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  • Articles  (4)
  • Nitrous oxide  (4)
  • 1975-1979  (4)
  • 1978  (4)
  • Geosciences  (4)
  • Energy, Environment Protection, Nuclear Power Engineering
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  • Articles  (4)
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  • 1975-1979  (4)
Year
  • 1978  (4)
Topic
  • Geosciences  (4)
  • Energy, Environment Protection, Nuclear Power Engineering
  • Physics  (4)
  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Pure and applied geophysics 116 (1978), S. 414-422 
    ISSN: 1420-9136
    Keywords: Biogenic sink ; Denitrification ; Nitrous oxide
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract Considering only net free energy change for the dissimilatory reduction of nitrate ion, the most efficient reaction with limited organic substrate is that resulting in the production of N2. Under conditions of abundant organic substrate and limited electron acceptor the reduction of nitrate to the level of ammonium would be more efficient. Thus the appearance of N2O in denitrification must reflect a metabolic accident or some reaction barrier (e.g., the activation energy of some intermediate) which prevents the full utilization of this energy. Laboratory studies with microaerophylic systems indicate that under these reducing conditions both nitrate ion and N2O can be reduced to the level of ammonium. The quantitative significance of these processes under natural conditions has not been evaluated but they may provide a significant sink for atmospheric N2O.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Pure and applied geophysics 116 (1978), S. 439-451 
    ISSN: 1420-9136
    Keywords: Carbon monoxide ; Nitrous oxide ; Plants ; Radiation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract It is shown by laboratory experiments and extensivein-situ measurements that higher plants (Vicia faba, Platanus acerifolia, Fagus silvatica, andPinus silvestris) produce carbon monoxide. The measurements were carried out under natural conditions with respect to the concentrations of O2 and H2O, and temperature. The CO2- and CO-mixing ratios were varied in the ranges 350 to 530 ppm and 3–270 ppb, respectively. The CO-production rates were found to be light dependent with an average value per cm2 of leaf area of 3×10−13 g/sec for a radiation intensity of 5×104 erg/cm2 sec. The production rates are independent of the CO2- and CO-mixing ratios employed in the test atmosphere. Considering the production rate of 3×10−13 g/cm2 sec to be representative for global conditions the total CO-production by plants is estimated to be 0.5–1.0×1014 g/year. In contrast to carbon monoxide atmospheric dinitrogen oxide is not influenced by plants in the same manner.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Pure and applied geophysics 116 (1978), S. 405-413 
    ISSN: 1420-9136
    Keywords: Continuous observation ; Global data ; Lifetime ; Nitrous oxide
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract Real-time N2O measurements have been madein situ at the South Pole, Antarctica, north and south of the equator from on board the Alpha Helix and over the Pacific Ocean on several aircraft flights from the U.S. to New Zealand, Australia and 90°S. In addition, an automated EC-GC has been operated for the past year intermittently monitoring N2O in surface air at a rural site in the wheatlands of eastern Washington state. The data obtained are consistent and in agreement with the data obtained from the analyses of a large number of samples collected both from ground stations and a variety of aircraft flights made in the southern and northern hemisphere. The observed global data show no interhemispheric differences. The present concentration of N2O in the troposphere is measured to be 330±3 ppbv. Its vertical distribution in the troposphere is very uniform. A small decrease (2–3 percent) across the tropopause is characteristically observed in the high altitude Learjet flights.
    Type of Medium: Electronic Resource
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  • 4
    ISSN: 1420-9136
    Keywords: Nitrous oxide ; Sources and sinks ; Waste nitrogen
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The N2O content of waters in the Potomac and Merrimack Rivers was measured on a number of occasions over the period April to July 1977. The concentrations of dissolved N2O exceed those which would apply in equilibrium with air by factors ranging from about 46 in the Potomac to 1.2 in the Merrimack. Highest concentrations of dissolved N2O were associated with sewage discharges from the vicinity of Washington, D.C. and analysis indicates a relatively high yield, 1.3 to 11 percent, for prompt conversion of waste nitrogen to N2O. The yield could be even higher if bubbles originating in sediments should contain as little as 0.3 percent N2O. Measurements of dissolved N2O in fresh water ponds near Boston demonstrate that aquatic systems may provide both strong sources and sinks for atmospheric N2O.
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