ALBERT

Description / Table of Contents: INTRODUCTION The evaporite deposits of the Werra district, especially in the Hattorf mining field, are considered a worldwide unique location for the occurence of numerous basalt dikes and magmatic fluid phases fixed in salt rocks. In spite of the great number of studies dealing with the magmatites in the Werra region, previous investigations have rarely attempted more than a predominantly 'qualitative' description of the basaltic rocks and the effects of volcanism on the evaporites (see Chapter 2). The method of interpreting the mineralogical and chemical composition of the evaporites at the basalt contact is based on previous works (KNIPPING 1984; KNIPPING & HERRMANN 1985). This study should contribute to understanding (i) the mechanism of intrusion of the basaltic rnelts and (ii) the metamorphic processes occurring in the evaporites caused by mobile phases during volcanism. Hence, the following methods were applied: The mineralogical and chemical description of the basaltic rocks with recent nomenclature including the possible differences between individual dikes and between surface- and subsurface-exposed basalts. Seven surface and 48 subsurface exposures at the Hattorf mine of Kali & Salz AG were studied. Application of the most recent knowledge on basalt genesis for interpreting observational and experimental results. Studies on the sulfur and carbon isotope distributions of the native sulfur from several subsurface exposures and the enrichments of gases (predominantly CO2) in the evaporites. Calculation of the spatial and temporal temperature distribution in the evaporite rocks following intrusion of the basaltic melts. For purposes of clarity a few of the terms which will be used frequently here will first be defined: basalt - all of the intrusive rocks studied can be assigned mineralogically and chemically to the basalt family in a broader sense. Thus, the terms basaltic rock or, in short, basalt will be used for these rocks. rock salt - instead of the term salt for halitic rocks the term rock salt is used. Besides, the evaporites are generally designated as host rocks (for the basalt dikes) as well. gases - especially in the German literature the term carbon dioxide or carbonic acid (= Kohlensäure) is frequently used for the gases enclosed in the evaporites of the Werra-Fulda district. ACKERMANN et al (1964) found, in addition to carbon dioxide, considerable amounts of nitrogen and minor amounts of methane. In the following therefore the terms gas mixture or gas will be used. The various basalt dikes found in the Hattorf mining field are described here in terms of their mineralogy and geochemistry for the first time. In doing so it is necessary to number them from east to west. To avoid confusion with older numerations (e.g. SIEMENS 1971) the various dike systems are designated by capital letters (A to P).

Description / Table of Contents: INTRODUCTION Sediments are increasingly recognized as both a carrier and a possible source of contaminants in aquatic systems, and these materials may also affect groundwater quality and agricultural products when disposed on land. Contaminants are not necessarily fixed permanently by the sediment, but may be recycled via biological and chemical agents both within the sedimentary compartment and the water column. Bioaccumulation and food chain transfer may be strongly affected by sediment-associated proportions of pollutants. Benthic organisms, in particular, have direct contact with sediment, and the contaminant level in the sediment may have greater impact on their survival than do aqueous concentrations. Following the findings of positive correlations between liver lesions in English Sole and concentrations of certain aromatic hydrocarbons in Puget Sound (Washington) sediment, it can be suspected that such substrates may also be responsible for a host of other serious and presently unrecognized changes at both the organismal and ecosystem levels (Malins et al., 1984). Modern research on particle-bound contaminants probably originated with the idea that sediments reflect the biological, chemical and physical conditions in a water body (Züllig, 1956). Based on this concept the historical evolution of limnological parameters could be traced back from the study of vertical sediment profiles. In fact, already early in this century Nipkow (1920) suggested that the alternative sequence of layers in a sediment core from Lake Zürich might be related to variations in the trophic status of the lake system. During the following decades of limnological research on eutrophication problems sediment aspects were playing only a marginal role, until it was recognized that recycling from bottom deposits can be a significant factor in the nutrient budget of an aquatic system. Similarly, in the next global environmental issue, the acidification of inland waters sediment-related research only became gradually involved. Here too, it is now accepted that particle-interactions can affect aquatic ecosystems, e.g. by enhancing the mobility of toxic metals. In contrast to the eutrophication and acidification problems, research on toxic chemicals has included sediments aspects from its beginning: Artificial radionuclides in the Columbia and Clinch Rivers in the early sixties (Sayre et al., 1963); in the late sixties heavy metals in the Rhine River system (De Groot, 1966) and methyl mercury (Jensen & Jerne- 16v, 1967) at Minamata Bay in Japan, in Swedish lakes, in Alpine Lakes, Laurentian Great Lakes and in the Wabigoon River system in Canada; organochlorine insecticides and PCBs in Lakes St. Clair and Erie during the seventies (Frank et al., 1977); chlorobenzenes and TCDDs in the Niagara River system and Lake Ontario in the early eighties (Oliver & Nicol, 1982; Smith et al., 1983). In the present lecture notes, following the description of priority pollutants related to sedimentary phases (Chapter 2), four aspects will be covered, which in an overlapping succession also reflect the development of knowledge in particle-associated pollutants during the past twenty-five years: - the identification, surveillance, monitoring and control of sources and distribution of pollutants (Chapter 3); - the evaluation of solid/solution relations of contaminants in surface waters (Chapter 4); - the study of in-situ processes and mechanisms in pollutant transfer in various compartments of the aquatic ecosystems (Chapter 5);- The assessment of the envlroD-mental impact of particle-bound contaminants, i.e. the development of sediment quality criteria (Chapter 6). A final chapter will focus on practical aspects with contaminated sediments. Available technologies will be described as well as future perspectives for the management of dredged materials. Here too, validity of remedial measures can only be assessed by integrated, multidisciplinary research. In the view of the growing information on the present subject and owing to the limitations in the framework of this monography, the reader is referred to additional selected bibliography, which is attached at the end of this Chapter i. Additional information on the more recent publications on contaminated sediments is given in the annual review volume of the Journal of the Water Pollution Control Federation, June edition.

Description / Table of Contents: PREFACE It is increasingly necessary to develop industrial and hydraulic engineering constructions under unfavourable geological or geotechnical conditions. Furthermore, it becomes more and more important to build effectively and economically and to find optimal solutions for a long-term steady function of the constructions. This emphatically demands exhaustive information on the structural situations and engineering parameters of local site assessments by areal investigations of the sites and the petrophysical parameters in situ. This requires, however, the use of geophysical techniques. During the last two or three decades international applied geophysics has systematically developed new possibilities for site investigations for the determination of petrophysical parameters in situ as well as for observation of the system building and site. As in "New techniques in engineering", geophysical methods make it possible to develop areal models of subsurface conditions of building sites, to quantify relevant engineering parameters in situ, as well as to analyze the longterm behaviour of the buildings, which are influenced by internal or external factors. With regard to the broad spectrum of applied geophysics, there are few methods, that especially favour application in engineering and groundwater studies. These methods are distinguished by a relatively simple measuring technique and good measuring progress, e.g. the geoelectrical self-potential method, the geoelectrical resistivity method as well as a newly developed devices for geothermic measurements. There exist numerous publications, broadly scattered in the technical literature, concerning the theoretical bases and applications of these methods, but until now, there have been only a few meetings to exchange experience and results on an international level. This was the aim of the symposium "Detection of Subsurface Flow Phenomena by Self-Potential/Geoelectrical and Thermometric Methods", held in Karlsruhe from 14-18 March 1988. An outstanding part of the symposioum was represented by the results of a research project, coordinated by the University of Karlsruhe (Department of Geology and Institute of Soil and Rock Mechanics) and the Federal Waterway Engineering and Research Institute (BAW), Karlsruhe. Regarding the subject "Experiments to ascertain the relations between hydraulic potentials in the underground and the geoelectrical and thermic potentials set off by these", the research work took four years. The project was sponsered by the Volkswagen Foundation/Hannover. The goal was to develop and test objective techniques for detecting leakages in dams, locating, demarcating and designating quantitatively inhomogeneous spheres in dams with the aim of detecting damage and subsurface flow phenomena as soon as possible. The symposium consisted of a three-day lecture meeting with about 40 papers and a summarizing respectively closing roundtable discussion, a visit to the laboratories and to the in situ constructions within the area of BAW developed in the frame of the research project. This included a technical excursion to the Rhine-Staustufe Iffezheim with its very impressive waterway constructions and an excursion to the Geophysical Observatory near Schiltach (Black Forest). The Observatory belongs to the Universities of Karlsruhe and Stuttgart. Approximately 80 scientists from 15 countries participated the symposium. They were welcomed by the Rector of the University, Professor Dr. A. Kunle and the representative of the Federal Ministry of Traffic, Dr. G. Schröder. Professor Dr. H. Hötzl elucidated the scientific problems and the economical importance of the project as a speaker of the research group. The following papers dealt with the fundamental aspects of geoelectrical and thermometric measurements, with the theory of these methods, the state and developing ter~dencies concerning devices, data acquisition, processing and interpretation as well as noise effects. It became clear that the solution of the complex scientific-technical problems of waterway constructions and environmental protection requires broad, interdisciplinary cooperation and international collaboration. Thus it would be possible to minimize the personnel, temporal and economic efforts. The intended cooperation of geoscientists, engineering geologists, building engineers and representatives of other disciplines make it possible, not only to exchange experiences and results relating to international problems unsolved until now, but also to determine new guidelines with regard to the scientific organization of further investigations. Thus in order to inform all interested parties of the main topics of the symposium and to advance international cooperation in the future, the present review includes a part of the papers and reports of the excursions recommended by the participants of the meeting, which have been divided into the following topics: - Introduction to engineering-geophysical problems and attempts at their solution; - Geoelectrical self-potential measurements; - Geoelectrical resistivity measurements; - Geothermic measurements; - Case histories; - Some topics of the roundtable discussion; - Reports concerning the excursions. The editors wish to thank very much all those, who contributed to the success of the symposium and to the publication of the present report. Finally they venture the note, that the authors theirselves are responsible for the content of their papers.

Description / Table of Contents: PREFACE During the so-called Mid-Cretaceous interval, approximately 100 million years ago, the earth experienced a dynamic phase in its geologic history. Enhanced global tectonic activity resulted in a major rearrangment of the continental plates; accelerated spreading rates induced a first-order sea level highstand; intense off-ridge volcanism contributed to a modeled high atmospheric CO 2 rate; climatic conditions fluctuated; and major changes occurred in biologic evolutionary patterns. With the initiation of a gradual change from an equatorial, east-west directed current-circulation pattern to a regime, dominated by south-north and north-south directed current systems, the earth's internal clock was set for Cenozoic, "modern" times. The Mid-Cretaceous dynamic phase is recorded in a suite of sediments of remarkable similarity around the globe. Shallow-water carbonate platforms drowned on a global scale; widespread sediment-starved, glauconite and phosphate- rich sequences developed; and consequently, pelagic sedimentary regimes "invaded" shelf and epicontinental sea areas. This typical "deepening-upward" pattern is well-documented in Mid-Cretaceous sequences along the northern Tethys margin. Shallow-water carbonates are overlain by condensed glauconitic and phosphatic sediments, which, in turn, are blanketed by pelagic carbonates. In this volume, the example of the western Austrian helvetic Alps, built up of inner and outer shelf sediments deposited along the northern Tethys margin, is used to elucidate the paleoceanographic conditions, under which the Mid-Cretaceous triad of platform carbonates, condensed phosphatic and glauconitic sediments, and pelagic carbonates was formed. In the first part, the evolution of this sequence is traced from the demise of the platform (Aptian) to the return of detritus-dominated deposition (Upper Santonian). The second part includes a discussion of the reconstructed paleoceanographic and tectonic variables, their possible interaction, as well as their influence on sediment properties during this period. Special attention is paid to (1) subsidence behavior of the inner, platform-based shelf and the outer shelf beyond the platform, (2) ammonoid paleobiogeography, (3) the northern tethyan current system and its impact on sediment patterns, (4) the influence of an oxygen minimum zone, (5) sediment bypassing mechanisms on the inner shelf, (6) condensation processes, (7) phosphogenesis, (8) relative sea level changes, (9) genesis and the development of unconformities, (10) tectonic phases and their impact on sediment configuration, (11) drowning of the shallow-water carbonate platform, and (12) "asymmetric" sedimentary cycles. The detailed reconstruction of the development of sedimentary patterns both in time and space in this particular area, and its environmental interpretation, given in this volume, may serve as a contribution to a better understanding of the Mid-Cretaceous dynamic phase in earth's history...

Description / Table of Contents: PREFACE Our planet is evolving and changing; its surface is capable of unleashing great violence as its crust is created and destroyed. Quite remarkably, it has been only recently that the fundamental elements of this evolution were fully appreciated, and only within the last decade have there been technologies capable of directly meastLring the global motions of the Earth's crust which are one of the most visible manifestations of these processes. Before the advent of space technologies, the nature of contemporary global plate motions went largely unobserved. These motions were understood from the geological records, and plate rates for million year averages were established_ Fortunately, the revolution in geophysics brought about by the general acceptance of plate tectonic theory has been paralleled by significant advances in space geodesy oceanography and geophysics. New space technologies have rapidly matured, yielding new insights and capabilities for more completely understanding the dynamical properties of the Earth, its oceans and atmosphere. Likewise, the evolving earth sciences capabilities from space are fostering new questions and goals made possible through the creative exploitation of satellite missions. A workshop entitled "The Interdisciplinary Role of Space Geodesy" was held in Erice, Italy, on the island of Sicily on July 23-29, 1988, to discuss the directions and challenges of space geodeys for the decades to come. This international gathering was made possible by the E. Majorana Centre for Scientific Culture int he framework of tis International School of Geodesy. The workshop was sponsored by the Italian Ministry of education, the Italian Ministry of Scientific and Technological Research, the Sicilian Regional Government, the Italian National Institute of Geophysics, and the National Aeronautics and Space Administration of the United States. This volume is the result of the dedicated effort undertaken by an international group of scientists and administrators who have contemplated the challenge of the future of space-based earth science for the next decade. Recognizing the need for defining new milestones both in science and technology, they have developed a detailed report of what could be achieved and what challenges remain after twenty fertile years of space exploration...

Description / Table of Contents: PAGEOPH, stratosphere, these differences provide us with new evidence, interpretation of which can materially help to advance our understanding of stratospheric dynamics in general. It is now weil established that smaller-scale motions-in particular gravity waves and turbulence-are of fundamental importance in the general circulation of the mesosphere; they seem to be similarly, if less spectacularly, significant in the troposphere, and probably also in the stratosphere. Our understanding of these motions, their effects on the mean circulation and their mutual interactions is progressing rapidly, as is weil illustrated by the papers in this issue; there are reports of observational studies, especially with new instruments such as the Japanese MV radar, reviews of the state of theory, a laboratory study and an analysis of gravity waves and their effects in the high resolution "SKYHI" general circulation model. There are good reasons to suspect that gravity waves may be of crucial significance in making the stratospheric circulation the way it is (modeling experience being one suggestive piece of evidence for this). Direct observational proof has thus far been prevented by the difficulty of making observations of such scales of motion in this region; in one study reported here, falling sphere observations are used to obtain information on the structure and intensity of waves in the upper stratosphere.

Description / Table of Contents: INTRODUCTION Over the past 18 years the author and several colleagues have developed a mathematical model designed to predict the propagation characteristics of acoustic waves in marine sediments. The model is based on the classical work of Maurice Biot who developed a comprehensive theory for the mechanics of porous, deformable media in a series of papers spanning the time period from 1941 to 1973. Since our objective was to develop a practical working model that could be used as a guide in planning and interpreting experimental work, we began with the simplest possible form of the model and added various complexities only as they were needed to explain new variations in the data that were obtained. Thus the number of material parameters that had to be measured or assumed at any stage in the development of the model was kept to a minimum. Since the first version of the model was introduced in 1970, we have published over twenty technical papers covering various stages of its development and many papers have been published by colleagues who have utilized our work in various ways. This monograph is an attempt to summarize the development and use of the model to date. Acoustic waves in ocean sediments may be considered as a limiting case in the more general category of mechanical waves that can propagate in fluid-saturated porous media. The general problem of wave motion in this kind of material has been studied extensively over the past thirty years by engineers, geophysicists and acousticians for a variety of reasons. In some cases, interest is focused on low-frequency waves of rather large amplitude, such as those that arise near the source of an earthquake or near a building housing heavy, vibrating machinery. At other times, the main interest is in waves of low frequency and amplitude that have traversed long distances through the sediment. In still another category, high-frequency waves that are able to resolve thin layering and other fine structural details are of interest in studying near-bottom sediments. Thus the full spread of frequency and amplitude has been studied for geological materials ranging from soft, unconsolidated sediments to rock. Because of the almost limitless combinations of different types of sediment, stratification and structure, accurate mathematical description of the wave field produced by a particular source can be constructed only if accurate descriptions of the acoustic properties of individual components can be specified. These properties depend on the geological history of the sediment deposit, on the frequency content of the wave field and on a number of other factors that depend on the environment in situ. A survey of the literature suggests that there are a number of parameters that play principal roles in controlling the dynamic response of saturated sediments...

Description / Table of Contents: PREFACE In a densily populated industrialized country, waste disposal must be compatible with the requirements of the environment. This is one of the indispensable requirements to guarantee an effective protection of the environment. In the past years the waste disposal industry has been given increasing attention by the general public as well as the authorities. This confirms the necessity of adapting the quality of waste disposal to the technological standard of the production. While in the past, waste disposal performance was more or less evaluated in terms of short-term costs, there is at present a reorientation in the direction of a science-based waste disposal industry. These new tendencies are taking into account ecological factors as well as the long-term consequences - i.e., for decades and centuries to come - of waste disposal methods. In this light, particular attention is given to the depositing of residues whose utilization does not appear meaningful from an ecological point of view, or would require disproportionate ressources. It is an important concern of the Federal Authorities to encourage the rapid materialization of disposal solutions which can function as ultimate deposits, and which will therefore cause neither water pollution nor gaseous emissions. In view of this goal it is necessary to establish criteria and regulations for the wastes to be deposited as well as for the characteristics of the deposits. This field confronts science with an urgent but rewarding challenge and calls for close collaboration between many different specialized disciplines...