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  • 1
    Schlagwort(e): Biomass conversion ; Biotechnology ; Chemical Engineering ; Chemistry industry ; Industrial Chemistry ; Kent ; Riegel ; biochemical engineering
    Beschreibung / Inhaltsverzeichnis: Substantially revising and updating the classic reference in the field, this handbook offers a valuable overview and myriad details on current chemical processes, products, and practices. No other source offers as much data on the chemistry, engineering, economics, and infrastructure of the industry. The Handbook serves a spectrum of individuals, from those who are directly involved in the chemical industry to others in related industries and activities. It provides not only the underlying science and technology for important industry sectors, but also broad coverage of critical supporting topics. Industrial processes and products can be much enhanced through observing the tenets and applying the methodologies found in chapters on Green Engineering and Chemistry (specifically, biomass conversion), Practical Catalysis, and Environmental Measurements; as well as expanded treatment of Safety, chemistry plant security, and Emergency Preparedness. Understanding these factors allows them to be part of the total process and helps achieve optimum results in, for example, process development, review, and modification. Important topics in the energy field, namely nuclear, coal, natural gas, and petroleum, are covered in individual chapters. Other new chapters include energy conversion, energy storage, emerging nanoscience and technology. Updated sections include more material on biomass conversion, as well as three chapters covering biotechnology topics, namely, Industrial Biotechnology, Industrial Enzymes, and Industrial Production of Therapeutic Proteins.
    Seiten: Online-Ressource (XIV, 1562 pages)
    ISBN: 9780387278438
    Sprache: Englisch
    Standort Signatur Erwartet Verfügbarkeit
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  • 2
    Publikationsdatum: 2020-10-29
    Beschreibung: We present new viscosity measurements for melts spanning a wide range of anhydrous compositions including: rhyolite, trachyte, moldavite, andesite, latite, pantellerite, basalt and basanite. Micropenetration and concentric cylinder viscometry measurements cover a viscosity range of 10−1 to 1012 Pas and a temperature range from 700 to 1650 °C. These new measurements, combined with other published data, provide a high-quality database comprising ∼800 experimental data on 44 well-characterized melt compositions. This database is used to recalibrate the model proposed by Giordano and Dingwell [Giordano, D., Dingwell, D. B., 2003a. Non-Arrhenian multicomponent melt viscosity: a model. Earth Planet. Sci. Lett. 208, 337–349] for predicting the viscosity of natural silicate melts. The present contribution clearly shows that: (1) the viscosity (η)–temperature relationship of natural silicate liquids is very well represented by the VFT equation [log η=A+B/ (T−C)] over the full range of viscosity considered here, (2) the use of a constant high-T limiting value of melt viscosity (e.g., A) is fully consistent with the experimental data, (3) there are 3 different compositional suites (peralkaline, metaluminous and peraluminous) that exhibit different patterns in viscosity, (4) the viscosity of metaluminous liquids is well described by a simple mathematical expression involving the compositional parameter (SM) but the compositional dependence of viscosity for peralkaline and peraluminous melts is not fully controlled by SM. For these extreme compositions we refitted the model using a temperature-dependent parameter based on the excess of alkalies relative to alumina (e.g., AE/SM). The recalibrated model reproduces the entire database to within 5% relative error (e.g., RMSE of 0.45 logunits).
    Beschreibung: Published
    Beschreibung: 42–56
    Beschreibung: reserved
    Schlagwort(e): Viscosity ; Model ; Silicate melts ; Metaluminous ; Peraluminous ; Peralkaline ; 04. Solid Earth::04.01. Earth Interior::04.01.05. Rheology ; 04. Solid Earth::04.04. Geology::04.04.05. Mineralogy and petrology ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
    Format: 717294 bytes
    Format: application/pdf
    Standort Signatur Erwartet Verfügbarkeit
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  • 3
    Publikationsdatum: 2021-06-16
    Beschreibung: A stable isotope record from a stalagmite collected from Antro del Corchia cave (Apuan Alps, Central Italy), supported by 17 uranium-series ages, indicates enhanced regional rainfall between ca 8.9 and 7.3 kyr cal. BP at the time of sapropel S1 deposition. Within this phase, the highest rainfall occurred between 7.9 and 7.4 kyr cal. BP. Comparison with different marine and lake records, and in particular with the Soreq Cave record (Israel), suggests substantial in-phase occurrence of enhanced rainfall between the Western and Eastern Mediterranean basins. There is no convincing evidence for major climatic change at the time of the “8.2 kyr event”.
    Beschreibung: Published
    Beschreibung: 279-286
    Beschreibung: 3.8. Geofisica per l'ambiente
    Beschreibung: JCR Journal
    Beschreibung: reserved
    Schlagwort(e): climatic change ; olocene ; sapropel S1 ; stalagmite ; 03. Hydrosphere::03.01. General::03.01.06. Paleoceanography and paleoclimatology
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
    Standort Signatur Erwartet Verfügbarkeit
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  • 4
    Publikationsdatum: 2020-09-29
    Beschreibung: This chapter summarizes a comparative study of shear-wave velocity models and seismic sources in the Campanian volcanic areas of Vesuvius and Phlegraean Fields. These velocity models were obtained through the nonlinear inversion of surfacewave tomography data, using as a priori constraints the relevant information available in the literature. Local group velocity data were obtained by means of the frequency–time analysis for the time period between 0.3 and 2 s and were combined with the group velocity data for the time period between 10 and 35 s from the regional events located in the Italian peninsula and bordering areas and two station phase velocity data corresponding to the time period between 25 and 100 s. In order to invert Rayleigh wave dispersion curves, we applied the nonlinear inversion method called hedgehog and retrieved average models for the first 30–35km of the lithosphere, with the lower part of the upper mantle being kept fixed on the basis of existing regional models. A feature that is common to the two volcanic areas is a low shear velocity layer which is centered at the depth of about 10 km, while on the outside of the cone and along a path in the northeastern part of the Vesuvius area this layer is absent. This low velocity can be associated with the presence of partial melting and, therefore, may represent a quite diffused crustal magma reservoir which is fed by a deeper one that is regional in character and located in the uppermost mantle. The study of seismic source in terms of the moment tensor is suitable for an investigation of physical processes within a volcano; indeed, its components, double couple, compensated linear vector dipole, and volumetric, can be related to the movements of magma and fluids within the volcanic system. Although for many recent earthquake events the percentage of double couple component is high, our results also show the presence of significant non-double couple components in both volcanic areas.
    Beschreibung: Published
    Beschreibung: 287-309
    Beschreibung: reserved
    Schlagwort(e): NONE ; 04. Solid Earth::04.06. Seismology::04.06.03. Earthquake source and dynamics
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: book chapter
    Format: 8247786 bytes
    Format: application/pdf
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  • 5
    Publikationsdatum: 2020-10-29
    Beschreibung: Viscosity of hydrous trachytes from the Agnano Monte Spina eruption (Phlegrean Fields, Italy) has been determined at 1.0 GPa and temperatures between 1200 and 1400 °C using the falling sphere method in a piston cylinder apparatus. The H2O content in the melts ranged from 0.18 to 5.81 wt.%. These high-temperature hydrous viscosities, along with previous ones determined at low-temperature (anhydrous and hydrous) and at high-temperature (anhydrous), at 1 atm on the same melt composition, represent the only complete viscosity data set available for K-trachyticmelts, frommagmatic to volcanic conditions.Viscosity decreases with increasing temperature andwater content in the melt.At constant temperature, viscosity appears to significantly decreasewhen the first wt.% ofH2Ois added.At H2O content higher than 3 wt.% the effect of temperature on viscosity is slight. Moreover, the deviation from Arrhenian behaviour towards greater “fragility” occurs with increasing water content. We combined low- and high-temperature viscosities (also from literature) and parameterized themby the use of a modified Vogel–Fulcher–Tamman equation, which accommodates the non-Arrhenian temperature dependence ofmelt viscosity.Moreover, in order to explore the extent to which the improved knowledge of Agnano Monte Spina trachyte viscosity may affect simulation of volcanic eruption at Phlegrean Fields, we included our viscosity models in numerical simulations of magma flow and fragmentation along volcanic conduits. These simulations show that the new parameterizations (and hence the new equations) give stronger predictions in the temperature interval relevant for magmatic and eruptive processes.
    Beschreibung: Published
    Beschreibung: 124-137
    Beschreibung: JCR Journal
    Beschreibung: reserved
    Schlagwort(e): Viscosity ; Trachyte ; Falling sphere method ; Vogel–Fulcher–Tamman equation ; 04. Solid Earth::04.08. Volcanology::04.08.02. Experimental volcanism ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
    Standort Signatur Erwartet Verfügbarkeit
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  • 6
    Publikationsdatum: 2021-01-14
    Beschreibung: The viscosity of shoshonitic melts from Vulcanello Peninsula (Vulcano Island, Italy) is experimentally determined at temperatures between 733 K and 1673 K. The water content of the melts varies from 0.03 to 4.75 wt% H2O. The micropenetration technique is employed at ambient pressure in the high viscosity range (109-1012 Pa·s). Falling sphere(s) experiments are performed at 500 and 2000 MPa in the low viscosity range (100.5-103 Pa·s). Results show a decrease of about 2 orders of magnitude in viscosity if ~ 3 wt% of water is added to the dry melt at 1300 K. At high temperature the viscosity of Vulcanello melts is intermediate between that of andesitic and basaltic melts. In contrast, at low temperatures (≤1050 K), the shoshonitic melt is characterized by a lower viscosity with respect to the two previous melts. Based on our new data set, a calculation model is proposed to predict the viscosity of the shoshonitic melts as a function of temperature and water content. The viscosity data are used to constrain the ascent velocity of shoshonitic magmas from Vulcanello within dikes. Using petrological data (temperature and crystal content of the magma) and volcanological information (geometrical parameters of the eruptive fissure and depth of magma storage), we estimate the time scale for the ascent of magma from the main reservoir to the surface. Results show time scales in the order of hours to few days. We conclude that the rapid ascent of poorly evolved melts from Moho depths should be taken into account for the hazard assessment of Vulcano Island.
    Beschreibung: Published
    Beschreibung: 89-102
    Beschreibung: 2.3. TTC - Laboratori di chimica e fisica delle rocce
    Beschreibung: JCR Journal
    Beschreibung: open
    Schlagwort(e): dikes ; ascent velocity ; 04. Solid Earth::04.01. Earth Interior::04.01.05. Rheology
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
    Standort Signatur Erwartet Verfügbarkeit
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  • 7
    Publikationsdatum: 2021-01-05
    Beschreibung: We investigate fault interaction through elastic stress transfer among a sequence of moderate-magnitude main shocks (5 〈 Mw 〈 6) which ruptured distinct normal fault segments during a seismic sequence in the Umbria-Marche region (central Apennines). We also model the spatial pattern of aftershocks and their faulting mechanisms through Coulomb stress changes. We compute stress perturbations caused by earthquake dislocations in a homogeneous half-space. Our modeling results show that seven out of eight main shocks of the sequence occur in areas of enhanced Coulomb stress, implying that elastic stress transfer may have promoted the occurrence of these moderate- magnitude events. Our modeling results show that stress changes caused by normal faulting events reactivated and inverted the slip of a secondary N-S trending strike-slip fault inherited from compressional tectonics in its shallowest part (1–3 km). Of the 1517 available aftershocks, 82% are located in areas of positive stress changes for optimally oriented planes (OOPs) for Coulomb failure. However, only 45% of the 322 available fault plane solutions computed from polarity data is consistent with corresponding focal mechanisms associated with the OOPs. The comparison does not improve if we compute the optimally oriented planes for Coulomb failure by fixing the strike orientation of OOPs using information derived from structural geology. Our interpretation of these modeling results is that elastic stress transfer alone cannot jointly explain the aftershock spatial distribution and their focal mechanisms.
    Beschreibung: Published
    Beschreibung: B05S20
    Beschreibung: 3.1. Fisica dei terremoti
    Beschreibung: JCR Journal
    Beschreibung: reserved
    Schlagwort(e): Coulomb Stress Changes ; Normal Faulting ; 04. Solid Earth::04.04. Geology::04.04.06. Rheology, friction, and structure of fault zones
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
    Standort Signatur Erwartet Verfügbarkeit
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  • 8
    Publikationsdatum: 2020-11-30
    Beschreibung: Auckland, New Zealand is unique in being a metropolitan area built on an active volcanic field. Despite the small size and intensity of Auckland eruptions, the risk from tephra fall is high because of the high density of buildings and lifelines. The nature of this threat can be evaluated by comparisons with historical Strombolian and Hawaiian eruptions, which have occurred in non-populated areas. Cone-building phases of such eruptions are typically protracted, i.e., weeks to months in duration, prolonging the period during which emergency managers will have to fine tune mitigation for numerous parameters such as fluctuations in intensity and wind shifts. Rapid cone growth during future eruptions will define a region of some 30 to 100 ha where complete destruction will occur on a time scale of hours. The cost of this destruction is likely to range between NZ$200M and NZ$1.4B (ca. US$130M to US$900M). Beyond this, we have modeled the cumulative long-term effect of the build-up of a downwind blanket of lapilli and ash by estimating accumulation rates for three phases of the 1959 Kīlauea Iki eruption in Hawaii. The effect of changing wind direction was evaluated using low-level wind data from Auckland. These results show that intervals between 4 and 100 h will lapse before onset of significant damage to buildings.
    Beschreibung: Published
    Beschreibung: 138-149
    Beschreibung: 4.3. TTC - Scenari di pericolosità vulcanica
    Beschreibung: JCR Journal
    Beschreibung: reserved
    Schlagwort(e): tephra hazard ; Auckland volcanic field ; cone growth ; tephra fall ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
    Standort Signatur Erwartet Verfügbarkeit
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  • 9
    facet.materialart.
    Unbekannt
    Springer
    Publikationsdatum: 2020-12-15
    Beschreibung: no abstract
    Beschreibung: Unpublished
    Beschreibung: 1.1. TTC - Monitoraggio sismico del territorio nazionale
    Beschreibung: open
    Schlagwort(e): earthquake location ; source parameters ; 04. Solid Earth::04.06. Seismology::04.06.10. Instruments and techniques
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: book chapter
    Standort Signatur Erwartet Verfügbarkeit
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  • 10
    Publikationsdatum: 2021-01-27
    Beschreibung: The eruptive dynamics of volcanic systems are largely controlled by the viscosity of deforming magma. Here we report the results of a series of high-temperature, high-pressure experiments at conditions relevant for volcanic conduits (250 MPa confining pressure and temperature between 500 °C and 900 °C) that were undertaken to investigate the rheology of magma with crystal fractions varying between 0.5 and 0.8 (50 to 80 wt.%) at different strain-rate conditions. The experiments demonstrate that the presence of crystals increases the relative viscosity (ratio between the viscosity of the mixture and the viscosity of the melt phase) of magmas and additionally induces a decrease of the relative viscosity with increasing strain-rate (shear thinning, non-Newtonian behavior). The experimental results, combined with existing data at low crystal fractions (0–0.3), were used to develop a semi-empirical parameterization that describes the variations of relative viscosity for crystal fractions between 0 and 0.8 and accounts for the complex non-Newtonian rheology of crystal-bearing magmas. The new parameterization, included into numerical models simulating the magma ascent dynamics, reveals that strain-rate-dependent rheology significantly modifies the dynamic behavior inside volcanic conduits, particularly affecting the magma fragmentation conditions.
    Beschreibung: Published
    Beschreibung: 402-419
    Beschreibung: 3.6. Fisica del vulcanismo
    Beschreibung: JCR Journal
    Beschreibung: partially_open
    Schlagwort(e): magma rheology ; experimental deformation ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
    Standort Signatur Erwartet Verfügbarkeit
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