ALBERT

Description: Many of the difficulties of staining plastic embedded tissues for light and electron microscopy derive from physical exclusion of hydrophilic staining reagents by hydrophobic embedding media. Structures which stain most intensely with hydrophilic reagents usually contain less hydrophobic plastic than do non-staining structures. Such incomplete infiltration is apparently caused by exclusion of viscous, hydrophobic monomers by physically dense and/or well hydrated tissue elements. In keeping with this, generalized staining of tissues embedded in hydrophobic media does occur when hydrophobic reagents are used. Staining of plastic-free structures with single hydrophilic reagents or with sequences of such reagents, is, however, largely rate-controlled. The surprising similarity of hydrophilic and hydrophobic plastic embedding media is discussed. Limits of this simple model are explored, with a consideration of the roles of fixative and of monomer-tissue reactions

Description: Samples collected at hourly intervals on May 18–19, 1980, at three sites 200 km downwind from Mount St. Helens, have made possible a detailed reconstruction of the conditions that contribute to the compositional heterogeneity of mineral and glass components observed in distal tephra layers. The air fall tephra deposited at the sites during the first 7 hours of the May 18 eruption is mostly coarse grained, microlite-rich, nonjuvenile glass and feldspar. Grain-size maxima in this initial tephra can be related to the cataclysmic blast at 0832 and a subsequent pulse of the eruption at 1200. Juvenile, microlite-free glass increases in relative abundance at the sampling sites beginning at about 1900. Such a change between nonjuvenile and juvenile tephra can be related to a 5-km increase in column height associated with the last major pulse of the eruption which occurred at 1700 at the volcano. Electron microprobe study of both microlite-rich and microlite-free pumice in the time series samples reveals significant compositional differences. Interstitial glass in nonjuvenile pumice deposited during the first few hours at the sampling sites is enriched in SiO2 and K2O and depleted in TiO2, FeO*, and MgO relative to juvenile glass. By comparison, major element composition of the least evolved juvenile glass sampled during the last several hours of the eruption displays a slight trend toward less evolved composition. Least squares calculations suggest that the more evolved character of the nonjuvenile glass can be explained by greater fractional crystallization brought about by enhanced cooling in a cryptodome prior to eruption, whereas the temporal changes observed in juvenile glass composition during the last several hours of the eruption suggest the presence of a small, slightly zoned magma chamber at depth. Electron microprobe study of glass-coated ilmenites, magnetites, and plagioclases provides the following estimates of the physical conditions in this reservoir: 865°±50°C, PH2O = 2.2 kbar and -log ƒO2 = 11.7. Analyses of bulk pumice, glass and selected mineral phases from May 25, June 12, July 22, and October 16–18 pumices erupted from Mount St. Helens indicate that the bulk pumice (magma) compositions have become slightly more andesitic with time, while mineral and co-existing glass compositions have changed significantly in post-May 18 eruptions with both being more highly evolved than those associated with the May 18 eruption. An application of the magnetite-ilmenite geothermometer to June 12 and July 22 samples indicates temperatures of 919°±30°C and 930°±50°C, respectively. Least squares calculations suggest that such evolved post-May 18 glass and mineral phases can be derived by fractional crystallization of a magma composition like bulk May 18 pumice into approximately 50% crystals and 50% residual liquid. Such partitioning between crystals and residual liquid appears to have occurred on the scale of centimeters and is interpreted as a consequence of accelerated crystallization under reduced water pressure.

Description: Sedimentation rates (corrected for compaction) from along the passive continental margin of Africa between the Equatorial Fracture Zone and Somalia are used to compare the rates of subsidence of the continental crust since early Mesozoic time. Three distinctive subsidence histories can be identified which correspond with basinal areas that have different structural styles: rifted (west coast), sheared (Equatorial and Agulhas fracture zones) and sunk (zones of vertical tectonics in eastern Africa). A comparison of subsidence rates with other tensional margins (NE USA and the North Sea) and a consideration of the plate tectonic history of the African margins leads to the proposal of a geo and thermodynamic model that takes cognizance of the worldwide mid-Cretaceous rheological discontinuity between taphrogenic and epeirogenic basin formation recognized by Kent, and the more generally accepted, purely plate tectonic driven model of margin subsidence. The new suggestion involves a lower Mesozoic worldwide rise in the geothermal gradient in the lithosphere which produces metamorphism of the base of the continental crust and initiates taphrogenesis along lineaments throughout Gondwanaland. A lowering of the geothermal gradient in the lower Cretaceous produces a switch to epeirogenic subsidence, driven solely by sediment loading and thermal contraction, by Aptian/Albian times. The thermal event facilitated continental separation, and sea floor spreading commenced locally at various times along the active taphrogenic belts. Local thermal and tectonic aberrations associated with this phenomenon over print onto the worldwide pattern of marginal basin subsidence. A further rise in the geothermal gradient may have been responsible for renewed taphrogenesis in eastern Africa in Tertiary times.

Description: We have compiled both laboratory and worldwide field data on electrical conductivity to help understand the physical implications of deep crustal electrical profiles. Regional heat flow was used to assign temperatures to each layer in regional electrical conductivity models; we avoided those data where purely conductive heat flow suggested temperatures more than about 1000°C, substantially higher than solidus temperatures and outside the range of validity of heat flow models. The resulting plots of log conductivity σ versus 1/T demonstrate that even low-conductivity layers (LCL) have conductivities several orders of magnitude higher than dry laboratory samples and that the data can be represented by straight line fits. In addition, technically active regions show systematically higher conductivities than do shield areas. Because volatiles are usually lost in laboratory measurements and their absence is a principal difference between laboratory and field conditions, these materials probably account for the relatively higher conductivities of rocks in situ in the crust; free water in amounts of 0.01–0.1% in fracture porosity could explain crustal conductivities. Other possibilities are graphite, hydrated minerals in rare instances, and sulfur in combination with other volatiles. As most of the temperatures are less than 700°C, partial melting seems likely only in regions of highest heat flow where the conductive temperature profiles are inappropriate. Another result is that at a given temperature, crustal high-conductivity layers (HCL) are more conductive by another order of magnitude and show more scatter than do LCL's. Because the differences between HCL's and LCL's are independent of temperature, we must invoke more than temperature increases as a cause for large conductivity increases; increased fluid concentration in situ seems a probable cause for enhanced conductivities in HCL's. From the point of view of these observations, it does not matter whether the fluids are in communication with the surface or trapped at lithostatic pressures.

Description: Before making a critical evaluation of the crude oil and natural gas prospects for the years to the end of the century, it is necessary to review the geology and structure of the three German hydrocarbon-producing provinces. Furthermore, past exploration, production and reserves should be discussed. The three hydrocarbon-producing provinces are: the NW German Basin, the Upper Rhine Graben and the Molasse Basin, which together make up about 41% of West German territory (Fig. 1). The NW German Basin contains a sedimentary sequence over 8,000 m thick ranging in age from Permian to Quaternary. Gas and oil, the two natural hydrocarbons, are generally confined to separate lower and higher stratigraphic levels respectively (Fig. 2). The NW German Basin is the most important prospective area in West Germany. It extends into the North Sea. The tectonic rift feature of the Upper Rhine Graben originated in the Eocene. The Tertiary fill is over 4,000 m thick. Oil is found mainly in Mesozoic, Eocene and Oligocene rocks; the Miocene and Pliocene reservoir rocks contain natural gas almost exclusively (Fig. 3). The Molasse Basin is part of the foredeep north of the Alpine and Carpathian mountain ranges. The basin is filled with Upper Eocene to Pliocene and Quaternary sediments which, near the Alpine nappes, reach a thickness of over 5,000m (Fig. 4). During this century there were peaks in annual oil-production in 1910, 1940 and 1968 (see Fig. 5). The 1910 peak was the result of drilling activity in the Wietze oilfield. During the period 1934–1945, government financial aid was made available for drilling exploration wells. The success of this collaboration is demonstrated by the oil output in 1940 of 1 × 106 t. After World War II, many different types of oil-bearing structure were found, particularly by reflection seismic techniques in conjunction with detailed stratigraphical and palaeogeographical investigations. The success achieved can be seen by the peak of 8 × 106 t oil production for 1968 (Fig. 5) and in the growth of oil reserves (Fig. 7). Intensive exploration also enabled many new gasfields to be developed, especially in the deeper horizons of the NW German Basin. In 1971, estimated gas reserves reached 360 × 109 m3 (Fig. 11), and annual gas production in 1979 was 20.7 × 109 m3 (731 Bcf) (Fig. 9). There is, no doubt, still scope for the discovery and exploitation of oil and gas in Germany, especially in the NW German Basin where the best prospects for the future lie. This is borne out by two recent offshore oil discoveries and also by the successful application of enhanced recovery methods in the oilfields. The chances of finding more gas at the lower stratigraphic levels are promising now that gas has been discovered in the deeper parts of the Permian basin. The results of massive-hydraulic-fracturing tests in low-permeability pay-horizons are also encouraging. The deeper parts of oil- and gas-producing basins contain interesting prospects and have yet to be tested by ultra-deep wells. Provided that the economic climate remains favourable, there should be no difficulty in finding and supplying German oil and gas in the future. Geologically and technically possible reserves should be converted into proven and/or probable reserves. German crude oil will be available for several years beyond the year 2000, and German natural gas for a far longer time. A production rate of 19 to 20 × 109 m3 of gas per annum is feasible over the next twenty years, and oil production will probably not sink below 3 × 106 t/a in this period.

Description: The basement morphology and sediment thickness of the Hess Rise, an oceanic plateau in the central North Pacific, have been mapped on the basis of seismic reflection profiles. The acoustic stratigraphy on and around the rise is correlated with the lithostratigraphy at Deep Sea Drilling Project sites 464, 310, 465, and 466. A total sediment isopach chart of the rise reveals small-scale departures from the expected sedimentary pattern (thick sediment in shallow areas; thin sediment in deep areas). Sediment-filled basement depressions result from mass transport; thin sediment (〈50 m) occurs on steep scarps, basement ridges, and areas affected by bottom currents. A pre-Senonian sediment isopach chart shows a thickening from less than 50 m to more than 250 m of sediment from the northeast to the southwest. This trend seems explainable only in terms of the time-transgressive nature of seafloor formed at a mid-ocean ridge. The axial trend of the rise (N30°W) parallels nearby Mesozoic magnetic lineations and seems to be isochronous as deduced from the Deep Sea Drilling Project data. The Hess Rise began developing in late Aptian time along a segment of the Pacific-Farallon Ridge. Important events in the history of the rise are late-stage volcanism on the southern margin of the rise along the Mendocino Fracture Zone, tectonism and volcanism about 85 Ma that resulted in a major regional unconformity (reflector C), and another period of tectonism and volcanism between 65 and 43 Ma that coincided with the formation of the Emperor Seamounts and created structural benches on the western side of the rise. A significant change in the paleoenvironment that apparently occurred around the Paleogene-Neogene boundary (∼25–20 Ma) caused pronounced changes in the depositional environment and resulted in another major regional unconformity (reflector A).

Description: The distribution of 234Th, 230Th, and 228Th between dissolved and particulate forms was determined in 17 seawater samples from the Guatemala and Panama basins. Sampling was carried out in situ with battery-powered, submersible pumping systems in which the seawater first passed through a Nuclepore filter (1.0-μm pore size) and then through a cartridge packed with Nitex netting that was impregnated with MnO2 to scavenge the dissolved Th isotopes. Natural 234Th was used as the tracer for monitoring the efficiency of scavenging. For all three isotopes, most of the activity was found in the dissolved form. On the average 4% of the 234Th, 15% of the 228Th, and 17% of the 230Th occurred in the particulate form, though the percentages were found to be strongly dependent on particle concentration. These distributions are not consistent with chemical scavenging models that assume irreversible uptake of Th on particle surfaces. The results can be explained, however, if continuous exchange of Th isotopes between seawater and the particle surfaces is assumed. Vertical profiles of both particulate and dissolved 230Th show increasing concentrations with depth, as required by the assumption of reversible exchange. Some of the dissolved 230Th profiles, however, show a reversal of this trend near the bottom, indicating accelerated scavenging near the water/sediment interface. Kinetics of both adsorption and desorption can be examined if at least two Th isotopes are measured in the same samples. Results show that reaction times are short (a few months) compared to the residence time of suspended matter in the deep ocean (several years), indicating that particles suspended in the deep sea are close to equilibrium with respect to exchange of metals at their surfaces.

Description: The existence of a southward‐flowing current beneath the northern part of the seasonally reversing Somali Current is documented in a 2½‐year‐long time series of currents obtained at moored stations near 5°N about 30 km off the Somali coast. Its mean annual transport in the layer 150–600 m amounts to about 5×106 m3/s. The undercurrent has a pronounced seasonal cycle in phase with the near surface flow, suggesting a close coupling to the monsoonal wind forcing. With the spin‐up of the deepreaching northern Somali gyre after the onset of the southwest monsoon, the undercurrent is temporarily destroyed in the northern Somali Basin during June/July but is re‐established in August. The undercurrent does not reach 3°N but turns offshore north of that latitude.

Description: The titanium to aluminum ratio in core V19–29 is correlated with aluminosilicate accumulation rates. This correlation may be due to Pleistocene eolian transport fluctuations which alter the mean grain size of sedimented eolian material. The relation between aluminum accumulation rate and Ti/Al, established from accumulation rates integrated over 11,000–50,000 year intervals, can be inverted to compute a high‐resolution record of aluminosilicate and calcium carbonate accumulation rates over the past 130,000 years. Carbonate accumulation rates are closely related to the oxygen isotope record in the core, with a phase lag and damping constant that is compatible with the response time (shown to be only 6000 years) of calcium carbonate in the ocean. Carbonate sedimentation at this site responds to several processes independently correlated with climatic change. The relative importance of these processes for carbonate sedimentation at this site can be constrained by the record in this core and other lines of evidence: 15% of the increased carbonate deposition at this site during glacial periods may be due to diminished NADW (North Atlantic deep water) formation; 10% is due to carbonate productivity decreases in the North Atlantic; 25% may be due to a diminished shallow‐sea carbonate sink; and the residual 50% must be due to a local productivity increase. These assignments are consistent with observations on carbonate paleoceanography in the North Atlantic. Aluminosilicate accumulation rate variations correlate with the record of eolian quartz deposition near northwest Africa and, in a general way, with the climatic record. But in detail the record differs substantially from the oxygen isotope record and may provide independent evidence on the nature of climate dynamics.

Description: The eastern boundary of the Caroline plate, in the western equatorial Pacific, is composed of three structural provinces distinguished primarily on the basis of morphology. Each province shows evidence for convergence between the Caroline and Pacific plates though the structural style varies considerably between each province. Most notably, the sense of underthrusting appears to change along the boundary at about 3°N. To the south, at the Mussau System, Caroline lithosphere underthrusts beneath the Mussau Ridge (which is part of the Pacific plate), while to the north the Caroline plate appears to overthrust the Pacific plate. Recently collected seismic reflection profiles across each province documents the structural changes along and across strike of the Caroline-Pacific plate boundary. With this information, we estimate that a minimum of approximately 4 km of crustal shortening has occurred at about 5°N due to convergence of the two plates. Further to the south (about 2°N), simple gravity models suggest that about 10 km of Caroline lithosphere lies beneath the present-day Pacific plate. Using a previously determined pole of rotation describing Caroline-Pacific relative motion (Weissel and Anderson, 1978), we grossly estimate the duration of the convergence between these two plates at about one million years. It is suggested that variation in the convergence rate along the plate boundary provides the primary control on the variation of structural deformation observed between provinces; however, favorable thermal conditions are factors that are considered. If the eastern boundary of the Caroline plate is a region of incipient though perhaps transient subduction, as we postulate, then the geophysical and geological evidence presented can constrain models on the initiation of subduction.

Description: Strain accumulation and release at a subduction zone are attributed to stick slip on the main thrust zone and steady aseismic slip on the remainder of the plate interface. This process can be described as a superposition of steady state subduction and a repetitive cycle of slip on the main thrust zone, consisting of steady normal slip at the plate convergence rate plus occasional thrust events that recover the accumulated normal slip. Because steady state subduction does not contribute to the deformation at the free surface, deformation observed there is completely equivalent to that produced by the slip cycle alone. The response to that slip is simply the response of a particular earth model to embedded dislocations. For a purely elastic earth model, the deformation cycle consists of a coseismic offset followed by a linear‐in‐time recovery to the initial value during the interval between earthquakes. For an elastic‐viscoelastic earth model (elastic lithosphere over a viscoelastic asthenosphere), the postearthquake recovery is not linear in time. Records of local uplift as a function of time indicate that the long‐term postseismic recovery is approximately linear, suggesting that elastic earth models are adequate to describe the deformation cycle. However, the deformation predicted for a simple elastic half‐space earth model does not reproduce the deformation observed along the subduction zones in Japan at all well if stick slip is restricted to the main thrust zone. As recognized earlier by Shimazaki, Seno, and Kato, the uplift profiles could be explained if stick slip were postulated to extend along the plate interface beyond the main thrust zone to a depth of perhaps 100 km, but independent evidence suggests that stick slip at such depths is unlikely.