ALBERT

Description: Using the fault plane mechanisms of the shallow earthquakes occurring along the Hellenic arc and the extent of the intermediate seismic belt, we make a quantitative estimate of the relative motion occurring between the Hellenic arc and the adjacent sea floor. This estimate is then used to evaluate the deformation in the Aegean area and to reconstruct the pattern of motion over the Eastern Mediterranean region for the last 13 m.y. It is shown that this pattern is compatible with the neotectonic and seismicity studies in Aegea. We then discuss the dynamics of the area and propose that, since Serravallian-Tortonian time, Aegea has been spreading gravitationally in front of the southwestward advancing Turkey. The reasons for this gravitational spreading are discussed.

Description: Data gathered by recent “Islas Orcadas” cruises reveal the seafloor spreading pattern for a region south of the Agulhas/Falkland fracture zone system. The presence of a magnetic anomaly bight about the Agulhas Plateau indicates that the Agulhas Plateau may have developed at the site of a tectonic plate triple junction during the Late Cretaceous. A westward jump in the seafloor spreading center during the Late Maestrichtian (anomaly 34−31) reduced the offset across the Falkland/Agulhas fracture zone system and resulted in the formation of two conjugate aseismic ridges here described as the Meteor and Islas Orcadas Rises. The magnetic lineation pattern in the Agulhas Basin suggests that a tectonic plate (Malvinas Plate) existed during Campanian to Maestrichtian times. Relative rates of motion are calculated for Antarctica, South America, and Africa for the Late Cretaceous.

Description: This chapter discusses the carbon turnover, calcification, and growth in coral reefs. Carbon turnover within a total reef community is a function of two distinct, biochemically interacting cycles. The first is the metabolic cycle consisting of the photosynthetic fixation of CO2 and the release of CO2 by respiration and decomposition processes. Superimposed on this are the direct incorporation of organic compounds (dissolved or particulate; living or non-living) originating outside the reef systems (in the adjacent ocean waters), and the loss of organic compounds from the reef system into the out-flowing water. The second is the inorganic carbonate cycle involving the biological and non-biological precipitation and dissolution of carbonates. Superimposed on this is the loss of particulate carbonates in suspension in the out-flowing water. The main chemical component of a coral-reef system is calcium carbonate, which occurs either as high-Mg calcite, aragonite, or low-Mg calcite. The mean calcification values in various environments at One Tree Reef are presented in the chapter. These data may be converted to an implied vertical growth rate potential assuming that accrual is dominantly aragonite (density = 2.89 g cm–3) and that there is 50% porosity after normal compaction.

Description: Microbial decomposition of organic matter in recent sediments of the Landsort Deep—an anoxic basin of the central Baltic Sea—resulted in the formation of a characteristic assemblage of authigenic mineral precipitates of carbonates, sulfides. phosphates and amorphous silica, The dominant crystalline phases are a mixed Mn-carbonate [(Mn0.85Ca0.10Mg0.05)CO3]. Mn-sulfide [MnS] and Fecarbonate [FeCO3]. Amorphous Fe-sulfide [FeS]. Mn-phosphate [Mn3(PO4)2] and a mixed Fe-Ca-phosphate [(Fe0.86Ca0.14)3(PO4)2] were identified by their chemical compositions only. The variability in composition of these solid phases and their mode of occurrence as a co-existing assemblage constrains the conditions and solution composition from which they precipitated. Estimates of activities for dissolved Fe. Mn. PO4, CO3 and S in equilibrium with such an assemblage are close to those found in recent anoxic interstitial water-sediment systems. It is important to have detailed knowledge of the composition and stability conditions of these solid precipitates in order to refine stoichiometric models of interstitial nutrient regeneration in anoxic sediments.

Description: Goban Spur lies on the continental margin of northwest Europe, southwest of Ireland. It is a marginal plateau underlain by Hercynian granites and Palaeozoic sediments, which form large horsts, grabens and tilted fault blocks with a trend that is approximately parallel to the main Celtic/Armorican Shelf edge. The spur is thought to be a westward continuation of the buoyant Cornubian Ridge, and is bounded to the north and south by large fault lines which probably represent reactivation of Hercynian structural trends. The continental basement is further divided longitudinally into a low-lying outer zone (Intermediate Zone) and a high inner region (Goban Spur proper). The ocean/continent boundary is thought to lie at the outer edge of the Intermediate Zone, Sea-floor spreading anomalies immediately west of the Intermediate Zone suggest that the adjacent ocean crust was created prior to anomaly 33 (say at ca. 90 m.y. B.P.). The sedimentary sequence on Goban Spur can be subdivided into four layers which can be tentatively correlated with the stratigraphic succession on the Meriadzek Terrace (IPOD sites). Such a correlation suggests that the lowermost sediment layer (?Jurassic-Albian) represents a tectono-sedimentary rift infill, and that Layers 2–4 (Upper Cretaceous to Quaternary) were deposited during slow epeirogenic downwarping of the plateau and that the sedimentary processes involved both draping and strong current moulding. The relatively buoyant nature of Inner Goban Spur has inhibited the accumulation of a thick post-rifting sedimentary sequence (700–1000 m), and has shielded the Intermediate Zone from downslope mass movements of material. This has resulted in the accumulation of an anomalously thin post-rift stage outer margin sediment prism (ca. 1000 m) compared to most continent rises (up to 10 km).

Description: A bathymetric map of the deep-sea floor off southeastern Africa shows the Agulhas Plateau to be separated from the continental margin of southeastern Africa by a narrow (50 km) elongate depression, the Agulhas Passage, which acts as a deep-water connection between the Agulhas and Transkei basins. Three regionally developed sediment layers occur in the deep (〉 4500 m) Transkei Basin/Agulhas Passage area. With the aid of a simple ocean crust sinking/carbonate compensation level (CCL) model these layers are related to the sedimentation history of the area. The model suggests that acoustic basement (Horizon X) represents Lower Cretaceous limestones draped over oceanic basement, and that this is overlain by an acoustically transparent sequence of pelagic/terrigenous material (Horizon A) that was deposited during a lengthy period (95 m.y.) beneath the carbonate compensation level. Post-Late Miocene sedimentation (Horizons B and C) has probably taken place above the CCL. Local sedimentation has always been influenced by strong sea-floor currents, but since middle Palaeogene times these currents have operated on a regional scale and have generated numerous large ridge and billow-like bed forms.

Description: The ratio of compressional wavevelocityV p to shear wavevelocityV s , and Poisson’s ratio in marine sediments and rocks are important in modeling the sea floor for underwater acoustics,geophysics, and foundation engineering. V p and V s versus depth information was linked at common depths in terrigenous sediments (to 1000 m) and in sands (to 20 m) to yield data on V p vs V s , and V p /V s and Poisson’s ratios versus depth. Soft, terrigenous sediments usually grade with depth into mudstones and shales; V p /V s ratios vary from about 13 or more at the sea floor to about 2.6 at 1000 m. Poisson’s ratios vary from above 0.49 at the sea floor to about 0.41 at 1000 m. In sands, V p , V s , and V p /V s have very high gradients in the first few meters; below about 5 m, V p /V s ratios decrease from about 9 to about 6 at 20 m; Poisson’s ratios vary from above 0.49 at the surface to above 0.48 at 20 m. The mean value of V p /V s in 30 laboratory samples of chalk and limestone is 1.90 (standard error: 0.03); mean Poisson’s ratio is 0.31. Literature data on basalts from the sea floor are reviewed. Equations relating V p to V s are given for terrigenous sediments, sands, and basalts.

Description: An estimate of average river particulate matter (RPM) composition was bàsed on analyses of more than 40 elements in the Amazon, Congo, Ganges, Magdalena, Mekong, Parana and Orinoco rivers, to which were added literature data for 13 other major world rivers, covering the whole spectrum of morphoclimatic features. Geographic variations of major elements in RPM are mostly linked to weathering types and to the balance between weathering rate and river transport. As a result of chemical erosion, Al, Fe and Ti are enriched in RPM with respect to the average parent rock, while Na, Ca, Mg and Sr are strongly depleted. These figures are directly related to the relative importance of dissolved and particulate transport in rivers; this has been computed for each of 40 elements. In order to study weathering on a global scale, the total observed elemental fluxes (dissolved + particulate) have been computed and compared to theoretical ones. The latter were derived from the elemental content in the average parent rock and the total quantity of weathered material, computed from the Al ratio in RPM and in parent rock. Observed and theoretical fluxes are balanced for the less mobilized elements (rare earths, Co, Cr, Cs, Fe, Mn, Rb, Si, Th, Ti, U and V) for which no enrichment relative to Al is noted in RPM, and for B, Ba, Ca, K, Mg, Na, Sr which are relatively depleted in RPM due to their high dissolved transport. Additional fluxes have been found for Br, Sb, Pb, Cu, Mo, Zn and are possible also for Ni and P. This is reflected by marked enrichments in RPM relative to Al for the poorly or moderately dissolved transports (Pb, Cu, Zn). Several hypotheses involving either the natural origin (volcanic dust, marine aerosols, geochemical fractionation) or the artificial origin (worldwide pollution) are discussed to explain these discrepancies, assuming river transport and weathering either to be in a steady state on a global scale or not. However, none of them can fully account for these additional fluxes. It is most likely that these excesses have multiple origins, anthropogenic or natural or both. The comparison between RPM and deep-sea clay compositions emphasizes the prime influence of river input on oceanic sedimentation of Si, Al, Fe, Ti, lanthanides, Sc, Rb, V, etc. A few elements such as Zn, Sb, occur in excess in RPM as compared to deep-sea clays; in order to balance this excess, a remobilization of these elements out of the sediment can be considered. Finally, the enrichment of Co, Cu, Mn and Ni in deep-sea clays compared to RPM is discussed and attributed to several sources and processes.

Description: Many occurrences of mineral resources in ocean water, on the ocean floor and in its deeper parts have long been well-known. This is readily understandable, because numerous ancient mineral products which are exploited on land were originally formed in marine milieus as far back as the Precambrian , e.g., marine sedimentary iron ores, rock salt, potassium, phosphate and manganese , as well as petroleum and natural gas. This book deals with ores in sediments, and in sedimentary and volcanic rocks. According to the Concise Oxford Dictionary (Fowler and Fowler , 1964), ore is defined as "solid native mineral aggregate from which valuable constituents not necessarily metal may be usefully extracted". Therefore , in tllis chapter only mineral resources of inorganic origin in ocean water and on the ocean floor are discussed and not those of organic derivation, although the existence of petroleum, natural gas and, to some extent, of coal in the subsurface of the ocean shelves is of greater economic importance. The amount of oil and gas produced in 1969 represented more than 90% by value of all mineral resources obtained from the oceans and ocean floors. Ore deposits in bed-rock formations of the shelf region, such as those which are exploited near Cornwall (England) and Newfoundland for example, are also irrelevant, as these are merely extensions of discoveries on the nearby mainland. The purpose of this chapter is to give a general review of the (inorganic) mineral resources of the oceans and the ocean floors . In this respect, not only are the economically important products which are already in use discussed, but also those materials which, in their oceanic environment, can become of economic value in the near or more remote future. For a better understanding of the existence of such materials, some deposits have also had to be reviewed which will not become of economic value . Since some contributions in this book are specifically dedicated to Recent marine ferromanganese deposits and Recent phosphorite deposits, these mineral resources are only briefly discussed in tllis chapter. (For details on Recent marine and lacustrine manganese deposits see Chapters 7 and 8 by Glasby/Read and by Callender/Bowser, respectively, in Volume 7.) The litarature on the mineral (inorganic) resources of the oceans and ocean floors is extremely extensive, so that a choice had to be made and, therefore, the bibliography added to this chapter consists mainly of recent publications.

Description: A complete set of linearly independent relationships among the different cross spectral components obtained from pairs of moored instruments is derived which can be utilized to test whether or not the observed fluctuations within the internal wave frequency band represent a field of propagating internal waves. A further complete set of relationships is derived which enables to test whether or not the internal wave field is horizontally isotropic and (or) vertically symmetric. These relations are compared with corresponding relations for alternative models (standing internal wave modes, three-dimensional isotropic turbulence) and their capability to discriminate between the various models is investigated. The tests are applied to a set of data for which it is found that the observed fluctuations are consistent with both propagating and standing internal waves whereas isotropic turbulence must be rejected for the most part of the internal wave frequency band.