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  • Physical Chemistry  (105)
  • Wiley-Blackwell  (105)
  • National Academy of Sciences
  • Oxford University Press
  • 1975-1979  (105)
  • 1978  (105)
Collection
Keywords
Publisher
  • Wiley-Blackwell  (105)
  • National Academy of Sciences
  • Oxford University Press
Years
  • 1975-1979  (105)
Year
  • 1
    Electronic Resource
    Electronic Resource
    Masthead (1978)
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 10 (1978) 
    Details
    ISSN: 0538-8066
    Keywords: Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/kin.550100101
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  • 2
    Electronic Resource
    Electronic Resource
    The reaction of S(3P) atoms with nitric oxide (1978)
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 10 (1978), S. 31-39 
    Details
    ISSN: 0538-8066
    Keywords: Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The flash photolysis-vacuum ultraviolet kinetic absorption spectroscopy technique has been used to measure the absolute rate constant for the reaction of ground state S(3P) atoms withnitric oxide,\documentclass{article}\pagestyle{empty}\begin{document}${\rm S}\left({^{\rm 3} P} \right) + {\rm NO}\mathop {\longrightarrow}\limits^{\rm M} {\rm SNO}\left({{\rm M} = {\rm CO}_2} \right)$\end{document} as a function of nitric oxide concentration and total pressure. The rateconstant was determined to be 1.9±0.1 × 1011 12/mol2.sec at 298°K, with a high-pressure limit of 9.3 ± 2.1×109 l/mol·sec-1. The observed kinetics are consistent with a termolecular energy transfer mechanism.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/kin.550100104
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  • 3
    Electronic Resource
    Electronic Resource
    Kinetics of the gas-phase reaction between iodine and trifluorosilane and the bond dissociation energy D(F3Si—H) (1978)
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 10 (1978), S. 101-110 
    Details
    ISSN: 0538-8066
    Keywords: Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The title reaction has been investigated in the temperature range 667-715K. The only reaction products were trifluorosilyl iodide and hydrogen iodide. The rate law \documentclass{article}\pagestyle{empty}\begin{document}$$ - \frac{{d\left[{{\rm I}_2} \right]}}{{dt}} = \frac{{k\left[{{\rm I}_2} \right]^{1/2} \left[{{\rm F}_3 {\rm SiH}} \right]}}{{1 + k\prime \left[{{\rm HI}} \right]/\left[{{\rm I}_2} \right]}} $$\end{document} was obeyed over a wide range of iodine and trifluorosilane pressures. This expression is consistent with an iodine atom abstraction mechanism and for the step \documentclass{article}\pagestyle{empty}\begin{document}$$ {\rm I}^ \cdot + {\rm F}_3 {\rm SiH}\mathop {\longrightarrow}\limits^1 {\rm F}_3 {\rm Si}^\cdot + {\rm HI} $$\end{document} log k1(dm3/mol·sec) = (11.54 ± 0.17) - (130.5 ± 2.2 kJ/mol)/RT In 10 has been deduced. From this the bond dissociation energy D(F3Si—H) = (419 ± 5) kJ/mol (100.1 kcal/mol) is obtained. The kinetic andthermochemical implications of this value are discussed.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/kin.550100108
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  • 4
    Electronic Resource
    Electronic Resource
    Flash photolysis study of the NO-catalyzed recombination of bromine atoms (1978)
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 10 (1978), S. 155-169 
    Details
    ISSN: 0538-8066
    Keywords: Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The recombination of bromine atoms at room temperature has been studied by flash photolysis in the range of 1-100 atm of the inert diluent He, leading to a value for the third-order rate constant of (1.5 ± 0.2) × 1015 cm6/mol2.sec. In the presence of NO the recombination is considerably accelerated. The falloff curve of the recombination Br + NO (+He) → BrNO (+He) was also measured resulting in a value for the limiting low-pressure rate constant of (3.4 ± 1.3) × 1015 cm6/mol2.sec. In experiments with excess NO, rate constants of (2.2 ± 1) × 1014 cm3/mol·sec for the reaction Br + BrNO → Br2 + NO, and (6.1 ± 0.4) × 109 cm6/mol2.sec for the reaction Br2 + 2NO → 2BrNO were obtained.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/kin.550100203
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  • 5
    Electronic Resource
    Electronic Resource
    Masthead (1978)
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 10 (1978) 
    Details
    ISSN: 0538-8066
    Keywords: Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/kin.550100301
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  • 6
    Electronic Resource
    Electronic Resource
    Diffusion of hydrogen atoms in spherical vessels (1978)
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 10 (1978), S. 233-248 
    Details
    ISSN: 0538-8066
    Keywords: Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A previously developed model for active species concentration profiles in infinite cylindrical systems has been extended to include the spherical system. The model couples the processes of diffusion to and reaction at the wall. Predictions of time buildup under conditions of homogeneous production by light, and time decay after extinguishing the light source, are made for H atoms. Such predictions require a knowledge of the wall recombination coefficient and the binary diffusion coefficient for H in heat bath gas. The model is experimentally tested by measuring the first-order decay constants of H at room temperature in various pressures (10-1500 torr) of six heat bath gases. The atomic concentration is monitored by Lyman-α absorption photometry. The results show good agreement with model predictions in the various heat bath gases up to ∼400 torr and depend only on one parameter,γ, the recombi-nation coefficient. This should be contrasted with the earlier work where slight variation in γ was invoked. The rate constants at pressures higher than 400 torr are consistently higher than model predictions.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/kin.550100303
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  • 7
    Electronic Resource
    Electronic Resource
    Masthead (1978)
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 10 (1978) 
    Details
    ISSN: 0538-8066
    Keywords: Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/kin.550100401
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  • 8
    Electronic Resource
    Electronic Resource
    Kinetics of fluorine atom reactions using resonance absorption spectrometry in the far vacuum ultraviolet reactions F + HCl, CH4, CHCl3 CHCl2F, and CHClF2 (1978)
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 10 (1978), S. 367-387 
    Details
    ISSN: 0538-8066
    Keywords: Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Atomic resonance absorption spectrometry with a nonreversed fluorine resonance lamp (∼95 nm) has been used to study the kinetics of elementary reactions of ground state F2PJ atoms in a discharge-flow system. The following rate constants (in cm3/molec·sec)All rate constants are given with 1.5 σ. were determined at 298° K: The reaction F 2PJ + HCl(1) was found to give J-excited Cl 2P1/2 atoms with a product branching ratio [Cl 2P1/2]/[Cl 2P3/2] = 0.10.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/kin.550100404
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  • 9
    Electronic Resource
    Electronic Resource
    Masthead (1978)
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 10 (1978) 
    Details
    ISSN: 0538-8066
    Keywords: Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/kin.550100201
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  • 10
    Electronic Resource
    Electronic Resource
    Calculation of the average energy and the energy distribution function of chemically activated species (1978)
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 10 (1978), S. 171-183 
    Details
    ISSN: 0538-8066
    Keywords: Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Equations for the average energy of chemically activated species are developed, and uncertainties in the various energy quantities involved are discussed. Various approaches to the energy distribution function of chemically activated species are discussed. Trial calculations on methylcyclobutane are presented.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/kin.550100204
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