ALBERT

All Library Books, journals and Electronic Records Telegrafenberg

Your email was sent successfully. Check your inbox.

An error occurred while sending the email. Please try again.

Proceed reservation?

Export
Filter
  • Column liquid chromatography  (133)
  • Sudan
  • Turbulence
  • Springer  (180)
  • Annual Reviews
  • 2020-2024
  • 2005-2009  (2)
  • 1990-1994  (113)
  • 1980-1984  (65)
  • 2009  (2)
  • 1990  (113)
  • 1984  (65)
Collection
Keywords
Years
  • 2020-2024
  • 2005-2009  (2)
  • 1990-1994  (113)
  • 1980-1984  (65)
Year
  • 1
    Publication Date: 2022-05-25
    Description: © 2008 The Author. This is an open-access article distributed under the terms of the Creative Commons Attribution Noncommercial License. The definitive version was published in Environmental Fluid Mechanics 8 (2008): 551-560, doi:10.1007/s10652-008-9076-5.
    Description: Experiments are reviewed in which a two-layer salt-stratified tank of water was mixed by turbulence. The density profile began as a single step and evolved to a smooth mixed profile. The turbulence was generated by many excursions of a horizontally moving vertical rod with Richardson number Ri 〉 0.9 and Reynolds Number Re 〉 600. There was almost perfect collapse of all the profiles to one universal profile as a function of a similarity variable. We develop a theoretical model for a simple mixing law with a buoyancy flux that is a function of internal Richardson number Rii. A similarity equation is found. A flux law that increases with small Rii and decreases with large Rii is considered next. Since no analytical solution is known, the similarity concept is tested by numerically integrating the equations in space and time. With buoyancy flux monotonically increasing with internal Richardson number, the similarity approach is valid for a profile starting from a slightly smoothed step. However, a shock forms for a mixing law with higher initial Rii (so that buoyancy flux decreases with Richardson number) and the similarity approach is invalid for those initial conditions.
    Keywords: Turbulence ; Mixing ; Stratified ; Similarity solution ; Layered fluid
    Repository Name: Woods Hole Open Access Server
    Type: Article
    Format: application/pdf
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 2
    Publication Date: 2022-05-25
    Description: © 2008 The Authors. This is an open-access article distributed under the terms of the Creative Commons Attribution Noncommercial License. The definitive version was published in Environmental Fluid Mechanics 8 (2008): 495-509, doi:10.1007/s10652-008-9107-2.
    Description: Estuarine turbulence is notable in that both the dissipation rate and the buoyancy frequency extend to much higher values than in other natural environments. The high dissipation rates lead to a distinct inertial subrange in the velocity and scalar spectra, which can be exploited for quantifying the turbulence quantities. However, high buoyancy frequencies lead to small Ozmidov scales, which require high sampling rates and small spatial aperture to resolve the turbulent fluxes. A set of observations in a highly stratified estuary demonstrate the effectiveness of a vessel-mounted turbulence array for resolving turbulent processes, and for relating the turbulence to the forcing by the Reynolds-averaged flow. The observations focus on the ebb, when most of the buoyancy flux occurs. Three stages of mixing are observed: (1) intermittent and localized but intense shear instability during the early ebb; (2) continuous and relatively homogeneous shear-induced mixing during the mid-ebb, and weakly stratified, boundary-layer mixing during the late ebb. The mixing efficiency as quantified by the flux Richardson number Rf was frequently observed to be higher than the canonical value of 0.15 from Osborn (J Phys Oceanogr 10:83–89, 1980). The high efficiency may be linked to the temporal–spatial evolution of shear instabilities.
    Description: The funding for this research was obtained from ONR Grant N00014-06-1-0292 and NSF Grant OCE-0729547.
    Keywords: Turbulence ; Estuaries ; Shear instability ; Buoyancy flux
    Repository Name: Woods Hole Open Access Server
    Type: Article
    Format: application/pdf
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 3
    ISSN: 1436-6215
    Keywords: protein-energymalnutrition ; vitaminE status ; children ; Sudan ; developingcountries ; Protein-Energie-Mangelernährung ; Vitamin-E-Status ; Kinder ; Sudan ; Entwicklungsländer
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Medicine
    Description / Table of Contents: Zusammenfassung Das Gesamttocopherol und alpha-Tocopherol wurden im Plasma von Kindern mit schwerer Mangelernährung (14 Maramus; 11 marantischer kwashiorkor; 5 kwashiorkor) bestimmt und auf die Gesamtlipide des Plasmas und auf die verschiedenen Plasmalipidklassen bezogen. Wenn die reinen Plasmakonzentrationen als ein Index des Vitamin-E-Status genommen würden, so wären 5 Kinder mit Marasmus, 5 Kinder mit marantischem kwashiorkor und 2 Kinder mit kwashiorkor als defizitär (〈500 μg/dl) anzusehen. Werden jedoch Gesamttocopherol und alpha-Tocopherol auf die Gesamtlipide bezogen, so zeigten alle mangelernährten Kinder — bis auf eines — Werte, die innerhalb der Grenzen lagen, die für gesunde amerikanische Kinder gefunden wurden. Die Studie zeigt, daß niedrige Tocopherol-Lipid-Verhältnisse kein konstantes Merkmal bei schwer mangelernährten Kindern sind.
    Notes: Summary Total tocopherols and alpha-tocopherols were estimated in the plasma of children with severe malnutrition (14 marasmus; 11 marasmic kwashiorkor; five kwashiorkor) and related to the total plasma lipids and different plasma lipid classes. If the mere plasma concentrations were taken as an index of the vitamin E status, five children with marasmus, five children with marasmic kwashiorkor, and two children with kwashiorkor would have been regarded as deficient (〈500 μg/dl). However, if total tocopherols and alpha-tocopherols were related to the total plasma lipids, all malnourished children — except one — showed values within the limits found in healthy American children. The study shows that low tocopherol/lipid ratios are not a constant feature in severely malnourished children.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Pure and applied geophysics 132 (1990), S. 457-479 
    ISSN: 1420-9136
    Keywords: Turbulence ; mesures aéroportées ; fluctuation de pression ; presso-corrélations
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Résumé Nous avons décrit dansBardeau et al. (1987), la réalisation, le fonctionnement et les tests d'un microdébitmètre basé sur l'anémométrie à fil chaud. Il a été particulièrement montré que cet appareil était bien adapté aux mesures de pression et pression différentielle avec une grande sensibilité et une très faible constante de temps. Nous présentons ici les applications qui ont été faites de ce capteur aux mesures à haute résolution à bord d'avions instrumentés pour la recherche atmosphérique. L'avion utilisé était spécialement équipé pour les mesures de turbulence et permettait donc l'acquisition d'un grand nombre de paramètres indispensables à l'analyse des données de ce capteur. Dans les applications aéronautiques qui ont été faites, le capteur a surtout été utilisé en tant que variomètre. Les comparaisons avec les mesures standards d'altitude par pression et couplages pression-données inertielles montrent que cet instrument pourrait apporter une contribution intéressante dans le domaine de la mesure à haute fréquence des fluctuations de pression.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 5
    ISSN: 1615-6110
    Keywords: Angiosperms ; Scrophulariaceae ; Striga hermonthica ; Hemiparasitism ; hostspecificity ; enzyme electrophoresis ; genetic diversity ; Flora of Burkina Faso ; Sudan
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Striga hermonthica is a root hemiparasite that attacks onlyGramineae, includingSorghum and millet for which it is a principal cause of lowered yield. Enzyme electrophoresis was used to investigate genetic diversity inStriga hermonthica and to determine the level of differentiation between host-specialized populations. Nine genetic loci coding eight enzymes were interpreted and data obtained from three populations: oneSorghum-adapted population from Sudan and two populations from Burkina Faso, oneSorghum-adapted and the other millet-adapted. Levels of polymorphism were similarly high in all three populations (P=0.625, A=2.6−2.8, H=0.293−0.401). Genotypic frequencies at most loci conformed to Hardy-Weinberg expectations in each population, consistent with outcrossing as predicted from previous studies of floral biology. Occasional heterozygote deficiencies were probably the result of Wahlund effect. The mean value of FST over the three populations was 0.068, indicating a slight to moderate level of genetic differentiation among the populations. The two Burkina Faso populations were more closely related (S=0.940, D=0.006) than either was to the Sudan population, suggesting that geographic separation is more important than host specialization in contributing to population differentiation. TheSorghum-adapted population was slightly closer to the Burkina FasoSorghum-adapted population (S=0.873, D=0.047) than to Burkina Faso millet-adapted population (S=0.851, D=0.074). The absence of substantial genetic divergence between host-specific populations ofStriga could result either from recent evolution of host-specialized strains or from strong selection for physiological specialization in the face of substantial gene flow between the populations.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 6
    ISSN: 1612-1112
    Keywords: Column liquid chromatography ; Aromatic acid isomers ; Low capacity ion-exchange resin ; Microbore packed columns
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary A low-capacity, anion-exchange, porous-polymer resin was used as the packing material in a microbore column. Using a phosphate buffer containing various organic modifiers, retention behavior of substituted benzoic acid isomers with amino, chloro, methyl, nitro and carboxylic groups was investigated. The effect of ethanol, acetonitrile and sodium dodecylsulfate used as organic modifiers on the retention behavior at various eluent pH values was studies and optimum separations of the positional isomers reported.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 7
    Electronic Resource
    Electronic Resource
    Springer
    Chromatographia 18 (1984), S. 668-672 
    ISSN: 1612-1112
    Keywords: Column liquid chromatography ; Mixed eluents ; Preferential sorption of eluents ; Pressure effects
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary Pronounced base line perturbations were repeatably observed in LC both in alternating recycling and in backflushing experiments when binary eluents and refractometric detectors were used. The perturbations which we call eigenzones appeared immediately after operating the recycling or the backflushing valve, and their size and shape depended on the nature of both the column filling and the mixed mobile phase as well as on the pressure drop across the column. Experimental results presented confirm that the primary causes of the eigenzones were the pressure changes in the columns which influenced the sorption equilibrium of mixed eluent components within the column packing. Some practical consequences of this effect are briefly discussed.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 8
    ISSN: 1612-1112
    Keywords: Polycyclic aromatic hydrocarbons ; Column liquid chromatography ; Polyphenyl bonded phases ; Retention and carbon content
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary The relationship between the retention of PAHs having various molecular sizes and the carbon contents (%) of bonded stationary phases with various types of ligands were investigated. The examined stationary phases were phenyl, diphenyl, triphenyl and benzyl-bonded silicas. The data indicated that sometimes it is not true that the retention of any solute relates linearly to the carbon content of the stationary phase. As the result, it is suggested that the pore size distribution of the silica support, the bulkiness of the ligand bonded to the silica and the molecular size of solute should also be considered before any precise statement can be made.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 9
    Electronic Resource
    Electronic Resource
    Springer
    Chromatographia 18 (1984), S. 175-182 
    ISSN: 1612-1112
    Keywords: Column liquid chromatography ; Fourier transform IR ; Polar compounds ; Coal products
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary Fourier-transform infrared spectrometry (FTIR) was utilized as a detection system for high-performance liquid chromatography of polar compounds on a normal bonded-phase system. In addition to FTIR, UV (254 nm) and refractive index detection were employed in the separation of model compounds containing oxygen and nitrogen atoms in their molecules (phenols, alcohols, neutral and weakly basic nitrogen compounds). A polar amino-cyano (PAC) bonded-phase column was employed with a binary mobile phase (98:2 CDCl3:CH3CN). The separations and the information gained from each detector is discussed, including interactions between sample material and mobile phase. A polar fraction of a coal-derived product is also chromatographed under identical conditions. The results based on FTIR detection and chromatographic retention behavior suggest the exclusive presence of hindered and unhindered phenols.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 10
    Electronic Resource
    Electronic Resource
    Springer
    Chromatographia 18 (1984), S. 211-215 
    ISSN: 1612-1112
    Keywords: Column liquid chromatography ; Alkylbenzenes ; PAHs ; Retention prediction ; Microcomputer
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary The microcomputer-assisted retention prediction system in C18 reversed-phase HPLC is described. The system is based on the use of the hydrophobic parameter and the correlation factor of alkylbenzenes and polycyclic aromatic hydrocarbons (PAHs) which are highly correlated to their retention in reversed-phase HPLC. The system is evaluated by comparing the retention data between measured and predicted values. One of the typical examples applied for PAH analysis in the extracts of diesel particulate matter shows the high potential of the system investigated.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 11
    Electronic Resource
    Electronic Resource
    Springer
    Chromatographia 18 (1984), S. 216-220 
    ISSN: 1612-1112
    Keywords: Cation exchangers ; Column liquid chromatography ; Exchange capacity, determination ; Organic peroxidation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary Two oxidation procedures for the synthesis of silicabased aliphatic sulfonic acid cation-exchangers for HPLC are described. Several reaction conditions for oxidizing a terminal-bonded thiol with organic peroxides are provided along with their yields, capacities, reproducibility, and chromatographic behavior. Also, three methods for determining exchange capacity are discussed, and their relationship to the capacity factors of charged solutes is compared. The maximum capacity determined by the titration of the bonded silica was 0.34 meq/gram. The general problems of synthesizing cation-exchangers, measuring their efficiencies and exchange capacities, and evaluating their overall performances are outlined.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 12
    Electronic Resource
    Electronic Resource
    Springer
    Chromatographia 18 (1984), S. 369-373 
    ISSN: 1612-1112
    Keywords: Column liquid chromatography ; Ion exchange ; dynamic ; Metal ions ; Equilibria effects
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary Equilibria occurring during the dynamic ion exchange separation of metal ions were examined, and their effect on the chromatography of the metal ions was evaluated. Bonded reversed-phase silica, pure organic reversed phase, and silica columns were used to differentiate between the role of silica and the reverse phase. The results show that system peaks had the most important influence on the applicability of dynamic exchangers to quantitative metal ion determinations. The response of system peaks to sample composition (pH, ionic strength, matrix effects) was complicated and could not be predicted easily. Equilibria effects that can cause analytical errors were identified and recommendations for elimination of such errors are given.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 13
    ISSN: 1612-1112
    Keywords: Column liquid chromatography ; Amines ; Phenols ; Fourier transform I.R.
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary Several chromatographic parameters have been examined as to their effect on detectability for microbore high-performance liquid chromatography coupled with Fourier-transform infrared spectrometry. Detection limits for several compound classes are presented as amount injected. Improvements in detectability for this technique are discussed.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 14
    ISSN: 1612-1112
    Keywords: Column liquid chromatography ; Polystyrene packings ; Pre-column derivatization ; Thiamine compounds ; UV and fluorescence detection
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary The chromatography of thiochrome and related phosphate esters was studied on two different polystyrene packing materials. The adsorbents were compared with respect to capacity factors, plate heights and resolution factors measured with different mixtures of phosphate buffer (pH 8.5) and methanol. In contrast with derivatized silica, these phases were found to be stable using an alkaline mobile phase and sample. Fast separations were possible with good peak symmetry at all organic modifier concentrations.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 15
    Electronic Resource
    Electronic Resource
    Springer
    Chromatographia 18 (1984), S. 445-448 
    ISSN: 1612-1112
    Keywords: Column liquid chromatography ; Amino-bonded stationary phase ; Ion-exchange ; Fermentation solution ; Biomass
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary In this work the analytical separation of biomass hydrolysis and fermentation products is described. Aminobonded phase and ion exchange materials (HPX 87H, HPX 42A, μ Spherogel Carbohydrate) were used as HPLC stationary phases for the determination of monomeric and oligomeric carbohydrates, carbohydrate degradation and fermentation products. The HPX 42A and the amino-bonded phase columns are especially suitable for the analysis of the gluco oligomers. The HPX 87H column separates the monomeric sugars and their degradation and fermentation products (e.g. furfurals and ethanol) very well. Using the μ Spherogel Carbohydrate column the lower gluco-oligomers as well as the monomeric sugars and their degradation and fermentation products, can be determined within 35 minutes.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 16
    ISSN: 1612-1112
    Keywords: Column liquid chromatography ; Chiral bonded phase ; Racemate resolution
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary A chiral stationary phase with an immobilized, optically active diamine was prepared for the separation of enantiomers. The synthesis of the phase was carried out by bonding (−)trans-1,2-cyclohexanediamine to microparticulate silica gel through the coupling agent 3-glycidoxypropylsilane. The resolution of the racemic compounds catechin, 2,2′-dihydroxy-1,1′binaphthyl and trans-1,2-cyclohexandiol, is reported.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 17
    Electronic Resource
    Electronic Resource
    Springer
    Chromatographia 18 (1984), S. 495-498 
    ISSN: 1612-1112
    Keywords: Column liquid chromatography ; PAHs ; Molecular shape recognition
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary The molecular-shape recognition of polycyclic aromatic hydrocarbons has been studied on various stationary phases in reversed-phase high-performance liquid chromatography. The examined stationary phases were phenyl-, diphenyl-, triphenyl- and benzyl-bonded silicas. The results of regression analysis inidcated that triphenylsilica is the best packing material to recognize the difference in the molecular-shape of structural isomers. This fact was confirmed by the separation of 4-ring isomers.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 18
    ISSN: 1612-1112
    Keywords: Column liquid chromatography ; Retention data ; Substituted benzene derivatives ; Correlations
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary The capacity factors of substituted benzene derivatives on bonded phases of various chain lengths in the reversed-phase mode have been measured and correlation of retention data between four stationary phases has been investigated by linear regression analysis. As a result, a difference in the retention mechanism between phases of shorter chain length and octadecylsilica was observed. In addition, it is also apparent that the multicombination treatment between retention data and descriptors such as π, HA, HD and σ promises the possibility of predicting the retention of substituted benzene derivatives on various reversed-phase stationary phases.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 19
    ISSN: 1612-1112
    Keywords: Column liquid chromatography ; Polyamines ; Dansyl derivatives ; Peak compression
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary Analytical conditions for the high-speed, reversed-phase, liquid chromatographic of a diamine (putrescine) and polyamines (spermine and spermidine) were determined. Various elution modes were employed using the same mobile phase constituents: 20mM sodium heptane sulfonate and 20mM acetic acid as solvent A and, pure acetonitrile as solvent B. Samples were derivatized with dansyl chloride before injection. Under isocratic conditions, the separation of the three polyamines was achieved in 7 min. The use of a linear elution gradient led to the same analytical time but with a better resolution of the putrescine peak from non-polyamine frontal peaks. For these measurements, the sample size was 5μl. This volume was increased to 20μl and the use of a steep gradient combined with the peak-compression technique allowed a fast analysis in 2–3 minutes, which may be compared with a 30 min run time necessary when a conventional column is used.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 20
    Electronic Resource
    Electronic Resource
    Springer
    International journal of anthropology 5 (1990), S. 193-202 
    ISSN: 1824-3096
    Keywords: Dental enamel defects ; Sudan ; Meroitic ; Christian
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract El Geili, located in the region of the Middle Nile, was occupied successively by Neolithic, Meroitic, and Christian populations at betweenn 3,500 BC and 1,500 AD. The scant archaeological evidence suggests that the Meroitic and Christian populations at Geili were patoral nomads. Dental enamel hypoplasias, indicators of general stress (malnutrition/disease), were studied in order to characterize and compare the health of these groups. A total of 130 individuals comprise the skeletal populations examined, from which a variety of appropriate sub-samples were analysed for defect presence, type, and age of occurence. Permanent incisors and canines represent the period of enamel development between birth and 6.5 years of age. Sample consisting of sets of incisors and canines (n=29) showed a negligibile difference of 77,8% vs. 81.8% in the Meroitic and Christian groups, respectively. Frequency differences by hypoplasia type reveal no obvious consistencies. Chronological analyses show chronic stress between 1 and 6 years of age.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 21
    ISSN: 1573-7691
    Keywords: Turbulence ; probability distributions ; temperature fluctuations ; vorticity
    Source: Springer Online Journal Archives 1860-2000
    Topics: Computer Science
    Notes: Abstract A phenomenological theory of single-point probability distributions in turbulence is presented. Expressions for the probability distribution functions are derived and analyzed for a decaying passive scalar, temperature fluctuations in Bénard convection and vorticity fluctuations in both stationary and decaying homogeneous, isotropic turbulence. The predictions of the theory are compared with the results of physical and numerical experiments.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 22
    ISSN: 1573-5117
    Keywords: Sudan ; Schistosoma mansoni ; Biomphalaria pfeifferi ; miracidia ; sporocysts ; host-parasite relations ; laboratory studies ; decoy snails
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Laboratory experiments have been carried out to determine the susceptibility of Gezira Biomphalaria pfeifferi snails to S. mansoni miracidia and the relationship between miracidia and daughter sporocyst production at the 10–17 day development stage. The relationship between snail numbers, miracidia numbers and water volume has also been studied. Two non susceptible snails, Bulinus truncatus and Cleopatra bulimoides, both of which occur naturally in Gezira canals, were tested to see if they act as decoys for S. mansoni miracidia. The results showed that the B. pfeifferi are 100% susceptible to S. mansoni invasion, at least to the daughter sporocyst development stage. The more miracidia that penetrated the more daughter sporocysts were produced, however individual variation and overlap were great. When one miracidium was released to find one snail it succeeded in low water volumes (5 m, 50 ml), but failed in 5 litres. When 100 miracidia were released mortality of snails was high suggesting superinfection particularly when only one or five snails were available. Among survivors daughter sporocyst counts were very high. Cleopatra and Bulinus snails do have a decoy effect when present in large numbers. In their presence the number of infected snails was marginally reduced and the number of daughter sporocysts greatly reduced. However, if superinfection is reduced by decoy effect, it is conceivable that Biomphalaria may be protected by decoy snails in circumstances where miracidia counts are high.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 23
    Electronic Resource
    Electronic Resource
    Springer
    Hydrobiologia 110 (1984), S. 241-245 
    ISSN: 1573-5117
    Keywords: Sudan ; pearl oyster ; feeding ; growth ; Red Sea ; Sudan
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Plankton samples and gut contents of P. margaritifera were analysed monthly from April 1972 to March 1973. Coscinodiscus sp. was the most ingested food by pearl oysters of all ages. However, food variety increased as the oyster grew older. Experiments confirmed the absence of food selectivity in P. margaritifera. Unlike the young ones, the adult showed reduced growth during summer (July–September), which coincides with its spawning season.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 24
    ISSN: 1573-5117
    Keywords: Sudan ; Schistosoma mansoni ; Biomphalaria pfeifferi ; miracidia ; sporocysts ; transmission of schistosomiasis ; host-parasite relations ; ecology
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract The efficiency of S. mansoni miracidia in locating and infecting Biomphalaria pfeifferi in Gezira canals has been studied under field conditions. When S. mansoni eggs were introduced into clean stagnant water in small field channels, the miracidia hatched to infect 100% of 30 snails in cages at the release point. Fifteen metres upstream and downstream 13% of caged snails were infected but no infections were found in snails 20 m away. When eggs were released into the same canal in flowing water (8.3 cm · s−1), no infections were detected in any of the caged snails placed 0–100 m downstream. Releasing hatched miracidia instead of eggs resulted in infections in all cages at 5 m intervals from 0-100 m. The release of eggs into flowing water was likened to the method by which S. haematobium eggs are deposited during urination. The 0% infection suggests that eggs will be swept away from the point of contamination by the flow. Thus only urination into stagnant water will lead to heavy snail infection rates. When eggs were released into a small pond-like minor canal tail end snail infection rates were only 3%. This was probably due to the larger water volume, smaller number of caged snails, and the presence of vegetation and other fauna which may be decoys or predators. The results highlight how very high snail infection rates can be produced under ideal conditions but also show how large snail and miracidia numbers are required in natural situations.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 25
    Electronic Resource
    Electronic Resource
    Springer
    Hydrobiologia 110 (1984), S. 213-217 
    ISSN: 1573-5117
    Keywords: Sudan ; Penaeus ; food ; food selection ; chemoreception
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract A study of food and food selection of Penaeus monodon (Fabricius) on the Sudanese Red Sea coast was carried out. Juveniles feed mainly on algal material. Adults feed on crustacea, annelids, algae, mud and unidentified matter. Adults were opportunistic in their feeding behaviour, but their preference was towards animal protein. Antennae, mouth parts and fore-chelipeds were found to carry long, slender setae which are probably of sensory function. Some setae on the carpus of the endopodite were serrated and seem to be used in grooming. Numerous tufts of setae in the chela of the fore periopods may hold a gustatory function. The inner edges of the chela are lined with a row of peg-like setae, which are probably another site of reception.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 26
    Electronic Resource
    Electronic Resource
    Springer
    Hydrobiologia 110 (1984), S. 57-59 
    ISSN: 1573-5117
    Keywords: Sudan ; algae ; Blue Nile ; primary productivity ; tropical rivers ; White Nile
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Phytoplankton production and respiration in the Blue Nile and White Nile at Khartoum were measured during the period November 1969–January 1971 using the light and dark bottle technique. Maximum rates of production coincided with periods of maximum phytoplankton densities. In the Blue Nile gross production varied between 0.00 gCm−3d−1 during the flood season and 2.19 gCm−3d−1 (0.49 mgO2l−1h−1) during November 1969. In the White Nile the range was from 0.41 gCm−3d−1 (0.09 MgO2l−1h−1) in May to 3.74 gCm−3d−1 (0.83 MgO2l−1h−1) in November. The maximum rates of respiration in the Blue Nile and White Nile were 0.10 and 0.63 MgO2l−1h−1 respectively. The ratios net:gross production were generally higher in the White Nile than in the Blue Nile.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 27
    Electronic Resource
    Electronic Resource
    Springer
    Hydrobiologia 110 (1984), S. 61-77 
    ISSN: 1573-5117
    Keywords: Sudan ; algae ; Nubian desert
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract The algae contained in some plankton samples from several localities on four wadi in N.E. Sudan were examined. The observed algae amount to 260 taxa, of which the diatoms, representing 50% of the algal flora, are the most numerous. Other large groups are the blue-green algae (17%) and the green algae (24%) among which the desmids (6%) are rather unimportant.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 28
    Electronic Resource
    Electronic Resource
    Springer
    Hydrobiologia 110 (1984), S. 109-111 
    ISSN: 1573-5117
    Keywords: Sudan ; mangroves ; Red Sea ; ecology
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract An ecological survey of the mangrove vegetation in the littoral salt marshes of the Red Sea coast of the Sudan was made during short periods between 1980 and 1982. Avicennia marina (Forsk) Vierh occurs in pure stands of different dimensions in four types of locations. In each location, the responses of Avicennia are expressed in the degree of compactness of aggregation, canopy, height and regeneration potential. Grazing by camels is the primary agent in degradation of accessible locations; salt pans and to a limited extend cutting contribute in part to the process of degradation. The badly damaged aggregations may benefit from protection through control of grazing by nomadic camel tribesmen.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 29
    ISSN: 1573-5117
    Keywords: Sudan ; Mollusca ; Gastropoda ; fresh water snails ; trematode parasites ; schistosomiasis
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract An account is given of the aquatic gastropod molluscs obtained in a survey made to assess future ecological effects of the Jonglei Canal now under construction in the Sudd region of southern Sudan. A total of about 23 species of aquatic snail lives in this region, of which a number are utilised as intermediate hosts by trematode parasites infecting man, livestock and wild herbivores, causing the diseases schistosomiasis, fascioliasis and amphistomiasis. Public health and veterinary authorities should be alert to the possibility that the Jonglei Canal will increase snail populations and raise the prevalence of parasitic diseases.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 30
    Electronic Resource
    Electronic Resource
    Springer
    Hydrobiologia 110 (1984), S. 273-279 
    ISSN: 1573-5117
    Keywords: Sudan ; Alestes ; growth ; feeding ; Nile
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract The food, feeding habits and growth of 0+ Alestes nurse (Rüppel) from the Blue Nile near Khartoum, was investigated. 0+ A. nurse were observed to change their food from phytoplankton and small zooplankton during their pre-metamorphosis stages, to larger zooplankton (Daphnia spp., Chydorus sp.) and insects (larvae, pupae and imagines) during their post-metamorphosis stage. Their growth in length and weight was characterized by two distinct stanzas; during the first stanza, the fish increased in total length at a rate of 0.196 mm mm−1 wk−1, and in wet weight at a rate of 0.430 g g−1 wk−1. These rates were reduced during the second stanza to 0.046 mm mm−1 and 0.080 g g−1 wk−1, respectively. The calculated value of the exponent b in their length-weight relationship suggested that their growth was allometric.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 31
    Electronic Resource
    Electronic Resource
    Springer
    Hydrobiologia 110 (1984), S. 281-286 
    ISSN: 1573-5117
    Keywords: Sudan ; frontal bone ; age determination ; cyprinidae ; Jebel Aulia
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract In spite of the exuberance of recent approaches to age determination of fish, many ecologists are convinced that the most valid method is age reading from permanent marks or growth rings laid on skeletal parts. Of the known structures used, only the vertebrae are suitable and readable for a large variety of species and sizes. Examination of different skeletal structures of Labeo horie, a Cyprinid collected from Jebel Aulia reservoir, revealed that the frontal bone carried well-defined growth rings. The validity of these rings was checked against other direct and indirect methods of age determination. Results proved to be statistically valid, and the frontal bone offers an additional device of age determination of L. horie.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 32
    ISSN: 1573-5117
    Keywords: Sudan ; abundance ; breeding ; sex-ration ; Tilapia ; Labeo ; White Nile
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Seasonal abundance, maturation and sex-structure were studied in populations of T. nilotica and L. niloticus in the Jebel Aulia reservoir and in the White Nile below the dam. L. niloticus showed a single annual breeding cycle from mid-July to December and was most abundant in October in the lake, and in early November in the river. T. nilotica showed two distinct annual seasons of abundance: summer (April to June) and autumn (November to October). Spawning activity was highest in summer (April to June) and autumn (late July to September). The sex-ratio varied inversely with age (size); males were predominant in populations of older fish, perhaps because of their greater endurance to adverse conditions as evidenced by their better survival in hypoxic water.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 33
    Electronic Resource
    Electronic Resource
    Springer
    Hydrobiologia 110 (1984), S. 305-314 
    ISSN: 1573-5117
    Keywords: Sudan ; fish species ; selectivity ; abundance ; distribution ; fish production
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Developing lake conditions in Lake Nubia were found to offer good commercial fisheries potential. This prospect initiated fishery research since 1967. In this study, 26 fish species belonging to 10 families were recorded. Compared with previous studies the total number has decreased and some of the species that were commercially important during the early years of the lake formation, are now negligible in occurrence (Distichodus, Citharinus, Bagrus). The species widely distributed in the lake are Labeo niloticus, Lates niloticus, Sarotherodon niloticus, Hydrocynus forskallii, Alestes baremose and Eutropius niloticus. Their highest production occurs during two periods: February to May and July to September. The dominant fish species feed on different items in a balanced equilibrium with the ecological and biological conditions.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 34
    Electronic Resource
    Electronic Resource
    Springer
    Hydrobiologia 110 (1984), S. 295-304 
    ISSN: 1573-5117
    Keywords: Sudan ; Clarias ; breeding ; maturation ; hormones ; growth ; cultivation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract The seasonal abundance, population structure, reproduction, feeding, respiratory adaptations and tolerance were studied in the catfish Clarias lazera (Cuv. & Val.) in the reservoir of Jebel Aulia on the White Nile, and in the Green-Belt canals near Khartoum. Continuous monitoring of the ripe, spent and spawning females and immature fish in the population revealed that C. lazera breed synchronously in the autumn in the reservoir and rather sporadically in the canals. Medium-sized females were more fecund than old and young females. Administration of pituitary extract enhanced maturation, induced spawning in mature fish, stimulated body growth, especially in maturing specimens, and produced, as a side-effect, a diuretic response. Mature fish depended on pulmonary respiration for about 45% of the total oxygen requirement. C. lazera fed preferentially on its fry and on decayed proteinaceous food. The suitability of this species for economic cultivation is discussed.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 35
    Electronic Resource
    Electronic Resource
    Springer
    Hydrobiologia 110 (1984), S. 315-317 
    ISSN: 1573-5117
    Keywords: Sudan ; Lake Nubia ; fisheries
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract The gill nets presently used in Lake Nubia fishing were subjected to a comparative study in regard to their relative efficiency. The results obtained indicate that Mesh 6 netted with Twine 4 is the most effective net, followed by Meshes 2, 4, 8 and 10 respectively. It has also been shown that, although individual nets undergo seasonal fluctuations in CUE, this does not, substantially affect their order of merit. The role of water characteristics on fish population distribution and subsequenct changes in the CUE was also noted.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 36
    Electronic Resource
    Electronic Resource
    Springer
    Hydrobiologia 110 (1984), S. 319-325 
    ISSN: 1573-5117
    Keywords: Sudan ; Pisces ; Cyprinidae ; Barbus bynni ; breeding ; Jebel Aulia Reservoir
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Barbus bynni begins to mature at Age IV. Ripening of gonads of mature fish starts in May when water temperature approaches the annual maximum. However, the spawning season coincides with the onset of the flood season in July. These facts, as well as the cyclic growth of the gonads, show that B. bynni spawns once a year. Fecundity varies with size of fish and gonads. However, this levels off in the middle size group. At this age the fecundity was estimated to be 1 424 693 eggs.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 37
    Electronic Resource
    Electronic Resource
    Springer
    Hydrobiologia 110 (1984), S. 327-332 
    ISSN: 1573-5117
    Keywords: Sudan ; Pisces ; Cyprinidae ; food and feeding
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Basic knowledge on the feeding ecology of one of the common and commercially important fish species in Jebel Aulia Reservoir is provided. The structure of the feeding apparatus indicates that Labeo niloticus is a bottom feeder, depending on soft and decayed vegetation, organic debris and whatever small organisms found within. However, juveniles and fry are prone to explore all layers and depths of the river selectively for plankton. There is little evidence of seasonal selection of food. Changes in diet quality are governed by the availability of type of food. Variability of feeding activity is connected with climate and breeding season.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 38
    Electronic Resource
    Electronic Resource
    Springer
    Hydrobiologia 110 (1984), S. 333-338 
    ISSN: 1573-5117
    Keywords: Sudan ; fish ; Characidae ; growth of rings ; back-calculation ; aging structure
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract The scales, opercula and vertebrae from 69 Hydrocyon forskali and 63 Alestes dentex were investigated for their reliability as aging structures. In both species the scales were unreliable due to their regenerative property, in spite of the clarity of their growth rings. Back-calculated lengths from the first growth ring laid on opercula and vertebrae resulted in values that coincided with the annual growth of the two species. In H. forskali, the mean back-calculated length from the two bones were 16.2 ± 5.9 and 16.8 ± 4.4 respectively, and for A. dentex, 11.1 ± 1.7 and 12.8 ± 1.8, respectively. Predictive equations for bone radius from fish length were written for both species. In this study, reliability was maximal between the observed and back-calculated lengths for both species (r 〉 0.95).
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 39
    Electronic Resource
    Electronic Resource
    Springer
    Hydrobiologia 110 (1984), S. 351-363 
    ISSN: 1573-5117
    Keywords: Sudan ; Polypterus ; aerial ; branchial ; respiration ; hypoxia ; hypercarbia
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract The respiratory behaviour and partitioning of O2 uptake between air and water were investigated in Polypterus genegalus using continuous-flow and two-phase respirometers and lung gas replacement techniques P. senegalus rarely resorts to aerial respiration under normal conditions. Partitioning of O2 consumption depends on the activity and age of fish and the availability of aquatic oxygen. Immature fish (12–22 g) cannot utilize aerial O2 but older fish exhibit age-dependent reliance on aerial respiration in hypoxic and hypercarbic waters. Pulmonary respiration accounts for 50% of the total requirement at aquatic O2 concentrations of about 3.5 mg · l−1 (or CO2 of about 5%) and fish rely exclusively on aerial respiration at O2 concentrations of less than 2.5 mg · l−1. Branchial respiration is initially stimulated by hypercarbia (CO2: 0.5–0.8%) but increased hypercarbia (CO2 − 1%) greatly depresses (by over 90%) brancial respiration and initiates (CO2: 0.5%) and sustains pulmonary respiration.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 40
    Electronic Resource
    Electronic Resource
    Springer
    Hydrobiologia 110 (1984), S. 339-349 
    ISSN: 1573-5117
    Keywords: Sudan ; Protopterus ; Polypterus ; Clarias ; ATP ; GTP ; development ; hypoxia
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract The ATP and GTP contents of erythrocytes of Protopterus annectens, Polypterus senegalus and Clarias lazera were assessed in relation to maturation and hypoxia. The steady state ‘normal’ concentrations of ATP were: 446, 316 and 475 µM/100 ml and those of GTP were 286, 93 and 85 µM/100 ml in Protopterus, Polypterus and Clarias, respectively. The level of ATP decreased and that of GTP increased with increments in body growth, especially during development of the pulmonary organs. The concentration of GTP also increased progressively with hypoxia (O2: 7.4 to 3.6 mg/l); the level ATP remained almost unaltered. The ratio of GTP increased markedly with increased hypoxia particularly in the adaptive respiratory range of aquatic oxygen concentrations (6.5–4.8 mg/l) when the fish were forced to depart from branchial respiration and became reliant on air-breathing.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 41
    Electronic Resource
    Electronic Resource
    Springer
    Hydrobiologia 110 (1984), S. 1-13 
    ISSN: 1573-5117
    Keywords: Sudan ; Nile ; hydrology ; control ; utilization
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract The Nile is a vital resource of north-eastern Africa. After a description of its basin, and its hydrology,the different phases in the process of man gaining control on the river are discussed. Presently, the Nile is used for irrigation, the generation of hydroelectric power, navigation, and, of particular importance to limnologists, fisheries. Future developments in the management of the Nile are summarized.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 42
    Electronic Resource
    Electronic Resource
    Springer
    Hydrobiologia 110 (1984), S. 15-19 
    ISSN: 1573-5117
    Keywords: Sudan ; RSC programme ; tailings ; impacts on environment
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract The unique Red Sea environment has up to now been relatively unaffected by polluting consequences of Man's activities, except for evidence of oil along the coasts and reefs from transiting ships, harbours, industrial and human wastes with growing population and industrialization. The discovery, in the mid-sixties, of deposits of metalliferous muds, rich in heavy metals, and the probable mining and processing of these was expected to add to the risk of pollution. The Saudi-Sudanese Red Sea Commission, entrusted with the development and exploration of these non-living resources, has already set out an environmental study programme, more or less directly related to the conservation of the living marine resources. Within this framework, the studies have focused on the assessment and magnitude of possible risks for the environment resulting from a tailings disposal in the Atlantis 11 Deep over an extended period of time, and on the development of methods to minimize these risks. The results obtained so far, indicate that a well-controlled tailings disposal below 1 000 metre water depth would keep the environmental impact of such an operation in acceptable dimensions. But it is hoped that the forthcoming Pilot Mining Operations will be capable of clarifying some uncertainties through further computer modelling, monitoring a full scale tailings disposal test, using realistic input conditions and evaluation of the ecosystem.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 43
    Electronic Resource
    Electronic Resource
    Springer
    Hydrobiologia 110 (1984), S. 33-44 
    ISSN: 1573-5117
    Keywords: Sudan ; lakes ; fauna ; distribution ; comparative survey
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Lakes Kundi and Keilak show large seasonal variations in area, but have permanent dry season residual areas rich in aquatic macrophytes. The faunas of the two lakes are similar, with L. Kundi (130 species recorded) being richer than L. Keilak (91 species). The fauna of L. Kundi includes the protomonad Rhipidodendron huxleyi, which has not been previously recorded in Africa. In L. Keilak we found Neozonocypris mirabilis, previously known only from L. Tanganika.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 44
    Electronic Resource
    Electronic Resource
    Springer
    Hydrobiologia 110 (1984), S. 21-32 
    ISSN: 1573-5117
    Keywords: Sudan ; Blue Nile ; chemical composition ; tropical rivers ; White Nile
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Fortnightly measurements of physical and chemical variables were made at two locations on the Blue and White Niles near Khartoum from August 1968 to December 1970. Variables analysed from each river were: temperature, pH, total residue, current velocity, oxygen, alkalinity, phosphate, nitrate, ammonia, silica, sulphate, iron, calcium, magnesium, sodium, potassium and oxidizable organic matter. The seasonal variations of these factors in the two Niles are compared and the interrelationships existing between some of them are discussed. Comparisons with earlier studies on the Nile and with some tropical rivers are made. In the Blue Nile, the amounts of suspended matter and nutrients are largely dependent upon the flood regime. Nitrate, phosphate, iron, oxidizable organic matter and total residue increase considerably in the Blue Nile when the river is in flood (peaks: 1 880 µg NO3-N l−1; 0.31 mg Fe l−1; 3 842 mg total residue · l−1). In the White Nile, concentrations of nitrate, phosphate, iron, oxidizable organic matter and total residue attain their peaks during the rainy season (270 µg NO3-N l−1; 163 tag PO4-P l−1; 0.46 mg Fe · l−1; 502 mg total residue · l−1). In both rivers, alkalinity, calcium, sodium and potassium tend to increase during the dry season while declining in the rainy season. Silica is depleted at certain times of the year, yet relatively high concentrations are maintained throughout the year and were not expected to limit growth of diatoms. Fall in silica concentrations, unlike nitrate, phosphate and iron, was always followed by a rapid restoration of a high level. Silica and magnesium showed no response to changes in discharge rates.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 45
    Electronic Resource
    Electronic Resource
    Springer
    Hydrobiologia 110 (1984), S. 47-55 
    ISSN: 1573-5117
    Keywords: Sudan ; algae ; Blue Nile ; plankton ecology ; tropical rivers ; White Nile
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract The variation in numbers of the major planktonic algae in the surface waters of the Blue Nile and White Nile were followed for 29 months (August 1968–December 1970). In terms of biomass, the phytoplankton was dominated by diatoms and blue-green algae; other groups were of minor importance. High phytoplankton densities occurred during winter in both rivers, and during summer in the Blue Nile, with values in the latter river greater than in the former. Melosira granulata and its variety angustissima and Anabaena flos-aquae var. intermedia f. spiroides were the most important taxa in the two Niles. Melosira distans and Attheya zachariasi, which are reported for the first time in the present study, preponderated at certain times in the Blue Nile. Microcystisflos-aqua which had been a minor component of the phytoplankton in both rivers during the early 1950s, showed a profuse growth in the Blue Nile. Lyngbya limnetica, Anabaenopsis cunningtonii and A. tanganyikae, which constituted important components of the phytoplankton in the early 1950s, either disappeared or maintained themselves in reduced numbers during the present study. This change in the algal flora of the two Niles may be attributed to the construction of the Roseres dam across the Blue Nile in 1966 and to the invasion of the White Nile by Eichhornia crassipes in 1957.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 46
    Electronic Resource
    Electronic Resource
    Springer
    Hydrobiologia 110 (1984), S. 79-90 
    ISSN: 1573-5117
    Keywords: Sudan ; swamp vegetation ; Sudd
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract This paper describes vegetation in the nothern Sudd area of the Sudan. A visit by boat was made in April 1978 along the White Nile from Malakal to Lake No; to the inflow regions of the Bahr el Jebel, the Bahr el Zeraf and to the Bahr el Ghazal. Only the vegetation along the fringe of the rivers was observed as plants were tall and dense and it was not possible to penetrate into the inner swamps. The outer edge of the vegetation was fringed by extensive mats of free-floating Eichhornia crassipes which was easily dislodged and formed floating islands to be carried downstream. The main rivers, excluding the Bahr el Ghazal, were too deep and turbid to support beds of submerged species but plants such as Ceratophyllum demersum could be found amongst floating plants. Vossia cuspidata usually produced a broad zone to the landward of Eichhornia. It dominated the shallow water with a floating raft of stems growing out from the shore over the water surface. Massive stands of Cyperus papyrus and/or Phragmites karka, over 5 metres tall, dominated the vegetation behind and sometimes excluded the Vossia zone. The papyrus could form dense, floating rafts of rhizomes at the water's edge, but Phragmites always remained firmly rooted to the bottom. Floating papyrus and Vossia would become detached from the main beds and drifted downstream with Eichhornia. Creepers were common amongst papyrus but less common amongst Phragmites where the vegetation was generally more dense. Large stands of Typa domingensis were observed behind the fringe vegetation. The vegetation of the Bahr el Ghazal, in marked contrast to the rest, was stunted, and reasons for this are suggested. Species diversity was greater and the less turbid waters allowed considerable development of floating-leaved and submerged species. Estimates of fresh weights and heights of dominant vegetation types were attained but methods were very laborious and alternative ways have been suggested. The fresh weight of Eichhornia from a one metre square quadrat in the White Nile was around 70 kg. The shoots of Phragmites weighed 18.5 kg and Cyperus papyrus, 11.0 kg m−2.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 47
    Electronic Resource
    Electronic Resource
    Springer
    Hydrobiologia 113 (1984), S. 93-98 
    ISSN: 1573-5117
    Keywords: tropical zooplankton ; swamps ; Sudan
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Samples from the main Nile channel yield a poor zooplankton, deficient in species and heavily laden with organic debris. Samples from side arms and floodplain lakes yield a richer zooplankton, often containing 15–20 species of rotifers and ten or more species of Crustacea. When the floodplain lakes are heavily vegetated the number of species increases. For the Crustacea the index of diversity (α) normally varies between 0.6 and 2.4, but in a side arm of the Bahr el Zeraf it reaches 6.1 and in Lake Ambadi on the Bahr el Ghazal it reaches 8.4. The diversity of the rotifers is somewhat higher, normally ranging between 2 and 4.5, but reaching 23 in Lake Ambadi. The zooplankton of Lake Ambadi is the most distinctive and contains several species not found at other stations. The reasons for the peculiar zooplankton of Lake Ambadi are discussed.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 48
    Electronic Resource
    Electronic Resource
    Springer
    Journal of statistical physics 61 (1990), S. 865-868 
    ISSN: 1572-9613
    Keywords: Turbulence ; screening ; vortices ; XY model ; Debye-Hückel theory
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract The statistical mechanics of some electric models predicts exponential decay of space correlations (screening). This suggests that one look also for screening in 2- and 3-dimensional hydrodynamic turbulence.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 49
    Electronic Resource
    Electronic Resource
    Springer
    Hydrobiologia 110 (1984), S. 99-108 
    ISSN: 1573-5117
    Keywords: Sudan ; water hyacinth ; nutrients ; P, N, Fe ; growth ; White Nile
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract The possibility that the stunted growth of the water hyacinth in Bahr el Ghazal river in Sudan is influenced by nutrient elements is considered. Greenhouse experiments were carried out to determine the effects of deficiency and mineral nutrient additions on the growth of this plant. The water hyacinth was found to grow at a wide range of nutrient levels. Maximum growth was recorded at 21 mg l−1 N, 62 mg l−1 P, and 0.60 mg l−1 Fe.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 50
    ISSN: 1573-5117
    Keywords: Sudan ; water hyacinth ; biological control ; weevils
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Water hyacinth Eichhornia crassipes (Mart.) Solms. is an aquatic weed that infests most of the White Nile system in the Sudan. Serious economical and ecological problems are caused by this weed. The two weevils Neochetina eichhorniae and Neochetina bruchi were imported and released in an attempted biological control against the weed. The adults of these weevils attack the plant and feed by removing tissues from the leaf pseudolamina and petioles. The larvae tunnel inside the petioles and the crown. The optimum temperature for feeding and development of both species is 25° C. Results obtained from stocking hyacinth plants with adults and larvae of both species separately revealed that N. bruchi is more efficient in checking the growth of the plant. The progeny of a pair of N. bruchi and N. eichhorniae reared separately on 41 hyacinth plants for a period of 61 days (one generation period) reduced their population growth by 25.4% and 12.7% respectively. The progeny of both species in a mixed culture reduced the growth of the plants by 22.5% in the same period, while in the control the population of the plants increased 136.6%.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 51
    Electronic Resource
    Electronic Resource
    Springer
    Hydrobiologia 110 (1984), S. 113-130 
    ISSN: 1573-5117
    Keywords: Sudan ; rotifers ; taxonomy ; biogeography ; Africa
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract A collection of rotifers contained in samples from the Blue, White and joint Niles in the Sudan, the Red Sea Hills, and Jebel Marra mountains is studied, and the previous literature on the rotifera of Sudan is reviewed. A total of 145 rotifer taxa are now known from this country. Ecological and distributional notes on selected species are added. Besides cosmopolitan, pantropical, and tropical species, a small but significant fraction of the fauna is of northern origin, possibly reflecting climatic conditions of the late-Pleistocene.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 52
    Electronic Resource
    Electronic Resource
    Springer
    Hydrobiologia 110 (1984), S. 131-134 
    ISSN: 1573-5117
    Keywords: Sudan ; amphipoda ; Bogidiellidae ; systematic ; ground water fauna
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Description of Bogidiella nubica, from interstitial waters in the Sudan. It is the first Bogidiella species known for the African continent, except for the Mediterranean area.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 53
    Electronic Resource
    Electronic Resource
    Springer
    Hydrobiologia 110 (1984), S. 135-136 
    ISSN: 1573-5117
    Keywords: Sudan ; Nile ; Acari ; Halacaridae
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Limnohalacarus africanus and L. fontinalis are recorded from Lake No. These are respectively the third and second records of these species, and represent considerable extensions of their known ranges.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 54
    Electronic Resource
    Electronic Resource
    Springer
    Hydrobiologia 110 (1984), S. 163-169 
    ISSN: 1573-5117
    Keywords: Sudan ; Cladocera ; biogeography ; taxonomy ; Sudan ; Nile
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Twenty species of Cladocera are reported from the Nile, where lacustrine species dominate, and from Jebel Marra and the Red Sea Hills, where chydorids dominate. The community found in the Red Sea Hills is more typically desertic than that of Jebel Marra, which appears closely related to the fauna of the West and Central African Sahel.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 55
    Electronic Resource
    Electronic Resource
    Springer
    Hydrobiologia 110 (1984), S. 171-175 
    ISSN: 1573-5117
    Keywords: Sudan ; Crustacea ; Bathynellacea ; Nile
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Nilobathynella predynastica n.g., n.sp. from Abri, Nubia, is the first representative of the Tribus Cteniobathynellini in the Nile Valley. Its relationship with the other Cteniobathynellini, as well as its biogeographical significance, are briefly discussed.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 56
    ISSN: 1573-5117
    Keywords: Sudan ; freshwater ostracods ; Africa ; taxonomy ; zoogeography
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract A collection of freshwater ostracods from the Sudan is studied and 18 species are recorded. Paracypretta amati sp.n. is new to science. A redescription of the holotype female of Paracypretta aratra (Brady, 1904) (not recorded in this collection) and a provisional key to the species of Paracypretta are given. Heterocypris giesbrechtii (G. W. Müller, 1898) is re-described; Heterocypris sobrinus (Masi, 1932) is placed in the synonymy of H. fretensis; Hemicypris intermedia (Lindroth, 1953) is recorded for the first time since its original description and is redescribed, while Cyprinotus largereticulatus Rome, 1969 is transferred to Hemicypris. The zoogeographical composition of this fauna is briefly discussed.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 57
    Electronic Resource
    Electronic Resource
    Springer
    Hydrobiologia 110 (1984), S. 177-180 
    ISSN: 1573-5117
    Keywords: Sudan ; Nubia ; groundwater ; Copepoda ; Nitocrella
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Description of Parapseudoleptomesochra attirei from a well in a dry wadi bed at At Tire, Nubia. Its closest relative is found in a semidesert area in Iran. The chorological implications of this finding are briefly discussed.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 58
    Electronic Resource
    Electronic Resource
    Springer
    Hydrobiologia 110 (1984), S. 181-190 
    ISSN: 1573-5117
    Keywords: Sudan ; Odonata ; Nile ; Red Sea Hills ; biogeography ; deserts
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Twenty-one species of dragonflies are recorded from the Nile and the Red Sea Hills in the Sudan. The majority are species of africotropical origin, but wide-ranging and tolerant of strongly fluctuating environmental conditions. A small but significant fraction is restricted to the Nile Valley, and another fraction, found only in the Red Sea Hills, is composed of Eremian species of Palaearctic origin. Besides adults, the last-instar larvae of Pseudogrion niloticum and of Paragomphus pumilio are described and figured.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 59
    Electronic Resource
    Electronic Resource
    Springer
    Hydrobiologia 110 (1984), S. 191-212 
    ISSN: 1573-5117
    Keywords: Sudan ; Copepoda ; Calanoida ; taxonomy ; biogeography ; Africa ; Nile
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract At least 11 or 12 calanoid taxa occur in the Nile system. One species is typical of the river and of Lake Chad (Th. galebi); two are restricted to Lake Victoria (Th. galeboides, T. stuhlmanni), but both might be only subspecies to more widespread species. One is restricted to Lakes Edward and George (T. worthingtoni) but is a little known species. No calanoids are on record from Lakes Albert and Kyoga, while the species reported from Lake Turkana (T. banforanus) is out of range, and almost certainly represents an erroneous record. Among the remaining species, four are East-African, ranging from the southern tip of the continent to the Ethiopian plateau and the Nile valley (P. schultzei, Th. mixtus, T. kraepelini, T. cf orientalis), while two are Sahelian species that span Africa from east to west (M. mauretanicus, T. processifer et ssp.). Two new synonyms are introduced. One new subspecies (T. processifier friedae) is described from the Ethiopian plateau. It is suggested that Tropodiaptomus orientalis (Brady, 1886), the type species of its genus, should not be considered a nomen dubium, but should be redescribed on its type female(s) and on topotypical males from Sri Lanka.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 60
    Electronic Resource
    Electronic Resource
    Springer
    Hydrobiologia 110 (1984), S. 219-225 
    ISSN: 1573-5117
    Keywords: Sudan ; Bivalvia ; Corbicula ; ring formation ; White Nile
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract The growth of C. consobrina of the White Nile near Khartoum was studied during March–December, 1977 from material collected from fish guts every two months. It was found that the growth season extends from February to July in correlation with the rise in temperature. Food was abundant and the concentration of the dissolved calcium in the river water was also increasing. During the flood season from July to October, the clams entered a resting state as a result of the annual siltation and consequently growth was arrested. Growth rings were found to be formed as a result of the siltation-induced resting state. There is evidence that little growth occurred during the cooler months from October to December. The development of the false rings on the shells is possibly a result of the changes in the water levels. Analysis of the growth of the adult clams showed that there is a clear size-time relation; there was close agreement between the calculated maximum sizes and the actual data collected from the field. Other examples from Sudanese inland waters were also discussed. The role of the annual hydrological cycles in regulating the populations activities and hence the growth of the individuals was found to be important.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 61
    Electronic Resource
    Electronic Resource
    Springer
    Chromatographia 29 (1990), S. 21-23 
    ISSN: 1612-1112
    Keywords: Column liquid chromatography ; Formaldehyde ; Reaction detector ; Polymer dispersions ; Nonwovens
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary A method for the determination of free formaldehyde in nonwovens in the presence of interfering components is described. After RP-HPLC separation the water extracted formaldehyde reacts with acetylacetone in a knitted open tube reactor to form a lutidine derivative which is measured, even at low concentrations, by the UV detector. The minimum detectable concentration is 25 μg/kg.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 62
    ISSN: 1612-1112
    Keywords: Column liquid chromatography ; Extraction cartridges ; Erythromycin ; Josamycin ; Serum and urine
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary The re-usability of C18 solid-phase extraction (SPE) cartidges was assessed utilizing two different analytical procedures developed for the analysis of erythromycin and josamycin in human serum and urine. A statistical procedure using confidence intervals was employed in order to determine a 10% change in drug recovery on re-use with a 95% degree of certainty. The results obtained indicated that the SPE cartridges could be successfully re-used up to three times for serum and urine samples containing physiological concentrations of erythromycin base and propionate. However, in the case of josamycin, results were inconsistent after the second re-use of the extraction cartridges for serum samples. Reproducible results, however, were still obtained for urine samples using the same SPE cartridges up to four times. The results indicate that although succesful re-use of SPE cartridges is possible, each drug and associated extraction conditions need to be carefully assessed prior to implementing such re-use.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 63
    Electronic Resource
    Electronic Resource
    Springer
    Chromatographia 29 (1990), S. 51-53 
    ISSN: 1612-1112
    Keywords: Column liquid chromatography ; Electrochemical detection ; Amino acid enantiomers ; OPA-TATG ; Fruit juices
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary A fast and simple HPLC-method for the determination of synthetic amino acids in adulterated orange juice has been developed. The amino acid enantiomers were derivatized with a chiral reagent and the derivatives separated on a 3 μm particle size C18 column. An electrochemical detector operating in the oxidative mode was used for detection. The potential at which the derivatives are oxidized was determined by cyclic voltammetry. By using selective (electrochemical) detection it is possible to reduce the sample clean-up to simple centrifugation and filtration steps.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 64
    ISSN: 1612-1112
    Keywords: Column liquid chromatography ; Mixed-functional silica ; Direct serum injection ; Drug analysis
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary A new mixed-functional silica material has been developed for direct injection analysis of drugs in serum. The mixed-functional material is synthesized from porous silica by three steps; introduction of 3-glycidoxypropyl groups, introduction of phenyl groups, and hydrolysis of the oxirane ring to diol groups. The prepared column packing can be used for direct injection analysis of hydrophobic and hydrophilic drugs in serum over the eluent pH range employed for ordinary siloxane-bonded silica. The recovery of drugs from serum was almost 100%, regardless of the difference in their protein bindings.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 65
    ISSN: 1612-1112
    Keywords: Column liquid chromatography ; Sample treatment ; Zone electrophoresis
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary The design of a new valve arrangement for zone-electrophoretic sample treatment (ZEST) coupled online with high performance liquid chromatography is described. Characteristics of this valve, such as the internal heat development as a function of the current, have been investigated. By using quinidine and desipramine as model compounds it is shown that charged compounds can be isolated from biological samples, in about 15 min, with high selectivity. The carry-over of proteins to the analytical column has been compared with the carry-over using a pre-column sample clean-up method. The detection limits of quinidine and hydroquinidine (50 ng/ml), using zone-electrophoretic sample treatment coupled with column liquid chromatography, are in the same range as with direct injections using pre-columns.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 66
    ISSN: 1612-1112
    Keywords: Column liquid chromatography ; Factor analysis ; Experimental design ; Chemically bonded and silica phases ; Chalcones
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary The retention of a group of 38 E-s-cis and Z-s-cis chalcones on silica vs. nine polar chemically bonded phases is discussed. It was established that the relatively greatest similarity to silica is observed with the NH2, DIOL and CN phases, whereas the chargetransfer type phases and the NO2 one offer a different separation selectivity.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 67
    Electronic Resource
    Electronic Resource
    Springer
    Chromatographia 29 (1990), S. 254-258 
    ISSN: 1612-1112
    Keywords: Column liquid chromatography ; On-line flame-AAS detection ; Hydraulic high pressure nebulization ; Trace metal speciation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary Hydraulic high pressure nebulization is used as an effective way of on-line coupling of HPLC to flame-AAS for speciation of metal compounds in the ng range. Compared to coupling with a conventional nebulizer a signal enhancement by a factor of 7.5 (peak height) and 10.1 (peak area) for copper is obtained. Using an injected volume of 50 μL the detection limits for Cu, Fe, Ni and Cd are below 0.1 μg/mL (=5ng) and for Mg below 0.01 μg/mL (=0.5ng). The effects of HPLC flow-rate and nebulization nozzle diameter on the signal peak height have been investigated. The performance of the system is demonstrated using speciation of iron. A base-line separation of Fe(II) and Fe(III) is achieved within two minutes. Also species changes (Fe acetate to Fe citrate) can be analysed using the proposed system.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 68
    ISSN: 1612-1112
    Keywords: Column liquid chromatography ; Kalman filter ; Cubic spline interpolation ; Al(III) and Cr(III)
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary A procedure for the simultaneous quantitation of Al(III) and Cr(III) ions by reversed-phase HPLC, after pre-column complexation with 8-hydroxyquinoline, is described. The deconvolution of the partially overlapped peaks was by the Kalman filter method which yielded accurate and precise results. Background removal from the chromatograms was by a new approach employing cubic splines as interpolators between the peak valleys. Finally, it is shown that the Kalman filter deconvolution, after subtraction of the background by cubic spline interpolation, allowed quantitation of Al(III) and Cr(III) down to 25 ppb for each metal. These concentrations were not detectable by conventional integration methods due to a very low signal-to-noise ratio.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 69
    ISSN: 1612-1112
    Keywords: Column liquid chromatography ; Hydrophobic parameter ; Capacity factor variation ; Organic modifier concentration ; Displacement model
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary The dependence of the capacity factor (k′) on the concentration of the organic modifier (D) in the aqueous binary mobile phase in reversed-phase high-performance liquid chromatography has been investigated to evaluate the hydrophobicity of the solute molecule. The r-values, defined as the slope of log k′ vs. log(1/D) plots, were measured for various solutes and related to the non-polar surface area and the partition coefficients. The r-value was found to be a good indication of solute hydrophobicity. Detailed investigation of the results allowed to consider statistically the molecular posture of the solute adsorbed onto the stationary alkyl ligand.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 70
    Electronic Resource
    Electronic Resource
    Springer
    Chromatographia 29 (1990), S. 419-428 
    ISSN: 1612-1112
    Keywords: Column liquid chromatography ; Acceptor-Donor complexes ; Selectivity enhancement ; Physical properties/retention correlation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary The paper describes the retention changes observed when an organic acceptor is added to the mobile phase of a liquid chromatography system. The capacity factor decrease depends on the donor character of the solute. Correlations with ionization potentials, HOMO energies and half wave oxidation potentials demonstrate the role of the organic acceptor. According monstrate the role of the organic acceptor. According to the chromatographic properties of the acceptor which is either unretained (TCNE) or slightly retained (TNF) different retention mechanisms are proposed.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 71
    ISSN: 1612-1112
    Keywords: Column liquid chromatography ; Ligand exchange ; α-Amino-acids ; Racemate resolution
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary Racemic α-alkyl-α-amino-acids are difficult solutes to resolve on chiral chromatographic phases derived from proline or pipecolic acid-polyacrylamide. The use of 3-carboxy-1,2,3,4-tetrahydroisoquinoline (porretine) as the chiral selector instead of the former α-amino-acids selectively resolves the α-alkyl-α-amino-acids.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 72
    Electronic Resource
    Electronic Resource
    Springer
    Chromatographia 29 (1990), S. 482-488 
    ISSN: 1612-1112
    Keywords: Column liquid chromatography ; Binary gradient elution ; Optimization
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary A general procedure for optimizing binary gradient elution is described and applied to the specific separation of PTC-Amino Acid derivatives. The method requires two preliminary experimental runs under gradient elution mode followed by computer optimization. The different steps of the optimization procedure are described and the actual chromatograms are compared to the predicted ones.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 73
    ISSN: 1612-1112
    Keywords: Column liquid chromatography ; Oxygen free radicalsin vivo ; Spin traps ; Chemical traps ; Biological fluid and tissue
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary We describe here anin vivo method for direct and simultaneous determination and quantitation of the oxygen free radicals (OFR) superoxide (O2 −) and hydroxy (OH) radicals in biological tissue and blood of 2 week-old swine. Our method utilizes OFR trapping techniques, a spin trap 5,5-dimethyl-1-pyrroline-n-oxide (DMPO), 50 mg/kg, for O2 − and a chemical trap, Na salicylate, (SA, 100 mg/kg) for OH, was infused into the right atrium or pulmonary artery of two-week old swine (n=12). The OFR contents of coronary sinus (CS) blood and left ventricular (LV) tissue (quick frozen at 77°K) were measured by an HPLC method developed by us (Waters 590 solvent delivery system, using Waters electrochemical 460 EC detector, and 740 data module) at +0.6V. The DMPO-O2 − (measured as DMPO-OH) adduct assay was performed with a mobile phase consisting of 0.03 M citric acid, 0.05 M NaOH and 8.5% acetonitrile (Ph 5.1) at a flow rate of 1 ml/min through a Waters Resolve 5 μ C18 column. The salicylate-OH products (2,5 and 2,3 dihydroxy benzoic acids, DHBA) were assayed using mobile phase of 0.03 M Na citrate, 0.03 M Na acetate, with N2 bubbled (pH 3.6) at a flow rate of 0.8 ml/min through a 5μ Resolve C18 column. The detected peak for DMPO-O2 − adduct (9.5 min) was standardized with a hypoxanthine (HX) and xanthine oxidase (XO) mixture and the salicylate-OH products (11.5 min) were standardized with HX, XO and FeCl3. Forin vitro experiments, the blood/tissue samples were immediately (〈30 sec) incubated directly with 100 mM DMPO and/or 200 mM salicylate for 1 min, vortexed and injected for HPLC analysis. Superoxide dismutase (1 μM) and DMSO (10 mM) scavenged O2 − and OH adduct peaks by 77 and 80% respectively. The coefficient of variation for DMPO-O2 − adduct was ±12.6% and for salicylate-OH adduct was ±10.9% (n=12). The normal LV tissue levels determined for O2 − and OH were 0.41 and 0.32 nm/g wet weight, respectively. (In blood, the OFR contents were very small: 0.09 and 0.06 nm/ml, respectively.) This method is very specific and sensitive, 50 pm for O2 − and 0.2 pm for OH radicals.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 74
    ISSN: 1612-1112
    Keywords: Column liquid chromatography ; Automation ; Column switching ; Serotonin in plasma ; Electrochemical detection
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary A simple, fast, fully automated method for plasma serotonin determination is described. Full automation is obtained by coupling two devices: a sample processing station and a solid-phase autosampler. The sample processing station dilutes the plasma sample and is then connected, on-stream, with the solid-phase autosampler. It firstly fills a loop with all the solvents necessary for the sample clean-up, then, inverting the flow, pumps these solvents through the silica-bonded cation-exchange disposable extraction cartridge positioned on the autosampler. For the elution, the cartridge is switched on-stream with the HPLC analytical column and serotonin is eluted by the HPLC mobile-phase. The HPLC separation is performed by ion-pairing reversed-phase liquid chromatography. The column effluent is completely reduced by an electrochemical reactor and serotonin is detected in an oxidation-mode by a dual-cell electrochemical detector. The plasma sample is 50 μl, the plasma sensitivity is 40 ng/l, the retention time is 6 min and the recovery is 95%. The repeatibility, the normal ranges for platelet-poor and for platelet-rich plasma have been established and correlation with manual HPLC calculated.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 75
    ISSN: 1612-1112
    Keywords: Column liquid chromatography ; Cyclodextrins inclusion complexes ; Structure-retention relationships ; Polycyclic aromatics
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary The retention behaviour of a group of polycyclic aromatic hydrocarbons having nearly equal ionization potentials but different molecular polarizability values was investigated using reversed-phase HPLC. Methanol-water binary systems containing β-cyclodextrin were applied as the mobile phase. The relationships between the capacity factors, molecular polarizabilities and the shape parameter of solute molecules are discussed.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 76
    ISSN: 1612-1112
    Keywords: Column liquid chromatography ; Phenolic Compounds ; Solvent extraction
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary The rate of extraction of phenolic compounds in two different solvents has been studied by liquid chromatography (HPLC) under reverse phase, gradient elution conditions. The solvents were diethyl ether and ethyl acetate. The method has been applied to two natural samples, a white wine and apple pulp.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 77
    ISSN: 1612-1112
    Keywords: Column liquid chromatography ; Charge transfer separations ; Hydrogenated polycyclic aromatics ; Coal liquefaction
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary Hydroaromatics (partially hydrogenated polycyclic aromatic hydrocarbons) generated in the course of the process play an important role in the catalytic hydroliquefaction of coal. A difficult analytical task is to identify and to quantify these hydroaromatics among the preponderant polycyclic aromatic hydrocarbons. Generally speaking, the method carried out uses the specific separation of hydroaromatic by charge transfer chromatography. Structural identification is effected by using gas chromatography, alone or coupled with mass spectrometry, and HPLC on amino bonded phase with UV detection. As an aid to obtaining the standard compounds that are essential in that work, this paper describes the application of the above analytical procedure to the catalytic hydrogenation products (RhCl3/NaBH4 and Pd/C) of benzo(a) and benzo(e)pyrenes.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 78
    ISSN: 1612-1112
    Keywords: Column liquid chromatography ; Isoniazid metabolites in urine ; Fluorometric detection ; Post column derivatization
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary A rapid, simple, and accurate method was developed for the determination of isoniazid and its metabolites (isonicotinic acid, acetylisoniazid and isonicotinylglycine) in urine by high-performance liquid chromatography. Urine is diluted with the mobile phase. After centrifugation, an aliquot of the supernatant is injected into the chromatograph. Isoniazid and its metabolites are separated by reversed-phase ionpairing chromatography with a mobile phase containing propanesulfonate and detected by fluorometry using postcolumn derivatization at high temperature (150°C) with hydrogen peroxide. The method was applied to the analysis of urine from patients receiving isoniazid therapy.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 79
    ISSN: 1612-1112
    Keywords: Column liquid chromatography ; Cephalosporins ; Column switching in HPLC ; On-line plasma sample clean-up
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary A new high performance liquid chromatographic method was developed using a column-switching technique for the simultaneous determination of cephalexin, cefuroxime, cefoxitin and cephaloridine in plasma. The plasma samples were injected onto a precolumn packed with Corasil RP C18 (37–50 μm) after simple dilution with an internal standard solution in 0.01 M acetate buffer (pH 3.5). Polar plasma components were washed out using 0.01 M acetate buffer (pH 3.5). After valve switching, the concentrated drugs were desorbed in back-flush mode and separated on a Partisil ODS-3 column using acetonitrile in 0.02 M acetate buffer (pH 4.3) (15∶85, v/v) as the mobile phase. The method showed excellent precision with good sensitivity and speed with a detection limit of 0.5 μg/ml. The total analysis time per sample was less than 25 min, and the mean coefficients of variation for intra- and inter-assay were both less than 4.9 %. This method has been successfully applied to plasma from rats after subcutaneous injection of cefuroxime.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 80
    ISSN: 1612-1112
    Keywords: Column liquid chromatography ; Optimization of variables ; Information theory ; Kalman filter
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary The following chromatographic variables are totally optimized based on the recently developed information theory of optimization: mobile phase composition, column length, flow rate, wavelength, and the amount of internal standard. The optimal internal standard is selected from among six candidates. Two types of optimal conditions (Φ- and ϑ-optimals) are proposed: the Φ-optimal is defined as the most precise analysis (the maximal Φ) while the ϑ-optimal is the most efficient (rapid) analysis (the maximal ϑ). The observation times for the determination of an antipyretics mixture (three components) in liquid chromatography are ca. 50 s for the ϑ-optimal and ca. 8 min for the Φ-optimal. The reliability of the Φ- and ϑ-optimals is verified by experiments.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 81
    Electronic Resource
    Electronic Resource
    Springer
    Chromatographia 30 (1990), S. 663-674 
    ISSN: 1612-1112
    Keywords: Column liquid chromatography ; New stationary phases ; Peptides ; Performance testing
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary Some new HPLC-phases (Polyencap, Hypercarb, Poly F, PRP∞) have been assessed for their suitability in the separation of peptides. Test criteria were peptide recovery, separation-efficiency, selectivity and stability. The eluents TFA/acetonitrile and acetatebuffer/propanol are compared. Of interest are the stability and recovery of Polyencap, the high separation efficiency of the standard RP-8 silica-based phase (Nucleosil C8) and the unusual peak-width of PRP∞. Acceptable conditions for peptide separations may be provided by Polyencap, but stability still has to be improved.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 82
    Electronic Resource
    Electronic Resource
    Springer
    Chromatographia 30 (1990), S. 696-702 
    ISSN: 1612-1112
    Keywords: Column liquid chromatography ; Ribosomal proteins ; Two-dimensional micro gel electrophresis ; Bacillus stearothermophilus
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary 50S subunits ofBacillus stearothermophilus ribosomes were isolated and crosslinked with the homobifunctional reagent diepoxybutane. Two protein-protein crosslinks consisting of the proteins L23-L29 and L3-L19 could be purified on a preparative scale using conventional column chromatography followed by a combination of different HPLC techniques. This procedure allows the isolation of the crosslinks in amounts high enough for the determination of the crosslinked amino acids.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 83
    Electronic Resource
    Electronic Resource
    Springer
    Chromatographia 30 (1990), S. 298-300 
    ISSN: 1612-1112
    Keywords: Column liquid chromatography ; Normal phase separations ; Binary liquid phases ; Molecular interactions
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary We apply our new retention model introduced elsewhere to the studies of intermolecular interactions between the solute and the remaining components of a normal-phase HPLC system using a binary mobile phase consisting of an alcohol and a hydrocarbon. This can be achieved through the analysis of the regressional parameters A, B, and C appearing in the relationship of solute retardation (RF) vs. mobile phase composition. Negative values of these parameters indicate a greater affinity of the solute to the stationary phase than to a given mobile phase moiety, whereas positive values have a reverse meaning. According to the absolute values of A, B, and C solute groups can be arranged according to the affinity toward a given mobile phase moiety, which is a detailed and important information regarding their separation, the stationary phase and with each individual constituent of the mobile phase.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 84
    ISSN: 1612-1112
    Keywords: Column liquid chromatography ; Chiral interaction reagents ; Vitamin C ; D(−)-and L(+)-ascorbic acids
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary An HPLC reversed-phase ion interaction reagent method is presented, which makes use of chiral compounds as the interaction reagents. By employing the optical isomeric forms of malic, tartaric and mandelic acids as the interaction reagents, a good separation of D(−) and L(+) ascorbic acid has been achieved. The method has also been applied to the identification of vitamin C in some medical formulations. The separation of te enantiomeric forms of DL malic acid has been attempted and a shor discussion is presented about the elution sequence in chromatographic separation of D- and L-enantiomers.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 85
    ISSN: 1612-1112
    Keywords: Column liquid chromatography ; Affinity chromatography ; Anhydrotrypsin ; C-terminal Arg- or Lys-containing peptides ; Diol silica
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary Anhydrotrypsin (AHT), a catalytically inert derivative of trypsin in which the active site serine residue was converted to dehydroalanine residue by chemical modification, was immobilized onto diol silica through the activation with trifluoroethanesulfonyl chloride, and an AHT-diol-silica column was used for high-performance affinity chromatography separation of peptides containing arginine or lysine at their C-termini from the others. Improved separation in terms of speed was accomplished.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 86
    ISSN: 1612-1112
    Keywords: Column liquid chromatography ; Mycotoxins ; Ochratoxin A ; Rumen fluid
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary An efficient procedure for the extraction and analysis of ochratoxins A, B, C and α from buffered rumen fluid has been developed. The samples have been cleaned up byliquid-liquid extraction and the separation of chratoxins was by isocratic elution on a 5μm C18 ODS-column which 0.083 M phosphoric acid/acetonitrile/isopropanol (55/35/10).
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 87
    ISSN: 1612-1112
    Keywords: Column liquid chromatography ; Metal-interaction chromatography ; Rapid HPLC ; Phosphopeptides, proteins and peptides ; Micropellicular stationary phases ; Interaction of phosphate with Fe3+
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary Short columns packed with micropellicular stationary phases consisting of 2-μm fused silica microspheres with covalently bound iminodiacetate (IDA) functions at the surface were used for rapid HPLC analysis of proteins by metal-interaction chromatography (MIC). In contrast to conventional porous stationary phases which elicit relatively long analysis times, the columns packed with sorbents having micropellicular configuration and Ni2+ or Co2+ chelated by the IDA functions yielded separation of model proteins in a few minutes with good resolution. A Fe3+/IDA column was used for separation of phosphorylated and non-phosphorylated peptides derived from enzymatically digested erythrocyte membrane proteins. Stability of the Fe3+/IDA column was quite satisfactory as determined by monitoring the iron content of the column effluent and by measuring the amount of iron present in the stationary phase.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 88
    Electronic Resource
    Electronic Resource
    Springer
    Chromatographia 30 (1990), S. 421-423 
    ISSN: 1612-1112
    Keywords: Gas chromatography ; Column liquid chromatography ; Carbofuran ; Hydroponics
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary Two analytical methods using GC/NPD and HPLC to analyse carbofuran in a nutrient solution used in hydroponic culture are described. Both methods show a high recovery, (greater than 90%), and their limits of detection are low.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 89
    Electronic Resource
    Electronic Resource
    Springer
    Chromatographia 30 (1990), S. 428-431 
    ISSN: 1612-1112
    Keywords: Column liquid chromatography ; Immunoaffinity ; Modified acrylic copolymers ; Antibody anti-human serum albumin
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary Copolymer beads from acrylonitrile and ethyl either butyl acrylate or vinyl acetate, with amino, hydroxyl or carboxyl groups were activated with glutaraldehyde or water-soluble carbodiimide and coupled to human serum albumin. The obtained immunoadsorbents were applied to the isolation of anti-human albumin anibody from rabbit antiserum. Among the 22 studied copolymers only a few showed satisfactory effectiveness for immunoaffinity chromatography, similar to that noted for immunoadsorbents from commerical polymers.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 90
    ISSN: 1612-1112
    Keywords: Column liquid chromatography ; Reversed-phase systems ; Octyl, octadecyl, phenyl and cyano-bonded phases ; Flavonoids ; Structure-retention relationships
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary Retention of an extended set of flavonoid compounds by octyl, octadecyl, phenyl and cyanopropyl-bonded, reversed-phase columns, with methanol, as the organic mobile phase modifier and acetic acid as the acid modifier is reported. Solvent strengths and useful ranges for both isocratic and gradient elution are determined. Relative retention is found to be independent of methanol volume fraction in the mobile phase for all the columns examined. Correlations between retention on different columns, specific selectivity effects and their dependence on molecular structure are analyzed. Practical applications for separation and identification are discussed.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 91
    ISSN: 1612-1112
    Keywords: Column liquid chromatography ; Tandem mass spectrometry ; Peptides ; Loop valve
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary The interfacing of a high performance liquid chromatograph, utilizing a dry-packed Spherisorb® C8 column (0.25×500 mm), with a four-sector tandem mass spectrometer via a frit-FAB probe is described. In order to utilize the sensitivity of the mass spectrometer, which is equipped with an array detector, the gradient solvent was split to a flow rate of 2–5 μL/min before the sample injector. The effluent flows directly into the mass spectrometer for the recording of the (M+H)+ ions of mixtures with the first of the two mass spectrometers (MS-1), or for their collision-induced-decomposition (CID) spectra by scanning the second mass spectrometer (MS-2). Those components that elute too close in time to allow the complete CID spectrum of each are diverted into a sample loop, which later can be switched in-line to the mass spectrometer to provide more time for collecting all the data. The method is demonstrated with a tryptic digest of the α-chain of human hemoglobin.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 92
    Electronic Resource
    Electronic Resource
    Springer
    Chromatographia 18 (1984), S. 574-578 
    ISSN: 1612-1112
    Keywords: Column liquid chromatography ; Microbore column ; Flow rate stability ; Performance ; Quantitative analysis
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary Some quantitative implications of the use of microbore columns in column liquid chromatography are investigated. Although for several pumps the flow rate stability at 50 μl min−1 is slightly worse than that of pumps operating at 1 ml min−1, the quantitative performance with respect to repeatability and reproducibility of response factors equals that of conventional liquid chromatography. Thermostatting is strongly recommended for microbore column operation.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 93
    Electronic Resource
    Electronic Resource
    Springer
    Chromatographia 18 (1984), S. 62-64 
    ISSN: 1612-1112
    Keywords: Column liquid chromatography ; Reversed phase ; Microparticulate packing ; Amino acids
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract A procedure is described by which 20 commonly occurring amino acids may be separated by reversed-phase liquid chromatography at room temperature in a total time, including derivatisation with o-phthalaldehyde/2-mercaptoethanol reagent, of approximately 15 minutes. Further, an increase in column temperature enables increased resolution of certain amino acids to be obtained with small but acceptable losses in fluorescence intensity. The only major drawback to the method is that the derivatisation reagent does not react with proline or hydroxyproline.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 94
    ISSN: 1612-1112
    Keywords: Column liquid chromatography ; Carboxylic acids ; Fruit juices ; Wine
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary A direct method for the simultaneous determination of tartaric, malic, lactic, acetic, citric, shikimic, fumaric and succinic acids in fruit juices and wines by isocratic reversed phase HPLC is reported. The variables (pH, ionic strength, flow and temperature) have been optimized by a modification of the original simplex method. The separation factor (s) and calibrated resolution product (r*) have been used as criteria for selectivity optimization. After validation, the method has been applied to the determination of carboxylic acids in apple, orange and lemon juices, white and red wines and musts during the fermenation process.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 95
    Electronic Resource
    Electronic Resource
    Springer
    Chromatographia 29 (1990), S. 583-586 
    ISSN: 1612-1112
    Keywords: Column liquid chromatography ; Intermolecular interactions ; Retention mechanisms in RP systems
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary In this paper we consider the possibility of gaining a better insight in the retetion mechanisms of solutes chromatographed in reversed-phase (RP) HPLC systems with the use of methanol-water binary mixtures as the mobile phase. This is done with help of the new retention model presented earlier as the relationship for the retardation coefficient (RF) of solute. The equation constants A, B and C were defined as proportional to the hypothetical retardation coefficients of the solute chromatographed separately in the three theoretically extracted moieties of the mobile phase (i.e. in pure methanol, pure water and the H-bonded associative methanol-water mixture); therefore the message imbedded in their numerical values can refer to the different and often opposite forces acting separately on the solute in a given RP-HPLC system from the side of each mobile phase moiety. An effort to decipher this message was undertaken upon the empirical results obtained for three groups of compounds, i.e., for dithia[3.3]phanes, and mono- and dihydroxyaromatics.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 96
    ISSN: 1612-1112
    Keywords: Column liquid chromatography ; Ovomucoid-bonded silica ; Chiral separation ; Propranolol ; Propranolol ester derivatives
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary The retention, enantioselectivity and enantiomeric elution order of racemic propranolol (PP) and its ester derivatives (O-acetyl,-propyl,-butyl and-valeryl PP) on an ovomucoid-bonded silica column have been investigated with respect to pH, ionic strength and organic modifier. For these cationic solutes, an increase in the organic modifier content and/or a decrease in the pH result in a decreased retention of both enantiomers. Enantioselectivity of the ester derivatives was higher than of underivated PP. The enantiomeric elution order was (S)/(R) for PP and (R)/(S) for the four ester derivatives, when ethanol or 2-propanol was used as the organic modifier. When methanol or acetonitrile was used as the organic modifier, inversion of the enantiomeric elution order was observed for O-valeryl PP with the use of methanol and for PP and O-propyl PP with acetonitrile. These results suggest that at least two chiral binding- or recognitionsites are present in a protein molecule and/or conformational changes occur in the chiral binding- or recognition-site(s) of the protein molecule bonded to a silica matrix.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 97
    Electronic Resource
    Electronic Resource
    Springer
    Chromatographia 29 (1990), S. 135-138 
    ISSN: 1612-1112
    Keywords: Column liquid chromatography ; Preparative scale separation ; Ceralure ; Trimedlure-related isomers ; Ceratitis capitata
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary A semi-preparative high-performance liquid chromatographic procedure on 5-μm silica was developed for the isolation of gram quantities of ethyltrans-5-iodo-trans-2-methylcyclohexane-1-carboxylate (B1) and ethyltrans-4-iodo-trans-2-methylcyclohexane-1-carboxylate (B2) for comparative evaluation as male Mediterranean fruit fly,Ceratitis capitata, attractants and for NMR studies. This procedure can also be used analytically to determine the content of B1 (the attractive isomer) in ceralure, the ethyl 4- and 5-iodo-trans-2-methylcyclohexane-1-carboxylate mixture. 1,1-Dimethylethylcis-5-iodo-trans-2-methylcyclohexane-1-carboxylate (A) and 1,1-dimethylethylcis-4-iodo-trans-2-methylcyclohexane-1-carboxylate (C) were isolated and converted to their ethyl esters, thus supplying the fourtrans-isomers of ceralure.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 98
    ISSN: 1612-1112
    Keywords: Column liquid chromatography ; Diode array T/mass spectrometry detection ; Atrazine, Diuron and Fenitrothion ; Photodegradation studies in distilled water and seawater
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary The advantages of liquid chromatography with diode array and mass spectrometric detection are described for the direct characterization of the photodegradation products of Fenitrothion, Atrazine and Diuron in distilled water and artifical seawater samples. The photodegradation (UV λ〉290 nm) of the herbicides Atrazine and Diuron was examined in distilled water and in artificial seawater containing humic acids. Major photodegradation products were hydroxyatrazine and Monuron, respectively. The results showed a faster degradation in seawater as compared to distilled water for Atrazine whereas for Diuron a quenching effect was observed thus retarding photodegradation. The photodegradation of Fenitrothion was also investigated. For this pesticide, hydrolysis predominates in seawater and photolysis is very slow in distilled water, so that acetone was needed as photosensitizer.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 99
    Electronic Resource
    Electronic Resource
    Springer
    Chromatographia 29 (1990), S. 151-154 
    ISSN: 1612-1112
    Keywords: Column liquid chromatography ; Aliphatic amines in air ; m-Toluoyl derivatives ; Annular denuder
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary Traces of C1−C4 aliphatic amines, sampled from ambient air on H3PO3-coated annular denuders, are derivatized with m-toluoyl chloride (MTC) in alkaline acetonitrile. The resulting derivatives are determined by reversed phase HPLC with ultraviolet detection at 230 nm. The detection limits of the individual amines are in the 1 to 5 picomole range corresponding to gasphase concentrations lower than 0.1 μg m−3 in air samples collected at 5 Lmin−1 for one hour.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 100
    ISSN: 1612-1112
    Keywords: Column liquid chromatography ; Amino acids ; O-phthaldialdehyde-2-mercaptoethanol ; Apples
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary A rapid and sensitive method for the simultaneous determination of primary amino acids in apple is described. After sample preparation, amino acids were derivatized with o-phthaldialdehyde/2-mercaptoethanol and separated on a reversed phase column with a gradient of phosphate buffer-tetrahydrofuran-methanol as the mobile phase. Detection was carried out with a fluorescence detector at excitation and emission wavelengths of 340 nm and 425 nm respectively. Recovery studies showed good results for all substances (91–109%) (with coefficients of variation ranging, from 0.1 to 9.0%). This method was applied to the monitoring of amino acids during the ripening of apples.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
Close ⊗
This website uses cookies and the analysis tool Matomo. More information can be found here...