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  • Wiley-Blackwell  (22,308)
  • Blackwell Publishing Ltd  (12,354)
  • 2015-2019
  • 1985-1989  (34,662)
  • 1989  (18,342)
  • 1987  (16,320)
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  • 2015-2019
  • 1985-1989  (34,662)
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  • 1
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    Wiley-Blackwell
    In:  Journal of Zoology, 218 (4). pp. 603-608.
    Publication Date: 2020-07-17
    Type: Article , PeerReviewed
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  • 2
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    Wiley-Blackwell
    In:  Marine Ecology, 8 . pp. 1-20.
    Publication Date: 2017-10-05
    Description: Benthic metabolism and standing stocks were investigated in the deep Red Sea between 21o and 27oN, Activity was assessed by the determination of respiration rates with a shipboard method and by calculating oxygen consumption from the activity in the electron transport system. We attempted to compare results from different latitudes within the warm Red Sea and with data from cold Atlantic environments. Our investigations were part of an environmental risk assessment to evaluate future mining of metalliferous sediments from the Atlantis II Deep.
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  • 3
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    Wiley-Blackwell
    In:  Journal of Zoology, 212 (2). pp. 303-324.
    Publication Date: 2020-07-17
    Description: The diet of the king penguin Aptenodytes patagonicus at Marion Island was examined throughout the year by analysis of stomach samples. Fish accounted for 87% by wet mass, 75% by numbers and 69% by reconstituted mass. Their proportional importance by wet mass increased from 68% during winter to almost 100% in summer and probably reflects a real increase in their local availability. Squid comprised most of the remainder with crustaceans forming less than 1% of the diet by numbers. Prey items were generally small, the most abundant being three species of myctophid fish, Krefftichthys anderssoni, Protomyctophum tenisonì and Electrona carlsbergi, and a squid Kondakovia longimana. King penguins took both juvenile and adult Krefftichthys anderssoni and P. tenisoni, but only adult E. carlshergi. The juvenile and adult modal size classes of K. anderssoni and P. tenisoni increased from March through to February and the proportion of juvenile to adult fish increased in winter. The increase in the modal size class of the K. anderssoni/P. tenisoni complex during the year probably reflects growth of the fish, rather than movement of different populations in and out of the area exploited by king penguins. All squid consumed were probably juveniles. The modal size class of Kondakovia longimana increased from March to August, but in September to October smaller squid again formed a large proportion of the squid component of the diet. Numbers of measurable squid beaks recovered from November to February were low. This is the first time that mesopelagic myctophid fish have been shown to comprise a major component of the diet of a vertebrate predator in the Southern Ocean.
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  • 4
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    Wiley-Blackwell
    In:  Nordic Journal of Botany, 7 (3). pp. 359-363.
    Publication Date: 2018-10-02
    Description: Blidingia minima var. ramifera is reported for the first time in eastern North America. It occurs in the Gulf of St. Lawrence, Nova Scotia and in Maine. In the estuary of the West and Rights Rivers (Antigonish Harbour, Nova Scotia) it is the most common intertidal alga and during its maximum growth period (June‐August) covers 75–90% of the intertidal zone for several km of shoreline at the mouth of the Rights River. In culture, spore germination and early development were typical of the taxon as described from Europe. The taxon is raised to specific status as Blidingia ramifera stat. nov. Blidingia subsalsa is confirmed from New England based on observations of spore germination in plants from Maine and Connecticut.
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  • 5
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    Oxford, UK : Blackwell Publishing Ltd
    Journal of metamorphic geology 7 (1989), S. 0 
    ISSN: 1525-1314
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: Microstructures in slate belt rocks at the Elura Mine, near Cobar, south-eastern Australia, indicate that volume loss by syntectonic dissolution is coupled with mass accretion by reprecipitation of the dissolved material in dilational sites. The mass accretion is sustained primarily by repetitive tensile microfracturing at high pore-fluid pressures. Oriented growth in the inter- and intragranular microcracks is locally host-controlled, creating lattice- and shape-preferred orientations. The grain-scale crack-seal features throughout the rock reflect rhythmic fluid pressure fluctuations; a balance is achieved between the fracture-induced permeability (and consequent flushing rates), and the rate of fluid build-up in a relatively sealed environment.Instability in the balancing factors can lead to localization and intensification of tensile failure (and hence, tension vein formation) in the grain aggregate. Growth of veins by crack-seal also reflects a steady state, but with more localized fluctuations of fluid flow on the aggregate scale. Still larger imbalances between flushing and fluid accumulation (i.e. pressure variations) induce breccia veining. The larger pressure gradients over greater distances, associated with dilation localization (from pervasive microfracturing to spaced breccia domains), allow fluid channelling with an increased potential for chemical fluid/rock disequilibrium. Therefore, large breccia vein systems tend to be sites of extensive fluid/rock interaction and replacement, as spectacularly illustrated by the syntectonic sulphide orebodies at Elura. The huge amounts of silicate, carbonate and sulphide accumulated during folding at Elura illustrate the large scale of source and sink couples possible in solute mass transfer.
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  • 6
    ISSN: 1525-1314
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: The Internal Zone of the Betic Cordilleras consists of several superimposed major thrust sheets with different P-T-t evolutions. On the basis of an integrated field, microscopic and laboratory study, the tectono-metamorphic history of the Mulhacen Complex and Almanzora Unit has been reconstructed in detail. The Mulhacen Complex has been affected by at least five phases of penetrative deformation, which have been labelled Dx-1, Dx, Dx+1, Dx+2 and Dx+3. Dx-1, and Dx are related to continent-continent collision, which is indicated by high pressure-low temperature (HP/LT) and subsequent intermediate P/T metamorphic conditions. Dx+1 is related to crustal thinning and heterogeneous extension. During this event the Almanzora Unit was juxtaposed against the Mulhacen Complex. This phase was succeeded by the establishment of low pressure-high temperature (LP/HT) conditions and at least two phases of folding and overthrusting. The Almanzora Unit shows a comparable tectono-metamorphic evolution post Dx+1. However, the P/T conditions prior to Dx+1 indicate a higher crustal position with respect to the Mulhacen Complex during the collisional event.
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  • 7
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    Oxford, UK : Blackwell Publishing Ltd
    Journal of metamorphic geology 7 (1989), S. 0 
    ISSN: 1525-1314
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: Following the Middle Devonian Acadian deformation an extensive belt of high grade metamorphism was formed in New England. In south-western Maine, at the northern end of this belt, there occurs a transition along the strike from regional low-pressure/high-temperature metamorphism to contact metamorphism in low-grade rocks. Petrological studies indicate that this transition occurs along a surface plunging to the north-east at about 3.5°, with respect to the Middle-to-Late Devonian erosion surface. In addition, detailed petrological mapping has defined a history of temporally separate, localized metamorphic events associated with plutonism and occurring at increasingly deeper levels to the south-west. Geochronological studies constrain ambient temperatures in the transition zone at the time of metamorphism to be less than 300° C in the north-east and between 350° C and 500° C in the south-west. They also establish a pattern of diachronous cooling due to differential uplift and erosion, with cooling occurring later and most rapidly to the south-west. Geophysical evidence suggests that along with this spatial variation in metamorphic style the shapes of the plutons in Maine undergo a transition from laterally extensive sheet-like bodies in the high grade terrane to more equant-shaped bodies in the low-grade terrane. Using the results of these petrological, geochronological and geophysical studies, as well as those of stratigraphical and structural studies we construct a thermal model for the transition zone. The model suggests that the Acadian metamorphism in south-western Maine is a result of deep-level contact metamorphism near laterally extensive granitic sills dipping to the north-east with respect to the present erosion surface. The plutons themselves are interpreted to be a result of lower crustal melting in response to crustal thickening in the presence of normal or slightly augmented mantle heat flux.
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  • 8
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    Oxford, UK : Blackwell Publishing Ltd
    Journal of metamorphic geology 7 (1989), S. 0 
    ISSN: 1525-1314
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
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  • 9
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    Oxford, UK : Blackwell Publishing Ltd
    Journal of metamorphic geology 5 (1987), S. 0 
    ISSN: 1525-1314
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: Abstract The effects of Tertiary Alpine metamorphism on pelitic Mesozoic cover rocks have been studied along a cross-section in the central Lepontine Alps in the Nufenen Pass area, Switzerland.Greenschist facies to amphibolite facies conditions are indicated by the formation of the index minerals chloritoid, garnet, staurolite and kyanite in pelitic rocks. Regional metamorphism reached maximum conditions during the interkinematic period between a main Alpine penetrative (D2) and a late Alpine (D3) crenulation type deformation phase or synchronous with the late Alpine deformation. Based on AFM phase relationships four different metamorphic zones can be distinguished: (1) chloritoid zone; (2) staurolite + chlorite zone; (3) staurolite + biotite zone; and, (4) kyanite zone.The isograds that separate these zones can be modelled by univariant reactions in the KFMASH system. The conditions of metamorphism calculated from geological ther-mobarometers for the maximum post-D2 por-phyroblast stage are from North to South: 500° C at 5-6 kbar and 600° C at 7-8 kbar.Detailed thermobarometry of garnet por-phyroblasts with complex textures suggests that maximum temperature was reached later than maximum pressure. Early garnet growth occurred along a prograde P-T-path, post-D2 rims grew with increasing temperature but decreasing pressure, and finally post-D3 garnet formed along a retrograde P-T-path.It may be concluded from the calculated pressure and temperature difference over a short distance (3 km) across the mapped area that the isogradic surfaces of the post-D2 metamorphism are steeply oriented. The data also suggest that isobaric and isothermal surfaces are parallel.Much of the observed metamorphic pattern can be explained as the result of a significant post-D2 differential uplift of the hot Pennine area relative to the Helvetic area along a tectonic contact zone. The closely spaced isograds (isotherms) in the North may then be interpreted as a thermal effect owing to the emplacement of the hot Pennine rocks against the Got-thard massif with its cover. Whereas, in the Pennine metasediments, post-D2 porphyroblast formation can be related to the decompression path which was steep enough for dehydration reactions to proceed. It is also remarkable that late kyanite porphyroblasts probably formed with decreasing pressure.The interpretation given here for the Nufenen Pass area may also apply to the Luk-manier Pass area where similar metamorphic patterns have been reported by Fox (1975). The formation of the ‘Northern Steep Belt’;, as denned by Milnes (1974b), and the associated late Alpine fold zones may, therefore, have significantly modified the metamorphic pattern of the Helvetic-Penninic contact zone.
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  • 10
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    Oxford, UK : Blackwell Publishing Ltd
    Journal of metamorphic geology 5 (1987), S. 0 
    ISSN: 1525-1314
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
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  • 11
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    Journal of metamorphic geology 5 (1987), S. 0 
    ISSN: 1525-1314
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: Abstract Porphyroblast textures in a Karakorum phyllite reveal that porphyroblast growth was syn-tectonic with respect to a cleavage forming deformation. During and after porphyroblast growth it partitions the deformation such that zones of intensified cleavage are developed which wrap around the porphyroblast whilst the porphyroblast and its strain shadow undergo little deformation. Porphyroblast strain shadows comprise quartz, calcite and felspar with little mica, and are probably formed by solution transfer during deformation. Unless the deformation is so strongly partitioned that no deformation of the porphyroblasts and their immediate surrounds occurs, inequidimensional porphyroblasts will rotate. Porphyroblasts undergo some dissolution after they have finished growing.
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  • 12
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    Oxford, UK : Blackwell Publishing Ltd
    Journal of metamorphic geology 5 (1987), S. 0 
    ISSN: 1525-1314
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: Abstract New isotopic (Rb–Sr, U–Pb zircon and Sm–Nd) and petrological data are presented for part of an extensive Proterozoic mobile belt (locally known as the Rayner Complex) in East Antarctica. Much of the belt is the product of Mid-Proterozoic (∼ 1800–2000 Ma) juvenile crustal formation. Melting of this crust at about 1500 Ma ago produced the felsic magmas from which the dominant orthogneisses of this terrain were subsequently derived. Deformation and transitional granulite-amphibolite facies conditions (which peaked at 750 ± 50°C and 7–8 kbar (0.7–0.8 GPa) produced open to tight folding about E–W axes and syn-tectonic granitoids about 960 Ma ago. Subsequent felsic magmatism occurred at about 770 Ma and not, as has been widely advocated, at 500–550 Ma, which appears to have been a time of widespread upper greenschist facies (400–500°C) metamorphism, localized shearing and faulting.Sm-Nd model ages of 1.65–2.18 Ga disprove a previously favoured hypothesis that the Rayner Complex mostly represents reworked Archaean rocks from the neighbouring craton (Napier Complex). Models that involve rehydration of the Napier Complex are no longer required, since the Rayner Complex was its own source of water. Two episodes of Proterozoic crustal growth are identified, the later of which occurred between about 1200 Ma and 1000 Ma, and was relatively minor. Sedimentation took place only shortly before Late Proterozoic orogenesis.The multiphase history of the Rayner Complex has resulted in complex isotopic behaviour. Three temporally discrete episodes of Pb loss from zircon have been identified, the earliest two of which are responses to the c. 960 Ma and 540 Ma tectonothermal events. Fluid leaching was operative during the later event for there is a good correlation between degree of isotopic discordance and secondary mineral growth. Pb loss during the high-grade event was probably governed by the same process or by lattice annealing. Some zircon suites also document recent Pb loss. Most lower concordia intercepts have no direct geological meaning and are explicable as mixed ages produced by incomplete Pb loss during two or more secondary events. Whereas all zircon separates from the orthogneisses produce U–Pb isotopic alignments, zircons from the only analysed paragneiss produce scattered data, in part reflecting a range of provenance. The 960 Ma event was also associated with the growth of a characteristically low U zircon (∼ 300 μg/g) in rocks of inferred high Zr content.There is ubiquitous evidence for the resetting of Rb–Sr total-rock isochrons. Even samples separated by up to 10 km fail to produce igneous crystallization ages. Minor mineralogical changes produced by the 540 Ma upper greenschist-facies metamorphism were sufficient to almost completely reset some Rb–Sr isochrons and to produce open system conditions on outcrop scale, at least in one location.
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  • 13
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    Oxford, UK : Blackwell Publishing Ltd
    Journal of metamorphic geology 5 (1987), S. 0 
    ISSN: 1525-1314
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: Abstract The preserved array of pressures in the eastern Dalradian indicates that considerable syn- to post-metamorphic differential uplift has occurred. This inferred differential uplift suggests that Buchan sillimanite zone rocks originally lay at higher structural levels than presently adjacent cooler kyanite zone rocks to the west. A number of features are believed to coincide with the western margin of the sillimanite zone. These are a maximum in temperature, sharp thermal features, a high strain zone, and a train of metabasites. These features are explained by invoking syn-metamorphic movement between the Buchan sillimanite zone and the kyanite zone to its west, involving some horizontal component of movement. It is suggested that the lateral, now eroded, equivalents of the Buchan area once provided part of the required tectonic thickening for other parts of the Dalradian. Areas surrounding the Buchan area suffered tectonic burial followed by metamorphism during uplift relative to the Buchan area.
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  • 14
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    Oxford, UK : Blackwell Publishing Ltd
    Journal of metamorphic geology 7 (1989), S. 0 
    ISSN: 1525-1314
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: All along the Himalayan chain an axis of crystalline rocks has been preserved, made of the Higher Himalaya crystalline and the crystalline nappes of the Lesser Himalaya. The salient points of the metamorphism, as deduced from data collected in central Himalaya (central Nepal and Kumaun), are:〈list xml:id="l1" style="custom"〉1The Higher Himalaya crystalline, also called the Tibetan Slab, displays a polymetamorphic history with a first stage of Barrovian type overprinted by a lower pressure and/or higher temperature type metamorphism. The metamorphism is due to quick and quasi-adiabatic uplift of the Tibetan Slab by transport along an MCT ramp, accompanied by thermal refraction effects in the contact zone between the gneisses and their sedimentary cover. The resulting metamorphic pattern is an apparent (diachronic) inverse zonation, with the sillimanite zone above the kyanite zone.2Conversely, the famous inverted zonation of the Lesser Himalaya is basically a primary pattern, acquired during a one-stage prograde metamorphism. Its origin must be related to the thrusting along the MCT, with heat supplied from the overlying hot Tibetan Slab, as shown by synmetamorphic microstructures and the close geometrical relationships between the metamorphic isograds and the thrust.3Thermal equilibrium is reached between units above and below the MCT. Far behind the thrust tip there is good agreement between the maximum temperature attained in the hanging wall and the temperature of the Tibetan Slab during the second metamorphic stage; but closer to the MCT front, the thermal accordance between both sides of the thrust is due to a retrogressive metamorphic episode in the basal part of the Tibetan Slab.
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  • 15
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    Oxford, UK : Blackwell Publishing Ltd
    Journal of metamorphic geology 7 (1989), S. 0 
    ISSN: 1525-1314
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: South of the Main Mantle Thrust in north Pakistan, rocks of the northern edge of the Indian plate were deformed and metamorphosed during the main southward thrusting phase of the Himalayan orogeny. In the Hazara region, between the Indus and Kaghan Valleys, metamorphic grade increases northwards from chlorite zone to sillimanite zone rocks in a typically Barrovian sequence. Metamorphism was largely synchronous with early phases of the deformation. The metamorphic rocks were subsequently imbricated by late north-dipping thrusts, each with higher grade rocks in the hanging wall than in the footwall, such that the metamorphic profile shows an overall tectonic inversion. The rocks of the Hazara region form one of a number of internally imbricated metamorphic blocks stacked, after the metamorphic peak, on top of each other during the late thrusting. This imbrication and stacking represents an early period of post-Himalayan uplift.
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  • 16
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    Oxford, UK : Blackwell Publishing Ltd
    Journal of metamorphic geology 7 (1989), S. 0 
    ISSN: 1525-1314
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: Crustal thickening along the northern margin of the Indian plate, following the 50 Ma collision along the Indus Suture Zone in Ladakh, caused widespread high-temperature, medium-pressure Barrovian facies series metamorphism and anatexis. In the Zanskar Himalaya metamorphic isograds are inverted and structurally telescoped along the Main Central Thrust (MCT) Zone at the base of the High Himalayan slab. Along the Zanskar valley at the top of the slab, isograds are the right way-up and are also telescoped along northeast-dipping normal faults of the Zanskar Shear Zone (ZSZ), which are related to culmination collapse behind the Miocene Himalayan thrust front. Between the MCT and the ZSZ a metamorphic-anatectic core within sillimanite grade rocks contains abundant leucogranite-granite crustal melts of probable Himalayan age. A thermal model based on a crustal-scale cross-section across the Zanskar Himalaya suggests that M1 isograds, developed during early Himalayan Barrovian metamorphism, were overprinted during high-grade MCT-related anatexis and folded around a large-scale recumbent fold developed in the hanging wall of the MCT.
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  • 17
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    Oxford, UK : Blackwell Publishing Ltd
    Journal of metamorphic geology 5 (1987), S. 0 
    ISSN: 1525-1314
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: Abstract The Cretaceous-Eocene basic to intermediate marine volcanic rocks of the Mucuchi Formation constitute the Western Cordillera in northern Ecuador. Their chemical features mostly correspond to those of tholeiitic basalts with some calc-alkaline affinities and suggest an oceanic island arc setting. The Macuchi rocks are affected by low-grade, non-deformative metamorphism, characterized by zeolite, prehnite-pumpellyite and lower greenschist facies assemblages. Depth-zonation is suggested by the downward mineral sequence: (i) laumontite+ (pistacitic epidote, pumpellyite + prehnite); (ii) pumpellyite+ prehnite + pistacitic epidote; (iii) actinolite+biotite+ pistacitic epidote + chlorite. This broad zonation and the chemistry of individual minerals point to an interaction between the volcanic rocks and sea-water under a moderate to high thermal gradient (= 75° C/km?). Alteration appears to have been dependent primarily on fluid control (volume, pressure, composition), temperature and reaction kinetics which together partly overshadow the role of load-pressure. Compositional variations of a mineral species at the scale of a contiguous flow or even at the scale of a thin section show that intensity of alteration was spatially uneven depending on rock permeability and consequently, metastable equilibrium commonly exists. However, a progressive approximation to equilibrium as a result of P–T control is shown by the mineralogy. A high fo2 of the fluid phase is evident from the mineral chemistry. The metamorphism of the Macuchi volcanics is similar to the hydrothermal-burial type produced during the development of a volcanic arc where lavas and volcanoclastics accumulated in a shallow marine environment. However, some of its characteristics point to a transition toward systems defined by a higher T/P ratio such as those found in ocean-floor metamorphism.A model is proposed in which the Macuchi volcanics are assigned to an oceanic island arc generated contemporaneously with a marginal basin which has opened as the outcome of progressive north-south attenuation of the continental crust due to mantle diapirism.
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  • 18
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    Journal of metamorphic geology 5 (1987), S. 0 
    ISSN: 1525-1314
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: Abstract Several small bodies of metabasite (maximum dimensions of 1000 m x 500 m) are included in the metamorphic rocks of the Nevado-Filabride Complex in the Betic Cordilleras (Almeria Region). The body of 400 m x 100 m, located 200 m due west of the Lubrin village, contains troctolitic gabbro with well-preserved igneous textures and mineral compositions, wholly amphibolitized gabbro, garnet-bearing metagabbro eclogite. Along with the textural and mineral changes, sensible and regular geochemical variations can be observed, where the content of MgO decreases from 24% to 11%, while that of CaO and Na2O increases from 7% to 11% and from 2% to 3%, respectively. In addition, the content of some minor elements such as Sr, Y, Nb, Zr and Sc increases while that of Ni and Cr decreases from troctolitic gabbro to the eclogite. The amphibolitized gabbro shows values scattered around those of the troctolitic gabbro. These geochemical variations are ascribed to inherited differences in the pre-metamorphic protolith, i.e. a fractionated gabbro which varies from olivine-rich to clinopyroxene-rich gabbro. Nevertheless, some metasomatism affected the Lubrin body without changing the main chemical trends, as documented by the significantly different 87Sr/86Sr ratios of each rock-type. This points to a metasomatism which involved the introduction of crustal radiogenic strontium. The petrographical and mineral chemical features are interpreted to be the result of syn-metamorphic fluid circulation possibly combined with deformation by shearing. The igneous texture and mineral chemistry have been retained wherever both fluid circulation and shearing were ineffective. On the contrary, where both events were effective, the formation of eclogite occurred. Later, the entire body underwent a retrogressive amphi-bolitic stage under greenschist facies conditions, which was probably responsible for the formation of the amphibolitized gabbro portion and for the retrogression of the eclogite.
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  • 19
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    Journal of metamorphic geology 5 (1987), S. 0 
    ISSN: 1525-1314
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: Abstract Scapolite, wollastonite, calcite, diopside, grossular-andradite garnet and sphene occur in calc-silicate rocks in the granulite terrain of the Arunta Block, central Australia. This assemblage buffers the CO2 activity at a low value, so that any coexisting fluid phase must be H2O rich and CO2 poor (Xco2= 0.2-0.3). In contrast, the H2O activity in the surrounding felsic and mafic granulites was low. Thus fluid activities during granulite facies metamorphism were locally buffered in various rock units and fluid flow appears to have been restricted or fluid may have been absent. Late retrograde rims of garnet and garnet-quartz separate phases formed in the high-grade stage. Formation of these rims would have required either an influx of water-rich fluid or a decrease in pressure. Evidence from the surrounding granulites shows that in one locality, the calc-silicate rocks had undergone late isobaric hydration; in another locality, minor uplift had occurred soon after peak P-T conditions. In both, scapolite had partly broken down to plagioclase-calite. A calc silicate rock from the granulite terrain of Enderby Land, Antarctica, contains scapolite, wollastonite, calcite, diopside, quartz and sphene; this assemblage also indicates low CO2 activities. In this rock, wollastonite has broken down to calcite-quartz, to indicate isobaric cooling without influx of hydrous fluid.
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  • 20
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    Journal of metamorphic geology 5 (1987), S. 0 
    ISSN: 1525-1314
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: Abstract Chloritoid-bearing metasedimentary rocks occur in close proximity to blueschists and eclogites in the Tertiary high-pressure metamorphic belt of northern New Caledonia. The typical assemblage of chloritoid-bearing rocks in the epidote zone is quartzchlorite-muscovite-garnet-chloritoid. In the omphacite zone, epidote is an additional member of the chloritoid-bearing assemblage. Paragonite is rare, plagioclase was not detected, and rutile and ilmenite are the Fe-Ti oxide phases. Chloritoid-glaucophane is not a common assemblage. Chloritoid-bearing rocks have relatively low (Ca+K+Na)/Al ratios and the chloritoids are relatively Mg-rich with Mg/ (Mg+Fe) up to about 0.4. A comparison of the mineral assemblages and mineral chemistry with experimental and computed phase equilibria suggest an upper temperature limit near 560° C in the omphacite zone and a minimum temperature limit near 450° C at 10 kbar. An empirical garnet-chlorite Fe-Mg exchange thermometer does not yield consistent results for the higher-grade rocks, suggesting Ts ranging from 390 to 535° C in the omphacite zone and 420–465° C in the epidote zone. The distribution coefficient KD= (Fe/Mg)ctd/(Fe/Mg)chl for chloritoid and chlorite ranges from 3.9 to 6.4, values which are lower than those (=10) from lower greenschist facies rocks, but are near those of upper greenschist facies and albite-epidote amphibolite facies.
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  • 21
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    Journal of metamorphic geology 5 (1987), S. 0 
    ISSN: 1525-1314
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: Abstract Considering the minerals cordierite (Cd), sapphirine (Sa), hypersthene (Hy), garnet (Ga), spinel (Sp), sillimanite (Si) and corundum (Co) in the system FeO-MgO-Al2O3-SiO2 (FMAS), the stable invariant points are [Co], [Ga], [Cd] and [Sa]. Constraints imposed by experimental data for the system MAS indicate that under low PH2o conditions the invariant points occur at high temperature (〉 900° C) and intermediate pressure (7-10 kbar). This temperature is higher than that commonly advocated for granulite facies metamorphism. In granulites Fe-Mg exchange geothermometers may yield temperatures of 100–150° C below peak metamorphic conditions and evidence for peak temperatures is best preserved by relict high-temperature assemblages and by Al-rich cores in orthopyroxene. Application of the FMAS grid to some well-documented granulite occurrences introduces important constraints on their P-T histories. Rocks of different bulk compositions, occurring in close proximity in the field, may record distinct segments of their P-T paths. This applies particularly to rocks with evidence for reaction in the form of coronas, symplectites and zoned minerals. Consideration of curved reaction boundaries and XMs isopleths may explain apparently contradictory results for the stability of cordierite obtained from low-temperature experiments and thermochemical calculations on the one hand and hightemperature experimental data on the other.
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    Journal of metamorphic geology 5 (1987), S. 0 
    ISSN: 1525-1314
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    Topics: Geosciences
    Notes: Abstract The Bergen-Jotun kindred rocks of this study, the Storådalen Complex (SCX), Svartdalen Gneiss (SG) and Mjølkedøla Purple Gabbro (MPG), have been shown to be a co-magmatic series with calc-alkaline affinities. The analyses of Ba, Nb, Y, and Zr presented here show no variation in these elements between the three rock units and are consistent with the calc-alkaline character of the rocks. The lithophile elements Ba, K, and Sr are enriched relative to MORB and the high field strength elements Nb, Y, and Zr are depleted relative to MORB, Zr especially so.The SCX contains rocks with low (〉30) differentiation indices which are interpreted as plagioclase + pyroxene ± olivine ± amphibole cumulates. The remainder of the SCX, together with the MPG and SG, is regarded as the congealed liquid in equilibrium with these cumulates. The distribution of trace elements between these two components of the SCX can be adequately modelled using a Rayleigh fractionation process, measured ‘liquid’compositions, and calculated bulk distribution coefficients. It is thus concluded that the trace element geochemistry of the rocks of this study is consistent with subduction-related, mantle-derived magmas that fractionate within a continental or mature island arc environment. Subsequent high-grade metamorphism and deformation of Sveconorwegian age have been essentially isochemical.
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  • 23
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    Journal of metamorphic geology 5 (1987), S. 0 
    ISSN: 1525-1314
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    Topics: Geosciences
    Notes: Abstract High-pressure granulite-facies gneisses in the NE Ox inlier in NW Ireland have undergone extensive Caledonian retrogression. In the local area of Slishwood, however, reworking was negligible and the gneisses (psammites, semipelites, pelites, metabasites and ultramafites) preserve evidence of P–T changes at high grade which mainly post-date pre-Caledonian polyphase deformation. Temperatures reached 850–900°C (based on garnet-clinopyroxene geothermometry and the presence of mesoperthite) during and after decompression from earlier eclogite-facies conditions (inferred from textural evidence of plagioclase release in sieve-textured augite). Subsequent cooling at high pressure is inferred from the unequivocal replacement of sillimanite by kyanite.A Sm–Nd mineral isochron (gt–cpx–plag–WR) of 605 ± 37 Ma is taken to date a point on the cooling path, and confirms the hitherto suspected pre-Caledonian age of the high-grade metamorphism. Geochemical and Sm–Nd isotopic data indicate that the protoliths were probably late Proterozoic arkosic sediments and tholeiites. Following metamorphism they apparently came to reside near the base of the crust where they slowly cooled. The eventual exhumation of these gneisses is attributed to Caledonian crustal imbrication, followed by rapid isostatic recovery.
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  • 24
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    Journal of metamorphic geology 5 (1987), S. 0 
    ISSN: 1525-1314
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    Topics: Geosciences
    Notes: Abstract Sphalerite geobarometry has long been known to give poor results when applied to regional metamorphic terranes. Application of the sphalerite geobarometer to three low-to medium-grade sulphide deposits—the Moke Creek and Waitahuna deposits, Otago, and the Goose Cove deposit, Newfoundland—yields pressures up to 9 kbar, which appear to be too high when compared with other geological data. Textural and mineralogical relationships suggest that the Goose Cove and, possibly, the Moke Creek deposits lacked the required equilibrium assemblage (pyrite + hexagonal pyrrhotite + sphalerite) during peak metamorphic conditions, rendering the geobarometer inapplicable. In addition, all three deposits show evidence of re-equilibration at T 〈 300°C, which has resulted in decreased FeS contents and high apparent pressures. Analyses of sphalerites from very low-grade metachert from South Georgia Island, which contains the assemblage sphalerite + pyrite + monoclinic pyrrhotite + chalcopyrite, confirm that low-temperature equilibration of this assemblage results in approximately 10–11 mol. % FeS in sphalerite. Comparison of these results with published descriptions of other deposits suggests that lack of the appropriate assemblage and retrograde re-equilibration of sphalerite probably account for most anomalously high-pressure estimates. Erratic compositions of sphalerites containing chalcopyrite inclusions may result from replacement of high-temperature intermediate solid-solution by chalcopyrite during cooling. Strain may enhance retrograde re-equilibration of sphalerite by grain-size reduction or dislocation-assisted diffusion and/or nucleation. Re-evaluation of the data from Moke Creek suggests that the sulphides experienced pervasive greenschist facies re-equilibration at pressures of about 4.5 kbar, with late stage mobilization at about 2.8 kbar, and thus sphalerite compositions are not likely to reflect blueschist facies conditions. Pressure estimates based on sphalerite geobarometry should take into account at what stage in the history of a metamorphic terrane the sphalerite composition equilibrated.
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  • 25
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    Journal of metamorphic geology 7 (1989), S. 0 
    ISSN: 1525-1314
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    Topics: Geosciences
    Notes: Experiments up to water pressures of 21 kbar have been undertaken to bracket the reactions chlorite + quartz = talc + kyanite + H2O, chlorite + quartz = talc + cordierite + H2O, and talc + kyanite + quartz = cordierite ± H2O by reversed runs in the system MgO-Al2O3-SiO2-H2O (MASH). These reaction curves intersect at an invariant point (IP1) at PH2O = 6.4 ± 0.2 kbar and a temperature of 624 ± 4°C. The curve of the chlorite + quartz breakdown to talc + kyanite + H2O at water pressures above 6.4 kbar shows a negative dP/dT, with the slope decreasing with rising pressure, whereas the slope of the breakdown curve to talc + cordierite + H2O at water pressures is clearly positive.The composition of the chlorite solid solution reacting with quartz has been estimated to be approximately Mg4.85Al1.15[Al1.15Si2.85O10](OH)8 over the entire pressure range investigated. The composition of the talc solid solution forming by the breakdown of chlorite + quartz appears to be Mg2.94Al0.06[Al0.06Si3.94O10](OH)2 at PH2O = 2kbar. With increasing pressure, the Al content of talc decreases, reaching a value of about 0.06 atoms per formula unit at P,H2O = 21 kbar.As a consequence of the new experimental data, the existing phase topologies of the MASH-system and K2O-MASH-system have been revised. For example, the invariant point IP1 and the univariant reaction curve kyanite + talc + H2O = chlorite + cordierite are stable. For this reason, the development of medium- to high-temperature metamorphic rocks compositionally approximating the MASH-system must be reconsidered. The whiteschists from Sar e Sang, Afghanistan, are treated as an example. The application of the present experimental data to metamorphic rocks of more normal composition requires the examination of the influence of further components. This leads to the conclusion that the introduction of Fe2+ into magnesian chlorite extends its stability field in the presence of quartz by 10°-15°C in comparison with pure Mg-chlorite.
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    Journal of metamorphic geology 7 (1989), S. 0 
    ISSN: 1525-1314
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    Topics: Geosciences
    Notes: A reaction producing jadeitic pyroxene in metagreywackes of the northern Diablo Range has been identified on the basis of mineral distribution, isograd patterns and composition of coexisting minerals. The appearance of jadeitic pyroxene (∼Jd80) is closely followed by the disappearance of pumpellyite, which indicates that pumpellyite plays a major role in the pyroxene-producing reaction. A new projection from hematite, lawsonite, chlorite, quartz and H2O on to the NaAlO2-FeO-MgO ternary confirms the role of pumpellyite in pyroxene production and suggests a reaction of the form: 1.00 pumpellyite + 0.31 chlorite + 8.71 albite + 0.70 hematite + 2.00 H2O = 8.54 jadeite + 0.57 glaucophane + 3.09 lawsonite + 5.26 quartz. Metagreywackes of the northern Diablo Range were metamorphosed under conditions of PH2O=Ptotal at 200-300 °C and 7.5-10.0 kbar. Despite the low temperatures attained during metamorphism, the assumption of equilibrium yields results consistent with field observations and phase relations.
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    Journal of metamorphic geology 7 (1989), S. 0 
    ISSN: 1525-1314
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    Topics: Geosciences
    Notes: Metabasites and metagreywackes from the Pelona and Rand Schists of southern California were analysed using three different electron microprobes. For all three instruments, the estimated Fe3+ contents of calcic amphibole, chlorite and epidote are positively correlated. For some samples, there is an additional correlation between high estimated Fe3+ and the presence of magnetite. These results imply that microprobe analyses can be used to discern relative differences in Fe3+. However, microprobe data and calculations on the sensitivity of the correction procedures to systematic analytical errors indicate that estimated values of Fe3+ are not significant in an absolute sense. Thus, estimates of Fe3+ are meaningful when comparing samples analysed with a single microprobe, but must be used with caution when comparing analyses obtained on more than one probe.
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  • 28
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    Journal of metamorphic geology 7 (1989), S. 0 
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    Topics: Geosciences
    Notes: All the Mesozoic and Cenozoic volcanic rocks of the Central Andes (from southern Ecuador to central Chile), except Recent ones, have been affected by episodes of regional metamorphism, without change in texture and structure. The metamorphism, which ranges from low zeolite to greenschist facies, can be classified as burial metamorphism because there is an overall increase in metamorphic grade with stratigraphic depth in the individual volcanic sequences separated by regional unconformities. Some sequences display metamorphic patterns transitional to ocean-floor and to geothermal field types, reflecting variations along and across the Andes in tectonic setting and thermal gradients.Volcanism was closely followed by metamorphism during each cycle characterizing the geological history of the Central Andes. The episodic nature of the metamorphism has led to breaks in metamorphic grade at regional unconformities and repetition of facies series, where strata of higher grade may even overlie those of lower grade. The existence of permeability-controlled distribution patterns of secondary minerals within individual flows shows that gradients of chemical activity, rate of reaction and Pfluid were acting, in addition to temperature and P,tot overall gradients, during the regional metamorphism. The alteration is accompanied by chemical changes and disturbances of the K-Ar and Rb-Sr isotope systems. Similarities between Mesozoic facies series in the western and eastern flanks of the Andes are consistent with a mechanism of ensialic spreading-subsidence.
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    Journal of metamorphic geology 7 (1989), S. 0 
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    Topics: Geosciences
    Notes: An analytical study to evaluate quantitatively weak zoning of a garnet from a high-grade kinzigite has been performed with an electron microprobe. The technique consists of the reconstruction of a profile step-by-step by successive analyses performed during relatively long counting times (30 s), along a radial profile of 2,500 μm length. The successive analytical data along this profile are statistically treated by Fisher's test and compared with the χ2 values (Pearson's law). These statistical tests were applied to assess microprobe stability and analysis homogeneity, and as a consequence to assure high credibility of the radial variations of the garnet. From core to rim, and for each element, zoning appears as the radial juxtaposition of stationary Poissonian samples. These samples being associated, the garnet appears to be constituted of successive concentric domains with stationary compositions. Different substitutions between Mg, Fe, Mn and Ca are evidenced. Such an analytical approach to chemical zoning can be useful for understanding growth mechanisms, and the possible diffusion reactions with the environment at each growth step. In addition, such a procedure can be used to evaluate accurately the fluid content of cordierite, and to appreciate the nature of the fluids concerned. As an example, the fluid content of a cordierite from a similar high-grade kinzigite has been evaluated.
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    Journal of metamorphic geology 7 (1989), S. 0 
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    Journal of metamorphic geology 7 (1989), S. 0 
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    Topics: Geosciences
    Notes: P-T conditions inferred from fluid inclusions in metamorphic rocks often disagree with the values predicted from mineral equilibria calculations. These observations suggest that inclusions formed during early stages of regional metamorphism continue to re-equilibrate during burial and subsequent uplift in response to differential pressure. P-T conditions accompanying burial and uplift were experimentally simulated by initially forming pure H2O inclusions in quartz at elevated temperatures and pressures, and then re-equilibrating the inclusions in the presence of a 20 wt% NaCl solution such that final confining pressures ranged from 5 kbar above to 4 kbar below the initial internal pressure of the inclusions at the temperature of re-equilibration.In all samples re-equilibrated at confining pressures below the internal pressure, some inclusions were formed that had compositions of 20 wt% NaCl and densities in accord with the final P-T conditions. Additionally, some inclusions were observed to contain fluids of intermediate salinities (between 0 and 20 wt% NaCl). Densities of these inclusions were also consistent with formation at the re-equilibration P-T conditions. The remainder of the fluid inclusions observed in these samples contained pure H2O and their homogenization temperatures corresponded to densities intermediate between the initial and final P-T conditions. In short-term experiments (7 days) where the initial internal overpressure exceeded 1 kbar, no inclusions were found that contained the original density and none were found to have totally re-equilibrated. Instead, most H2O inclusions re-equilibrated until their internal pressures were between ∼750 and 1500 bars above the confining pressure, regardless of the initial pressure differential. In a long-term experiment (52 days), inclusions re-equilibrated at a lower confining pressure than the initial internal pressure displayed homogenization temperatures corresponding to a range in final internal pressures between 0 kbar (i.e. total re-equilibration) and 1.2 kbar above the confining pressure.In experiments where the confining pressure during re-equilibration exceeded the initial internal pressure, densities of pure H2O inclusions increased to values intermediate between the initial and final P-T conditions. Additionally, these inclusions were generally surrounded by a three-dimensional halo of smaller inclusions, also of intermediate density, resulting in a texture similar to that previously ascribed to decrepitation from internal overpressure. In extreme cases where confining pressures were 4–5 kbar above the initial pressure, the parent inclusion almost completely closed leaving only the three-dimensional array of small (〈inlineGraphic alt="leqslant R: less-than-or-eq, slant" extraInfo="nonStandardEntity" href="urn:x-wiley:02634929:JMG243:les" location="les.gif"/〉5 μm) inclusions, the outline of which may be several times the volume of the original inclusion. Groups of such inclusions closely resemble textures commonly observed in medium- to high-grade metamorphic rocks.Inclusions containing 10 and 42 wt% NaCl solutions trapped at 600 °c and 3 kbar were re-equilibrated at 600 °c and 1 kbar for 5 days in dry argon to evaluate the importance of H2O diffusion as a mechanism of lowering the inclusion bulk density. Salinities of re-equilibrated inclusions obtained from freezing point depressions and halite dissolution temperatures indicate that original compositions were preserved. Density changes similar to those previously described were noted in these experiments, in inclusions showing no visible microfractures. Therefore, density variations observed in inclusions in this study, re-equilibrated under rapid deformation conditions, are considered to result from a change in the inclusion volume, without significant loss of contents by diffusion or leakage.
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    Journal of metamorphic geology 7 (1989), S. 0 
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    Topics: Geosciences
    Notes: In the main Himalayan range in the Ladakh-Zanskar area, domal structures have been observed at structurally deeper levels in the tectonic unit of the Higher Himalayan Crystalline. Their formation occurred during a second, temperature-dominated phase (M2) of high-grade regional metamorphism, characterized by the semipelitic paragenesis of sillimanite-K-feldspar and incipient anatexis. The doming event reveals a local system of synmetamorphic uplift superimposed on a regional system of northeast-southwest trending compression. In the main Himalayan range the development of the dominant S2 foliation is related to deformation during the doming phase, which started early in the M2 event. The deformation propagated continuously north-east and south-west with time. In the north-east, on the northern slopes of the main Himalayan range, this deformation is expressed by extensional shear movements of the upper tectonic levels finally leading to the late- to postmetamorphic normal fault system of the Zanskar shear zone. Towards the south-west, deformation is expressed by compressional movements, e.g. at the Main Central Thrust (MCT) in the Kishtwar window area. The observed compression and extension is inferred to relate to an increased uplift of the domal bulges of the tectonic Kishtwar window and of the whole main Himalayan range.
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    Journal of metamorphic geology 7 (1989), S. 0 
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    Topics: Geosciences
    Notes: The pressure-temperature and temperature-time paths derived for rocks in the Kohistan arc and adjacent Nanga Parbat-Haramosh massif record the dynamics of the collision between the island arc and the Indian plate. Studies of P-T-t paths show that the Kohistan arc was thrust over the Nanga Parbat-Haramosh massif at least 25 Ma ago, but not more than 30–35 Ma ago. Rocks in the Kohistan arc followed decreasing pressure paths, with the early metamorphism beginning at high pressures (9.5 kbar) and later metamorphism occurring at 8.0 kbar. In contrast, rocks in the Nanga Parbat-Haramosh massif (Indian plate) experienced increasing pressure and temperature paths. Prior to thrusting, the massif was at low pressures (4.0 kbar) and low temperatures (450°c). Later, the pressure and temperature increased to 8 kbar and 580°c. The authors interpret the convergence (to approximately the same pressure and temperature) of the P-T paths in the two terranes as being the result of thrusting and thermal equilibration between the thrust sheets. 40Ar/39Ar cooling ages of hornblendes and other geochronological data suggest that the time of peak metamorphism and hence the completion of thickening was approximately 30–35 Ma ago.Temperature-time paths show that after thrusting, during the period 25–10 Ma, the Kohistan arc and Nanga Parbat-Haramosh massif were uplifted at similar rates (0.5 km Ma). However, in the past 10 Ma the Nanga Parbat-Haramosh massif has been uplifted more rapidly than the adjacent Kohistan arc. Rapid uplift has been accommodated by late faults along the edge of the massif.
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    Journal of metamorphic geology 7 (1989), S. 0 
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    Topics: Geosciences
    Notes: The Kanskaya formation in the Yenisey range, Eastern Siberia is a newly studied example of retrogression of granulite facies rocks. The formation consists of two stratigraphical units: the lower Kuzeevskaya group and the upper Atamanovskaya group. Rocks from both of these units show rare reaction textures such as replacement of cordierite by garnet, sillimanite and quartz, silimanite coronas around spinel and corundum, and garnet rims around plagioclase in metabasites, while plagioclase rims around garnet can be seen in associated metapelites. The paragenesis quartz + orthopyroxene + sillimanite is a feature of the Kuzeevskaya group. In many samples, chemical zoning of garnet and cordierite shows an increase in Mg from core to rim as well as the reverse.Biotite-garnet-cordierite-sillimanite-quartz as well as spinel±biotite-garnet°Cordierite±sillimanite-quartz assemblages were studied using geothermometers and geobarometers based on both exchange and net-transfer reactions (Perchuk & Lavrent'eva, 1983; Aranovich & Podlesskii, 1983; Gerya & Perchuk, 1989). Detailed investigation of 10 samples including 1000 microprobe analyses revealed decompression (first stage) followed by the near isobaric cooling of the granulites. From geological studies, the 7 km total thickness of the sequence closely corresponds to the pressure difference (∼ 2.2kbar) measured by geobarometers in the samples taken from different levels in the sequence. Individual samples yield P-T paths ranging from 100°C/kbar to 140°C/kbar depending on their locations with respect to the large Tarakskiy granite pluton. In places the 100°C/kbar path changed to the 140°C/kbar due to the influence of the intrusion. In a P-T diagram these trajectories are subparallel lines, whose P-T maxima define the Archaean geotherm between 3.1 and 2.7 Ga, determined isotopically. A petrological model for P-T evolution of the Kanskaya formation is proposed.
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    Journal of metamorphic geology 7 (1989), S. 0 
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    Topics: Geosciences
    Notes: A method is proposed for adjusting the mass balance to characterize quantitatively the behaviour of minerals in anatexis. The method is based on an unconstrained simple mixing model that can be expressed as: 〈displayedItem type="mathematics" xml:id="mu1" numbered="no"〉〈mediaResource alt="image" href="urn:x-wiley:02634929:JMG619:JMG_619_mu1"/〉 where B, A0, and A1-n, are compositional vectors of segregate, source rock and source minerals, respectively. The most important concepts are: (1) degree of partial fusion: FMM= 1/a0; (2) mineral fractionation index: 〈displayedItem type="mathematics" xml:id="mu2" numbered="no"〉〈mediaResource alt="image" href="urn:x-wiley:02634929:JMG619:JMG_619_mu2"/〉 and (3) plagioclase differentiation index: 〈displayedItem type="mathematics" xml:id="mu3" numbered="no"〉〈mediaResource alt="image" href="urn:x-wiley:02634929:JMG619:JMG_619_mu3"/〉 .For a given mineral, the MFI values have the following meaning: (a) MFI 〈0: residual phase originated, at least partly, as a product of incongruent melting; (b) 0 〉 MFI 〈1: preferential retention in the residue; (c) MFI= 1: identical modal fraction in source and melt; (d) a0 〉 MFI 〉 1: preferential incorporation into the segregate, and (e) MFI 〉 a0: external contribution to the anatectic system defined by a0A0. To test the method and illustrate its use, it was applied to two real problems of partial melting in the Peña Negra Anatectic Complex (Central Spain). The first is a very simple case of segregation of a diktyonitic neosome from an orthogneiss through partial melting located in vertical shear zones. This process is characterized by: (1) FMM= 0.51; (2) active incorporation of K-feldspar, plagioclase and biotite into the segregate; (3) disequilibrium melting of plagioclase; (4) residual behaviour of quartz and ilmenite. The second case concerns the formation of a cordierite-bearing granite from granodioritoid diatexites through an anatectic process, whose most salient characteristics are: (1) FMM= 0.45; (2) incongruent melting of biotite; (3) residual behaviour of plagioclase, which melted with a PDI of 1.22; (4) preferential incorporation of quartz into the segregate; (5) total extraction of K-feldspar from the residue.
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    Topics: Geosciences
    Notes: Graphitic metapelites from the Howard Ridge area, British Columbia, have been studied to estimate the pressure, temperature and fluid composition attending amphibolite facies metamorphism. Results from thermobarometric calculations indicate that P-T conditions of 610–625°C and 6.7kbar were reached during metamorphism. The equilibrium paragonite-quartz-albite-kyanite-H2O gives significantly different estimates of XH2O in the metamorphic fluid using different paragonite solution models. Estimates of XH2O range from a maximum of 0.93 (Eugster et al., 1972) to a minimum of 0.29 (Chatterjee & Flux, 1986). H2O estimates obtained using the Eugster et al. (1972) and Chatterjee & Froese (1975) solution models give similar results (i.e. 0.8 ± 0.1 versus 0.7 ± 0.1, respectively). Non-ideal mixing in the C-O-H system provides an XH2O estimate of 0.74 at H2O maximum conditions, 0.5 log units below the QFM buffer. The Chatterjee & Flux (1986) paragonite solution model provides unrealistically low estimates of XH2O relative to other paragonite solution models, C-O-H equilibria, and published fluid inclusion and mineral equilibria data. Consistent estimates of fluid composition between C-O-H and mineral equilibria suggest that a H2O-rich fluid attended metamorphism of graphitic metapelites at Howard Ridge.
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    Topics: Geosciences
    Notes: Rocks from the metamorphic basement of the Azuero and Sona peninsulas, Panama, consist of schistose amphibolites and minor amounts of metasediment. In the Sona peninsula, strongly zoned amphiboles indicate that the amphibolites followed a progressive anticlockwsie P-T path prograde from low T/low P to medium T/high P, and are retrograded into the greenschist facies. In contrast, the amphibolites of the Azuero peninsula are affected by a low to medium T/low P metamorphism.The metamorphic events of the Sona amphibolites occurred prior to the intra-Senonian tectonic phase which affects the Mesozoic formations along the Pacific coast of Costa Rica and Panama. The regional significance of such a basement in Isthmian Central America is discussed.
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    Topics: Geosciences
    Notes: Microstructural and petrological data from the Jumping Brook metamorphic suite, western Cape Breton Highlands, suggest that a single episode of syntectonic prograde metamorphism, followed by uplift, cooling and associated retrogression, affected these rocks during mid-Palaeozoic times. Microstructures indicative of progressive crenulation foliation development can be traced from low-grade (chlorite zone) through high-grade (kyanite zone) rocks, allowing a clear sequence of porphyroblast growth to be established. Metamorphic reactions and P-T calculations suggest metamorphic conditions of 700-750°C at 8-10 kbar were achieved in kyanite zone rocks. Although a complete P-T-t path was not defined, combined petrological and geochronological data can be used to constrain computed P-T-t models. These models suggest that a component of post-metamorphic tectonic exhumation is required to explain the observed times of cooling and uplift. The microstructural and petrological data to not support the interpretation that the high-grade rocks represent pre-existing crystalline basement. Indeed, the metamorphic history, geochronology and computed tectonic models all point to a single, short-lived episode of Silurian-Devonian volcanism, intrusion, convergence, regional metamorphism and uplift, probably resulting from collision tectonics at an irregular continental margin.
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  • 39
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    Journal of metamorphic geology 7 (1989), S. 0 
    ISSN: 1525-1314
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    Topics: Geosciences
    Notes: Dissolution and solution transfer during deformation/metamorphism are controlled by the partitioning of deformation into progressive shearing and shortening components. Progressive shearing is readily accommodated by slip on the planar crystal structure of phyllosilicates and graphite without accumulating dislocation density gradients across grain boundaries.Progressive shortening is accommodated by the cores of most other minerals (including sulphides). These minerals develop strain, and hence dislocation density gradients, on their rims due to progressive shearing along grain boundaries. These gradients are particularly large when the mineral abuts phyllosilicate or graphite. The resulting chemical potential gradients between the core and rim drive dissolution, causing removal of the highly strained grain margins.Removal of dissolved material by solution transfer is aided by the geometry of shearing of phyllosilicates and graphite around other grains in an active anastomosing foliation. Interlayers and interfaces on boundaries lying at a low angle to the direction of shearing, and oriented relative to the sense of shear such that they can open, gape by small amounts. Water present in these interlayer spaces becomes destructured, considerably enhancing diffusion rates along the foliation.Penetrative volume loss, especially in deforming/metamorphosing pelitic rocks, is large at all metamorphic grades, increasing and becoming more penetrative with depth to at least the transition into granulite and eclogite facies. Transference of material by fluid flow from deep to high levels in the earth's crust is precluded because thousands to tens of thousands of rock volumes of fluid are required, necessitating continual recirculation of fluid from shallow to deep crustal levels in one large or several small sets of cells, unless some extremely large-scale form of fluid channelling is possible. Reassessment of diffusion mechanisms, and hence rates, during deformation and pervasive foliation generation in large volumes of rock where fluid channeling cannot provide enough fluid, indicates that diffusion can proceed with sufficient rapidity that massive recirculation of fluid is no longer required. The amount of fluid can be reduced sufficiently to allow large volume losses by a one-way flow of fluid to the earth's surface, in deforming/metamorphosing environments where the fluid pressure equals or exceeds the hydrostatic pressure.Deformation partitioning-controlled dissolution progressively changes the bulk chemistry of a rock containing phyllosilicates or graphite during deformation/metamorphism because matrix minerals, other than phyllosilicates and graphite, are preferentially removed. The large size of porphyroblasts, if present, tends to preserve them from dissolution. Hence, the bulk chemistry operative during subsequent porphyroblast growth can have changed considerably from that operative when the first porphyroblasts grew, in rocks in which bedding is still well preserved.
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    Topics: Geosciences
    Notes: Low-pressure granulite facies metasedimentary gneisses exposed in MacRobertson Land, east Antarctica, include hercynitic spinel-bearing metapelitic gneisses. Peak metamorphic mineral assemblages include spinel + rutile + ilmenite + sillimanite + garnet, spinel + ilmenite + sillimanite + garnet + cordierite, ortho-pyroxene + magnetite + ilmenite + garnet, spinel + cordierite + biotite + ilmenite and orthopyroxene + cordierite + biotite, each with quartz, K-feldspar and melt. The presence of garnet + biotite- and cordierite + orthopyroxene-bearing assemblages implies crossing tie-lines in AFM projection for the K2O-FeO-MgO-Al2O3-SiO2-H2O (KFMASH) system. This apparent contradiction, and the presence of spinel, rutile and ilmenite in the assemblages, is acounted for by using the KFMASH-TiO2-O2 system, i.e. AFM + TiO2+ Fe2O3. We derive a petrogenetic grid for this system, applicable to low-pressure granulite facies metamorphic conditions. Retrograde assemblages are interpreted from corona textures on hercynitic spinel and Fe-Ti oxides. The relative positions of the peak and retrograde metamorphic assemblages on the petrogenetic grid suggest that corona development occurred during essentially isobaric cooling.
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  • 41
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    Journal of metamorphic geology 7 (1989), S. 0 
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    Topics: Geosciences
    Notes: Sequential reaction textures in Archaean garnet-corundum-sapphirine granulites from the Central Zone of the Limpopo Belt document a progression from early, coarse-grained, high-pressure (P 〉 9.5 kbar) granulite-facies assemblages (M1) to late, low-pressure (P 〈6 kbar) granulite-facies sub-assemblages (M2).The stable M1 assemblage was garnet (57% pyrope; Mg/(Mg + Fe) = 62) + sapphirine + corundum + gedrite + phlogopite + rutile. Late-M1 boron-free kornerupine grew at the expense of garnet and corundum, and coexisted with garnet, sapphirine and gedrite. Partial or complete breakdown of coarse garnet and kornerupine during M2 resulted in the development of pseudomorphs and coronas consisting of fine-grained symplectic intergrowths of cordierite, gedrite and sapphirine (later, spinel).The majority of reaction textures can be explained in terms of a stable reaction sequence, and a model time-sequence of mineral facies can be constructed. When compared with a qualitative petrogenetic grid of (Fe, Mg)-discontinuous reactions in the FMASH multisystem sapphirine-garnet-corundum-spinel-cordierite-gedrite-kornerupine, the facies-sequence indicates decompression at essentially constant T assuming constant a(H2O).Exhumation of M1 corundum inclusions during M2 breakdown of kornerupine resulted in production of metastable spinel by a disequilibrium reaction with gedrite. A second disequilibrium reaction of the spinel with cordierite produced sapphirine. The operation of such reaction while pressure was decreasing (the opposite dP from that implied by the texture if assumed to be the product of an equilibrium reaction) has serious implications for the use of reaction textures in the construction of P-T vectors.Garnet-biotite thermometry on garnet interiors and phlogopite inclusions in corundum yields temperatures of ca. 850°C for the M1 stage. A minimum late-M1 pressure of ca. 7 kbar is indicated by the former association of kornerupine and corundum. Relict M1 kyanites reported by other workers indicate a minumum early-M1 pressure of 9.5 kbar, implying metamorphism at depths of at least 33 km (probably 〈inlineGraphic alt="geqslant R: gt-or-equal, slanted" extraInfo="nonStandardEntity" href="urn:x-wiley:02634929:JMG383:ges" location="ges.gif"/〉 38km). The high-pressure granulite-facies metamorphism was followed by an almost isothermal pressure decrease of 〉 5 kbar, indicative of rapid uplift. The P-T path is interpreted as the product of a single metamorphic cycle which probably took place in response to tectonic thickening of the crust. Such a process contrasts with the extensional origin recently proposed for isobarically cooled granulite-facies terranes.
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  • 42
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    Journal of metamorphic geology 7 (1989), S. 0 
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    Topics: Geosciences
    Notes: The early metamorphic history of high-grade exotic blocks in the Franciscan Complex may be more complicated than previously supposed. The different assemblages of high-grade glaucophane schist, eclogite, amphibolite and hornblende schist are commonly considered to have formed at the same time from essentially unmetamorphosed oceanic crust. However, new textural and mineralogical data presented here suggest that high-grade glaucophane schist and eclogite have replaced an earlier epidote-amphibolite facies assemblage that is identical to the primary assemblages in many of the hornblende-rich blocks. At least some of the hornblende-rich blocks may therefore be well-preserved remnants of the earlier metamorphism. Comparison of the mineral assemblages and element partitioning in the mixed-assemblage blocks suggests that the glaucophane schist and eclogite metamorphism took place at slightly lower temperatures but at the same or higher pressures than the earlier, hornblende-forming stage.
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  • 43
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    Journal of metamorphic geology 7 (1989), S. 0 
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  • 44
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    Journal of metamorphic geology 7 (1989), S. 0 
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    Topics: Geosciences
    Notes: The High Himalayan Crystallines (HHC) of SE Zanskar consist of biotite paragneisses, of orthogneisses that derive from early-Palaeozoic granitoids, of minor metabasics and of post-metamorphic leucogranites of Miocene age.Two main metamorphic events have been documented in the HHC. The first event occurred at P= 12.0 ± 0.5 kbar and T= 750 ± 50° C in rare metabasics intruded by early-Palaeozoic granitoids. In the biotite paragneisses, thermobarometric estimates of the first event point to comparable T at P 4–5 kbar lower. The first event is followed by a pervasive syn-tectonic crystallization characterized by lower P and T. On the basis of the cooling ages of the metamorphic minerals and on the geological evidence, the second event is referred to the Tertiary Himalayan crystallization. Further petrological and geochronological studies are necessary to prove whether a few mineral relics ascribed to the first event define a polyphase Himalayan evolution or if they record the incomplete obliteration of an older history during the Himalayan event.The HHC of SE Zanskar show a decrease in metamorphic grade from the middle structural levels upward, close to the Kade unit, and downward, close to the Lesser Himalaya (from sillimanite-K-feldspar-biotite-bearing assemblages to kyanite-staurolite-muscovite-bearing assemblages). This metamorphic zonation is probably a consequence of the polyphase history of intracontinental thrusts and of the tectonic emplacement of hot crustal slabs within shallower and colder thrust sheets at relatively late stages of the continental collision between India and Eurasia.
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  • 45
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    Journal of metamorphic geology 7 (1989), S. 0 
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    Topics: Geosciences
    Notes: Blueschists occur along the Indus Suture Zone in Ladakh as tectonic thrust slices, as isolated blocks within mélange units and as pebbles within continental detrital series. In the Shergol-Baltikar section high-pressure rocks within the Mélange unit lie between the Dras-Naktul-Nindam nappes in the north and the Lamayuru units in the south. The blueschists are imbricated with mélange formation of probably upper Cretaceous age. They are overlain discordantly by the Shergol conglomerate of post Eocene (Oligo-Miocene ?) age. Blueschist lithologies are dominated by volcanoclastic rock sequences of basic material with subordinate interbedding of cherts and minor carbonates. Mineral assemblages in metabasic rocks are characterized by lawsonite-glaucophane/crossite-Na-pyroxene-chlorite-phengite-titanite ± albite ± stilpnomelane. In the quartz bearing assemblages garnet is present but omphacite absent. P-T estimates indicate temperatures of 350 to 420°c and pressures around 9–11 kbar. Geochemical investigations show the primary alkaline character of the blueschist, which suggests an oceanic island or a transitional MORB type primary geotectonic setting. K/Ar isotopic investigations yield middle Cretaceous ages for both whole rocks and minerals. Subduction related HP-metamorphism affecting the Mesozoic Tethyan oceanic crust developed contemporaneously with magmatism in the Dras volcanic are and the Ladakh batholith. Subsequent collision of India with Asia obducted relics of subduction zone material which later became involved in nappe emplacement during the Himalayan mountain building.
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  • 46
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    Journal of metamorphic geology 7 (1989), S. 0 
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  • 47
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    Journal of metamorphic geology 5 (1987), S. 0 
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    Journal of metamorphic geology 5 (1987), S. 0 
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    Topics: Geosciences
    Notes: Abstract The sedimentary and igneous rocks comprising the lower Proterozoic Olary Block, South Australia, were deformed and metamorphosed during the mid-Proterozoic ‘Olarian’Orogeny. The area is divided into three zones on the basis of assemblages in metapelitic rocks, higher grade conditions occurring in the south-east. Mineral assemblages developed during peak metamorphism, which accompanied recumbent folding, include andalusite in Zones I and II and sillimanite in Zone III. Upright folding and overprinting of mineral assemblages occurred during further compression, the new mineral assemblages including kyanite in Zone II and kyanite and sillimanite in Zone III. The timing relationships of the aluminosilicate polymorphs, together with the peak metamorphic and overprinting parageneses, imply an anticlockwise P–T path for the ‘Olarian’Orogeny, pressure increasing with cooling from the metamorphic peak.
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  • 49
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    Journal of metamorphic geology 5 (1987), S. 0 
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    Journal of metamorphic geology 5 (1987), S. 0 
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    Topics: Geosciences
    Notes: Abstract Sodic amphiboles are common in Franciscan type II and type III metabasites from Cazadero, California. They occur as (1) vein-fillings, (2) overgrowths on relict augites, (3) discrete tiny crystals in the groundmass, and (4) composite crystals with metamorphic Ca–Na pyroxenes in low-grade rocks. They become coarse-grained and show strong preferred orientation in schistose high-grade rocks. In the lowest grade, only riebeckite to crossite appears; with increasing grade, sodic amphibole becomes, first, enriched in glaucophane component, later coexists with actinolite, and finally, at even higher grade, becomes winchite. Actinolite first appears in foliated blueschists of the upper pumpellyite zone. It occurs (1) interlayered on a millimetre scale with glaucophane prisms and (2) as segments of composite amphibole crystals. Actinolite is considered to be in equilibrium with other high-pressure phases on the basis of its restricted occurrence in higher grade rocks, textural and compositional characteristics, and Fe/Mg distribution coefficient between actinolite and chlorite. Detailed analyses delineate a compositional gap for coexisting sodic and calcic amphiboles. At the highest grade, winchite appears at the expense of the actinolite–glaucophane pair.Compositional characteristics of Franciscan amphiboles from Ward Creek are compared with those of other high P/T facies series. The amphibole trend in terms of major components is very sensitive to the metamorphic field gradient. Na-amphibole appears at lower grade than actinolite along the higher P/T facies series (e.g. Franciscan and New Caledonia), whereas reverse relations occur in the lower P/T facies series (e.g. Sanbagawa and New Zealand). Available data also indicate that at low-temperature conditions, such as those of the blueschist and pumpellyite–actinolite facies, large compositional gaps exist between Ca- and Na-amphiboles, and between actinolite and hornblende, whereas at higher temperatures such as in the epidote–amphibolite, greenschist and eclogite facies, the gaps become very restricted.Common occurrence of both sodic and calcic amphiboles and Ca–Na pyroxene together with albite + quartz in the Ward Creek metabasites and their compositional trends are characteristic of the jadeite–glaucophane type facies series. In New Caledonia blueschists, Ca–Na pyroxenes are also common; Na-amphiboles do not appear alone at low grade in metabasites, instead, Na-amphiboles coexist with Ca-amphiboles throughout the progressive sequence. However, for metabasites of the intermediate pressure facies series, such as those of the Sanbagawa belt, Japan and South Island, New Zealand, Ca–Na pyroxene and glaucophane are not common; sodic amphiboles are restricted to crossite and riebeckite in composition and clinopyroxenes to acmite and sodic augite, and occur only in Fe2O3-rich metabasites.The glaucophane component of Na-amphibole systematically decreases from Ward Creek, New Caledonia, through Sanbagawa to New Zealand. This relation is consistent with estimated pressure decrease employing the geobarometer of Maruyama et al. (1986). Similarly, the decrease in tschermakite content and increase in NaM4 of Ca-amphiboles from New Zealand, through Sanbagawa to New Caledonia is consistent with the geobarometry of Brown (1977b). Therefore, the difference in compositional trends of amphiboles can be used as a guide for P–T detail within the metamorphic facies series.
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  • 51
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    Journal of metamorphic geology 7 (1989), S. 0 
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  • 52
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    Notes: Mineral assemblages in pelitic, mafic, calcareous and ultramafic rocks within a metamorphosed tectonic mélange indicate that the Marble Mountain terrane and adjacent Western Hayfork subterrane (northern California) underwent regional low- to medium-pressure amphibolite facies metamorphism. Metamorphic conditions estimated by comparison of observed assemblages with experimentally-determined reaction boundaries and by geothermometry constrain metamorphic temperatures between about 500° and 570°C. The occurrence of andalusite in regionally metamorphosed pelites indicates pressures below about 370 MPa. Metabasite amphibole compositions also suggest low to intermediate metamorphic pressures.Metaserpentinites containing the upper amphibolite facies assemblage (olivine + enstatite + anthophyllite) are found locally within the study area and have been reported previously by other workers elsewhere in the Marble Mountain terrane. These assemblages may reflect higher temperatures of recrystallization than assemblages in surrounding rocks and may represent vestiges of an earlier high-temperature metamorphic event undergone by the ultramafic rocks prior to incorporation in the mélange.Although the age of the low- to intermediate-pressure metamorphism is poorly constrained, cross-cutting plutons indicate that metamorphism must be older than about 162 Ma. Therefore this regional metamorphic event, which probably marks the accretion of these terranes to the North American continental margin, is older than the currently accepted 151–147 Ma age of the Nevadan event in the Klamath Mountains. The inferred low to intermediate pressures of metamorphism and the lithologies of the protoliths suggest a near-arc tectonic setting and refute a subduction zone model for this event.
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  • 53
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    Journal of metamorphic geology 7 (1989), S. 0 
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    Topics: Geosciences
    Notes: In regionally metamorphosed pelites of the Mount Raleigh pendant, the fibrolite isograd occurs 5km downgrade from the sillimanite isograd. Fibrolite formed from the decomposition of biotite, a reaction that probably resulted from the late-stage influx of acidic volatiles. In contrast, sillimanite formed by the direct,‘volume-for-volume’replacement of andalusite. Andalusite and sillimanite coexist in a 3 km-wide zone above the sillimanite isograd. Electron probe analyses of these phases reveal low minor element contents and yield KD[=X] values close to unity; the low Fe2O3 contents are compatible with reducing conditions implied by the ubiquity of graphite. Because KD→ 1.0, the zone of coexisting andalusite + sillimanite cannot be attributed to multivariancy resulting from partitioning of minor elements between these phases. Rather, the metastable persistence of andalusite into the sillimanite P-T stability field is suggested. The modal proportions of sillimanite versus andalusite imply that minimal (〈5%) and alusitesillimanite reaction occurred in a zone 1.5km above the sillimanite isograd; in contrast, there was a marked increase in reaction progress immediately above this zone. With an estimated thermal gradient (in the plane of exposure) of approximately 20°C/km, the 1.5 km-wide zone of nil reaction suggests that the andalusite-sillimanite equilibrium boundary was overstepped by about 30 °C before significant reaction occurred. Inclusion-rich areas in andalusite provided favourable sites for sillimanite nucleation; however, the growth of sillimanite may have been impeded by‘pinning’of sillimanite grain boundaries by inclusions.
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  • 54
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    Journal of metamorphic geology 7 (1989), S. 0 
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    Topics: Geosciences
    Notes: Thermobarometric studies on various granulite facies areas along the Prydz Bay coast, East Antarctica (73°-79°E, 68°-70°S), show that, at around 1100 Ma, during a late Proterozoic orogeny, the rocks of the Larsemann Hills suffered a lower pressure metamorphic peak than the surrounding areas. Along the Prydz Bay coast, the rocks affected by this event include parts of the Vestfold Hills block plus all of the Rauer Group, the Larsemann Hills and the Munro Kerr Mountains. The dykes in the south-west corner of the Vestfold Hills were recrystallized during this event with little deformation at temperatures not quite as high as in the areas further south-west (650°C, 6.5 kbar) (Collerson et al., 1983), the Rauer Group was metamorphosed at 800°C and 7.5 kbar (Harley, 1987a), the Larsemann Hills at 750°C and 4.5 kbar, and the Munro Kerr Mountains probably at around 850°C and 5 kbar. Retrograde equilibration in the different areas occurred during decompression to about 10 km depth in all areas, followed by isobaric cooling at this depth.This paper shows that the peak metamorphism in the Larsemann Hills occurred at a pressure which is too low to have been the consequence of thermal relaxation of overthickened crust with normal mantle heat flow. Although other areas in Prydz Bay were metamorphosed at sufficiently high pressures so that their decompression paths are not inconsistent with a continental collision model, the inferred pre-metamorphic peak histories and the requirement of consistency with the Larsemann Hills, make it unlikely that collision followed by erosion-driven decompression is an appropriate model. We suggest that the thermal regime of the crust in the Larsemann Hills region was controlled by a perturbation in the asthenosphere, with magma invasion of the crust. We suggest that the 500 Ma event, represented in Prydz Bay by granitic outcrops at Landing Bluff and by several K/Ar ages from the Larsemann Hills area, was responsible for the final excavation of the terrane.
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    Journal of metamorphic geology 7 (1989), S. 0 
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    Notes: Detailed microstructural analysis of inclusion trails in hundreds of garnet porphyroblasts from rocks where spiral-shaped inclusion trails are common indicates that spiral-shaped trails did not form by rotation of the growing porphyroblasts relative to geographic coordinates. They formed instead by progressive growth by porphyroblasts over several sets of near-orthogonal foliations that successively overprint one another. The orientations of these near-orthogonal foliations are alternately near-vertical and near-horizontal in all porphyroblasts examined. This provides very strong evidence for lack of porphyroblast rotation.The deformation path recorded by these porphyroblasts indicates that the process of orogenesis involves a multiply repeated two-stage cycle of: (1) crustal shortening and thickening, with the development of a near-vertical foliation with a steep stretching lineation; followed by (2) gravitational instability and collapse of this uplifted pile with the development of a near-horizontal foliation, gravitational spreading, near-coaxial vertical shortening and consequent thrusting on the orogen margins. Correlation of inclusion trail overprinting relationships and asymmetry in porphyroblasts with foliation overprinting relationships observed in the field allows determination of where the rocks studied lie and have moved within an orogen. This information, combined with information about chemical zoning in porphyroblasts, provides details about the structural/metamorphic (P-T-t) paths the rocks have followed.The ductile deformation environment in which a porphyroblast can rotate relative to geographic coordinates during orogenesis is spatially restricted in continental crust to vertical, ductile tear/transcurrent faults across which there is no component of bulk shortening or transpression.
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  • 56
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    Notes: The western metamorphic belt of the Coast Plutonic Complex, south-east Alaska and adjacent British Columbia, contains strongly deformed rocks and a prominent topographic low: the Coast Range megalineament. Near Holkham Bay, south-east Alaska, the lineament separates the western metamorphic belt into: a western low-grade (greenschist facies) terrane, and an eastern medium-grade (amphibolite facies) terrane.Sphalerite compositions of grains in direct contact with pyrite and pyrrhotite in chlorite-muscovite zone rocks in the low-grade terrane give pressures of about 8 kbar; compatible with pressures of 8-10 kbar at 500°C calculated from plagioclase-biotite-garnet-muscovite assemblages adjacent to the Windham Bay pluton about 15 km away. A pressure of 4.8 ± 0.7 kbar was calculated from sphalerite compositions in staurolite zone rocks east of the Coast Range megalineament. This is indistinguishable from pressures of 4.8 ± 1 kbar at 585°C and 5.1 ± 1 kbar at 680°C (plagioclase-garnet-aluminum silicate-quartz equilibria), and 4.1 ± 1 kbar at 585°C (plagioclase-biotite-garnet-muscovite equilibrium) determined for the medium-grade terrane. An identical pressure of 4.8 ± 0.7 kbar was calculated from sphalerite compositions in biotite zone rocks adjacent to the lineament; this is considerably higher than a pressure of 3.1 ± 1 kbar at 525°C obtained using plagioclase-biotite-garnet-muscovite geobarometry from shear zones within the lineament. The discrepancy may be explained by later equilibration of mineral phases within the shear zones.The geothermobarometry suggests relatively low temperatures and high pressures for the low-grade terrane (6-10 kbar), and intermediate temperatures and pressures for the medium-grade terrane to the east (4-6 kbar). Comparison of the barometers indicate that sphalerite can be used to estimate metamorphic pressures, similar to those estimated from silicate mineral chemistry when pyrrhotite-sphalerite-pyrite assemblages are used.
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    Notes: Metabasalts and metasedimentary rocks of the Devonian Central Metamorphic Belt comprise the lower plate of the east-dipping Trinity thrust system in the Klamath province. An inverted metamorphic gradient is preserved in the Central Metamorphic Belt; metamorphic conditions decrease from amphibolite facies adjacent to the Trinity thrust, through albite-epidote amphibolite facies, to upper greenschist facies at the base of the Central Metamorphic Belt. Mineral chemistry, mineral assemblages and limited geothermometry suggest that peak metamorphic conditions decrease structurally downward from 650 ± 50° C at the Trinity thrust to 500 ± 50° C at the base of the Central Metamorphic Belt, under pressures of 5 ± 3 kbar. Synmetamorphic Ab + Qtz veins, up to 1 m thick, increase in abundance towards the Trinity thrust. Infiltration of H2O-CO2 fluids derived from prograde devolatilization reactions in the Central Metamorphic Belt caused extensive hydration and metasomatism of the Trinity peridotite; the hanging wall block of the Trinity thrust zone.Geological relationships and the preserved inverted metamorphic gradient suggest that the Central Metamorphic Belt formed in an east-dipping Devonian subduction zone in an oceanic environment. The Central Metamorphic Belt appears to represent a discrete slice of accreted oceanic crust several km thick, rather than progressively accreted material. Metamorphic pressures recorded by the Central Metamorphic Belt are intermediate between the ∼2 kbar pressures recorded in dynamothermal aureoles beneath obducted ophiolites and the 7–10 kbar preserved in subduction-related inverted metamorphic gradients. The lack of blueschist facies mineral assemblages in the Central Metamorphic Belt may possibly be explained by an anomalously warm geotherm prior to subduction or early shear heating prior to the arrival of wet rocks at depth.
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    Notes: Abstract Contact metamorphism adjacent to a porphyritic quartz-monzodiorite at Kentucky, New South Wales, Australia has produced hornfelses in porphyritic leucogranite at a peak temperature of about 650–700° C and a maximum confining pressure of about 2 kbar (200 MPa). A gradation appears to exist from normal slightly peraluminous to modified strongly peraluminous metagranite hornfelses, which have also been enriched in sulphur. The strongly peraluminous hornfelses, containing cordierite, andalusite, sillimanite, biotite, pyrite and pyrrhotite, retain residual porphyritic igneous microstructures. These rocks appear to have been formed by leaching of base cations, during and possibly just before the contact metamorphism. Folia of fibrous sillimanite anastomose between lenticular grains of quartz and feldspar and truncate igneous zoning in plagioclase grains, suggesting that cation leaching and solution transfer occurred during growth of the sillimanite. Fibrous sillimanite also grew in grain boundaries of polygonal aggregates formed by the contact metamorphism. Therefore, at least some of the cation leaching appears to have occurred at the highest metamorphic grade. Metasandstones that are locally strongly peraluminous adjacent to the monzodiorite stock also, have probably undergone similar leaching.
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    Journal of metamorphic geology 5 (1987), S. 0 
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    Notes: Abstract The Paikon Series is considered to be a volcanic arc sequence with a mainly neritic sedimentary sequence and bimodal tholeiitic volcanism of early Mesozoic age. The metamorphic assemblages are syn- to post-kinematic with respect to a pre-Tithonian tectonic phase and range from the lawsonite-chlorite-albite facies through transitional Na-amphibole-greenschist facies to the chlorite sub-zone of the greenschist facies. The metamorphic imprint of the Paikon Series corresponds to a temperature range from less than 330° C to ± 450° C under a total pressure from 3 kbar to 6–7 kbar. The overprinting of these facies on an earlier blueschist assemblage, related either to a subduction zone or to a tectonic overpressure caused by thrusting, is suspected.
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    Notes: Abstract Textural evolution and compositional variation of clinopyroxenes in Ward Creek metabasites are described. Pyroxenes change, with increasing grade, from finegrained aggregates through fan-shaped medium-grained prisms to blocky coarse crystals. Characteristic features of metamorphic pyroxenes include: (1) the occurrence of coexisting pyroxene pairs, the compositions of which are used to delineate compositional gaps; (2) the existence of large compositional variations of pyroxenes, within a single specimen, which record a considerable span of P and/or T for crystallization; and, (3) the development of compositional trends in single specimens and in three metamorphic zones which are progressive in nature.The first formed clinopyroxene (Jd20Aug65Ac15) in the lower lawsonite zone mimics the composition of relict igneous augite. It changes continuously, with increasing grade, at nearly constant low XJd content towards acmite. At a composition around Jd20Aug30Ac50, the trend turns towards jadeite and intersects a solvus to form two coexisting clinopyroxenes in the middle lawsonite zone. At higher grade, the compositional gap becomes restricted towards the jadeite-omphacite join and clinopyroxene increases in XJd toward jadeite. A reversed compositional trend occurs at higher grade; clinopyroxenes decrease in jadeite component at nearly constant Aug/Ac ratio of 50/50 and finally become omphacite in the uppermost pumpellyite and epidote zones. The Na–Ca pyroxenes, close to the binary join Jd–Ac, occur in the lawsonite- and pumpellyite-zones, ranging from XJd= 1.0–0.30 together with Ab and Qz. The ubiquitous occurrence of aragonite at temperature estimates of 170–240° C by Taylor & Coleman (1968) for these zones does not support the low-temperature extrapolation of the Jd–Ab–Qz curve by Holland (1980).The estimated metamorphic field gradient indicates an inflection point at 7 kbar, 200° C. Below this, blueschist facies metamorphism proceeded under dominant pressure-increase from 4 to 7 kbar at nearly constant temperature, about 150–200° C, whereas at higher grade recrystallization, above the inflection point, the metamorphic temperature increased from 200 to 350° C at nearly constant pressure, about 7–8 kbar. Such an inflection point suggests the depth of underplating of either seamounts or accretionary packages in a subduction zone.
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    Notes: Abstract Sapphirine-bearing rocks occur in three conformable, metre-size lenses in intrusive quartzo-feldspathic orthogneisses in the Curaçà valley of the Archaean Caraiba complex of Brazil. In the lenses there are six different sapphirine-bearing rock types, which have the following phases (each containing phlogopite in addition):A: Sapphirine, orthopyroxene;B: Sapphirine, cordierite, orthopyroxene, spinel;C: Sapphirine, cordierite;D: Sapphirine, cordierite, orthopyroxene, quartz;E: Sapphirine, cordierite, orthopyroxene, sillimanite, quartz;F: Sapphirine, cordierite, K-feldspar, quartz.Neither sapphirine and quartz nor orthopyroxene and sillimanite have been found in contact, however. During mylonitization, introduction of silica into the three quartz-free rocks (which represent relict protolith material) gave rise to the three cordierite and quartz-bearing rocks. Stable parageneses in the more magnesian rocks were sapphirine–orthopyroxene and sapphirine–cordierite. In more iron-rich rocks, sapphirine–cordierite, sapphirine-cordierite–sillimanite, cordierite–sillimanite, sapphirine–cordierite–spinel–magnetite and quartz–cordierite–orthopyroxene were stable. The iron oxide content in sapphirine of the six rocks increases from an average of 2.0 to 10.5 wt % (total Fe as FeO) in the order: C,F–A,D–B,E. With increase in Fe there is an increase in recalculated Fe2O3 in sapphirine.The four rock types associated with the sapphirine-bearing lenses are:I: Orthopyroxene, cordierite, biotite, quartz, feldspar tonalitic to grandioritic gneiss;II: Biotite, quartz, feldspar gneiss;III: Orthopyroxene, clinopyroxene, hornblende, plagioclase meta-norite;IV: Biotite, orthopyroxene, quartz, feldspar, garnet, cordierite, sillimanite granulite gneiss.The stable parageneses in type IV are orthopyroxene–cordierite–quartz, garnet–sillimanite–quartz and garnet–cordierite–sillimanite.Geothermobarometry suggests that the associated host rocks equilibrated at 720–750°C and 5.5–6.5 kbar. Petrogenetic grids for the FMASH and FMAFSH (FeO–MgO–Al2O3–Fe2O3–SiO2–H2O) model systems indicate that sapphirine-bearing assemblages without garnet were stabilized by a high Fe3+ content and a high XMg= (Mg/ (Mg+Fe2+)) under these P–T conditions.
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    Notes: Abstract Chloritoid–hornblende occurs in quartz–muscovite pelitic schist derived from sediment in a volcaniclastic sequence of the Grenville Supergroup and from reworked sedimentary and regolithic material above the unconformity at the base of the Flinton Group. Comparison of these samples with other pelitic rocks on triangular composition diagrams and in the ACNF and ACFM tetrahedra indicates that the presence of hornblende cannot be explained by unusually high CaO content. The rare assemblage is attributed to a combination of relatively low Al2O3 and high K2O with high CaO/(CaO+Na2O) and FeO/(FeO+MgO).On two qualitative reaction grids derived from AFM diagrams projected through CaO and plagioclase, respectively, the P–T stability field of chloritoid–hornblende overlaps the first appearance of staurolite–biotite in normal pelitic rocks in the kyanite field. Staurolite–hornblende overlaps chloritoid–hornblende and extends to the higher temperatures and pressures of the kyanite–hornblende field.The phase relations in these rocks provide a link between the conventional hornblende-absent grids for pelitic rocks and those for K2O-poor (muscovite-absent) pelitic and mafic amphibolitic rocks.
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    Journal of metamorphic geology 5 (1987), S. 0 
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    Notes: Abstract The effect of ductile deformation (dislocation creep) on the kinetics of the aragonite-calcite transformation has been studied at 1 atm (330° C and 360° C) and 900-1500 MPa (500° C) using undeformed and either previously or simultaneously deformed samples (500° C and a strain rate of 10-6 s). Deformation enhances the rate of the transformation of calcite to aragonite, but decreases the rate of transformation of aragonite to calcite. The difference results from a dependence of transformation rate on grain size, coupled with a difference in the accommodation mechanisms, climb versus recry-stallization, of these minerals during dislocation creep. Dislocation climb is relatively easy in calcite and thus plastic strain results in high dislocation densities without significant grain size reduction. The rate of transformation to aragonite is enhanced primarily because of the increase in nucleation sites at dislocations and subgrain boundaries. In aragonite, on the other hand, dislocation climb is difficult and thus plastic strain produces extensive dynamic recry-stallization resulting in a substantial grain size reduction. The transformation of aragonite is inhibited because the increase in calcite nucleation sites at dislocations and/or new grain boundaries is more than offset by the inability of calcite to grow across high angle grain boundaries. Thus the net effect of ductile deformation by dislocation creep on the kinetics of polymorphic phase transformations depends on the details of the accommodation mechanism.
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    Journal of metamorphic geology 7 (1989), S. 0 
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    Journal of metamorphic geology 7 (1989), S. 0 
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    Notes: The Bunger Hills, East Antarctica, experienced a low-pressure granulite facies orogenic event during the Proterozoic. The stable coexistence of the S1 foliation-parallel M1 assemblages, garnet-cordierite-spinel-ilmenite and garnet-sillimanite-spinel-ilmenite-rutile, in quartz-bearing pelitic gneisses is evidence for metamorphic peak pressures of around 4 kbar during M1, at temperatures of about 800°C. The growth of massive reaction coronas of garnet and cordierite around hercynitic spinel and iron-titanium oxides during M2 is evidence for the destabilization of the M1 assemblages during compression. Thermodynamic calculations on the M2 assemblages indicate formation pressures of 6–7 kbar at temperatures of about 750°C. Thus, the gneisses from the Bunger Hills indicate about 2 kbar or more of compression during minimal cooling. Such a P-T path is different from that of many other Proterozoic terranes which are characterized by isobaric cooling or decompression. A large charnockite body, which is undeformed, was intruded at ∼950°C, towards the end of compression.The low pressures during M1 can be best explained by metamorphism at mid-crustal levels in thin continental crust in thin lithosphere above a thermal perturbation in the underlying asthenosphere. We suggest that the compression during cooling was a result of gravitational backflow in which the action of body forces between adjacent normal thickness crust and the thin crust of the Bunger Hills is 'switched on’by the thermal perturbation. Within such a model, the timing of intrusion of the charnockite exposed in the Bunger Hills is consistent with its generation by partial melting during the metamorphic maximum of the lowermost crust.
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    Notes: There is no significant difference in the diffusion profiles across albite-adularia bicrystals that were simultaneously deformed at a strain rate of 10-6S-1 and those from hydrostatic experiments at the same conditions (1500 MPa and 1000°C for 156 h). This indicates that the bulk alkali diffusion rate, which is the sum of lattice diffusion (D, 1) and dislocation pipe diffusion (Dp), is not significantly enhanced by dislocations at these conditions, and that the maximum value for the ratio of Dp/D1 is about 105. This is equal to the value previously reported for‘oxygen’diffusion in albite. If this ratio is independent of temperature, the contribution of either static (pre-deformed) or moving (syn-deformed) dislocations to the bulk diffusion rate of alkalis is probably minor at all metamorphic conditions. For Al and Si diffusion the ratio of Dp/D1 may be larger if D1 is lower. Thus a significant contribution from dislocations to bulk diffusion cannot be ruled out, especially during simultaneous deformation.
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    Notes: In the Woodroffe Thrust mylonite zone, central Australia, recrystallization in plagioclase and K-feldspar involved subgrain rotation, assisted by grain-boundary or kink band boundary bulging, without contribution from a change in the chemical composition from host grains to new grains. The size of subgrains and new grains changes across the mylonite zone, apparently as a function of the strain rate and the H2O content of the rock.The partitioning of deformation into zones of progressive shearing and progressive shortening controls the sites of recovery and recrystallization in feldspar during mylonitization. The size of feldspar porphyroclasts in well developed mylonites is governed by the scale of deformation partitioning reached in the earlier stages of mylonitization, before the formation of a large proportion of fine-grained matrix that can accommodate the progressive shearing component of the deformation.Recrystallization occurs in microcline, apparently without involving a translation to a monoclinic structure, as microcline-twinned new grains are common adjacent to microcline-twinned host grains. K-feldspar triclinicity values calculated from XRD traces increase from the margins to the interior of the mylonite zone, in conjunction with deformation intensity. K-feldspar host grains locally have cores of orthoclase or untwinned microcline, surrounded by mantles of twinned microcline, suggesting a relationship between the presence of microcline twinning and the degree of K-feldspar triclinicity.
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    Journal of metamorphic geology 7 (1989), S. 0 
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    Notes: The decrepitation behaviour of fluid inclusions in quartz at one atmosphere confining pressure has been evaluated using pure H2O synthetic inclusions formed by healing fractures in natural quartz. Three different modes of non-elastic deformation, referred to as stretching, leakage or partial decrepitation, and total decrepitation have been observed. The internal pressure required to initiate non-elastic deformation is inversely related to inclusion size according to the equation:internal pressure (kbar) = 4.26 D-0.423where D is the inclusion diameter in microns. Regularly shaped inclusions require a higher internal pressure to initiate non-elastic deformation than do irregularly shaped inclusions of similar size. Heating inclusions through the α/β quartz inversion results in mechanical instability in the quartz crystal and leads to mass decrepitation of inclusions owing to structural mismatches generated by pressure gradients in the quartz around each inclusion.Long-term heating experiments (∼2 years) suggest that the internal pressure required to initiate non-elastic deformation does not decrease significantly with time and indicates that short-lived thermal fluctuations in natural systems should not alter the inclusion density and homogenization temperature. Inclusions that do exhibit decreased density (higher homogenization temperature) are, however, always accompanied by a change in shape from irregular to that of a negative crystal.Observations of this study are consistent with elasticity theory related to fracture generation and propagation around inclusions in minerals. These results indicate that an inclusion will not be influenced by a neighbouring inclusion, or other defect in the host phase, as long as the distance between the two is 〉2–4 diameters of the larger of the two inclusions.
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    Notes: Sapphirine has been found in two types of magnesian, metabasic lenses from tectonite zones within the Central Gneiss Belt of the south-west Grenville Province, Canada. The first type (association I) comes from a lenticular mafic lens within highly tectonized anorthosite, the second type (association II) comes from meta-eclogitic pods with foliated amphibolite rims. In each case the sapphirine-bearing assemblages record a wealth of reaction textures. The primary mineralogy in association II is represented by high alumina clinopyroxene, garnet and kyanite ± plagioclase and records pressures of around 14-16 kbar; in association I the primary mineralogy is represented by plagioclase, two pyroxenes and possibly olivine but here the equilibrium pressure is unknown.The host gneisses equilibrated at approximately 8 to 10 kbar and 700-750°C by continuous cation exchange reactions during and after the culmination of the Grenvillian orogeny at 1.16-1.0 Ga. It is unlikely that the higher pressures recorded in the meta-eclogitic pods represent an earlier high-pressure metamorphism as the pods are restricted to shear zones. A tectonic mode of emplacement into a crust undergoing granulite facies metamorphism is more likely. Sapphirine formed by discontinuous decompression reactions; in association II this involved a reaction between garnet and kyanite and resulted in the formation of magnesian granulite facies assemblages. At the same time primary clinopyroxene became much less aluminous by evolving plagioclase. Pressures and temperatures from coexisting phases, that are believed to have equilibrated at the same time as sapphirine formation, are estimated as 11 to 12 kbar and 750°C. These probably represent the peak conditions for granulite facies metamorphism in the south-west Grenville Province.
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    Notes: Several examples of deformation-induced myrmekite have been found in two amphibolite facies mylonites derived from granitic protoliths, namely a muscovite-poor S-C mylonite and a single foliation, muscovite-poor mylonitic gneiss. Back-scattered SEM and conventional optical microscopy show that in both rock types, syntectonic myrmekitic intergrowths of oligoclase and quartz formed on the two sides of K-feldspar grains that faced the local inferred incremental shortening direction for the mylonite. Myrmekite does not occur on the two ends of the grain that faced the incremental stretching direction.The replacement of K-feldspar by plagioclase and quartz results in a volume decrease and is favoured on high normal stress sites around the grains. We suggest that the ambient temperature, pressure and chemical activities were such that the replacement reaction was favoured, but the addition of extra strain energy along the high-pressure sides of the grains localized the reaction at these sites. This energy could arise from elastic strain, or strain associated with tangled dislocations or twin boundaries. The relative roles of stress and strain energy concentrations in driving the replacement reaction are not known, but both were probably important.
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    Notes: The Main Central Thrust (MCT) south of Mt Everest in eastern Nepal is a 3 to 5km thick shear zone separating chlorite-bearing schist in the lower plate from sillimanite-bearing migmatitic gneiss in the overlying Tibetan Slab. The metamorphic grade increases through the MCT zone toward structurally higher levels. Previous workers have suggested that either post- or synmetamorphic thrust movement has caused this inversion of metamorphic isograds. In an effort to quantify the increase in grade and to constrain proposed structural relations between metamorphism and slip on the fault, four well-calibrated thermobarometers were applied to pelitic samples collected along two cross-strike transects through the MCT zone and Tibetan Slab. Results show an increase in apparent temperature up-section in the MCT zone from 778 K to 990 K and a decrease in temperature to ∼850 K in the lower Tibetan Slab, which is consistent with synmetamorphic thrust movement. A trend in calculated pressures across this section is less well-defined but, on average, decreases up-section with a gradient of ∼28MPa/km, resembling a lithostatic gradient. Pressure-temperature paths for zoned garnets from samples within the MCT zone, modelled using the Gibbs' Method, show a significant decrease in temperature and a slight decrease in pressure from core to rim, which might be expected for upper plate rocks during synmetamorphic thrust movement. Samples from the uppermost Tibetan Slab yield higher temperatures and pressures than those from the lower Tibetan Slab, which may be evidence for later‘resetting’ of thermobarometers by intrusion of the large amounts of leucogranite at that structural level.
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    Notes: Along a cross-section through the Lesser and Higher Himalayan units at the Kishtwar window area (north-west India), a polyphase, Barrovian-type metamorphism has been delineated in relation to the development of the Main Central Thrust (MCT). In the metapelitic mineral assemblages, three metamorphic phases have been distinguished:〈list xml:id="l1" style="custom"〉(a)conditions up to amphibolite grade at moderate to high pressures (alm + rut + ilm + kya + qtz) characterize the M1 phase;(b)pressure release and/or temperature increase as a result of movement along the MCT and the formation of gneiss domes in the Higher Himalaya, as expressed by oriented (N70°-100° E) fibrolite, defines the M2 phase; and,(c)finally during uplift of the Kishtwar window area, a retrogressive M3 phase is characterized by the assemblage quartz-muscovite-chlorite.Both optically zoned and single-stage garnets have been examined with the electron microprobe to determine their element partitioning. Normal zoning has been found in samples below the MCT in the Lesser Himalaya, indicating prograde growth during the M2 phase, whereas tectonically above, in the Higher Himalaya unit, the garnets reveal double-stage growth with a complex zoning pattern due to reaction-partitioning during M1 and M2 and reverse-zoning at their rims during the retrogressive M3 phase. Geothermometry on metapelites along a cross-section through the MCT zone and the Higher Himalaya imply distinct readjustments of garnet-biotite exchange equilibria and indicate isothermal conditions (500-600° C) throughout the section during the M3 retrogression. Pressure calculations (gro-an-kya-qtz and alm-rut-ilm-kya-qtz) suggest a decrease in pressure towards the top of the section (6-7.5 to 4.5-5 kbar), as corroborated by fibrolite replacing kyanite. The spatially inverse metamorphism exposed within the Lesser Himalaya of the Kishtwar window is regarded as a product of polyphase metamorphism combined with ongoing thrusting and shearing and is reflected by condensed M2 isograds around the Kishtwar window.
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    Topics: Geosciences
    Notes: The Darjeeling-Sikkim region provides a classic example of inverted Himalayan metamorphism. The different parageneses of pelitic rocks containing chlorite, biotite, garnet, staurolite, kyanite, sillimanite, plagioclase and K-feldspar are documented by a variety of textures resulting from continuous and discontinuous reactions in the different zones. Microprobe data of coexisting minerals show that XMg varies in the order: garnet 〈 staurolite 〈 biotite 〈 chlorite. White mica is a solid solution between muscovite and phengite. Garnet is mostly almandine-rich and shows normal growth zoning in the lower part of the Main Central Thrust (MCT) zone, and reverse zoning in the upper part of the zone. Chemographical relations and inferred reactions for different zones are portrayed in AFM space. In the low-grade zones oriented chlorites and micas and rolled garnets grew syntectonically, and were succeeded by cross-cutting chlorites and micas and garnet rims. In the upper zones sillimanite, kyanite and staurolite crystallized during a static inter-kinematic phase. P-T contitions of metamorphism, estimated through different models of geothermobarometry, are estimated to have been 580°c for the garnet zone to a maximum of 770°c for the sillimanite zone. The preferred values of pressure range from 5.0 kbar to 7.7 kbar. Models to explain the inverted metamorphism include overthrusting of a hot high Himalayan slab along a c. 5 km wide ductile MCT zone and the syn- or post-metamorphic folding of isograds.
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  • 79
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    Journal of metamorphic geology 5 (1987), S. 0 
    ISSN: 1525-1314
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: Abstract Cordierite-anthophyllite rocks and related cordierite-rich, talc-rich and chlorite-rich rocks occur in the Rosebud Syncline, north-west Queensland, Australia, as part of a Proterozoic metasedimentary sequence. Field relations and rock compositions attest the sedimentary origin of these rather unusual metamorphic rocks. Their chemical composition is comparable to that of unmetamorphosed, alkali- and Ca-poor pelites, which are associated with some evaporite deposits.Other occurrences of cordierite-anthophyllite rocks have commonly been interpreted as metamorphosed chloritic alteration products derived from mafic or felsic volcanics. A comparative chemical study, using analyses of cordierite-anthophyllite rocks from such alteration zones and analyses of unmetamorphosed magnesian pelites, demonstrates the general chemical similarity between these two rock groups of entirely different origin. However, distinct differences in major element relations help to distinguish these two genetic groups. Particularly useful are Al2O3–FeO–MgO plots, in which evaporitic pelites occupy the Fe-poor side.The highly magnesian metamorphic rocks from the Rosebud Syncline fall entirely into the compositional field of evaporitic clays and shales. Furthermore, analyses of relatively immobile trace elements give supporting evidence for the sedimentary origin of these cordierite-anthophyllite rocks. The correlation with trace element ranges of clays and shales is very good. However, the correlation with trace element ranges of mafic and felsic volcanics is poor, and major discrepancies occur with Cr, Ni, Co, Nb, Sc, Th and Ti.Thus, the magnesian metamorphics of the Rosebud Syncline appear to be derived from evaporitic clays rich in magnesian clay minerals, such as palygorskite, sepiolite, chlorite or corrensite. The complete metamorphic rock assemblage of interlayered calcareous, aluminous and magnesian rocks is interpreted as a metamorphosed carbonate-evaporite-pelite sequence.
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  • 80
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    Journal of metamorphic geology 5 (1987), S. 0 
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    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
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  • 81
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    Journal of metamorphic geology 5 (1987), S. 0 
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    Topics: Geosciences
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  • 82
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    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: Abstract A suite of granulites including a meta-ironstone, pyroxenites, and spinel-lherzolites from East Tonagh Island, Enderby Land, Antarctica, preserve exsolution-recry-stallization features consistent with a shared metamorphic evolution that involves marked cooling from initial metamorphic temperatures of nearly 1000°C. Reintegrated pre-exsolution and pre-reaction grain compositions in the meta-ironstone indicate the former coexistence of metamorphic pigeonite (Wo12En38Fs50) and ferroaugite (Wo35En31Fs34) at temperatures in excess of 980°C for pressures of 7 kbar (0.7 GPa) using pyroxene quadrilateral thermometry (Lindsley, 1983). Intra-grain lamellae relationships indicate the exsolution of a second pigeonite (Wo12En35Fs53) from the ferroaugite at temperatures in the range 930–970°C, prior to the c. 720–600°C exsolution of orthopyroxene and clinopyroxene (100) lamellae and later partial recrystallization at similar temperatures. Although pyroxenitic and iherzolitic granulites preserve a much less complete history, reintegrated porphyroclast compositions in these yield temperature estimates which approach those inferred from the metaironstone. Pyroxene thermometry based on neoblast compositions suggests that recrystallization post-dating a late, low intensity, deformation phase (D3) occurred at temperatures greater than 600°C. These results are consistent with the independent evidence obtained from studies of metapelitic and felsic rock types for very high temperature metamorphism throughout the Napier Complex followed by near-isobaric cooling and later deformation under lower-grade granulite facies conditions. Comparison with similar pyroxene data from Fyfe Hills (Sandiford & Powell, 1986) demonstrates further the regional significance of these high temperatures, and implies broadly isothermal metamorphic conditions over a large area (∼ 5000 km2) and thickness (6–9 km) of lower crust at c. 3070 Ma.
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  • 83
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    Journal of metamorphic geology 5 (1987), S. 0 
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    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: Abstract A detailed field and petrological study of rocks from nappes cut by the Valle dell'Orco (Italian Western Alps), in particular the Sesia–Lanzo composite unit, has revealed geological and metamorphic histories which started in pre-alpine times and lasted up to the alpine subduction-collisional processes. During these processes the nappes sustained an early high P–low T stage and a later low P greenschist facies stage, but followed partly distinctive P–T–time trajectories. This paper discusses the kinematic evolution and the thermal history of the alpine belt from the early subduction/underthrust to the later exhumation stage. The metamorphic crystallization is often governed by incomplete and/or local equilibrium, and the pervasive syn-metamorphic deformation and the composition of the syn-metamorphic fluid phase (if present) have exerted an effective local control on reaction kinetics.
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  • 84
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    Journal of metamorphic geology 5 (1987), S. 0 
    ISSN: 1525-1314
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: Abstract Optical and X-ray studies of carbonaceous material in the Tono contact metamorphic aureole, Kitakami Mountains, northeast Japan, have revealed that metamorphic graphitization proceeded through two discontinuous changes: first, optically anisotropic domains develop within the coaly phytoclast, forming transitional material, and then, ordered graphite crystallizes by the decomposition of pre-existing carbonaceous materials. Coaly material disappears in the uppermost chlorite zone. Transitional material appears in the middle of the lower chlorite zone. Graphite appears in the upper chlorite zone and its modal abundance increases across the andalusite iso-grad to the cordierite isograd where all the carbonaceous materials have converted to graphite. The apparently continuous variation in the crystallographic parameters of the bulk carbonaceous material during graphitization is largely due to variation in the modal proportions of three types of carbonaceous materials. The temperature of graphitization in the present area is at least 100°C higher than the temperature in the Sanbagawa and New Caledonia high-pressure metamorphic terrains, probably due to the slow reaction rate of metamorphic graphitization and to the short duration of contact metamorphism.
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  • 85
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    Journal of metamorphic geology 5 (1987), S. 0 
    ISSN: 1525-1314
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: Abstract Dissolution of quartz and the recryst-allization and re-equilibration of phyllosilicates produce the dark anastomosing seams that dominate microstructures of tectonic melange which occur in a low-grade, imbricated and multiply deformed, mid-Palaeozoic, intracra-tonic fiysch sequence in northeastern Australia. Seams are composed of very closely spaced or coalesced cleavage lamellae, which are very thin layers of extremely fine-grained phyllosilicates. Cleavage seams enclose lenses of silt-stone or greywacke, which formerly occurred in continuous sedimentary layers, indicating extremely heterogeneous and disruptive deformation. Microphacoids enclosed by cleavage seams have subtle shape asymmetries analogous to those of porphyroclasts. Phyllosilicate-preferred orientations within microphacoids commonly lie at a low angle to enclosing seams, and asymmetric relationships occur within seams. The shape and fabric asymmetries appear to be constant, and are regarded as analgous to S and C planes. The number and extent of seams, the amount of dissolution they indicate, and the efficiency of deformation partitioning imply some enhancement of chemical activity and substantial silica loss from the system. This, in turn, suggests the passage of large amount of silica-undersaturated fluid, and melanges may be zones of high fluid flow. However, the microstructures and the disruptive nature of the fabrics may also reflect the influence of high bulk shear strains and suggest some relationship between the shearing component of deformation and the development of cleavages and foliations.
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  • 86
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    Journal of metamorphic geology 5 (1987), S. 0 
    ISSN: 1525-1314
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: Abstract In the Bois de Cené area, blueschist facies rocks, characterized by glaucophane and/ or chloritoid, provide evidence for a suture zone in the Variscan. This terrain is considered to be the eastern equivalent of the Ile de Groix high-pressure metamorphic terrain. Petrological study of the two characteristic types of rocks found in the area shows that the primary high-pressure paragenesis was modified during a retrogression which followed substantial decompression, probably at constant or decreasing temperature. The simplest interpretation is that this retrogression followed tectonic emplacement within a nappe pile.
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  • 87
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    Journal of metamorphic geology 5 (1987), S. 0 
    ISSN: 1525-1314
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: Abstract In the Fleur de Lys Supergroup, western Newfoundland, inclusion trails in garnet and albite porphyroblasts indicate that porphyroblasts overgrew a crenulation foliation, without rotation, probably during the deformation event that produced the crenulations. Further deformation of the matrix resulted in strong re-orientation and retrograde metamorphism of the matrix foliation, which is consequently highly oblique to the crenulation foliation preserved in the porphyroblasts. The resulting matrix foliation locally preserves relics of the early crenulations, and also has itself been crenulated later in places. Thus the porphyroblasts grew before the later stages of deformation, rather than during the final stage, as had been suggested previously. The new interpretation is consistent with available 40Ar/39Ar cooling ages which indicate a late Ordovician-early Silurian metamorphic peak, rather than the Devonian peak suggested by previous workers. The inclusion patterns and microprobe data indicate normal outward growth of garnet porphyroblasts from a central nucleus, rather than as a series of veins as proposed by de Wit (1976a, b). However, the observations presented here support growth of porphyroblasts without rotation, which is implied by the de Wit model.
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  • 88
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    Journal of metamorphic geology 5 (1987), S. 0 
    ISSN: 1525-1314
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: Abstract In foliated K-feldspar-sillimanite metapelites, fibrous sillimanite is commonly concentrated in folia that anastomose between lenticular pods of coarser-grained aggregates rich in quartz, feldspar and biotite, with or without garnet, cordierite and residual andalusite. Many of the folia appear to be limbs of crenulation microfolds. The sillimanite concentrations may be due largely to the ability of fibrous sillimanite aggregates to undergo strong non-coaxial deformation by grain-boundary sliding (‘fibre sliding’;) without appreciable build-up of dislocations, whereas other minerals are unstable in these zones and so concentrate in lower-strain interfolial zones. Initiation, and especially concentration of the sillimanite in folia, may be assisted by fluid flow and local base-cation leaching, whereby minerals unstable in zones of strong non-coaxial strain are dissolved and removed from these zones.
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  • 89
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    Journal of metamorphic geology 5 (1987), S. 0 
    ISSN: 1525-1314
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: Abstract Comparison of the stability relations of Fe-piemontite, Pm17Ps17Cz66 (Ca2Al2Mn0.5 Fe0.5Si3O12(OH)), with similar experimentally determined results on Pm33Cz67 suggests that, at moderate fo2, addition of Fe to piemontite raises its thermal stability and slightly decreases its sensitivity to oxygen fugacity. Reversal study of the reaction: Fe-piemontite + quartz = garnet (Gr33Sp27And40) + anorthite + fluid at Pfluid= 2 kbar in cold-seal apparatus using solid oxygen buffers was completed. The data indicated breakdown of Pm17Ps17Cz66 at 645°± 10° C along the Cu2O–CuO buffer, 477°± 10° C along the Cu–Cu2O buffer, and 365°± 10° C for the hematite-magnetite buffer. Mn-free clinozoisite and epidote have been shown to be stable to much higher temperatures than piemontite at moderate fo2 (〈 Cu–Cu2O). At very high fo2, however, the presence of Mn+3 in a distorted octahedral site may permit persistence of piemontite to higher temperatures than Mn-poor epidote minerals.The compositional range of natural Fe–Mn–Al piemontites supports these results. Cation partitioning from piemontite-bearing parageneses also indicates crystallization at high fo2, but application of the cited results should be made with caution. Synthetic phases were too fine-grained for optical or microprobe analysis, and reaction was often incomplete. The assumption that all Fe + Mn was contained in piemontite and garnet, respectively, in the low- and high-temperature assemblages is supported by the cell dimensions for these synthetic minerals, which are close to predicted values. The reaction is pseudo-univariant, as solid solution in garnet and piemontite would be fo2-dependent in a more complex chemical system. Although bulk rock and fluid compositions may also have a marked effect on the stability of natural epidote–piemontite, fo2 is the major control on Fe : Mn : Al in epidote minerals.
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  • 90
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    Journal of metamorphic geology 5 (1987), S. 0 
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  • 91
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    Journal of metamorphic geology 5 (1987), S. 0 
    ISSN: 1525-1314
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    Topics: Geosciences
    Notes: Abstract Pelitic assemblages from all major Witwatersrand gold fields record metamorphic conditions of the greenschist facies, with minimal regional grade changes over at least 200 km strike length. Diagnostic metamorphic assemblages are less common in the volumetrically dominant quartzites, the actively-exploited auriferous conglomerates and some of the regionally persistent metapelitic horizons. Bulk rock composition has been a major control on assemblage development.Key metapelitic assemblages include pyrophyllite, chloritoid, chlorite and muscovite in each gold field, with less common metamorphic biotite. Accessory minerals are pyrite, tourmaline, rutile and zircon. The abundance of chloritoid and pyrophyllite in thin shaly units, together with their minor, but widespread, distribution in quartzites and conglomerates, indicate that metamorphic temperatures reached 350°C ± 50°C in all the gold fields. Pressures are less-well constrained, 1–2 kbar being inferred. Outside the gold fields, higher grades are indicated by andalusite and kyanite near granitoid domes and later intrusions.The temperatures during peak metamorphism and the abundance of pyrite provide ideal conditions to (re)mobilize gold and may explain its secondary textural features.
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  • 92
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    Journal of metamorphic geology 5 (1987), S. 0 
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    Topics: Geosciences
    Notes: Abstract Corona textures, which developed in alternating layers in rocks in a supracrustal belt at Errabiddy, Western Australia, involved:(a) The production of staurolite, cordierite and quartz or sapphirine between Kyanite and/or sillimanite and gedrite; and(b) The production of cordierite between garnet and gedrite.These textures are inconsistent with development along the same pressure–temperature path in the system FeO–MgO–Al2O3–SiO2–H2O, but can be accounted for if CaO, mainly in garnet, is taken into account. The sapphirine-bearing kyanite–gedrite textures are explained by lower a(SiO2) during their development. The assemblages indicate a consistent pressure–temperature (P–T) trajectory involving substantial uplift with only a slight decrease in temperature. The history of these rocks includes reheating of originally high-grade rocks that had cooled to a stable conductive geotherm, followed by substantial, essentially isothermal uplift. The tectonic environment for this was presumably the one responsible for emplacement of the high-grade terrain in the upper crust.
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  • 93
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    The @photogrammetric record 13 (1989), S. 0 
    ISSN: 1477-9730
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Architecture, Civil Engineering, Surveying
    Notes: This short note sets out a personal experience of the transition from an academic environment to the great wide world of marketing and discusses some of the similarities and differences between the two.
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    The @photogrammetric record 13 (1989), S. 0 
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    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Architecture, Civil Engineering, Surveying
    Notes: In order to realise the full potential of photogrammetry for national map revision, photographic acquisition lead times and, where possible, costs must be significantly reduced. In this paper a review of alternative platform and camera configurations is made and tests are undertaken utilising simulated data and medium format data taken from an existing project. The results suggest that the medium format camera and helicopter combination may have much to offer while the small format camera and microlight aircraft systems have yet to be developed into an effective data acquisition and map compilation system.
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    The @photogrammetric record 13 (1989), S. 0 
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    Topics: Architecture, Civil Engineering, Surveying
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  • 96
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    The @photogrammetric record 13 (1989), S. 0 
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    Topics: Architecture, Civil Engineering, Surveying
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  • 97
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    The @photogrammetric record 13 (1989), S. 0 
    ISSN: 1477-9730
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Architecture, Civil Engineering, Surveying
    Notes: The author draws attention to the public nature of an archive compared with the privacy of a collection in the commercial sector. He emphasises the nature of copyright as it affects the products of his own company and explains some of the characteristic features of a commercial operation involved in the acquisition and supply of aerial photography.
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    The @photogrammetric record 12 (1987), S. 0 
    ISSN: 1477-9730
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Architecture, Civil Engineering, Surveying
    Notes: The availability of data in digital formats, the rapid evolution of computer systems and the increased demands for cartographic databases are causing photogrammetrists to consider ways of integrating photogrammetric, remote sensing and database technologies. Examples are presented involving the use of aerial photographs and satellite images in combination with geographical information systems and image processing techniques to assess soil erosion, growth of aquatic vegetation and to enhance satellite images for the compilation or revision of map products.
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    The @photogrammetric record 12 (1987), S. 0 
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    The @photogrammetric record 12 (1987), S. 0 
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    Topics: Architecture, Civil Engineering, Surveying
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