of ionic strength by dilution, increase in surface charge by alteration in pH and reduction in suspension temperature. The effectiveness of each of these methods in stopping the aggregation of colloidalhematite without altering the aggregate size distribution is examined in this study. Reduction in aggregate temperature is found to be a particularly effective way of stopping the aggregation of hematite while preserving size distribution information.
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    Particle and Particle Systems Characterization 10 (1993) 
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    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
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    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
    Notes: As potential approximation functions for measured two-dimensional distributions, the two-dimensional normal distribution and the two-dimensional log-normal distribution are presented, in addition to mixed forms in which one of the two variables is linearly and the other logarithmically normally distributed. For all four distribution functions, regression curves are calculated, with x being understood as independent and y as dependent variable. The general concept is applied to the specific case of a two-dimensional distribution of particle size x and particle velocity y. In this context, a number of particularities result from the fact that a distinction has to be made between concentration-dependent and flux-dependent measurement.
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    Particle and Particle Systems Characterization 10 (1993), S. 173-181 
    ISSN: 0934-0866
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The particle mass loading effect on the flow structure of a two-phase turbulent jet flow was studied. A particle mass loading ratio ranging from 0 to 3.6 was used as the control parameter. The polystyrene solid particles used had nominal diameters of 210 and 780 μm. The flow Reynolds number, which was based on the pipe nozzle diameter and the fluid-phase centerline mean velocity, was 2 × 104 in the current test. A two-color laser Doppler anemometer (LDA), combined with the amplitude discrimination method and the velocity filter method, was employed to measure the mean velocity distributions for the particle and fluid phases, and the turbulent intensities and Reynolds stresses of the flow. The two-phase jet flow field was measured from the initial pipe exit to 90 D downstream. Another one-component He—Ne laser LDA system was also applied to obtain the energy spectra and temporal correlations of the two-phase jet flow.
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    Particle and Particle Systems Characterization 10 (1993), S. 182-190 
    ISSN: 0934-0866
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Three-dimensional transport processes of monosized droplets in a turbulent swirling shear layer were investigated experimentally and theoretically. A model experiment was designed that represents the spray dispersion produced by airblast atomizers. Based on the experimental results, a stochastic dispersion model was developed in the frame of a Lagrangian formulation. Comparison with these experimental data for the dispersion of monosized droplets were made and proved to be satisfactory. The analysis of the remaining differences between calculation and measurement emphasized the importance of an accurate description of gas-phase turbulence characteristics.
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    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The practical performances of single and multi-angle photon correlation spectroscopy (PCS) for resolving bimodal distributions of industrial poly (methyl methacrylate) samples was investigated in a comparative study by several users affiliated to academic and industrial groups and by two suppliers of commercial equipment. The results for the harmonic intensity averaged diameters obtained by cumulants analysis reported by the different laboratories are in agreement, in addition to the results for the normalized second cumulants. The uncertainty on the latter quantities is large, however. For the bimodal samples with two populations with average diameters in a ratio of about 2.5 : 1, not all users were able to resolve the distribution in its components by single-angle PCS. Some slight improvement was obtained by multi-angle PCS. Other indirect techniques (polarization intensity differential scattering, static light scattering data and disc photosedimentometer) appeared to be superior for resolving the bimodal distributions.
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    Particle and Particle Systems Characterization 10 (1993), S. 156-156 
    ISSN: 0934-0866
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
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    Particle and Particle Systems Characterization 10 (1993), S. 138-145 
    ISSN: 0934-0866
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Essentially the laser two-focus (L2F) and laser Doppler anemometer (LDA) are time-of-flight anemometers. The velocity of particles in the micrometre range is determined within the limits of an optically fixed measurement distance. For this only one optoelectronic receiver for the detection of the scattered light is required [1, 2]. With an arrangement of two receiving optics, positioned under an off-axis angle ϕ and an elevation angle ± ψ to the optical axis of the measurement system, a resolution of three-dimensional structures can be achieved and with regard to spherical particles it is possible to determine the dimensions by means of the temporal or phase shift of the signals in the receiving optics. A particle size-dependent distance inside the measurement volume can be fixed, which has to be passed in order to change the signal from one receiving optics to the other. An LDA with an arrangement of two receiving optics for particle sizing is known as a phase Doppler anemometer (PDA); an L2F designed with two receiving optics can be termed a pulse-displacement two-focus anemometer (P2F). The physical analysis of the two methods with respect to a temporal signal displacement in the receivers yielded new results.
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    Particle and Particle Systems Characterization 10 (1993), S. 229-233 
    ISSN: 0934-0866
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Several solid-liquid suspensions containing submicron particles at moderate to high concentrations (5 to 50 volume percent) are encountered in industrial slurry processing. Measurements of ultrasonic attenuation spectra are used in a newly developed AcoustoPhor particle analysis system to get particle size distributions of such colloidal suspensions. This paper deals with the performance evaluation of the AcoustoPhor system. The automated ultrasonic spectrometer component of the AcoustoPhor system was tested using a reference silicone liquid for its accuracy and precision. The particle size distribution (PSD) estimation capabilities were evaluated using a set of well-dispersed slurries covering a wide range of particle concentrations. Sensitivity to process variations was evaluated in field tests at a pigment manufacturing plant. The AcoustoPhor system appears to be capable of providing reliable PSD data for inorganic pigment slurries with particle diameters ranging from 0.01 to 100 micrometers at particle concentrations as high as 50 volume percent.
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    Particle and Particle Systems Characterization 10 (1993), S. 222-225 
    ISSN: 0934-0866
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Dry test sieving results given by woven wire cloths with a square mesh and by round electroformed apertures were compared using sands of various origin. The difference has been found to be constant and independent of substance and quantile. The quantile obtained on a square mesh was converted into the corresponding quantile on an electroformed sheet of the same nominal aperture by multiplication by a constant factor of 1.21 ± 0.04.
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    Particle and Particle Systems Characterization 10 (1993), S. 201-211 
    ISSN: 0934-0866
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The transmission and diffraction of radiation through dense monolayers of monodisperse opaque spheres were studied for the Fraunhofer domain. Theoretical considerations, numerical calculations and experiments on ultrasonic transmission and on laser light transmission and diffraction yielded corresponding results. Complementary studies included the cases of sterically non-interacting particles (by numerical simulation) and of small particle size parameters (by ultrasonic extinction). Transmission was found to be, in general, a non-linear function of the monolayer density. Secondary effects on the transmission can be attributed to the effect of the monolayer structure (characterized by the pair correlation function) on the angular distribution of diffracted intensity. The results were found to be in accordance with experimental results on extinction in three-dimensional systems.
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    Particle and Particle Systems Characterization 10 (1993), S. 228-228 
    ISSN: 0934-0866
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
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  • 79
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    Particle and Particle Systems Characterization 10 (1993), S. 275-278 
    ISSN: 0934-0866
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An investigation is presented concerning the ability of neural nets to classify particles using contour data. Different nets were trained to classify limestone, quartz and coffee particles by their outer boundaries. The contour lines of the analysed particles were similar and differed only in a complex way. A new method of interpreting the Fourier coefficients is shown, which might lead to a possibility of defining particle shape classes by examples. Information is given concerning the selection and design of the appropriate neural net, e.g. back-propagation, and self-organizing maps. In addition, a possibility of interpreting the trained neural nets is demonstrated.
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  • 80
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    Particle and Particle Systems Characterization 10 (1993), S. 308-312 
    ISSN: 0934-0866
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
    Notes: This paper describes preliminary work carried out on the applicability of fractal geometry for differentiating between wear and contaminant particles found in mining machinery lubrication systems.Coal dust, stone dust and roadstone dust from a granite quarry were used as the contaminant particles and the particles from two crushers, which had failed whilst in service, were used to provide the wear particles.Two differing populations appeared with the wear particles having higher boundary fractals than the contaminant, but tending to spread across a wide range of fractal numbers, whereas the contaminants were lower and fairly tightly grouped.The underfractal distributions of the two populations of particles, generate straight lines when plotted on Gaussian probability paper. This leads to the probability of being able to predict the distribution of particles, in fractal terms between wear and contaminant particles.
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  • 81
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    Particle and Particle Systems Characterization 10 (1993), S. 321-331 
    ISSN: 0934-0866
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A combined theoretical and experimental study has been conducted to evaluate the effectiveness of using large, hollow micro-balloons as LDV seed particles. The study has focused on the ability of phase Doppler systems to size hollow microballoons, the ability of large micro-balloons to respond to high frequency spatial and temporal flow field variations, and the overall advantages and disadvantages of using large microballoons instead of conventional LDV seed particles, such as very small water droplets or polystyrene latex (PSL) particles. This paper discusses the development of a theoretical phase Doppler response model for stratified spheres, the experimental facility, and the theoretical and experimental results.
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  • 82
    ISSN: 0934-0866
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
    Notes: With progress in the advancement of measuring techniques and information processing, it is increasingly possible to analyse even complex signals with on-line methods. After fundamental considerations concerning the evaluation of such signals, digital Fourier spectroscopy is explained as an example of a new development. With this method the image of a particle collection will be transformed by the Fourier transformation. Methods such as used with laser diffraction spectrometry are applied to calculate back to the particle size distribution. After a description of the principles of the procedure, its application is demonstrated by different examples. It can be shown that digital Fourier spectroscopy is superior to conventional image analysis methods especially if the particle density in the image is high and the particles overlap. In a further development step it should be possible to determine the particle size distribution of the bulk from an image of its surface.
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  • 83
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    Particle and Particle Systems Characterization 10 (1993), S. 56-61 
    ISSN: 0934-0866
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An aerosol measurement instrument is presented which allows for the simultaneous measurement of the size distribution, number concentration and velocities of particles. A commercial optical particle counter (OPC) was modified in terms of optics and signal evaluation to provide the required measurement information. The design of this instrument allows the definition of a cubic measuring volume by purely optical means. This is achieved by an aperture/lens system which projects a sharply defined light beam into a stream of aerosol flow. Light scattered from single particles at average angles of 90° is collected by two opposite receiver units, each projecting light on to a separate photomultiplier. The intensity of the scattered light with this instrument is found to be an unambiguous function of the particle size. The total number of particles detected per unit time results in the particle flux. The particle velocity can be calculated, in principle, through the correlation of the signal length and the optical length of the measuring volume, provided that the particles have a straight trajectory through the measuring volume and the measuring volume length in the mean flow direction is well defined. The absence of sharpness in real optical projections effects a border zone of definite length, in which the illumination declines to zero. This leads, together with the low-pass filtering of the particle signals, to an increase in the length of the signal slopes, causing some difficulties in the determination of the signal length. A digital signal evaluation technique was developed that renders possible the clear differentiation between the slope and the kernel region of the signal. The latter represents the motion of particles through the completely illuminated region, which can be a more accurate parameter to define the signal length. In addition to the signal length determination, a cross-correlation technique was tested for its potential to obtain particle velocity. the instrument has two interlaced measuring volumes of nearly the same size, which are shifted for this special application in the main flow direction by 20 μm. The phase difference between the signals from the two photomultipliers, together with the optical distance, yields the particle velocity.
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  • 84
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    Particle and Particle Systems Characterization 10 (1993), S. 74-78 
    ISSN: 0934-0866
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
    Notes: In jet agglomeration plants, powders are agglomerated to obtain good instant properties. The free-falling initial material is wetted in a spray cone by droplets or in a steam jet by condensation at the particle surface. In a subsequent region of high particle concentration, collision between particles occurs and agglomerates form, if the forces of adhesion are strong enough. A commercial measurement device, working according to the principle of Fraunhofer diffraction, was modified for in-line application. It was used to measure particle size distributions and concentrations of solid particles and droplets in jets. A model is presented to calculate local particle sizes by means of mass balances from integral measurements over large volumes. The results of in-line particle size and agglomerate size analyses show the practical importance of dry agglomeration during transport and lead to a better understanding of the subsequent wet agglomeration process.
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  • 85
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    Particle and Particle Systems Characterization 10 (1993), S. 92-94 
    ISSN: 0934-0866
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
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  • 86
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    Particle and Particle Systems Characterization 10 (1993) 
    ISSN: 0934-0866
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
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  • 87
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    Particle and Particle Systems Characterization 10 (1993), S. 99-110 
    ISSN: 0934-0866
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Fractal Geometry developed in 1977 by B. Mandelbrot describes the structure of rugged systems by extending the concepts of classical dimensional analysis to include a fractional addendum to the topological dimension of a system in order to describe the space filling properties of the rugged system. In the 15 years since the publication of Mandelbrot's book describing his seminal ideas fractal geometry has found many applications in fineparticle science and technology. This body of applied knowledge is now known as Applied Fractal Geometry. The purpose of this review is to focus on the various branches of applied fractal geometry of interest to the fineparticle specialist in a systematic manner. The first part is concerned with ruggedness of fineparticle boundaries, the structure of simple porous bodies, fragmentation and powder production, the assessment of the properties of such materials as paper, and the characterization of rough surfaces. The second part will explore the use of fractal dimensions to describe mixing operations, composite bodies, such as synthetic bones, and paint films.
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  • 88
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    Particle and Particle Systems Characterization 10 (1993), S. 158-158 
    ISSN: 0934-0866
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
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  • 89
    ISSN: 0934-0866
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The drawback of conventional sedimentation methods, mainly their extremely long sedimentation time for small particles, can be overcome in two phase flow systems. In this paper several principles which permit the rapid determination of settling rate distributions are discussed. Settling rate distributions can be determined from the accelerated particle movement in a flow of constant velocity at low and high solids concentrations. Another system uses accelerated flow at low solids concentrations. The best utilisation of settling rate applications have socalled cross flow systems as set up in a stagnation point flow, in a flow round a bend, or in the decelerated particle movement perpendicular to a flow of constant velocity.
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  • 90
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    Particle and Particle Systems Characterization 10 (1993), S. 191-200 
    ISSN: 0934-0866
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Fractal dimensions in data space are being used to describe fineparticle systems. The relationship between these new parametric descriptions of fineparticle systems and a more classical description of such system using the classical hyperbolic function is discussed. It is shown that fractal dimensions in data space are useful for presenting data for such diverse systems as pigment clusters in composite materials, avalanching powder systems, ballistically fractured material and pore size distribution of porous bodies as determined by mercury intrusion methods. In particular new data is presented on the usefulness of fractal dimensions for describing the flow properties of powders with and without silica flow agents.
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  • 91
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    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The effect of the geometry of the fiber ends on the scattered intensities is considered. A new modification of the Rayleighdebye-Gans (RDG) approximate theory, the Mie Substitution Theory (MST) theory, is introduced. The Boundary Value Method (BVM) for the infinite cylinder, the RDG theory, the Shifrin (SFR) modification of the RDG theory and the MST theory are compared with the EBCM theory for various values of fiber diameter, length, refractive index and for various fiber orientations, including random orientation. Scattering from suspensions of fibers, typical of UICC crocidolite and anthophyllite asbestos fibers, is considered using the BVM, the MST and the RDG theories when the fibers are assumed to be aligned and the MST and the RDG theories when the fibers are assumed to be randomly oriented.
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  • 92
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    Particle and Particle Systems Characterization 10 (1993) 
    ISSN: 0934-0866
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
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  • 93
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    Particle and Particle Systems Characterization 10 (1993), S. 347-352 
    ISSN: 0934-0866
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Pellets of sintered Al2O3 of approximately 3 mm diameter and length were broken in the Brazilian mode and the distribution of strength obtained. It was found that there was also a distribution of Young's modulus E. Hertzian theory implies that the maximum impact force of a pellet fired against a rigid target would depend on E. However, since the pellets can strike in different geometries there is a distribution of impact force for a fixed E. Comparison of theory with data obtained with a force-time transducer as the target showed that the major variation of maximum recorded force could be assigned to the variation of E. The median of the maximum recorded force varied with velocity as v6/5, implying that the pellets behaved approximately as impacting spheres. An attempt was made to predict the probability of breakage in one impact from convoluting the distribution of impact force with the strength distribution from the Brazilian test converted to the equivalent strength distribution expected for impacting spheres. This gave the correct order of magnitude but did not accurately predict the experimental values.
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  • 94
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    Particle and Particle Systems Characterization 10 (1993), S. 353-356 
    ISSN: 0934-0866
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Investigations on the size control of pneumatically conveyed coarse particles were carried out using a microphone which detects the structure-borne sound caused by the impact of the particles on the pipe wall. Modes of eigenvibrations of the pipes are excited up to a maximum frequency, which decreases with increasing particle size. In an assembly of different sized particles, the lower frequencies are more stimulated as the fraction of larger particles increases. Changes in the particle size distribution are detected by analysing the intensities of the vibration modes which are set up in the walls of the tube by particle impact. One application is the monitoring of the upper range of a particle size distribution.
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  • 95
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    Particle and Particle Systems Characterization 10 (1993), S. 364-365 
    ISSN: 0934-0866
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
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  • 96
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    Particle and Particle Systems Characterization 10 (1993), S. 300-300 
    ISSN: 0934-0866
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
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  • 97
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    Particle and Particle Systems Characterization 10 (1993), S. 301-307 
    ISSN: 0934-0866
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The apparent fractal dimension of normalized rugged compressive force-deformation curves of two types of brittle particulates was determined using the blanket algorithm. Although the shape of the original force-deformation relationships of the individual specimens was irreproducible, the apparent fractal dimension of the normalized data was fairly constant and characteristic of the material. The applicability of the algorithm and the validity of the results were tested with computer simulated relationships generated with a set of Weierstrass functions whose fractal dimension was known a-priori. It is demonstrated that as long as the resolution along the two axes is the same, the fractal dimension so calculated provides an absolute rather than a relative measure of the relationship's jaggedness.
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  • 98
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    Particle and Particle Systems Characterization 10 (1993), S. 313-320 
    ISSN: 0934-0866
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The development and change of surface ruggedness in chars was studied at conditions typical in a pulverized coal furnace. The fractal dimension, a measure of surface ruggedness, of chars was measured using physisorption techniques. By adjusting the temperature encountered (1173 to 1773 K) and residence time (0.1 to 1.5 s) of the synthetic coal (sized to 46-106 μm diameter), chars at different stages of combustion were prepared in a laminar flow (drop-tube) furnace. The particles were quickly cooled and quenched in an inert atmosphere. The samples were examined using a scanning electron microprobe, and their fractal dimensions were determined using gas physisorption. The adsorption data were used to test if the char surface was fractal on a molecular scale, to determine the fractal dimension, and to quantify changes in the fractal dimension during combustion. The fractal dimension of the unburned synthetic coal was approximately 2. The fractal dimension increased as high as 2.85 as the carbon matrix burned away and exposed mineral moieties. However, as combustion continued the carbon burned completely away leaving a mineral fly ash particle with a fractal dimension as low as 2.47.
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  • 99
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    Particle and Particle Systems Characterization 10 (1993), S. 332-338 
    ISSN: 0934-0866
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The effects of the particle trajectories on phase Doppler measurements were explored numerically using generalized Lorenz-Mie theory. Computations were performed for a commercial phase Doppler system and various schemes for elimination of the trajectory effects were examined. It is shown that these effects cannot be completely suppressed if the ratio of the two measured phase shifts from a single receiving unit is used to validate the measurements. On the other hand, the errors due to particle trajectories can be eliminated satisfactorily by employing an additional receiving unit, which allows one to detect the asymmetry of the scattered light pattern due to displacement of the particle trajectory from the centre of the measuring volume. A preliminary experimental evaluation of this method is presented and discussed.
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  • 100
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    Polymer Engineering and Science 33 (1993), S. 83-91 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The memory effect of shear history was studied with poly(ethylene terephthalate) (PET) prepared under different shear conditions of 11.7 to 1168 s-1 in a capillary rheometer. The shear history of PET resin led to a memory effect, which in turn affected the crystallization kinetics. The crystallization rate increased with increasing shear rate. Double peaks of heating crystallization exotherms and a low value of Avrami exponent appeared at low shear rates, which was attributed to the existence of crystallization processes with different rates; one was the fast process involving the disentangled molecules that persisted during melting, and the other was the slow process involving the highly entangled molecules. The change of instantanenous Avrami exponent and overall crystallization rate constant was in good agreement with the expected trends assuming coexistence of the two crystallization processes. The crystallization kinetics of PET with shear history could be regarded as a growth rate decrease problem to be interpreted by the modified Avrami equation, 1 - Vc = exp[- K·f(t)n], when the fast process dominated the overall crystallization. The effect of shear history was reduced because of the relaxation process as the holding time in melt state before crystallization was increased.
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