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  • LUNAR AND PLANETARY EXPLORATION  (1,318)
  • Chemical Engineering  (850)
  • 1980-1984  (1,061)
  • 1975-1979  (1,107)
  • 1925-1929
  • 1981  (1,061)
  • 1975  (1,107)
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Years
  • 1980-1984  (1,061)
  • 1975-1979  (1,107)
  • 1925-1929
Year
  • 101
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 27 (1981), S. 312-315 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 102
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    AIChE Journal 27 (1981), S. 588-592 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Quantitative measurements of the effect of a third phase of buoyant solid particles on the settling rates of suspensions of heavy particles are reported. It is found that for a wide range of concentration of both buoyant and heavy particles, the settling rates of both solid phases are greatly increased. If the phases are dilute, the settling velocities of both are retarded. The total settling time of heavy particles can be halved, but only under conditions that the light phase is unaccelerated. This suggests that small gas bubbles would form a more satisfactory buoyant phase. The high concentrations of thickened suspensions which result from the acceleration process are also reported.
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  • 103
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    AIChE Journal 27 (1981), S. 632-636 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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  • 104
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    AIChE Journal 27 (1981), S. 673-679 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A procedure for inserting vapor pressure data in the equations of state is presented. It provides a straightforward scheme for the extension of direct methods to the study of phase equilibria of polar mixtures and of solutions containing nonvolatile electrolytes. Some examples of application are also given.
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  • 105
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    AIChE Journal 27 (1981), S. 861-863 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Experimental data and theory both support the contention that there is a maximum solubility in solid-fluid equilibria. An example system, naphthalene-ethylene, at temperatures between the upper and lower critical end points and at pressures from 1 to 1000 bar is considered. There is also a solubility minimum in this system.
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  • 106
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    AIChE Journal 27 (1981), S. 829-836 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A general analysis of a cascade of identical recycle units is presented by means of studying the fluid history inside the system. This is an extension of Part I (Mann et al., 1979) in which a single recycle unit was analyzed. The history of a fluid element is expressed in terms of the number of cycles it completes, the time it resides in the system and the total time it resides in a specific section of the system - all are random variables. Concepts from probability theory and stochastic processes are used to derive the number of cycles distribution (NCD), residence time distribution (RTD) and various total regional residence time distributions (TRRTDs) as well as their means and variances. Expressions for the joint distributions of pairs of these random variables are also derived as well as explicit expressions for their covariances and correlation coefficients. Two applications of the results are illustrated: one in analyzing a continuous spouted-bed coating unit and the second in using the cascade as a flexible, physically based multi-parameter flow model.
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  • 107
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    AIChE Journal 27 (1981), S. 928-937 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The Isotherm Migration Method of numerically analyzing conduction with phase change is modified to handle surface and external resistances, appearance, and propagation of successive fronts into slabs of composite material of one or more constituents finely dispersed in a matrix, different components transforming at different temperatures. Procedures are developed for selecting temperature intervals between isotherms, initially locating isotherms by means of analytical approximations to the earliest stages, and thereafter inserting and removing isotherms as appropriate, particularly when each component gives rise to a separate front.
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  • 108
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    AIChE Journal 27 (1981), S. 968-974 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An improved model and solution procedure for nonequilibrium, multicomponent, two-phase, steady-state mass transfer problems are developed. Processes as diverse as packed column operation and the drying of porous solids are included. Ideas such as “HETP,” “HTU” or “mass transfer section” are avoided. “Stiff” systems appear to be handled well.
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  • 109
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    AIChE Journal 27 (1981), S. 1002-1008 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Our purpose is to give the physical conditions under which transfer of a surfactant through a fluid interface between two immiscible liquids may induce aperiodic convective motion.Adsorption-desorption rates are considered together with diffusional exchanges. New kinds of surface instabilities are then predicted.
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  • 110
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    AIChE Journal 27 (1981), S. 1017-1020 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 111
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    AIChE Journal 27 (1981), S. 1026-1028 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 112
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    AIChE Journal 27 (1981), S. 1039-1041 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 113
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    AIChE Journal 27 (1981), S. 509-514 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 114
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    AIChE Journal 27 (1981), S. 521-523 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 115
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    AIChE Journal 27 (1981), S. 527-528 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 116
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    AIChE Journal 27 (1981), S. 526-526 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 117
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    AIChE Journal 27 (1981), S. 529-545 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The increasing demands for oil, water, and food produced in an environmentally sound manner have placed emphasis on the manner of their production, a major part of which is concerned with flow through porous media.The movement of materials through porous media is of interest in many disciplines: in chemical engineering - adsorption, chromatography, filtration, flow in packed columns, ion exchange, reactor-engineering; in petroleum engineering - displacement of oil with gas, water and miscible solvents including surface-active agent solutions and description of reservoirs; in hydrology - movement of trace pollutants in water systems, recovery of water for drinking and irrigation, salt water encorachment into fresh water reservoirs; in soil physics - movement of water, nutrients, and pollutants into plants; in biophysics - life processes such as flow in the lung and the kidney.This paper reviews the fundamentals of steady flow through porous media: it discusses the pseudotransport coefficients permeability, capillary pressure, and dispersion and relates these coefficients to the geometry of porous media. It also discusses single-fluid flow, multifluid immiscible flow, and multifluid miscible flow including the effects of heterogeneity, nonuniformity, and anisotropy of media.
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  • 118
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    AIChE Journal 27 (1981), S. 578-587 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: This paper deals with the problem of finding, among many alternatives, the sequence of separation units that will isolate desired products from given feed at the minimum cost. Multicomponent products can be specified. An evolutionary procedure is presented. This method consists of two phases. In the first phase, a good initial structure is created by heuristic methods. In the second phase, the initial structure is successively modified by making evolutionary structural changes. This logic has been programmed on a digital computer and has been tested on several problems.
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  • 119
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    AIChE Journal 27 (1981), S. 605-613 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Previously published data for the six binary combinations that can be formed from CO2, H2S, N2 and methanol are used to obtain parameters of the four-suffix Margules equation describing liquid solution behavior. The vapor phase is described by the Soave modification of the Redlich-Kwong equation of state. Isothermal binary data are fit well by these equations. The effects of temperature on the Margules parameters are significant and, except for N2-containing mixtures, the parameters were taken to be inversely proportional to absolute temperature.Experimental data were obtained for multicomponent mixtures of CO2, H2S, N2 and methanol. Model predictions were tested against these data. Comparisons of predicted and measured values of bubble point pressure and equilibrium vapor compositions are satisfactory.
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  • 120
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    AIChE Journal 27 (1981), S. 613-619 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The objective of this paper is to point out the relationship between the relative gain array (RGA) and control system stability and design. Rigorous stability limits are presented for a general 2 × 2 system for several cases involving both steady state and dynamic interactions. These stability limits explicity involve the RGA. Two specific examples of interaction in distillation models are also discussed.
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  • 121
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    AIChE Journal 27 (1981), S. 637-645 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 122
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    AIChE Journal 27 (1981), S. 654-663 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A theoretical model is presented to describe the kinetics of nonisothermal sorption for a system in which the main resistance to mass transfer is the macrodiffusional resistance of the absorbent particle bed while the main resistance to heat transfer is the resistance at the external surface of the adsorbent sample. The model is used to interpret experimental kinetic data for the sorption of several hydrocarbons in 10X and 13X zeolite crystals. By varying the configuration of the sample bed and the size of the zeolite crystals it is shown that, for n-heptane and iso-octane in 13X, the intracrystalline diffusional resistance is negligible even in 40-μm crystals. The assumption of intracrystalline diffusion control which has been made in earlier kinetic studies of similar systems is therefore incorrect.
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  • 123
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    AIChE Journal 27 (1981), S. 690-693 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A general theory for examining the dynamic as well as static interactions among inputs and outputs in a multivariable control system has been developed. Both state space and frequency domain approaches are used, and at steady state the interaction equations assume the same form as the relative gain array developed by Bristol. Implications of selecting input-output pairings with regard to steady state vs. dynamic consideration are discussed. The application of the method of analysis to a distillation column control system is presented.
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  • 124
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    AIChE Journal 27 (1981), S. 697-699 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 125
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    AIChE Journal 27 (1981) 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 126
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    AIChE Journal 27 (1981), S. 733-739 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A mathematical model and iterative correction algorithm are described for the exact solution of separation systems which contain interlinked columns in which some stages have two liquid phases and others have a vapor and liquid phase. The correction algorithm is based on Newton's method and provides for simultaneous correction of all iteration variables. The derivatives are calculated analytically from the model equations. The separation of a binary mixture which forms a heterogeneous azeotrope is analyzed. Modifications to the correction algorithm which provide for fixed condenser temperature and fixed product flows are described. The separation of butanol and water is used to illustrate the method.
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  • 127
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    AIChE Journal 27 (1981), S. 761-767 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The kinetics of the esterification of n-butyl alcohol with acetic acid has been studied experimentally in concentrated solutions at near ambient temperature in the presence of a sulphuric acid catalyst and the rate constants for the forward and reverse reaction determined.The rate data obtained from the homogeneous system has been applied to analyse the performance of a batch-extractive reactor using n-heptane as solvent. The rate of mass transfer of the ester was found to be significant and when introduced in a model of the reaction process gave good agreement with the experimental results.
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  • 128
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    AIChE Journal 27 (1981), S. 793-805 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: This paper deals with defining the relation between modeling of process units and controller design. In the process industries, it is often difficult to obtain accurate process models. It is shown that advanced algorithms such as dead-time compensators require more detailed process information for design than do with PI and PID controllers. A method is described to systematically evaluate the relation between process identification and controller design, stability, and performance. It is shown that conventional gain and phase margins do not provide proper safety margins for dead-time compensators and optimal controllers. Methods for safe design of dead-time compensators are derived, and the approach could be useful in a wide class of problems.To illustrate the approach presented, the design of PI controllers by conventional methods is analyzed. The conditions, as well as the exceptions, are specified in which methods such as described by Ziegler and Nichols or Cohen and Coon will give good results. It is shown that for any stable nonlinear system with an input/output function y = G*p(u), a linearized design function G′pd can be constructed and identified that guarantees stability and reasonable performance of the controller (Eqs. 21 and 22 and Figures 4-7) over a wide range of operating conditions. A rigorous framework for identifying the exceptions and understanding the reason why such methods work is presented.
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  • 129
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    AIChE Journal 27 (1981), S. 819-823 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Electrochemical measurements of overall mass transfer rates from a single sphere have been performed in a highly turbulent liquid. The increase in mass transfer rate due to turbulence has been shown to be more important at high Reynolds number and high turbulence intensity. Various equations of correlation have been proposed between the overall Sherwood number, the Reynolds number and turbulence intensity, the simplest one being \documentclass{article}\pagestyle{empty}\begin{document}$$ Sh = 6.82\,{\mathop{Re}\nolimits} ^{0.559}\, Tu^{0.069} $$\end{document} A correct agreement has been found with previous heat or mass transfer results between a gas and a sphere.
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    AIChE Journal 27 (1981), S. 851-853 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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    AIChE Journal 27 (1981), S. 853-856 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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    AIChE Journal 27 (1981), S. 864-866 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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    AIChE Journal 27 (1981), S. 872-875 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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    AIChE Journal 27 (1981), S. 876-876 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
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    AIChE Journal 27 (1981), S. 881-888 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: We hereby submit three different numerical methods for the solution of the multicomponent distillation model for two partially immiscible liquids. A procedure to define the real number of phases present on each stage has been developed. The proposed Newton-Raphson method allows efficient solution of problems with a large selection of the unknowns and the specification equations.
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    AIChE Journal 27 (1981), S. 888-892 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Based on terLinden's (A. J. terLinden, “Investigations into Cyclone Dust Collectors,” IME Proc., 160, 233, 1949) experimental observations, a three-region model is proposed for the fluid flow in a cyclone. Within each region, turbulence is assumed to promote mixing of the suspended particles. Incorporation of this mixing concept into the three-region model allows an analytic expression for the collection efficiency of the cyclone to be developed.The theoretical result is compared with data obtained in the high temperature, high pressure exhaust from a pressurized fluidized bed combustor.
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    AIChE Journal 27 (1981), S. 920-927 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A series of seven coals were oxidized in a fixed bed reactor to determine the controlling reaction regimes during mild coal oxidation. The effects of coal porosity and particle size, reactor temperature, and oxygen partial pressure were evaluated. The results show that coal-oxygen reactions are controlled by the rate of internal gaseous diffusion for most coals, and by the rate of chemical reaction for the most porous coal of the set tested. Particle size effects also suggest internal diffusional control. Determinations of cumulative oxygen deposition indicate that surface areas several orders of magnitude greater than the superficial surface can participate in oxidation reactions, putting in doubt the applicability of the model previously derived by Kam et al. (1976a) for external mass transfer control.
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  • 138
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    AIChE Journal 27 (1981), S. 946-951 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A novel experimental setup allowed both the kinetics of the thermal cracking of ethane and of the coke formation to be studied over a temperature range extending from 750 to 870°C. The overall kinetics of ethane disappearance are in excellent agreement with previously reported pilot results. Coking rates are initially high but rapidly decrease to reach an asymptotic value. The initial product distribution also differs from the asymptotic product distribution. A kinetic model for the coking is derived from the experiments and used in conjunction with a set of conservation equations for the simulation of industrial ethane cracking. The predicted run length, thickness of the coke layer and evolution of the tubeskin temperatures are in agreement with industrial observations.
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    AIChE Journal 27 (1981), S. 984-993 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
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    Notes: A theoretical model of venturi scrubber performance consisting of the governing differential equations for momentum, material, and energy exchange is solved using a Milne fourth-order predictor - Hamming corrector numerical integration procedure. The model provides for specification of the operating variables, including scrubber geometry, throat gas velocity, liquid to gas loading ratio, and collector droplet and particle-size distributions. Liquid loading ratio and gas velocity are shown to be the two most important operating variables, while the dispersity of the droplet size distribution only slightly affects collection efficiency over the operating range normally encountered. Location of the liquid injection site and length of the throat are also important design considerations. While particle collection in venturi scrubbers has typically been assumed to occur in the potential flow regime, the present results show that collection can also occur under conditions corresponding to viscous flow about the collecting droplets. The transition Reynolds number used to change from the potential to viscous flow equations affects the predicted performance.
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    AIChE Journal 27 (1981), S. 1024-1026 
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    Keywords: Chemistry ; Chemical Engineering
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    AIChE Journal 27 (1981), S. 1035-1038 
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    Keywords: Chemistry ; Chemical Engineering
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    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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    AIChE Journal 21 (1975), S. 289-298 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Measurements of diffusion and partitioning of nearly monodisperse polystyrene, having molecular weights of from 600 to 670,000, in chloro-form and dichloroethane and of two proteins in aqueous solution were made with leached borosilicate glass cubes having a narrow pore size distribution and pore radi of from 2.5 to 47.6 nm. With increasing ratio of molecular to pore size, the partition coefficient for all solutes decreased; the ratio of effective to bulk diffusivity decreased for the proteins but remained constant for polystyrene. This suggests that polystyrene behaved like a free-draining macromolecule under the conditions of this study.
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    Notes: Dielectric constants and Clausius-Mossotti functions (CM) have been determined for selected pure components, binary mixtures, and ternary mixtures at temperatures between 91 and 115 K and pressures near saturation. Excess Clausius-Mossotti functions (CME) have been calculated from the pure fluid and mixture values.Mixture CME values are found to be generally less than 0.1% of the mixture CM values for systems containing only nonpolar species. Thus, dielectric constant measurements can be conveniently used as substitute density measurements for simple liquid mixtures. Methods have been developed to utilize dielectric constant measurements to accurately determine densities and heating values per unit liquid volume for liquefied natural gas mixtures.
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    AIChE Journal 21 (1975), S. 299-307 
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    Notes: In this study a new mathematical model for predicting permeabilities of porous media has been developed. The model consists of a set of cubic networks of arbitrary orientations with respect to the macroscopic flow direction. The networks consist of capillary tubes which are made up of segments of different diameters. It is shown that a cubic network of capillaries has isotropic permeability properties. The permeability model requires two pore size distributions and the porosity of the sample for the calculations. The calculated permeabilities agreed with experimental results for a wide range of permeabilities of highly compacted materials to within ± 23%, without using adjustable tortuosity factors.
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    AIChE Journal 21 (1975), S. 308-318 
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    Notes: Inception criteria for droplet entrainment in concurrent gas-liquid film flow were developed from simple physical models. For film Reynolds number ≳ 160, an entrainment model based on the shearing off of roll-wave crests was used. At lower film Reynolds numbers, a wave undercutting mechanism was introduced. Experimentally observed abrupt changes in the critical gas velocity corresponding to the onset of entrainment at a certain film Reynolds number have been explained by the shift in the entrainment mechanisms. An agreement of the present inception criteria with various experimental data is shown to be satisfactory, and significant improvements over the existing empirical correlations have been made.
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    AIChE Journal 21 (1975), S. 391-392 
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    AIChE Journal 21 (1975), S. 392-395 
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    AIChE Journal 21 (1975), S. 396-397 
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    AIChE Journal 21 (1975), S. 406-407 
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    AIChE Journal 21 (1975), S. 402-404 
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    AIChE Journal 21 (1975), S. 410-411 
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    AIChE Journal 21 (1975), S. 412-412 
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    AIChE Journal 21 (1975), S. 487-494 
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    Keywords: Chemistry ; Chemical Engineering
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    Notes: General equations for (1) thickness, (2) specific holdup, and (3) specific flow rate of non-Newtonian films under conditions of plane free drainage with negligible inertial and interfacial tension forces and normal stresses as functions of position and time are derived. Use of these equations reduces the heretofore tedious process of derivation for a particular rheological model of expressions for film thickness, holdup, and flow rate to a single-step operation for film thickness and relatively simple processes for holdup and flow rate. The general equations are evaluated for popular non-Newtonian models, with description of efficient methods for doing so, and the results for thickness, holdup, and flow rate, many new, in compact dimensionless form made available to the interested reader in a supplement.
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    AIChE Journal 21 (1975), S. 567-571 
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    Notes: A new method of analyzing the behavior of dynamic systems containing time delays is presented. The method, which is based on the construction of a subsidiary system where the delayed state variables are approximated by Taylor series expansion, is simple and easy to apply. The stability and the region of stability of the subsidiary equation correspond closely to that of the original system.
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    AIChE Journal 21 (1975), S. 607-608 
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    AIChE Journal 21 (1975), S. 622-622 
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    AIChE Journal 21 (1975), S. 622-622 
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    AIChE Journal 21 (1975), S. 706-713 
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    Notes: Liquid holdup and mass transfer rates were measured in a 2.58-cm I.D. tube, packed with glass beads and granular CuO · ZnO catalyst or β-naphthol particles, and operated as a trickle bed. Gas-to-liquid (water) transport coefficients were determined from absorption and desorption experiments with oxygen at 25°C and 1 atm. Liquid-to-particle mass transfer was studied using β-naphthol particles.Holdup and both mass transfer coefficients were unaffected by gas flow rate but increased with liquid rate. The data were correlated with equations that could be used for predicting mass transfer coefficients at high temperatures and pressures for use in the reaction studies reported in Part II.
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    AIChE Journal 21 (1975), S. 714-720 
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    Notes: Dilute solutions (132 ppm) of formic acid in water were oxidized with air in a trickle-bed reactor at 212° to 240°C and 40 atm. Particles 0.291 and 0.0541 cm in diameter, prepared from a commercial CuO · ZnO catalyst, were used to provide a model system for studying water purification by catalytic oxidation.Differential reactor runs were made to measure the global rate of reaction. These data were compared with predicted rates from the known intrinsic kinetics and intraparticle diffusivities, and the mass transfer coefficients measured in Part I.High conversion (of formic acid) data were also obtained in order to test models for trickle-bed reactors. Experimental conversions agreed reasonably well (within 10%) with predicted values based upon intrinsic kinetics and the several transport rates. Axial dispersion was found to be less important than gas-to-liquid mass transfer and intraparticle diffusion. In our laboratory studies (reactor I.D. = 1 in.) careful arrangements were made to obtain nearly uniform distribution of liquid over the reactor cross section. Hence effects of maldistribution, which may be important in large-scale reactors, were minimized.
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    AIChE Journal 21 (1975), S. 720-730 
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    Notes: A model to determine stresses and friction forces in moving packed beds with interstitial fluid flow has been developed. The scaling parameters are determined from the governing equations. A plane and an axisymmetric bed geometry are studied and the wall stress calculated under uniform one-dimensional axial flow conditions. The effect of added transverse flow (for example, due to a screen in the wall) is investigated. The present model is an improvement over earlier, one-dimensional models with capability to include in the stress analysis varying pressure gradients in all directions which may exist in practical moving bed systems.
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    AIChE Journal 21 (1975), S. 730-735 
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    Notes: The behavior of a vibrating column of liquid as a slurry reactor and the dependence of the mass transfer resistances on the frequency of oscillation and liquid temperature were studied. The hydrogenation of liquid acetone over Raney nickel was chosen as the model reaction. The tortuosity factor of the catalyst was determined from measurements with two different particle sizes.
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    AIChE Journal 21 (1975), S. 735-743 
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    Notes: A new method to reduce vapor-liquid equilibrium data of binary mixtures and to evaluate a thermodynamic model is presented. It is based on the principle of maximum likelihood. Deviations between all measured and predicted quantities are calculated and confidence limits in model parameters are evaluated from the given estimates of experimental errors. Many examples illustrate the practical applications of the method.
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    AIChE Journal 21 (1975), S. 743-752 
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    Notes: A study on the effects of flow pulsations on interphase mass or heat transfer has been made. The situation corresponds to fully developed flow in a long conduit with a periodic pressure gradient at amplitudes which cause flow pulsations without flow reversal. It is shown that the basic three-parameter formulation can be reduced to a one-parameter problem in the boundary layer formulation. Solutions are developed over wide ranges of the parameters in both the basic and the boundary layer formulations.The boundary approach gives accurate results over wide ranges of the parameters. Pulsations cause increases in the time-averaged interphase flux at intermediate values of a composite frequency-space variable. However, at small values of this variable the pulsations cause a decrease in the flux such that the overall space-averaged flux is always decreased.
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    AIChE Journal 21 (1975), S. 752-756 
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    Notes: Simultaneous diffusion and homogeneous reaction during the turbulent flow of a power-law fluid in a tubular reactor has been studied using the correlations for the velocity profile and eddy diffusivity proposed by Krantz and Wasan. The results of the theory indicate that while the cup-mixing concentration is unaffected by variations in the Reynolds number, the Schmidt number, or the flow behavior index, it is significantly influenced by the reaction parameter and the reaction order.
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    AIChE Journal 21 (1975), S. 756-763 
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    Notes: The kinetics of isothermal transformations or decompositions of solids proceeding through nucleation and subsequent growth is treated in the spirit of Avrami, eliminating, however, some of the internal contradictions of his treatment. Universal solutions of the dimensionless integral equation are computed. The theory is extended to nonisothermal systems and the resulting integral equations are solved numerically for the adiabatic case. It is shown that two kinds of catastrophic behavior can occur: one is characterized by slopes approaching infinity in the conversion vs. time curve following a long period of quiescent behavior; the other is characterized by a very short time for total conversion and by milder slopes in the conversion vs. time curve throughout the course of reaction. In the first kind the nucleation is mainly responsible for the catastrophic behavior, while in the second kind the rate of growth is responsible.
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    AIChE Journal 21 (1975), S. 763-769 
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    Notes: The reduction of oxygen in neutral saline solution and in seawater was studied using the rotating disk electrode (RDE). The objective was to test the applicability of the RDE as a primary reference standard for the measurement of oxygen concentrations below 0.1 ppm in seawater. Limited success was achieved with an activated platinum electrode. A gold electrode was less effective. If one postulates that the 2-electron reduction of oxygen at an activated RDE is rapid, it appears that little or no 4-electron reduction occurs and that the subsequent 2-electron reduction or catalytic decomposition of hydrogen peroxide is relatively slow. The anodic activation procedure developed appears to impart a transient catalytic activity to the electrode surface for the peroxide reaction(s).
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    AIChE Journal 21 (1975), S. 775-782 
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    Notes: The stability problem of the free coating of wires and tubes by withdrawal is formulated and solved. The necessary condition for the stability of the film coating is given explicitly in terms of the Reynolds number, wave number, the Weber number, and implicitly in terms of the withdrawal velocity. The outcome of the competition between the destabilizing capillary pinching and the stabilizing capillary restoring force associated with the film thickness variation is shown to dictate the stability of the film. The comparisons between the present theoretical results and the known experimental results for falling films and creeping annular threads of viscous liquids are good. A possible application of the present results to some aspects of the qualitative design of a coating process is given.
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    AIChE Journal 21 (1975), S. 782-786 
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    Notes: Affinity chromatography and parametric pumping were combined to reduce trypsin concentration in an aqueous solution. The trypsin inhibitor, chicken ovomucoid, was covalently bonded to Sepharose 4B beads. A solution was cycled over this packing in a column at a low pH in one direction followed by a high pH in the other direction. Trypsin retention was favored at the high pH and elution at the low pH. The decrease in trypsin concentration at one end of the column was fitted to an equation derived from the equilibrium parametric pumping model and was a function of the pH limits imposed on the column. Separation was much less than predicted by equilibrium data, but the equation based on trypsin reduction agreed with the α-chymotrypsin-trypsin separation.
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    AIChE Journal 21 (1975), S. 786-791 
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    Notes: Effective reaction rates and selectivities on surfaces having active and inactive regions are calculated for systems in which diffusion of reactants and products through a boundary layer is significant. With a single reaction it is shown that rates are larger than those calculated assuming area weighted averages. The selectivity of production of an intermediate in a series of reactions on a heterogeneous surface is higher than on a homogeneous surface, and with parallel reactions selectivities may be lower or higher depending on the kinetics of the competing reaction.Numerical examples from NH3 oxidation on a Pt gauze and CO oxidation in the automotive converter indicate that these effects may be important in determining selectivities and conversions in some industrial reactors.
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    AIChE Journal 21 (1975), S. 791-799 
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    Notes: The equations for steady isothermal spinning of a viscoelastic liquid are solved for a fluid model with constant modulus and a single constant relaxation time. High stress levels are predicted for elastic liquids, and the velocity approaches a linear profile in the limit of maximum drawdown. These predictions are in accordance with the observed behavior of polymeric liquids in isothermal spinning. Relaxation times computed from spinning data of Spearot and Metzner and Acierno et al. for four low density polyethylene melts are comparable to those measured rheogoniometrically, though the spinning relaxation times are 20 to 80% larger.
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    AIChE Journal 21 (1975), S. 807-810 
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    AIChE Journal 21 (1975), S. 830-830 
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    AIChE Journal 21 (1975), S. 830-830 
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    AIChE Journal 21 (1975), S. 831-831 
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    AIChE Journal 21 (1975) 
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    AIChE Journal 21 (1975), S. 849-853 
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    Notes: The application of monolithic catalysts to automotive emission control has frequently been complicated by unexplained thermal degradation phenomena. This paper reports experimental and theoretical studies aimed at the understanding of how heat is generated and distributed in catalytic monoliths during an exothermal, mass transfer limited reaction.Theoretical considerations indicate that under certain operating conditions the steady state solid catalyst temperature can exceed the adiabatic reaction temperature. It is also shown that the catalyst overtemperature is influenced by the nature of the reactive species and by the geometry of the catalyst. These predictions have been verified by experiments in a novel tubular reactor.
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    AIChE Journal 21 (1975), S. 894-901 
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    Notes: A Deborah number is introduced as a means of characterizing diffusional transport in amorphous polymer-solvent systems. Two types of temperature-penetrant concentration diagrams are constructed, and the various regions on these figures are identified by their Deborah number values. The utility of the diffusion Deborah number is demonstrated by using this dimensionless group to anticipate conditions under which thickness anomalies can be expected in sorption experiments for the atactic polystyrenepentane system.
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    AIChE Journal 21 (1975), S. 1123-1132 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Generalized van der Waals theory is used to establish a partition function that considers the effect of density on rotational and vibrational motions in addition to translational degrees of freedom. A three-parameter equation of state is derived from this partition function. The equation of state is applicable to small, spherical (argon-like) molecules and also to large, structurally complex molecules, including polymers. Parameters are presented for three polymers and twenty-two common fluids including light hydrocarbons, heavy hydrocarbons, nitrogen, carbon dioxide, hydrogen, carbon monoxide, hydrogen sulfide, sulfur dioxide, and water. The equation of state gives good liquid densities, and vapor pressures, and fair second virial coefficients.
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  • 179
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    AIChE Journal 21 (1975), S. 1142-1148 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The vapor-liquid equilibrium of the hydrogen-n-butane system was studied at temperatures between 54° and 121°C and at pressures up to 167 atm. The fugacity of hydrogen in the vapor phase was measured directly by using a palladium-silver semipermeable membrane, whereas p-T-x-y data were obtained in a conventional manner.Henry's constants for hydrogen in n-butane were obtained from the experimental fugacity data without making any assumptions about the vapor phase. Constant-pressure, liquid-phase activity coefficients for both hydrogen and n-butane were calculated and correlated by using a modified van Laar equation.
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    AIChE Journal 21 (1975), S. 1149-1158 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Quantitative theories based on first principles are derived to explain the roles of heat and mass transfer in the attainment of steady state or ultimate separation in closed direct-thermal-mode parametric pumps. The theoretical results are in agreement with applicable experimental data, including the experimental anomaly called reversed separation. Under conditions when the axial dispersion is much greater than molecular diffusion, the theory predicts and experiments confirm that 1/ln(α∞) varies in a linear way with fluid displacement at constant frequency. An additional asymptotic result suggests that when Sh » PeM, there is a simple linear connection between 1/ln(α∞) and PeM which is supported by experimental data.
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    AIChE Journal 21 (1975), S. 1189-1192 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A correlation is developed for predicting in-situ (or true) liquid holdups for two-phase, gas-liquid slug flows in inclined pipes. The correlation is based on experimental data collected in pipes ranging from 2.54 to 7.94 cm in diameter with the air-water system used.The experimental data used to develop the correlation were collected at zero input liquid qualities, as previously discussed by Greskovich (1973), and extended over the entire range. These data revealed little diameter effect on holdup for diameters greater than 2.54 cm but a marked effect of angle of inclination. Predicted holdup values show good agreement with experimental data.
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    AIChE Journal 21 (1975), S. 1192-1199 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An experimental method is described for measuring the permeability of small tubular (hollow fiber) membranes by means of an unsteady state diffusion experiment. Permeability data obtained by this method are reported for experimental collagen and commercial cellulose acetate membranes for urea, sucrose, and polyethylene glycol (MW ∼ 4 000).
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    AIChE Journal 21 (1975), S. 1204-1207 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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    AIChE Journal 21 (1975), S. 1200-1204 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The sorption of dissolved oxygen on activated carbon was characterized with manometric and packed column apparatus. All carbons tested, granular and powdered, virgin and reactivated, sorbed 150 to 600 μmole of oxygen/g after run times up to 1 700 hr., but sitll not at equilibrium. The rate data generally conform to a model of sorption limited by intraparticle diffusion. Carboxylic acid groups increase by about 200 μeq/g as a result of dissolved oxygen sorption, which can account for at least 10 to 50% of the oxygen sorbed. Also, about 5% of the sorbed oxygen can be eluted into deoxygenated water.
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    AIChE Journal 21 (1975), S. 1207-1209 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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    AIChE Journal 21 (1975), S. 1209-1209 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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    AIChE Journal 21 (1975), S. 1210-1213 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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    AIChE Journal 21 (1975), S. 1218-1220 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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    AIChE Journal 21 (1975), S. 1213-1218 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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    AIChE Journal 21 (1975), S. 1220-1223 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
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    AIChE Journal 21 (1975), S. 1223-1225 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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    AIChE Journal 21 (1975), S. 1225-1227 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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    AIChE Journal 21 (1975), S. 1227-1230 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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    AIChE Journal 21 (1975), S. 1230-1233 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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    AIChE Journal 21 (1975), S. 1233-1234 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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    AIChE Journal 21 (1975), S. 1235-1235 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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    AIChE Journal 21 (1975), S. 1235-1235 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
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    AIChE Journal 21 (1975), S. 1236-1237 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
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    AIChE Journal 21 (1975), S. 1237-1237 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
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    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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