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  • 1
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    Geozon Science Media
    Publikationsdatum: 2022-08-04
    Beschreibung: Im Zuge der geologisch-telmatologischen Untersuchung des geplanten Prüfgeländes der Mercedes-Benz AG in Papenburg sind zahlreiche Bohrungen in sehr dichtem Abstand in den Mooren südöstlich von Papenburg durchgeführt worden. Die dortigen Hochmoore (Wildes Moor, Kortemoor und Klostermoor) erwiesen sich als z. T. wurzelecht, z. T. vom Versumpfungsmoortyp mit Schwarztorf-Auflage auf Mudden, lokal auch auf Niedermoor- und Bruchwaldtorf. Eine enge Bindung der Vermoorung an Ortsteinhorizonte einer frühpostglazialen Podsolierung, welche sowohl über den Talsanden als auch den Älteren Flugsanden ausgebildet ist, ist festzustellen. Die Hochmoortorfbildung setzt üblicherweise erst in der zweiten Hälfte der Pollenzone VII, gleichzeitig mit der Neolithischen Revolution ein. Starke Beteilung von Eriophorum ist für die Schwarztorfe typisch. Die der Leda und Ems tributären Nebenflüsse zeigen eine spätglazial-frühpostglaziale, auf den spätweichselzeitlichen tiefen Meeresspiegel bezogene Einschneidungsphase in die weichselzeitliche Talsandebene. Mit dem postglazialen Meeresspiegelanstieg schritt die Akkumulation - auf die ansteigende Vorflut eingespielt - von den Flußunterläufen aufwärts fort. Junge Dünenzüge begleiten die für die Siedlungsgeschichte wichtigen Talsandterrassenränder, hinter denen das Sphagnentorfwachstum bis in die Weißtorffazies fortschritt.
    Beschreibung: research
    Schlagwort(e): ddc:551.7
    Sprache: Deutsch
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  • 2
    Publikationsdatum: 2022-08-02
    Beschreibung: Funde nicht-alpiner Gerölle südlich des altpleistozänen Donaulaufs in der östlichen Iller-Lech-Platte werden als umgelagerte Reste pliozäner Donauschotter gedeutet und geben so erste Hinweise auf ein Ausgreifen der Donau 35-40 km südlich ihres heutigen Laufs. Die bisher als Tertiärrelikt angesehene Dinkelscherbener Altwasserscheide dieses Bereichs kann somit erst im Pleistozän entstanden sein und dürfte kaum am Staufenberg vorbei weiter nach NNO gereicht haben.
    Beschreibung: research
    Schlagwort(e): ddc:551.7
    Sprache: Deutsch
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  • 3
    Publikationsdatum: 2022-08-05
    Beschreibung: Korngrößen-, Kies- und Schwermineralanalysen würmzeitlicher Grundmoränen-Ablagerungen des Rheingletschers im baden-württembergischen Alpenvorland zeigen einen meist relativ niedrigen Einfluß des aus Molasse bestehenden Substrats auf die Zusammensetzung dieser Sedimente. Auf Grund theoretischer Überlegungen und großmorphologischer Beobachtungen wird geschlossen, daß auch die Aufnahme präexistierender quartärer Ablagerungen untergeordnet war und daß die Petrographie der Moränen-Ablagerungen hauptsächlich bestimmt wird vom während der letzten Vorland-Vergletscherung vom Rheingletscher ins Vorland transportierten Schutt.
    Beschreibung: research
    Schlagwort(e): ddc:551.7
    Sprache: Englisch
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  • 4
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    Geozon Science Media
    Publikationsdatum: 2022-08-05
    Beschreibung: Mineralische Rohstoffe werden in großen Mengen für die verschiedensten Wirtschaftszweige benötigt. Die Gewinnung oberflächennaher Rohstoffe bedingt i. a. eine Abbaugrube, welche später wieder in die Umgebung eingefügt, d. h. rekultiviert oder renaturiert, werden muß. Im Zuge eines erstarkenden Umwelt- und Ökologiebewußtseins ist der Renaturierung verstärkte Aufmerksamkeit zu schenken.
    Beschreibung: research
    Schlagwort(e): ddc:551.7
    Sprache: Deutsch
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  • 5
    Publikationsdatum: 2022-08-05
    Beschreibung: Verschieden alte, datierte Böden auf den Niederterrassen des Rheins werden mikromorphologisch charakterisiert und ausgewählte Merkmale dem Bodenalter gegenübergestellt. Klare Beziehungen zum Alter zeigen. Entkalkung und Tonwanderung. Bereits in der Gruppe der 1800jährigen Böden wird eine Entwicklung sichtbar. Ab 6000 Jahren kommen Parabraunerden vor. Stark entwickelt sind die Böden auf präholozänen Sedimenten. Die Bodenbildung in situ wird vom Wechselspiel aus Bodenentwicklung und -abtrag im Liefergebiet der Sedimente mitbestimmt. Die im Liefergebiet begonnene Silicatverwitterung läuft in der Aue weiter, während die Horizontdifferenzierung durch Tonverlagerung nach dem Transport in der Aue neu beginnt. Die Böden aus präholozänen Sedimenten können kurzstreckig verlagertes Material von Bt-Horizonten eemzeitlicher Böden enthalten. Die systematische Stellung der Böden wird diskutiert. Die Bedeutung der Tonwanderung zwischen Sandkörnern wird anhand verdichteter Böden des Versuchsgutes Wahn dargestellt.
    Beschreibung: research
    Schlagwort(e): ddc:551.7
    Sprache: Deutsch
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  • 6
    Publikationsdatum: 2022-08-05
    Beschreibung: Die modernen Anforderungen an den Trinkwasserschutz, die zunehmende Zersiedelung und die landwirtschaftliche Nutzung weiter Teile der Niederrheinischen Bucht führen immer häufiger zu Nutzungskonflikten. Da die einmal vorhandenen Nutzungsstrukturen wie Naßabgrabungen und Gewerbegebiete die Flächen für eine schutzfähige Grundwassergewinnung reduzieren, bleibt oft nur die Verlagerung der Trinkwassergewinnung in zuvor nicht beanspruchte Gebiete. Am Beispiel einer Prognose für die Verschiebung einer Entnahmegalerie aus einer Zone mit gewerblicher und lagerstättentechnischer Nutzung im Umfeld des Xantener Stauchmoränenbogens kann gezeigt werden, daß auf der Grundlage quartärgeologischer Grundlagendaten und eines numerischen Grundwasserströmungsmodells eine Optimierung der Ortslage für eine Trinkwassergewinnung durchgeführt werden kann. Die eiszeitliche Überprägung weiter Teile des hydrogeologischen Grundwasserleitersystems im Xantener Bogen bedingte zahlreiche Restriktionen für die Optimierung eines Grundwassergewinnungsbereichs. Mit Hilfe der Geländeaufnahmen und der Modellrechnungen wurden verschiedene neue Brunnenstandorte simuliert und hinsichtlich der ökologischen und hydrogeologischen Restriktionen bewertet. Die Modellrechnungen ermöglichten bereits im Planungsstadium eine Vorausschau auf die Auswirkungen und den Nutzen einer Verlagerung der ursprünglichen Entnahmeschwerpunkte. Die Ergebnisse zeigen aber auch, daß ein Ausweichen der Trinkwassergewinnung zugunsten anderer Flächennutzungen mit neuen Restriktionen am neuen Standort verbunden sein kann und somit in jedem Einzelfall zu überprüfen ist.
    Beschreibung: research
    Schlagwort(e): ddc:551.7
    Sprache: Deutsch
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  • 7
    Publikationsdatum: 2022-08-05
    Beschreibung: Die MATUYAMA/BRUNHES-Grenze konnte am Mittelrhein in der Schichtenfolge von Kärlich relativ stark eingeengt werden. Sie ist dort älter als die 6. Eiszeit vor heute und liegt in einer Wechselfolge von Sedimenten, die dem „Ville-Interglazial-Komplex" zugeordnet wird. Möglicherweise muß diese Grenze sogar noch etwas tiefer gelegt werden in einen Horizont mit ersten Zeugnissen eiszeitlichen Dauerfrostbodens. In allen anderen untersuchten Lokalitäten ist die Lückenhafbigkeit der Überlieferung zu groß für detailliertere Aussagen. Die MATUYAMA-Epoche ist vorerst sowohl am Rhein wie an der Donau wegen der vorwiegend gröberklastischen Gesteinsfazies nur bedingt mit der Feingliederung des ältesten Pleistozäns korrelierbar. So sind in der Ville (Tgb. Frechen) mehrere altquartäre warmklimatische Tonhorizonte revers magnetisiert (Tonhorizont B2 und C). Darüber folgt ein normal magnetisierter Horizont (Tonhorizont D), der sich ebenfalls noch im Liegenden der Hauptterrassenfolge befindet. Schließlich wurde neuerdings im Liegenden dieser Abfolge ein weiterer, bereits quartärer Horizont (Bl) gefunden, in welchem sich eine Umpolung von normal nach revers vollzieht. Die Schwierigkeit besteht vorerst noch darin, diese Abfolge geobotanisch genauer zu definieren. Die GAUSS-Epoche läßt sich hingegen in einen guten Zusammenhang mit dem mittleren bis höheren Pliozän bringen (Brunssumium bis mittleres Reuverium). Die Tertiär/Quartär-Grenze auf geobotanischer Grundlage kann nach diesen Befunden etwa mit 2 Mio. Jahre vor heute relativ gut festgelegt werden; denn im höchsten Reuverium (C), das zumeist der Erosion zum Opfer gefallen ist, wurde bereits die Umpolung zur reversen Matuyama-Epodie (Beginn rd. 2,4 Mio. Jahre vor heute) gefunden.
    Beschreibung: research
    Schlagwort(e): ddc:551.7
    Sprache: Deutsch
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  • 8
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    Elsevier
    In:  Amsterdam, 357+IX pp., Elsevier, vol. 121, no. Publ. No. 12, pp. 127, (ISBN 0-521-66034-3, ISBN 0-521-66948-0 paper)
    Publikationsdatum: 1976
    Schlagwort(e): Earthquake precursor: prediction research ; Textbook of geophysics
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  • 9
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    Elsevier
    In:  Int. J. Rock Mech. & Min Sci., Taipei, Elsevier, vol. 34, no. 3-4, pp. 155-162, pp. B09401, (ISBN: 0-12-018847-3)
    Publikationsdatum: 1997
    Schlagwort(e): Borehole geophys. ; Stress ; Borehole breakouts ; Hydraulic fracturing ; stability ; Anisotropy ; shear ; tensile ; Strength ; Rock mechanics
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  • 10
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    Elsevier
    In:  Amsterdam, Elsevier, vol. 1, no. 22, pp. 65-70, (ISBN 3-7643-0253-4)
    Publikationsdatum: 1976
    Schlagwort(e): Textbook of geophysics ; Filter- ; Recursive filters
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  • 11
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    Elsevier
    In:  Amsterdam, Elsevier, vol. 65, no. ALEX(01)-FR-77-01, AFTAC Contract F08606-76-C-0025, pp. 95-104, (ISBN: 0-08-044051-7)
    Publikationsdatum: 1993
    Schlagwort(e): Textbook of geophysics ; GeodesyY ; Geothermics ; Planetology ; ConvolutionE
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  • 12
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    Elsevier
    In:  Int. J. Rock Mech. & Min. Sci., Hannover, Elsevier, vol. 34, no. 3-4, pp. 13021-13032, pp. L15S14, (ISSN: 1340-4202)
    Publikationsdatum: 1997
    Schlagwort(e): Stress ; Stress measurements ; Hydraulic fracturing ; Borehole geophys. ; stability ; North ; Sea ; Norway
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  • 13
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    Elsevier
    In:  Marine Pollution Bulletin, 26 (3). pp. 152-155.
    Publikationsdatum: 2018-03-22
    Beschreibung: Skin and hair samples of harbour seals (Phoca vitulina) found dead along the west coast of northern Germany in 1988 were analysed for total mercury, cadmium and lead. Cadmium and lead concentrations were below the detection limit in most skin samples. The mercury content of the hair (median: 23.1 μg g−1 wet wt) was several magnitudes higher than the mercury content of the skin (0.27 μg g−1 wet wt). Mercury concentrations in hair samples were significantly higher than lead concentrations (0.54 μg g−1 wet wt), which significantly exceeded cadmium levels (0.09 μg g−1 wet wt). Female seals revealed lower cadmium concentrations in the hair than male seals. Accumulations of metals with age were observed for cadmium and lead in hair samples and for mercury in skin samples of male seals. A connection between metal accumulation and pigmentation or rather moult was clearly recognizable.
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  • 14
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    Elsevier
    In:  Deep Sea Research Part I: Oceanographic Research Papers, 40 (2). pp. 267-291.
    Publikationsdatum: 2018-03-22
    Beschreibung: The spreading of Mediterranean Water (MW) released through the Straits of Gibraltar is studied with hydrographic data, oxygen, nutrients and for the first time with chlorofluoromethane (CFM, compounds F11 and F12) distributions along seven sections in the Gulf of Cadiz, and with measurements in the Western Alboran Sea and west of the Gulf. The properties of MW entering the Gulf are deduced from CFM-salinity correlations east and west of the Straits as well as from property-depth profiles in the Western Alboran Sea. At the time of the survey, the outflow originated from depths above the salinity maximum of the Intermediate Water in the Alboran Sea. It turned out that the F11/F12 ratio of the outflow is equal to the ratios found in the Atlantic water in the Gulf of Cadiz; thus the ratio carries no time information in the region. A model is developed to describe mixing of the MW undercurrent with overlying North Atlantic Central Water (NACW) from different depths. The contribution of each layer to the mixing is parameterized by a weighting factor, which has to satisfy the balances of potential temperature (θ), CFMs, oxygen and nutrients in the MW undercurrent. It is shown that entrainment of water from shallower depths into the undercurrent is important near the Iberian Continental Shelf. Farther west and south, the undercurrent mainly mixes with water from near the salinity minimum of the NACW. For regions where the undercurrent has left the bottom, additional mixing with North Atlantic Deep Water (NADW) has to be taken into account. The percentage of MW in the undercurrent decreases from 76% hear the Straits to about 34% at 7°30′W for the lower core (MI) and about 22–24% for the upper core (Mu). Assuming an outflow of undiluted MW through the Straits of 1.0 Sv, the transport of the undercurrent can be calculated by determining an average dilution factor for each section. The undercurrent transports 2.0 Sv just west of the Straits and 3.6 Sv leave the Gulf of Cadiz. At 36°N, 9°54′W, a meddy with unusually high temperatures and salinities below 500 m was found, covering the density range for both cores, Mu and Ml. From the θ−S characteristics and the evaluated mixing scheme of the meddy it appears to have formed near 7°W in the Gulf, a region up to now not proposed in the literature, and moved westward without much further mixing.
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  • 15
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    Elsevier
    In:  International Journal for Parasitology, 23 (6). pp. 749-755.
    Publikationsdatum: 2018-03-23
    Beschreibung: In April 1990, 488 marine fish belonging to 30 species from central Phillipine waters were examined for flesh parasitic infections that may affect their consumability. One species of hemirhamphids and 3 species of belonids harboured plerocercoids of Otobothrium penetrans Linton, 1907 (Proceedings of the U.S. National Museum33, 85–126). This is the first record of this parasite from Pacific fish species. The highest intensity of infection found was 8 in Tylosurus crocodilus. Most of the larvae were located between the dorsal spines of the vertebral column, only 32% were found in the fillets. Based on the present material we give a description of the plerocercoid stage of the species using scanning electron microscopy of the armature and morphometrical measurements. Comparison to results from earlier findings of O. penetrons by Linton (1907; 1924, Proceedings of the U.S. National Museum64, 1–114) and to O. kurisi by Shields (1985, International Journal for Parasitology15: 635–643) lead to the conclusion that the latter species is a synonym for O. penetrans.
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  • 16
    Publikationsdatum: 2018-03-21
    Beschreibung: Nine large box cores collected in the western Greenland-Iceland-Norwegian (GIN) Sea were analyzed for calcium carbonate content and coarse fraction components. Stratigraphic control is based on oxygen isotope records performed on four of the cores. All cores were correlated using oxygen and carbon isotope data, fluctuations in calcium carbonate content, coarse terrigenous particle content and volcanic ash beds. Glacial and interglacial cycles are documented by a number of terrigenous particle events and differentiated calcium carbonate production which can be correlated to major paleoceanographic and paleoclimatic shifts. In the older core sections, extensive deposition of ice-rafted detritus (IRD) persisted until about oxygen isotope stage 9 and document a relatively stable environment in this area, strongly influenced by cold surface water masses. The following interval was characterized by variations in the general surface water circulation pattern, although high amounts of IRD are still present in Iceland Sea sediments. Pronounced shifts in terrigenous input and pelagic carbonate records were identified close to the oxygen isotope stage Full-size image (〈1 K) and Full-size image (〈1 K) boundaries, indicating massive melting of icebergs in the western GIN Sea. These enormous inputs of debris were followed by an increase in calcium carbonate production caused by maximum intrusion of warm Atlantic surface waters. Relatively high calcium carbonate contents also show that only little dilution by fine-grained material and a minimum of ice melting occurred during these warm phases. During oxygen isotope stage 5, conditions were more uniform indicating a less pronounced westward penetration of Atlantic waters as compared to the Holocene. The last glacial (stages 4-2) is characterized by the occurrence of “Heinrich”-like events, although high IRD contents were present throughout this interval. A distinct contrast between the northernmost cores and the cores in the south is indicative of a rather strong westward penetration of Atlantic water in the north and of an area dominated by cold water east of the Kolbeinsey Ridge during the Holocene. However, conditions west of Jan Mayen seem to have remained constantly dominated by cold surface waters throughout the whole time investigated.
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  • 17
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    Elsevier
    In:  Deep Sea Research Part II: Topical Studies in Oceanography, 40 (3). pp. 783-800.
    Publikationsdatum: 2018-03-05
    Beschreibung: Horizontal distribution of myctophid fishes were studied from two transects in the Arabian Sea in 1987. Species numbers exhibited a south-north decline in diversity, with only half of the fish taxa occupying the northeastern region. Diaphus arabicus was the dominant species both in the south and north. All recorded myctophid fish species migrate in a diel pattern, residing during daytime at depths of extremely low oxygen levels (〈0.1 ml O2 1−1) and foraging in the oxygen-rich surface layer at night. Feeding patterns were determined for the six most abundant myctophid species. All species appeared to be opportunistic predators that prey on a comparatively narrow food spectrum consisting principally of small to medium sized copepods. Numerically, non-calanoid copepods (with Oncaea conifera and O. venusta dominating) made up to 70% of the diet of D. arabicus and Bolinichthys longipes. Of the 26 calanoid copepod species identified from the six myctophid taxa, the genera Euchaeta, Pleuromamma and Candacia generally dominated in the stomachs, with P. indica constituting between 21 and 95% (by numbers) of the calanoid copepod prey.
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  • 18
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    Elsevier
    In:  Deep Sea Research Part I: Oceanographic Research Papers, 40 (6). pp. 1155-1168.
    Publikationsdatum: 2018-03-05
    Beschreibung: Particulate fluxes of aluminium, cadmium, cobalt, copper, iron, manganese, nickel, phosphorus, lead, vanadium and zinc in the northeast subtropical Atlantic Ocean have been determined from sediment trap samples collected between 1 December 1986 and 30 April 1987 at 1020 and 4120 m below the ocean surface. The fluxes of most elements (except Cd and P) show small variations between the different layers, and are closely associated with the vertical transport of aluminium. Elemental composition and flux rates suggest that aerosol loadings from northeast trade winds are the major contributor of these elements to depositing material. Extremely low fluxes of copper, lead and zinc also indicate that anthropogenic perturbations are of insignificant importance in this region.
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  • 19
    Publikationsdatum: 2018-03-05
    Beschreibung: Within the framework of the JGOFS Pilot Study in 1989 mesozooplankton (0.2–20 mm) was sampled by means of a Hydro-Bios multinet in five depth strata (0–25, 25–50, 50–100, 100–200, 200–500 m) during four Lagrangian drift experiments of 8–14 days' duration at 18, 33, 46 and 58°N, to follow the seasonal progress of the phytoplankton spring bloom development in the northeast Atlantic. Mesozooplankton standing stock, measured as dry weight and ash-free dry weight, increased by a factor of about 6 from 18 to 58°N. Day/night differences amounted to 10–20% of the average and were—with one exception at 18°N—not statistically significant. Using the data on weight-specific respiration rates measured by colleagues on the same cruise, the ingestion rates and potential community grazing of mesozooplankton on phytoplankton within the upper 100 m of the water column were calculated. During all four drift experiments, quasi-steady-state conditions were observed in phyto- and zooplankton standing stock, primary production and daily sedimentation at 100 m depth. The maximum potential grazing rate by mesozooplankton accounted for about half of the daily primary production. Since sedimentation of fresh phytoplankton was negligible, it is concluded that the grazing pressure exercised by mesozooplankton together with micro- and nanozooplankton was responsible for keeping the phytoplankton standing stock at a more or less constant level during the investigated spring bloom in the four areas. Particle flux was thus dominated by zooplankton faecal material.
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  • 20
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    Elsevier
    In:  Journal of Chromatography A, 642 (1-2). pp. 425-434.
    Publikationsdatum: 2019-02-27
    Beschreibung: Accurate congener-specific determination of chlorobiphenyl congeners (all 209 congeners) is finally possible with the use of multidimensional gas chromatography-electron-capture detection techniques. The effectiveness of this technique for environmental analyses is enhanced by ultraclean laboratory practices, non-destructive extraction and clean-up steps and the use of low-volume, high-efficiency HPLC separation for various classes of organic contaminants. In the light of these new developments conventional procedures for chlorobiphenyl analysis are evaluated.
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  • 21
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    Elsevier
    In:  Deep Sea Research Part II: Topical Studies in Oceanography, 40 (3). pp. 711-735.
    Publikationsdatum: 2018-03-05
    Beschreibung: The productivity regime and size structure of phytoplankton are described for three different epipelagic systems in the Arabian Sea during the inter-monsoon period in spring 1987: (1) the coast of Oman; (2) the central Arabian Sea; and (3) the shelf off Pakistan. These results are related to the functioning of the specific ecosystem. Off the coast of Oman, the transition from a surface maximum of autotrophic biomass and production to a more oligotrophic system, with a chlorophyll subsurface maximum, was observed. Concomitantly, the size spectrum changed towards a higher significance of picoplankton. In the central Arabian Sea, a typical oligotrophic system with a pronounced subsurface maximum of autotrophic biomass and primary production was encountered. Here, the epipelagic system could be divided into two distinct sub-systems: the surface layer “regenerated” production, the predominance of picophytoplankton and minor losses due to sedimentation, thus a “closed” system; and the subsurface maximum layer at the nutricline characterized by higher sedimentation losses and more diatoms. Both sub-systems showed about the same productivity, the turnover in the surface layer having been much greater than in the subsurface maximum. The system on the shelf off Pakistan is seen as a decay stage of the open ocean system when water from offshore is transported onto the shelf during the onset of monsoon winds.
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  • 22
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    American Chemical Society
    In:  ACS Division of Fuel Chemistry Preprints, 42 (2). pp. 544-547.
    Publikationsdatum: 2018-04-11
    Beschreibung: Test specimens of methane hydrate were grown under static conditions by combining cold, pressurized CH4 gas with H2O ice grains, then warming the system to promote the reaction CH4 (g) + 6H2O (s???l) ??? CH4??6H2O. Hydrate formation evidently occurs at the nascent ice/liquid water interface, and complete reaction was achieved by warming the system above 271.5 K and up to 289 K, at 25-30 MPa, for approximately 8 hours. The resulting material is pure methane hydrate with controlled grain size and random texture. Fabrication conditions placed the H2O ice well above its melting temperature before reaction completed, yet samples and run records showed no evidence for bulk melting of the ice grains. Control experiments using Ne, a non-hydrate-forming gas, verified that under otherwise identical conditions, the pressure reduction and latent heat associated with ice melting is easily detectable in our fabrication apparatus. These results suggest that under hydrate-forming conditions, H2O ice can persist metastably at temperatures well above its melting point. Methane hydrate samples were then tested in constant-strain-rate deformation experiments at T= 140-200 K, Pc= 50-100 MPa, and ????= 10-4-10-6 s-1. Measurements in both the brittle and ductile fields showed that methane hydrate has measurably different strength than H2O ice, and work hardens to a higher degree compared to other ices as well as to most metals and ceramics at high homologous temperatures. This work hardening may be related to a changing stoichiometry under pressure during plastic deformation; x-ray analyses showed that methane hydrate undergoes a process of solid-state disproportionation or exsolution during deformation at conditions well within its conventional stability field.
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  • 23
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    Elsevier
    In:  Continental Shelf Research, 13 (10). pp. 1083-1101.
    Publikationsdatum: 2018-03-07
    Beschreibung: In February 1988, 60 near surface samples were taken on a track between 2°W in the English Channel, the Pentland Firth and the inner German Bight. Determinations were made on filtered and unfiltered samples. Concentrations of dissolved metals in the North Sea normalized to a salinity of 34.5 were Al 31, Cd 0.13, Co 0.13, Cu 3.4, Mn 6.2 and Ni 3.9 nM. In July 1984 the equivalent concentrations were Al 11, Cd 0.15, Co 0.15, Cu 4.3, Mn 12 and Ni 3.6 nM. Distinct regional differences were detectable which can be related to the origin of the water, differing river inputs, and solution-solid phase exchange reactions. The degree of the influence of exchange reactions was investigated through the concept of Kd, the distribution coefficient. A Kd of 105 ml g−1 for Al is consistent with other observations and explains the relatively high concentrations of dissolved Al detected in the English Channel on this cruise. The data suggest a higher Kd for Mn approaching 106 ml g−1. The high Mn Kd coupled to higher suspended sediment loads in winter may be sufficient to explain the lower concentration of dissolved Mn in winter. Comparison of concentrations across the shelf break suggests that for all the metals studied, the European Shelf is a source of dissolved metals to the deep sea. Calculations based on the limited available data indicate that this export is of similar magnitude to the fresh water input of dissolved metals.
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  • 24
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    Elsevier
    In:  Deep Sea Research Part II: Topical Studies in Oceanography, 40 (1-2). pp. 91-114.
    Publikationsdatum: 2018-03-05
    Beschreibung: An overview is given of the multinational investigations carried out at 47°N 20°W for the period 24 April–31 May, with the main emphasis on the succession of plankton communities and the flux of organic carbon through various plankton components. The depth of the upper mixed layer decreased rapidly after 25 April, triggering the start of the spring bloom that developed within a 2-week period. Chlorophyll a stocks integrated to 80 m water depth reached peak concentrations during the first 10 days in May. The observed decline was partly due to the seasonal development, but also may have been influenced by changes in water masses associated with a cyclonic eddy. Primary production ranged from 50 to 150 mmol C m−2 day−1 with highest values in the first half of May. After the first bloom phase, dominated by diatoms, nanophytoplankton gained more importance as primary producers when silicate was depleted. Stocks of bacteria, microzooplankton and mesozooplankton increased in the second half of May. Bacterial production averaged 30% of primary production and probably metabolized a large amount of dissolved organic carbon (DOC) per day, but due to uncertain carbon conversion efficiencies total bacterial carbon consumption is difficult to estimate. Largely daily changes in the DOC standing stock could not be reconciled with the measured primmary production and are probably an expression of spatial rather than temporal variations. Microzooplankton was found to consume around 64% of primary production in the second half of May. Grazing estimates for mesozooplankton varied but seem to be small (〈5% of primary production) for most of the investigation period. The small mesozooplankton size classes (〈1 mm) dominated biomass and grazing. Vertical particulate organnic carbon (POC) flux measured by sediment traps in 150 m depth was around 9.8 mmol C m−2 day−1 representing approximately 11% of primary production. The spring bloom pulse of particle flux reached the deep ocean and benthos 4–6 weeks after the surface water peak.
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  • 25
    Publikationsdatum: 2018-03-22
    Beschreibung: Altimetric data from Geosat and some critical hydrographic measurements were used to estimate in real time the mesoscale physical oceanographic environment surrounding the Joint Global Ocean Flux Study (JGOFS) 1989 North Atlantic Bloom Experiment. Three cyclonic eddies, including an exceptionally large one, evolved and interacted over the 10 weeks of observations. Subsequent analysis of all available hydrographic data confirmed the real time estimates and provided further quantitative information concerning the mesoscale and submesoscale structure of the upper ocean. Remotely sensed indicators of near-surface chlorophyll content reveal significant biological variability on these wavelengths. The altimetric and hydrographic data have been assimilated into a dynamical model to produce optimal estimates of physical fields of interest as they evolve in time for use in physical and biological process studies
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  • 26
    Publikationsdatum: 2018-03-22
    Beschreibung: The influence of increasing amounts of surfactants on the toxicity of hydrocarbons was determined using the bioluminescence inhibition test (Microtox test). Three biogenic and three synthetic surfactants were tested against the water-soluble fractions (WSF) of crude and weathered Ekofisk oil, phenol, and naphthalene. Surfactant concentrations below 100 mg litre−1 lowered the toxicity of the WSF, indicating an antagonistic interaction reducing the toxicities of surfactants and hydrocarbons. At concentrations greater than 100 mg litre−1 the toxicity rose again and was higher than the untreated WSF. The point of reversal seemed to be the critical micelle concentration, at which the formation of oil/water emulsions is possible.
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  • 27
    Publikationsdatum: 2017-03-30
    Beschreibung: Biological and fishery features of the waves of abundance of Illex argentinus in three fishery regions −52°S (shelf with 180–230 m depths in exclusive economic zone of Argentina—EEZA), 46° and 42°S (continental slope with 600–800 m depths off the EEZA) in April–June 1990 were studied. According to age analysis of 629 statoliths made aboard, age-length structure of each wave of abundance were determined. In April–June active spawning migrations of I. argentinus were observed from feeding grounds located in limits 50–52°S along the continental slope northwards through 46° and 42° fishery regions. Only winter-hatched squids (hatched from June to September of the previous year) took part in migrations which were observed as waves of abundance in all three regions. Each migratory wave of abundance consisted of 2–4 successive monthly generations. The start of spawning movement was corresponded with the age and maturity state of the squid. Squid of all monthly generations began migrating from the 52°S region at a mean age of approximately 250 days, passed through 46°S at mean age 280 days and through 42°S at mean age 295 days. Males migrated 2–3 weeks earlier than females of the same generation. Rates of somatic growth were very low during migrations from 52° to 46°S (RDGR - 0.13% mantle length (ML) in mature males and 0.2% ML in maturing females). During movement from 46° to 42°S and, obviously further, mature squids practically ceased somatic growth. Estimated rate of migrations was 23.2–28.9 km day−1 (including current velocity), or 26–30 cm s−1 (0.47 body length s−1). Spawning was considered to occur on the continental slope of Uruguay and Brazil north of 35°S in July–August. Methodical approaches of efficient determination of squid age, growth and stock structure by means of investigation of squid biological features and statolith microstructure in each distinguished wave of abundance were elaborated.
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  • 28
    Publikationsdatum: 2017-05-04
    Beschreibung: The effects of feeding a prepared surimi diet (fish-based) and a prepared pelleted diet (shrimpbased) on the survival, growth and feeding rate of the cuttlefish Sepia officinalis L. were evaluated during a 45-day experiment. One hundred and twenty juveniles of laboratory cultured cuttlefish (74.5 ± 12.36 g) were divided into three treatments and were fed thawed shrimp (control), pellets or surimi. Survival rates on these diets were 95.0%, 67.5% and 22.5%, respectively. Preliminary data indicated that the low survival of cuttlefish fed surimi may have been caused by low levels of copper in their blood (131 vs 244 μg/ml) since copper is required for their respiratory blood pigment, hemocyanin. Instantaneous growth rates were 2.71 % body weight BW/day for cuttlefish fed raw shrimp, 0.33% BW/day for cuttlefish fed pellets, and 0.54% BW/day for cuttlefish fed surimi. The feeding rate of cuttlefish fed shrimp was high (6–8% BW/day). The feeding rate on pellets increased with time (from 〈 1 to 3% BW/day) but never reached the level for raw shrimp. The feeding rate on surimi increased to equal the rate for raw shrimp during days 1–30 (8 to 9% BW/day) and thereafter decreased (〈4% BW/day). In conclusion, there was a major distinction between the palatability of a prepared diet and the ability of that diet to support growth. Surimi was highly palatable but resulted in poor survival, suggesting low nutritional quality. In contrast, pellets were less palatable but produced maintenance growth. Development of practical surimi diets will require supplementation of the surimi with soluble micro- and macronutrients.
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  • 29
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    Elsevier
    In:  Acta Oecologica - International Journal of Ecology, 14 (3). pp. 463-470.
    Publikationsdatum: 2020-04-23
    Beschreibung: Changes in marine ecosystems can be manifested in many different ways, on different temporal and spatial scales. Seabirds are top consumers in marine foodwebs and offer opportunities to detect and assess the biological effects of changes in physical parameters (sea-surface temperature [SST], salinity, depth of thermocline etc.) of the marine ecosystem. We compare six-eight years' of data on the biology (diet, and breeding success) of four species of seabird (arctic tern Sterna paradisaea and common tern S. hirundo, which feed at the sea surface; and Atlantic puffin Fratercula antica and razorbill Alca torda, which dive 30-60 m for their prey) breeding on Machias Seal Island (MSI) in the Bay of Fundy with both our own meteorological and oceanographic measurements, and with standard measurements from conventional sources. These are compared with fisheries data on changes in the main prey of all the seabirds concerned (juvenile or '0-group' herring Clupea harengus) which are the most direct link between the seabirds and the physical properties of the marine system. We explore relationships between seabird productivity and diet, and other aspects of both herring biology (larval surveys, and fat content) and oceanography (SST data from the island, and remotely sensed data from the entrance to the Bay of Fundy). Timing of laying by puffins followed SST variation at neither the local (MSI) nor regional scales, but at the scale of the North Atlantic, following the trend of populations breeding off northern Norway. The proportion of herring in the diet of terns over 6 years varied inversely with herring larval abundance the previous fall; this relationship was not statistically significant in the puffin and razorbill. A major new finding is the considerable (approximately 50%) inter-annual variation in the energy density (fat content) of juvenile herring that are the main seabird prey; breeding success of both species of tern varied in parallel with the energy density of juvenile herring in the diet until the last two years of the study, when sandlance (Ammodytes sp.) and euphausid shrimp predominated in the diet. Our long-term research approach combines traditional population monitoring (of numbers of breeding birds) with demographic, behavioural and environmental monitoring, to provide new understanding of the marine ecosystem as well as of seabirds.
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  • 30
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    Elsevier
    In:  Deep Sea Research Part II: Topical Studies in Oceanography, 40 (1-2). pp. 495-519.
    Publikationsdatum: 2018-03-05
    Beschreibung: Productivity regime and phytoplankton size structure are described for two different epipelagic systems in the tropical/subtropical Northeast Atlantic Ocean investigated during 9–11 day drift studies in spring 1989 in the JGOFS North Atlantic Bloom Experiment, 18°N, 30°W and 33°N, 20°W. At the 18°N study site, an oligotrophic system was encountered. The water column above the main pycnocline at about 50–60 m depth was nutrient-depleted, and both chlorophyll and primary production displayed subsurface maxima at the nutricline. Picoplankton was the dominant size fraction, accounting for 78–90% of chlorophyll and 83–98% of primary production. Synechococcus-type coccoid cyanobacteria were the dominant picoplankters. The hydrographic situation was characterized by high small-scale variability; the most interesting feature was the intrusion of nutrient-depleted Subtropical Salinity Maximum Water into the euphotic zone, whose impacts on the productivity regime are discussed. At 33°N study site, a post-bloom situation was encountered. Although the euphotic zone was nutrient-depleted, higher amounts of larger phytoplankton were present, the contribution of picoplankton being 42–53% of chlorophyll and 42–86% of primary production. Over the course of the drift study, subsurface maxima of chlorophyll and productivity evolved, the contribution of picoplankton having increased. Picocyanobacteria again were the dominant picoplankters. At both study sites the profiles of abundance ratios of picocyanobacteria to picoeucaryotes cell numbers proved to be a useful tool to characterize water masses.
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  • 31
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    Elsevier
    In:  Deep Sea Research Part I: Oceanographic Research Papers, 40 (11-12). pp. 2167-2177.
    Publikationsdatum: 2018-03-07
    Beschreibung: The origin and the spreading of the shallow Mediterranean water core (Ms) in the Iberian basin is discussed with a quasi-synoptic hydrographic data set enhanced by chlorofluoromethane (CFM) measurements. Its characteristic density level is found to be σt = 27.4. Characterized by high temperature and CFM values, Ms enters the Iberian basin in the region of Cape St Vincent between depths of 500–750 dbar. A heat anomaly of 〉11.8 × 109 J m−2 is chosen as the boundary between the presence of Ms and the background field. The core is found in a tongue-like shape as well as in separate isolated eddies of both cyclonic and anticyclonic circulation. Using the optimum multiparameter analysis (Tomczak and Large, 1989, Journal of Geophysical Research, 94, 16141–16149), the North Atlantic Central Water (NACW), which mixes with the Mediterranean outflow to form Ms, turned out to be in the mean 1°C warmer and 0.11 saltier than in regions with minor Mediterranean influence. This points to the Gulf of Cadiz as the origin of Ms, where the Mediterranean oufflows is in contact with NACW of the appropriate characteristics.
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  • 32
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    Elsevier
    In:  Journal of Marine Systems, 4 (2-3). pp. 231-233.
    Publikationsdatum: 2018-03-07
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  • 33
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    Elsevier
    In:  Marine Chemistry, 42 (1). pp. 57-70.
    Publikationsdatum: 2018-03-07
    Beschreibung: Gas chromatography-mass spectrometry (GC-MS) analyses of organic concentrates from eastern Mediterranean surface water show that dissolved fossil fuel residues are dominated by unsubstituted aromatic hydrocarbons and heterocyclic aromatics and thus resemble products of incomplete combustion. Deviating from this interpretation, preferential photochemical oxidation of alkyl-substituted aromatics is suggested as the principal causative mechanism, although, especially near land-based sources. the influence of combustion-derived unsubstituted aromatics is not defined. Total concentrations of dissolved aromatics as determined by GC-FID (flame ionization detection) and GC-MS from a limited data subset were in reasonable agreement with UV fluorescence measurements of dissolved/dispersed oil residues. The same preponderance of unsubstituted aromatics over their alkyl derivatives was found in extracts of the particulate phase, but concentrations were small relative to alkanes and/or alkenes of recent marine biosynthetic origin. CPI (carbon preference index) values of higher molecular weight n-alkanes indicated varying contributions of plant waxes to the particulate hydrocarbon pool. CPI values of corresponding dissolved n-alkanes were found to be near unity, indicating fossil fuel origin. Despite differences in higher molecular weight n-alkane CPI values and the predominance of recent biosynthetic aliphatics, the similarity of dissolved and particulate aromatic fractions suggests limited adsorption by particles of fossil fuel derived hydrocarbons and heterocyclics.
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  • 34
    Publikationsdatum: 2018-03-07
    Beschreibung: Saudi Arabian coastal waters near sandy beaches, severely contaminated with crude oil released in Kuwait during the 1991 Gulf War, as well as underlying sediments and a few bivalves, were analysed to assess concentrations and composition of petrogenic hydrocarbon mixtures and structurally related oxidation products. Concentrations of dissolved oil residues determined by UV spectrofluorometry (UVF) near oil deposits on beaches did not exceed 3.5 μg l−1; concentrations dropped to approximately 1/10th of this value a few miles offshore. Gravimetric concentrations of unfractionated lipophilic material extracted from large volumes of seawater at the same stations were up to 10 times those determined by UVF. After chromatography on silica gel, individual petroleum hydrocarbons in the low polarity fractions and oxidation products in the polar fractions were characterized by their spectra (GC/MS) and quantitated by Selected Ion Monitoring (SIM) GC/MS. Concentrations of oxidation products (ketones, aldehydes, alcohols) of aromatic hydrocarbons exceeded those of their parent compounds by more than an order of magnitude. Significant concentrations were also found of the presumably pyrogenic triplett sensitizer anthraquinone. Contributions to polar fractions of water extracts by biosynthesized lipids were negligible. UVF determinations appear to underestimate concentrations of dissolved oil residues, because many oxidation products have lower fluorescence quantum yields than the respective parent hydrocarbons. Their ecotoxicological properties are unknown. Concentrations measured in sediments by UVF ranged from 13 to 540 μg g−1 dry wt and 0.5 to 103 μg g−1 as measured by gas chromatography with flame ionization detection (FID GC). Bivalves ranged from 0.8 to 1.5 μg mg−1 extractable organic matter (EOM) by UVF, and 0.1 to 0.3 μg mg−1 EOM by GC analysis. PAHs were identified in sediment and bivalve extracts by GC/MS and quantitated by SIM GC/MS. None of the relatively water soluble alkylbenzene photo-oxidation products found in water samples nor any higher molecular weight quinones could be detected in sediment extracts. However, ion chromatograms strongly suggest the presence of numerous high molecular weight aromatics in that matrix.
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  • 35
    Publikationsdatum: 2018-03-07
    Beschreibung: As part of the NOAA/ROPME/MSRC sponsored assessment of the coast of Saudi Arabia, heavily impacted by the large oil spills of the 1991 Gulf War, we measured benthic community respiration (R) and primary production (P) rates in shallow subtidal basins near heavily oiled coastlines. Study sites were located in zones predicted to be basins of maximum deposition of any oiled sediments likely to wash off the adjacent coast and in reference bays predicted to be clean and unaffected. We measured oxygen exchange using in situ benthic respirometers and analysed petroleum hydrocarbon (PHC) levels in the near surface sediments at five stations. We concentrated our efforts in mud habitats to complement related studies in seagrass habitats. Measured community R rates ranged from a low of 700 μM m2 h−1 in coarse sand sediments with total organic carbon content (TOC) of only 0.16% of dry wt to the highest rate of 2184 μm m−2 h−1 in finer mud-sand habitats with 0.39% TOC. All measured rates were in the range of literature values for shallow marine sediments at temperatures of 17 to 19°C. Sediment oil content was 13–540 μg g−1 dry wt by ultraviolet fluorescence (UVF) analysis and 0.5–103 μg g−1 by gas chromatography (GC). Benthic P rates, calculated as light minus dark changes in dissolved oxygen, ranged from a low of 1162 μm m−2 h−1 at the most heavily oiled site to a high of 5216 μm m−2 h−1 at less oiled sites. While a weak inverse relationship between benthic P and sediment oil content was not significant statistically due to the small number of samples, a significant inverse relationship was found between the ratio of production to respiration (P/R) and the total petroleum content of the sediments by UVF. The effect appears to be driven more by differences in production than an effect on respiration which showed little relationship with either oil content or productivity. We conclude that within 1 year after the oil grounded on the intertidal sands of Saudi Arabia, the levels of oil in subtidal benthic sediments had decreased in most habitats to levels that did not show community stress by our oxygen measurements. Rather, long term damage to benthic subtidal habitats was limited only to enclosed bays adjacent to the most heavily oiled coastlines. Preliminary estimates of yearly P converted to carbon units indicates that the shallow mud sediments of the Gulf are at least as productive as most oligotrophic water columns. Since benthic habitats covered by seagrass, algae beds or coral reefs are likely to have even higher production rates, we conclude that benthic processes contribute significantly to the overall carbon flux in the Gulf ecosystem.
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  • 36
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    Elsevier
    In:  Deep Sea Research Part I: Oceanographic Research Papers, 40 (2). pp. 257-266.
    Publikationsdatum: 2018-03-21
    Beschreibung: A method for the collection of large-volume samples of oceanic particles is described. Near-surface seawater is pumped from below the ship to a continuous-flow centrifuge at rates of up to 1.2 m3 h−1. The seawater is in contact with polyethylene, polypropylene, Teflon and titanium materials only. The retention efficiency of the centrifuge for marine particles is the same as for standard membrane filters, as shown by comparisons with separate samples from Go-Flo bottles. The pumping system is non-contaminating with respect to both particulate and dissolved species. Several subsampling facilities for additional chemical constituents and other parameters can be supplied simultaneously due to the modular design of the system and the high flow rates
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  • 37
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    In:  Quaternary Research, 40 (3). pp. 368-379.
    Publikationsdatum: 2018-03-02
    Beschreibung: Sediments of 13 piston cores from opposite continental slopes of the South China Sea, off southern China and Sabah (northern Borneo), were analyzed by sedimentological methods and dated by oxygen isotope stratigraphy. Sediments mostly consist of hemipelagic clay with 20% carbonate off Sabah and 40% off China. We calculated terrigenous and carbonate accumulation rates for up to 11 time-slices from the Holocene to oxygen-isotope stage 6. Terrigenous accumulation rates generally increase with water depth and reach a maximum at the middle slope off Sabah and at the lower continental slope off China. During glacial and interglacial times this distribution pattern did not markedly change, despite an increase of accumulation rates for glacial periods by a factor of 2 to 5 compared to interglacial periods. Rates are negatively correlated with positions of sea level, which controls the partition of fluviatile terrigenous material for deposition on shelf, slope, and abyssal plain. Carbonate accumulation rates are higher off China by a factor of 2 compared to Sabah, probably indicating higher calcareous plankton productivity.
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  • 38
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    In:  In: Handbook of strata-bound and stratiform ore deposits Pt. 1, Vol. 3: Supergene and surficial ore deposits; textures and fabrics. , ed. by Wolf, K. H. Elsevier, Amsterdam, pp. 245-294. ISBN 0-444-41403-7
    Publikationsdatum: 2016-04-18
    Beschreibung: Many occurrences of mineral resources in ocean water, on the ocean floor and in its deeper parts have long been well-known. This is readily understandable, because numerous ancient mineral products which are exploited on land were originally formed in marine milieus as far back as the Precambrian , e.g., marine sedimentary iron ores, rock salt, potassium, phosphate and manganese , as well as petroleum and natural gas. This book deals with ores in sediments, and in sedimentary and volcanic rocks. According to the Concise Oxford Dictionary (Fowler and Fowler , 1964), ore is defined as "solid native mineral aggregate from which valuable constituents not necessarily metal may be usefully extracted". Therefore , in tllis chapter only mineral resources of inorganic origin in ocean water and on the ocean floor are discussed and not those of organic derivation, although the existence of petroleum, natural gas and, to some extent, of coal in the subsurface of the ocean shelves is of greater economic importance. The amount of oil and gas produced in 1969 represented more than 90% by value of all mineral resources obtained from the oceans and ocean floors. Ore deposits in bed-rock formations of the shelf region, such as those which are exploited near Cornwall (England) and Newfoundland for example, are also irrelevant, as these are merely extensions of discoveries on the nearby mainland. The purpose of this chapter is to give a general review of the (inorganic) mineral resources of the oceans and the ocean floors . In this respect, not only are the economically important products which are already in use discussed, but also those materials which, in their oceanic environment, can become of economic value in the near or more remote future. For a better understanding of the existence of such materials, some deposits have also had to be reviewed which will not become of economic value . Since some contributions in this book are specifically dedicated to Recent marine ferromanganese deposits and Recent phosphorite deposits, these mineral resources are only briefly discussed in tllis chapter. (For details on Recent marine and lacustrine manganese deposits see Chapters 7 and 8 by Glasby/Read and by Callender/Bowser, respectively, in Volume 7.) The litarature on the mineral (inorganic) resources of the oceans and ocean floors is extremely extensive, so that a choice had to be made and, therefore, the bibliography added to this chapter consists mainly of recent publications.
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  • 39
    Publikationsdatum: 2017-06-22
    Beschreibung: Benthic foraminifera and surface sediments were analyzed from 23 box-core and core-top samples from 250 to 3600 m depth at the southern Portuguese continental margin between 37 and 38 °N. This area is affected by the MOW which flows northwards along the slope between 600 and 1500 m waterdepth. Sediment structures, grain-size distribution and clay mineral assemblages of surface sediments indicate active winnowing in the upper part of the MOW, and deposition of the fine fraction near its lower boundary. R-mode cluster analyses of foraminiferal census data from the 〉 250 μm fraction revealed four associations. The ‘Shelf Edge Association’ occurs on glauconitic shelf and upper slope sands down to 268 m. The ‘Upper Slope Association’ is recognized between 498 and 1300 m where sand-silt-clays to clayey silts are encountered. The ‘Lower Slope Association’ is found between 1405 and 2985 m and differs markedly from assemblages below 3000 m (‘Deep Water Association’) where the near-surface sediments are soft hemipelagic clays. The ‘Boundary Layer Association’ shows no significant depth limits but abundance maxima both in the density interface above the MOW and in the interval of decreasing turbulence below it. The boundaries of the ‘Shelf Edge’ and ‘Upper Slope Association’ correspond to these hydrographic boundary layers whereas the boundary between ‘Lower Slope’ and ‘Deep Water Assemblage’ is related to threshold values of nutrient flux to the benthic community. Examination of hard-substrates reveals 27 different species of epibenthic foraminifera. Six of these, the ‘Epibenthos Group’, were found attached to elevated substrates only within the MOW. Above the MOW, elevated substrates were inhabited by different species, whilst below the MOW they were not used by any epibenthic foraminifers. Evidently, the hydrodynamic environment of the MOW current provides an ecological niche which is efficiently used by opportunistic suspension feeders. The ‘Epibenthos Group’ is more abundant in the middle part of the study area between 37 °20′ and 37 °40′N where the sand content of surface sediments is also higher. Both indicate an enhanced sediment-water interaction in this area which results from an obstruction of the MOW flow by the ‘Principes d'Avis’ basement spur.
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  • 40
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    In:  Deep Sea Research Part I: Oceanographic Research Papers, 40 (9). pp. 1925-1933.
    Publikationsdatum: 2018-03-02
    Beschreibung: The Vema Channel represents a prominent location for the nortward flow of bottom water in the subtropical western South Atlantic. A recent multibeam echo-sounding survey of the Vema Sill on board F.S. Meteor revealed a narrow and shallow portion of the Vema Channel at 31°12′S, 39°24′W, the Vema Sill. The survey also showed the remarkably asymmetric shape of the sill region, suggesting an interaction between the bottom flow and the shape of the channel.
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  • 41
    Publikationsdatum: 2016-11-14
    Beschreibung: During the ARCTIC '91 expedition aboard RV Polarstern (ARK VIII/3) to the Central Arctic Ocean, a box corer sample on the Gakkel Ridge at 87 degrees N and 60 degrees E yielded a layer of sand-sized, dark brown volcanic glass shards at the surface of the sediment core. These shards have been investigated by petrographic, mineralogical, geochemical and radiogenic isotope methods. The nearly vesicle-free and aphyric glass shards bear only minute microphenocrysts of magnesiochromite and olivine (Fo(88-89)). Most glasses are fresh, although some show signs of incipient low-temperature alteration. From their shapes and sizes, the glass shards most likely formed by spalling of glassy rinds of a nearby volcanic outcrop. Geochemically, the glasses are relatively unfractionated tholeiites with E-MORB trace element compositions. Thus, they are quite similar to the previously investigated ARK IV/3-11-370-5 basalts from 86 degrees N. The Nd and Sr isotopic ratios of PS 2167-2 glasses are significantly lower than for ARK IV/3-11-370-5 basalts and suggest an isotopically heterogeneous mantle source of Gakkel Ridge MORE between 86 degrees and 87 degrees N. The positive Delta-8/4 Pb value (similar to 16) and high Sr-87/Sr-86 ratio (0.70270), found for PS 2167-2 glasses are similar to that of ARK IV/3-11-370-5 basalts and show the influence of the DUPAL isotopic anomaly in the high Arctic mantle. These results argue against the presence of an 'anti-DUPAL anomaly' in the mantle below the North Pole region and simple models of whole-mantle convection.
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  • 42
    Publikationsdatum: 2017-07-21
    Beschreibung: Live observations, cytological characteristics and biometrical measurements on Miliolinella subrotunda (Montagu, 1803) sampled from the northern and southern Atlantic Ocean are presented.M. subrotunda facultatively constructs a long, detritic tube lifting the test several millimeters above the sediment surface. A thickened conical base anchors the construction on the sediment surface and a long, flexible tube protrudes into the velocity profile of the bottom currents. The miliolid test is placed on top, surrounded by the uppermost part of the tube. This construction allows the organisms to feed in the particle stream above the sediment surface. In comparison to species living in and on the surface sediments,M. subrotunda apparently shows higher nutritional values in food ingested and larger amounts of reserve substances. Characteristics of the shape and structure that reduce drag on the tubes include a broadened conical base, a flexible tube, and a rounded top. From biometrical measurements it is concluded, that the tubes are constructed over a short period of their ontogeny.
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  • 43
    Publikationsdatum: 2017-10-05
    Beschreibung: Water samples from surface and bottom waters of two bights of the Baltic Sea were analysed for dissolved and/or particulate concentrations of Al, Cd, Co, Cu, Fe, Hg, Mn, Ni, Pb and Zn, in addition to the main oceanographic variables, at 27 stations during six cruises between February 1990 and July 1992. The metal values show distinct regional differences, with maximum concentrations at the near-shore stations, The levels of total Hg exhibit a significant negative relationship with salinity. In surface layers, seasonal differences due to biogenic uptake of elements could not be detected for any of the dissolved metals. In bottom waters, however, summer-time concentrations of a number of metals are in clear excess of winter levels either due to diffusion of metals (Go, Fe, Mn) from the sediments under low-oxygen or anaerobic conditions, or due to mineralization processes (Cd, Zn) of recently sedimented biogenic particulates. With the exception of Fe and Pb, the particulate fractions are of minor importance, with slight variabilities between the seasons only. The K-D values (ratio between metal concentrations in the particulate and dissolved fractions) decrease by more than two orders of magnitude in the order Fe-Pb-Mn-Co-Zn-Cd-Cu-Ni. Finally, the results are discussed with regard to a trace metal monitoring programme in the area.
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  • 44
    Publikationsdatum: 2016-11-14
    Beschreibung: The Houtman Abrolhos Islands, situated at the western passive margin of the Australian continent, consist of a series of shelf-edge coral reefs. The central platforms of the reefs are Late Pleistocene in age and are generally some 3–5 m above present sea level. The uppermost part of the Last Interglacial reefs normally has an upward-shallowing sequence, consisting of coral framestone, coralline algal bindstone and skeletal grainstone to rudstone. This sequence represents deposition in water depths of less than 2 m, and provides a good indicator of sea level. High-precision mass-spectrometric dates of corals from the Abrolhos reefs, including dates obtained from drill cores, arological, isotopic and stratigraphic criteria are established for the selection of suitable samples for dating and for assessing the reliability of dates. Using the screened dates and the stratigraphic evidence, the timing and character of the sea level variations of the Last Interglacial in the Abrolhos region are examined. The data show that sea level of the Last Interglacial in the Abrolhos was 4 m below its present height by ca. 134 ka BP and probably reached about 2 m above present height at ca. 133 ka BP. The exact time at which sea level reached its peak (6 m above present sea level) cannot be determined from our data. But it is clear that the sea level high stand of the Last Interglacial lasted until ca. 116 ka BP and that for much of the Last Interglacial sea level at the Abrolhos was at a height of about 4 m above its present level
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  • 45
    Publikationsdatum: 2019-01-22
    Beschreibung: The gene coding for the anion-specific porin of the halophilic eubacterium Ectothiorhodospira (Ect.) vacuolata was cloned and sequenced, the first such gene so analyzed from a purple sulfur bacterium. It encodes a precursor protein consisting of 374 amino acid (aa)-residues including a signal peptide of 22-aa residues. Comparison with aa sequences of porins from several other members of the Proteobacteria revealed little homology. Only two regions showed local homology with the previously sequenced porins of Neisseria species, Comamonas acidovorans, Bordetella pertussis, Alcaligenes eutrophus, and Burkholderia cepacia. Genomic Southern blot hybridization studies were carried out with a probe derived from the 5′ end of the gene coding for the porin of Ect. vacuolata. Two related species, Ect. haloalkaliphila and Ect. shaposhnikovii, exhibited a clear signal, while the extremely halophilic bacterium Halorhodospira (Hlr.) halophila (formerly Ect. halophila) did not show any cross-hybridization even at low stringency. This result is in good accordance with a recently proposed reassignment within the family Ectothiorhodospiraceae, which included the separation of the extremely halophilic species into the new genus Halorhodospira.
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  • 46
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    Elsevier
    In:  Chemical Geology, 103 (1-4). pp. 271-281.
    Publikationsdatum: 2015-11-24
    Beschreibung: Accurately weighed aliquots of the ∼ 500-Ma-old interlaboratory standard hornblende MMHb-1 were mixed with known quantities of a ∼ 100 Ma-old Himalayan biotite and subjected to normal Full-size image (〈1 K) incremental heating analysis. The addition of the biotite created monotonically increasing apparent ages, similar to profiles interpreted as showing Ar diffusive loss in the literature. The release of Ar from biotite dominates the low-temperature portion of the spectra and lowers the observed age. Lower Ca/K ratios in the first increments are consistent with contamination, but do not distinguish the composition of the contaminant phase. A large number of published amphibole “diffusive loss” profiles may, in fact, be due to contamination by biotite or other phases which release Ar at low extraction temperatures.
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  • 47
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    Elsevier
    In:  Quaternary Science Reviews, 16 (10). pp. 1115-1124.
    Publikationsdatum: 2016-09-19
    Beschreibung: Stable carbon and oxygen isotopes of the polar planktic foraminifera Neogloboquadrina pachyderma sinistral from sediment cores of the Norwegian Sea reveal several anomalous 13C and δ18O depletions in the surface water during the last glacial to interglacial transition and during the later Holocene. The depletions that are observed between the Last Glacial Maximum (LGM) and the end of the main deglacial phase were caused by massive releases of freshwater from thawing icebergs, which consequently resulted in a stratification of the uppermost surface water layer and a non-equilibrium between the water below and the atmosphere. At ~8.5 ka (14C BP) this strong iceberg melting activity ceased as defined by the cessation of the deposition of ice-rafted detritus. After this time, the dominant polar and subpolar planktic foraminiferal species rapidly increased in numbers. However, this post-deglacial evolution towards a modern-type oceanographic environment was interupted by a hitherto undescribed isotopic event (~7–8 ka) which, on a regional scale, is only identified in eastern Norwegian Sea surface water. This event may be associated with the final pulse of glacier meltwater release from Fennoscandia, which affected the onset of intensified coastal surface water circulation off Norway during a time of regional sea-level rise. All these data indicate that surface water changes are an integral part of deglacial processes in general. Yet, the youngest observed change noted around 3 ka gives evidence that such events with similar effects occur even during the later Holocene when from a climatic point of view relativelystable conditions prevailed.
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  • 48
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    Elsevier
    In:  Journal of Marine Systems, 10 (1-4). pp. 445-465.
    Publikationsdatum: 2017-06-26
    Beschreibung: Abundance, biofacies and ATP content of benthic foraminifera (〉63 μm) were studied in the Northeast Water (NEW) Polynya (77–81°N, 5–17°W) over the ice-free summer, 1993, to investigate how a polynya system might influence the underlying benthic community. In the living assemblage, distinguished by Rose Bengal staining, over 60 taxa could be identified. The biofacies identified was similar to that of other Arctic shelf habitats. Foraminifera were counted in 3 size fractions (63–125 μm, 125–250 μm and 〉250 μm), with 65% of the foraminifera occurring in the smallest size fraction (63–125 μm). Total abundances (〉63 μm) in the uppermost 1 cm averaged approximately 200 ind/10 cm3 and declined down-core, as did the number of species. Abundances and species composition correlated positively with sediment chlorophyll and ATP content, with maxima occurring in the shallower northern regions of the polynya, suggesting a general dependence on food. Foraminera biomass was estimated to be 0.1-0.3 g Corg/m2. Abundances, biomass and ATP content were comparable to ice-free, deep-sea regions in the Norwegian Sea. Temporal changes observed over a 2 month period at one location were difficult to distinguish from spatial and analytical variability. Contrary to expectations, growth was unpronounced at the community and at a species level, implying either a delayed response of the benthic foraminiferal community to food inputs from the overlying water column or the presence of biological limitations other than food, such as predation.
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  • 49
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    Elsevier
    In:  Journal of Marine Systems, 11 (3-4). pp. 269-278.
    Publikationsdatum: 2016-01-29
    Beschreibung: The present literature on biologically mediated fluxes from the benthic nepheloid layer (BNL) across the sediment-water interface into the sediment and vice versa is reviewed. The processes involved are categorised according to direct bioresuspension and biodeposition, i.e. direct interception of the animal with particles, and those effects, which are indirectly created by benthic organisms, e.g., changes of physical properties in the sediments, constructions like tubes and pits and the corresponding changes in hydrodynamic conditions. It is concluded that benthic organisms significantly increase the flux of particles across the interface and that the physically created fluxes are easily modified by a factor of 2 and more.
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  • 50
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    Elsevier
    In:  Palaeogeography, Palaeoclimatology, Palaeoecology, 130 (1-4). pp. 1-23.
    Publikationsdatum: 2017-01-23
    Beschreibung: The late Quaternary sedimentary history of the continental margin off Portugal was reconstructed from sediment gravity cores. Hemipelagic sedimentation (lithofacies A) was dominant during glacial times. It was interrupted periodically by deposition of shelf- and upper-slope-derived silty and sandy terrigenous material by dilute turbidity currents (lithofacies B and C), ice-rafted debris during distinct periods of breakdown of North Atlantic ice sheets (Heinrich events, lithofacies D) and large amounts of pteropods (lithofacies F). Settling of biogenic particulate material (lithofacies E) prevailed during the Holocene, when sea level and sea surface temperatures were high and terrigenous shelf-input was low. Downslope transport was dominant on the northern part of the Portuguese margin, culminating in frequent turbidity current transport between 35 and 70 ka. This may be due to a humid climate and a high fluvial input. Pteropod muds are confined to cores south of 41°N. Prominent peaks in pteropod concentration were radiocarbon dated at 17.8 and 24.6 ka. Layers rich in ice-rafted debris (IRD) were found along the entire margin. The base of these layers have been dated at 13.6–15.9 14C ka, 21.0–22.0 14C ka, 33.8 14C ka and ±64.5 ka, which correspond well with the ages of Heinrich events 1, 2, 4 and 6 in the central North Atlantic. Heinrich events 0 (10.5 ka), 3 (27 ka) and 5 (50 ka) rarely influenced sedimentation on the Portuguese slope. A mineralogical study of the IRD within Heinrich layers suggests that most icebergs were derived from the Laurentide Ice Sheet in the Hudson Strait and Hudson Bay area through the Labrador Current and the Canary Current and flowed in a southward direction along the margin. IRD from European ice sheets may have been mixed in during Heinrich event 6. On their way along the margin the icebergs lost much of their sediment load due to melting of the ice in a progressively warmer climate. The southernmost latitude studied (37°N) may be close to the southeastern extension of iceberg transport during Heinrich events.
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  • 51
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    Elsevier
    In:  Chemical Geology, 135 (1-2). pp. 21-34.
    Publikationsdatum: 2017-12-08
    Beschreibung: Quenched tholeiitic glasses and glassy rims of tholeiitic lava flows and pillow lavas from the neovolcanic rift zone on Iceland (Reykjanes and Hengill fissure swarms) contain olivine phenocrysts (Fo87–91) with abundant primary glass inclusions. These inclusions and host glasses were analyzed by ion microprobe for boron concentrations and isotopic compositions. Inclusions are believed to represent primary or near-primary mantle melts that have not been modified at shallow levels. Boron concentrations and B/K ratios in these melt inclusions are highly variable (0.18–1.35 ppm B, B/K = 2.8 × 10−4−6.1 × 10−3), whereas their δ11B values are nearly constant (−11.3, Full-size image (〈1 K)). This indicates that the Icelandic mantle is likely to have a constant boron isotope composition similar to that previously proposed for the primitive mantle (Full-size image (〈1 K)). The Hengill host glasses are characterized by low concentrations of B (0.26–0.42 ppm) and δ11B values similar to melt inclusions (−11.3, Full-size image (〈1 K)). In contrast, the Reykjanes host glasses have higher δ11B values (∼ −3‰) at the same relatively low concentrations of B (0.43–0.44 ppm), which are likely to be due to interactions of the ascending magmas with the crustal rocks hydrothermally altered at low temperatures by seawater-derived fluids. Boron concentrations and B/K ratios in melt inclusions and matrix glasses correlate with TiO2, K2O and P2O5 contents, and La/Sm)n ratios. Boron contents recalculated on the basis of melt inclusion compositions for the Icelandic mantle are slightly different for the Reykjanes and Hengill areas (0.21, 1σn ± 0.05 and 0.13, 1σn ± 0.03 ppm B, respectively). This is likely to reflect the presence of zones within the Icelandic mantle variously enriched and/or depleted in boron of similar isotopic composition.
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  • 52
    Publikationsdatum: 2017-09-26
    Beschreibung: Iron speciation was determined in hemiplegic sediments from a high productivity area to investigate systematically the early diagenetic reactivity of Fe. A combination of various leaching agents (1 M HCI, dithionite buffered in citrate/acetic acid, HF/H2SO4, acetic Cr(II)) was applied to sediment and extracted more than 80% of total Fe. Subsequent Fe species determination defined specific mineral fractions that are available for Fe reduction and fractions formed as products of Fe diagenesis. To determine the Fe speciation of (sheet) silicates we explored an extraction procedure (HF/H2SO4) and verified the procedure by application to standard rocks. Variations of Fe speciation of (sheet) silicates reflect the possible formation of Fe-bearing silicates in near surface sediments. The same fraction indicates a change in the primary input at greater depth, which is supported by other parameters. The Fe(II)/ Fe(III) -ratio of total sediment determined by extractions was compared with Mössbauer-spectroscopy ] at room temperature and showed agreement within 10%. M6ssbauer-spectroscopy indicates the occurrence of siderite in the presence of free sulfide and pyrite, supporting the importance of microenvironments during mineral formation. The occurrence of other Fe(II) bearing minerals such as ankerite (Ca-, Fe-, Mg-carbonate) can be presumed but remains speculative.
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  • 53
    Publikationsdatum: 2017-08-09
    Beschreibung: Oxygen isotope analyses of marine diatoms were performed in two independent ways. Stepwise fluorination of hydrous opal-A results in plateau δ180 values representing the isotopic composition of the silica frame oxygen. A method of controlled isotope exchange before silica dehydration also produces reliable results, although the exchangeability of the silica was variable. Consequently, a calibration of the isotope exchange method using the results from stepwise fluorination experiments is very useful (and sometimes essential) in order to select a water vapor of an appropriate isotopic composition to be used for equilibration. Sediment diatom samples Ethmodiscus rex and Thalassiothrix longissima from the Antarctic and the North Atlantic Ocean, respectively, show strong 180 enrichments of 46.8 and 44.1‰, which are caused by large isotope fractionation occurring at the low temperature prevailing during silica-water isotope exchange reactions. However, phytoplankton samples from surface waters of the Norwegian-Greenland Sea and the Bellingshausen Sea (Antarctica) have δ180 values between 30.4 and 35.0‰. Thus, the true silica-water isotopic fractionation is approximately 3 to 10‰ lower than the temperature-dependent silica-water equilibrium published in the literature for sedimentary diatoms. Our results indicate that successive isotope exchange reactions of diatomaceous silica with ambient seawater and/or pore water determine the isotope values of diatoms in sediments.
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  • 54
    Publikationsdatum: 2017-08-03
    Beschreibung: In situ oxygen fluxes were measured at vent sites in the Aleutian trench at a water depth of almost 5000 m using a TV-guided benthic flux chamber. The flux was 2 orders of magnitude greater than benthic oxygen fluxes in areas unaffected by venting on the continental margin off Alaska. Porewater profiles taken from the surface sediment below a vent site showed high concentrations of sulfide, methane, and ammonia. The reduced carbon and nitrogen compounds are transported to the vent site by fluids expelled from deeper anoxic sediment layers by the forces of plate convergence. The tectonically driven fluid flow was determined from the biochemical turnover in vent communities and was found to be 3.4 ± 0.5 m yr−1. A model was used to quantify the transport of silica, Ca2+, and sulfate via diffusion, advection, and bioirrigation through the surface sediments of a vent site. A nonlocal mixing coefficient of 20–30 yr−1 was determined by fitting the model curves to the measured porewater profiles showing that the transport of solutes within the near-surface sediments and across the sediment-water interface is dominated by the activity of the vent fauna. Sulfate-containing oceanic bottom water and methane-rich vent fluids were mixed below the clam colony to produce sulfide and a CaCO3 precipitate. The vent biota shape their immediate environment and control the sediment-water exchange and the benthic fluxes at vent sites. The oxygen consumption at vent sites is a major sink for oxygen at the study area.
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  • 55
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    Elsevier
    In:  Continental Shelf Research, 17 (14). pp. 1765-1784.
    Publikationsdatum: 2019-09-23
    Beschreibung: A combined 3-D physical oceanographic model and a field sampling program was performed in July and August 1994 to investigate the potential drift of larval Baltic cod from the center of spawning effort in the Bornholm Basin, Baltic Sea. The goal of this exercise was to predict the drift trajectories of cod larvae in the Bornholm Basin, thereby aiding in the development of future sampling programs as well as the identification of processes influencing larval retention/dispersion in the Bornholm Basin. Distributions of variables (T, S and larval distribution) were obtained utilizing a three-dimensional eddy-resolving baroclinic model of the Baltic Sea based on the Bryan-Cox-Semtner code. Larval drift was simulated by the incorporation of a passive tracer into the model utilized to represent individual cod larvae. Additionally, simulated Lagrangian drift trajectories are presented. For model purposes, initial fields of temperature, salinity and cod larvae concentration for the Bornholm Basin were constructed by objective analysis using observations taken during a research survey in early July, 1994. Outside the Bornholm Basin generalized hydrographic features of the Baltic Sea were utilized with the baroclinic model forced by wind data for the whole Baltic taken from the Europa-Modell (EM) of the German weather service, Offenbach. Verification of simulations was performed by comparison with field measurements of hydrographic variables and ADCP derived current measurements taken during the surveys. In general, most of the hydrographic features observed during the second research cruise are correctly simulated, with variations mainly attributed to the prescribed initial conditions outside the Bornholm Basin. Results from larval sampling during the second cruise could not entirely confirm the modeled larval distributions due to the low numbers of larvae captured. However, the modeled results based on the agreement of the flow fields and hydrographic properties with observed features suggest that predictions of larval distributions can be made with a high degree of confidence if appropriate larval behaviours are included in the simulations.
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  • 56
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    Elsevier
    In:  Geochimica et Cosmochimica Acta, 139 (1-4). pp. 287-297.
    Publikationsdatum: 2017-08-25
    Beschreibung: The dating of polymetamorphic rocks with the U-Pb zircon method often results in discordant data. Thus a new technique combining cathodoluminescence imaging (CL) and thermal ion mass spectrometry (TIMS) measurements was developed. Cathodoluntinescence-controlled UPb dating (CLC-method) works with bisected zircons and was successfully applied to the multistage S-type granitoids of the Swiss Silvretta nappe. CLC-method enables the resolution of the different anatectic events and later major overprints (Cambrian, Ordovician, Silurian) and gives information about the protolith (Archaean) of the investigated gneisses. This is achieved by conventional UPb dating of selected grains, recovered from the SEM (scanning electron microscope) mounts after cathodoluminescence (CL) imaging. Applying this new combination of two established techniques yields geologically meaningful UPb zircon ages even for complex polymetamorphic rocks.
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  • 57
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    Elsevier
    In:  Deep Sea Research Part I: Oceanographic Research Papers, 44 (8). pp. 1377-1403.
    Publikationsdatum: 2016-09-30
    Beschreibung: Particle flux data have been collated from the literature representing most areas of the open ocean to determine regional trends in deep water flux and its seasonal variability. Organic carbon flux data normalised to a depth of 2000 m exhibits a range of an order of magnitude in areas outside the polar domains (0.38 to 4.2 g/m2/y). In polar regions the range is wider (0.01–5.9 g/m2/y). Latitudinal trends are not apparent for most components of the flux although calcite flux exhibits a poleward decrease. Limited data from polar regions show fluxes of opaline silica not significantly higher than elsewhere. The variability of flux over annual cycles was calculated and expressed as a Flux Stability Index (FSI) and the relationship between this and vertical flux of material examined. Somewhat surprisingly there is no significant relationship between FSI and fluxes of dry mass, organic carbon, inorganic carbon or opaline silica. At each site, net annual primary production was determined using published satellite derived estimates. There is a negative but weak relationship between FSI and the proportion of primary production exported to 2000 m (e2000 ratio). The most variable of the non-polar environments export to 2000 m about twice as much of the primary production as the most stable ones. Polar environments have very low e2000 ratios with no apparent relationship to FSI. At primary production levels below 200 g C/m2/y there is a positive correlation between production and organic carbon flux at 2000 m but above this level, flux remains constant at about 3.5g C/m2/y. A curve derived to describe this relationship was applied to estimates of annual primary production in each of 34 of the open ocean biogeochemical provinces proposed by Longhurst et al. (1995). Globally, open ocean flux of organic carbon at 2000 m is 0.34 Gt/yr which is 1% of the total net primary production in these regions. This flux is nearly equally divided between the Atlantic, Pacific and Southern Oceans. The Indian and Arctic oceans between them only contribute 5% to the total. The eight planktonic climatological categories proposed by Longhurst (1995) provide a most useful means of examining the data on flux and its variability. A characteristic level of FSI was found in each category with highest levels in the tropics and lowest levels in the Antarctic. There is also a characteristic level of export ratio in each category with the highest in monsoonal environments (1.7%) and the lowest in Antarctica (0.1%)
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  • 58
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    Elsevier
    In:  Journal of Quantitative Spectroscopy and Radiative Transfer, 57 . pp. 767-794.
    Publikationsdatum: 2017-10-05
    Beschreibung: Since large, homogeneous dielectric particles have positive asymmetry parameters even when they are densely packed, it has been hypothesized that negative asymmetry parameters retrieved with Hapke's phenomenological model of bidirectional reflectance result from a complicated internal structure of planetary regolith particles. This paper tests that hypothesis by theoretically computing asymmetry parameters for isolated and densely packed composite spherical particles with size typical of regolith grains. It is assumed that the wavelength of the scattered light is much smaller than the particle size, and that particles are filled with large numbers of small inclusions. The computations show that it is essentially impossible to make asymmetry parameters of planetary regolith particles even slightly negative by filling the particles with large numbers of internal inclusions in the form of voids and/or grains with a refractive index substantially different from that of the host medium. Asymmetry parameters are positive even for densely packed composite particles with no internal absorption and extreme values of the internal scattering coefficient. Furthermore, they are sharply increased by even modest absorption inside composite particles, by reducing the refractive index contrast between the inclusions and the host particles, and/or by decreasing the packing density. Thus, the negative asymmetry parameters retrieved with Hapke's model need another explanation rather than assuming that they are real and are the result of a complicated internal structure of regolith particles. Besides the opposition-effect term, Hapke's model is nothing more than an approximate solution of the radiative transfer equation which inherently violates the energy conservation law. Therefore, the negative asymmetry parameters are likely to be numerical artefacts resulting from the approximations made in the model.
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  • 59
    Publikationsdatum: 2016-05-25
    Beschreibung: Oceanic and atmospheric circulation patterns varied considerably during the Tertiary and Quaternary and influenced the geochemical cycles of elements in seawater. We report the first resolution lead and neodymium isotopic record of such changes at a high time resolution in two depths profiles from a hydrogenous FeMn crust. The crust, Va13-2, is located in the central Pacific (146°W, 9°25′N, 4830 m) and has previously been dated by 230Th and 10Be. The first profile was drilled with a sample time resolution of ∼3 kyr and allows evaluation of short-term changes to lead and neodymium sources to central Pacific seawater over the last 400 kyr (marine δ18O stages 2 to 11). Longer-term changes were monitored at lower time resolution in a second profile to an age of 10 Ma. Short-term variations in lead and neodymium isotope ratios are resolved in the high resolution profile (0 to 400 kyr). Superimposed on the short-term variations is a secular decrease in Full-size image (〈1 K) ratios beginning at ∼130 kyr in marine δ18O stage 5, implying a change in the lead sources to the central Pacific. Lead and neodymium isotopic compositions indicate an increased influence from Central American eolian sources to Pacific seawater at this time. Lead isotopes are found to be statistically more variable during interglacial than glacial periods. These observations are supported by the greater eolian dust fluxes found in sediment cores from the equatorial Pacific during interglacial stages. The most important paleoceanographic event of the last 10 Ma to affect Pacific seawater was the closure of the Panama gateway. Changes in lead and neodymium isotopes in Val3-2 during the last 10 Ma occurred along with gradual closure of the Panama straits. However, these changes did not occur in tandem: while neodymium isotope ratios increase between 10 and 8 Ma, lead isotope ratios remain constant. In contrast, the period 7 to 1 Ma is marked by a secular increase in lead isotope ratios but nearly constant neodymium. These changes are consistent with a source of radiogenic lead and neodymium conveyed by the Circumpolar Current into the Pacific, rather than by the Panama gateway, and involve 20 to 40% Southern Component Water (SCW) input of lead and neodymium. Modelling of lead and neodymium isotopic mixing between the different water masses involved in generating Pacific deep waters lead us to the following conclusions: (1) Small variations in the strength and composition of North Atlantic Deep Water (NADW) have a relatively minor effect on the amounts of lead and neodymium from SCW contributing to the Pacific and (2) an enhanced SCW flow with an open isthmus of Panama, as suggested by General Circulation Models (GCM), requires a corresponding reduction in NADW Pb and Nd contributions to SCW. The general agreement between the isotopic compositions of surface layers of Mn nodules, integrated over such long time intervals, and those of present-day bottom waters at their respective locations show that the present-day ocean circulation pattern has dominated through the Pleistocene. Our study of Mn crust Va13-2 shows that shorter-term changes in lead and neodymium isotope ratios can be resolved, provided that such crusts are sampled at an appropriate time resolution.
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  • 60
    Publikationsdatum: 2017-09-26
    Beschreibung: Precise strontium isotope ratios, combined with chemical analyses and sedimentological information, are used to monitor the water sources and the evolution of the Dead Sea and its late Pleistocene precursor, Lake Lisan (70-18 kyr B.P.). The materials analyzed include bulk aragonite, water-leached soluble salts, and residual aragonite and gypsum from the Lisan Formation in the Perazim Valley (near the SW shore of the Dead Sea). The residual aragonite and the associated soluble salts display systematic fluctuations in 17Sr86Sr ratios between 0.70803 and 0.70806 and from 0.70805 to 0.70807, respectively. In individual soluble salt-residual aragonite pairs, the soluble salt displays a higher 87Sr86Sr ratio. Gypsum samples yield 17Sr86Sr ratios similar to the soluble salts from adjacent layers in the section. This shows that, in individual samples, the source of Sr in aragonite was distinct from that in soluble salts and the gypsum. The sterility of the Lisan sediments, their strictly nonbioturbated fine lamination, and their high content of chloride salts indicate that Lake Lisan was a saline, or even hypersaline water body. In the absence of alternative sources of HCO3− and S042− the abundance of primary aragonite and gypsum in the Lisan column reflects an import of very large volumes of freshwater into the otherwise saline lake, resulting in a density stratification of this water body. The history of the upper water layer and that of the lower brine is reflected in the chemical and strontium isotope composition of the aragonite and in that of the associated soluble salts and in the gypsum samples, respectively. Whereas the bicarbonate and much of the Ca2+ required for aragonite crystallization were supplied by the freshwater, the complementary Ca2+ (and Sr 2+) were added by the lower brine. The upper water layer of Lake Lisan acted as a SO42− capacitor during the lake's rise periods. It was removed therefrom, as prominent gypsum beds, upon climatic-induced (drier period) mixing or even complete overturn of the lake. The evolution of Lake Lisan took place between two distinct modes. The first was characterized by an extensive supply of freshwater and resulted in a rise of the lake's level, a (density) layered structure, and precipitation of aragonite. The second mode was marked by a diminishing freshwater input, resulting in mixing or complete overturn of its water, and precipitation of gypsum. These two modes reflect the climatic evolution of the region in the late Pleistocene which fluctuated between drier and wetter periods. The transition to the Holocene is accompanied by the dry up of Lake Lisan and its contraction to the present Dead Sea.
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  • 61
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    Elsevier
    In:  Deep Sea Research Part I: Oceanographic Research Papers, 40 (8). pp. 1547-1557.
    Publikationsdatum: 2016-10-19
    Beschreibung: Moored Acoustic Doppler Current Profilers (ADCPs) were used to analyse the daily vertical zooplankton migration and its seasonality. One-year records of vertical velocity and acoustic backscatter were obtained at four stations in the Greenland Sea. Both parameters exhibited a diurnal cycle typical for vertically migrating zooplankton. Upward and downward migration occured in short periods approximately 5 h long, and peak migration velocities were around 1.5 cm s−1. Similar structures were observed at all four mooring sites in the 200–300 m depth range. Farther down, between 1000 and 1400 m, no daily migration was observed. Strong seasonal variations are evident, and both the phase and intensity of the migration pattern change with daylight as the season progresses. In summer and during the polar night the migration became very weak and was only detectable in the displacement of scattering layers. When the day/ night contrast was large, intense upward or downward motion was accompanied by sloping backscatter isopleths. We observed two main scattering layers, a deep layer that varies in depth with season and an almost invariable shallow scattering layer at about 150 m depth. The deep layer was interpreted as the “resting depth” of the migrating plankter, and the latter as their “feeding horizon”. Changes in the “resting depth” from about 400 m in autumn and spring to about 200 m in winter lead to seasonal variations in the migration distance. This behaviour is discussed with respect to environmental conditions.
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  • 62
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    Elsevier
    In:  Sedimentary Geology, 82 (1-4). pp. 145-155.
    Publikationsdatum: 2016-09-07
    Beschreibung: 50 m of Middle Eocene pure radiolarian ooze were drilled at ODP Site 660 in the equatorial East Atlantic, 80 km northeast of the Kane Gap. The oozes comprise a 10 m high and 2 km broad mound of seismic reverberations, covered by manganese-rich sediment, and contain trace amounts of sponge spicules and diatoms, negligible organic carbon (0.15%), clay, and variable amounts of pyrite. The yellow to pale brown silty sediments are relatively coarse-grained (30–45% coarser than 6 μm), little bioturbated, and commonly massive or laminated on a cm-scale. The unlithified radiolarian ooze may indicate an interval of high oceanic productivity, probably linked to a palaeoposition of Site 660 close to the equatorial upwelling belt during Middle Eocene time. The absence of organic matter, however, and both the laminated bedding and the mound-like structure of the deposit on the lower slope of a continental rise indicate deposition by relatively intense contour currents of oxygen-rich deep water, which passed through the Kane Gap, winnowed the fine clay fraction, and prevented the preservation of organic carbon. The ooze may be either a contourite-lag deposit, or a contourite accumulation of displaced radiolarians, originating south of the Kane Gap and being deposited in its northern lee, thus documenting the passage of a strong cross-equatorial bottom-water current formed near Antarctica. These Eocene contourites may be an analogue for ancient radiolarites in the Tethyan Ocean.
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  • 63
    Publikationsdatum: 2017-09-26
    Beschreibung: Pelitic schists from the lower garnet to lower staurolite zones from the Rangeley, Perry Mountain, and Smalls Falls formations of western Maine were analyzed for major elements, trace elements, and neodymium isotopes. These formations were derived from highlands created during the Taconian orogeny, deposited into a trough, and metamorphosed during subsequent orogenic events. Most major and trace element abundances relative to Al2O3 were statistically identical between zones of the same formation, as well as between formations. Although the average major element composition of these formations are the same, there are systematic variations in some elements. Notably, plots of SiO2 vs. Al2O3 and K2O vs. Al2O3 suggest that most of the variation could be produced by mixing of a fairly constant ratio of clay minerals and feldspar with varied amounts of quartz due to sorting in the sedimentary system. Different amounts of these minerals should not influence the shape of the REE patterns of the metapelites, but higher amounts of quartz and feldspar may dilute the REEs and most elemental abundances of the clay minerals and lead to lower elemental abundances. The major difference between the samples within the Perry Mountain Formation are different LREE and MREE abundances relative to Al2O3 which are not correlated to differences in major element or other trace element abundances relative to Al2O3. The samples in the Perry Mountain with higher LREE and MREE abundances have, for example, 42.3 ± 8.3 ppm, and those with low abundances have 5.6 ± 3.6 ppm. The samples with the high REE abundances of the Perry Mountain Formation are similar in abundances and REE patterns to those of the Rangeley and Smalls Falls formations typical of mudstones derived from granitoids. Another difference between the low and high REE abundance samples are the calculated Tdm model ages. The high REE abundance samples of the Perry Mountain Formation show Tdm similar to the samples of the Rangeley Formation, with ages of about 1.7–1.8 Ga. The Perry Mountain samples with low REE abundances, however, give unrealistically old Tdms between 2.5 and 5.3 Ga. These unrealistically old Tdms are due to the relatively high Sm/Nd ratios (compared to crustal values) which are characteristic of samples of the Perry Mountain Formation with lower REE abundances. We therefore suggest that these samples may be indicators for open system behavior of the neodymium isotopic system. The timing of this disturbance of the neodymium isotope system is difficult to determine and cannot be tied to weathering or a definite postdepositional event. The complexities of the data suggest more than one resetting event. The most likely event that could have produced much of the movement of the LREEs and MREEs could have been due to small scale migration between anoxic hemipelagites and turbidite mudstones during diagenesis, but some migration may have continued during metamorphism in order to reconcile the neodymium isotopic data.
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  • 64
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    Unbekannt
    Elsevier
    In:  Deep-Sea Research Part II-Topical Studies in Oceanography, 44 (1/2). pp. 69-90.
    Publikationsdatum: 2016-10-10
    Beschreibung: High biogenic silica (BSi) concentrations (maximum: 11.7μmoll−1) were recorded during late November at the southern border of the Polar Frontal region (PFr). Position of the BSi maximum at depth suggested the occurrence of a sinking diatom population. By contrast, siliceous biomass was low (BSi 〈0.6 μmol l−1) in the Marginal Ice Zone (MIZ) despite a sea-ice retreat of 200 km during the study period. Diatoms released from the receding ice were not actively growing. The Permanently Open Ocean Zone also showed very low BSi biomass (〈0.5μmol l−1) and appeared as an area where phytoplankton are not dominated by siliceous organisms, especially in its middle part where BSi/POC (particulate organic carbon) molar ratios ranged between 0.04 and 0.06 at 53°S, from surface to 200 m depth. At the southern border of the PFZ, the bloom coincided with an area of high lithogenic silica concentrations probably of aeolian origin. In addition, BSi/POC molar ratios measured in the PFZ were the highest ever recorded in the surface waters of the Southern Ocean (maximum: 1.75). This could be due to the presence of heavily silicified diatoms such as Fragilariopsis kerguelensis or also could reflect the more rapid recycling of POC as compared to BSi. Within the bloom area BSi concentrations were positively correlated to pyrophaeophytin pigments, possibly indicating the occurrence of a senescent diatom population. High concentrations of BSi (〉 1.5 μmol Si 1−1) extended to 200 m between 49°S and 51°S. Numerous empty frustules also were observed, suggesting significant sedimentation of siliceous particles between 49°S and 51°S. Estimates of the BSi production of the Polar Frontal region are derived from 14C primary production and appropriate BSi/POC ratios, and implications for the total annual production of BSi for the Southern Ocean are discussed.
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  • 65
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    Elsevier
    In:  Marine Micropaleontology, 20 . pp. 215-234.
    Publikationsdatum: 2017-07-21
    Beschreibung: In situ observations of microhabitat preferences of living benthic foraminifera are presented from sediments of the Norwegian-Greenland Sea, the upwelling area off northwestern Africa and the shallow-water Kiel Bight (Baltic Sea). Certain foraminiferal species (e.g.Cibicidoides wuellerstorfi andRupertina stabilis) can be regarded as strictly epibenthic species, colonizing elevated habitats that are strongly affected by bottom water hydrodynamics. Large epibenthic foraminifera (e.g.Rhabdammina abyssorum andHyperammina crassatina) colonize the sediment surface in areas where strong bottom currents occur and might have by virtue of their own size an impact on the small-scale circulation patterns of the bottom water. Motile species changing from epifaunal to infaunal habitats (e.g.Pyrgo rotalaria, Melonis barleeanum, Elphidium excavatum clavatum, Elphidium incertum, Ammotium cassis andSphaeroidina bulloides) are regarded here as highly adaptable to changes in food availability and/or changing environmental conditions. This flexible behaviour is regarded as a dynamic adaptation to optimize food acquisition, rather than a static concept leading to habitat classification of these ubiquitous rhizopods.
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  • 66
    Publikationsdatum: 2017-06-23
    Beschreibung: The Houtman Abrolhos reefs, situated on the western continental margin of Australia, occupy a transitional position between cool-water shelf carbonate sediments to the south and more tropical environments to the north. Their existence at the outer limits of the geographical range for coral reef growth is a result of the warm, poleward-flowing Leeuwin Current. Though the modern reefs differ ecologically from tropical reefs, their geological characteristics have been little known until recently. Each of the three island groups in the Abrolhos consists of a central platform of Last Interglacial reefs, about which windward and leeward Holocene reefs have developed asymmetrically. In the Easter Group the subtidal windward reef in the west is ca. 10 m thick and is backed by a leeward-prograding, lagoon sand sheet which is 0–3 m thick. The emergent parts of the leeward reefs in the east consist of an upward-shallowing sequence comprising reef facies, peritidal rudstone facies, and coral rubble storm ridges. This is underlain by over 26 m of Holocene reef facies. Coring and dating of the Holocene reefs (using both TIMS and 14C methods) in the Easter Group has shown significantly different lithofacies in the windward and leeward reefs, and has allowed reconstruction of Holocene reef growth and sea-level history. Coralline algal bindstones and interbedded coral framestone facies characterise the relatively slow-growing windward Holocene reefs, whereas the fast-growing leeward reefs consist of coral framestone facies which are dominated by Acropora. The leeward reefs commenced growth about 10,000 years ago and the Morley reef grew to 0.3 m above present sea level by 6400 years B.P., recording a relative high sea-level event. This generated Holocene constructional topography characterised by “blue-hole” terrain. Windward Holocene reef growth commenced after 8200 years B.P. following erosion of the windward part of the Last Interglacial platform. High wave energy and competition with macroalgae limited coral growth, and the coralline algal-dominated windward reefs grew more slowly to sea level. The Holocene sea-level record provided by dates from the 26 m core of the Morley reef (a “keep-up” reef) is the first such record from the western continental margin of Australia.
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  • 67
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    Elsevier
    In:  Deep-Sea Research Part II-Topical Studies in Oceanography, 44 (1/2). pp. 23-50.
    Publikationsdatum: 2016-10-10
    Beschreibung: Small-scale features of the Antarctic Circumpolar Current (ACC) along a meridional section at 6°W between the Polar Front and the ACC-Weddell Gyre Boundary Front are discussed using data collected during the austral spring cruise ANT X/6 of R. V. Polarstern organized within the framework of the European IGBP-JGOFS (Southern Ocean). The section covered three distinct fronts, namely the Polar Front, the Southern Polar Front (also Southern ACC Front), and the ACC-Weddell Gyre Boundary Front. Physical measurements during repeated transects over a period of 6 weeks in October/November revealed a large variability in the Polar Frontal region, indicating meandering and eddy shedding. The positions of the Southern Polar Front and the ACC-Weddell Gyre Boundary Front were observed to be far more stable than that of the Polar Front. A possible reconstruction of the meandering flow field near the Polar Front, based upon the physical observations, is presented. Details in the flow field coincide with the spatial distribution of a number of biological parameters such as phytoplankton biomass and species, and photosynthetic pigments. Although a causal relationship between them is likely, biomass enhancement cannot be understood simply in terms of macronutrients from deeper layers entering the euphotic zone, as substantiated for other oceanic frontal regions, because macronutrients do not limit phytoplankton blooms. This process, however, can be important for the micronutrient iron. Evidence is presented that the Antarctic Zone of the ACC can be subdivided into a number of spheres of influence related to the fronts. Interleaving of water is apparent between positions within such a region, but not between the regions.
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  • 68
    Publikationsdatum: 2017-06-23
    Beschreibung: The Foundation Seamounts form a 1400 km-long chain on the Pacific plate from 32 °S, 127 °W to the Pacific-Antarctic spreading axis at 38 °S, 111 °W. Previously only known from sparse single-beam echosoundings and satellite altimetry, we present here the first multibeam bathymetric survey and geological sampling results. We confirm that the submarine topography correlates with the altimetry, and that the chain is volcanic rather than tectonic or microcontinental in origin. The chain can be divided up morphologically and geochemically into three section: (1) west of 125 °W large flat-topped volcanoes composed of incompatible-element depleted lavas ( ≈ 1) of a near-ridge origin with little or no plume influence, (2) between 125 and 115 °W true intraplate volcanoes with incompatible element enrichment ( 〉 1.9) generated over the Foundation plume, (3) east of 115 °W E-W-trending volcanic ridges with compositions ( 2.0-0.3) suggestive of interaction between the plume and the Pacific-Antarctic spreading axis. On the spreading axis moderate incompatible element enrichments ( ≈0.8, cf. ≈ 0.3 outside the Foundation area) also suggest plume influence. It appears that the activity of the Foundation plume in the last few million years has (1) significantly waned and (2) become wholly channeled towards the spreading axis. The Foundation plume may be in the process of “dying”.
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  • 69
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    Elsevier
    In:  Deep Sea Research Part II: Topical Studies in Oceanography, 40 (1-2). pp. 521-536.
    Publikationsdatum: 2019-01-21
    Beschreibung: During a R.V. Meteor JGOFS-NABE cruise to a tropical site in the northeast Atlantic in spring 1989, three different vertical regimes with respect to nitrate distribution and availability within the euphotic zone were observed. Besides dramatic variations in the depth of the nitracline, a previously undescribed nose-like nitrate maximum within the euphotic zone was the most prominent feature during this study. Both the vertical structure of phytoplankton biomass and the degree of absolute and relative new production were related to the depth of the nitracline, which in turn was dependent on the occurrence/non-occurrence of the subsurface subtropical salinity maximum (S(max)). The mesoscale variability of the nitracline depth, as indicated from a pre-survey grid, and published data on the frequent occurrence of the S(max) in tropical waters suggest higher variability of new production and F-ratio than usually expected for oligotrophic oceans. The importance of salt fingering and double diffusion for nitrate transport into the euphotic zone is discussed.
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  • 70
    Publikationsdatum: 2016-05-17
    Beschreibung: Al- and Ti-rich smectites associated with alkaline volcanic rocks were dredged during several cruises of the German research vessel “SONNE” as part of an extensive survey of manganese crusts in the Central Pacific seamount region. X-ray diffraction, chemical composition and infrared spectroscopy suggest that the smectites are constituents of the nontronite-beidellite solid solution series. X-ray fluorescence analyses yield considerable amounts of Al2O3 and Fe2O3 averaging 14.5 and 12.4 wt%, respectively. According to ASTM data the smectites are Al-rich nontronites rather than Fe-rich beidellites. A TiO2 content of up to 4.9 wt% is thought to be due to anatase impurities. δ18O-values in the range of +23.8 to +21.0‰ vs. SMOV indicate formation temperatures of 32–48°C. The rare-earth element patterns of the nontronitic smectites and associated alkaline volcanics are almost identical, showing a relative enrichment of light and a depletion of heavy rare-earth elements. It is concluded that the smectites formed as low-temperature alteration products during interaction of seawater with cooling basaltic/alkaline rocks rather than by mixing of hydrothermal fluids with seawater.
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  • 71
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    Elsevier
    In:  Marine Micropaleontology, 31 (3-4). pp. 157-175.
    Publikationsdatum: 2016-06-15
    Beschreibung: The Skagerrak basin is a deep water extension of the North Sea. It is of particular interest as an analogue for past epicontintal shelf basins because it presents environmental contrasts with the adjacent shelf seas. In this study the distribution patterns of benthic foraminifera have been used to infer taphonomic and oceanographic processes. Only by separating living from dead assemblages is it possible to interpret taphonomic changes. The transport of foraminiferal tests to the Danish slope is inferred from the presence there of dead exotic tests whose provenance is considered to be from the south. The abundance of detrital organic matter on the Danish slope is likewise inferred to be sourced from the same direction. Thus, the Danish slope is interpreted to be a depositional sink. Apart from transport, another taphonomic process is the dissolution of calcareous tests. This is clearly demonstrated both by the fragility of some tests as viewed under the microscope and by the disparity between the composition of the living and dead factor associations. In the deep basin in particular, the two predominantly calcareous living associations are replaced by a single predominantly agglutinated dead association due to carbonate dissolution. The Danish slope of the Skagerrak Basin is demonstrated to be an area of high benthic fertility. This is based on the high density of living (stained) benthic foraminifera (comparable with that of the Mississippi delta), particularly the abundance of Stainforthia fusiformis, an opportunistic species, and tubular agglutinated forms. The fertility is linked with the high abundance of particulate organic matter here. Previous regional studies have focused on total (living plus dead) distributions of 〉 100 or 〉 125 μm sized foraminifera. These factor assemblages are distinct from the 〉63 μm living and dead associations described here.
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  • 72
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    Elsevier
    In:  Earth and Planetary Science Letters, 119 (3). pp. 365-378.
    Publikationsdatum: 2016-07-19
    Beschreibung: Dissolved silica (Si) and inorganic germanium (Ge) concentrations were measured in hydrothermal fluids from black smoker vents on the East Pacific Rise (21°N EPR) and the Southern Juan de Fuca Ridge (45°N SJdFR: North and South Cleft Sites, Axial Volcano). These typically display end-member concentrations ranging from 16 to 23 mM (Si) and 150 to 280 nM (Ge), and end-member Ge/Si ratios clustering between 8 and 14 × 10−6, more than 10-fold greater than the ratio entering the ocean via rivers (0.54 × 10−6) and being recycled in seawater (0.7 × 10−6). ‘Excess’ concentrations of dissolved Si and Ge above oceanic background are observed in mid-water hydrothermal plumes over mid-ocean ridge (MOR) spreading centers on the Southern EPR (SEPR) (10°–20°S) and the SJdFR. The largest Si and Ge concentration anomalies occur over the North Cleft Segment of the SJdFR. These are a factor of three greater than anomalies over the SEPR (10°–20°S). Excess Ge correlates with excess3He in plumes at a Ge/3He molar ratio of about 1 × 104, approximately the same ratio as in black smokers. These observations, combined with low abundances of Ge in Fesingle bondMn-rich metalliferous sediments, suggest that Ge (and Si) behave conservatively in mid-ocean ridge hydrothermal plumes. A simple ocean Si and Ge balance, constrained by the global river silica flux and Ge/Si ratios in hydrothermal vents, rivers and biogenic silica, suggests that the global hydrothermal silica flux is about 1–4 × 1011 mole yr−1, much lower than that estimated from3He. Either (1) 70–80% of the Ge flux to the ocean is removed in as-yet undiscovered sinks (not opal), or (2) only 10% of the mantle to ocean3He and heat fluxes is associated with MOR hydrothermal convection through the 350°C isotherm (90% is off-ridge), or (3) the oceanic Ge/Si,3He/ (and87Sr86Sr) balances today are far from steady-state.
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  • 73
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    Elsevier
    In:  Deep Sea Research and Oceanographic Abstracts, 23 (7). pp. 613-628.
    Publikationsdatum: 2018-03-08
    Beschreibung: A complete set of linearly independent relationships among the different cross spectral components obtained from pairs of moored instruments is derived which can be utilized to test whether or not the observed fluctuations within the internal wave frequency band represent a field of propagating internal waves. A further complete set of relationships is derived which enables to test whether or not the internal wave field is horizontally isotropic and (or) vertically symmetric. These relations are compared with corresponding relations for alternative models (standing internal wave modes, three-dimensional isotropic turbulence) and their capability to discriminate between the various models is investigated. The tests are applied to a set of data for which it is found that the observed fluctuations are consistent with both propagating and standing internal waves whereas isotropic turbulence must be rejected for the most part of the internal wave frequency band.
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  • 74
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    Elsevier
    In:  Earth and Planetary Science Letters, 146 (1-2). pp. 47-58.
    Publikationsdatum: 2016-11-14
    Beschreibung: Data from the Nansen Basin of the Arctic Ocean are used to investigate the habitat and conditions under which the polar planktic foraminifer Neogloboquadrina pachyderma (sin.) calcifies. The vertical distribution of δ18O values of net-sampled speciments, together with their abundances and proportion of calcification, are compared with δ18O values from both water samples and foraminiferal tests from core-top sediments. Within the Nansen Basin the average depth of habitat of N. pachyderma (sin.) changes from about 150 m in the southern part to about 80 m in the northern. The average depth of calcification, however, in both regimes varies between 100 and 200 m water depth. δ18O data from net sampled N. pachyderma (sin.) are directly reflected in the core-top sediment data, but compared to equilibrium calcite δ18O values derived from measurements of the ambient water, a consistent offset of about 1‰ over all depth intervals is observed. While in the southern part of the Nansen Basin advection through Fram Strait of planktic foraminifers from further south may play a role, the data from the northern part of the Nansen Basin give clear evidence that the observed offset in δ18O values is caused by a vital effect of N. pachyderma (sin.).
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  • 75
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    Elsevier
    In:  Global and Planetary Change, 8 . pp. 1-8.
    Publikationsdatum: 2018-03-08
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  • 76
    Publikationsdatum: 2014-02-04
    Beschreibung: The chemical speciation of Cu, Ni, and Cr and the dissolved and unfiltered concentrations of Mo, Ti, Co, Fe, Mn, and Zn were determined in the water column of a lake with a seasonally anoxic hypolimnion (Esthwaite Water, Cumbria, UK) during three surveys in the summer of 1991. Cathodic stripping voltammetry (CSV) with ligand competition was used for this speciation study. The metal data, in conjunction with physical and nutrient data, were used to assess the biogeochemical processes controlling the distribution and speciation of the trace metals in the lake and their seasonal variation. Thermodynamic calculations were used to assess the dissolved trace metal speciation and the saturation state of metal-sulphide phases. The development of anoxia in the lake had an important influence on the redox speciation of dissolved Cr, with Cr(III) forming the major Cr species under anoxic conditions. Cobalt showed enhanced concentrations in the hypolimnion during anoxia, coinciding with enhanced Fe and Mn levels. Dissolved Cu, Ni, and Zn concentrations in the hypolimnion decreased during anoxia, which could possibly be explained by particle scavenging (iron sulphides) and a decline in hypolimnetic supply as the season develops. Regeneration processes of sunken organic detritus on the sediment-water interface were the most likely causes for enhanced hypolimnetic concentrations of Ni, Cu, and Zn, during periods when the lake was completely oxic. Substantial organic Ni and Cu complexation was observed in Esthwaite Water, which was attributed to the eutrophic character of the lake. Between 25 and 80 of the dissolved Ni in Esthwaite Water was strongly complexed by natural ligands. The highest proportions of Ni complexation were observed in the epilimnion and hypolimnion, with a minimum in the thermocline. Strong Cu complexing ligands were observed in the lake, with dissolved ligand concentrations between 6.8 and 29.4 nM and conditional stability constants between 10 11.1 and 10 14.4. More than 94 of the dissolved Cu in Esthwaite Water was complexed by the natural ligands. Copyright © 1997 Elsevier Science Ltd.
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  • 77
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    Elsevier
    In:  Deep-Sea Research Part II-Topical Studies in Oceanography, 44 (3-4). pp. 693-720.
    Publikationsdatum: 2014-02-04
    Beschreibung: The chemical speciation of dissolved Cr and Ni was measured onboard ship in the western Mediterranean Sea using cathodic stripping voltammetry (CSV) during the winter of 1992 and summer of 1993. Vertical profiles for dissolved Cr(III) in the water column showed concentrations between 0 and 1.4 nM, with highest concentrations in the surface layer, possibly caused by photochemical conversion of Cr(VI) to Cr(III) during summer periods and by atmospheric inputs during winter periods. Enhanced Cr(III) levels also were encountered in the deeper Mediterranean waters and were attributed to mineralisation of sinking biological material and diffusion from sediments. Dissolved Cr(VI) concentrations ranged between 2 and 3 nM, and total dissolved Cr concentrations between 2 and 3.5 nM. Lowest concentrations of total Cr and Cr(VI) occurred in the surface Atlantic waters and highest levels in the deeper Mediterranean waters. Total dissolved Ni concentrations ranged between 1.5 and 5 nM. Between 10 and 20 of the total dissolved Ni in the western Mediterranean appeared to be strongly organically complexed. Both labile and total dissolved Ni concentrations were lower in the surface Atlantic waters than in the Mediterranean deeper waters Little difference was observed between the data sets for winter and summer, indicating that the influence of seasonal changes on the speciation of Ni was small. A clear nutrient-like behaviour was not apparent for Ni and Cr, and their vertical and horizontal distributions were mainly determined by physical processes. Dissolved budget results for Cr and Ni for the Valdivia and Discovery (data in parentheses) cruises of -572 (55) and -439 (369) t yr-1 were calculated, indicating that the dissolved budgets for these elements were well balanced. The budget deficits and surpluses for dissolved Cr and Ni were small compared to the mass fluxes involved in the calculation of the mass balances.
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  • 78
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    Unbekannt
    American Chemical Society
    In:  Journal of Natural Products, 60 (9). pp. 874-879.
    Publikationsdatum: 2020-07-22
    Beschreibung: Seven new labdane diterpenoids, leopersin G−L (1−4, 6−7) and 15-epi-leopersin J (5), and two known ones, 13-hydroxyballonigrinolide (8) and ballotenol (9), were isolated from the aerial parts of Leonurus persicus along with β-sitosterol and stigmasterol. The structure determinations were mainly based on 1D and 2D NMR spectra. The stereochemical configuration of ballotenol (9) was reestablished by 2D ROESY spectroscopy and by single-crystal X-ray diffraction analysis.
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  • 79
    Publikationsdatum: 2013-07-16
    Beschreibung: In Eckernfoerde Bay in the western Baltic, an enclosed basin with organic-rich mud, acoustic turbidity has been observed since 1952. To investigate the relationships between acoustic properties and free gas we developed a method for rapid sub-sampling of gravity cores to determine the total methane content. From temperature measurements, determinations of the salinity of the pore water and data from the literature, saturation limits were calculated for each core. It is demonstrated that there is a certain amount of free gas in the mud of Eckernfoerde Bay but subbottom depths of the oversaturation and of the acoustic turbidity do not correspond. The existence of free gas implies the existence of bubbles in the sediment which are regarded to be responsible for the acoustic turbidity. Bubble sizes observed by X-ray computed tomography while still under in situ pressure and temperature vary between 1 and 10 mm equivalent diameter. The distribution of bubbles is discontinuous, occurring in depth zones from 2 to 20 cm thickness.
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  • 80
    Publikationsdatum: 2019-02-27
    Beschreibung: Résumé Quatre sites ont été forés dans le talus volcanoclastique sous-marin de l'île volcanique de Gran Canaria au cours du Leg ODP 157. La sédimentation du talus enregistre l'évolution volcanique de l'île. Les grandes phases éruptives s'expriment clairement par d'importants apports clastiques contemporains au niveau du talus. En revanche, les périodes d'inactivité volcanique se traduisent par des taux de sédimentation très faibles. II est possible ainsi d'établir un découpage volcanostratigraphique à partir des sédiments marins. Abstract Four sites have been drilled in the submarine volcaniclastic apron of the volcanic island of Gran Canaria during the ODP Leg 157. The volcaniclastic submarine apron reflects the volcanological evolution of the island. The main volcanic phases are recorded in the sedimentation by an important contemporaneous clastic influx on the apron. However, periods of volcanic quiescence are characterized by very weak sedimentation rates. Consequently, it is possible to establish a volcanostratigraphy from the sedimentary record of the apron.
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  • 81
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    Unbekannt
    Elsevier
    In:  Journal of Experimental Marine Biology and Ecology, 167 (1). pp. 91-108.
    Publikationsdatum: 2019-03-13
    Beschreibung: A mechanistic account of skeletal density band formation in massive colonies of Porites is developed by linking observations from vital staining of growing skeletons with measurements of density band characteristics, dissepiment spacing and the depth to which skeleton was occupied by tissue. Three growth processes contribute to density band formation. First, addition of new skeleton at the outer surface of the colony. Second, thickening of existing skeleton through the depth of the tissue layer (tissue usually occupies skeleton formed over the last 4–13 months). Third, the density pattern is then modified by periodic and abrupt uplift of the lower margin of the tissue layer which occurs about every 30 days. Uplift is associated with formation of new dissepiments and produces a fine density band at the lower margin of the tissue layer. Less regular, fine bands are formed within the tissue layer probably as a result of variations in calcification at the colonial surface. X-radiography of skeletal slices compresses and combines the results of these mechanisms making it difficult to distinguish the contribution of individual mechanisms to the overall X-ray image. The relative importance of the three mechanisms — extension, thickening and tissue uplift — to overall skeletal growth may differ between individual colonies. Variability in the way the mechanisms operate and combine may account for widely differing reports of coral density banding.
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  • 82
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    Unbekannt
    Elsevier
    In:  Computers and Geotechnics, 21 (3). pp. 163-182.
    Publikationsdatum: 2019-09-20
    Beschreibung: Inhomogeneities caused by end restraint and insufficient drainage during conventional compression triaxial tests are analysed by a numerical method. A finite element model is presented to simulate the testing procedure. The soil-platen interaction is represented by contact elements which allow frictional sliding between contacting nodes. The soil mass is represented by the modified Cam clay model. Coupled hydro-mechanical analyses are carried out in order to simulate both drained and undrained tests. The distributions of stresses and strains in the specimen for different end conditions are compared with the ideal case where no end restraint exists, in order to find representative measuring positions in the sample. Different rates of axial strain are tested in order to study the inhomogeneities caused by insufficient drainage during drained tests. Simulated results show that both end restraint and insufficient drainage can cause the barrel-shape deformation of the specimen. Stress-strain and strength properties based on global measurements are not a good representation of the true material behaviour of one single soil element at constitutive level.
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  • 83
    Publikationsdatum: 2019-07-01
    Beschreibung: A distinct porcellanite layer from the Southwest Indian Ridge intercalated in Pleistocene diatom ooze was studied using nondestructive physical property measurements and sedimentological data. This bed was sampled by two piston cores at a water depth of 2615 m. The 3–5 cm thick porcellanite layer appears in the cores at a depth of 6.03 m (Core PS2089-2) and 7.73 m (Core PS2089-1) below the seafloor. Due to its characteristic physical properties the porcellanite bed can be detected with core measurements, and its distribution and lateral extent mapped with echosounding. The physical index properties, wet bulk density and electrical resistivity, increase significantly across this bed. Magnetic susceptibility is used to compare the lithological units of both cores and to distinguish whether resistivity anomalies are caused by a higher amount of terrigenous components or by the presence of porcellanite. The porcellanite has the special characteristic to affect a positive anomaly in resistivity but not in susceptibility. Most marine sediments, in contrast, show a positive correlation of magnetic susceptibility versus electrical resistivity; therefore a combination of electrical resistivity and magnetic susceptibility logs yields a definite detection of the porcellanite bed. Images from the X-ray CT survey indicate that the porcellanite is lithified and brittle and fragmented when the piston corer penetrated the bed.
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  • 84
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    Unbekannt
    Elsevier
    In:  Continental Shelf Research, 17 (2). pp. 205-233.
    Publikationsdatum: 2019-09-23
    Beschreibung: Based on remote-sensing data and an expedition during August-September 1993, the importance of the Laptev Sea as a source area for sediment-laden sea ice was studied. Ice-core analysis demonstrated the importance of dynamic ice-growth mechanisms as compared to the multi-year cover of the Arctic Basin. Ice-rafted sediment (IRS) was mostly associated with congealed frazil ice, although evidence for other entrainment mechanisms (anchor ice, entrainment into freshwater ice) was also found. Concentrations of suspended particulate matter (SPM) in patches of dirty ice averaged at 156 g m(-3) (standard deviation sigma = 140 g m(-3)), with a background concentration of 5 g m(-3). The potential for sediment entrainment over the broad, shallow Laptev Sea shelf during fall freeze-up was studied through analysis of remote-sensing data and weather-station records for the period 1979-1994. Freeze-up commences on 26 September (sigma = 7 d) and is completed after 19 days (sigma = 6 d). Meteorological conditions as well as ice extent prior to and during freeze-up vary considerably, the open-water area ranging between 107 x 10(3) and 447 x 10(3) km(2). Ice motion and transport of IRS were derived from satellite imagery and drifting buoys for the period during and after the expedition (mean ice velocities of 0.04 and 0.05 m s(-1), respectively). With a best-estimate sediment load of 16 t km(-2) (ranging between 9 and 46 t km(-2)), sediment export from the eastern Laptev Sea amounts to 4 x 10(6) t yr(-1), with extremes of 2 x 10(6) and 11 x 10(6) t yr(-1). Implications for the sediment budget of the Laptev shelf, in particular with respect to riverine input of SPM, which may be of the same order of magnitude, are discussed.
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  • 85
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    Elsevier
    In:  Comparative Biochemistry and Physiology Part B: Biochemistry and Molecular Biology, 105 (1). pp. 183-192.
    Publikationsdatum: 2021-01-19
    Beschreibung: 1. The salivary enzymes of the octopus Eledone cirrhosa were separated using isoelectric focusing techniques (IEF) and HPLC. 2. The use of casein zymograms allowed the detection of at least 10 caseinolytic bands in analytical IEF gels and a preliminary, based on pI values, is described. 3. There appear to be two salivary chitinases. 4. Using HPLC, it was possible to separate the most cationic of these from the proteolytic enzymes of similar pI.
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  • 86
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    Unbekannt
    Elsevier
    In:  Marine Pollution Bulletin, 26 (12). pp. 683-686.
    Publikationsdatum: 2021-02-25
    Beschreibung: The Hg concentration in horned octopus was studied in relation to its biological cycle. The metal was measured in the muscle tissue of specimens of different size, sex and maturity. This species proved to be a strong accumulator of mercury, whose concentration was found to be correlated with length independently of the sex. The relationship with size was found also for the organic form. Consideration was given to the danger of frequent consumption of this cephalopod and to its use as a biomonitor of environmental mercury impact.
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  • 87
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    Unbekannt
    Elsevier
    In:  In: The biogeography of the oceans. , ed. by Gebruk, A. V. Advances in marine biology, 32 . Elsevier, San Diego, Calif., pp. 243-324, 82 pp. ISBN 0-12-026132-4
    Publikationsdatum: 2021-05-11
    Beschreibung: This review is based on the author's own data and all available published data (mostly Russian and Japanese) on the ecology, biogeography and role in the ecosystem of gonatid squids in the northern North Pacific. For the best studied species, Berryteuthis magister, information is given on size, horizontal and vertical distribution, diel and ontogenetic vertical migrations, maturation, mating, spawning, fecundity, population structure, age, growth, life cycle, horizontal migrations, underwater behaviour, food and feeding, and predators. The assessed biomass and its interannual dynamics and the fisheries importance are also covered. For other, less studied, species of the genera Berryteuthis (B. anonychus), Gonatopsis (three species) and Gonatus (seven species) all available ecological and biogeographical data are included. All species are compared according to their size, horizontal and vertical distribution, spawning habitats, diel vertical migrations and gelatinous degeneration associated with maturation. The “ecological individuality” of each species is evaluated. It is shown that each occupies its own ecological niche but these niches overlap to different degrees. The history of niche divergence in North Pacific gonatids during the Neogene-Pleistocene period is briefly reviewed. Common features are described of the horizontal and vertical distribution, relative abundance and biomass of North Pacific gonatids in general. Their roles in the ecosystem, as predators, prey, competitors and hosts of parasites is evaluated. The total biomass of gonatid squids in the whole subarctic North Pacific and the Russian Far Eastern seas is estimated as approximately 15–20 million t. They contribute some 10–15% of the total production of mesopelagic cephalopods in the World Ocean. Their yearly food consumption is assessed at 100–200 million t. The life cycle of gonatids is shorter and their P/B-coefficient much higher than that of subarctic mesopelagic fishes. As a result, though the squid biomass (calculations for the Okhotsk Sea) is less than 10% of the total mesopelagic fish and squid population, they form 58–67% of annual total fish and squid production. Thus gonatid squids have an important place in the ecosystem of the northern North Pacific and the Far Eastern seas of Russia.
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  • 88
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    Unbekannt
    Elsevier
    In:  Journal of Marine Systems, 13 (1-4). pp. 51-59.
    Publikationsdatum: 2021-04-16
    Beschreibung: The distribution at sea of seabirds was studied in the North-East Water (NEW) polynya, Greenland, during transect counts in the summers of 1991, 1992 and 1993 on board the ice-breaking RVs Polarstern and Polar Sea. Data collected within the polynya ‘box’ (78–82°N; 5–18°W) concern observations of 8000 birds counted during 1350 half-hour counts. Distribution is presented as density (N/km2) and calculated daily food intake. Five bird species were selected for discussion, representing more than 95% of the total numbers encountered: Fulmar (Fulmarus glacialis), Ivory Gull (Pagophila eburnea), Kittiwake (Rissa tridactyla), Glaucous Gull (Larus hyperboreus) and Ross's Gull (Rhodostethia rosea). For these species, densities are comparable in the NE Greenland polynya and in other European Arctic seas. The main difference is the absence in NEW of the species playing the main role in Arctic seas: Brünnich's Guillemot (Uria lomvia) and Little Auk (Alle alle). In the absence of fish-eating birds and of birds consuming zooplankton in the water column, the NEW polynya ecosystem is thus dominated by surface feeders and, closer to the coast, by benthic feeders like eiders, Somateria mollissima and S. spectabilis, and walrus, Odobenus rosmarus. The density and daily food intake for all seabirds are one order of magnitude lower in the polynya than in the Arctic seas. The distribution and abundance of seabirds in the NEW polynya seems to reflect a very low density of pelagic fish and Zooplankton in the water column, while Zooplankton must be present at ‘normal’ concentrations in the upper layer.
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  • 89
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    Unbekannt
    Elsevier
    In:  Fisheries Research, 33 (1-3). pp. 139-147.
    Publikationsdatum: 2021-04-21
    Beschreibung: Diet and feeding habits of the short-finned squid Illex argentinus were studied from the analysis of 729 stomachs of juveniles, subadults and adults caught with trawls on the continental shelf and slope off southern Brazil (26 °35′S–34 °31′S) from 1981 to 1992. Food, in different degrees of digestion, was found in 363 stomachs (49.8%). Feeding activity occurred at day and night and seemed to be most intense at dusk and early night. The proportion of stomachs with food increased with size and sexual maturity. Fish occurred in 43.8%, cephalopods in 27.5% and crustaceans in 18.7% of the stomachs with food. Identified prey included the fish Diaphus dumerilii, Maurolicus muelleri and Merluccius hubbsi, the cephalopods I. argentinus, Loligo sanpaulensis, Spirula spirula, Semirossia tenera and Eledone gaucha and the crustaceans Oncaea media and Euphausia sp. The occurrence of fish increased with squid size, but both cephalopods and crustaceans were equally important for all sizes. Cannibalism was observed at all sizes. The overall low proportion of stomachs with food, the high rate of cannibalism and the low frequency of occurrence of crustaceans for the juveniles and subadults in all seasons, but particularly in the summer and autumn, may reflect a limited availability of food in the region. If this is true, the main nursery grounds for the spawners off southern Brazil are likely to be off the Rio de La Plata Front or in the offshore confluence between the Brazil and Malvinas Currents, where primary and secondary production is higher than off southern Brazil.
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  • 90
    Publikationsdatum: 2021-04-30
    Beschreibung: This paper presents data on the diet of the squid, Loligo vulgaris (Lamarck, 1799) from the south coast of Portugal (Algarve) and from the Saharan Bank (Central-East Atlantic). A total of 964 squid was collected from the Algarve coast, between March 1993 and October 1994, from bottom trawling. An additional sample of 70 stomachs was obtained in the Algarve coast from the hand jigging fishery during 1991 and 1992. In the Saharan Bank, 848 squid were obtained, between June 1993 and January 1994, with bottom trawling. Stomachs with contents for trawled squid from the Algarve coast, and the Saharan Bank represented 28.1% and 40.8%, respectively. Fish was always the main component of the diet in both regions, representing 88.6% of the total weight of the prey found in the stomachs, for the Algarve coast, and 70.9% for the Saharan Bank. The occurrence percentage and the percentage in number indicated that Trachurus trachurus and fish belonging to the family Gobiidae were the most frequent fish found in the Algarve samples, while flatfish were the most common fish in the Saharan Bank samples. Loligo vulgaris was the dominant cephalopod found in the stomachs for both regions. No differences in the diet were found between males and females. The comparison between immature and mature squid showed that the importance of fish was higher in mature squid, for both regions. The squid captured from the Algarve coast by bottom trawling (at greater depths and offshore) fed primarily on fish, while those captured with hand jigging (inshore, at lower depths) contained an important percentage of crustaceans.
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  • 91
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    Unbekannt
    Elsevier
    In:  Marine Pollution Bulletin, 34 (4). pp. 250-258.
    Publikationsdatum: 2021-02-22
    Beschreibung: Residue levels of persistent organochlorines in deep-sea organisms collected from Suruga Bay, Japan, were determined. PCBs (polychlorinated biphenyls) were the predominant group of organochlorines ranging in concentrations from 380 to 2800 ng g−1 on a lipid weight basis. DDTs (DDT and its metabolises) were the next most abundant organochlorine compounds followed by CHLs (chlordane compounds), HCHs (hexachlorocyclo-hexanes) and HCB (hexachlorobenzene). In comparison with coastal shallow water organisms, higher concentrations of HCHs were found in deep-sea organisms, while no significant difference was noted for other organochlorines. Organochlorine residue levels in Suruga Bay were comparatively lower than those in other deep-sea organisms reported elsewhere. The deep-sea organisms showed no consistent trend between organochlorine concentrations and food chain relationships. Lipid-dependent accumulation of organochlorines by equilibrium partitioning may be attributable to this residue pattern. Among DDT compounds, p,p′-DDE was the highest in most deep-sea organisms. Trans-nonachlor and β-HCH were the major constituents of CHLs and HCHs, respectively, in these organisms.
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  • 92
    Publikationsdatum: 2021-04-30
    Beschreibung: Longitudinal sections of statoliths were observed by light microscopy on 237 individuals (158–510 mm mantle length, ML) of Ommastrephes bartrami, obtained from the North Pacific (26 °–46 °N, 143 °E–149 °W) during 1991–1994. The width of each increment sharply decreased from 5–7 μm to about 1–2 μm between the 80th and 100th increment, with a transition zone where increments were inconspicuous. ML-age relationships were linear, and slope and intercept values differed by geographic area, hatch season and sex. Overall growth rates (mm day−1) were generally higher in females (1.1–2.5) than in males (1.1–2.1). Since these values were similar to the growth rates of four individuals which were tagged and recaptured (0.8–2.4), the increments were assumed to be formed daily. The growth rate was highest for individuals hatched in summer, followed by those hatched in spring. Growth rate obtained by length-based methods may be underestimated. The hatch dates of neon flying squid are almost year-round, and the life span is likely 1 year since mature individuals were 7–10 months old.
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  • 93
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    Unbekannt
    Elsevier
    In:  Nuclear Instruments & Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, 130 (1-4). pp. 374-380.
    Publikationsdatum: 2021-07-07
    Beschreibung: Distribution of elements in statoliths of squid Loligo vulgaris reynaudii d'Orbigny, 1845 was studied, using the true elemental imaging system (Dynamic Analysis) of the NAC nuclear microprobe. The analysis revealed various patterns of Ca and Sr distributions. The biological interpretation of the most frequent pattern is linked with the role of Sr in the statolith deposition process. Other patterns are linked with the technique used and the specific characteristics of the sample. Traces of other elements (Cr, Mn, Fe, Cu, Zn, Br, Pb) were also found. Likewise, their presence may have the biological interpretation (Zn, Cu and Br), or is an artefact linked to the methods and conditions of sample preparation and/or analysis. Methodical aspects of using proton backscattering for PIXE X-ray yield corrections are also discussed.
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  • 94
    Publikationsdatum: 2016-11-14
    Beschreibung: U/Th (TIMS) and 14C (AMS) measurements are presented from two coral cores from the Easter group of the Houtman Abrolhos Islands between 28°S and 29°S on the western continental margin of Australia. The U/Th measurements on the Morley core from Morley Island cover a depth interval from 0.2 m above present sea level to 24.4 m below present sea level and comprise eleven samples. The ages vary between 6320 ± 50 a, at 0.2 m above sea level, and 9809 ± 95 a, at 24.4 m below sea level (all errors are 2σ). The mean growth rate is 7.1 ± 0.9 m/ka. The 14C dates of selected Morley core corals show that the 14C ages are ∼ 1000 a younger than their corresponding U/Th ages, which agrees with previous results. The main purpose of our 14C measurements is to be able to compare them precisely with other coral cores where no U/Th measurements are available. The U/Th measurements of the Suomi core from Suomi Island cover a depth interval from 0.05 m to 14.2 m below present sea level and consist of four samples. The ages vary between 4671 ± 40 a, at 0.05 m below sea level, and 7102 ± 82 a, at 14.2 m below sea level, with a mean growth rate of 5.8 ± 0.2 m/ka. The growth history of both cores is explained by a simple model in which the growth rates of the Morley core can be interpreted as reflecting local rates of sea level rise, whereas the Suomi core is interpreted as reflecting lateral growth during the past ∼ 6000 a. Our results indicate that sea level relative to the western margins of the Australian continent was about 24 m lower than present at about 9800 a B.P. (14C gives a date of 8500 a B.P.). Sea level then rose and reached a highstand, slightly higher than the present position at about 6300 a B.P (14C date: 5500 a). This highstand declined but was still higher than present at 4600 a B.P. This is in agreement with previous observations along the Australian coastal margins and with observations from the Huon peninsula (Papua New Guinea). Our results are very similar to theoretical numerical models, which take into consideration water loading and isostatic compensation and viscous mantle flow. In contrast, coral cores from Barbados show that corals with a 14C age of ∼ 5500 a B.P. are some ∼ 10 m b.p.s.l. We interpret the difference between the Barbados core and the Morley core as resulting from additional “flooding” of Barbados by water redistribution, due to changes in the Earth's geoid but not reflecting global sea level rise or major addition of melt waters over the past ∼ 6000 a. The difference in the geoid at Barbados between ∼ 6000 a B.P. and the present will require a refinement in the geophysical models. Precise230Th (TIMS) measurements on continental coasts will be required to provide an adequate data base for modelling deformation, flow of mantle material and sea-level height
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  • 95
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    Elsevier
    In:  Deep-Sea Research Part II-Topical Studies in Oceanography, 44 (1-2). pp. 341-354.
    Publikationsdatum: 2016-10-10
    Beschreibung: Concentrations of dissolved organic carbon (DOC) and nitrogen (DON) were measured during early austral Spring 1992 at a number of stations along the 6°W meridian between 47° and 60°S. This included the Polar Front in the north, the zone of melting sea-ice in the south, and waters of the Antarctic Circumpolar Current in between. Concentrations of DOC were low in deep water (34–38 μM) with generally similar or slightly higher values in the surface mixed layer (38–55 μM). DOC:DON ratios are wider in surface water than in deep water, i.e. surface accumulations contain relatively C-rich dissolved organic matter. The highly variable distribution of the surface DOC was not related to hydrographic or biotic features (fronts, plankton development) indicating the lability and transient occurrence of this material. Growth rates of bacteria were determined in subsamples from 51 0.8-μm-filtered batches of seawater incubated in the dark at in-situ temperature. Thymidine and leucine uptake and bacterial biomass change as well as changes in dissolved organic carbon in the batches, and oxygen consumption in parallel incubations correlated linearly over 2 weeks of incubation which allowed extrapolation to in-situ conditions. Bacterial growth in these experiments depended strongly on the amount of initial DOC. Growth in water from greater depth (1000 m) containing 38 μM DOC was minimal, as were DOC-decrease and oxygen consumption. Higher rates were observed in surface water slightly enriched with DOC, and highest rates in surface water amended with DOC-rich melted sea ice. Bacterial growth efficiencies (biomass C-increase vs DOC consumed) were about 30%. The experiments showed that at least 40–60% of the DOC in excess of deep water concentrations was available to bacteria.
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  • 96
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    Elsevier
    In:  Deep Sea Research Part I: Oceanographic Research Papers, 40 (4). pp. 727-737.
    Publikationsdatum: 2019-09-23
    Beschreibung: Coupling between surface water plankton and abyssal benthos was investigated during a mass development of salps (Salpa fusiformis) in the Northeast Atlantic. Cyanobacteria numbers and composition of photosynthetic pigments were determined in faeces of captured salps from surface waters, sediment trap material, detritus from plankton hauls, surface sediments from 4500–4800 m depth and Holothurian gut contents. Cyanobacteria were found in all samples containing salp faeces and also in the guts of deep-sea Holothuria. The ratio between zeaxanthin (typical of cyanobacteria) and sum of chlorophyll a pigments was higher in samples from the deep sea when compared to fresh salp faeces, indicating that this carotenoid persisted longer in the sedimenting material than total chlorophyll a pigments. The microscopic and chemical observations allowed us to trace sedimenting salp faeces from the epipelagial to the abyssal benthos, and demonstrated their role as a fast and direct link between both systems. Cyanobacteria may provide a simple tracer for sedimenting phytodetritus.
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  • 97
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    Elsevier
    In:  Deep Sea Research Part II: Topical Studies in Oceanography, 44 (1/2). pp. 261-282.
    Publikationsdatum: 2020-08-05
    Beschreibung: The development of phytoplankton biomass and composition was investigated on three occasions along a longitudinal transect (6°W) between 60°S and 47°S from October 13 to November 21, 1992 by measurement of photosynthetic pigments with high performance liquid chromatography (HPLC). Measured accessory pigment concentrations were multiplied by conversion factors to derive the proportions of phytoplankton groups contributing to the biomass indicator chlorophyll a. Phytoplankton blooms developed in the Polar Frontal region (PFr) and were dominated (80%) by diatoms. Other groups contributing to the phytoplankton included prymnesiophytes, green algae, autotrophic dinoflagellates, cryptophytes, pelagophytes and micromonadophytes, and their distributions varied with time. In contrast, phytoplankton biomass remained low in the southern Antarctic Circumpolar Current (ACC) and was dominated by flagellates, particularly green algae and prymnesiophytes. Green algae contributed more to total biomass than in previous investigations, partly attributed to “Chlorella-like” type organisms rather than prasinophytes. Cryptophytes decreased during the investigation, possibly due to salp grazing. No bloom was observed at the retreating ice-edge, presumably due to strong wind mixing. Only a slight increase in phytoplankton biomass, composed primarily of diatoms, was found at the ACC-Weddell Gyre front. Cluster analysis revealed that different phytoplankton communities characterised the different water masses of the PFr and southern ACC; the history of different water masses in the PFr could be reconstructed on this basis.
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  • 98
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    Elsevier
    In:  Journal of Marine Systems, 10 . pp. 199-209.
    Publikationsdatum: 2017-06-26
    Beschreibung: The Northeast Water Polynya has been suggested as acting as a sink for carbon, especially during the spring and summer when phytoplankton growth is active. During 1993 the polynya was sampled for the entire growing period (late May through mid-August) in order to more accurately assess the magnitude, controls and patterns of new and total (ammonium, nitrate and urea) nitrogen production. This represents the first assessment of new production throughout an entire season in the Arctic. We found that, in 1993, new production, based on 15N-tracer techniques and integrated over the euphotic zone, was 0.141 mmol N m−2 h−1 (0.361 g C m−2 d−1 when converted using observed C/N ratios). Measured f ratios averaged 0.65 and demonstrate that the system, to a great extent, was using nitrate as a nitrogen source. In general f ratios were greatest early in the season and minimal in mid-summer. Urea uptake was highly variable and contributed slightly less than ammonium to phytoplankton nitrogen demand. Nitrate uptake at stations with low (〈 0.5μM) nitrate concentrations was significantly reduced, implying that nitrate concentrations limited phytoplankton growth late in the growing season. Long-term new production rates calculated from nutrient depletion patterns from the polynya as a whole as well as a time-series constructed from a single location were ca. 0.144-0.281 g C m−2 d−1. The relationship between new production as measured by incubations and nutrient depletion budgets suggests that phytoplankton growth is the dominant factor influencing the nitrogen budget of the polynya. The amount of material available for removal from the euphotic zone is limited and constrains the degree to which the polynya can act as a regional carbon sink.
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  • 99
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    Unbekannt
    Elsevier
    In:  Earth and Planetary Science Letters, 116 (1-4). pp. 81-99.
    Publikationsdatum: 2016-11-14
    Beschreibung: Seabeam mapping in the central Pacific Ocean, southeast of Pitcairn Island, has revealed a number of large volcanic edifices, some of which appear to be currently active. Here we document the first isotope and trace element data obtained for dredge samples from these volcanoes which are believed to represent the present-day surface expression of the Pitcairn mantle plume. Striking linear trends in multi-isotope plots suggest the operation of a simple two-component mixing process in the genesis of these lavas with end-members of extreme EM-I and isotopically more depleted type. Isotope-trace element covariations allow limits to be placed upon the composition of the Pitcairn plume source, which is then compared with other EM-type oceanic islands. Current hypotheses for the generation of EM components are then evaluated in the light of these data. Temporal trends, similar to those seen on Pitcairn Island, are present within the seamount data, although samples equivalent to the post-shield formations on Pitcairn Island are not observed. These evolutionary trends suggest a high level origin for the depleted component rather than entrainment of asthenospheric material into a rising diapir. Three of the Pitcairn seamounts are much older, in the region of 20–25 Ma, and were probably formed in a near-ridge environment.
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  • 100
    Publikationsdatum: 2016-11-14
    Beschreibung: The reconstruction of geomagnetic field intensity variations during the last 200 kyr from paleomagnetic data is at present the subject of numerous studies and major debate. There is currently no generally accepted record. Here we present a global stacked record of (230Thex-normalized)10Be deposition in marine sediments representing relative variations in 10Be production rate which are translated into field intensity variations. The record shows major periods during which the field intensity was between 10% and 40% of the present day value; namely 30–42, 60–75, 85–110 and 180–192 kyr B.P. Our results are compared to independently derived paleomagnetic studies and Th/U calibrations of 14C dates on corals. During most of the observed period the geomagnetic field intensity was weaker than today, resulting in an overall 30% reduced value for the last 200 kyr.
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