ISSN:
1573-4889
Keywords:
oxidation
;
cyclic
;
spalling
;
stress
Source:
Springer Online Journal Archives 1860-2000
Topics:
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
Notes:
Abstract The effect of thermal shock on the spalling of oxides from the surfaces of several commercial alloys was determined. The average cooling rate was varied from approximately 240°C/sec to less than 1.0°C/sec during cyclic oxidation tests in air. The tests consisted of 100 cycles of 1 hr at the maximimum temperature (1100 or 1200°C). The alloys were HOS-875, TD-Ni, TD-NiCrAl, In-601, In-702, and B-1900 plus Hf. All of these alloys exhibited partial spalling within the oxide rather than total oxide loss down to bare metal. Thermal shock resulted in deformation of the metal, which in turn resulted, in most cases, in change of the oxide failure mode from compressive to tensile. Tensile failures were characterized by cracking of the oxide and little loss, while compressive failures were characterized by explosive loss of platelets of oxide. This behavior was confirmed by examination of mechanically stressed oxide scales. The thermally shocked oxides spalled less than the slow-cooled samples with the exception of TD-NiCrAl. This material failed in a brittle manner rather than by plastic deformation. The HOS-875 and the TD-Ni did not spall during either type of cooling. Thus, the effect of thermal shock on spalling is determined, in large part, by the mechanical properties of the metal.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00603788
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