ALBERT

Notes: Abstract Regionally distributed pelitic granulites in the Wilson Lake region contain the assemblage sapphirine + hypersthene + sillimanite + quartz. Geochronology and geobarometry suggest it developed in early Proterozoic rocks at temperatures approaching 900°C and pressures above 10 kbar. Vein-like metasomatized rocks around a suite of mafic to ultramafic intrusions, emplaced near the peak of metamorphism about 1700 Ma ago, contain sapphirine, but these assemblages developed at temperatures near 750°C and pressures of 4.5 kbar. Both types of assemblage occur as relics in amphibolite-grade (biotite–sillimanite) migmatites. P–T determinations indicate rapid isothermal uplift of 20 km accompanied by mafic intrusion and hydration. The metamorphic history and tectonic setting suggest exposure of deep continental crust by thrusting during continental collision, followed by essentially isothermal decompression.

Notes: Abstract The upper Jurassic Nikoro greenstone complex of eastern Hokkaido suffered high-pressure intermediate type metamorphism. Characteristic minerals include lawsonite, aragonite, sodic pyroxene of the aegirinejadeite series, winchite. sodic amphibole of the glaucophane-riebeckite series, pumpellyite, epidote and actinolite.High-pressure metamorphism of the Nikoro greenstone complex is related to subduction of the Kula plate toward the Palaeo-Okhotsk Land during Cretaceous time.

Notes: Abstract The Berzosa fault is a major ductile shear zone, the Berzosa Shear Zone (BSZ), which separates the ‘Ollo de Sapo’anticline from the inner higher-grade crystalline axis of the Iberian Hercynian Belt. This shear zone is the site of abundant early kinematic quartz (± Al-silicates) segregations, rich in fluid inclusions. Host rocks are medium-grade staurolite schists and sillimanite gneisses.Fluid inclusions in selected quartz segregations across the Berzosa shear zone have been studied by microthermometric methods as well as, in some instances, by Raman analysis. The recorded fluid inclusion history begins at the end of an intense secondary recrystallization period during late-peak metamorphic conditions and lasts until late in the uplift history of the zone.Three types of inclusions have been found, which in a time sequence are: CO2± H2O; H2O+salt (B-type); and, N2+CH4. Three types of B inclusion may be distinguished in turn, depending on whether they were trapped during an earlier dynamic-recovery phase (B1-type), formed later as intergranular trails (B2-type), or were trapped apparently along with N2+CH4 in clusions from a heterogeneous fluid (B3-type).Considerations from isochores confirm that CO2± H2O inclusions were trapped during late-peak and high-T retrograde metamorphic conditions (in the range 650–500°C and 5–2 kbar), whilst N2+CH4 inclusions, along with the B3-type of inclusions, formed at low-pressures (〈1 kbar) and temperatures (± 300°C). B2-type inclusions were trapped chronologically between these two in a period in which strong inverse lateral thermal gradients developed in the zone. Inferred P-T paths for the area are convex to the T-axis.

Notes: Abstract The orthopyroxene-clinopyroxene, garnet-orthopyroxene and garnet-clinopyroxene geothermometers, and the garnet-orthopyroxene-plagioclase, garnet-clinopyroxene-plagioclase and anorthite-ferrosilite-grossular-almandine-quartz geobarometers are applied to metabasites and the garnetplagioclase-sillimanite-quartz geobarometer is applied to a metapelite from the Proterozoic Arendal granulite terrain, Bamble sector, Norway. P–T conditions of metamorphism were 7.3 ± 0.5 kbar and 800 ± 60°C.This terrain shows a regional gradation from the amphibolite facies, into normal LILE content granulite facies rocks and finally strongly LILE deficient granulite facies gneisses. Neither P nor T vary significantly across the entire transition zone. The change in ‘grade’parallels the increasing dominance of CO2 over H2O in the fluid phase.LILE-depletion is not a pre-condition of granulite facies metamorphism: granulites may have either ‘depleted’or ‘normal’chemistries. The results presented herein show that LILE-deficiency in granulite facies orthogneisses is not necessarily related to variations in either P or T. The important mechanisms in the Arendal terrain were (a) direct synmetamorphic crystallization from magma, with primary LILE-poor mineralogies imposed by the prevailing fluid regime, and (b) metamorphic depletion, involving scavenging of LILEs during flushing by mantle-derived CO2-rich fluids. The latter process is constrained by U–Pb and Rb–Sr isotopic work to have occurred no later than 50 Ma after intrusion of the acid-intermediate gneisses, and was probably associated with contemporary basic magmatism in a tectonic environment similar to a present day cordilleran continental margin.

Notes: Abstract Peridotite and infolded marble of the Seiad ultramafic complex were recrystallized in the upper amphibolite facies as part of the regional progressive metamorphism of the Rattlesnake Creek terrane. Field relations, including the occurrence of metarodingites, and metasomatic zones between dissimilar rock types, demonstrate that the metasediments and serpentinized ultramafic rocks were juxtaposed prior to regional, barrovian metamorphism. Temperatures are estimated to have reached 760–800°C at pressures of 7–8 kbar during the peak of metamorphism. Four low-variance parageneses have been identified within a small (3 km2) area of the complex, which may reasonably be assumed to have formed under the same P and T conditions. Isobaric T-Xco2 diagrams of appropriate equilibria are presented for three different internally consistent sets of thermodynamic data. Despite the seemingly small numerical differences between the standard state thermodynamic properties of the data sets, only one diagram allows the four observed assemblages to coexist within a reasonable temperature range. All three phase diagrams require differences in fluid composition on the scale of a thin section; strong evidence for effective control of pore fluid composition by local mineral reactions during metamorphism.

Notes: Abstract Chromian omphacite which contains up to 4 wt % Cr2O3 has been identified from low-grade metamorphic rocks in Nishisonogi, Kyushu, Japan. It occurs as aggregates, forming a thin horizon ([20 mm thick) in alayered metagabbro within a serpentinite melange zone, together with Cr-free omphacite, actino-lite, epidote and sphene. It may have been formed by the metasomatic introduction of Cr into the metagabbro from the serpentinite rather than by reaction with chromite. The structural formula, based on EPMA analyses, and the optical absorption spectrum of the chromian omphacite show that the Cr is positioned in the octahedral site.

Notes: Abstract A diagenctic through anchizone to epizone transition is demonstrated in pelitic rocks of the Lower Palaeozoic marginal basin of Wales by examination of variations in phyllo-silicate mineralogy, illite crystallinity and bo parameter of white micas. This transition represents a temperature range from ∼ 150°C to ∼ 400°C and the metamorphism is of a low-pressure facies series type, with a geothermal gradient of ∼ 40°Ckm-1. Variations in grade can be correlated largely with the original basin and shelf form, suggesting a depth-related metamorphism. However, in areas closer to the site of Caledonian plate collision an increasingly syn-tectonic metamorphic event is apparent.Correlation of pelite data with metabasite assemblages is variable, the most consistent relationship being between epizone crystallinity values andepidote-actinolite (greenschist facies) assemblages. Diagenetic clay mineral assemblages are found associated with prehnite-pumpellyite assemblages in metabasites and it is suggested that the latter represent non-buffered, and therefore non-diagnostic, assemblages.

Notes: Abstract In the contact metamorphic aureole of the Tinaroo Batholith (north Queensland, Australia), mylonitic rocks were metamorphosed during a regional folding/crenulation event (D2) synchronous with the emplacement of muscovite-bearing granitoids. Prismatic and skeletal andalusite porphyoblasts grew in carbonaceous schists, mainly from the dissolution of staurolite. Muscovite, quartz and biotite played a dual role in this reaction, acting in a catalytic capacity as well as reactants or products. Staurolite was replaced by coarse-grained muscovite ± biotite, whereas andalusite locally replaced quartz ± muscovite ± biotite, with diffusion of H, Al, Si, Mg, Fe and K ionic species linking sites of dissolution and growth.Graphite contributed to the reaction mechanism in a number of ways. Accumulations of graphite in front of advancing andalusite crystal faces led to skeletal growth and the formation of chiastolite structure, where incremental growth occurred on adjacent {110} faces, with subsequent filling in and inclusion of graphite along the diagonal zones. The presence of graphite in some layers in the schist matrix prevented recrystallization of strained muscovite grains. The muscovite grains in these layers, in contrast to adjacent thin non-graphitic layers, were preferentially replaced by quartz. This resulted in muscovite-depletion haloes in graphitic layers around andalusite porphyroblasts. Somewhat arcuate zones of graphite, concentrated during dissolution of quartz along a crenulation cleavage, occur on some andalusite faces. Reactivation of the mylonitic foliation during the formation of D2 crenulations led to a preferential dissolution of quartz in zones of progressive shearing localized near andalusite porphyroblasts and hence the accumulation of graphite.Lack of deflection of the pre-existing mylonitic foliation and anastomosing of the axial planes of D2 crenulations around andalusite porphyroblasts demonstrate not only the timing of growth, but also that growing porphyroblasts do not push aside existing foliations.

Notes: THE YOUNG EARTH: AN INTRODUCTION TO ARCHAEAN GEOLOGY. By E.G. Nisbet. Allen and Unwin, Boston, 1987. pp. 402.

Notes: Abstract Mica porphyroblasts in schists from several regions show nearly planar inclusion trails that are parallel over areas much larger than the wavelengths of later folds. This indicates that the porphyroblasts have not rotated, with respect to geographical co-ordinates, during deformation. Instead, the matrix has rotated, as suggested by Ramsay (1962). Even in zones of marked shortening in the matrix adjacent to large rigid porphyroblasts (e.g. of cordierite or staurolite), small biotite porphyroblasts have not rotated, but have become thinned by solution, as indicated by parallelism of inclusion trails in separate biotite grains and by evidence of truncation of inclusion trails by the matrix foliation. Less common are biotite porphyroblasts that have single asymmetrical microfolds in the matrix adjacent to the porphyroblasts and so appear to have rotated; these porphyroblasts are characterized by kinking.

Notes: Abstract Two major problems which exist in the use of illite crystallinity to define low-grade metamorphic zones are the variety of values chosen for the zone boundaries and the persistent use of three different indices of crystallinity. Although measurement techniques, which cause much of the interlaboratory variation, can be standardized, it is shown that there is, nevertheless, significant additional variation which demands calibration on standards. The greatest variations are due to choices of different absolute values of crystallinity to define zone boundaries. The problem of relating measurements between different indices is approached by fitting mathematical relationships to pairs of measurements from the same sample. A power–law relationship is a satisfactory fit to the Kubler–Weaver and Weaver–Weber pairs, while the Kubler–Weber indices are linearly related. These relationships are used to transform definitions of the diagenetic zone, anchizone and epizone from one index to the others, although they apply strictly only to the data set from which they are derived. This results in compatibility between the three zones and shows that previous definitions to the anchizone in different indices have been chosen at incompatible values. The boundaries of Kubler's anchizone (0.42 and 0.25 Δ2θ) are 0.4 and 0.215 Δ2θ in this study, which become 5.1 and 14.6 in the Weaver index and 278 and 149 in the Weber index. An error analysis shows that percentage errors in both Kubler and Weaver indices increase with crystallinity; the Kubler measurements are marginally preferred at all grades.

Notes: Abstract Migmatites in the Quetico Metasedimentary Belt contain two types of leucosome: (1) Layer-parallel leucosomes that grew during deformation and prograde metamorphism. These are enriched in SiO2, Sr, and Eu, but depleted in TiO2, Fe2O3, MgO, Cs, Rb, REE, Sc, Th, Zr, and Hf relative to the Quetico metasediments. (2) Discordant leucosomes that formed after the regional folding events when metamorphic temperatures were at their peak. These are enriched in Rb, Ba, Sr and Eu, but display a wide range of LREE, Th, Zr, and Hf contents relative to the Quetico metasediments.Layer-parallel leucosomes formed by a subsolidus process termed tectonic segregation. This stress-induced mass transfer process began when the Quetico sediments were deformed during burial, and continued whilst the rocks were both stressed and heterogeneous. Subsolidus leucosome compositions are consistent with the mobilization of quartz and feldspar from the host rocks by pressure solution. The discordant leucosomes formed by partial melting of the Quetico metasediments, possibly during uplift of the belt. The range of composition displayed by the anatectic leucosomes arises from crystal fractionation during leucosome emplacement. Some anatectic leucosomes preserve primary melt compositions and have smooth REE patterns, but those with negative Eu anomalies represent fractionated melts, and others with positive Eu anomalies represent accumulations of feldspar plus trapped melt.

Notes: Abstract The effects of varying amounts of partial melt on the deformation of granitic aggregates have been tested experimentally at conditions (900°C, 1500 MPa, 10-4 to 10-6/s) where melt-free samples deform by dislocation creep, with microstructures approximately equivalent to those of upper greenschist facies. Experiments were performed on samples of various grain sizes, including an aplite (150 μm) and sintered aggregates of quartz-albitemicrocline (10–50 and 2–10 μm). Water was added to the samples to obtain various amounts of melt (1–15% in the aplite, 1–5% in the sintered aggregates). Optical and TEM observations of the melt distribution in hydrostatically annealed samples show that the melt in the sintered aggregates is homogeneously distributed along an interconnected network of triple junction channels, while the melt in the aplites is inhomogeneously distributed.The effect of partial melt on deformation depends an melt amount and distribution, grain size and strain rate. For samples deformed with ˜ 1% melt, all grain sizes exhibit microstructures indicative of dislocation creep. For samples deformed with 3–5% melt, the 150 μm and 10–50 μm grain size samples also exhibit dislocation creep microstructures, but the 2–10 μm grain size samples exhibit abundant TEM-scale evidence of dissolution-precipitation and little evidence of dislocation activity, suggesting a switch in deformation mechanism to predominantly melt-enhanced diffusion creep. At natural strain rates melt-enhanced diffusion creep would predominate at larger grain sizes, although probably not for most coarse-grained granites.The effects of melt percentage and strain rate have been studied for the 150 μm aplites. For samples with ˜ 5 and 10% melt, deformation at 10–6/s squeezes excess melt out of the central compressed region allowing predominantly dislocation creep. Conversely, deformation at 10-5/s produces considerable cataclasis presumably because the excess melt cannot flow laterally fast enough and a high pore fluid pressure results. For samples with 15% melt, deformation at both strain rates produces cataclasis, presumably because the inhomogeneous melt distribution resulted in regions of decoupled grains, which would produce high stress concentrations at point contacts. At natural strain rates there should be little or no cataclasis if an equilibrium melt texture exists and if the melt can flow as fast as the imposed strain rate. However, if the melt is confined and cannot migrate, a high pore fluid pressure should promote brittle deformation.

Notes: Abstract Crystal-chemical relationships between coexisting sodic and calcic amphiboles have been studied in eclogitic metagabbros from the Aosta Valley, Western Alps. Textural analysis gives evidence of three successive high-pressure parageneses:1. Pre-kinematic high-grade blueschist assemblages, preserved as polymineralic inclusions in garnet cores and made of glaucophane and actinolite (stage A).2. Synkinematic eclogite assemblages, composed of garnet + omphacite + glaucophane ± actinolite ± white mica ° Clinozoisite + quartz + rutile (stage B).3. Post-kinematic epitactic overgrowths of barroisitic amphibole on glaucophane and actinolite (stage C). P–T conditions of the eclogitic metamorphism have been estimated at around 500–550°C, 16 kbar.Glaucophane and actinolite coexist as discrete grains in stage A and B assemblages. This texture and the chemistry of the amphiboles unambiguously denotes the existence of a miscibility gap between sodic and calcic amphiboles (from NaM4= 0.80 in actinolite to NaM4= 1.70 in glaucophane at T= 500–550°C). A comparison with published analyses allows a new solvus along the glaucophane–actinolite join to be drawn.The later barroisitic amphibole (stage C) exhibits strong chemical zonation indicating disequilibrium growth. This amphibole cannot either be used to define a miscibility gap with glaucophane or actinolite or be considered as an intermediate stage between these two end-members.

Notes: Abstract Garnet granulites from Sri Lanka preserve textural and chemical evidence for prograde equilibration at temperatures of at least 700–750°C and pressures in the vicinity of 6–8 kbar. Associated strain patterns suggest prograde metamorphism occurred during and immediately following an episode of crustal thickening, with the prograde P–T conditions probably reflecting a combination of the conductive and advective transport of heat at the mid-levels of tectonically thickened crust. The occurrence of prograde wollastonite provides evidence for internally buffered fluid compositions, or fluid absent conditions, during peak metamorphism and precludes pervasive advection of a CO2-rich fluid. The advective heat component is therefore likely to have been provided by the transport of silicate melt. Intricate symplectitic textures record partial re-equilibration of the garnet granulites to lower pressures (˜ 4–6 kbar) at high temperatures (600–750°C), and testify either to the erosional denudation of the overthick crust prior to significant cooling (i.e. quasi-isothermal decompression) or to a subsequent static heating possibly of early Palaeozoic age (Pan-African). The metamorphic history of the Sri Lankan granulites is compared with high grade terrains in the neighbouring fragments of Gondwana, with the emphasis on similarities with Proterozoic granulites of the East Antarctic craton.

Notes: TECTONIC SETTINGS OF REGIONAL METAMORPHISM. Edited by E.R. Oxburgh, B.W.D. Yardley and P.C. England. Royal Society of London. 1987.

Notes: Abstract This paper provides methods and a description of a Pascal computer program, thermocalc, for various thermodynamic calculations using the thermodynamic dataset presented in earlier papers in this series (Holland & Powell, 1985; Powell & Holland, 1985). The dataset involves uncertainties on the thermodynamic parameters and therefore allows uncertainties to be calculated on results, for example in geothermometry and geobarometry. Recommendations are made for the uncertainties on activities to be used in calculations on rocks, particular emphasis being placed on preventing underestimates of these uncertainties at small mole fractions. Apposite examples of phase diagram and rock calculations are presented with ouput from thermocalc, demonstrating the utility of the program. Of the rock calculations, the most valuable are considered to be those involving simultaneous combination ‘least squares’of calculated conditions for a set of reactions applicable to a rock. This set of reactions involves the independent reactions which can be written between the end-members in the minerals in a rock and in the thermodynamic dataset. In contrast to an approach based on specific geothermometers and geobarometers, this approach maximizes the benefit of having an internally consistent thermodynamic dataset. thermocalc is available in IBM PC and Mac versions, from Roger Powell for A$25 or Tim Holland for £10 per version.

Notes: Abstract An inverted metamorphic gradient associated with the northern mylonite zone of the Cheyenne belt, a deeply eroded Precambrian suture in southern Wyoming, has been documented within metasedimentary rocks of the Early Proterozoic Snowy Pass Supergroup. Metamorphic grade in the steeply dipping supracrustal sequence increases from the chlorite through the biotite, garnet, and staurolite zones both stratigraphically and structurally upward toward the northern mylonite zone. A minimum temperature increase of approximately 100° C over a km-wide zone is required for this transition. Parallelism of inverted isograds with the trace of the northern mylonite zone implies a genetic relationship between deformation associated with that zone and the inverted metamorphic gradient within the Snowy Pass Supergroup.Field evidence together with microstructural and petrofabric analysis indicate northward thrusting of amphibolite-grade rocks over rocks of the Snowy Pass Supergroup along the northern mylonite zone. Mineral equilibria and garnet-biotite geothermometry on synkinematic mineral assemblages within the Snowy Pass metasedimentary rocks indicate deformation at minimum temperatures of 480° C and pressures of 350–400 MPa (3°5–4°0 kbar). This implies tectonic burial or upper plate thickness of 13–15 km.The narrow character of metamorphic zonation and microtextures within the Snowy Pass Supergroup which indicate late synkine-matic growth of garnet and staurolite, preclude rotation of pre-existing isograds by folding as a mechanism for development of the inverted gradient. Conductive transport of heat from the upper into the lower plate across the originally low-angle thrust is insufficient to produce the necessary temperatures in the lower plate. Shear heating is considered insufficient to produce the observed metamorphic transition unless high shear stresses are postulated. Up-dip advection of metamorphic fluids is a feasible, but unproven, mechanism for heat transport. The possibility that rapid uplift due to stacking of several thrust sheets may have played a role in preserving the inverted metamorphic gradient cannot be evaluated at present.

Notes: Abstract Partial melting of tonalitic gneisses in the 2.7 Ga Badcallian granulite facies metamorphic episode in the Scourian complex of north-west Scotland produced a suite of granitic to trondhjemitic liquids. On cooling and excavation of the complex, these melts underwent fractional crystallization and the residual liquids eventually became water saturated. Comparison with experimental data suggests that water saturation would have occurred in these melts at around 620–700°C. From the retrograde P–T-time path followed by the complex it is estimated that H2O-dominated fluids were exsolved from these melts at c. 2.5 Ga. It is proposed that these fluids were the cause of the 2.5 Ga Inverian retrogression of the Scourian complex and that water-saturated melts formed during the crystallization of the leucogneisses were intruded as a suite of pegmatites. The timing of pegmatite intrusion is consistent with this proposition as are the temperature estimates, timing, distribution and nature of the Inverian phase of metamorphism. It is likely that the crystallization of melts is an important process in bringing about hydrous retrogressive metamorphic episodes in a number of other basement terrains, such as West Greenland and Australia.

Notes: Abstract Partitioning of Fe and Mg between garnet and phengitic muscovite was calibrated as a geothermometer by Green & Hellman (1982) using experimental data at 25–30 kbar. When the thermometer is applied to pelites regionally metamorphosed at pressures of between 3 and 7 kbar it yields temperatures much higher than those from the garnet–biotite thermometer. A new empirical calibration is proposed for use with such rocks, with particular application where garnet occurs at lower grades than biotite. The new calibration is where K is given by: In K= In Kd and Xii are mole fractions in the garnets.The calibration was derived from comparison with the garnet–biotite thermometer of Ferry & Spear (1978), assuming no pressure-dependence for the partitioning between garnet and muscovite, no ferric iron partitioning, ideal mixing in muscovite, and the garnet mixing model of Ganguly & Saxena (1984) modified for a non-linear Ca effect. This latter garnet mixing model was selected because it gave the geologically most reasonable results. It has not proved possible to distinguish a pressure effect from a ferric-iron effect.Despite the simplifying assumptions used to derive the calibration, it yields temperatures generally within 15°C of those given by the garnet–biotite thermometer, and has been used to supply thermometric data in a low-grade region of the Canadian Rockies.

Notes: Abstract Mineral assemblages in different samples of amphibolite facies pelitic schists collected from two separate outcrops in the Moosilauke area, NH, record differences in the chemical potential of water during metamorphism. Mineralogical, petrological, and field relations indicate that mineral assemblages at both outcrops equilibrated at 520°C and 3.5–4.0 kbar. Thermodynamic analysis of the mineral assemblages demonstrates that maximum chemical potential differences at each outcrop were of the order of 150 calories, over distances of 10–20 m.The differences in the chemical potential of water recorded in both bed-to-bed and outcrop-to-outcrop relations are consistent with the following conclusions: (1) mineral assemblages on a specific outcrop did not equilibrate with an external reservoir of fluid of fixed composition, (2) the relatively small magnitude of the chemical potential differences suggests little or no infiltration of externally derived fluid, (3) these differences on the outcrop scale are probably related to initial compositional variations and the buffer capacity of the mineral assemblage, and (4) the different values of the chemical potential of water exhibited by the various mineral assemblages permits an understanding of the effects of variable μH2O for amphibolite facies pelitic schists.

Notes: Abstract A detailed study of garnet–chloritoid micaschists fom the Sesia zone (Western Alps) is used to constrain phase relations in high pressure (HP) metapelitic rocks. In addition to quartz, phengite, paragonite and rutile, the micaschists display two distinct parageneses, namely garnet + chloritoid + chlorite and garnet + chloritoid + kyanite. Talc has never been observed. Garnet and chloritoid are more magnesian when chlorite is present instead of kyanite. The distinction of the two equilibria results from different bulk rock chemistries, not from P–T conditions or redox state. Estimated P–T conditions for the eclogitic metamorphism are 550–600°C, 15–18 kbar.The presence of primary chlorite in association with garnet and chloritoid leads us to construct two possible AFM topologies for the Sesia metapelites. The paper describes a KFMASH multisystem for HP pelitic rocks, which extends the grid of Harte & Hudson (1979) towards higher pressures and adds the phase talc. Observed parageneses in HP metapelites are consistent with predicted phase relations. Critical associations are Gt–Ctd–Chl and Gt–Ctd–Ky at relatively low temperatures and Gl–Chl–Ky and Gt–Tc–Ky at relatively high temperatures.

Notes: Abstract Low-pressure prograde metamorphism of pelitic rocks in the Cooma Complex, south-east Australia, has produced cordierite-andalusite schists at intermediate grades. The first foliation (S1) is preserved largely as inclusion trails in cordierite porphyroblasts. Microstructural evidence indicates that the cordierite porphyroblasts grew during the early stages of development of a crenulation-foliation (S2) and that andalusite porphyroblasts grew during the development of a later crenulation-foliation (S3). Microstructural evidence also indicates that the andalusite was a product of the prograde reaction: cordierite + muscovite ± andalusite + biotite + quartz. The occurrence of the products of this reaction in ‘beard’structures between cordierite microboudins formed by extension in S3 confirms that the andalusite grew during the development of S3. The investigation shows that porphyroblast-matrix relationships can preserve the orientation of an early S-surface that has been largely obliterated from the matrix, as well as providing relatively direct evidence of sequential mineral growth and metamorphic reactions.

Notes: Abstract The magnitudes of plastic strains of 104 metacherts were determined from the deformed shape of initially spherical radiolarians in the Sambagawa high-P type metamorphic belt of Western Shikoku, Japan. The strain magnitude increases with increasing metamorphic temperature from several per cent to 250%. The a2/a3 ratio of strain ellipsoids in the higher metamorphic grades decreases with increasing metamorphic grade while the a1/a2 ratio increases rapidly. The long axis of the strain ellipsoid for every grade is nearly parallel to the length of the metamorphic belt, suggesting that the flow direction of the synmetamorphic deformation was uniform along the belt. A map of strain zones within the Sambagawa high-P type metamorphic belt reveals that the metamorphic belt underwent a progressive bulk inhomogeneous shear deformation and that the high-grade zones represent a deep-seated boundary shear zone on the accretionary wedge between a subducting oceanic plate and the immobile rigid continental plate.

Notes: Abstract Compositions of actinolite, hornblende and cummingtonite, together with pyroxene and plagioclase, are studied in basic intrusions in the Dalradian of north-east Scotland, and the Glen Scaddle complex in the West Moine. Amphibolitization is due to influx of water from the country rocks. Pyroxene compositions are found to have adjusted to the regional metamorphic environment. Owing to the difficulty of diffusion of Al and Si, calcic amphiboles are zoned and commonly contain quartz blebs. Discontinuities in zoning give rise to actinolite-hornblende pairs. Compared with north-east Scotland, disequilibrium is less strong in the Glen Scaddle area: in the latter, plagioclase compositions have been greatly changed, Na partition between hornblende and plagioclase is close to equilibrium, the maximum Al content of hornblende is lower and zoning patterns are more consistent. The Fe/Mg ratio in calcic amphiboles varies with Al content, while approaching equilibrium partition with other minerals. Both zoning patterns and Fe/Mg partition with cummingtonite suggest that Fe/Mg of the calcic amphiboles increases more strongly with increasing (Alvi+Fe3+) than can be explained simply by substitution of Al,Fe3+ for Mg on M2. Model reactions for amphibole formation are constructed. Cummingtonite formed at lower chemical potential of CaO than actinolite: Ca was exchanged for Mg,Fe between orthopyroxene-derived and clinopyroxene-derived local systems. Both cummingtonite and actinolite were formed because of kinetic constraints, as intermediate reaction products: actinolite-hornblende pairs represent disequilibrium. This work suggests that many occurrences of actinolite with hornblende, where the minerals are zoned, may also be due to diffusion kinetics.

Notes: Abstract Lewisian grey gneisses from Gruinard Bay, North-west Scotland retain mineralogical and geochemical evidence for Scourian horn-blende-granulite facies metamorphism, and they may be used to assess current models of elemental depletion at granulite grade. Their ‘immobile’major and trace element geochemistry is indistinguishable from that of Lewisian amphibolite and pyroxene-granulite facies counterparts. The K, Rb, Th and U contents of the Gruinard Bay gneisses are depleted relative to amphibolite facies gneisses, but generally the abundances of these elements are above those of comparable pyroxene granulites. U and Th have reached an advanced stage of depletion, but allanite appears to be crucial in maintaining significantly higher U and Th abundances at Gruinard Bay than in pyroxene granulites. K and Rb loss is less extreme, and depends on the stability of the rock-forming minerals: K-feldspar; biotite; and, amphibole. Early removal of K and Rb has resulted in a small rise in K/Rb, but further preferential Rb loss would have been required to generate the characteristically high K/Rb ratios of Lewisian pyroxene granulites.The residence of U and Th in the accessory minerals of granulite facies gneisses, which are often correlated with the residua of intracrustal partial melting, renders unlikely their extreme incompatibility required by such models. Even if such phases are ignored, high mineral-melt partition coefficients for silicic melts argue against partial fusion as an efficient depletion mechanism. On the other hand, the advanced stage of U and Th depletion reached in Gruinard Bay gneisses, which were still partly hydrous, severely restricts the role played by CO2-dominated fluids and a hydrous medium is preferred.

Notes: Abstract Oxygen and hydrogen isotope analyses have been made of coexisting quartz, ilmenite, muscovite, and biotite from Late Precambrian metapelitic rocks, staurolite-kyanite to K-feldspar-muscovite-sillimanite zones, from Mica Creek, British Columbia. The δ18O and †D values of these minerals are generally uniform and do not decrease significantly with increasing metamorphic grade. This implies that there has not been significant infiltration of deep crustal, possibly magmatic, fluids into the metapelites that has been suggested for other high-grade metamorphic terranes. The uniformity of oxygen isotope compositions of the Mica Creek metapelite rocks may reflect isotopic uniformity in the sedimentary protolith rather than widespread exchange with an isotopically homogeneous metamorphic pore fluid.Temperature estimates based upon 18O exchange thermometry for samples below the sillimanite zone are in reasonable agreement with the results of garnet-biotite Fe–Mg exchange thermometry. In the higher grade rocks, the oxygen isotope and garnet-biotite thermometry yield results which disagree by about 100°C. The highest temperatures recorded by oxygen isotope thermometry, 595°C, are at least 60°C below the minimum temperatures required by phase equilibria. These discrepancies appear to result from pervasive equilibrium retrograde exchange of oxygen isotopes between coexisting minerals. In addition, there are problems with calibration of garnet-biotite thermometry at higher temperatures. Retrograde oxygen isotope exchange may be a general characteristic of high-grade metamorphic rocks and oxygen isotope thermometry may not usually record peak metamorphic temperatures if they significantly exceed 600°C.

Notes: Abstract Mctamorphic rocks of the St Anthony Complex of north-western Newfoundland are best interpreted in terms of a high-temperature shear zone formed between down-going continental margin rocks and overriding oceanic lithosphere in a subduction zone. High-grade rocks, immediately beneath the oceanic lithosphere peridotite, display retrograde meta-morphism in high-strain zones, whereas lower grade rocks, near the base of the metamorphic complex, display prograde metamorphism in high-strain zones. Mylonite zones in meta-basitcs at all levels in the complex contain the assemblage epidote-hornblende-albite-sodic oligoclase. These observations suggest that the ‘inverted metamorphic gradient’within the St Anthony Complex results from the fortuitous preservation of residual metamorphic assemblages from different crustal levels within an epidote amphibolite facies shear zone. The degree of re-equilibration is strongly dependent on the degree of strain, and is best achieved in synmetamorphic mylonite zones. This interpretation of the St Anthony Complex can be extended to other sub-ophiolite metamorphic sheets, which show very similar relationships. It is proposed that most metamorphic sheets beneath ophiolites are high temperature shear zones, the P-T paths of which preserve records of burial and exhumation in subduction zones.

Notes: Abstract In the northeastern part of the Grenville Province, along the gulf of St Lawrence, cordierite is widespread in the migmatites of Baie Jacques Cartier (BJC) and Baie des Ha! Ha! (BHH). In the BJC area, rafts of mesosome occur in a pervasive network of leucosome consisting of cordierite-bearing pegmatite. In BHH, however, the mesosome and leucosome are well segregated and locally separated by thin biotite –hornblende melanosomes.Leucosomes in the BJC area record the highest temperatures (oxide thermometry = 900°C), whereas leucosomes of BHH and mesosomes of both areas indicate peak temperatures around 800°C (oxide thermometry; biotite–garnet thermometry with fluorine-rich biotite). Peak pressures were constrained at 720 MPa using the Ilm-Sil–Qtz–Grt–Rt (GRAIL) equilibrium.The area is thought to have undergone extensive melting under relatively modest pressures. The highest temperatures recorded in the BJC area are probably related to a pervasive impregnation of this terrane by aluminous granitic melts.Most post-peak P–T estimates for the mesosomes fall on a nearly isobaric, clockwise, P–T path (0.6 MPa/°C) with the exception of the high-temperature leucosomes of BJC, which fall about 100°C away from this path; this is additional evidence for the external origin of these leucosomes. The ultimate source of heat that generated the migmatites is thus though to be an underlying plutonic complex (anorthosite?).

Notes: Abstract The introduction of externally derived fluids into rocks of the Zermatt–Saas zone of the Swiss Alps gave rise to the simultaneous formation of shear and hydraulic fractures. These fractures are now filled with albite-rich assemblages and surrounded by alteration halos up to c. 2 m wide. The alteration assemblages are zoned and an examination of reactions in P–T–aH2O space implies that the parageneses developed by the hydration of fluid-absent eclogites. A mechanical analysis of the veins (after Sibson, 1981) shows that Pfluid/Pload must have been at least 0.96. Fluid migration into the country rocks must have been driven by excess hydraulic head either derived from the vertical extent of the veins or due to their connection to a deeper, external reservoir, possibly tapped along thrust surface(s). Diffusive and capillary transport were insignificant. The fluids may have been derived from underlying metasediments that were dehydrating during the quasi-isothermal uplift of this part of the Alps, or they may have originated during the prograde mesoalpine metamorphism documented in the area.

Notes: Abstract The Catalina Schist of southern California is a subduction zone metamorphic terrane. It consists of three tectonic units of amphibolite-, high-P greenschist- and blueschist-facies rocks that are structurally juxtaposed across faults, forming an apparent inverted metamorphic gradient. Migmatitic and non-migmatitic metabasite blocks surrounded by a meta-ultramafic matrix comprise the upper part of the Catalina amphibolite unit. Fluid-rock interaction at high-P, high-T conditions caused partial melting of migmatitic blocks, metasomatic exchange between metabasite blocks and ultramafic rocks, infiltration of silica into ultramafic rocks, and loss of an albitic component from nonmigmatitic, clinopyroxene-bearing metabasite blocks.Partial melting took place at an estimated P=˜8–11 kbar and T=˜640–750°C at high H2O activity. The melting reaction probably involved plagioclase + quartz. Trondhjemitic melts were produced and are preserved as leucocratic regions in migmatitic blocks and as pegmatitic dikes that cut ultramafic rocks.The metasomatic and melting processes reflected in these rocks could be analogous to those proposed for fluid and melt transfer of components from a subducting slab to the mantle wedge. Aqueous fluids rather than melts seem to have accomplished the bulk of mass transfer within the mafic and ultramafic complex.

Notes: Abstract Migmatite structures in the Coast Plutonic-Metamorphic Complex are well exposed in the inlet of Boca de Quadra, southeast Alaska. Two types of anatectic migmatites are present. Patch migmatites formed by in situ melting and subsequent crystallization of melt. Diktyonitic migmatites comprise a discontinuous veined network of leucocratic material, in which leucosomes enclose boudins of host rock. The margins of these boudins show the development of both melanosomes and shear band fabrics.Strain analysis of diktyonitic melanosomes indicates that these regions have undergone volume decreases of 20-27%. This volume decrease is attributed to melt extraction into the adjacent fracture-filling leucosomes. Thus, diktyonitic migmatites formed by shear-induced segregation of partial melt, whereas in patch migmatites the lack of shear stresses inhibited melt segregation. The variable structural style of anatectic migmatites in Boca de Quadra is not related to host-rock composition, but may be due to differences in the amount of differential stress during migmatization. These in turn may be controlled by host-rock strength and/or diachroneity of migmatization and deformation.Determination of volume changes during migmatization using strain analysis is potentially capable of discriminating intrusive and anatectic migmatites and consequently of documenting melt segregation and subsequent migration across crustal levels.

Notes: Abstract Chloritoid and pyrophyllite occur together in all major goldfields of the Witwatersrand Basin and are widespread in virtually all rock types of the upper Witwatersrand Supergroup, including metaconglomeratic reefs and altered mafic rocks. Both minerals are particularly characteristic of the pelitic horizons intimately associated with reef packages, but they are also developed locally in the regionally persistent metapelites that have basin-wide extent. Pyrophyllite is particularly common in foliated zones, adjacent to quartz veins, and near unconformably overlying auriferous conglomerates.The wide distribution of chloritoid and pyrophyllite in metapelites of the Witwatersrand Basin is attributed to alteration of chlorite-rich shales, rather than to unusual premetamorphic starting materials. This alteration event involved the redistribution of many elements, with up to 40% volume loss, mainly due to removal of silica. Removal of most of the Mg and some Fe accounts for the stabilization of chloritoid and pyrophyllite. Relatively immobile elements included Al, Ti, Nb, Cr, V, P, La and Ce, whereas Si, Fe, Mn, Zn, Co, Ni, Cu, Mg and Ca were lost, and K, Rb and Ba were introduced by an infiltrating fluid.The alteration event is inferred to have been within the chloritoid and pyrophyllite stability field (and thus syn-metamorphic) as bulk chemical changes in metapelites are from chlorite directly towards chloritoid and then pyrophyllite, rather than to lower grade minerals such as kaolinite. Muscovite–chlorite–chloritoid and muscovite–chloritoid–pyrophyllite assemblages are attributed to fluid buffering along appropriate curves, as their production by metamorphism of lower grade mineral mixes is considered unlikely, based on the present bulk rock compositional data. A metamorphic timing for the alteration accounts for the correlation of strongly foliated areas with greater degrees of inferred alteration. The transitions from chlorite to chloritoid to pyrophyllite define zones of increasing alteration.Widespread infiltration as part of peak metamorphism is suggested by the distribution of chloritoid and pyrophyllite, quartz veining and textures. Fluid:rock ratios calculated from a silica budget in one metapelitic horizon exceed 100:1 over many square kilometres. These values need not imply multi-pass fluid flow, as much of the silica migration may be redistribution on a scale of a few metres, from source rocks into veins. Although infiltration during metamorphism may have affected much of the upper Witwatersrand succession, channelized fluid flow within reef packages, along faults and unconformities and in certain metaconglomerates and metapelites is inferred.

Notes: Abstract Biotite and cordierite occur in a 1-km wide zone of pelitic hornfelses around the McGerrigle pluton. These phases display systematic changes in XFe that can be attributed to continuous reactions involving chlorite or andalusite in the system KFMASH. Through much of the zone biotite and cordierite were products of the ‘breakdown’of chlorite. Close to the pluton this continuous reaction was terminated by a discontinuous reaction that introduced andalusite. Pelites which interdigitate with apophyses of the intrusive at the pluton margin contain assemblages that record a continuous reaction between biotite, cordierite, andalusite, muscovite, and quartz or, alternatively, the discontinuous breakdown of muscovite and quartz to K-feldspar and andalusite.The mole fraction of Fe in biotite and cordierite increased significantly with the progress of the first continuous reaction and apparently decreased during the second continuous reaction. The KD of Fe-Mg between the minerals decreased and apparently increased, respectively, during the two reactions.Biotite-cordierite-chlorite assemblages are interpreted to have been stable at temperatures between 525° C and 615° C and biotite-cordierite-andalusite assemblages stable at temperatures between 615° C and 635° C. The confining pressure was estimated to have been 〈 2 kbar.The results of this study suggest that the KD of Fe-Mg between biotite and cordierite is a function of temperature, the Fe-Mg exchange characteristics of the controlling continuous reaction and non-ideal mixing of Fe and Mg.

Notes: Abstract Layer-parallel (i.e. parallel to foliation or bedding) vein formation in the graywackes and pelites of the Quetico Metasedimentary Belt occurred during synchronous prograde metamorphism and regional (D2) compression. In a traverse across metasediments which change in metamorphic grade from greenschist to upper amphibolite (migmatite) facies, layer-parallel veins show the following trends: (1) an increase in thickness and internal complexity, the latter due to successive boudinage; (2) low-grade veins are parallel to planes of anisotropy due to the original sedimentary fabric of the host rocks, but at higher grades other sites are also used and (3) a systematic increase in plagioclase/quartz ratio in the veins towards higher grade, adjacent mafic selvedges first exhibit quartz depletion then, in the amphibolite facies, plagioclase depletion. Mineralogical zoning is often preserved in a single vein, older parts are more quartz-rich than younger.Mass balance calculations and whole-rock geochemistry based on veins, mafic selvedges and country rock are consistent with a closedsystem subsolidus segregation origin. The layerparallel veins are syntectonic, and migration of the mobile components required to form their mineralogy is a stress-induced mass transfer. The source of these components appears to be dominantly pressure solution of the same minerals in the host rocks, although metamorphic reactions may also have contributed. Veins nucleated first at those sites where initial sedimentary heterogeneites, such as fine-scale graded bedding, provided gradients of normal stress across grain boundaries, and hence of chemical potential, necessary to drive the subsolidus segregation process. The earliest veins are thus parallel to bedding. Later, nucleation of the veins could also occur along more randomly distributed sites within the metasediments, and these veins grew parallel to the schistosity rather than bedding, if the two were distinct. Once formed, the veins themselves, which are more competent than the surrounding rock, provide the stress heterogeneity required for their further growth. The increasing plagioclase/quartz ratio in the veins may be due to a temperature dependent increase in plagioclase component mobility relative to quartz. Alternatively, the increasing transfer distances for silica, resulting from prior quartz depletion in the inner parts of the mafic selvedge, may increase the relative mobility of plagioclase component.

Notes: Abstract Gneisses from the southern part of the Bunte Series have been studied in order to determine their metamorphic evolution. They all belong to the paragenetic facies type Bt+Sil+ Kfs+Qtz+Grt. The garnets of these rocks generally exhibit typical features of garnets from this high-temperature facies type: diffusional homogenization throughout the bulk of the garnet and retrograde zoning patterns at the outer rim. Ca- and Mn-richer relict cores in some garnets are evidence of the early metamorphism. These cores are enveloped by the high-temperature homogenized garnet. The element distribution curves of the relict cores show evidence of partial element-specific modification by volume diffusion.Paragenetic and textural relations as well as temperature and pressure calculations suggest the following conditions of the main metamorphism: 700–770°C at 7-9 kbar and PH2O PtotDespite the uncertainty due to the incomplete equilibration among garnet rims and other matrix minerals, an attempt is made to model the cooling and uplift history of the rocks using textural, paragenetic, chemical and literature data.〈section xml:id="abs1-1"〉〈title type="main"〉ZusammenfassungGneise aus dem südlichen Teil der Bunten Serie wurden im Hinblick auf ihre Metamorphoseentwicklung untersucht. Sie gehören allgemein dem Faziestyp Bt+Sil+Kfs+Qtz+Grt an. Die Granate weisen alle für diesen Faziestyp charakteristischen Merkmale auf: weitgeheride Homogenisierung durch Diffusion und Abkühlungserscheinungen am äuβeren Rand. Ca- und Mn- reiche reliktische Kerne mancher Granate weisen auf ein älteres Ereignis hin. Diese Relikte werden im homogenisierten Granat höherer Bildungstem-peratur eingeschlossen. Ihre Element- Verteilungskurven sind teilweise durch die intrakristalline Diffusion dem Kationenradius entsprechend abgeflacht.Paragenetische Beziehungen und T- und P-Berechnungen ergeben folgende Bedingungen für die Hauptmetamorphose: 700–770°C bei 7-9 kbar und PH2OPtot.Trotz der Unsicherheit, die auf eine unvoll-ständige Einstellung des Gleichgewichtes zwischen Granaträndern und den übrigen Matrixmineralen zurückzuführen ist, wurde ver-sucht, ein Modell über die Abkühlungs- und Hebungsgeschichte der untersuchten Gesteine zu erstelleu.

Notes: Abstract A study has been made of the high-pressure early-Alpine re-equilibration in the eclogites and metasedimentary cover of the Val d'Ala di Lanzo ophiolite. All of the main high-pressure minerals have been analysed and their compositions used to determine re-equilibration temperatures. The minimum conditions proposed (P= 1.3 GPa, T= 450–460°C) are also indicated by the presence of a jadeite+quartz-bearing metagranite.The temperatures are compared with those reported for similar eclogites from the Voltri Group, the Aosta Valley and the Valais. Comparison of recalculated temperatures shows that the temperature (and probably the pressure) of the eclogitic re-equilibration increased in the Aosta Valley and the Valais, in keeping with what has been observed in the internal Penninic basement of the Gran Paradiso and Monte Rosa crystalline massifs.

Notes: MIGMATITES

Notes: Abstract This work uses a simplified model of equilibrium to predict the assemblage sequence and compositional zoning in garnet that should result from prograde metamorphism of common bulk compositions of pelitic rocks. An internally-consistent set of model thermodynamic data are derived for natural mineral compositions from natural assemblages. Equilibrium assemblages can be calculated for pelitic compositions with excess quartz and either muscovite or K-feldspar at any pressure and water pressure. The compositions and abundances of phases in equilibrium assemblages can be calculated where the elements Mg, Fe and Mn are exchanged among phases. The prograde metamorphic assemblage sequences and the effects of pressure on assemblages, predicted by the simulation method presented here, are similar enough to natural observations to suggest that the simulations can be used to analyse natural equilibrium and growth processes.The calculated phase diagrams at moderate and high crustal pressures explain the mineral assemblage sequence produced by prograde metamorphism in common pelitic compositions. Garnet appears by continuous reaction of biotite and chlorite as the garnet-biotite-chlorite divariant field migrates toward higher Mg/Fe ratios over the bulk composition. Staurolite appears in common bulk compositions when garnet and chlorite become incompatible. An aluminum silicate phase can appear when staurolite and chlorite react. Staurolite breaks down at an extremum point to produce garnet. Continuous reaction of biotite and sillimanite causes growth of abundant garnet.The reaction sequence involving garnet, staurolite and aluminum silicates is probably different at low pressure, but the main reason that staurolite and garnet are rare is the restricted compositional range over which their assemblages exist. Andalusite appears by the divariant reaction of chlorite and cordierite appears at low temperature in low pressure assemblages for common bulk compositions by the extremumpoint breakdown reaction of chlorite.Compositional zoning of garnet and the systematic variation of biotite composition in metamorphic sequences indicate that garnet is probably fractionated during growth. Fractionation of garnet causes garnet-consuming, univariant reactions to become multivariant. The metastable persistence of garnet should reduce the abundance and stability range of staurolite. Fractionation of even small quantities of garnet should deplete the equilibrating bulk composition of Mn, but have little effect otherwise. The simulations show that the prograde assemblage sequence in pelitic rocks can be complex in detail, with some assemblages lasting over temperature intervals of only a few degrees.The major prograde reactions that release water are the breakdown of chlorite to form garnet at low grade and the breakdown of muscovite at high grade. The volume of water released by formation of garnet at high grade is also important. These reactions have the capacity to buffer water pressure.The density of anhydrous pelitic rock increases markedly when chlorite breaks down and by the continuous reaction forming garnet at high grade. The heat content is controlled principally by heat capacity and continuous reactions. Discontinuous reactions have little thermal buffering capacity.Simulations of garnet fractionation show that commonly-observed garnet zoning profiles can be formed by garnet growth in the assemblage garnet-biotite-chlorite in common bulk compositions. A reversal of Fe-zoning in garnet can occur when garnet resumes growth above staurolite grade in the assemblage garnetbiotite-sillimanite. Discontinuities in zoning profiles can be caused only by disequilibrium. The disequilibrium can be due to either metastable persistence during a hiatus in growth or to growth by irreversible reaction.Because the appearance of garnet is controlled by a continuous rather than a discontinuous reaction, the appearance of garnet is very sensitive to bulk composition. The early development of garnet is also sensitive to the pressure and water pressure of metamorphism. As a consequence the first garnet isograd is of limited thermometric value.Metastable persistence of kyanite and manite at high grades could reduce the abundance of garnet and allow biotite to persist. Metastable persistence would also limit the of cordierite formation.

Notes: Abstract The textural and compositional features of phlogopites in a contact-metamorphic dolomite marble inclusion in the Bergell intrusion (central Alps) and in a metasomatic reaction vein cutting through this marble suggest different origins for vein phlogopites:(a) High-Al vein phlogopite represents former marble phlogopite which has been compositionally modified by reaction with the vein forming fluid.(b) Low-Al vein phlogopite represents phlogopite precipitated from the vein forming fluid.As both types of vein phlogopite were in contact with the same vein forming fluid at the same time, low-Al phlogopite most likely represents an equilibrium phlogopite composition, whereas high-Al phlogopite does not. High-Al vein phlogopite retained its Al-content from the contact-metamorphic marble parent phlogopite and only underwent Fe-Mg exchange with the metasomatic fluid.All the vein phlogopites studied are strongly enriched in Fe relative to marble phlogopite. The data may suggest in general that phlogopite Al/Si ratios may be retained from the conditions under which the phlogopites first formed, whereas the Mg/Fe-ratios may be substantially modified by exchange with other ferromagnesian solid phases and/or a metamorphic fluid at later stages in their metamorphic history. This may have significant effects on calculated pressures and temperatures from thermobarometers involving biotite.

Notes: Abstract The Saint-Martin des Noyers Formation is interpreted as a slice of an island-arc system of Lower to Middle Palaeozoic age, located in the internal part of the Variscan orogen in Vendée (Armorican Massif, France). Metamorphosed igneous rocks range in composition from ultramafic to rhyolitic. The regular increase in the FeO/(FeO+MgO) ratio, from mafic to silicic samples, results in a systematic variability in the nature and composition of the metamorphic phases. In basaltic samples, the occurrence of relict garnet-barroisite assemblages suggests relatively high-pressure conditions for the peak of metamorphism. During a subsequent retrograde evolution, the primary barroisitic hornblendes recrystallized to texturally complex mixtures of actinolite and hornblende. Despite this complication, it is possible to decipher a P–T-t path based on amphibole chemistry. The P–T trajectory deduced is dominated by the effect of pressure and consistent with early underthrusting and subsequent tectonic uplift of the ancient arc of Saint-Martin des Noyers.

Notes: Abstract In order to study the thermal structure of active thrust belts, we have developed a numerical model of conductive heat transfer between thrust sheets during deformation. Our finite difference approach alternates small, instantaneous increments of displacement and isotherm translation with conductive relaxation of perturbed isotherms. In each step, conduction occurs for a length of time equal to the displacement increment divided by the thrust velocity. Computer simulations demonstrate that conductive heat transfer is significant during deformation and that temperatures in hanging-wall rocks decrease while temperatures in foot-wall rocks increase over distances of up to 10 km from the thrust surface. When the effects of internal heat production are also calculated, heating of foot-wall rocks exceeds cooling of hanging-wall rocks. Rocks located between two thrusts may experience a complicated temperature–time path of early heating followed by cooling. These models help to explain the rapid metamorphism of rocks in the Taconian thrust belt in the northern Appalachians of New England soon after deposition of the youngest sediments.

Notes: Abstract 40Ar/39Ar age spectrum analysis of phengite separates from Naxos, part of the Attic Cycladic Metamorphic Belt in Greece, indicates that cooling following high-pressure, low- to medium-temperature metamorphism, M1, occurred about 50 Ma ago. Phengite has 40Ar* gradients that suggest that part of the scatter observed in conventional K–Ar ages was caused by diffusion of radiogenic argon from the minerals during a younger metamorphism, M2. In central Naxos, this metamorphism (M2) has overprinted the original mineral assemblages completely, and is associated with development of a thermal dome. Excellent 40Ar/39Ar plateaus at 15.0 ± 0.1 Ma, 11.8 ± 0.1 Ma, and 11.4 ± 0.1 Ma, obtained on hornblende, muscovite and biotite, respectively, from the migmatite zone, indicate that relatively rapid cooling followed the M2 event, and that no significant thermal overprinting occurred subsequent to M2. Toward lower M2 metamorphic grade, 40Ar/39Ar plateau ages of hornblendes increase to 19.8 ± 0.1 Ma; concomitantly the proportion of excess 40Ar in the spectra increases as well. We propose that the peak of M2 metamorphism occurred beween 15.0 and 19.8 Ma ago. K–Ar ages of biotites from a granodiorite on the west coast are indistinguishable from those found in the metamorphic complex, and hornblende K–Ar ages from the same samples are in the range 12.1–13.6 Ma. As the latter ages are somewhat younger than most ages obtained from the metamorphic complex, intrusion of the granodiorite most likely followed the peak of the M2 metamorphism.The metamorphic evolution of Naxos is consistent with rapid crustal thickening during the Cretaceous or early Tertiary, causing conditions at which supracrustal rocks experienced pressures in the range 900–1500 MPa. Transition to normal crustal thicknesses ended the M1 metamorphism about 50 Ma ago. The M2 metamorphism and granodiorite intrusion occurred during a period of heat input into the crust, possibly related to the migration of the Hellenic volcanic ar°C in a southerly direction through the area.

Notes: Abstract The layers of six stromatic migmatites from Northern, Western, and Central Europe display small but systematic chemical and mineralogical differences. At least five of these migmatites do not show any signs of largescale metamorphic differentiation, metasomatism, or segregation of melts. It is concluded, therefore, that the compositional layering observed in most of the investigated migmatites is due to compositional differences inherited from the parent rocks. Almost isochemical partial melting seems to be the most probable process transforming layered paragneisses, metavolcanics, or schists into migmatites.The formation of neosomes is believed to be caused by higher amounts of partial melts formed due to higher amounts of water moving into these layers. The neosomes have less biotite and more K-feldspar, if K-feldspar is present at all, than the adjacent mesosomes. These differences are small but systematic and seem to control the access of different amounts of water to the various rock portions. Petrographical observations, chemical data, and theoretical considerations indicate a close relationship between rock composition, rock deformation, transport of water, partial melting, and formation of layered migmatites.

Notes: Abstract Anatectic migmatites of contrasting structural style are found adjacent to the contacts of the Ballachulish Igneous Complex, Argyllshire, Scotland. On the east flank, evidence for migmatization is largely restricted to the local development of millimetre-centimetre scale Kfs + Qtz-rich leucocratic segregations, which accompany fragmentation of brittle hornfels layers and ductile deformation of mm-cm scale semipelitic layers. Large volumes of semipelitic rock rich in feldspar and quartz on the east flank show no migmatitic features, and bedding is usually preserved undisturbed right up to the contact. On the west flank, in contrast, similar semipelitic rocks show widespread migmatitic features and disruption of layering is substantial and widespread over a 400 m wide zone. Within the west-flank migmatites, 1–100 cm scale rigid bedding fragments (schollen) may be suspended and disoriented in a semipelitic matrix that underwent ductile deformation. The P-T conditions on both flanks are in the same range: 3 kbar and 650–700°C.The contrast in gross structural style is believed to result from differences in the volumes of melt produced and differences in the proportion of rock in which the critical melt fraction of the rocks was exceeded. On the east flank, only on a mm-cm scale was enough melt locally accumulated to cause disruption of some layers and segregation of melt. On the west flank, melting proceeded substantially in a broad tract of semipelitic rocks, resulting in larger scale contrasts in rheology that led to the present chaotic structures in this zone.Because migmatization occurred at a pressure too low for muscovite dehydration melting, and at temperatures too low for substantial biotite dehydration melting, the different amounts of melting on the east and west flanks most probably resulted from the introduction of differing amounts of externally derived water. On the east flank, and throughout most of the aureole, the absence of melting even in quartzofeldspathic protoliths indicates that there was no substantial movement of fluid towards or away from the igneous complex during migmatization. The contrasting situation on the west flank may have resulted from devolatilization of underlying quartz diorite magma (˜ 690–710°C), which released heat and fluids into the overlying quartz- and feldspar-rich semipelites (solidus temperature ˜ 650–680°C).

Notes: Abstract The paragenetic relations of epidote-glaucophane schists are described in terms of the system Al2O3-Fe2O3-Fe2O3-MgO-CaO with excess of quartz, albite and epidote. If alkali-amphibole is free from Ca and AlIV, its composition when associated with epidote is invariant, univariant or divariant at a given pressure and temperature on Miyashiro's (1957) diagram of alkali-amphibole solid solution if it is also associated, respectively, with three, two or one additional minerals in the system.Using a group of epidote-glaucophane schists from the Kotu area of the Sanbagawa metamor-phic belt in Shlkoku, Japan (isophysical compositional),univariant boundary lines were determined for the assemblages that, in addition to the ubiquitous quartz + albite + phengitic mica, contain hematite + chlorite, garnet + chlorite and actinolite + chlorite, respectively. The slopes of the univariant boundary lines obtained from petrographical data are in good agreement with those calculated in a model system.The positions of isophysical univariant boundary lines on the amphibole compositional diagram serve to distinguish the grade of metamorphism among the rocks of the same mineral facies. The hematite-chlorite univariant boundary line can be used to divide the zone of epidote-glaucophane schists of the Sanbagawa metamorphic belt into three, and the garnet-chlorite-paragonite invariant equilibrium can be used to divide the epidote zone of New Caledonia into three.

Notes: Abstract In regional metamorphic rocks, the partitioning of deformation into progressive shearing and progressive shortening components results in strain and strain-rate gradients across the boundaries between the partitioned zones. These generate dislocation density gradients and hence chemical potential gradients that drive dissolution and solution transfer. Phyllosilicates and graphite are well adapted to accommodating progressive shearing without necessarily building up large dislocation density gradients within a grain, because of their uniquely layered crystal structure. However, most silicates and oxides cannot accommodate strain transitions within grains without associated dislocation density gradients, and hence are susceptible to dissolution and solution transfer.As a consequence, zones of progressive shearing become zones of dissolution of most minerals, and of concentration of phyllosilicates and graphite. Exceptions are mylonites, where strain-rates are commonly high enough for plastic deformation to dominate over diffusion rates and therefore over dissolution and solution transfer. Porphyroblastic minerals cannot nucleate and grow in zones of active progressive shearing, as they would be dissolved by the effects of shearing strain on their boundaries. However, they can nucleate and grow in zones of progressive shortening and this is aided by the propensity for microfracturing in these zones, which allows rapid access of fluids carrying the material presumed to be necessary for nucleation and growth. Zones of progessive shortening also have a number of characteristics that help to lower the activation energy barrier for nucleation, this includes a build up of stored strain-energy relative to zones of progressive shearing, in which dissolution is occuring.Porphyroblast growth is generally syndeformational, and previously accepted criteria for static growth are not valid when the role of deformation partitioning is taken into account.Porphyroblasts in a contact aureole do not grow statically either, as microfracturing, associated with emplacement, allows access of fluids in a fashion that is similar to microfracturing in zones of progressive shortening.The criteria used for porphyroblast timing can be readily accommodated in terms of deformation partitioning, reactivation of deforming foliations, and a general lack of rotation of porphyroblasts, with the spectacular exception of genuinely spiralling garnet porphyroblasts.

Notes: Abstract Edenite/tremolite and edenite/magnesio-hornblende in equilibrium with plagioclase, chlorite, epidote, quartz and vapour involve several types of reactions for which KD can be related to T and P. Thermodynamic calculation of these equilibria leads to isopleth systems. Given knowledge of the progressive changes of end-member activities in zoned Ca–Mg amphiboles (based on microprobe analyses), it is possible to construct precise pressure–temperature–time paths (P–T–t paths) which have been followed by metabasites during polyphase metamorphism. When applied to basic rocks from the River Vilaine area, this method allows us to construct a P–T–t path that can be compared directly to the P–T–t path constructed from interbedded acid rocks (aluminous micaschists) in the same structural unit. Through time, both basic and acid rocks underwent the same complex deformation history that can be described conveniently in the L–S fabric system of Flinn. This allows us to construct a P–T–t deformation path for this structural unit.These paths are interpreted in terms of an under/overthrusting continental collision belt (the Hercynian belt), and represent an illustration of the time delay caused by stacking of more than two crustal units.

Notes: Abstract The Western Baja terrane (WBt) of west-central Baja California is an uplifted subduction complex that is divided into smaller ‘subterranes’on the basis of bounding faults and petrological differences. Each subterrane contains coherent Early Jurassic to Early Cretaceous sedimentary and mafic volcanic rocks (not melange) that have been metamorphosed under blueschist facies conditions. Key phases in metabasites and metaturbidites include jadeitic to acmitic clinopyroxene, sodic amphibole, lawsonite, aragonite, chlorite, titanite and white mica. Pressure indicators include the jadeite content of clinopyroxene and the presence of aragonite. Temperature indicators include the presence of lawsonite, the absence of greenschist facies minerals and results from vitrinite reflectance studies. Conditions at the peak of metamorphism were 〉8 kbar, 225–325°C for subterrane 1, 7–8 kbar, 170–220°C for subterrane 2, and 5–6 kbar, 175–200°C for subterrane 3; these correspond to cold geothermal gradients (6–9/km). Vein assemblages that include aegerine–jadeite and aegerine, albite, aragonite, lawsonite and sodic amphibole indicate uplift during continued cold conditions, probably during steady-state subduction.

Notes: LOW TEMPERATURE METAMORPHISM. Edited by M. Frey. Blackie & Son Limited, Glasgow and London. 1987. pp. 364.

Notes: Abstract A deerite-bearing rock occurs at the boundary between quartzite and metabasites within the ‘schistes lustrés’of eastern Corsica. It contains the typomorphic assemblage pyroxene, blue amphibole, hematite and magnetite. Pyroxene shows homogeneous composition close to the aegirine end-member and blue amphibole is zoned from crossite core to riebeckite rim. The bulk chemical analysis of the rock is remarkable by its very high iron content and the presence of an unusually large amount of Zn which is concentrated in both deerite and amphibole. Electron microprobe analyses of the Corsican deerite are compared with those published in the literature; as shown by deerite from the Fransciscan iron formation, the principal substitution for Fe2+ is Mn whereas the amount of substitution for Fe3+ is low. In the system SiO2-FeO-Fe2O3-Al2O3-Na2O-MgO-H2O the typomorphic paragenesis can be described by an univariant reaction interpreted as the result of a pressure decrease. P-T conditions of metamorphism, previously estimated to be 8 kbar and 300°C, are in good agreement with present knowledge of the deerite stability field. The occurrence of hematite and magnetite in equilibrium permits an estimation of the oxygen fugacity (log fo2= -29.41 bar). Oxidation conditions are higher than those previously mentioned in the literature for similar assemblages.

Notes: Abstract Reactivation of early foliations accounts for much of the progressive strain at more advanced stages of deformation. Its role has generally been insufficiently emphasized because evidence is best preserved where porphyroblasts which contain inclusion trails are present. Reactivation occurs when progressive shearing, operating in a synthetic anastomosing fashion parallel to the axial planes of folds, changes to a combination of coarse- and finescale zones of progressive shearing, some of which operate antithetically relative to the bulk shear on a fold limb. Reactivation of earlier foliations occurs in these latter zones.Reactivation decrenulates pre-existing or just-formed crenulations, generating shearing along the decrenulated or rotated pre-existing foliation planes. Partitioning of deformation within these foliation planes, such that phyllosilicates and/or graphite take up progressive shearing strain and other minerals accommodate progressive shortening strain, causes dissolution of these other minerals. This results in concentration of the phyllosilicates in a similar, but more penetrative manner to the formation of a differentiated crenulation cleavage, except that the foliation can form or intensify on a fold limb at a considerable angle to the axial plane of synchronous macroscopic folds.Reactivation can generate bedding-parallel schistosity in multideformed and metamorphosed terrains without associated folds. Heterogeneous reactivation of bedding generates rootless intrafolial folds with sigmoidal axial planes from formerly through-going structures. Reactivation causes rotation or ‘refraction’of axial-plane foliations (forming in the same deformation event causing reactivation) in those beds or zones in which an earlier foliation has been reactivated, and results in destruction of the originally axial-plane foliation at high strains. Reactivation also provides a simple explanation for the apparently ‘wrong sense’, but normally observed ‘rotation’of garnet porphyroblasts, whereby the external foliation has undergone rotation due to antithetic shear on the reactivated foliation. Alternatively, the rotation of the external foliation can be due to its reactivation in a subsequent deformation event.Porphyroblasts with inclusion trails commonly preserve evidence of reactivation of earlier foliations and therefore can be used to identify the presence of a deformation that has not been recognized by normal geometric methods, because of penetrative reactivation. Reactivation often reverses the asymmetry between pre-existing foliations and bedding on one limb of a later fold, leading to problems in the geometric analysis of an area when the location of early fold hinges is essential. The stretching lineation in a reactivated foliation can be radically reoriented, potentially causing major errors in determining movement directions in mylonitic schistosities in folded thrusts.Geometric relationships which result from reactivation of foliations around porphyroblasts can be used to aid determination of the timing of the growth of porphyroblasts relative to deformation events. Other aspects of reactivation, however, can lead to complications in timing of porphyroblast growth if the presence of this phenomenon is not recognized; for example, D2-grown porphyroblasts may be dissolved against reactivated S1 and hence appear to have grown syn-D1.

Notes: Abstract Endogreisens which replace K-feld-spar-quartz dykes in a Devonian (360 Ma) tin deposit at Mt Bischoff, north-west Tasmania, formed from the interaction of unusual solutions, probably derived from an underlying leucogranite pluton, porphyry dykes and limited quantities of local dolomitic country rock components. The intensity of greisenization and pH of the solutions increase inward to the greisenized dykes’cores and downward. The following types of greisen assemblages indicate increasing degrees of greisenization: ‘sericite’muscovite + quartz ± tourmaline ± fluorite, topaz + quartz ± tourmaline ± fluorite, weberite, prosopite, ralstonite, Ca-ralstonite; and quartz ± topaz ± fluorite. Where the solutions interacted with dolomite, exogreisens consisting of topaz- or tourmaline-bearing assemblages were formed. The greisens were subsequently overprinted to varying degrees by siderite, sulphides and hydrous silicates (talc, serpentine, chlorite, micas).The temperature during greisenization ranged from 180 to 414°C, based on fluid inclusions in topaz, quartz, fluorite, sellaite and cassiterite. The main greisen-forming event occurred at temperatures of 360±20°C. The fluids boiled intermittently. Their salinities ranged from 31.5 to 38.9 wt% total dissolved salts, consisting of Ca–K–Na–Fe–Cl±hydrocarbon species. Fluid inclusion data indicate that only 0.5–1.5 km of cover were present above this deposit at the time of formation.The greisenized dykes were intruded by and intrude different stages of breccias. The breccias consist mainly of country rock and greisenized dyke fragments, with rock-flour and later tourmaline alteration. The Mt Bischoff greisen system is possibly part of a ‘porphyry tin’style deposit formed at near-surface conditions (0.5–1.0 km).

Notes: Abstract Dehydration-melting reactions, in which water from a hydrous phase enters the melt, leaving an anhydrous solid assemblage, are the dominant mechanism of partial melting of high-grade rocks in the absence of externally derived vapour. Equilibria involving melt and solid phases are effective buffers of aH2,o. The element-partitioning observed in natural rocks suggests that dehydration melting occurs over a temperature interval during which, for most cases, aH2o is driven to lower values. The mass balance of dehydration melting in typical biotite gneiss and metapelite shows that the proportion of melt in the product assemblage at T± 850°C is relatively small (10–20%), and probably insufficient to mobilize a partially melted rock body.Granulite facies metapelite, biotite gneiss and metabasic gneiss in Namaqualand contain coarse-grained, discordant, unfoliated, anhydrous segregations, surrounded by a finer grained, foliated matrix that commonly includes hydrous minerals. The segregations have modes consistent with the hypothesis that they are the solid and liquid products of the dehydration-melting reactions: Bt + Sil + Qtz + PI = Grt ° Crd + Kfs + L (metapelite), Bt + Qtz + Pl = Opx + Kfs + L (biotite gneiss), and Hbl + Qtz = Opx + Cpx + Pl + L (metabasic gneiss). The size, shape, distribution and modes of segregations suggest only limited migration and extraction of melt. Growth of anhydrous poikiloblasts in matrix regions, development of anhydrous haloes around segregations and formation of dehydrated margins on metabasic layers enclosed in migmatitic metapelites all imply local gradients in water activity. Also, they suggest that individual segregations and bodies of partially melted rock acted as sinks for soluble volatiles. The preservation of anhydrous assemblages and the restricted distribution of late hydrous minerals suggest that retrograde reaction between hydrous melt and solids did not occur and that H2O in the melt was released as vapour on crystallization.This model, combined with the natural observations, suggests that it is possible to form granulite facies assemblages without participation of external fluid and without major extraction of silicate melt.

Notes: Abstract Nearly pure CO2 fluid inclusions are abundant in migmatites although H2O-rich fluids are predicted from the phase equilibria. Processes which may play a role in this observation include (1) the effects of decompression on melt, (2) generation of a CO2-bearing volatile phase by the reaction graphite + quartz + biotite + plagioclase = melt + orthopyroxene + CO2-rich vapour, (3) selective leakage of H2O from CO2+ H2O inclusions when the pressure in the inclusion exceeds the confining pressure during decompression, and (4) enrichment of grain-boundary vapour in CO2 by subsolidus retrograde hydration reactions.

Notes: Abstract The Hidaka metamorphic terrane in the Meguro-Shoya area, Hokkaido, Japan is divided into four progressive metamorphic zones: A—biotite zone; B—cordierite zone; C—cordierite–K-feldspar zone; and, D—sillimanite–K-feldspar zone of the andalusite–sillimanite facies series type of metamorphism. The metamorphic grade ranges from the higher temperature part of the greenschist facies (zone A) through the amphibolite facies (zones B and C) to the lower temperature part of the granulite facies (zone D). The zone boundaries intersect the bedding planes at high angles. P–T conditions estimated are 450–550°C and 2 kbar for zone A, 550–600°C and 2–2.5 kbar for zone B, 600–650°C and 2.5–3 kbar for zone C and 650–750°C and 3–4 kbar for zone D. The metapelites of zone D were partially melted.At the later stage of the regional metamorphism which is early Oligocene to early Miocene in age, cordierite tonalite and biotite tonalite intrusives associated with segments of the highest grade rocks (zone D) were emplaced into the lower temperature part of the regional metamorphic rocks, giving rise to a contact metamorphic aureole. The thermally metamorphosed terrain (zone C') belongs to the amphibolite facies and its P–T conditions are estimated to have been 550–700°C and 2 kbar.The P–T–t paths of the Hidaka metamorphism show a thickening–heating–uplifting process. The metamorphism is inferred to have taken place beneath an active island arc accompanied by partial melting of the crust.

Notes: Abstract Textural relationships between porphyroblasts of biotite and garnet in metasediments in the Nordkinn Peninsula area of the Finnmarkian Caledonides of North Norway are apparently complex. There is evidence for two textural zones in both mineral phases and superficially the development of these appears to have overlapped, at least in part, in time and space. This apparently complex porphyroblast growth history can be considerably simplified if only one period of garnet growth occurred and if different inclusion fabrics developed where garnet replaced biotite porphyroblasts and where it overgrew the matrix foliation. The possibility that porphyroblasts with textural evidence for multiphase growth histories actually grew during a single crystallization event is of importance in the interpretation and elucidation of tectonometamorphic relationships.

Notes: Abstract Retrograde and prograde mineral assemblages from metapelitic and metabasic rocks of the Iforas Granulitic Unit (Mali) were generated by the superimposition of two granulite facies metamorphic events. They clearly result from a polycyclic evolution and can be related to a late Eburnean unroofing followed by a Pan-African burial.Thermobarometry on Pan-African garnet-bearing assemblages yields (P, T) estimates of 620±50°C and 5± Ikbar. The nearly anhydrous conditions produced in the Eburnean appear to be the direct cause of the unusually lowtemperature granulite-facies metamorphism in the Pan-African. These P, T estimates are compared with those obtained on the underlying unit (Kidal Assemblage) upon which the Iforas Granulitic Unit was thrust. A P-T-t path, during the Pan-African orogeny, is proposed and discussed for both the Iforas Granulites and Kidal Assemblage.

Notes: Abstract Fluids, some of which are CO2-rich (up to 40 mol.% CO2) and some of which are highly saline (up to 18 wt% NaCl equivalent), are trapped as fluid inclusions in quartz-calcite (∼ metallic minerals) veins which cross-cut the pumpellyite-actinolite to amphibolite facies rocks of the Alpine Schist. Fluids were commonly trapped as immiscible liquid-vapour mixes in quartz and calcite showing open-space growth textures. Fluid entrapment occurred at fluid pressures near 500 bars (possibly as low as 150 bars) at temperatures ranging from 260 to 330° C. Saline fluids may have formed by partitioning of dissolved salts into an aqueous phase on segregation of immiscible fluids from a low-density CO2-rich fluid. Calcite deposited by these fluids has δ13C ranging from – 8.4 to – 11.5 and δ18O from + 4 to + 13. Isotopic data, fluid compositions and mode of occurrence suggest that the fluids are derived from high-grade metamorphic rocks. Fluid interaction with wall-rock has caused biotite crystallization and/or recrystallization in some rocks and retrogression of biotite to chlorite in other rocks.Fluid penetration through the rock is almost pervasive in many areas where permeability, probably related to Alpine Fault activity, has focussed fluids on a regional scale into fractured rocks. The fluid flow process is made possible by high uplift-rates (in excess of 10 mm/year) bringing hot rocks near to the surface.

Notes: Abstract Fluid inclusions in ore skarn minerals reflect the physiochemical nature of the solutions present during the skarn-forming process. Because of the dense nature of skarn minerals and the dynamic processes operative during skarn genesis, sufficient primary fluid inclusions are usually present. Ore skarn solutions, as opposed to metamorphic skarn or ore vein solutions, have much higher CaCl2 contents and usually very high formation temperatures (〉500°C) and salinities (〉40 wt % T.D.S.). Temperatures and salinities generally decrease away from the solution source, both in time and space. The gradients found at greater distances from the source in distal (far from contact) skarns tend to be less (e.g. 210–350°C) for a particular skarn stage to that in proximal (near contact) skarns (e.g. 400–650°C). This information is useful for delineating the parts of such a hydrothermal system. Temperatures also tend to decrease with time, which is reflected by the superimposition of various overprinting, retrograde mineral stages. In a few areas (e.g. Naica, Mexico) intermittent boiling of ore solutions occurs, periodically elevating both temperatures and salinities, but commonly boiling only occurs early in skarn genesis just after an early, commonly lower temperature, phase.Most fluid inclusions represent a mix of‘exhaust’or reacted solutions with minor unreacted or new (pre-) ore solution components. Limited data on the distribution of elements present in fluid inclusions that do not normally take part in skarn genesis (Na, K and Cl) indicate that their proportions reflect the nature of the associated pluton. High KC1 contents are found in skarns adjacent to high K granitoids, whereas high NaCl contents are found in skarns adjacent to calcic granitoids.In many examples, daughter minerals present in minor proportions in opened fluid inclusion cavities reflect the metal characteristics of the ore solution. Small rare-earth metal, tungsten, zinc and copper daughter(?) minerals have been identified. The temperature and (or) salinity data for skarns of different metal or geological type is not particularly useful to delineate whether a skarn locality is part of a more complex, as yet unexplored system. Solutions in Pb–Zn skarns tend to be lower-temperature (150–400°C) and more dilute (〈30 wt % T.D.S.) than in other skarn types, but exceptions occur.

Notes: Abstract In the Kamuikotan zone, jadeite occurs in pelitic rocks, in metaplagiogranites, in veins in amphibolites and mafic sedimentary rocks, and in jadeite-albite rocks. In the first and second types, jadeite is associated with quartz, and is often in direct contact with it. However, such rock-types never occur as part of the coherent metamorphic sequence, but are found only as exotic blocks enclosed in serpentinite. Thus, jadeite + quartz-bearing assemblages are not regarded as representative of the Kamuikotan metamorphism. Lawsonite and aragonite, however, commonly do occur in the Kamuikotan metamorphic rocks, and this metamorphism belongs to a subfacies of the lawsonite-albite facies, in which aragonite is stable. The serpentinite matrix which carried jadeite + quartz-bearing pelites and metaplagiogranites into the metamorphic sequence is interpreted as a tectonic rather than a sedimentary melange.

Notes: Abstract Contact aureoles of plutons emplaced into regionally metamorphosed terranes can provide indicators of physical conditions along a portion of regional metamorphic P-T trajectories, thereby allowing reconstruction of more complete P-T loops than would be otherwise possible. In the Northern Alabama Piedmont of the southern Appalachians, Wedowee Group metapelites preserve evidence for two regional metamorphic phases overprinted by contact metamorphism adjacent to the Blakes Ferry Trondhjemite. Textural evidence indicates that an early bt+st+grt assemblage was replaced by bt+chl+grt during the latter stages of regional metamorphism. Changes in AKFM topology, complex Fe-Mg-Ca garnet zoning, and the latestage appearance of epidote indicate that a sequence of continuous reactions (bt+st = grt+ ms followed by chl+ms+Ca-grt+Ca-pl=bt+ (Fe+Mg)-grt+ep) occurred in response to increasing pressure and resulted in the observed changes in mineral assemblage. Pl-ms-bt-grt thermobarometry indicates conditions of 580° 65°C, 8.5±0.8 kbar for equilibration of grt+ bt+chl. Pluton emplacement, subsequent to penetrative deformation, caused textural annealing and mineral re-equilibration by the continuous reaction bt+(Fe+Mg)-grt+ep = chl+ms+Ca-grt+Ca-pl within 50 m of the pluton. Conditions of 510±65°C, 5-7 kbar are inferred. A reconstructed P-T trajectory for this area is characterized by (1) early moderate-T, moderate-P metamorphism; (2) an increase in P to approximately 8.5 kbar; and (3) decompression and slight cooling prior to pluton emplacement. The compressional phase of this path is interpreted to result from underthrusting of the Wedowee metasediments to mid-crustal levels during Palaeozoic crustal thickening. Late-stage decompression prior to intrusion records uplift of these rocks in response to movement on structurally lower thrusts.

Notes: Abstract Mineralogical and petrological studies of Triassic Verrucano metasediments of the Northern Apennines are reported. The widespread occurrence of Al-silicates allows the delineation of four metamorphic zones with increasing metamorphic grade: (1) kaolinite zone (well Perugia 2, Umbria); (2) kaolinite-pyro-phyllite zone (Monte Argentario and part of the Verrucano of the Monticiano-Roccastrada area and Monti Leoni); (3) pyrophyllite zone (Monti Pisani, Iano, Monti Leoni, the Monticiano-Roccastrada area and some wells in the Larderello region); (4) kyanite zone (Massa area and some wells in the Larderello area).The four metamorphic zones correspond to temperatures ranging from 300°C to about 450°C. On the basis of the Si content of muscovite and geological arguments, pressures of between 3 and 5 kbar are estimated. The metamorphic zones are located more or less parallel to the bent north-west-south-east trending structural zonation of the Northern Apennines, with the concave side towards the Tyhrrenian Sea.During the Alpine orogeny, the Verrucano metasediments underwent three folding phases each of which has produced an axial plane schistosity (S1, S2, S3). During the first folding phase the Verrucano sediments were buried increasingly deeply within the crust from east to west. The climax of Alpine metamorphism was attained prior to the second folding phase with crystallization of porphyroblasts of kyanite and chloritoid in a central area located between Massa and Larderello. The inferred paleo-temperature distribution pattern resembles an asymmetric thermal high defined by the kyanite zone, and surrounded by the pyrophyllite zone. A similar pattern is still present in the Tuscan crust, as indicated by a series of geothermal anomalies passing through the Northern Apennines.

Notes: Abstract Rare layers of an aluminous, muscovite-rich rock from the Lewisian Complex at Stoer, North-West Scotland, display evidence which suggests that the rock has undergone local partial melting to form quartz-bearing veins and a corundum-bearing restite. The assemblages observed in these rocks match those predicted by modelling in the system KAlO2-NaAlO2-Al2O3-SiO2-H2O (KNASH) where certain bulk compositions melt peritectically to give corundum-bearing restites and quartz-normative melts. Study of the model system shows that the observed parageneses could have formed from a range of bulk compositions with a variety of possible values of aH2O which could have been internally or externally buffered. The KNASH petrogenetic grid, together with another in the system CaO-Na2O-FeO-Al2O3-SiO2-H2O (CNFASH), allows the P–T path of the rocks to be delineated and an estimate to be made of the conditions at the peak of metamorphism as 〉 11 kbar and 900-925°C. This estimate is in agreement with P–T estimates using thermobarometric methods on adjacent lithologies: The activity of H2O in the system throughout metamorphism is calculated to have been 〉0.3.

Notes: Abstract The Tal y Fan Intrusion is a 110 m thick sub-concordant metabasite sheet intruded into volcaniclastic and pyroclastic rocks of Ordovician age in North Wales. Despite low grade metamorphism, primary textural zones resulting from initial cooling of the sheet are preserved and retain primary mineralogical and chemical variations which influenced the nature and extent of metamorphic recrystallization. This has resulted in a vertical sequence of secondary mineral assemblages through the intrusion. During early hydrothermal alteration K-feldspar replaced plagioclase micropheno-crysts in the marginal and contact zones, and olivine in the central zone was replaced by saponite. Subsequent regional metamorphism resulted in the development of (metastable) prehnite-pumpellyite-epidote assemblages in two sub-zones characterized by high Fe2O3. Elsewhere the assemblage prehnite-actinolite-epidote developed except in the contact and marginal zones where activity of CO2 suppressed both prehnite and pumpellyite. Both assemblages contain excess albite, quartz and chlorite and, on the basis of uniform mineral compositions over the area of an individual thin section, are considered to represent buffered equilibrium assemblages indicative of prehnite-pumpellyite and prehnite-actinolite facies conditions. A metamorphic temperature of 310° C at 1.85 kbar is obtained using the P-T-X grid of Liou, Maruyama & Cho (1985), which implies a field gradient of ∼ 44° C km-1. Assuming that metamorphism relates to burial, an overburden thickness of ∼ 7 km is indicated. Total maximum thicknesses, however, of Ordovician, Silurian and Lower Devonian strata, in the area, do not exceed 6 km indicating a field gradient of 52° C km-1. These relatively high gradients may possibly be related to concealed late Caledonian intrusions, or alternatively may result from high heat flow as a consequence of crustal thinning, rapid sedimentation and intense magmatic activity in a marginal basin setting.

Notes: Abstract Mineralogical and geochemical evidence indicates that partial melting and desulphidation have occurred in the Big Bell gold deposit. Decarbonation may also have occurred, to account for the lack of a carbonate alteration halo; this is compatible with the present data, but difficult to test.The Big Bell deposit consists of auriferous sulphide-bearing (‘lode’;) schists with muscovite and K-feldspar, and surrounding biotite schists, all derived by intense premetamorphic alteration of rocks of mafic composition. Assemblages which include cordierite-sillimanite-K-feldspar-garnet-biotite-quartz suggest peak metamorphic conditions of 4–5 kbar, and 650–700° C, based on phase relations, geobaro-meters and garnet-biotite Fe-Mg exchange partitioning. Partial melting occurred at peak metamorphism, particularly in the altered mafic rocks in and around the deposit, and its occurrence may have been essential to the preservation of the deposit. Melting greatly limited the importance of devolatilization reactions, resulting in negligible aqueous fluids and no means of removing appreciable gold. Minor gold loss may have accompanied desulphidation. A diversity of complex metamorphic assemblages occurs around the mine, compared to the assemblages developed regionally; variable bulk rock composition influences this contrast, but there is no evidence of higher metamorphic grades at the mine, nor that this might have been the prime control on the different assemblages in this narrow belt.It is suggested that the Big Bell and Hemlo deposits are the higher metamorphic grade equivalents of the more abundant greenschist facies gold deposits within Archaean greenstone belts. This interpretation is favoured by the host rock setting and geochemical characteristics of Big Bell. Alternative models that suggest that this class of deposit is a new type must account for the absence of high-grade equivalents of the greenschist facies deposits and also the lack of low-grade equivalents of the Big Bell/Hemlo type.Archaean gold deposits in high-grade metamorphic terrains have undergone a series of processes that are not recorded in the more typical gold deposits of the greenschist facies.

Notes: Abstract. Simple predictions of deep drainage in the soil profile are often required for preliminary planning of land management where the cost of direct measurement is not warranted. Soil hydraulic conductivity and drainage of water below the root zone can be related to the salt content at the bottom of the root zone, assuming steady-state balances of water and salt. A physically based empirical model uses readily measured soil properties to predict the quantity of drainage below the root zone under varying regimes of water management and shows a good relationship with ponded infiltration rate.

Notes: Abstract. The applicability of the ‘threshold concentration’ concept in formulating guidelines for irrigating with saline water was tested under field conditions on red-brown earths from different field experiments in south eastern Australia. Infiltration of water in the field and the effect of rainfall impact were studied using ring infiltrometers and a rotating-disc rainfall simulator.Three threshold concentration lines relating sodium adsorption ratio (SAR) and total cation concentration (TCC) in soil extracts were tested. These lines were based on laboratory tests of soil permeability, spontaneous dispersion and mechanical dispersion. They were found to predict the infiltration problems due to rainfall impact under three different surface soil conditions - bare soil without cultivation, soil with no tillage and complete crop cover, and cultivated soils without any crop cover.Infiltration rates in continuous pasture plots were predicted by the threshold concentration line of spontaneous dispersion except in a high salt treated soil where reduced plant growth affected evapotranspiration and water intake during infiltration.

Notes: Abstract. The soil solution may contain both plant nutrients and toxic ions. The total salt concentration affects both osmotic pressure and plant water stress. This review describes the main methods of evaluating soil salinity. They are listed as extraction methods (saturation and other soil extracts, suction cups), displacement methods (pressure membrane, centrifugation) and electrical methods of total salinity measurement (salinity sensors, four-electrode methods and time-domain reflectometry). The methods are compared so that the reader may choose the one most suitable for his purpose, based on cost, on the inherent advantages or drawbacks of the methods themselves, on his need for single or repeated measurements and either estimates of total salinity or the concentration of selected ions.

Notes: Abstract. The interaction of caesium isotopes with soil has been widely investigated and the influence of important soil properties studied. From the results of such work and a detailed knowledge of the physico-chemical properties of soils it is possible to classify Cumbrian soil according to its ability to immobilize caesium. The ‘immobilization capacity’ is a reflection principally of the clay mineral content and type, organic content, pH, ammonium content and potassium status. Although it is not quantifiable, the immobilization capacity permits ranking of the soils and indicates which areas may give rise to persistent caesium problems. Combination of the soil sensitivity classification with deposition data for Cumbria indicates that the mountainous region in the south-west of the county is the most vulnerable. This conclusion is supported by field evidence, since the area identified coincides closely with that where sheep movement and slaughter are restricted and where caesium remains persistently available to the plant-animal chain.

Notes: Abstract. Mathematical models describing radionuclide transport in soil developed for radiological assessment have increased in complexity over the last decade. In particular fairly simple ‘black box’, equilibrium approaches have given way to more complex, time-dependent, process-orientated methods. The increase in complexity of these models has outstripped the available data to specify, test and validate them. Current issues in model development include those that are associated with times up to a million years. Further development requires new laboratory and field research to provide adequate data to justify the inclusion or omission of known soil processes.

Notes: Abstract. The factors influencing uptake of radionuclides from soils into vegetation are discussed with reference to soil type, radionuclide, plant species and organ, and time since initial contamination. Gaps in knowledge are identified, particularly as highlighted by the unexpected behaviour of radiocaesium in many upland areas of Britain, following deposition after the Chernobyl accident. The importance of resuspended soil for contamination of aerial plant parts is also considered in relation to radionuclide type, vegetation height, and meteorological conditions.The development of an international database by the International Union of Radioecologists for soil to crop transfer factors of radionuclides derived from European experiments is briefly described. This database is now being used for statistical analyses aimed at quantifying the importance of environmental and biological factors in influencing uptake of radionuclides from the soil.

Notes: Abstract. The Rothamsted Drain Gauges built in 1870 comprise blocks of soil, 0.5, 1.0 and 1.5 m deep, isolated laterally by brickwork and undermined for the collection of drainage water but otherwise undisturbed. The soil has not been cropped, manured or cultivated subsequently. The annual nitrate leakages from these blocks were recorded for the 38 years from 1877/8 to 1914/5. The soil in the 0.5 and 1.5-m gauges lost on average about 45 kg ha−1 of nitrate-N per year during the first seven years of this period; that in the 1.0-m gauge lost slightly less. The overall decline in leakage was masked by large annual fluctuations attributable mainly to variation in rainfall. Fitting a simple function that assumed an exponential decline and took account of rainfall fluctuations gave a rate constant for each gauge from which the half-life could be estimated for the organic nitrogen feeding the leakage. The half-life for the 1.5-m gauge was 41 yr. The average nitrate leakage during the first seven years of the record differs little from estimates of the current leakage from soil carrying fully fertilized crops of winter wheat. This and the long half-life of the leakage show that pollution of drainage water by nitrate will not be controlled by limiting the use of fertilizer in the short term.

Notes: Abstract. Fifteen soil profiles in the Alltcailleach Forest in NE Scotland have been resampled after almost 40 years. The pH, in 0.01 M CaCl2, of the soil has decreased by 0.07 to 1.28 units in 80% of the surface organic horizons and by 0.16 to 0.54 units in 73% of the mineral horizons below 40 cm. The key factors governing increases and decreases in soil pH are changes in ground vegetation and tree canopy, although some effects of acid deposition cannot be ruled out.

Notes: Abstract. Erosion and excessive runoff from a crusting and hard-setting red-brown earth may he ameliorated with suitable management. A field trial, near Cowra, New South Wales, to assess the long-term effect of different tillage systems was used to compare the effect of direct drilling with conventional district cultivation practices under continuous wheat. The soil was sampled in the eighth year for assessment of the soil macropore structure, measurement of bulk density and hydraulic conductivity under tension. Vertical faces were prepared from resin impregnated blocks and the macropore structure described mathematically and visually using digital images and data generated from these images. Infiltration, bulk density and image analysis data all lead to the same conclusions about changes in pore structure. Under direct drilling no crust was evident, and there was greater macroporosity (〉 0.175 mm diameter in section). The treatment effects appeared to be significant to about 30 to 35 mm depth at the time of sampling. Greater root and faunal activity were observed under direct drilling.

Notes: Abstract. People in rural areas have disposed of their wastes on land for centuries, relying on the soil's ability to degrade and render harmless any toxic elements the wastes may contain. Leather tanneries produce a large amount of sludge and liquid wastes. The liquids contain much sodium and in most circumstances adversely affect both the soil and groundwater. However, in some countries they are used for irrigation. The sludges contain nitrogen, calcium, magnesium, phosphorus, trivalent chromium and some sodium. Given careful management these sludges can be used as soil amendments, either directly or after composting. Application rates of about 200 tonnes ha−1 have proved toxic to crops in pot trials, though larger applications than this have not adversely affected crops in the field. Much smaller rates, of less than 20 tonnes ha−1, have been used in the field to minimize nitrate contamination of groundwater. The effects of CrIII depend on complex interactions between the sludge, the soil to which it is added and the plant species grown. Safe limits for the disposal of the sludges and their long term effects are not known.

Notes: Abstract. Research on soil erosion under forest in Britain is reviewed. Erosion can increase as a result of afforestation in the uplands, sometimes with undesirable consequences for surface water quality. Published rates of erosion are usually close to ‘natural’ ones, at around 500 kg ha−1 yr−1. Of the forest operations that can lead to erosion ploughing is the most important. Clearfelling may also increase erosion, but little is known of its long-term effects. New developments in forestry may do much to reduce the risk of soil erosion, particularly the replacement of ploughing by subsoiling and the control of drain gradients.

Notes: Abstract. A simple model for droughtiness, when linked to the distribution of soil types in England and Wales, is potentially valuable for estimating drought-induced losses of yield in winter wheat at either particular places or in larger areas of the country. The model defines droughtiness, D, in terms of the soil water extractable by the crop, AP, and the adjusted potential moisture deficit, MD: D=AP−MD.The model should represent well the growth of actual crops of winter wheat if AP, which is based on laboratory measurements, accurately simulates the extraction of soil water by roots, if MD represents the cumulative transpiration of water by wheat crops by mid-July, and if the latter is an appropriate date for testing the effect of drought on grain growth. These three assumptions have been investigated using measurements of artificially draughted crops of winter wheat.The results indicate that mid-July is a good choice for a single date and MD a good representation of the water requirement of a wheat crop that has been draughted to the point where yield is beginning to be affected. For the deep-rooting crops studied, AP underestimates the soil water extracted by the crop, and therefore overestimates the susceptibility of the soil to droughtIf average MD values are replaced by means and a standard deviation the resulting normal distribution of D-values can be used to assess the probability that drought will limit yields. When applied to a droughtiness map of England and Wales with AP-values used for the soils the model predicts that the soils growing wheat will be susceptible to drought in 16–84 years out of every 100. Our results suggest, however, that this probably applies to shallow rooting or diseased crops and that for deep-rooting, healthy crops the drought risk is much less serious.

Notes: Abstract. Ploughing and tine cultivation to depths of 5, 15 and 25 cm were used to prepare land before sowing winter wheat. The methods were compared for two years with or without the presence of straw residues from the previous crop and the effects on crop growth and yield were assessed.Some combinations produced large differences in yield. In 1985–86 volunteer cereals were a problem where straw was not burnt, but deeper ploughing controlled them. In both years the concentrations and uptake of nitrogen, phosphorus and potassium differed during the early period of growth but not at maturity.

Notes: Abstract. The experiment conducted jointly by the Forestry Commission (FC) and the Institute of Terrestrial Ecology (ITE) at Beddgelert Forest, North Wales, studies the effect of conventional clear-felling (CF) and whole-tree harvesting (WTH) of Sitka spruce (Picea sitchensis) on the local ecosystem and on the future productivity of forestry at the site. Bulked soil samples were taken from Block 2 of the experiment just before felling in 1984 and two years later in 1986. Sub-samples from the horizons Ah, E and B+C were analysed for exchangeable and short- and long-term reserves of K using Ca-resin and strong acid extraction procedures. The flux of K through the soil profile after both CF and WTH resulted in a small increase in exchangeable K throughout the profile after both treatments, but in a loss of short-term reserves from the surface Ah horizons of both and an overall loss of these after WTH. The nutrient flux down-slope through the Ah horizon could result in differential nutrient deficiency in future. The data suggest that exchangeable and short-term reserves of K will support about two further cycles of conifers, with either CF or WTH, but that long-term reserves are likely to be released quickly enough to meet the needs of such a slow-growing crop; these would support about 30 cycles. Other nutrients, such as Ca or P, may prove to be more limiting than K.

Notes: Abstract. The effect of eight years of applications of five rates (0, 134, 269, 538 and 1075 m3 ha−1 a−1) of pig slurry on the soil strength two years later were studied in a field experiment. Soil strength in the 0–150 mm depth was measured on five occasions in winter using a hand-held recording cone penetrometer. On one occasion the penetration resistance at some depths greater than 100 mm was significantly (P 〈 0.001) decreased by adding more than 269 m3 of slurry ha−1 a−1. On three occasions different amounts of slurry caused significant differences in the rate of increase of penetration resistance with depth. Large applications of slurry may decrease penetration resistance because they increase organic matter, thereby increasing the water retention of the soil.

Notes: Abstract. In a field experiment over two years, broad beans (Vicia faba), cabbage (Brassica oleracea var. capitata), leeks (Allium porrum) and red beet (Beta vulgaris var. esculenta) were grown on a sandy clay loam soil in which a range of bulk densities and penetration resistances had been established by (1) thorough loosening to 0.9 m by trenching, (2) artificially compacting with tractor wheelings or (3) leaving unloosened.Loosening the soil substantially increased, and compacting it decreased, yields of all four crops. The mean penetration resistance of the subsoil at field capacity correlated negatively with dry matter production. The relationship was broadly similar for all crops and years, showing a decrease in dry matter production of about 1 t ha-1 per 0.5 MPa increase in resistance over the range examined.

Notes: Abstract. Soil water samples from five horizons in a stagnopodzol were collected regularly over a five-year period in a Sitka spruce plantation at Beddgelert Forest, North Wales. Samples were analysed for nitrate-N and ammonium-N. After felling, inorganic-N concentrations increased markedly in the C horizon, generally decreased in the surface horizons and showed little change in the E and Bs horizons. Fluxes through the C horizon increased after felling from 10 to 70 kg N ha-1 a-1, the latter being equivalent to leaching losses in intensive lowland agricultural systems. Trends in concentration and flux were attributed to seasonal temperature and rainfall variations.Nitrate-N dominated the dissolved inorganic-N, especially in the lower horizons. Nitrification was obviously active, despite the acid soil. Nitrate leaching losses occurred, even beneath the standing crop. On felling, cessation of nitrogen uptake allowed substantially more nitrate to be leached as no alternative sink was immediately available.

Notes: Abstract. Plots of spring barley, winter wheat and winter barley were sheltered with netting in a coastal area of North-East England. Crop height, yield components and grain yield were measured and compared with unsheltered crops receiving the same agronomic treatments. Plant height, ears m-2, 1000 grain weight and grain yield were increased by shelter in seasons with windy, dry weather during the tillering and stem extension phases. Negligible response was found in a wet season. One experiment suggests that greater applications of nitrogen fertilizer can counteract the effects of exposure.

Notes: Abstract . A combination of crop photography and crop radiance (near-infrared and red) values are used to measure ground cover establishment (leaf area). The high correlation between the green leaf area and near-infrared/red ratio (NIR/R) can provide a non-destructive method for monitoring crop growth. Using this relationship the effects of pre- and post-emergence herbicide treatments (Metazachlor) on winter oilseed rape were studied. It is shown that pre-emergence spraying reduces germination and autumn and spring growth rates. One management aspect of pre-emergence spraying is the delay in achieving ground cover. For marginal crops on soils with a high risk of erosion critical ground cover may be delayed by as much as two weeks.