ALBERT

Description: The quantum yield and reaction threshold for the photochemical dissociation of cyanoacetylene into a hydrogen atom and the cyanoethynyl radical have been determined. The quantum yield at 185 nm is approximately 0.09. The threshold is approximately 240 nm. Combination of this data with literature values shows that production of excited-state cyanoacetylene is the major primary process resulting from irradiation between 185 and 254 nm. Also determined are the relative rate constants for the abstraction of a hydrogen atom from hydrogen, methane, and ethane by the cyanoethynyl radical (k(H2):k(CH4):k(C2H6) = 1:9.3:63). Implications of these results for the proposal that hydrogen abstraction plays an important role in the conversion of methane to ethane and in the protection of unsaturated compounds from photoconsumption in the atmosphere of Titan are discussed.

Description: The atmospheric flow on Io is numerically computed in a flat 2-D axisymmetric geometry for a sublimation atmosphere on the trailing hemisphere subjected to plasma bombardment, UV heating, and IR cooling. Calculations are performed for subsolar vapor pressures of approximately 6.5 x 10(exp -3) Pa (approximately 3 x 10(exp 18) SO2/sq cm) and 6.8 x 10(exp -4) Pa (approximately 4 x 10(exp 17) SO2/sq cm); the latter approximates the vapor pressure of F. P. Fanale et al. (1982). The amount of plasma energy deposited in the atmosphere is 20% of the plasma flow energy due to corotation (J. A. Linker et al., 1988). It is found that plasma heating significantly inflates the upper atmosphere, increasing both the exobase altitude and the amount of surface covered by more than an exospheric column of gas. This in turn controls the supply of the Io plasma torus (M. A. McGrath and R. E. Johnson, 1987). The horizontal flow of mass and energy is also important in determining the exobase altitude; and it is shown that IR cooling can be important, although our use of the equilibrium, cool-to-space approximation for a pure SO2 gas (E. Lellouch et al., 1992) may overestimate this effect. The calculated exobase altitudes are somewhat lower than those suggested by McGrath and Johnson (1987) for supplying the torus, indicating the details of the plasma energy deposition and sputter ejection rate near the exobase, as well as the IR emission from this region need to be examined. In addition, the molecules sublimed (or sputtered) from the surface are transported to the exobase in times short compared to the molecular photodissociation time. Therefore, the exobase is dominated by molecular species and the exobase is supplied by a small region of the surface.

Description: Iapetus shows a greater hemispheric albedo asymmetry than any other body in the solar system. Hapke scattering theory and optical constants measured in the laboratory are used to identify possible compositions for the dark material on the leading hemisphere of Iapetus. The materials considered are poly-HCN, kerogen, Murchison organic residue, Titan tholin, ice tholin, and water ice. Three-component mixtures of these materials are modeled in intraparticle mixture of 25% poly-HCN, 10% Murchison residue, and 65% water ice is found to best fit the spectrum, albedo, and phase behavior of the dark material. The Murchison residue and/or water ice can be replaced by kerogen and ice tholin, respectively, and still produce very good fits. Areal and particle mixtures of poly-HCN, Titan tholin, and either ice tholin or Murchison residue are also possible models. Poly-HCN is a necessary component in almost all good models. The presence of poly-HCN can be further tested by high-resolution observations near 4.5 micrometers.

Description: We prospose a new center and ring assignment for the original Chryse impact basin based upon photogeologic mapping of Noachian outcrops and re-examination of the published geology using orthographic projections. While others have centered the Chryse impact on the topographic low associated with Hesperian volcanic and fluvial deposits, we suggest that the center of the Noachian-age excavation cavity was located approximately 800 km to the north, and that the basin topography was modified significantly from the Noachian into the Hesperian. Evolution of the topographic low included structural modification by a later impact centered in Acidalia, restricted volcanic deposition and loading, localized subsidence, and restricted deposition from the circum-Chryse outlfow channels.

Description: The formation of a large volcano loads the underlying lithospheric plate and can lead to lithospheric flexure and faulting. In turn, lithospheric deformation affects the stress field beneath and within the volcanic edifice and can influence magma transport. Modeling the interaction of these processes is crucial to an understanding of the history of eruption characteristics and tectonic deformation of large volcanoes. We develop models of time-dependent stress and deformation for the Tharsis volcanoes on Mars. By means of a finite element code, we calculate stresses and displacements due to a volcano-shaped load emplaced on an elastic plate overlying a viscoelastic mantle. Models variously incorporate growth of the volcanic load with time and a detachment between volcano and lithosphere. The models illustrate the manner in which time-dependent stresses induced by lithospheric plate flexure beneath the volcanic load may affect eruption histories, and the derived stress fields can be related to tectonic features on and surrounding Martian volcanoes. As a result of flexure there are three regions where stresses become sufficiently large to cause failure by faulting, according to the Mohr-Coulomb criterion: at the surface of the plate just outward of the volcano, near the base of the elastic lithosphere beneath the center of the volcano, and on the upper flanks of the volcano early in its growth history.

Description: The temperature structure within the northern auroral region of Jupiter is studied by reanalyzing the Voyager 1/infrared interferometer and radiometer spectrometer (IRIS) spectra. The total measured excess infrared auroral zone emission (averaged over the IRIS field of view) in the hydrocarbon bands between 7 and 13 microns is found to be about 208 ergs/cm/s over an area of about 2 x 10(exp 18) sq cm with a resulting power output of 4 x 10(exp 13) W. In comparison, the total energy deposition by magnetospheric charged particles has been estimated on the basis of UV observations to range between 1 x 10(exp 13) and 4 x 10(exp 13) W over a comparable area. The large amount of radiated energy observed in the infrared may imply an additional heat source in the auroral regions (possibly Joule heating). A new set of thermal profiles of Jupiter's high-latitude upper atmosphere has also been derived. These profiles have a large temperature enhancement in the upper stratosphere and are constrained to reproduce the CH4 emission at 7.7 microns. The emission in the other hydrocarbon bands (C2H2 and C2H6) is found to depend on the depth to which the temperature enhancement extends, which further constrains the thermal profiles. This study shows that a large temperature enhancement in the upper stratosphere and lower thermosphere can explain the observed excess hydrocarbon emission bands; thus smaller variations in hydrocarbon abundances (between the high latitudes and the equatorial and middle latitudes) are required than has been assumed in previous models.

Description: Observations of (O I) 6300-A emission near Io have been obtained in 1990, 1991, and 1992 by the National Solar Observatory staff using the solar-stellar spectrography on the McMath-Pierce telescope at Kitt Peak. High-resolution spectra with a resolving power of about 1.2 x 10(exp 5) were obtained with an integration time of 10-15 min each. The viewing aperture for the observations was 5.2 arc sec x 5.2 arc sec centered on Io, with spatial resolution limited within this area by seeing conditions. Observations thus far have been reduced to obtain average brightness values over the aperture which range from approximately 200 to 1000 R for a number of different Io phase angles and Io system III longitudes. The (O I) 6300-A emission brightness exhibits an east-west asymmetry, where the average intensity for Io phase angles in the west (receding ansa) is 1.5 times brighter than in the east (approaching ansa). Similar east-west intensity ratios have also been observed for neutrals near Io and ions in the plasma torus for a number of other optical and ultraviolet emission lines which are excited by electron impact. In addition to the east-west asymmetry, the (O I) 6300-A emission brightness exhibits a strong dependence on the Io system III longitude angle, with a maximum value occurring in the range 200 deg +/- 50 deg. Earlier IUE observations of ultraviolet emission lines of O and S near Io obtained over a number of years have measured the east-west asymmetry, but the long IUE integration times of approximately 7-14 hours masked any detection of system III variability. For the (O I) 6300-A emission, the O(1D) state may be excited by electron impact of atomic oxygen and by electron impact dissociation of SO. The molecule SO may be present at the exobase or may be produced above the exobase as the dominant product of SO2 dissociation by electron impact. Preliminary assessment indicates that production of O(1D) by molecular dissociation may be more important. The (O I) 6300-A emission may therefore provide a remote signature for monitoring (1) the upward transport rates of molecular species in Io's atmosphere, (2) the relative abundance and time-variable dissociation of SO2 and/or SO at the exobase and in the corona of Io, and (3) the spatial distribution of these escaping molecular and atomic species and their ion production rates in the planetary magnetosphere.

Description: Multiangle Advanced Solid State Array Spectroradiometer (ASAS) and Portable Apparatus for Rapid Acquisition of Bidirectional Observations of Land and Atmosphere (PARABOLA) visible and near infrared reflectance data covering the Lunar Lake playa, Nevada, were modeled using specular and volume scattering theory. The volume component used to model the data was based on the Hapke (1986) model and the specular scattering component was based on Fresnel reflection from surface facets with a distribution of tilts. Specular scattering was needed to explain the several-fold increase in reflectance observed at high phase angles in the solar principal plane. Results imply single scattering albedos of approximately 0.93 to 0.95, a real index of refraction value of approximately 1.52 (at a wavelength of 0.66 micron), a small imaginary index of refraction and an exponential facet tilt probability function for the playa. Electron micrographs showed th playa surface to consist of ensembles of smooth, micrometer-scale ellipsoidal particles on gently undulating topography at the millimeter to centimeter scale. The exponential probability function is consistent with this observation. Mars and the icy satellites are discussed as possible places to look for a significant specular scattering component.

Description: This report describes a general plan and the pertinent technological requirements for TOPS (Toward Other Planetary Systems), a staged program to ascertain the prevalence and character of other planetary systems and to construct a definitive picture of the formation of stars and their planets. The first stages focus on discovering and studying a significant number of fully formed planetary systems, as well as expanding current studies of protoplanetary systems. As the TOPS Program evolves, emphasis will shift toward intensive study of the discovered systems and of individual planets. Early stages of the TOPS Program can be undertaken with ground-based observations and space missions comparable in scale to those now being performed. In the long term, however, TOPS will become an ambitious program that challenges our capabilities and provides impetus for major space initiatives and new technologies.

Description: We present a comprehensive analysis of data obtained during the 1989 July 3 occultation of 28 Sgr by Titan. The data set includes 23 lightcurves from 15 separate stations, spanning wavelengths from 0.36 to 0.89 micron. A detailed model of the structure of Titan's atmosphere in the altitude range 250 to 450 km is developed, giving the distribution of temperature, pressure, haze optical depth, and zonal wind velocity as a function of altitude and latitude. Haze layers detected in Titan's stratosphere are about one scale height higher than inferred from Voyager data, and show a wavelength dependence indicative of particle sizes on the order of 0.1 micron. A marked north-south dichotomy in haze density is observed with a transition to lower density south of about -20 deg latitude. Zonal wind speeds are inferred from global distortions from spherical symmetry and are of the order of 100 m/s with significant increase toward higher latitudes. Titan's high atmosphere shows substantial axial symmetry; the position angle of the symmetry axis is equal to the position angle of Saturn's spin axis to within about 1 deg.