ALBERT

All Library Books, journals and Electronic Records Telegrafenberg

Your email was sent successfully. Check your inbox.

An error occurred while sending the email. Please try again.

Proceed reservation?

Export
Filter
  • Articles  (4,138)
  • Springer  (3,847)
  • Society of Exploration Geophysicists  (291)
  • 1985-1989  (4,138)
  • 1950-1954
  • 1986  (4,138)
  • Geosciences  (3,760)
  • Philosophy  (378)
Collection
  • Articles  (4,138)
Years
  • 1985-1989  (4,138)
  • 1950-1954
Year
Journal
  • 1
    ISSN: 1572-8854
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The structure of the title compound, C16H14, was determined by X-rays:M r =206.29, monoclinic, space groupP21/n,a=5.002(1),b=23.972(5),c=9.505(2) Å,β=102.56(2)°,V c =1112.4 Å3,Z=4,D x =1.23 Mg m−3, MoKα radiation (graphite crystal monochromator, $$\bar \lambda = 0.71069$$ Å),μ(MoKα)=0.75 cm−1,T=290 K. Final conventionalR-factor=0.028,R w =0.030 for 742 unique reflections and 187 variables. The structure was solved usingMultan.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Journal of chemical crystallography 16 (1986), S. 31-39 
    ISSN: 1572-8854
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The X-ray structure of putrescinium hydrogen phosphate dihydrate, $$H_3 \mathop N\limits^ + (CH_2 )_4 \mathop N\limits^ + H_3 \cdot HPO_4^{2 - } \cdot 2H_2 O$$ , has been determined from three-dimensional diffractometer data and refined by full-matrix least-squares techniques. The crystals are monoclinic,P21/c, a=6.5932(4),b=16.776(1),c=9.2375(7) Å,β=95.772(6)°, andZ=4; finalR=0.036 for 1360 observed reflections. The putrescinium dication has the all-trans conformation. The structure contains a three-dimensional network of H bonds in which all available proton do nors are utilized. Each of the $$ - \mathop N\limits^ + H_3$$ groups interacts with three electron-rich atoms arranged in an equilateral triangle, but the character of the individual N-H⋯O bonds is different at opposite sides of the dication. The water molecules are involved in relatively strong H bonds but they do not interact with the cation.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Journal of chemical crystallography 16 (1986), S. 79-89 
    ISSN: 1572-8854
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The crystal structure of glycinium monophenylphosphate [NHsk3/+CH2COOH·C6H5OPO3H− has been determined. The crystals are orthorhohombic:Pbca (NO. 61),a=26.001(3),b=7.423(2),c=11.273(2) Å,Z=8. The structure was solved by direct methods, are refined toR=0.035 for 1499 independent reflections. The crystal structure is stabilized by a three-dimensional network of hydrogen bonds. The phosphate group is involved in five H bonds: three N⋯O and two O⋯O bonds, with the shortest distances 2.745(3) and 2.608(2) Å, respectively. The glycine cation is entirely planar, and a cationo-anionic form of the title compound has also been confirmed in solution byIR studies.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Journal of chemical crystallography 16 (1986), S. 101-106 
    ISSN: 1572-8854
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The structure of the polymeric rhodanine compound , C6H6CuIN2O2S4, was determined by X-rays.M r =456.8, monoclinic, space groupP21/c,a=4.1947(7),b=17.6999(12),c=17.1048(8) Å,β=96.15(1)°,V c =1262.6 Å3,Z=4,D c =2.40Mg m−3, CuKα radiation (graphite crystal monochromator, λ=1.54056 Å),μ(CuKα)=278.9 cms-1,F(000)=872,T=290 K. Final conventionalR-factor=0.029, andR w =0.044 for 2384 unique reflections and 153 variables. The structure was solved using Patterson methods andDirdif, and refined by full-matrix least-squares methods. The compound forms zigzag chains alonga. The copper atom is in trigonal pyramidal coordination, with two sulfur atoms of the thiocarbonyl group and two bridging iodine atoms. The copper-sulfur distances are 2.278(1) and 2.299(1) Å, and the copper-iodine distances are 2.657(1) and 2.814(1) Å.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Journal of chemical crystallography 16 (1986), S. 107-113 
    ISSN: 1572-8854
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The crystal structure of has been determined by X-ray analysis. The monoclinic cell, space groupC2/c witha=12.956(2),b=15.873(2),c=17.437(2) Å,β=105.90(1)° contains eight formula units. The structure was determined using MoKα. automatic diffractometer X-ray data and refined by full-matrix least squares toR=0.039 for 3025 reflections. Two crystallographically independent 3-memylrhodanines are coordinated to copper, and another 3-methylrhodanine is not bonded to copper and is in a disordered position around the crystallographic two-fold axis. In the dimeric structure with bridging chlorine atoms, the copper is in tetrahedral coordination with two chlorine and two sulfur atoms. The copper-copper distance is 2.906(1) Å.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 6
    ISSN: 1572-8854
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract Several alkyl-, aralkyl-, and aryl-substituted diammoniumμ-oxobis[trichloroferrate(III)] salts, of potential interest as model compounds for the study of certain electrophysical and biological processes, are synthesized via the corresponding tetrachloroferrate(III) salts and are characterized by IR and Raman spectroscopy. A structure analysis is performed on the representative bis(benzyldimethylphenylammonium)μ-oxobis(trichloroferrate). The (tetracoordinate) iron atoms in the oxo-bridged dinuclear anion of the salt each possess an ever so slightly distorted tetrahedral ligand environment; the bridge geometry [Fe-O distances 1.757(5) and 1.775(5) Å, Fe-O-Fe angle 147.7(3)°] compares well with that of other salts containing the [Cl3Fe-O-FeCl3]2- anion. Crystallographic Data:a=26.392(5) Å,b=14.015(3) Å,c=9.638(2) Å,β=92.65(2)°, andZ=4; space groupP21/n.R(F)=0.070,R W (F)=0.078 for 4447 observed reflections.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 7
    ISSN: 1572-8854
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The crystal structure of the title compound (C15H19NO4, MW 277.3 amu) was determined by three-dimensional X-ray analysis from diffractometer data. Crystal data are: monoclinic,P21/n,a=9.600(3) Å,b=11.964(6) Å,c=12.802(4) Å,β=101.25(3)°,V=1442.1(16) Å3,Z=4;D x =1.277 Mg m−3;μ(MoKα)=0.10 mm−1. FinalR=0.055 for 1686 observed reflections having 2θ (MoKα)〈50° andI〉2.5 σ(I). The compound is isostructural withN-(2-methoxyacetyl)-N-(2,6-xylyl)-3-amino-1,3-oxazolidin-2-one. The dimethylphenyl ring is almost perpendicular to the amidic plane of the molecule (dihedral angle 81.9°); the butyrolactone ring is in the typical envelope conformation.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 8
    ISSN: 1572-8854
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The crystal structure of the title compound has been determined from diffractometer data and refined with isotropic thermal parameters to finalR w factors ofR=0.058 andR w =0.056. It crystallizes in the orthorhombic space groupp212121 (No. 19), witha=9.706(7),b=18.826(6), andc=25.258(6) Å. The asymmetric unit contains four nitroprusside ions, eight potassium ions, and five water molecules, one of which shows disorder. The infrared spectra of the polycrystalline compound, both normal and with different degrees of deuteration at temperatures ranging from liquid nitrogen to room temperature, were obtained. The vibrational spectra present an unusual number of fundamental and first overtone NO stretching bands and a rich structure in the water bending region, in accordance with the existence of inequivalent nitroprusside ions and water molecules.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 9
    ISSN: 1572-8854
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The crystal and molecular structure of the title compound has been determined by X-ray diffraction methods. It crystallizes in the monoclinic space groupP21/n witha=10.072(2),b=19.434(7),c=19.462(3) Å,β=101.07(1)° andZ=4. The anion has a geometry similar to that observed in other related complexes. The two water molecules are hydrogen bonded to each other and are located at van der Waals distances from nitrogen atoms of neighbor nitroprusside anions.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 10
    ISSN: 1572-8854
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The title compound, Rb2H4M3, is C9H10O12Rb2, triclinic,P¯1,a=7.254(2),b=9.683(2),c=11.514(3) Å,α=107.05(2),/gb=103.81(2), γ=93.89 (2)°. The structure was solved by the heavy-atom method and refined by least-squares techniques to anR factor of 0.043 for 1649 observed reflections. Rb2H4M3 occurs as three independent molecules, two HM− and one H2M with different conformations. Rb2H4M3 has a type B2IR spectrum and has four short, intermolecular and unsymmetrical hydrogen bonds. Rb(1)+ and Rb(2)+ ions are coordinated to nine and ten carboxylate oxygen atoms, respectively. The coordination polyhedron for each Rb+ ion is a distorted tricapped trigonal prism.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 11
    Electronic Resource
    Electronic Resource
    Springer
    Journal of chemical crystallography 16 (1986), S. 181-190 
    ISSN: 1572-8854
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract From an aqueous mixture of 1,2,4,5-benzenetetracarboxylic acid, C6H2(CO2H)4, and KF we grew crystals first of KHF2 then of the title compound. An X-ray crystallographic determination of this compound shows a network of C6H2(CO 2 − )4 units linked through hydrogen bonds to water molecules. This is the first reported structure of a benzenecarboxylate anion. Two carboxylate groups are coplanar with the benzene ring, whereas the other two are perpendicular to it.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 12
    ISSN: 1572-8854
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract Δ1(6)-Dehydrosparteinium monoperchlorate, [C15H25N2]+·ClO 4 − , is orthorhombic∶P212121,a=12.473(2),b=24.292(3),c=10.835(1) Å,V c =3353.7(9) Å3,Z=8,D x =1.32,D m =1.32 g cm−3, μ(CuKα)=20.7 cm−1. The finalR was 0.097 for 2091 observed counter reflections. A partial disorder of the crystal structure has been observed. The two independent perchlorate anions are orientationally disordered, and the peripheral atoms in the cation skeletons have large temperature factors due both to conformational disorder of ringsA and to disordered orientations of the whole cations alike. In ringsA, atoms C(3) and C(4), trans-annular to the immonium bond, are disordered to a different extent in each of the two independent cations. RingsB,C, andD have sofa (distorted towards half-chair), chair, and chair conformations, respectively. The quinolizidinium and quinolizidine moieties have planar and cis configurations, respectively. The title compound was obtained from Δ5-dehydrosparteine, the product of mercuric acetate dehydrogenation of sparteine at room temperature. From13C NMR measurements in2H2O and in DMSO-2H6 it is evident that, in solution, the molecular geometry with chair/chair cis-ring fusion within the quinolizidine moiety is present, as was found in the crystalline state by X-ray analysis.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 13
    Electronic Resource
    Electronic Resource
    Springer
    Journal of chemical crystallography 16 (1986), S. 227-232 
    ISSN: 1572-8854
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The crystals of the title compound (C12H13NO4) are orthorhombic,P212121 witha=8.541(3),b=10.988(1), andc=11.912(1) Å.M r =235.24, mp 427 K,Z=4,D x =1.348 Mg m−3, λ(MoKα=0.71069 Å, μ=0.11 mm−1,T=293 K. The structure was solved by direct methods and refined by full-matrixs least squares to a finalR=0.028 for 1180 observed reflections. The molecules are connected by N-H⋯O (ring carbonyl) intermolecular H⋯O hydrogen bonds of 2.24(2) Å. The 4-oxo-1,3-dioxane ring is in a slightly distorted sofa conformation with a ΔC s 1 asymmetry parameter of 3.6(2)° and the 5-methyl substituent in a pseudoaxial position. The benzoyl oxygen is turned toward the ring, resulting in a close O⋯H(C6) contact of 2.45(2) Å.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 14
    ISSN: 1572-8854
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The crystal structures ofendo- andexo-2,3-dimethoxy-N-[8(phenylmethyl)-8-azabicyclo[3.2.1]oct-2-y1]benzamide hydrochloride have been determined by single-crystal X-ray diffraction techniques, and refined by full-matrix least squares. The endo-compound crystallizes in the monoclinic space groupP21/n witha=12.389(2) Å,b=22.861(3) Å,c=8.019(2) Å,β=93.58(2)°, andZ=4; the exo-compound crystallizes in the monoclinic space groupP21/a witha=26.295(12) Å,b=12.503(4) Å,c=6.667(7) Å,β=97.80(6)°, andZ=4. The calculated densities are 1.22 and 1.27 g cm−3 respectively. FinalR-factors are 0.04 for the endo and 0.05 for the exo-compound. Comparison with a very active analog, the tropapride, suggests that the lack of antipsychotic activity is due to a different orientation of the dimethoxyphenyl or carbonyl group for the exo- and endo-compound, respectively.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 15
    Electronic Resource
    Electronic Resource
    Springer
    Journal of chemical crystallography 16 (1986), S. 217-226 
    ISSN: 1572-8854
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The linear dichroism of the complexes of thymine and cytosine with silver(I) ions dispersed in stretched polyvinylalcohol films was measured in the infrared and in the near ultraviolet regions of the spectrum. The infrared results were helpful in establishing the orientation of the complexes in the films; they also confirmed that the site of silver binding in the case of cytosine involves the carbonyl oxygen. The ultraviolet spectra were deconvoluted into separate electronic transitions and the corresponding transition moments of silver complexes were determined.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 16
    ISSN: 1572-8854
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The crystal and molecular structure of the title compound hexamethyl-perhy-drotetraazapyrene (I) has been determined by X-ray diffraction methods. The compound crystallizes in the triclinic system, space groupP¯1, with cell dimensionsa=7.715(1),b=10.580(2),c=11.926(2) Å, andα=94.37(1)°,β=104.87(1)°, and γ=107.27(1)°. Since the usual direct methods failed, the structure was solved by a semiempirical optimization of packing a model ofI in the unit cell, in terms of the van der Waals' intermolecular energy. The atomic parameters at the most energetically favored position were then refined by least squares against 2396 observed unique reflections, giving a finalR of 0.067. The semiempirical solution used here seems to be limited to particular cases. The molecule ofI consists of two fused piperazine and two fused hexahydropyrimidine rings, having slightly distorted chair conformations. The rings form a foldedcis-10b,10c system of almost exactC 2 point group symmetry. The lone methyl groups in positions 3 and 8 (at the folding) are found to be axially attached. The geminal methyl groups in positions 1 and 6 are situated away from the folding.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 17
    ISSN: 1572-8854
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The crystal stucture of a synthetic monoquaternary azasteroid containig an acetylcholine-like moiety, 17a-(2-acetoxyethyl)-17a-aza-d-homo-5 androsten-3β-yl-acetate methiodide (HS465) (C26H42NO4)+I−, has been determined by the heavy-atom method and refined by full-matrix least squares toR=0.0410 for 2462 reflections, using MoKα radiation (λ=0.7114 Å). The crystals are monoclinic:P21,a=15.244(4),b=9.009(6),c=9.886(3) Å,β=104.26°(3),Z=2. RingsA andC have distorted-chair conformations, ring d-homo is a symmetrical chair, and ringB is a half-chair. The acetoxyethyl side-group appended to N(17a) simulates an acetylcholine-like moiety, and exhibits a conformation similar to that frequently adopted by acetylcholine itself in the presence of heavy anions.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 18
    ISSN: 1572-8854
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The racemic form of the title compound C8H18O4S4 (TTCD), a twelve-membered cyclic disulfide, has been synthesized and studied by X-ray diffraction. TTCD·H2O crystallizes in a multiply twinned pseudo-monoclinicC-centered lattice. For convenience aC-centered triclinic unit cell was chosen of dimensionsa=33.855(3),b=5.534(1),c=14.836(2) Å, α=90.05(1),β=94.76(1), γ=89.22(1)°,V=2769(1) Å3,Z=8, space groupC¯1. The structure, solved by direct methods, was refined to anR of 0.063, using 2769 observed reflections. The two crystallographically independent TTCD molecules in the unit cell have very similar conformations. The distortion from the pseudomonoclinic symmetry is discussed in relation to the hydrogen bonding network.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 19
    Electronic Resource
    Electronic Resource
    Springer
    Journal of chemical crystallography 16 (1986), S. 429-441 
    ISSN: 1572-8854
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract 6-Nitro-trichloromethy1-4-dichloromethylene-1,3-benzdioxin is monoclinic,C2/c,a=12.906(2) Å,b=19.957(2) Å,c=19.992(2) Å,β=99.05(1)°,Z=8. The structure was solved by direct methods, from data collected at room temperature on an Enraf-Nonius CAD4 diffractometer, and refined by least squares to a finalR value of 0.032 using 1838 reflections. The compound exhibits a distorted envelope structure in the dioxin ring, and the trichloromethyl group is in the equatorial position. The angle between the planes each containing a group of three atoms from either end of the double bond of the:C(ring)=CCl2 moiety is 3.8(2)°: a short discussion of deformations found in other compounds which contain:C(ring)=CC12 in light atom structures is given. The benzene ring is slightly puckered and planarity has been retained about the carbon atoms which are common to both rings.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 20
    Electronic Resource
    Electronic Resource
    Springer
    Journal of chemical crystallography 16 (1986), S. 449-458 
    ISSN: 1572-8854
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The crystal structure of a well-defined 5-coordinate complex, dichloro-(2,2′∶6′, 2″-terpyridyl)-tin(II), is described. The stereochemistry of this complex is strongly influenced by the stereochemically active pair of electrons, illustrating clearly the potential donor capabilities of this molecule. The complex (C15H11Cl2N3Sn) crystallizes in the monoclinic space groupC2/c (No. 15) witha=15.770(5),b=9.450(2),c=10.482(2) Å,β=97.53(2)°,Z=4. The finalR value is 0.029 for 1085 observed reflections.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 21
    Electronic Resource
    Electronic Resource
    Springer
    Journal of chemical crystallography 16 (1986), S. 475-482 
    ISSN: 1572-8854
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The title compound is Ru3(μ-Cl)2(CO)8(PPh3)2. Crystal data: formula C44H30O8Cl2P2Ru3;f w =1122.9; monoclinic,P21; cell parameters (at 293 K)a=10.971(2) Å,b=17.066(2) Å,c=11.833(2) Å,β=92.91(1)°,V=2213 Å3,Z=2,ρ calcd=1.68,ρ meas=1.68. Final discrepancy indices areR(F)=0.030,R W (F)=0.036. The structure consists of an open trinuclear unit involving two metal-metal bonds [Ru(1)-Ru(2)=2.845(1) Å, Ru(2)-Ru(3)=2.860(1) Å]. The open edge of the metal framework [Ru(1)⋯Ru(3)=3.254(1) Å] is supported by two symmetric bridging chloride ligands [Cl(1)-Ru(1)=2.461(2) Å; Cl(1)-Ru(3)=2.464(2) Å; Cl(2)-Ru(1)=2.470(2) Å; Cl(2)-Ru(3)=2.472(2) Å]. Both phosphorus ligands are cis to the Cl atoms and trans to the unique ruthenium atom Ru(2). Geometric features of the edge dibridged complex are discussed.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 22
    Electronic Resource
    Electronic Resource
    Springer
    Journal of chemical crystallography 16 (1986), S. 467-474 
    ISSN: 1572-8854
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The crystal structure of 1β-methyl-4α-isopropylcyclohexyl-spiro-5′-hydantoin has been determined by single-crystal X-ray diffraction techniques, and refined by full-matrix least-squares methods. The molecule C12H20N2O2·H2O crystallizes with one molecule of water in the orthorombicP212121 space group, witha=15.869(5),b=14.043(4),c=6.240(2) Å, andZ=4; the finalR factor was 0.032. The X-ray results showed that both substituents (methyl and isopropyl) in the cyclohexyl ring are in thetrans configuration. The configuration of the molecule is in agreement with suggestions of organic chemists.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 23
    ISSN: 1572-8854
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract C34H43O16N·CH3OH·H2O is monoclinic,C 2 2 -P21. Unit cell dimensions at 293 K area=9.159(3),b=17.017(5),c=13.675(5) Å,β=109.49(2)°,V=2009(1) Å3,D c =1.28 g cm−3, andZ=2. The structure has been determined from single-crystal data collected with a four-circle diffractometer and refined from 2367 reflections down toR=0.064 andωR=0.082. The structural features determined from chemical and spectroscopic studies are confirmed and extended. The absolute configuration was determined by comparison with known absolute stereochemistry of the bromoacetylneoevonine monohydrate. The acanthothamine molecule is an evonine and neoevonine analogue showing an epimeric configuration at C(17) of the evoninic acid residue. The A and B rings adopt chair conformations. The C ring has a half-chair conformation. The crystal structure is stabilized by a three-dimensional network of hydrogen bonds and a number of intramolecular C-H⋯O and C-H⋯N interactions.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 24
    ISSN: 1572-8854
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The crystal structure of the 2∶1 channel complex of desoxycholic acid and ethyl acetate has been investigated at 298 and 163 K. The space group isP212121(No. 19) with four molecules of desoxycholic acid in the unit cell. The ethyl acetate molecules are enclathrated along the 21 axes parallel toc and exhibit differing degrees of disorder in the low- and room-temperature structures. Differences in the disorder imply that it is both statistical and dynamic in nature. Our best model for each structure yieldsR=0.064 [R w =0.058,w=(σ 2 F)−1] andR=0.068 [R w =0.064,w=(σ 2 F) −1 ] for the ambient- and low-temperature studies respectively.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 25
    Electronic Resource
    Electronic Resource
    Springer
    Journal of chemical crystallography 16 (1986), S. 577-584 
    ISSN: 1572-8854
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract Reaction of [Rh(CO)2Cl]2 with Bu t SLi followed by refluxing with PPh3 yields [Rh(μ-SBu t )(CO)(PPh3)]2(1). The structure of (1) has been determined by X-ray crystallography. Empirical formula: Rh2P2S2C46H48O2,M=964.78, triclinic, P¯1,a=11.408(9),b=13.241(8),c=15.830(3) Å,α=93.67(3),β=93.12(5),γ=110.8(6)°,Z=2,D calc=1.44 g cm−3,R=0.048 (R w =0.062) for 5939 observed reflections. In the solid state, the compound exhibitscis geometry with respect to the phosphine and CO ligands. The geometry about the two metals is essentially square planar, with a dihedral angle of 103.2°, and a “butterfly angle” of 102.3°. Compound (1) is stereochemically rigid on the NMR time scale from −80 to +80°C.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 26
    Electronic Resource
    Electronic Resource
    Springer
    Journal of chemical crystallography 16 (1986), S. 597-606 
    ISSN: 1572-8854
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The crystal structure ofN-(2-morpholinoethyl)-2-oximato-1-phenylpropan-1-iminechloropalladium(II), [Pd(L)Cl], has been determined from X-ray data collected by counter methods. The compound crystallizes in the orthorhombic space groupPna21 with four molecules per unit cell, the dimensions of which area=9.602(2),b=8.150(1),c=21.181(4) Å. Full matrix least-squares refinement gave a finalR value of 0.042 for the 3218 independent observed reflections. The oxime ligand is deprotonated and is acting as a tridentate ligand coordinating to the palladium through the oxime nitrogen, the imine nitrogen, and the tertiary amine nitrogen of the morpholine moiety. To complete four-coordination about the palladium atom, a chloride ion is also attached to the central metal atom. The donor atoms plus the palladium atom are planar.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 27
    Electronic Resource
    Electronic Resource
    Springer
    Journal of chemical crystallography 16 (1986), S. 607-616 
    ISSN: 1572-8854
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract 6-nitro-2-trichloromethyl-1,3-benzdioxin-4-one is monoclinic,P21/n;a=5.969(2),b=11.646(1),c=16.953(1) Å;β=98.03(2)°;Z=4. The structure was solved by direct methods, from data collected at room temperature on an Enraf-Nonius CAD4 diffractometer, and refined by least squares to a finalR value of 0.030 using 1530 reflections. The heterocyclic ring is a distorted half-boat and is substituted equatorially by a trichloromethyl group. Dihedral angles are (a) 4.87(7)° between the mean plane of the aromatic ring and the plane containing the two carbon atoms common to both rings plus the two atoms bonded to these, and (b) 16.8(2)° between the carbonyl group and the aromatic ring. The conformation is discussed with reference to the two previously reported X-ray structures of 1,3-benzdioxin-4-ones and to two isocoumarins.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 28
    ISSN: 1572-8854
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The crystal structures of the gallium(II) complexes (Ph3PH)2Ga2X6 (X=Cl, Br, I) have been determined. The anions are Ga-Ga bonded species, with staggered ethane conformations; the length of the Ga-Ga bond increases only slightly along the series I〉Br〉Cl, although there are significant changes in the Ga-Ga stretching force constant in the order Cl〉Br〉I. The vibrational spectra and derived force constants are discussed, as is the splitting of thev(P-H) [andv(P-D)] mode of the cation which is related to disorder in the structure of the neighboring Ga2X6 2− anions.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 29
    Electronic Resource
    Electronic Resource
    Springer
    Journal of chemical crystallography 16 (1986), S. 1-1 
    ISSN: 1572-8854
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 30
    Electronic Resource
    Electronic Resource
    Springer
    Journal of chemical crystallography 16 (1986), S. 3-21 
    ISSN: 1572-8854
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The electronic and magnetic circular dichroism spectra of thin layers of Cu1 and AgI halides have beem measured at low (~ 10 K) temperatures. The mcd spectra show clearA-terms which, in the case of the silver halides and for one band of cuprous iodide, have unexpected negative signs. A qualitative theoretical interpretation of these signs has been attempted by considering halogen-p and metals/d atomic orbital mixing within the framework of a simple, tight-binding model. Reasonable agreement of theory with experiment has been achieved for the positive copper halideA-terms, but it has not proved possible to obtain by calculation the experimentally observed negativeA-term sign of the silver salts and cuprous iodide.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 31
    ISSN: 1572-8854
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The title mixed-ligand copper(II) complex has been synthesized and its crystal structure at room temperature solved. The crystals are monoclinic:P21/c,a=12.004(3),b=19.402(5),c=14.192(4) Å,β=108.80(3)°,Z=4. The structure was solved by direct methods, and refined to anR value of 0.041 for 4457 nonzero independent reflections. The crystal structure consists of discrete [Cu(bipy) (MPhP)] units, noncoordinated MPhPH2, and H2O molecules. Each [Cu(bipy)2(MPhP)] unit involves a five coordinate CuN4O chromophore with a distorted trigonal-bipyramidal stereochemistry. The phosphate groups are linked together by short hydrogen bonds of (P)-O-H-⋯-O-P type.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 32
    Electronic Resource
    Electronic Resource
    Springer
    Journal of chemical crystallography 16 (1986), S. 71-78 
    ISSN: 1572-8854
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The structure of the title compound, C10H13ClO2S, was determined by X-rays:M r =232.72, monoclinic, space groupP21,a=6.4902(6),b=12.022(1),c=14.130(3) Å,β=103.11(1)°,V c =1073.7 Å3,Z=4,D x =1.44 Mg m−3. MoKα radiation (graphite crystal monochromator, λ=0.71069 Å),μ(MoKα)=4.9 cm−1,F(000)=342,T=293 K. Final conventionalR-factor=0.035 for 2221 observed reflections and 252 variables. The structure was solved usingDirdif. The absolute configuration of the structure is reported. The two independent molecules differ primarily in the orientation of the sulfine group with respect to the camphor moiety.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 33
    ISSN: 1572-8854
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The structure of the title compound (perhydroisoindole) was determined by X-rays, using CuKα radiation (graphite-crystal monochromator, λ=1.54184 Å):T=290 K, C16H17NO4,M r =287.31, orthorhombic, space groupPbcn,a=18.732(1),b=10.663(1),c=14.074(1) 0A,V c =2811.2 Å3,Z=8,D x =1.361 Mg m−3 and μ(CuKα)=8.19 cm−1. The final conventionalR-factor=0.036, (R w =0.046) for 1951 unique reflections and 241 variables. The structure was solved usingMultan. The six-membered ring of the molecule is in the chair configuration. The molecules are connected by hydrogen bonds.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 34
    ISSN: 1572-8854
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 35
    Electronic Resource
    Electronic Resource
    Springer
    Journal of chemical crystallography 16 (1986), S. 347-416 
    ISSN: 1572-8854
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The crystal structure analyses along with other physical measurements of 1,2-dithiolene complexes have made it possible to derive many interesting properties of these complexes. This review focuses attention mainly on the structural aspects and physical properties of 1,2-dithiolene complexes of transition metals. Brief mention of the structural aspects of complexes such as 1,2-dithiooxalate complexes and dithiosquarate complexes is included. In addition, structural aspects of a few available non-transition metal complexes are briefly discussed. The idea that bulky counterions lead to nonplanar structures has been disproved by the nonplanarity observed in the anion of [(CH3)4N]2[Cu(S2C2(CN)2)2]. The analysis of the significance of overall charge shows that the ionic effect is prevalent in [M(dithiolene)2] n− systems. Crystal structure analyses of some bis(dithiolene) complexes of transition metals along with conductivity measurements have shown that it is possible to correlate the electrical behavior to the crystal structure, provided the sample crystals are good. The two-dimensional network structure of the mixed valence compound, [(n-C4H9)4N]0.29 [Ni(S2C2S2CS)2], proposes the possibility of reaching the ultimate goal (superconductivity) with this type of compounds.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 36
    Electronic Resource
    Electronic Resource
    Springer
    Journal of chemical crystallography 16 (1986), S. 443-443 
    ISSN: 1572-8854
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 37
    ISSN: 1572-8854
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The structure of the title compound C21H22O3, was determined by X-rays.Minr=322.4, monoclinic, space groupP21/a,a=11.960(2),b=14.275(3),c=10.858(2) Å,β=103.20(2)°,V c =1804.8 Å3,Z=4,D x =1.223 Mg m−3. CuKα radiation (graphite crystal monochromator,λ=1.54184 Å),μ(CuKα)=6.53 cm−1,F(000)=688, T=290 K. Final conventionalR factor=0.050,R w =0.069 for 1679 unique reflections and 284 variables. The structure was solved usingMultan.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 38
    Electronic Resource
    Electronic Resource
    Springer
    Journal of chemical crystallography 16 (1986), S. 495-505 
    ISSN: 1572-8854
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract Ethanoldiphenylthallium(III) dithizonate, (C27H27N4SOTl,M r =659.97) is monoclinic,P21/c,a=9.776(3),b=16.761(4),c=16.750(5) Å,β=95.72(2)°,Z=4. The structure was solved by the heavy atom method, from data collected at room temperature on an Enraf-Nonius CAD4 diffractometer. The data were corrected for absorption, and the refinement, using 2329 reflections, by least squares with anisotropic temperature factors for the thallium and sulfur atoms, converged atR=0.046. The complex is monomeric and comprises a distorted trigonal bipyramid with an almost planar bidentate dithizone residue coordinating through sulfur and nitrogen. A molecule of ethanol is coordinated axially as is the nitrogen atom of the dithizone, while the carbon atoms of the phenyl rings attached to the metal and the sulfur atom of the ligand are equatorial. Tl-S and Tl-N distances are 2.648(4) and 2.62(1) Å respectively while Tl-O is 2.64(1) and Tl-C are 2.12(1) and 2.14(1) Å.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 39
    ISSN: 1572-8854
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The synthesis and crystal and molecular structure of the title compound is reported. It belongs to the monoclinic space groupP21/a witha=29.3990 (20),b=7.1150 (6),c=8.3140 (9) Å,β=98.060 (9)° andZ=4. The structure was refined to a finalR of 3.52% (R w %=3.82) for 2354 observed reflections. Vibrational spectra have been recorded and discussed.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 40
    ISSN: 1572-8854
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The title compound crystallizes in the orthorhombic space groupp212121∶a=8.674(1),b=8.944(1),c=23.255(4) Å,Z=4. The structure was solved by direct methods, and refined by full-matrix least squares toR=0.047 for 1472 observed reflections. Determination of the absolute configuration [S at C(9)] enabled a discrepancy in the literature concerning the stereochemical outcome of the reaction between SOCl2 and quinine to be resolved.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 41
    ISSN: 1572-8854
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract Spectroscopic analysis of eight copper(II) complexes of Schiff bases derived from taurine and eight different salicylaldehydes and naphthaldehydes are reported. X-ray structural analysis of the copper(II) complex of the 5-NO2-sali-cylaldehyde imine of taurine (5-NO2-salicylaldimine ethylene sulfonic acid) as the tetran-butylammonium salt [Cu(C9H8N2O6S)2]2−2[(C4H9)4N]+ (CUTAU-TBA) has been carried out. The space group isP¯1, witha=8.761(4),b=10.410(3),c=16.528(4) Å,α=77.85(3),β=86.53(4), γ=79.15(3)°, andZ=1. The structure was solved by the heavy-atom method and refined by least-squares techniques to anR factor of 0.068 for 2807 observed reflections. The CUTAU cation is centrosymmetric, with the Cu atom sitting on a crystal-lographic centre of symmetry. The copper atom has a square-planar environment, coordinated by the potentially tridentate Schiff base only through the imino nitrogen and the phenolate oxygen with the deprotonated sulfonic group directed away from the coordination sphere of the Cu(II).
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 42
    Electronic Resource
    Electronic Resource
    Springer
    Journal of chemical crystallography 16 (1986), S. 159-167 
    ISSN: 1572-8854
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The crystal and molecular structure of the title compound, C20H8N4S12Ni, is reported. Crystals are triclinic, space groupP¯1 (No. 2) withz=1 in a cell of dimensionsa=8;482(2),b=7.950(2),c=9.976(2) Å,α=95.64(2),β=98.60(2), and γ=87.65(2)°. The structure was solved by Fourier methods and refined by the method of least squares toR=0.033 for 2027 unique reflections. The Ni atom has an approximate square-planar configuration with Ni-S(1)=2.179(1), Ni-S(2)=2.175(1) Å, and the S(1)-Ni-S(2) bite angle of 91.89(4)°. The anions and the cations form a mixed stack (DAD-DAD-⋯) along the diagonal of theab plane, showing the possibility of unusual electrical behavior.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 43
    ISSN: 1572-8854
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 44
    Electronic Resource
    Electronic Resource
    Springer
    Journal of chemical crystallography 16 (1986), S. 681-685 
    ISSN: 1572-8854
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The title compound, [(CH3)4N] [VO(l-His)(NCS)2]·H2O, has been prepared by the reaction of [(CH3)4N]4[VO(NCS)4]2·H2O with histidine in aqueous solution. The crystal is orthorhombic, space groupP212121 witha=9.839(6),b=11.835(5),c=17.366(6) Å,Z=4. The structure was solved by direct methods and refined by full-matrix least-squares to anR of 0.073 for 1067 reflections. In the complex anion VO2+ was coordinated by two thiocyanate groups and al-histidine which functions as a tridentate chelate.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 45
    Electronic Resource
    Electronic Resource
    Springer
    Journal of chemical crystallography 16 (1986), S. 629-637 
    ISSN: 1572-8854
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract Crystals of 5-ethyl,5-(1′,3′-dimethylbut-2′-enyl) barbituric acid (13M2B), mp 139°C, are triclinic, space groupP¯1,Z=2, witha=8.134(2),b=9.210(2),c=9.265(2),α=91.91(1),β=105.66(2), and γ=96.83(2)°. The structure was solved by direct methods, and refined by least-squares procedures to giveR=0.065 for 2056 observed diffraction data. The 5-ethyl and the 1′,3′-dimethylbut-2′-enyl groups are both directed over the plane of the barbiturate ring. It is suggested that the conformation of the latter is stabilized byπ interactions between the isobutenyl group and the delocalizedπ system of the ring.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 46
    ISSN: 1572-8854
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract A 1∶1 crystalline adduct of hexamethylenetetramine with phenylacetic acid, (CH2)6N4·C6H5CH2COOH, has been isolated and characterized by X-ray analysis. The compound crystallizes in space groupI¯4 (No. 82), witha=20.576(3),c=6.907(1) Å, andZ=8. The crystal structure is composed of a packing of discrete molecular aggregates corresponding to the stoichiometric formula, each being consolidated by a N⋯H-O hydrogen bond of length 2.643(8) Å, which has no significant effect on the regular geometry of the (CH2)6N4 cage system. The C-CO2 and phenyl groups in the C6H5CH2COOH moiety make a dihedral angle of 74(1)°. The structure has been refined toR=0.071 for 1350 observed (∥F o ∥〉2σ∥F o ∥) MoKα data.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 47
    ISSN: 1572-8854
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The structure of the title compound, C12H16O3, was determined by X-rays.M r =208.26, triclinic, space groupP¯1,a=7.802(2),b=8.449(2),c=9.069(1) Å,α=90.79(1)°,β=105.57(1)°, γ=106.07(1)°,Z=2,D x =1.26 Mg m−3; MoKα radiation (graphite crystal monochromator, λ=0.71069 Å),μ(MoKα)=0.96 cm−1,T=290 K. Final conventionalR-factor=0.046,R w =0.067 for 3009 “observed” reflections and 184 variables. The structure was solved using Patterson methods andDirdif, and the resulting all cis-endo configuration of the alcohol group on C(3) and the ethoxy group on C(5) shows that the stereochemistry of the metal-mediated addition reaction involved is solely determined by steric factors.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 48
    ISSN: 1572-8854
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract Reaction of dmpe (bis(1,2-dimethylphosphino)ethane) with CrCl3(THF)3 gives deep red crystalline Cr2(dmpe)3(Cl)6·2CH2Cl2 in 85% yield. The X-ray crystal structure of the title compound shows a bridgingtrans dmpe ligand between two isolated Cr(III) centers. Each Cr(III) atom bears a chelating dmpe group and three Cl atoms in a roughly octahedral geometry. Crystal data: C20H48Cl10Cr2P6,M=933.0, monoclinic,P21/n,a=9.221(3),b=10.587(2),c=21.868(2) Å,β=98.962(3)°,D calc=1.47 g cm−3,Z=2. FinalR=0.054,R w =0.063 from 1964 observed reflections (I〉3σ(I)), 3489 measured.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 49
    Electronic Resource
    Electronic Resource
    Springer
    Journal of chemical crystallography 16 (1986), S. 687-694 
    ISSN: 1572-8854
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The formula of the title compound is C22H30N2,M T =322.5; monoclinic:P21,a=7.569(3),b=9.381(1),c=13.684(4) Å,β=105.81(2)°,Z=2,V c =933.7 Å3,D x =1.15 g cm−3,μ(CuKα)=5.1 cm−1. The sparteine skeleton (bis-quinolizidine system) has atrans-trans configuration. RingA has an intermediate form between the sofa and half-chair conformations, ringsB andD-chair, and ringC-boat conformations, respectively. The double bond C(2)=C(3) is equal to 1.343(9) Å. The phenyl ring is planar and makes an angle with a plane through N(1), C(2), C(3), and C(4) atoms equal to 43.9°.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 50
    ISSN: 1572-8854
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract cis-Diaquabis(2,2′-bipyridyl)chromium(III) nitrate crystallizes in the mono-clinic system, space groupP21/c, witha=16.102(6),b=10.792(5),c=15.076(6) Å,β=112.90(5)°, andZ=4. The saltlike structure was determined from X-ray crystallography and refined toR=7.5% for 3342 observed reflections. The Cr atom is octahedrally surrounded by twocis water molecules and by two chelated 2,2′-bypiridyl ligands forming two nearly orthogonal planes. Selected bond distances are: Cr-O, 2.00(1) and 1.98(1) Å, Cr-N, 2.04 Å (mean).
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 51
    Electronic Resource
    Electronic Resource
    Springer
    Journal of chemical crystallography 16 (1986), S. 721-727 
    ISSN: 1572-8854
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The crystal and molecular structure of the title compound is reported. The crystals are monoclinic,P21/c,a=9.578 (1),b=15.339 (2),c=7.674(1) Å,β=109.61(1)°. The structure was solved by Patterson and Fourier methods, and refined by full-matrix least squares toR=0.0542,R w =0.0575 for 645 unique reflections. Coordination around the mercury is intermediate between tetrahedral and trigonal pyramidal with two terminal and two bridging bonds. Vibrational spectra were also redetermined and discussed.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 52
    Electronic Resource
    Electronic Resource
    Springer
    Journal of chemical crystallography 16 (1986), S. 729-738 
    ISSN: 1572-8854
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The X-ray crystal structures of three halo(tetramethylethylenediamine)copper(I) complexes have been determined. (TMED)2Cu+CuCl 2 − (I) crystallizes in monoclinic space groupP21/n with lattice constantsa=9.332(9),b=15.126(7),c=14.49(1) Å,β=96.95(7)°. (TMEDCuBr)2 (II) crystallizes in monoclinic space groupP21/c with lattice constantsa=12.064(5),b=11.888(6),c=15.841(6) Å,β=113.97(3)°. (TMED CuI)2 (III) crystallizes in monoclinic space groupP21/c with lattice constantsa=12.401(6),b=12.159(6),c=15.412(9) Å,β=109.12(4)°. Compound (I) is a molecule exhibiting two discrete environments for copper(I). The cation is a pseudotetrahedral monomer and the anion a linear monomer. Both (II) and (III) are dimers with asymmetrically bridging bromine and iodine atoms, respectively. Distortions from tetrahedral geometry are observed about the copper atoms in (II) and (III).
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 53
    Electronic Resource
    Electronic Resource
    Springer
    Journal of chemical crystallography 16 (1986), S. 747-754 
    ISSN: 1572-8854
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The structure of the title compound, C13H14N2O3, was determined by X-rays.M r =246.26, orthorhombic, space group P212121,a=6.809(1),b=10.041(2),c=17.571(2) Å,V c =1196.5 Å3,Z=4,D x =1.36 Mg m−3. MoKα radiation (graphite crystal monochromator, λ=0.71069 Å),μ(MoKα)=1.06 cm−1,T=290 K. Final conventionalR-factor=0.037,R w =0.039 for 1377 unique reflections and 205 variables. The structure was solved usingMultan. The synthesis of the title compound involved a ring-closing reaction with an optically pureN-α-halophenylacetyl-(S)-proline methyl ester of known absolute configuration. From this the absolute configuration of the title compound could be determined, and it could be proved that the reaction proceeds according to anS N 2 process.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 54
    Electronic Resource
    Electronic Resource
    Springer
    Journal of chemical crystallography 16 (1986), S. 283-294 
    ISSN: 1572-8854
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The boat conformation ofα-parachloral [2,4,6-tris(trichloromethyl)-1,3,5-trioxane] has been confirmed by X-ray crystallography. Evidence for a chair conformation based upon calculations of dipole moments has been shown to be unreliable, but the possibility of this existing in solution has been studied by1H and13C NMR spectroscopy. The X-ray structures of bothα- andβ-parachloral have been redetermined.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 55
    Electronic Resource
    Electronic Resource
    Springer
    Journal of chemical crystallography 16 (1986), S. 301-301 
    ISSN: 1572-8854
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 56
    Electronic Resource
    Electronic Resource
    Springer
    Journal of chemical crystallography 16 (1986), S. 303-303 
    ISSN: 1572-8854
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 57
    ISSN: 1572-8854
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract Δ1(6)-Dehydrosparteinium diperchlorate, [C15H26N2]2+·2ClO 4 − , is tetragonal; space groupP43,a=9.368(1),c=21.719(3) Å,Z=4,V c =1906.1(5) Å3,D x =1.51g cm−3,μ(CuKα)=35.0 cm−1. The finalR=0.055 for 1259 independent reflections. Atoms C(3) and C(4), which are trans-annular to the immonium bond in ringA, are disordered, as was observed for other bis-quinolizidine immonium salts. RingsB, C, andD have sofa, chair and chair conformations, respectively. The quinolizidinium and quinolizidine moieties have planar and cis configurations. The title compound was obtained by mercuric acetate dehydrogenation of sparteine to Δ5-dehydrosparteine and protonation of the latter with methanolic solution of perchloric acid to pH=2.0. From13C NMR measurements in DMSO-2H6 and in2H2O it is evident that in solution the chair/chair cis-ring fusion is present within the protonated quinolizidine moiety-identical to that found in the crystalline state by X-ray analysis.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 58
    ISSN: 1572-8854
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The structure of the title compound (C10H8N8Br2Zn·1/2H2O), prepared from the ligand and zinc bromide in ethanol, was solved by X-rays analysis.M r =465.18, monoclinic, space groupP21/n,a=21.2376(11),b=7.1339(6),c=20.0469(11) Å,β=98.583(4)°,V c =3003.2 Å3,Z=8,D x =2.057 Mg m−3,μ(Cu Kα)=87 cm−1,F(000)=1832,T=300 K. Final conventionalR-factor=0.034 andR w =0.036 for 4255 unique reflections withI〉 3σ(I) out of 5685 measurements. The structure was solved using automatic programsPatsys andDirdif. The two independent molecules are almost identical. The Zn atom is tetrahedrally coordinated by two Br atoms and two N(3) atoms of the triazolopyrimidine ligands. The planar triazolopyrimidine ligands make angles of 94.0 and 57.5° (moleculeA) with the ZnBr2 plane (98.6 and 57.0° for moleculeB). The water molecule is involved in hydrogen bonds with bromine only.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 59
    ISSN: 1572-8854
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The structure of the the title compound, C30H29NO, was determined by X-rays.M r =419.57, triclinic, space groupP1,a=5.8922(12),b=8.5855(11),c=12.2216(20) Å,α=78.145(12)°,β=79.181(15)°, γ=76.108(14)°,V c =581.1(1) Å3,Z=1,D x =1.199 Mg m−3. CuKα radiation (graphite crystal monochromator, λ=1.54184 Å),μ(CuKα)=5.17 cm−1,T=290K. Final conventionalR-factor=0.039,R w =0.042 for 2795 observed reflections and 377 variables. The structure was solved usingMultan andDirdif. With a view to determining the conformational preference of the piperidine ring when it is highly sustituted with a bulky group like the phenyl group, the present X-ray investigation was undertaken.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 60
    Electronic Resource
    Electronic Resource
    Springer
    Journal of chemical crystallography 16 (1986), S. 841-850 
    ISSN: 1572-8854
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract 6,8-dinitro-2,4-bis(trichloromethyl)-1,3-benzdioxin is monoclinic,P21/c,Z=4,a=12.348(2),b=11.575(3),c=12.183(4) Å,β=107.48(2)°. The structure was solved by direct methods, from data collected at room temperature on an Enraf-Nonius CAD4 diffractometer, and refined by least-squares to a finalR value of 0.032 using 2192 reflections. The heterocyclic ring is an envelope structure, the dihedral angle between the plane of the aromatic ring and that containing five of the atoms of the heterocycle being 4.98(6)°. One -CCl3 group is pseudoequatorial while the (Ar-C)CCl3 group is pseudoaxial. C-Ceq 1.526(3) Å; C-Cax 1.537(3) Å; C-C(Cax)-O 112.4(2)°; C(Cax)-O-C(Ceq) 115.2(2)°.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 61
    ISSN: 1572-8854
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract 2,6-bis (trichloromethyl)-4-dichloromethylene-1-oxa-3,5-dithian is triclinic,P¯1,a=10.125(3),b=10.294(3),c=14.631(10) Å,α=92.84(5),β=96.51(5), γ=96.18(2)°,V=1503 Å3,Z=4. The structure was solved by direct methods, from data collected at room temperature on an Enraf-Nonius CAD4 diffractometer, and refined by least squares to a finalR value of 0.035 using 3961 reflections. The conformation of the molecules is twist-boat, one molecule being almost symmetrically twisted about the O-C(Cl2) direction. The range of endocyclic O-C-S angles is 111.8(3) to 115.1(3)° and data are given which support the possibility of there being a correlation between the endocyclic O-C(X)-S angle, the C-O-C(X)-C(Cl3) torsion angle, and the C-S-C(X)-C(Cl3) torsion angle. The -CCl3 groups are in pseudoequatorial positions. Average bond lengths (Å) for the two molecules are C-O 1.405, C(sp 3)-S 1.822, C(sp 2)-S 1.759, C-Ceq 1.529 and average endocyclic angles (°) are O 117.3, C (sp 3) 113.5, S 97.4, C(sp 2) 119.3, the esds on the individual bond lengths and angles being in the ranges of 0.003–0.004 Å and 0.2–0.4° respectively.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 62
    Electronic Resource
    Electronic Resource
    Springer
    Journal of chemical crystallography 16 (1986), S. 907-912 
    ISSN: 1572-8854
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract Crystals of (p-PhOC6H4)2TeCl2 are monoclinic with space groupP21/c,a=8.063(2),b=21.695(5),c=12.622(2) Å,β=101.57(2)°, andZ=4. The structure refined to a finalR value of 0.055 for 2135 unique observed reflections. The compound adopts a primary four-coordinate geometry based on a distorted trigonal bipyramid with an equatorial lone pair. A weak Te-Cl secondary interaction links the molecules into centrosymmetric dimers.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 63
    ISSN: 1572-8854
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The structure of the title compound, C18H20N2O5, was determined by X-rays atT=290 K.M r =344.366, orthprombic, space groupP212121,a=9.350(5),b=11.954(2),c=15.455(3) Å,V c =1727.3 Å3,Z=4,D c =1.324 Mg m−3. CuKα. radiation (graphite crystal monochromator, λ=1.54178 Å),μ(CuKα)=7.70 cm−1. Final conventionalR-factor=0.065,R w =0.086 for 2887 “observed” reflections and 265 variables. The structure was solved usingMultan.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 64
    ISSN: 1572-8854
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The structure of the title compound, C10H9BrO2, was determined by X-rays.M r =241.08, triclinic, space groupP¯1,a=5.800(1),b=6.441(1),c=12.030(1) Å,α=92.90(1)°,β=95.65(2)°, γ=95.69(2)°,V c =444.2 Å3,Z=2,D x =1.80 Mg m−3, MoKα radiation (graphite crystal monochromator, λ=0.71069 Å),μ(MoKα)=48.58 cm−1,T=290 K. Final conventionalR-factor=0.037,R w =0.044 for 1863 “observed” reflections and 145 variables. The structure was solved usingMultan andDirdif. The results show that the 5-bromo substituent has a marked effect on the geometry of the homocubane skeleton. Its presence prevents a complete release of geometrical strain and induces a shortening of the bond distances to the apex carbon atom.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 65
    Electronic Resource
    Electronic Resource
    Springer
    Journal of chemical crystallography 16 (1986), S. 647-656 
    ISSN: 1572-8854
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The crystal structure of the [AuCl4]−-stabilized hydronium ion diadduct of 4-picolineN-oxide has been determined using 1388 reflections collected on a CAD4 diffractometer. The structure was refined to anR value of 0.46. Two 4-picolineN-oxide molecules form a short hydrogen-bonded hydronium ion diadduct [H(4-picNO)2]+ with an O⋯O distance of 2.442(4) Å. The planar [AuCl4]− acts as a counter anion. Due to the nonbonding packing interactions, the Au(III) ion appears to be in an unusual six-coordinate distorted octahedral environment in the solid state. The changes in the N=O distance, the shifts in the infrared absorptions, and the downfield NMR chemical shifts for the bridged protons are explained in terms of inductive effects of the substituents on the pyridineN-oxide ring.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 66
    Electronic Resource
    Electronic Resource
    Springer
    Journal of chemical crystallography 16 (1986), S. 713-720 
    ISSN: 1572-8854
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The structure and absolute configuration of brianthein X, C24O9H31Cl, was determined by single-crystal X-ray diffraction. Space groupP61,a=10.539(1),c=36.397(6) Å. The structure was solved from 2455 diffractometer data taken at −135°C, and refined to anR value of 0.037. The structure and stereochemistry is compared with similar compounds fromBriareum species.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 67
    Electronic Resource
    Electronic Resource
    Springer
    Journal of chemical crystallography 16 (1986), S. 703-711 
    ISSN: 1572-8854
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract 6-Nitro-2,4-bis(trichloromethyl)-1,3-benzdioxin is triclinic,P¯1;a=6.604(2),b=7.678(6),c=15.201(4) Å; α=91.57(5),β=99.39(2), γ=90.50(5)°;Z=2. The structure was solved by direct methods from data collected at room temperature on an Enraf-Nonius CAD4 diffractometer and refined by least squares to a finalR value of 0.035 using 2092 reflections. The molecule consists of a heterocycle in a distorted screw boat conformation fused to a significantly nonplanar aromatic ring. One-CCl3 group is pseudoequatorial while the (Ar-C)CCl3 group is pseudoaxial. The CAr-C-O-C side of the ring is much flatter than the CAr-CAr-O-C side, the distortion being caused by the necessity of the-CaxCl3 group to bend away from the heterocycle. C-Ceq 1.532(4) Å; C-Cax 1.550(4) Å; C-C(Cax)-O 113.0(3)°; C(Cax)-O-C(Ceq) 115.5(2)°.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 68
    ISSN: 1572-8854
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The structure of the title compound, C14H16NO3Br, was determined by X-rays.M r =326.19, tetragonal, space groupP43,a=9.2030(6),c=16.9979(9) Å,V c =1439.6 Å3,Z=4,D x =1.51 Mg m−3. CuKα radiation (graphite crystal monochromator, λ=1.54184 Å),μ(CuKα)=39.49 cm−1,T=290 K. Final conventionalR-factor=0.039,R w =0.052 for 2566 unique reflections and 204 variables. The structure was solved usingMultan andDirdif. The presence of bromine in the structure enabled the unambiguous assignment of the space group. The synthesis to prepare the title compound yields only one stereoisomer with theS-configuration, caused by the chirality of theS-proline methyl ester.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 69
    ISSN: 1572-8854
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract [W3(O)O3Cl3(C5H5N)6]2W6O19·6C5H5N, the side product of the reaction between WCl4(C5H5N)2 and pyridine, crystallizes in the rhombohedral space groupR¯3 (No. 148), witha=14.044(1) Å,α=87.70(1)°, andZ=1. The structure was solved by the heavy-atom method, and refined to the unweighted and weighted residuals of 0.068 and 0.055, respectively. The tungsten atoms define an equilateral triangle with a capping and three bridging oxygen atoms. Two pyridines in thecis position and a chlorine atom form, together with the oxygens, a distorted octahedron around the tungsten atoms; three octahedra are connected through common edges. Important bond lengths are: W-W (single bond) 2.532(1), W-O (tricapped) 2.09(1), W-O (bridging) 1.92(1) and 1.94(1), W-C1 2.424(5), and W-N (pyridine) 2.23(1) and 2.26(1) Å. In W6O 19 2− , six WO6 octahedra have one common central oxygen, twelve bridging and six terminal oxygen atoms. Corresponding W-O bond lengths are: 2.323(1) (central oxygen), from 1.90 to 1.94(1) (bridging oxygens), and 1.70(2) Å (terminal oxygens). Lattice pyridine molecules have no important contacts with either anion or cation.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 70
    Electronic Resource
    Electronic Resource
    Springer
    Journal of chemical crystallography 16 (1986), S. 797-798 
    ISSN: 1572-8854
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 71
    Electronic Resource
    Electronic Resource
    Springer
    Journal of chemical crystallography 16 (1986), S. 785-795 
    ISSN: 1572-8854
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The crystal structure of the title compound, C26H32N2O2, has been determined by three-dimensional X-ray diffraction methods. The crystals are monoclinic:P21/c,a=13.338(9),b=17.364(12),c=10.320(8) Å,β=99.84(6)°,Z=4. The structure was solved by direct methods, and refined to anR value of 0.069 for 2258 observed reflections. Bond lengths and angles have normal values. The isoxazoline rings are in an envelope conformation and their best planes are twisted by 77.8°; the mesityl groups are inclined to the heterocyclic rings (63.3 and 69.0°). No significant conjugation is evident within the molecule.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 72
    ISSN: 1572-8854
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 73
    ISSN: 1572-8854
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract Δ1(6),11(16)-Didehydrosparteinium diperchlorate,M r =431.27, (C15H24N2)2+ ·2C1O 4 − , orthorhombic, C2221,a=9.295(1),b=12.447(1),c=16.834(2) Å,V c =1947.5(4) Å3,Z=4,D m =1.47 g cm−3,D c =1.47 g cm−3,μ(CuKα)=31.7 cm−1. The finalR=0.052 for 733 counter reflections. The dication and the perchlorate anions lie on two-fold axes, and one perchlorate anion is disordered in two symmetrically equivalent positions. The two independent rings of the dication have conformations intermediate between half-chair and sofa, and the quinolizidine moiety (AB system) has a planar configuration. The title compound was obtained by mercuric acetate dehydrogenation of sparteine to Δ5,11-didehydrosparteine and protonation of the latter in methanol with perchloric acid.13C-NMR spectra in DMSO-2H6 and in2H2O revealed the presence of the symmetrical diimmonium structure of the salt in solution.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 74
    ISSN: 1572-8854
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The infrared spectra, in the HOH-bending region, of water molecules in very dilute solution in a number of ketones and ethers have been recorded, at room temperature. The bending band wavenumber shifts and half-widths have been measured, and correlated with the properties of the bands in the stretching region in the same solvents, reported earlier, and with the protonation constants of the solvents. Relationships have also been found between the bending band wavenumber shifts and their half-widths and peak absorptivities reported in the literature. The results are entirely consistent with earlier deductions concerning the nature and type of solute: solvent hydrogen bonds formed, based on data obtained from the OH-stretching region. The shapes of the bending bands in all but one solvent are predominantly Lorentzian; only in the case of tetrahydropyran is the band almost purely Gaussian.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 75
    Electronic Resource
    Electronic Resource
    Springer
    Journal of chemical crystallography 16 (1986), S. 889-893 
    ISSN: 1572-8854
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The structure of bis(acetylacetonato)copper(II) has been redetermined from single crystal X-ray diffraction data. The unit cell parameters area=11.331(9),b=4.697(3),c=10.290(9) Å, andβ=91.84(7)dg. A finalR=0.056 for 727 observed reflections was obtained. The O-Cu-O chelate (bite) angle is 93.2(2)°. The two Cu-O bond lengths are 1.914(4) and 1.912(4) Å. The complex has a slight chair structure and a step angle of 7.05°.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 76
    Electronic Resource
    Electronic Resource
    Springer
    Studia logica 45 (1986), S. 2-2 
    ISSN: 1572-8730
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mathematics , Philosophy
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 77
    Electronic Resource
    Electronic Resource
    Springer
    Studia logica 45 (1986), S. 19-33 
    ISSN: 1572-8730
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mathematics , Philosophy
    Notes: Abstract A semantical proof of Craig's interpolation theorem for the intuitionistic predicate logic and some intermediate prepositional logics will be given. Our proof is an extension of Henkin's method developed in [4]. It will clarify the relation between the interpolation theorem and Robinson's consistency theorem for these logics and will enable us to give a uniform way of proving the interpolation theorem for them.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 78
    Electronic Resource
    Electronic Resource
    Springer
    Studia logica 45 (1986), S. 35-38 
    ISSN: 1572-8730
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mathematics , Philosophy
    Notes: Abstract Important positive as well as negative results on interpolation property in fragments of the intuitionistic propositional logic (INT) were obtained by J. I. Zucker in [6]. He proved that the interpolation theorem holds in purely implicational fragment of INT. He also gave an example of a fragment of INT for which interpolation fails. This fragment is determined by the constant falsum (⊥), well known connectives: implication (→) and conjunction (∧), and by a ternary connective δ defined as follows: δ (p, q, r)= df (p∧q)∨(ℸp∧r). Extending this result of J. I. Zucker, G. R. Renardel de Lavalette proved in [5] that there are continuously many fragments of INT without the interpolation property. This paper is meant to continue the research mentioned above. To be more precise, its aim is to answer questions concerning interpolation and amalgamation properties in varieties of equivalential algebras, particularly in the variety determined by the purely equivalential fragment of INT.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 79
    Electronic Resource
    Electronic Resource
    Springer
    Studia logica 45 (1986), S. 39-53 
    ISSN: 1572-8730
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mathematics , Philosophy
    Notes: Abstract The logic of the weak law of excluded middleKC p is obtained by adding the formula ℸA ∨ ℸ ℸA as an axiom scheme to Heyting's intuitionistic logicH p . A cut-free sequent calculus for this logic is given. As the consequences of the cut-elimination theorem, we get the decidability of the propositional part of this calculus, its separability, equality of the negationless fragments ofKC p andH p , interpolation theorems and so on. From the proof-theoretical point of view, the formulation presented in this paper makes clearer the relations betweenKC p ,H p , and the classical logic. In the end, an interpretation of classical propositional logic in the propositional part ofKC p is given.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 80
    Electronic Resource
    Electronic Resource
    Springer
    Studia logica 45 (1986), S. 101-118 
    ISSN: 1572-8730
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mathematics , Philosophy
    Notes: Abstract Intermediate prepositional logics we consider here describe the setI(Ω) of regular informational types introduced by Yu. T. Medvedev [7]. He showed thatI(Ω) is a Heyting algebra. This algebra gives rise to the “logic of infinite problems” from [13] denoted here asLM 1. Some other definitions of negation inI(Ω) lead to logicsLM n (n ⩽ ω). We study inclusions between these and other systems, proveLM n to be non-finitely axiomatizable (n ⩽ ω) and recursively axiomatizable (n 〈 ω). We also show that formulas in one variable do not separateLM ∞ from Heyting's logicH, andLM n (n 〈 ω) from Scott's logic (H+S).
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 81
    Electronic Resource
    Electronic Resource
    Springer
    Studia logica 45 (1986), S. 371-375 
    ISSN: 1572-8730
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mathematics , Philosophy
    Notes: Abstract I distinguish between sentences like (1) Last Thursday we drove from Wellington to Waikanae and (2) Last Thursday my copy of Aspects of the Theory of Syntax remained on my bookshelf. Sentence (2) has the subinterval property. If it is true at an interval t it is true at every subinterval of t. (1) lacks this property. (1) reports an event. (2) reports a state. Events do not have the subinterval property but states do have it, and so do objects. If something is a linguist at an interval t then that person is a linguist at all subintervals of t. I argue that ‘exists’ applies to things which have the subdinterval property, and ‘occurs’ applies to things which lack it.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 82
    Electronic Resource
    Electronic Resource
    Springer
    Studia logica 45 (1986), S. 415-424 
    ISSN: 1572-8730
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mathematics , Philosophy
    Notes: Abstract The main theorem says that a consequence operator is an effective part of the consequence operator for the classical prepositional calculus iff it is a consequence operator for a logic satisfying the compactness theorem, and in which every finitely axiomatizable theory is decidable.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 83
    Electronic Resource
    Electronic Resource
    Springer
    Studia logica 45 (1986), S. 1-1 
    ISSN: 1572-8730
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mathematics , Philosophy
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 84
    Electronic Resource
    Electronic Resource
    Springer
    Studia logica 45 (1986), S. 9-17 
    ISSN: 1572-8730
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mathematics , Philosophy
    Notes: Abstract The main part of the proof of Kripke's completeness theorem for intuitionistic logic is Henkin's construction. We introduce a new Kripke-type semantics with semilattice structures for intuitionistic logic. The completeness theorem for this semantics can he proved without Henkin's construction.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 85
    Electronic Resource
    Electronic Resource
    Springer
    Studia logica 45 (1986), S. 69-75 
    ISSN: 1572-8730
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mathematics , Philosophy
    Notes: Abstract For intermediate logics, there is obtained in the paper an algebraic equivalent of the disjunction propertyDP. It is proved that the logic of finite binary trees is not maximal among intermediate logics withDP. Introduced is a logicND, which has the only maximal extension withDP, namely, the logicML of finite problems.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 86
    Electronic Resource
    Electronic Resource
    Springer
    Studia logica 45 (1986), S. 77-99 
    ISSN: 1572-8730
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mathematics , Philosophy
    Notes: Abstract Coming fromI andCl, i.e. from intuitionistic and classical propositional calculi with the substitution rule postulated, and using the sign ο to add a new connective there have been considered here: Grzegorozyk's logicGrz, the proof logicG and the proof-intuitionistic logicI Δ set up correspondingly by the calculi For any calculusи we denote byяи the set of all formulae of the calculusи and byℒи the lattice of all logics that are the extensions of the logic of the calculusи, i.e. sets ofяи formulae containing the axioms ofи and closed with respect to its rules of inference. In the logiclɛℒG the sign □ is decoded as follows: □A = (A & ΔA). The result of placing □ in the formulaA before each of its subformula is denoted byTrA. The maps are defined (in the definitions of x and λ the decoding of □ is meant), by virtue of which the diagram is constructed In this diagram the mapsσ, x andλ are isomorphisms, thereforex −1 = λ; and the maps △ andμ are the semilattice epimorphisms that are not commutative with lattice operation +. Besides, the given diagram is commutative, and the next equalities take place:σ −1 =μ −1 λ△ and σ = △−1 xμ. The latter implies in particular that any superintuitionistic logic is a superintuitionistic fragment of some proof logic extension.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 87
    Electronic Resource
    Electronic Resource
    Springer
    Studia logica 45 (1986), S. 119-134 
    ISSN: 1572-8730
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mathematics , Philosophy
    Notes: abstract Section 1 contains a Kripke-style completeness theorem for arbitrary intermediate consequences. In Section 2 we apply weak Kripke semantics to splittings in order to obtain generalized axiomatization criteria of the Jankov-type. Section 3 presents new and short proofs of recent results on implicationless intermediate consequences. In Section 4 we prove that these consequences admit no deduction theorem. In Section 5 all maximal logics in the 3 rd counterslice are determined. On these results we reported at the 1980 meeting on Mathematical Logic at Oberwolfach. This paper concerns propositional logic only.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 88
    Electronic Resource
    Electronic Resource
    Springer
    Studia logica 45 (1986), S. 199-206 
    ISSN: 1572-8730
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mathematics , Philosophy
    Notes: Abstract The aim of this paper is to provide a decision procedure for Dummett's logic LC, such that with any given formula will be associated either a proof in a sequent calculus equivalent to LC or a finite linear Kripke countermodel.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 89
    Electronic Resource
    Electronic Resource
    Springer
    Studia logica 45 (1986), S. 231-231 
    ISSN: 1572-8730
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mathematics , Philosophy
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 90
    Electronic Resource
    Electronic Resource
    Springer
    Studia logica 45 (1986), S. 251-273 
    ISSN: 1572-8730
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mathematics , Philosophy
    Notes: Abstract It is well known that the manner in which a definitely descriptive term contributes to the meaning of a sentence depends on the place the term occupies in the sentence. A distinction is accordingly drawn between ordinary contexts and contexts variously termed ‘non-referential’, ‘intensional’, ‘oblique’, or ‘opaque’. The aim of the present article is to offer a general account of the phenomenon, based on transparent intensional logic. It turns out that on this approach there is no need to say (as Frege does) that descriptive terms are referentially ambiguous or to deny (as Russell does) that descriptive terms represent self-contained units of meaning. There is also no need to tolerate (as Montague does) exceptions to the Principle of Functionality. The notion of an ordinary (i.e., ‘non-intensional’) context is explicated exclusively in terms of logical structure and it is argued that two aspects of ordinariness (termed ‘hospitality’ and ‘exposure’) must be distinguished.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 91
    Electronic Resource
    Electronic Resource
    Springer
    Studia logica 45 (1986), S. 281-292 
    ISSN: 1572-8730
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mathematics , Philosophy
    Notes: Abstract In the paper [2] the following theorem is shown: Theorem (Th. 3,5, [2]), If α=0 or δ=∞ or α⩾δ, then a closure space X is an absolute extensor for the category of 〈α, δ〉 -closure spaces iff a contraction of X is the closure space of all 〈α, δ〉-filters in an 〈α, δ〉-semidistributive lattice. In the case when α=ω and δ=∞, this theorem becomes Scott's theorem: Theorem ([7]). A topological space X is an absolute extensor for the category of all topological spaces iff a contraction of X is a topological space of “Scott's open sets” in a continuous lattice. On the other hand, when α=0 and δ=ω, this theorem becomes Jankowski's theorem: Theorem ([4]). A closure space X is an absolute extensor for the category of all closure spaces satisfying the compactness theorem iff a contraction of X is a closure space of all filters in a complete Heyting lattice. But for separate cases of α and δ, the Theorem 3.5 from [2] is proved using essentialy different methods. In this paper it is shown that this theorem can be proved using, for retraction, one uniform formula. Namely it is proved that if α= 0 or δ= ∞ or α ⩾ δ and $$F_{\alpha ,\delta } \left( L \right) \subseteq B_{\alpha ,\delta }^\mathfrak{n} $$ and if L is an 〈α, δ〉-semidistributive lattice, then the function $$r:{\text{ }}B_{\alpha ,\delta }^\mathfrak{n} \to F_{\alpha ,\delta } \left( L \right)$$ such that for x ε ℘ ( $$\mathfrak{n}$$ ): (*) $$r\left( x \right) = inf_L \left\{ {l \in L|\left( {\forall A \subseteq L} \right)x \in C\left( A \right) \Rightarrow l \in C\left( A \right)} \right\}$$ defines retraction, where C is a proper closure operator for $$B_{\alpha ,\delta }^\mathfrak{n} $$ . It is also proved that the formula (*) defines retraction for all 〈α, δ〉, whenever L is an 〈α, δ〉 -pseudodistributive lattice. Moreover it is proved that when α=ω and δ=∞, the formula (*) defines identical retraction to the formula given in [7], and when α = 0 and δ=ω, the formula (*) defines identical retraction to the formula given in [4].
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 92
    Electronic Resource
    Electronic Resource
    Springer
    Studia logica 45 (1986), S. 377-391 
    ISSN: 1572-8730
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mathematics , Philosophy
    Notes: Abstract The notion of local deduction theorem (which generalizes on the known instances of indeterminate deduction theorems, e.g. for the infinitely-valued Łukasiewicz logic C ∞) is defined. It is then shown that a given finitary non-pathological logic C admits the local deduction theorem iff the class Matr(C) of all matrices validating C has the C-filter extension property (Theorem II.1).
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 93
    Electronic Resource
    Electronic Resource
    Springer
    Studia logica 45 (1986), S. 167-179 
    ISSN: 1572-8730
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mathematics , Philosophy
    Notes: Abstract The first part of the paper deals with some subclasses of B-algebras and their applications to the semantics of SCI B , the Boolean strengthening of the sentential calculus with identity (SCI). In the second part a generalization of the McKinsey-Tarski construction of well-connected topological Boolean, algebras to the class of B-algebras is given.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 94
    Electronic Resource
    Electronic Resource
    Springer
    Studia logica 45 (1986), S. 135-154 
    ISSN: 1572-8730
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mathematics , Philosophy
    Notes: Abstract We give an idea of uniform approach to the problem of characterization of absolute extensors for categories of topological spaces [21], closure spaces [15], Boolean algebras [22], and distributive lattices [4]. In this characterization we use the notion of retract of the closure space of filters in the lattice of all subsets.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 95
    Electronic Resource
    Electronic Resource
    Springer
    Journal of chemical crystallography 16 (1986), S. 57-69 
    ISSN: 1572-8854
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract Urea (U) and salicylic acid (SA) crystallize from aqueous solution as a 1∶1 adduct whose structure shows them to be linked via several weak and one strong hydrogen bonds. The ir spectra of the adduct and its deuterated counterpart have been analyzed and the stretching modes of the various hydrogen bonds identified. The1H and13C nmr. spectra are also interpreted to show that discrete adducts of U·SA persist in solution. On heating, U·SA decarboxylates at a much lower temperature than SA itself.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 96
    Electronic Resource
    Electronic Resource
    Springer
    Journal of chemical crystallography 16 (1986), S. 91-99 
    ISSN: 1572-8854
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The crystal and molecular structures of chloro(triphenylphosphineselenide)gold(I), [(C6H5)3PSe]AuCl, have been determined from three-dimensional X-ray intensity data collected on a CAD4 diffractometer. The compound crystallizes in the triclinic space groupPl witha=9.322(3),b=10.639(5),c=9.252(3) Å, α=104.74(4), β=99.52(3), γ=76.97(3)°, andZ=2. Atomic parameters were refined by full-matrix least-squares to anR value of 5.7% for 2591 observed reflections. This is one of the few known examples of linear gold(I) complexes having an Au-Se linkage. The Se-Au-Cl angle is 178.6(1)°, and the Au-Se and Au-Cl distances are 2.371(2) and 2.277(6) Å, respectively. As expected, the Au-Se bond length is 0.10–0.18 Å longer than the Au-S bond length observed in similar two-coordinate linear gold(I) complexes.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 97
    Electronic Resource
    Electronic Resource
    Springer
    Journal of chemical crystallography 16 (1986), S. 139-139 
    ISSN: 1572-8854
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 98
    Electronic Resource
    Electronic Resource
    Springer
    Journal of chemical crystallography 16 (1986), S. 141-141 
    ISSN: 1572-8854
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 99
    Electronic Resource
    Electronic Resource
    Springer
    Journal of chemical crystallography 16 (1986), S. 519-524 
    ISSN: 1572-8854
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract Crystals of osmocene, Os(η-C5H5)2, are orthohombic:Pnma,M r =321.3,a=7.079(2),b=8.908(1),c=12.771(2),V c =806 Å3,Z=4,D x =2.640 g cm−3, MoKα (λ=0.71069 Å),μ=151 cm−1,F(000)=584,T=293 K,R=0.04 for 730 observed reflections. Osmocene is isomorphous with ruthenocene and the molecules have averageD 5h symmetry with a mean Os-C distance of 2.19(1) Å (compared with 2.186 Å forRu-C).
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 100
    Electronic Resource
    Electronic Resource
    Springer
    Journal of chemical crystallography 16 (1986), S. 569-576 
    ISSN: 1572-8854
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract C14H17NO4 crystallizes in the monoclinic space groupP21/n (Z=4) witha=10.208(2),b=10.888(2),c=11.909(2) Å, andβ=90.89(2)°. The structure was solved by direct methods and refined by full-matrix LSQ to anR factor of 0.036. The 4-oxo-1,3-dioxane ring is in a slightly distorted O(1)-sofa conformation flattened at the C(4) end with the 5-isopropyl substituent in a pseudoaxial position and planar lactone group. The molecules form dimers by means of intermolecular N-H⋯O(4) hydrogen bonds of 3.091(2) Å. The1H NMR spectrum of the title compound shows unusual features.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
Close ⊗
This website uses cookies and the analysis tool Matomo. More information can be found here...