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  • Chemical Engineering  (356)
  • Wiley-Blackwell  (356)
  • Blackwell Publishing Ltd
  • PANGAEA
  • 1985-1989
  • 1970-1974  (356)
  • 1973  (356)
Collection
Publisher
  • Wiley-Blackwell  (356)
  • Blackwell Publishing Ltd
  • PANGAEA
Years
  • 1985-1989
  • 1970-1974  (356)
Year
  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 19 (1973), S. 58-67 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A new model for porous media comprised of monosized, or nearly monosized grains, is developed. In applying this model to a packed bed, the bed is assumed to consist of a series of statistically identical unit bed elements each of which in turn consists of a number of unit cells connected in parallel. Each unit cell resembles a piece of constricted tube with dimensions which are random variables. The problem of flow through each unit cell is reduced, subject to reasonable assumptions, to the determination of the flow in an infinitely long periodically constricted tube. The solution of this flow problem is given in a companion publication. This model, together with the solution of the flow through it, can be used for the modeling of processes which take place in the void space of a bed.As a preliminary test, theoretical friction factor values, based on the proposed model, were compared with experimental ones for two different beds and found to be in good agreement even in the region of high Reynolds numbers where the nonlinear inertia terms are significant.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 19 (1973), S. 94-101 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An analytical study was carried out on the effects of mixing on radiation-induced polymerization in which the species initiating the polymerization were not uniformly produced because of a nonuniform dose rate distribution. The analysis is based on the periodic irradiation of fluid elements circulating in a stirred-tank reactor having a high dose rate region and a very low dose rate region. It is shown that the rate of polymerization increases with agitation speed and that the bimodal molecular weight distribution of the polymer formed at low agitation speed moves to a unimodal distribution as the agitation speed increases.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 19 (1973), S. 145-151 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Liquid-vapor phase equilibria measurements were made at 112.00 K on the binary systems nitrogen-argon, nitrogen-methane, and argon-methane and the ternary system nitrogen-argon-methane. Values of gE, the excess Gibbs free energy, have been calculated from the experimental data for all the systems studied. The data and derived gE values for the binary systems were compared with the results of previous investigations with satisfactory agreement.
    Additional Material: 8 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 19 (1973), S. 167-173 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A generalized equation of state is developed by combinin a hard-sphere equation with a truncated virial equation and generalizing the reduced hard-sphere diameter as a function of reduced temperature and acentric factor. The new equation quantitatively agrees with Pitzer's table of compressibility factor over wide ranges of gas and vapor states and is always better than the truncated virial equation. Since the terms in the equation are physically meaningful it is capable of being improved systematically by including higher virial coefficients and by using hard-core equations of state for nonspherical cores. The equation is extended to mixtures with well-developed combination rules.
    Additional Material: 9 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 19 (1973), S. 183-185 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 19 (1973), S. 112-119 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A geometric model for an homogeneous and isotropic porous medium composed of spherical particles is proposed. This model requires a minimum of geometric simplifications and lends itself to the study of hydrodynamic as well as diffusive flow processes, permitting in each application a mathematically rigorous and fully predictive analysis leading to mathematical representations of the respective flow parameters.This particular investigation seeks to evaluate, and to provide physical insight into, diffusive flow processes occurring within an homogeneous swarm of spherical particles.
    Additional Material: 6 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 19 (1973), S. 371-372 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 19 (1973), S. 379-381 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 19 (1973), S. 335-343 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Structured design systems are systems which may be represented by generally nonlinear equality and inequality constraints, each of which contains few of the variables in the system. Assuming the existence of an automatic capabity to derive and modify as needed effective solution procedures for sets of structured equality constraints, a two-step strategy for optimizing design systems is presented in the form of two algorithms. An earlier paper presented an algorithm for locating a first feasible point, and this paper presents a companion algorithm based on the strategy known as restriction to optimize the system once feasible.This companion algorithm divides the set of inequality constraints into three sets: the set of those currently being held as equality constraints, the set currently released but being used as search coordinates, and the set of all remaining constraints which are not currently part of the problem. Solution procedures are modified as inequality constraints and are moved from one set to another. Added constraints in the set being held tend to aid the optimization process by reducing the dimension of search space for what is usually a marginal added burden in solving an enlarged set of (structured) equations.The strategy has proved remarkably effective on three relatively simple examples, including a nonlinear 31 constraint, 10 variable alkylation problem.
    Additional Material: 2 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 19 (1973), S. 356-364 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Models are developed to describe sintering of metal crystallites during heat treatment. The growth rate of such crystallites is assumed to depend upon particle migration over the surface of the support as well as on the rate the colliding particles merge (sinter) into a single unit. The theory predicts that the rate of decay of exposed metal surface area S is given as in Equation (1a). The exponent n is related to the assumed size dependence of the diffusion coefficients or of the rate constant of the merging process. It varies from 4 to 8 for diffusion controlled decay and it is less than 3 for sintering controlled decay, that is, when the rate controlling step is the merging of two colliding particles. Diffusion control is associated with strong interactions between the metal and the support, but in sintering control there is a weaker metal-support interaction.
    Additional Material: 4 Ill.
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