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  • Chemistry  (6,605)
  • LUNAR AND PLANETARY EXPLORATION  (815)
  • 1975-1979  (7,420)
  • 1945-1949
  • 1979  (7,420)
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Years
  • 1975-1979  (7,420)
  • 1945-1949
Year
  • 1
    Publication Date: 1979-12-14
    Description: The structure and absolute stereoconfigurations of four adenosine adducts with (+/-)-7 alpha,8 beta-dihydroxy-9 beta, 10 beta-epoxy-7,8,9,10-tetrahydrobenzo(a)pyrene (BPDE) and their deoxyadenosine analogs have been determined. They result from both cis and trans addition of the N6 amino group of ademine to the 10 position of both enantiomers of BDPE. This was determined from studies of the nuclear magnetic resonance spectra, mass spectra, and circular dichroism spectra, as well as from their pKa values and chemical reactivities.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Jeffrey, A M -- Grzeskowiak, K -- Weinstein, I B -- Nakanishi, K -- Roller, P -- Harvey, R G -- New York, N.Y. -- Science. 1979 Dec 14;206(4424):1309-11.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/316186" target="_blank"〉PubMed〈/a〉
    Keywords: *Benzopyrenes ; Chemical Phenomena ; Chemistry ; Circular Dichroism ; Dna ; *Deoxyadenosines/analogs & derivatives ; Magnetic Resonance Spectroscopy ; Mass Spectrometry ; Molecular Conformation ; Mutation ; Stereoisomerism
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 2
    Publication Date: 1979-06-08
    Description: It has been proposed that nitrilotriacetic acid be substituted for trisodium polyphosphates in detergents as a way to reduce the rate of eutrophication in the Great Lake Basin. The reaction of nitrilotriacetic acid with chlorine-containing solutions produces a hitherto unknown degradation production, N-formyliminodiacetic acid, in high yield. The toxicological and environmental implications of this reaction are unclear.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Spanggord, R J -- Tyson, C A -- New York, N.Y. -- Science. 1979 Jun 8;204(4397):1081-2.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/36659" target="_blank"〉PubMed〈/a〉
    Keywords: *Acetates ; Chemical Phenomena ; Chemistry ; *Chlorine ; Dicarboxylic Acids ; Environmental Pollutants ; Hydrogen-Ion Concentration ; *Imino Acids ; Mutagens ; *Nitrilotriacetic Acid
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 3
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    American Association for the Advancement of Science (AAAS)
    Publication Date: 1979-03-16
    Description: 〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Ferris, J P -- New York, N.Y. -- Science. 1979 Mar 16;203(4385):1135-7.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/218287" target="_blank"〉PubMed〈/a〉
    Keywords: Chemical Phenomena ; Chemistry ; *Hydrogen Cyanide ; *Peptides
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 4
    Publication Date: 2011-08-24
    Description: Two unique meteorites were identified by means of a mineralogical examination of the smaller-sized Yamato achondrites. Yamato-74130 is the most iron-rich ureilite with Na, Cr-rich augite instead of pigeonite. Yamato-74160 was extensively recrystallized, but the composition and proportion of olivine, orthopyroxene, augite, and plagioclase is consistent with LL7 chondrites. ALHA77005 is a unique achondrite with olivine, possibly three pyroxene assemblages, and maskelynite. These meteorites provide evidence that there may be other 'thermalized' asteroids than the howardite parent body. Detailed petrologic descriptions of the unique achondrites, recrystallized diogenite Yamato-74013, and the rapidly cooled eucrite Yamato-74450 with pyroxene phenocrysts are given. It is inferred from the bulk chemistry and the mineralogical reexamination of Yamato-75028 that it is composed of the H5-type clasts and chondrule-rich H(L)3-like matrix with the H5 fragments. A close relationship in the collisional evolution of some asteroids with these materials is inferred.
    Keywords: LUNAR AND PLANETARY EXPLORATION
    Type: National Institute of Polar Research, Memoirs (ISSN 0386-0744); 15, 1; 54-76
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  • 5
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    In:  CASI
    Publication Date: 2006-06-26
    Description: The high closing speed of 57km/s between the spacecraft and Halley poses special problems in the design of the required meteoroid protection. A double wall structure with a total thickness equal to 0.1 to 1 times the diameter of the largest meteoroid encountered is sufficient to stop that meteoroid. However, the unusually high number of meteoroid impacts on the Halley probe will cause significant erosion of the outer wall so that failure of the second wall is more likely to occur from a small meteoroid passing through a previously created hole in the outer wall and then penetrating the second wall. Calculations of the shielding required based on this failure mode, show that a double wall structure must actually have a total thickness 1.2 to 7.3 times the diameter of the largest meteoroid encountered, depending on the size distribution of the meteoroids.
    Keywords: LUNAR AND PLANETARY EXPLORATION
    Type: ESA Comet Halley Micrometeoroid Hazard Workshop; p 73-76
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  • 6
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    In:  CASI
    Publication Date: 2006-01-16
    Description: Design principles of spaced, multiwall meteoroid protection are investigated in the light of experimental data generated during the Apollo Program. The outer wall or shield is shown to be the most important element in the meteoroid-spacecraft interaction. The condition of the debris is primarily a function of the shock pressure, the melting points of the meteoroid and the shield, and the length of the meteoroid and thickness of the shield. Spacing between the walls is effective up to approximately 100 times the length of the meteoroid. The required thickness of the second wall is shown to be proportional to the meteoroid mass, velocity, and density, and to the spacing between the walls, taken with exponents dependent upon the condition of the debris. The effects of placing additional elements (insulation or honeycomb cells) between the two walls are discussed, and the efficiency of various protective configurations is presented. An analysis of the meteoroid protection proposed for the Comet Halley probe is included as an appendix.
    Keywords: LUNAR AND PLANETARY EXPLORATION
    Type: ESA Comet Halley Micrometeoroid Hazard Workshop; p 85-92
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  • 7
    Publication Date: 2006-01-12
    Description: The beneficiation of lunar plagioclase and ilmenite ores to feedstock grade permits a rapid growth of the space manufacturing economy by maximizing the production rate of metals and oxygen. A beneficiation scheme based on electrostatic and magnetic separation is preferred over conventional schemes, but such a scheme cannot be completely modeled because beneficiation processes are empirical and because some properties of lunar minerals have not been measured. To meet anticipated shipping and processing needs, the peak lunar mining rate will exceed 1000 tons/hr by the fifth year of operation. Such capabilities will be best obtained by automated mining vehicles and conveyor systems rather than trucks. It may be possible to extract about 40 kg of volatiles (60 percent H2O) by thermally processing the less than 20 micron ilmenite concentrate extracted from 130 tons of ilmenite ore. A thermodynamic analysis of an extraction process is presented.
    Keywords: LUNAR AND PLANETARY EXPLORATION
    Type: Space Resources and Space Settlements; p 275-288
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  • 8
    Publication Date: 2006-01-12
    Description: Although bulk lunar soil is not a suitable feedstock for extracting metals, certain minerals such as anorthite and ilmenite can be separated and concentrated. These minerals can be considered as potential ores of aluminum, silicon, titanium, andiron. A separation and metal extraction plant could also extract large amounts of oxygen and perhaps hydrogen from these minerals. Anorthie containing 19 percent aluminum and 20 percent silicon can be concentrated from some highland soils where it is present in amounts up to 60 percent. Ilmenite containing 32 percent titanium and 37 percent iron can be concentrated from some mare soils where it is present in amounts up to 10 percent. The ideal mining site would be located at the boundary between a high-titanium mare and a high-aluminum highlands. Such area may exist around the rims of some eastern maria, particularly Tranquilitatis. A location on Earth with raw materials as described above would be considered an economically valuable ore deposit if conventional terrestrial resources were not available.
    Keywords: LUNAR AND PLANETARY EXPLORATION
    Type: NASA. Ames Res. Center Space Resources and Space Settlements; p 243-255
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  • 9
    Publication Date: 2011-08-17
    Description: Surface sampler activities on Mars during the Viking extended mission are considered, including excavation of deep trenches, construction of conical piles of materials, backhoe touchdown experiments, and acquisition of contiguous pictures of the surface beneath number 2 terminal descent engines using mirrors. Results of the Physical Properties Investigation that are relevant to aeolian processes are also discussed. Both pictures and surface sampler data indicate that the surface materials in the sample fields of the Viking landers may be grouped, in order of increasing strength, into drift material, crusty to cloddy material, blocky material and rocks.
    Keywords: LUNAR AND PLANETARY EXPLORATION
    Type: Journal of Geophysical Research; 84; Dec. 30
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  • 10
    Publication Date: 2011-08-17
    Description: The Western Desert of Egypt is one of the most arid regions on earth and is probably the closest terrestrial analog to the surface of Mars. An expedition to the area in 1978 revealed an abundance of quartzite and basalt rocks that have been pitted and fluted by wind erosion and deflation of the desert surface. These pitted rocks are internally homogeneous, show no internal holes or vesicles, and are considered an important but neglected type of ventifact. They bear a striking resemblance to the pitted and fluted rocks seen by the Viking Landers, rocks that have generally been interpreted as vesicular basalts only slightly modified by wind erosion. Wind tunnel studies of the air flow over and around nonstreamlined hand specimens from the Western Desert show that windward abrasion coupled with negative flow, secondary flow, and vorticity in a unidirectional wind can explain the complex arrays of pits and flutes. These field and laboratory observations suggest that the pitted rocks at the Viking Lander sites are also ventifacts, and thus the Martian surface may be far more wind eroded than previously thought.
    Keywords: LUNAR AND PLANETARY EXPLORATION
    Type: Journal of Geophysical Research; 84; Dec. 30
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