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  • Chromatographie, Dünnschicht  (20)
  • 42.55  (16)
  • Neurosecretion
  • Springer  (41)
  • American Geophysical Union
  • Irkutsk : Ross. Akad. Nauk, Sibirskoe Otd., Inst. Zemnoj Kory
  • Krefeld : Geologischer Dienst Nordhein-Westfalen
  • Wiley
  • 2015-2019
  • 2005-2009
  • 1975-1979  (41)
  • 1970-1974
  • 1977  (41)
Collection
Keywords
Publisher
  • Springer  (41)
  • American Geophysical Union
  • Irkutsk : Ross. Akad. Nauk, Sibirskoe Otd., Inst. Zemnoj Kory
  • Krefeld : Geologischer Dienst Nordhein-Westfalen
  • Wiley
Years
  • 2015-2019
  • 2005-2009
  • 1975-1979  (41)
  • 1970-1974
Year
  • 1
    ISSN: 1432-0630
    Keywords: 42.55
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract Lasing in atomic lines of noble gases and fluorine, prior to excimer radiation, was observed in an electric discharge ArF/XeF excimer laser. Some Ar/Xe lines end at metastable levels, which are very important for the formation of ArF/XeF excimer molecules. Five new lasing lines of atomic fluorine have been obtained. Consideration is given to the use of lasing in atomic and molecular lines, that occurs in one burst, in investigations of the excitation kinetics of excimer states under the conditions of a high-pressure electric discharge.
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  • 2
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    Applied physics 14 (1977), S. 277-282 
    ISSN: 1432-0630
    Keywords: 42.55 ; 52
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract The paper deals with the properties andI-V characteristics of discharges in narrow capillaries used, for example, for He−Ne waveguide lasers. It has been observed that discharges in He−Ne waveguide lasers are unstable because of the strongly falling characteristic. A theory is presented which assumes that at low currents wall charges restrict the positive column to a narrow plasma channel and are the main reason for the observed falling characteristic. A numerical evaluation for helium gives results which agree well with experimental data.
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  • 3
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    Applied physics 13 (1977), S. 97-99 
    ISSN: 1432-0630
    Keywords: 42.55 ; 82.50
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract First cw laser oscillation with thresholds below 1 mW was observed for various B1Пu → X1 ∑ g + transitions of diatomic molecular sodium excited by different argon laser lines in the range of 454–488 nm. For pump powers of 0.5 W output powers up to 3 mW and single-pass gain up to 0.1 cm−1 were obtained. Some properties of the heat pipe laser system are discussed.
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  • 4
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    Applied physics 13 (1977), S. 383-385 
    ISSN: 1432-0630
    Keywords: 42.55 ; 42.80
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract An optically pumped FIR laser was operated with a copper mesh Fabr-Perot output coupler. With this device a Gaussian output beam was obtained andthe degree of coupling could be varied continuously, thus allowing optimum coupling. From the measured properties of the wire mesches grains of two FIR laser lines are calculated and the saturation intensities estimated.
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  • 5
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    Applied physics 14 (1977), S. 25-28 
    ISSN: 1432-0630
    Keywords: 42.55 ; 42.80
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract A new device for magnetically displacing the output mirror of a laser resonator and synchronously tilting an etalon in order to obtain single-mode tuning of a dye laser over a tuning range of at least 10 GHz is described. Comparatively large displacements with good linearity of a coil mounted on a membrane and placed inside the strong magnetic field of a ring magnet are obtained for currents in the order of several hundred milliamperes. Together with etalon flats of appropriate thickness and reflection mounted in the resonator of the laser a versatile instrument for application in intra and extra cavity spectroscopy has been developed.
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  • 6
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    Applied physics 14 (1977), S. 393-398 
    ISSN: 1432-0630
    Keywords: 34 ; 42.55
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract A flowing afterglow method has been used to study a number of reactions of importance in KrF lasers using NF3 as the fluorine donor. Total rate constants are reported for Kr*(3 P 2)+NF3 and Kr++NF3. The thermal energy attachment coefficient has been measured for NF3 and the cross section for the electron excitation process Kr*(3 P 2) +e→Kr*(3 P 1)+e has been estimated. The relevance of these results to discharge pumped KrF lasers is discussed.
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  • 7
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    Applied physics 14 (1977), S. 193-197 
    ISSN: 1432-0630
    Keywords: 42.55 ; 52
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract Planar and cylindrical discharges for argon lasers are compared by plasmatheoretical calculations. The maximum laser output power available in the two arrangements is computed in dependence of various parameters neglecting saturation mechanisms. A transverse discharge arrangement confining the positive column by two parallel walls is described and experimental laser threshold values for the current and pressure are reported.
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  • 8
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    Applied physics 14 (1977), S. 255-268 
    ISSN: 1432-0630
    Keywords: 42.80 ; 42.55 ; 85.60
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract GaAs double heterostructure semiconductor injection lasers which now exhibit more than 25000 h cw room temperature lifetime are of great interest for future use as directly modulated transmitters for high bit-rate fiber optical communications. The effects limiting this application are modulation distortions, spectral width and additional spectral broadening in the case of modulation and spontaneous fluctuations of the output power. The dynamic and spectral behavior of injection lasers, the methods of high bit-rate modulation and the improvement of the high bit-rate modulation capability by coupling two lasers are discussed.
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  • 9
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    Applied physics 13 (1977), S. 109-110 
    ISSN: 1432-0630
    Keywords: 42.55
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract A simple technique is described that allows the generation of a short pulses (1 ns) from dye lasers pumped by a much longer (7 ns) N2-laser pulse. Dye-laser pulses, either with a narrow bandwidth or a short duration, can thus be obtained with the same N2-laser pump.
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  • 10
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    Applied physics 14 (1977), S. 121-122 
    ISSN: 1432-0630
    Keywords: 42.55
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract Frequency-tunable generation by means of F 2 + and F 2 − colour centers in a LiF crystal is reported. Colour centers were created by illuminating LiF crystals with electrons of 3 meV energy at the electron current density of 1 μA/cm2. The pumping source was a ruby laser with a peak power of 20 MW, a pulse duration of 20 ns, and a repetition rate of 1 Hz. The frequency tuning is obtained in the range of 0.88–1.25 μm. Discussed are the ways of pumping of colour centers and the possibility of lasing in the spectral region of 0.85 to 2 μm in the type of colour centers under investigation.
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  • 11
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    Applied physics 13 (1977), S. 107-108 
    ISSN: 1432-0630
    Keywords: 42.55
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    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract Intense laser oscillation has been observed from ArF molecules at 1933 Å. Excitation of the gas mixture NF3:Ar:He=1:55:630 at total pressures above 2.1 atm was produced by a transverse electric discharge. The range of fine tuning was from 1927 Å to 1936 Å. An output energy of 0.8 mJ was measured from a laser pulse 15 ns in duration.
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  • 12
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    Applied physics 13 (1977), S. 1-3 
    ISSN: 1432-0630
    Keywords: 42.55
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract Disappearance of NF3 and appearance of NF2 and N2F2 in an excimer laser is followed quantitatively with a mass spectrometer. A model for the kinetics is presented.
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  • 13
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    Applied physics 13 (1977), S. 55-58 
    ISSN: 1432-0630
    Keywords: 42.55 ; 78.60
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract NdxLa1−xP5O14 (0.25≦x≦1) single crystals, placed within a confocal optical resonator, were pumped with ruby laser fundamental and second-harmonic nanosecond pulses. In both cases laser oscillations at 1.05 μm exceeding in duration many times the pumping pulse were obtained.
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  • 14
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    Applied physics 14 (1977), S. 343-350 
    ISSN: 1432-0630
    Keywords: 33 ; 42.55
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract By means of nonlinear absorption spectroscopy data necessary for the interpretation of molecular spectra can be obtained in such spectral regions, where conventional spectroscopic methods yield only a quasi-continuous absorption curve. Using a Zeeman-tuned He−Ne laser at the wavelength of 3.39μm we have measured significant differences in the intensity and temperature behaviour for several ethane absorption lines, the analysis of which made possible a preliminary qualitative assignment of these lines.
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  • 15
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    Applied physics 14 (1977), S. 377-380 
    ISSN: 1432-0630
    Keywords: 42.55 ; 42.65
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract Due to spatial hole burning, standing-wave dye lasers require a large amount of selectivity inside the cavity for single-mode operation. The output power of these lasers is limited by losses caused by the frequency selecting elements. In a travelling-wave laser, on the other hand, spatial hole burning does not exist, thereby eliminating the need for high selectivity. A travelling-wave cw dye laser was realized by unidirectional operation of a ring laser, yielding single mode output powers of 1.2 W at 595 nm and of 55 mW in the UV-region with intracavity frequency doubling.
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  • 16
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    Applied physics 14 (1977), S. 199-203 
    ISSN: 1432-0630
    Keywords: 42.55 ; 82.50
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract Loss of gain in a dye medium as a result of decomposition by pump photons is considered in terms of disappearance of dye molecules and the appearance of a new, single chemical product having absorption in the fluorescence band. The cases of small signal gain and saturated gain are applied to a single pass through a transversely excited amplifier. Loss of output, defined as “quantum yield of laser deterioration”,Q L , is related to the true quantum yield of molecular destruction of the dye,Q M , and other known parameters. For the experimentally common, saturated gain condition, the smallestQ L can be isQ M , which requires a photochemically bleachable dye with high gain, preferably at high concentration, in a long cavity, operating at high injection and pumping fluxes. Reversing these conditions, the highest valueQ L can be, compared withQ M , is unrestricted.
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  • 17
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    Cell & tissue research 182 (1977), S. 557-564 
    ISSN: 1432-0878
    Keywords: Sinus gland ; Gammarus ; Neurosecretion ; Ultrastructure
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Medicine
    Notes: Summary The sinus gland of Gammarus oceanicus, like that of other crustaceans, is composed of three elements: neurosecretory axons, glial cells and stromal sheath. Five neurosecretory axon types are identified on the basis of granule diameter, shape, and electron density, and axon matrix density. Exocytosis appears to be the major release mechanism of neurosecretory material. The preterminal regions of neurosecretory axons contain axoplasmic reticulum and neurotubules. Their arrangement in the axon and relationship with one another suggest a transport function. Multilamellar bodies are found in the terminal regions of neurosecretory axons. They arise from mitochondria and may be involved in granulolysis.
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  • 18
    ISSN: 1432-0878
    Keywords: Neurosecretion ; Alcian blue ; Alcian yellow staining ; Ultrastructure ; Bulinus truncatus
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Medicine
    Notes: Summary The neurosecretory system of the freshwater snail Bulinus truncatus was investigated. With the Alcian blue-Alcian yellow (AB/AY) staining method at least 10 different types of neurosecretory cells (NSC) were distinguished in the ganglia of the central nervous system. The differences in staining properties of the NSC — with AB/AY the cells take on different shades of green and yellow — are borne out at the ultrastructural level: the NSC types contain different types of neurosecretory elementary granules. The neurosecretory system of B. truncatus is compared to that of Lymnaea stagnalis, the species which has received the most attention among the pulmonates. It appears from the comparison that the systems of both species show many similarities, although some differences are also apparent.
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  • 19
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    Cell & tissue research 176 (1977), S. 109-120 
    ISSN: 1432-0878
    Keywords: Achatina fulica ; Aplysia californica ; Neurosecretion ; Homology
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Medicine
    Notes: Summary The right parietal ganglion of the African snail Achatina fulica contains an identifiable cluster of 20–40 white cells with somatic diameters of 80–110 μ. Cobalt chloride injection into these cells revealed an axon projection in the right parietal nerve as well as apparent terminations in the capsule. The cells contain an abundance of electron dense granules 1000–2000 Å in diameter which are formed in the Golgi apparatus. The granules stain with Gomori's chrome hematoxylin and paraldehyde fuchsin methods. While most cluster cells showed no “spontaneous” electrical activity, there was a correlation for the active cells between rate of activity and intensity of cell whiteness. These and other data suggest that the cluster cells are neurosecretory. A claim of homology with the “rostral white cells”, R3–R13, in the parieto-visceral ganglion of Aplysia is based on a similarity of morphological and electrophysiological features, together with analogous locations in the respective ganglia. It is concluded that the right parietal ganglion of Achatina is homologous with the right half of the parieto-visceral ganglion of Aplysia.
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  • 20
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    Cell & tissue research 180 (1977), S. 253-261 
    ISSN: 1432-0878
    Keywords: Microtubules ; Neurohypophysis ; Neurosecretion ; Axoplasmic transport
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Medicine
    Notes: Summary The microtubules in the neurosecretory neurones of the posterior pituitary were studied using different electron microscopical techniques. Tannic acid staining indicated that the microtubules had a 13 protofilament substructure similar to that described for microtubules from other tissues and organisms; the dimensions of the microtubules were also similar to that previously reported. Albumen pretreatment clearly showed the microtubules running across axonal swellings, but not continuing across the nerve endings. The only organelles showing possible association with the microtubules were small vesicles and smooth endoplasmic reticulum, no association between hormone granules and microtubules could be seen.
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  • 21
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    Cell & tissue research 178 (1977), S. 129-141 
    ISSN: 1432-0878
    Keywords: Choroid plexus ; Vasopressin ; Neurosecretion ; Rat ; Electron microscopy
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Medicine
    Notes: Summary Light and electron microscopic examination of choroid plexuses from lateral ventricles of water-deprived and subcutaneously or intravenously vasopressin administered rats reveal morphologic changes typical for vasopressin responsive fluid transporting epithelia during hormonal stimulation. Ultrastructural changes noted in both dehydrated and vasopressin treated animals included: the frequent occurrence of choroidal “dark” cells, dilatation of the lateral and basal intercellular spaces, increased vacuolization of the apical cytoplasm, and a change in microvillar conformation from the normal clavate type to those with a filiform shape. On the basis of the ultrastructural changes observed it is proposed that the choroid plexus be regarded as a target tissue for vasopressin. These findings indicated that a vasopressinmediated transchoroidal cerebrospinal fluid absorption capability exists.
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  • 22
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    Fresenius' Zeitschrift für analytische Chemie 283 (1977), S. 32-32 
    ISSN: 1618-2650
    Keywords: Nachw. von LSD, Ergot-Alkaloiden ; Chromatographie, Dünnschicht
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
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  • 23
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    Fresenius' Zeitschrift für analytische Chemie 284 (1977), S. 47-48 
    ISSN: 1618-2650
    Keywords: Analyse von Ergotalkaloiden ; Chromatographie, Dünnschicht
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    Topics: Chemistry and Pharmacology
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  • 24
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    Fresenius' Zeitschrift für analytische Chemie 285 (1977), S. 48-48 
    ISSN: 1618-2650
    Keywords: Nachw., Best. von Dichlorvos in Biolog. Material ; Chromatographie, Dünnschicht
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    Topics: Chemistry and Pharmacology
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  • 25
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    Fresenius' Zeitschrift für analytische Chemie 285 (1977), S. 255-255 
    ISSN: 1618-2650
    Keywords: Trenn. von Thiazolylbenzothiazolen ; Chromatographie, Dünnschicht ; isomere
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    Topics: Chemistry and Pharmacology
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  • 26
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    Fresenius' Zeitschrift für analytische Chemie 286 (1977), S. 50-53 
    ISSN: 1618-2650
    Keywords: Trenn, von Seltenen Erden ; Chromatographie, Dünnschicht ; Verteilungsverfahren ; Tetrahydrofuran, Triphenylphosphinoxid, Paraldehyd, Di-iso-propyläther-Tetrahydrofuran
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Zusammenfassung Die Verteilungskonstanten von Selten-Erd-Nitraten im System Tributylphosphat-wäßrige Nitrat-Lösung werden berechnet. Dünnschicht-chromatographisch können mit Tributylphosphat in Isooctan als Laufmittel die Selten-Erd-Nitrate von La bis Gd vom Gd bis Lu getrennt werden. Eine Trennung von 13 Seltenen Erden auf einem Chromatogramm gelingt mit den Laufmitteln a) Tetrahydrofuran/Paraldehyd/Salpetersäure (20∶70∶10), b) dem Laufmittel Triphenylphosphinoxid (0,3 M in Paraldehyd) und konz. Salpetersäure im Verhältnis 90∶10, c) Di-iso-propyläther/Tetrahydrofuran/Salpetersäure (100 ∶ 60 ∶ 10). Der Trennmechanismus wird diskutiert.
    Notes: Abstract The distribution constants of the rare earth nitrates in the system tri-n-butylphosphate/aqueous nitrate solution are calculated. With thin-layer chromatography it is possible to separate the rare earth nitrates from La to Gd and from Gd to Lu in the solvent system tri-n-butylphosphate in i-octane. A separation of 13 rare earths in only one chromatogram is possible in the solvent systems a) tetrahydrofuran/paraldehyde/nitric acid (20∶70∶10), b) tri-phenylphosphinoxide (0.3 M in paraldehyde)/conc. nitric acid in the ratio 90∶10, c) di-iso-propylether/tetrahydrofuran/nitric acid (100∶60∶10). The mechanism of the separation is discussed.
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  • 27
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    Fresenius' Zeitschrift für analytische Chemie 285 (1977), S. 111-120 
    ISSN: 1618-2650
    Keywords: Chromatographie, Dünnschicht ; Steuergerät zur automatischen Registrierung
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Zusammenfassung Ein Gerät zur vollautomatischen Steuerung eines DC-Spektralphotometers wurde entwickelt. Zusätzlich zur automatischen Registrierung aller Spuren eines Dünnschicht-Chromatogramms werden Remissionsminima erkannt und ihre Remissionsgrade und Ortskoordinaten ausgedruckt. Eine zweite Betriebsart ermöglicht ein manuelles Abrastern und Ausmessen eines Fleckes an jeder beliebigen Stelle der DC-Platte. Ein Rechneranschluß zur Auswertung der Meßergebnisse ist vorhanden. An Hand von Beispielen wird gezeigt, daß Reproduzierbarkeits- und Konzentrationsfehler bei der automatischen Registrierung strichförmiger Flecke wesentlich kleiner sind als bei Handpositionierung kreisförmiger Flecke. Die Linearität verschiedener Analysenfunktionen wird über 2 Zehnerpotenzen der Strichbelegung untersucht. Dabei erweist sich die Kubelka-Munk-Funktion in bezug auf Linearität allen anderen untersuchten Funktionen überlegen. Eine Kosten-Nutzen-Rechnung zeigt, daß in einem Routinelabor durch Einsatz eines Auftragegerätes und eines Steuergerätes für die automatische Registrierung trotz höherer Investitionskosten die Gesamtkosten einer Analyse um 70% gesenkt werden können.
    Notes: Abstract An instrument has been constructed for the automatic control of a TLC spectrophotometer. In addition to the automatic scanning of all tracks of a thin-layer chromatogram the positions and values of diffuse reflectance minima are recognized and printed. A second mode allows the manual scanning and measurement of a spot at any position on the TLC plate. A digital output is provided for the evaluation of the results with a computer. The errors of reproducibility and of concentration are much smaller using the automatic scanning of bands than using the manual positioning of circular spots as the examples show. The linearity of several analytical functions is analysed within two decades of concentration. The Kubelka-Munk function was found to be superior in linearity to all other functions studied. Calculations of costs show, that the total costs of an analysis in a routine laboratory can be lowered to an extend of about 70% by the use of an application instrument and a controlling instrument for automatic scanning inspite of the higher costs of investments.
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  • 28
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    Fresenius' Zeitschrift für analytische Chemie 285 (1977), S. 270-270 
    ISSN: 1618-2650
    Keywords: Trenn. von Aryl-p-methoxybenzoylbenzofuranyl-thiosemicarbazonen, Contraceptiva ; Chromatographie, Dünnschicht
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
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  • 29
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    Fresenius' Zeitschrift für analytische Chemie 286 (1977), S. 95-99 
    ISSN: 1618-2650
    Keywords: Nachw. von Herbiciden ; Chromatographie, Dünnschicht ; Dansylierung
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Zusammenfassung Die Reaktion von Dansylchlorid mit verschiedenen Herbiciden und Derivaten, die Aminogruppen enthalten oder zu Anilinen hydrolysierbar sind, wird beschrieben. Auf der Dünnschichtplatte lassen sich die fluorescierenden Stoffe gut trennen und identifizieren, was anhand von schematischen Darstellungen der Dünnschicht-Chromatogramme gezeigt wird.
    Notes: Abstract The reaction of dansyl chloride with various herbicides and derivatives containing amino groups or hydrolyzable to anilines is described. On TLC plates the fluorescent substances can be readily separated and identified as shown by diagrammatic representation of the thin-layer chromatograms.
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  • 30
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    Fresenius' Zeitschrift für analytische Chemie 286 (1977), S. 247-247 
    ISSN: 1618-2650
    Keywords: Trenn. von Diolen ; Chromatographie, Dünnschicht
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    Topics: Chemistry and Pharmacology
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  • 31
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    Fresenius' Zeitschrift für analytische Chemie 286 (1977), S. 248-248 
    ISSN: 1618-2650
    Keywords: Trenn. von Ketoester-Kupplungsprodukten ; Chromatographie, Dünnschicht ; Aryldiazoniumchloride
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    Topics: Chemistry and Pharmacology
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  • 32
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    Fresenius' Zeitschrift für analytische Chemie 286 (1977), S. 249-249 
    ISSN: 1618-2650
    Keywords: Trenn. von Thiosemicarbaziden ; Chromatographie, Dünnschicht ; 4-phenyl-substituiert
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
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    Fresenius' Zeitschrift für analytische Chemie 286 (1977), S. 250-250 
    ISSN: 1618-2650
    Keywords: Trenn. von 5,5-Dimethylcyclohexan-2-arylhydrazon-1,2,3-trionen ; Chromatographie, Dünnschicht
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
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    Fresenius' Zeitschrift für analytische Chemie 286 (1977), S. 255-255 
    ISSN: 1618-2650
    Keywords: Trenn. von Kationen ; Chromatographie, Dünnschicht ; ÄDTA-imprägn. Platten
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
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    Fresenius' Zeitschrift für analytische Chemie 286 (1977), S. 254-254 
    ISSN: 1618-2650
    Keywords: Trenn. von Arylbenzimidazolyl-thiocarbamiden, Antithyroide Mittel ; Chromatographie, Dünnschicht
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
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    Fresenius' Zeitschrift für analytische Chemie 287 (1977), S. 264-270 
    ISSN: 1618-2650
    Keywords: Best. von Benzpyren in Schwebstaub ; Chromatographie, Dünnschicht ; Routinemethode
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Zusammenfassung Es wird ein Verfahren zur dünnschicht-chromatographischen Bestimmung von Benz(a)pyren im Schwebstaub beschrieben, bei dem nach Extraktion mit Cyclohexan im Ultraschallbad die Trennung eindimensional auf Celluloseacetat-Folien nacheinander mit den Laufmitteln 95%ig. Äthanol/Dichlormethan (8∶2) und Pyridin/Methanol/Wasser (3∶5∶2) durchgeführt wird. Die Auswertung erfolgt fluorimetrisch direkt auf der Platte. Das Verfahren, das eine sichere Abtrennung des Benz(a)pyrens von Benz(k)fluoranthen und Anthanthren erlaubt, ist für die Bestimmung von 0,4–20 ng Benz(a)pyren/m3 Luft bei 24stündiger Probenahme mit einem „High Volume Air Sampler“ geeignet. Eine Erweiterung des Arbeitsbereiches nach oben und unten ist möglich. Der Gesamtzeitbedarf für die Analyse von drei Filterproben beträgt rund 5 h, von denen etwa 3 h auf die chromatographische Entwicklung entfallen.
    Notes: Summary A method is described for the thin-layer chromatographic determination of benzo(a)pyrene in suspended particulate matter, including the ultrasonic extraction with cyclohexane and the separation on cellulose acetate thin-layer foils by subsequent development in one direction with 95% ethanol-dichloromethane (8∶2) and pyridine-methanol-water (3∶5∶2). The quantitative evaluation is carried out by fluorimetric scanning of the plate. The method permits a reliable separation of benzo(a)pyrene from benzo(k)fluoranthene and anthanthrene and is suited for the determination of 0.4–20 ng of benzo(a)pyrene/m3 of air, if sampling is done with a High Volume Air Sampler during 24 h. The total time necessary to analyze three filters is about 5 h, wherein the chromatographic development takes 3 h.
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    Fresenius' Zeitschrift für analytische Chemie 287 (1977), S. 312-313 
    ISSN: 1618-2650
    Keywords: Trenn. von Bixanthenen ; Chromatographie, Dünnschicht ; Mikrobestimmung
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
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    Fresenius' Zeitschrift für analytische Chemie 287 (1977), S. 319-319 
    ISSN: 1618-2650
    Keywords: Trenn. von Carbamyldimethylarylazopyrazolen ; Chromatographie, Dünnschicht
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
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    Fresenius' Zeitschrift für analytische Chemie 288 (1977), S. 28-31 
    ISSN: 1618-2650
    Keywords: Nachw. und Trenn, von Seltenen Erden in Erzen, Monazit, Techn. Produkten ; Chromatographie, Dünnschicht ; Di-isopropyläther/Tetrahydrofuran/HNO3
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Zusammenfassung In Monaziten, technischen Produkten und Reinelementen (Verbindungen) wurden die Seltenen Erden dünnschicht-chromatographisch mit dem Laufmittel Di-isopropyläther-Tetrahydrofuran-Salpetersäure (65%) (100∶70∶6) getrennt und nachgewiesen. Mengenverhältnisse von 400∶1 sind zu trennen und eindeutig zu identifizieren. Bei größeren Unterschieden in den Rf-Werten kann das Verhältnis bis zu 1000∶1 betragen. Die absolut nachweisbare Menge auf einem Chromatogramm beträgt 0,05–0,1 μg. Die Größe der Flecken ermöglicht eine halbquantitative Abschätzung der Gehalte. Die Analysendauer beträgt mit Aufschluß 2 h, ohne Aufschluß 70 min.
    Notes: Summary In monazites, technical products and pure elements, rare earth elements were separated and identified by thin-layer chromatography using a 100∶70∶6 mixture of diisopropyl ether, tetrahydrofuran and HNO3 (65%) as an eluent. It is possible to separate and characterize them in concentrations of 400∶1 unambiguously. If the Rf-values differ remarkably a ratio of 1000∶1 is acceptable. The amount absolutely detectable on a chromatogram is 0.05–0.1 μg. The area of the spots allows a semiquantitative estimation. The time required for one analyses is without decomposition 70 min and including decomposition 2 h.
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    Fresenius' Zeitschrift für analytische Chemie 288 (1977), S. 285-285 
    ISSN: 1618-2650
    Keywords: Trenn. von Aminothiazolyl-benzothiazolen ; Chromatographie, Dünnschicht
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
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    Fresenius' Zeitschrift für analytische Chemie 288 (1977), S. 288-288 
    ISSN: 1618-2650
    Keywords: Trenn. von Seltenen Erden aus Uran ; Chromatographie, Dünnschicht
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
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