ISSN:
0570-0833
Keywords:
High-pressure chemistry
;
Transition states
;
Kinetics
;
Chemistry
;
General Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
High pressure kinetics appears to be a valuable tool in investigating the mechanism of specific organic reactions. For instance, in pericyclic, Mentshutkin, cage, and polymerization reactions, such studies reveal various features of the transition state, in particular its localization along the reaction coordinate and its nature. However, precise conclusions require separation of the different effects (electrostatic, steric, orbital, etc.) which may contribute to the structure of the transition state.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/anie.197501371
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