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  • Wiley-Blackwell  (9,827)
  • PANGAEA
  • 2010-2014
  • 1980-1984
  • 1960-1964  (9,876)
  • 1964  (5,173)
  • 1963  (4,703)
Collection
Years
  • 2010-2014
  • 1980-1984
  • 1960-1964  (9,876)
Year
  • 1
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    PANGAEA
    In:  Supplement to: Arrhenius, Gustaf (1963): Pelagic sediments. In: Hill, M.N. (Ed.) The Earth Beneath the Sea, History, The Sea - Ideas and Observations on Progress in the Study of the Seas, Wiley J, New York, U.S.A., 3, 655-727, hdl:10013/epic.46253.d001
    Publication Date: 2023-08-28
    Description: Attempts to classify pelagic sediments have been based either on appearance and composition, or on the ultimate origin of the components. In particular it appears feasible to distinguish minerals which crystallized in sea-water from those which formed in magmas, in hydrothermal solution, or by weathering under acidic conditions. It is the case of iron and manganese oxide mineral aggregates which constitute one of the major types of rock encountered on the ocean floor; according to Menard (unpublished) about 10% of the pelagic area of the Pacific is covered by such nodules. The nodules consist of intimately intergrown crystallites of different minerals among those identified, besides detrital minerals and organic matter, are opal, goethite, rutile, anatase, barite, nontronite, and at least three manganese oxide minerals of major importance. Arrhenius and Korkisch (1959) have attempted to separate from each other the different minerals constituting the nodules, in order to establish the details of their structure and the localization of the heavy metal ions. The results demonstrate (Table II) that copper and nickel are concentrated in the manganese oxide phases concentrated in the reducible fraction. Cobalt, part of the nickel and most of the chromium are distributed between these and the acid-soluble group of the non-manganese minerals, dominated by goethite and disordered FeOOH.
    Keywords: Acid soluble, total; ALB-13; ALB-2; Albatross (1882-1921); Albatross1899-1900; Albatross1904-1905; ALBTR-13; ALBTR-2; ALBTR-4711; ALBTR-4721; Barium; Chromium; Cobalt; Copper; DEPTH, sediment/rock; DNWB0ABD; DOWNWIND-B1; DOWNWIND-H; Dredge; DRG; DWBD4; DWHD72; Event label; Horizon; Identification; Iron; Lanthanum; Lead; Manganese; Molybdenum; Nickel; Niobium; NOAA and MMS Marine Minerals Geochemical Database; NOAA-MMS; Northern_Holiday; North-West Pacific Ocean; NTHL02HO-010PH; NTHL-10; Optical spectrographic analysis; Pacific Ocean; Reducible total; Residual; Scandium; Spencer F. Baird; Strontium; Thorium; Titanium; Wired profile sonde; WP; Ytterbium; Yttrium; Zirconium
    Type: Dataset
    Format: text/tab-separated-values, 386 data points
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  • 2
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    PANGAEA
    In:  Supplement to: Goodell, H G (1964): Eltanin Cruise 05 - Descriptions of cores, submarine photography and dredges. in Goodell, H.G., 1964. Marine geology of the Drake Passage, Scotia Sea, and South Sandwich Trench; USNS Eltanin marine geology cruises 1-8. Sedimentology Research Laboratory Contribution. Department of Geology, Florida State University, Tallahassee, Florida
    Publication Date: 2023-08-28
    Description: Cores, submarine photography and dredges described in this report were taken during the R/V Eltanin Cruise 5 in 1962 by the Department of Geology, Florida State University. Cores and dredges were recovered for 31 stations and are available at the Antarctic Research Facility, Florida State University for sampling and study.
    Keywords: Comment; Deposit type; Depth, bottom/max; DEPTH, sediment/rock; Depth, top/min; Description; Dredge, rock; DRG_R; Elevation of event; ELT05; ELT05.001-MT; ELT05.001-TC; ELT05.002-PG; ELT05.004SS-RD; ELT05.005-PG; ELT05.009-PC; ELT05.009-TC; ELT05.010-TC; ELT05.011-PC; ELT05.012-PC; ELT05.014-PC; ELT05.015-RD; ELT05.016-RD; ELT05.017-RD; ELT05.028-PC; ELT05.029-PC; ELT05.031-PC; ELT05.10-C; ELT05.11-C; ELT05.17-C; ELT05.18-C; ELT05.20-C; ELT05.25-C; ELT05.27-C; ELT05.28-C; ELT05.29-C; ELT05.30-C; ELT05.9-C; Eltanin; Event label; GC; Grab; GRAB; Gravity corer; Latitude of event; Longitude of event; NOAA and MMS Marine Minerals Geochemical Database; NOAA-MMS; PC; Photo/Video; Piston corer; Position; PV; Quantity of deposit; Sample ID; Sediment type; Size; South Pacific Ocean; Substrate type; TRAWL; Trawl net; Uniform resource locator/link to image
    Type: Dataset
    Format: text/tab-separated-values, 396 data points
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  • 3
    Publication Date: 2023-08-28
    Description: In May 1964 the Institute of Marine Science (University of Miami), Scripps Institution of Oceanography (University of California), Woods Hole Oceanographic Institution, and Lamont Geological Observatory (Columbia University) joined in the establishment of the JOINT OCEANOGRAPHIC INSTITUTIONS DEEP EARTH SAMPLING (JOIDES) program. The long range purpose of this organization is to obtain continuous core samples of the entire sedimentary column from the floors of the oceans. It was decided that initial efforts would be limited to water depths of less than 1000 fathoms (6000 feet), and tentative locations were selected for drilling operations off the eastern, western and Gulf coasts of the United States. Near the end of December 1964 it was found that the M/V Caldrill I, a drilling vessel capable of working to depths of 6000 feet, was to engage in drilling operations on the Grand Banks of Newfoundland during the summer of 1965 for the Pan American Petroleum Corporation. Thus it was agreed to organize a drilling program along the track of Caldrill between California and the Grand Banks. Selection was made of an area on the continental shelf and the Blake Plateau off Jacksonville, Florida. Based upon many previous geological and geophysical investigations by the participating laboratories, a considerable body of knowledge had been gained about this region of the continental-oceanic border. For this initial program of JOIDES, the Lamont Geological Observatory was chosen as the operating institution with J. L. Worzel as principal investigator, and C. L. Drake and H. A. Gibbon as program planners.
    Keywords: Blake Plateau, Atlantic Ocean; Caldrill I; Comment; Deposit type; DEPTH, sediment/rock; Description; DRILL; Drilling/drill rig; JOID-6; JOIDES_prelim; NOAA and MMS Marine Minerals Geochemical Database; NOAA-MMS; Position; Quantity of deposit; Sample code/label; Sample ID; Sediment type; Size; Substrate type
    Type: Dataset
    Format: text/tab-separated-values, 10 data points
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  • 4
    Publication Date: 2023-08-28
    Keywords: Atlantic Ocean; Comment; Deposit type; Depth, bottom/max; DEPTH, sediment/rock; Depth, top/min; Description; Dredge, rock; DRG_R; Event label; File name; Identification; Indian Ocean; NOAA and MMS Marine Minerals Geochemical Database; NOAA-MMS; Pacific Ocean; PC; Photo/Video; Piston corer; Position; PV; Quantity of deposit; Sediment type; Size; Substrate type; Uniform resource locator/link to image; V19; V19-1; V19-10; V19-100; V19-103; V19-105; V19-106; V19-109; V19-10C; V19-111; V19-112; V19-115; V19-117; V19-118; V19-119C; V19-11RD; V19-12; V19-121; V19-121C; V19-122C; V19-123; V19-124C; V19-125C; V19-126C; V19-128C; V19-13; V19-130; V19-130C; V19-131; V19-134; V19-136; V19-138; V19-14; V19-141C; V19-144C; V19-145C; V19-15; V19-150; V19-151; V19-152; V19-154; V19-155; V19-157; V19-158; V19-159; V19-161; V19-162C; V19-163; V19-164; V19-165; V19-166; V19-166C; V19-167; V19-168; V19-168C; V19-169; V19-170; V19-171; V19-172; V19-172C; V19-179C; V19-18; V19-182; V19-184; V19-186; V19-192C; V19-198C; V19-1C; V19-1RD; V19-20; V19-201C; V19-205; V19-209; V19-21; V19-210; V19-211; V19-213; V19-214; V19-216; V19-217; V19-22; V19-220C; V19-223; V19-224C; V19-226; V19-228; V19-23; V19-230; V19-231; V19-232; V19-239; V19-242; V19-244; V19-247; V19-248C; V19-254C; V19-255C; V19-269; V19-272; V19-276; V19-280; V19-281; V19-282; V19-28C; V19-295; V19-296; V19-29C; V19-2C; V19-2RD; V19-305; V19-307; V19-312; V19-38; V19-3C; V19-4; V19-43; V19-44; V19-45; V19-5; V19-52; V19-53; V19-54; V19-55; V19-58; V19-59C; V19-5C; V19-6; V19-60; V19-61C; V19-64C; V19-66; V19-67; V19-68; V19-68C; V19-69; V19-69C; V19-7; V19-70; V19-71; V19-72; V19-74C; V19-75; V19-75C; V19-76; V19-78; V19-79; V19-8; V19-80; V19-81; V19-82; V19-83; V19-84; V19-85; V19-87; V19-88; V19-8C; V19-9; V19-91; V19-93; V19-94; V19-96; V19-97; V19-99; V19-9C; Vema; Visual description
    Type: Dataset
    Format: text/tab-separated-values, 3057 data points
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  • 5
    Publication Date: 2023-08-28
    Description: Cores, submarine photography and dredges described in this report were taken during the R/V Eltanin Cruise 6 in 1963 by the Department of Geology, Florida State University. Cores and dredges were recovered for 32 stations along with bottom photography and are available at the Antarctic Research Facility, Florida State University for sampling and study.
    Keywords: Comment; Deposit type; Depth, bottom/max; DEPTH, sediment/rock; Depth, top/min; Description; Dredge, rock; DRG_R; ELT06; ELT06.003-BT; ELT06.003-MT; ELT06.004-BT; ELT06.005-RD; ELT06.006-PC; ELT06.006-RD; ELT06.007-BT; ELT06.007-MT; ELT06.007-PC; ELT06.007-RD; ELT06.007-TC; ELT06.009-B; ELT06.009-RD; ELT06.010-RD; ELT06.011-B; ELT06.011-PC; ELT06.012A-RD; ELT06.012-PC; ELT06.013-PC; ELT06.013-RD; ELT06.014-BT; ELT06.015-BT; ELT06.015-PC; ELT06.016-PC; ELT06.019-PH; ELT06.041-PH; ELT06.10-13C; ELT06.11-13C; ELT06.12-13C; ELT06.13-14C; ELT06.19-12C; ELT06.36-20C; ELT06.41-22C; ELT06.42-23C; ELT06.43-23C; ELT06.44-23C; Eltanin; Event label; File name; GC; Gravity corer; Identification; NOAA and MMS Marine Minerals Geochemical Database; NOAA-MMS; PC; Photo/Video; Piston corer; Position; PV; Quantity of deposit; Sediment type; Size; Southern Ocean; Substrate type; TC; TRAWL; Trawl net; Trigger corer; Uniform resource locator/link to image; Visual description
    Type: Dataset
    Format: text/tab-separated-values, 757 data points
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  • 6
    Publication Date: 2023-08-28
    Keywords: Comment; Deposit type; Depth, bottom/max; DEPTH, sediment/rock; Depth, top/min; Description; Dredge, rock; DRG_R; ELT07; ELT07.001-RD; ELT07.002-MT; ELT07.007-BT; ELT07.008-BT; ELT07.014-PG; ELT07.016-PC; ELT07.016-RD; ELT07.017-PC; ELT07.017-RD; ELT07.018-PC; ELT07-12C; ELT07-13C; ELT07-14C; ELT07-16C; ELT07-20C; ELT07-22C; ELT07-3C; ELT07-5C; Eltanin; Event label; File name; Grab; GRAB; Identification; NOAA and MMS Marine Minerals Geochemical Database; NOAA-MMS; PC; Photo/Video; Piston corer; Position; PV; Quantity of deposit; Sediment type; Size; Southern Ocean; Substrate type; TRAWL; Trawl net; Uniform resource locator/link to image; Visual description
    Type: Dataset
    Format: text/tab-separated-values, 319 data points
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  • 7
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    PANGAEA
    In:  Antarctic Research Facility, Florida State University
    Publication Date: 2023-08-28
    Keywords: Comment; Deposit type; Depth, bottom/max; DEPTH, sediment/rock; Depth, top/min; Description; Elevation of event; ELT08; ELT08.007-PC; ELT08.011-PH; ELT08.012-PH; ELT08.013-PH; ELT08.015-PH; ELT08.016-PH; ELT08-12C; ELT08-14C; ELT08-19C; ELT08-1C; ELT08-2C; ELT08-4C; Eltanin; Event label; File name; GC; Gravity corer; Identification; Latitude of event; Longitude of event; Method/Device of event; NOAA and MMS Marine Minerals Geochemical Database; NOAA-MMS; PC; Photo/Video; Piston corer; Position; PV; Quantity of deposit; Sediment type; Size; Southern Ocean; Substrate type; Uniform resource locator/link to image; Visual description
    Type: Dataset
    Format: text/tab-separated-values, 144 data points
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  • 8
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    In:  Supplement to: Bouma, Arnold H; Marshall, N F (1964): A method for obtaining and analysing undisturbed oceanic sediment samples. Marine Geology, 2(1), 81-99, https://doi.org/10.1016/0025-3227(64)90028-3
    Publication Date: 2023-08-28
    Description: A German coring device (Reineck, 1958) has been improved to obtain oriented, undisturbed cores at any depth of water. The samples are rectangular in shape, 8 × 12 inches in plan and a maximum of 18 inches high. Good cores have been obtained from clayey material as well as from gravelly sand. No disturbances due to coring were observed on the collected samples. These large samples make it possible to conduct many varieties of investigations, such as study of living organisms and shear strength measurements, as soon as the sample is on deck of a ship; radiography on slices, peeling and impregnation techniques, granulometry, mineralogy, porosity, fossil content, etc. Construction and use of the box corer and applications of some of these analytical techniques are described.
    Keywords: BCR; Box corer (Reineck); Comment; Deposit type; DEPTH, sediment/rock; Description; Identification; NOAA and MMS Marine Minerals Geochemical Database; NOAA-MMS; Pacific Ocean; Position; Quantity of deposit; SAN_JUAN_1963; Sediment type; SNJ-C8; Spencer F. Baird; Visual description
    Type: Dataset
    Format: text/tab-separated-values, 7 data points
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  • 9
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    PANGAEA
    In:  Supplement to: Murata, K J; Erd, R C (1964): Composition of sediments from the experimental Mohole Project (Guadalupe Site). Journal of Sedimentary Research, 34(3), 633-655, https://doi.org/10.1306/74D7110E-2B21-11D7-8648000102C1865D
    Publication Date: 2023-08-28
    Description: Based on chemical, spectrographic and X-ray analyses, 34 samples from the experimental Mohole consist of variable proportions of calcite (0-60 percent), biogenic opal (0-50 percent), and normal lithogenous matter (14-97 percent) with an average of 20, 32, and 48 percent, respectively. Contamination with trachytic ash, rhyolitic ash, and saponite and dolomite occurring as alteration products of basaltic material affects the composition of a few samples. Magnesium, manganese, and phosphorus seem to have been derived from basaltic material also. The amounts of barium in the samples seems to be inversely related to sedimentation rates.
    Keywords: Comment; Date/Time of event; Deposit type; DEPTH, sediment/rock; Description; Drillship_CUSS-I; Elevation of event; GC; Gravity corer; Latitude of event; Longitude of event; MOHO-1; MOHOLE_phase-1; NOAA and MMS Marine Minerals Geochemical Database; NOAA-MMS; Pacific Ocean; Position; Quantity of deposit; Sample ID; Sampling/drilling; Sediment type
    Type: Dataset
    Format: text/tab-separated-values, 7 data points
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  • 10
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    In:  Supplement to: Pachadzhanov, D N; Bandurkin, G A; Migdisov, Areg A; Girin, Yury P (1963): Data on the geochemistry of manganese nodules from the Indian Ocean. Geokhimiya, 5, 493-499, hdl:10013/epic.46169.d001
    Publication Date: 2023-08-28
    Description: Analyses are given for the core and outer colliform shell of a manganese nodule collected at a depth of 5000 m in the Indian Ocean, and for the red clay that encloses the nodules. Trace elements determined include rare earths, Nb, Ta, Th, and V. The cores of the nodules were once composed of basaltic rock, but now are phillipsite and nontronite. The outer shell is composed of manganite, with admixed quartz, phillipsite, and some geothite. The correlations established between the redox potentials and the concentration coefficients for 12 elements indicate that Eh plays a greater role in the formation of the manganiferous shells than coprecipitation properties.
    Keywords: GC; Gravity corer; Indian Ocean; NOAA and MMS Marine Minerals Geochemical Database; NOAA-MMS; Vityaz (ex-Mars); Vityaz-31; VITYAZ4575
    Type: Dataset
    Format: application/zip, 2 datasets
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  • 11
    Publication Date: 2023-08-28
    Description: The cores and dredges described in this report were taken on the DODO Expedition in May 1964 until December 1964 by the Scripps Institution of Oceanography from the R/V Argo. A total of 290 cores and dredges were recovered and are available at Scripps for sampling and study.
    Keywords: Argo; Comment; Core; CORE; Date/Time of event; Deposit type; Depth, bottom/max; DEPTH, sediment/rock; Depth, top/min; Description; DODO; DODO-006D; DODO-007D; DODO-008D; DODO-009D-1; DODO-009D-2; DODO-011D; DODO-012D; DODO-013D; DODO-014D; DODO-015D-1; DODO-015D-2; DODO-017PG; DODO-020C; DODO-025PG; DODO-026P; DODO-027P; DODO-027PG; DODO-031PG; DODO-048D; DODO-057P; DODO-060P; DODO-062D; DODO-065P; DODO-065PG; DODO-066DA; DODO-067P; DODO-070C; DODO-072P; DODO-075P; DODO-077G; DODO-084G; DODO-110P; DODO-112P; DODO-113D; DODO-114D; DODO-116D; DODO-123D; DODO-125D; DODO-127D; DODO-128D; DODO-129V; DODO-130G; DODO-132P; DODO-143D; DODO-232D; Dredge; DRG; Elevation of event; Event label; GC; Gravity corer; Indian Ocean; Latitude of event; Longitude of event; Method/Device of event; NOAA and MMS Marine Minerals Geochemical Database; NOAA-MMS; Pacific Ocean; PC; Piston corer; Position; Quantity of deposit; Sample ID; Sediment type; Size; Solomon Sea; Substrate type; Uniform resource locator/link to image
    Type: Dataset
    Format: text/tab-separated-values, 475 data points
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  • 12
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    PANGAEA
    In:  Supplement to: Arrhenius, Gustaf; Bonatti, Enrico (1963): Neptunism and vulcanism in the ocean. Progress in Oceanography, 3, 7-22, https://doi.org/10.1016/0079-6611(65)90005-4
    Publication Date: 2023-08-28
    Description: The origin of authigenic minerals on the ocean floor has been extensively discussed in the past with emphasis on two major processes; precipitation from solutions originating from submarine eruptions, and slow precipitation from sea water of dissolved elements, originating from weathering of continental rocks. It is concluded that in several marine authigenic mineral systems these processes overlap. A diagnostic principle is suggested, permitting a qualitative or semiquantitative discrimination between marine authigenic minerals crystallized from dissolved species, which have spent a long time in solution on the one hand, and the same minerals generated from solutions, near their source on the other. Extensive data are available for the manganese and iron oxide minerals forming manganese nodules. It is indicated on the basis of their composition and structure that many of the nodules found in the vicinity of the continents are made up essentially of manganese derived from continental weathering. In contrast to this group, all of the nodules found in the Pacific area of submarine vulcanism display the criteria for rapid precipitation near the source of solution. The distribution of barium minerals over the deep ocean floor is discussed.The same diagnostic principle is suggested for application to these solids, in order to discriminate between baryte and harmotome crystallized near the source of barium- rich, acidic vulcanites, and the same minerals formed from continental solution with passage through the biosphere. In the case of the authigenic aluminosilicates it is found that many of the framework elements (Si and particularly Al) have low passage time through solution, and the major fraction of these elements is consequently removed from solution in the vicinity of the eruptive source materials. Extensive modification of the crystal structures, however, takes place over long periods of time, adding particularly cations from sea water, and probably to some extent silica from siliceous fossils, which on their decay on the ocean floor appear to contribute to the silicate framework of growing zeolites. The marked fractionation of the rare earth ions between coexisting phases is pointed out, with discussion of the potential use of this phenomenon to indicate the processes of formation. The use of the hafnium/zirconium ratio as a tracer for the igneous source type is suggested, and the application of ideally imperfect tracers to establish the varying relative importance of volcanic versus halmeic source of marine minerals is discussed in general.
    Keywords: ALB-13; ALB-2; Albatross (1882-1921); Albatross1899-1900; Albatross1904-1905; ALBTR-13; ALBTR-2; ALBTR-4711; ALBTR-4721; Chromium; Cobalt; DEPTH, sediment/rock; DNWB0ABD; DOWNWIND-B1; DOWNWIND-H; Dredge; DRG; DWBD4; DWHD72; Event label; Horizon; Identification; NOAA and MMS Marine Minerals Geochemical Database; NOAA-MMS; Optical spectrographic analysis; Pacific Ocean; Spencer F. Baird
    Type: Dataset
    Format: text/tab-separated-values, 42 data points
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  • 13
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    In:  National Institute of Oceanography, Wormely | Supplement to: National Institute of Oceanography, Wormley (1964): International Indian Ocean Expedition, RRS Discovery Cruise 2 Report. Geology and Geophysics in N.W. Indian Ocean, 23 August to 4 December 1963. The Royal Society, London, 35 pp, https://www.bodc.ac.uk/resources/inventories/cruise_inventory/reports/d2.pdf
    Publication Date: 2023-08-28
    Description: This report gives a comprehensive general description of the scientific activities of Cruise 2 of R. R. S. 'Discovery'. These were largely geological and geophysical and were part of the British contribution to the International Indian Ocean Expedition. In addition to the thirteen geophysicists and geologists on board, there were five scientists involved in ocean chemistry, temperature measurements and ornithology making continuous observations - their accounts are also included. The report of a geological expediton ashore in the Seychelles is given in section 6.
    Keywords: D2; D5106; D5111; D5113; D5123; D5127; D5128; D5132; D5133; D5136; D5137; D5138; D5172; D5173; D5175; D5179; Deposit type; DEPTH, sediment/rock; Description; Discovery (1962); Dredge, rock; DRG_R; Elevation of event; Event label; Identification; Indian Ocean; Latitude of event; Longitude of event; Method/Device of event; NOAA and MMS Marine Minerals Geochemical Database; NOAA-MMS; Photo/Video; Position; PV; Quantity of deposit; Sediment type; Substrate type; Visual description
    Type: Dataset
    Format: text/tab-separated-values, 91 data points
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  • 14
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    In:  Supplement to: Arrhenius, Gustaf; Mero, John L; Korkisch, J (1964): Origin of oceanic manganese minerals. Science, 144(3615), 170-173, https://doi.org/10.1126/science.144.3615.170
    Publication Date: 2023-08-28
    Description: A criterion is suggested for discrimination between ferromanganese oxide minerals, deposited after the introduction of manganese and associated elements in sea water solution at submarine vulcanism, and minerals which are slowly formed from dilute solution, largely of continental origin. The simlultaneous injection of thorium into the ocean by submarine vulcanism is indicated, and its differentiation from continental thorium introduced into the ocean by runoff is discussed.
    Keywords: ALB-13; ALB-2; Albatross (1882-1921); Albatross1899-1900; Albatross1904-1905; ALBTR-13; ALBTR-2; ALBTR-4711; ALBTR-4721; Cobalt; Colorimetry; DEPTH, sediment/rock; DNWB0ABD; DOWNWIND-B1; DOWNWIND-H; Dredge; DRG; DWBD4; DWHD72; Event label; Horizon; Identification; NOAA and MMS Marine Minerals Geochemical Database; NOAA-MMS; Optical spectrographic analysis; Pacific Ocean; Spencer F. Baird; Thorium
    Type: Dataset
    Format: text/tab-separated-values, 18 data points
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  • 15
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    In:  Supplement to: Menard, H William (1964): Manganese nodules (Chapter 8). In: Marine Geology of the Pacific. McGraw-Hill, New York, U.S.A., 171-190
    Publication Date: 2023-08-28
    Description: Prof. H. H. W. Menard has brought together nearly all that was known of the Pacific geology in the early 1960s. His book contains a particular chapter on manganese nodules giving a stimulating review of the features and processes known to govern their distribution and chemical composition.
    Keywords: Comment; Deposit type; DEPTH, sediment/rock; Description; Eastern Basin, Pacific Ocean; Eastern Mariana Basin, Pacific Ocean; Elevation of event; Event label; Latitude of event; Longitude of event; Method/Device of event; NOAA and MMS Marine Minerals Geochemical Database; NOAA-MMS; Northwestern Basin, Pacific Ocean; Pacific Ocean; Photo/Video; Position; PV; Quantity of deposit; Sample ID; Sediment type; Size; Substrate type; VITYAZ; Vityaz (ex-Mars); Vityaz-29; VITYAZ3630-PH; VITYAZ3632-PH; VITYAZ3644-PH; VITYAZ3844-PH; VITYAZ3846-PH; VITYAZ4239-PH; VITYAZ4249-PH; VITYAZ4261-PH; VITYAZ4265-PH; VITYAZ4273-PH; VITYAZ4279-PH; VITYAZ4285-PH
    Type: Dataset
    Format: text/tab-separated-values, 131 data points
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  • 16
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    In:  Supplement to: Hewett, DF; Fleischer, Michael; Conklin, Nancy (1963): Deposits of the manganese oxides; supplement. Economic Geology, 58(1), 1-51, https://doi.org/10.2113/gsecongeo.58.1.1
    Publication Date: 2023-08-28
    Description: In an earlier paper by two of the authors the conclusion was reached that the 33 recognized species of oxides of Mn could be separated into 3 groups: 1) those which appeared to be persistently supergene in origin, 2) those which appeared to be persistently hypogene, and 3) those which were supergene in some localities and hypogene in other localities. When that paper was written, there were available about 250 X-ray diffraction analyses of mineral specimens, also 35 complete and about 150 partial chemical analyses. The conclusions of that paper were based upon the interpretation of the geologic conditions under which these specimens occurred. Late in the preparation of that paper, it seemed worthwhile to make numerous semiquantitative analyses of specimens, largely from 9 western [U.S.A] states, selected carefully from 5 groups of geologic environments, in the hope that the frequency and percentages of some elements might be distinctive of the several geologic groups. For this purpose, 95 specimens were selected from the 5 groups, as follows: 19 specimens interpreted as supergene oxides by the geologists who collected them, 35 specimens of hypogene vein oxides, 22 specimens of Mn-bearing hot spring aprons, 9 specimens of stratified oxides, and 10 specimens of deep-sea nodules. The spectrographic analyses here recorded indicate that a group of elements - W, Ba, Sr, Be, As, Sb, Tl, and Ge - are present more commonly, and largely in higher percentages, in the hypogene oxide than in the supergene oxides and thus serve to indicate different sources of the Mn. Also, the frequency and percentages of some of these elements indicate a genetic relation of the manganese oxides in hypogene veins, hot spring aprons, and stratified deposits. The analyses indicate a declining percentage of some elements from depth to the surface in these 3 related groups and increasing percentages of some other elements. It is concluded that some of the elements in deep-sea nodules indicate that sources other than rocks decomposed on the continents, probably vulcanism on the floors of the seas, have contributed to their formation.
    Keywords: ALB-13; ALB-173; Albatross (1882-1921); Albatross1899-1900; Albatross1904-1905; ALBTR-13; ALBTR-173; ALBTR-4662; Aluminium; Barium; Beryllium; Bismuth; Boron; Calcium; Cerium; Chromium; Cobalt; Copper; DEPTH, sediment/rock; DNWB0ABD; DOWNWIND-B1; DOWNWIND-H; Dredge; Dredge, chain bag; Dredge, rock; DRG; DRG_C; DRG_R; DWBD1; DWHD47; Elevation of event; Event label; FANB01BD; FANBD-25D; FANFARE-B; Horizon; Indian Ocean; Iron; Lanthanum; Latitude of event; Lead; LGO-BT-57 or VM14 SBT57 (SIO); Longitude of event; Magnesium; MDPC02HO-MP-025F-2; MDPC02HO-MP-033K; MIDPAC; Molybdenum; MPC-25F-2; MPC-33K; NAGA; NAGA10C; Neodymium; Nickel; Niobium; NOAA and MMS Marine Minerals Geochemical Database; NOAA-MMS; Pacific Ocean; Photo/Video; Potassium; PV; Sample ID; Scandium; Silicon; Sodium; Spectrographic analysis; Spencer F. Baird; Stranger; Strontium; Thallium; Titanium; V14; V14-57RD; Vanadium; Vema; Ytterbium; Yttrium; Zinc; Zirconium
    Type: Dataset
    Format: text/tab-separated-values, 296 data points
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  • 17
    Publication Date: 2023-08-28
    Description: The cores described in this report were taken during the R/V Robert Conrad Cruise 02 from 26 until 28 January 1963 by the Lamont Geological Observatory, Columbia University. A total of 5 cores were recovered and are available at Lamont-Doherty Earth Observatory for sampling and study.
    Keywords: Atlantic Ocean; Comment; Date/Time of event; Deposit type; Depth, bottom/max; DEPTH, sediment/rock; Depth, top/min; Description; Elevation of event; Event label; Latitude of event; Longitude of event; NOAA and MMS Marine Minerals Geochemical Database; NOAA-MMS; PC; Piston corer; Position; Quantity of deposit; RC02; RC0201; RC02-1; RC02-2; RC02-4; RC02-5; Robert Conrad; Sample ID; Sediment type; Size
    Type: Dataset
    Format: text/tab-separated-values, 75 data points
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  • 18
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    In:  Institute of Oceanographic Sciences, Wormley
    Publication Date: 2023-08-28
    Description: This report gives a comprehensive general description of the scientific activities of Cruise 2 of R. R. S. 'Discovery'. These were largely geological and geophysical and were part of the British contribution to the International Indian Ocean Expedition. In addition to the thirteen geophysicists and geologists on board, there were five scientists involved in ocean chemistry, temperature measurements and ornithology making continuous observations - their accounts are also included. The report of a geological expediton ashore in the Seychelles is given in section 6.
    Keywords: D2; D5106; D5111; D5113; D5123; D5127; D5128; D5132; D5133; D5136; D5137; D5138; D5172; D5173; D5175; D5179; Deposit type; DEPTH, sediment/rock; Description; Discovery (1962); Dredge, rock; DRG_R; Event label; Identification; Indian Ocean; NOAA and MMS Marine Minerals Geochemical Database; NOAA-MMS; Photo/Video; Position; PV; Quantity of deposit; Sediment type; Substrate type; Uniform resource locator/link to image; Visual description
    Type: Dataset
    Format: text/tab-separated-values, 95 data points
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  • 19
    Publication Date: 2023-08-28
    Description: The cores described in this report were taken during the R/V Robert Conrad Cruise 05 from March until April 1963 by the Lamont Geological Observatory, Columbia University. A total of 13 cores were recovered and are available at Lamont-Doherty Earth Observatory for sampling and study.
    Keywords: Atlantic Ocean; Comment; Date/Time of event; Deposit type; Depth, bottom/max; DEPTH, sediment/rock; Depth, top/min; Description; Dredge, rock; DRG_R; Elevation of event; Event label; Latitude of event; Longitude of event; NOAA and MMS Marine Minerals Geochemical Database; NOAA-MMS; PC; Piston corer; Position; Quantity of deposit; RC05; RC05-1; RC05-10; RC05-11; RC05-12; RC05-13; RC05-14; RC05-1RD; RC05-7; RC05-8; RC05-9; Robert Conrad; Sample ID; Sediment type; Size; Substrate type
    Type: Dataset
    Format: text/tab-separated-values, 306 data points
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  • 20
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    In:  Supplement to: Burckle, Lloyd H; Hekinian, Roger; Lair, C (1963): Robert Conrad Cruise 04 - Preliminary Megascopic Descriptions of Split Cores. Lamont Geological Observatory, Columbia University, New York, unpublished, 13 pp
    Publication Date: 2023-08-28
    Description: The cores described in this report were taken during the R/V Robert Conrad Cruise 04 in March 1963 by the Lamont Geological Observatory, Columbia University. A total of 9 cores were recovered and are available at Lamont-Doherty Earth Observatory for sampling and study.
    Keywords: Atlantic Ocean; Comment; Core; CORE; Date/Time of event; Deposit type; Depth, bottom/max; DEPTH, sediment/rock; Depth, top/min; Description; Elevation of event; Event label; Latitude of event; Longitude of event; NOAA and MMS Marine Minerals Geochemical Database; NOAA-MMS; PC; Piston corer; Position; Quantity of deposit; RC04; RC04-1; RC04-2; RC04-3; RC04-4; RC04-7CC; RC04-8; Robert Conrad; Sample ID; Sediment type
    Type: Dataset
    Format: text/tab-separated-values, 114 data points
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  • 21
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    In:  Supplement to: Lamont-Doherty Earth Observatory (1963): Robert Conrad Cruise 06 - Preliminary Megascopic Descriptions of Split Cores. Lamont Geological Observatory, Columbia University, New York, unpublished, 9 pp
    Publication Date: 2023-08-28
    Description: The cores described in this report were taken during the R/V Robert Conrad Cruise 06 from May until June 1963 by the Lamont Geological Observatory, Columbia University. A total of 5 cores were recovered and are available at Lamont-Doherty Earth Observatory for sampling and study.
    Keywords: Comment; Date/Time of event; Deposit type; Depth, bottom/max; DEPTH, sediment/rock; Depth, top/min; Description; Elevation of event; Event label; Latitude of event; Longitude of event; NOAA and MMS Marine Minerals Geochemical Database; NOAA-MMS; PC; Piston corer; Position; Quantity of deposit; RC06; RC06-1; RC06-2; RC06-3; Robert Conrad; Sample ID; Sediment type; Size
    Type: Dataset
    Format: text/tab-separated-values, 55 data points
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  • 22
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    In:  Supplement to: Anderson, N D; Burckle, Lloyd H; Baker, R (1963): R/V Robert Conrad Cruise 7 - Preliminary Megascopic Descriptions of Split Cores. Lamont Geological Observatory, Columbia University, New York, unpublished, 48 pp
    Publication Date: 2023-08-28
    Description: The cores and dredges described in this report were taken during the Robert Conrad Cruise 7 from July until October 1963 by the Lamont Geological Observatory, Columbia University from the R/V Robert Conrad . A total of 29 cores and dredges were recovered and are available at Lamont-Doherty Earth Observatory for sampling and study.
    Keywords: Atlantic Ocean; Comment; Date/Time of event; Deposit type; Depth, bottom/max; DEPTH, sediment/rock; Depth, top/min; Description; Dredge, rock; DRG_R; Elevation of event; Event label; Latitude of event; Longitude of event; NOAA and MMS Marine Minerals Geochemical Database; NOAA-MMS; PC; Piston corer; Position; Quantity of deposit; RC07; RC0701-RC0708; RC07-1; RC07-10; RC07-12; RC07-13; RC07-15; RC07-16; RC07-17; RC07-1RD; RC07-20; RC07-21; RC07-25; RC07-26; RC07-28; RC07-29; RC07-3; RC07-30; RC07-4; RC07-5; RC07-6; RC07-7; Robert Conrad; Sample ID; Sediment type; Size; Substrate type
    Type: Dataset
    Format: text/tab-separated-values, 353 data points
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  • 23
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    In:  Supplement to: Kaneps, A; Lair, C; Morgenstein, M (1964): R/V Robert Conrad Cruise 8 - Preliminary Megascopic Descriptions of Split Cores. Lamont Geological Observatory, Columbia University, New York, unpublished, 208
    Publication Date: 2023-08-28
    Description: The cores and dredges described in this report were taken during the Robert Conrad Cruise 8 from November 1963 until August 1964 by the Lamont Geological Observatory, Columbia University from the R/V Robert Conrad. A total of 140 cores and dredges were recovered and are available at Lamont-Doherty Earth Observatory for sampling and study.
    Keywords: Atlantic Ocean; Comment; Date/Time of event; Deposit type; Depth, bottom/max; DEPTH, sediment/rock; Depth, top/min; Description; Dredge, rock; DRG_R; Elevation of event; Event label; Latitude of event; Longitude of event; NOAA and MMS Marine Minerals Geochemical Database; NOAA-MMS; PC; Piston corer; Position; Quantity of deposit; RC08; RC08-100; RC08-102; RC08-103; RC08-106; RC08-107; RC08-109; RC08-11; RC08-110; RC08-112; RC08-113; RC08-114; RC08-116; RC08-12; RC08-120; RC08-125; RC08-126; RC08-128; RC08-129; RC08-12RD; RC08-130; RC08-135; RC08-137; RC08-14; RC08-140; RC08-141; RC08-143; RC08-144; RC08-145; RC08-147; RC08-148; RC08-15; RC08-16; RC08-19; RC08-20; RC08-21; RC08-25; RC08-26; RC08-27; RC08-31; RC08-32; RC08-34; RC08-35; RC08-36; RC08-37; RC08-38; RC08-39; RC08-42; RC08-43; RC08-44; RC08-45; RC08-48; RC08-49; RC08-4RD; RC08-5; RC08-50; RC08-53; RC08-55; RC08-6; RC08-63; RC08-67; RC08-69; RC08-70; RC08-71; RC08-72; RC08-73; RC08-75; RC08-7RD; RC08-8; RC08-80; RC08-81; RC08-82; RC08-83; RC08-84; RC08-85; RC08-86; RC08-87; RC08-88; RC08-89; RC08-8RD; RC08-90; RC08-94; RC08-97; RC08-98; RC08-99; RC08-9RD; Robert Conrad; Sample ID; Sediment type; Size; Substrate type
    Type: Dataset
    Format: text/tab-separated-values, 1616 data points
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  • 24
    Publication Date: 2023-08-28
    Keywords: Comment; Deposit type; DEPTH, sediment/rock; Description; Event label; GC; Gravity corer; Identification; Mariana Basin, Pacific Ocean; NOAA and MMS Marine Minerals Geochemical Database; NOAA-MMS; Northwestern Basin, Pacific Ocean; OKEAN; Okean Grab; Position; Quantity of deposit; Sediment type; Size; Substrate type; TRAWL; Trawl net; Visual description; VITYAZ; Vityaz (ex-Mars); Vityaz-25; Vityaz-29; VITYAZ3150-TR; VITYAZ3631-GR-1; VITYAZ3729-GC-1; VITYAZ3802-TR; VITYAZ3899-GR-1; VITYAZ3996-TR; VITYAZ4074-TR; VITYAZ4084-GR-1; VITYAZ4090-TR; VITYAZ4104-TR; VITYAZ4191-TR; VITYAZ4217-TR; VITYAZ4265-TR; VITYAZ4281-TR; VITYAZ4331-GR-1; VITYAZ4351-GR; VITYAZ4359-GR-1; VITYAZ4362-GR-1; VITYAZ4370-TR
    Type: Dataset
    Format: text/tab-separated-values, 149 data points
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  • 25
    Publication Date: 2023-08-28
    Keywords: Aluminium oxide; Calcium oxide; Cobalt oxide; DEPTH, sediment/rock; Description; DNWB0ABD; DOWNWIND-B1; Dredge; DRG; DWBD15; DWBD4; Event label; Identification; Iron oxide, Fe2O3; Loss on ignition; Magnesium oxide; Manganese oxide; Mariana Basin, Pacific Ocean; Nickel oxide; NOAA and MMS Marine Minerals Geochemical Database; NOAA-MMS; Northwestern Basin, Pacific Ocean; OKEAN; Okean Grab; Oxygen; Pacific Ocean; Phosphorus pentoxide; Silicon dioxide; Spencer F. Baird; Titanium dioxide; TRAWL; Trawl net; VITYAZ; Vityaz (ex-Mars); Vityaz-29; VITYAZ3631-GR-1; VITYAZ3802-TR; VITYAZ3899-GR-1; VITYAZ3996-TR; VITYAZ4084-GR-1; VITYAZ4090-TR; VITYAZ4104-TR; VITYAZ4191-TR; VITYAZ4281-TR; VITYAZ4351-GR; VITYAZ4370-TR; Wet chemistry
    Type: Dataset
    Format: text/tab-separated-values, 252 data points
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  • 26
    Publication Date: 2023-08-28
    Keywords: Aluminium oxide; Barium oxide; Calcium oxide; Carbon dioxide; Cobalt oxide; Copper(II) oxide; DEPTH, sediment/rock; Description; DOWNWIND-H; Dredge; DRG; DWHD47; DWHD72; Event label; GC; Gravity corer; Horizon; Identification; Iron oxide, Fe2O3; Lead oxide; Magnesium oxide; Manganese dioxide; Manganese oxide; Nickel oxide; NOAA and MMS Marine Minerals Geochemical Database; NOAA-MMS; Northwestern Basin, Pacific Ocean; OKEAN; Okean Grab; Pacific Ocean; Potassium oxide; Silicon dioxide; Sodium oxide; Titanium dioxide; TRAWL; Trawl net; VITYAZ; Vityaz (ex-Mars); Vityaz-25; Vityaz-29; VITYAZ3150-TR; VITYAZ3729-GC-1; VITYAZ4074-TR; VITYAZ4217-TR; VITYAZ4265-TR; VITYAZ4331-GR-1; VITYAZ4359-GR-1; VITYAZ4362-GR-1; Water in rock; Wet chemistry
    Type: Dataset
    Format: text/tab-separated-values, 212 data points
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  • 27
    Publication Date: 2023-08-28
    Keywords: Deposit type; DEPTH, sediment/rock; Description; Event label; Identification; NOAA and MMS Marine Minerals Geochemical Database; NOAA-MMS; Northwestern Basin, Pacific Ocean; Position; Quantity of deposit; Size; Substrate type; TRAWL; Trawl net; Visual description; VITYAZ; Vityaz (ex-Mars); VITYAZ3782-TR; VITYAZ3996-TR
    Type: Dataset
    Format: text/tab-separated-values, 13 data points
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  • 28
    Publication Date: 2023-08-28
    Keywords: Calcium; DEPTH, sediment/rock; Description; Emanescence radiometry; Event label; Gas chromatography; Identification; Insoluble residue; Iron; Loss on ignition; Luminescent analysis; Manganese; Nickel; NOAA and MMS Marine Minerals Geochemical Database; NOAA-MMS; Northwestern Basin, Pacific Ocean; Phosphorus; Radium; Silicon; Thorium; Thorium-230; TRAWL; Trawl net; Uranium; VITYAZ; Vityaz (ex-Mars); VITYAZ3782-TR; VITYAZ3996-TR; Wet chemistry; X-ray radiometry
    Type: Dataset
    Format: text/tab-separated-values, 142 data points
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  • 29
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    In:  Supplement to: Nikolayev, D S; Yefimova, E I (1963): On the age of iron-manganese concretions from the Indian and Pacific Oceans. Geochemistry, 7, 703-714, hdl:10013/epic.47397.d001
    Publication Date: 2023-08-28
    Description: Uranium, radium, thorium and ionium were determined directly on seven concretions from three stations in the Indian Ocean, and on two concretions and a manganese-rich crust from two stations in the Pacific Ocean. The uranium content averages 3 to 5 gamma/g and the thorium content varies only slightly, but the Th/U ratio in the concretions is typically 2 to 5 in the Indian Ocean and 5 to 15.5 in the Pacific. The ionium content ranges from 1.0 x 10-9 to 3.6 10**-9 g/g in concretions from both oceans. Radium is more abundant in specimens from the Pacific Ocean (Ra = 3 - 12.7 x 10**-11 g/g) than from the Indian Ocean (1.5 - 5.2 x 10**-11 g/g). Analyses for Ca, Mn, Fe, Si, Ni, P, and ignition loss are also given. Radioactive equilibria between uranium, ionium, and radium are strongly disturbed throughout the concretions, and the RA/U and lo/U ratios generally exceed equilibrium ratios. Migration of radium from interior layers was established, so that neither determination of the ages of the concretions nor of their rates of growth can be considered reliable. The age of the concretions cannot exceed 800,000 years, and all grew within relatively short periods of time; there may have been "dormant" periods during growth. Estimates of growth rates are calculated from the radium and ionium contents; they show marked discordance.
    Keywords: NOAA and MMS Marine Minerals Geochemical Database; NOAA-MMS; Northwestern Basin, Pacific Ocean; TRAWL; Trawl net; VITYAZ; Vityaz (ex-Mars); VITYAZ3782-TR; VITYAZ3996-TR
    Type: Dataset
    Format: application/zip, 2 datasets
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  • 30
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    In:  Supplement to: Nayudu, Y Rammohanroy (1964): Palagonite tuffs (hyaloclastites) and the products of post-eruptive processes. Bulletin of Volcanology, 27(1), 391-410, https://doi.org/10.1007/BF02597539
    Publication Date: 2023-08-28
    Description: A synoptic review of the studies of well-known occurrences of palagonite tuffs is presented. Included are palagonite tuffs from Iceland, and pillow-lava palagonite complexes from Columbia River basalts and from the central Oregon coast. Additional petrologic and x-ray defraction data for selected samples are presented. Petrologic evidence shows that basaltic glass of aqueous tuffs and breccias consists of sideromelane, which is susceptible to palagonitization. It is shown that palagonitization is a selective alteration process, involving hydration, oxidation and zeolitization. Some of the manganese nodules dredged from the Pacific Ocean floor contain nucleus of palagonite-tuff breccias or of zeolite. A brief megascopic and microscopic description of nodules from the south Pacific, the Mendocino ridge and the 'Horizon' Nodule from the north Pacific is presented. Petrographic studies of palagonite-tuff breccias of manganese nodules and other palagonites suggest that migration and segregation of metallic elements occur during and subsequent to palagonitization. During the palagonitization of sideromelane, nearly 30 percent of sea water is absorbed. The hydration of sideromelane is also accompanied by oxidation of iron and other elements. These oxides may be released either in colloidal form or in true solution and tend to precipitate first from the unstable palagonite.
    Keywords: CHIN02BD; CHIN0ABD-002G; CHINOOK; CHNK-2G; Date/Time of event; DEPTH, sediment/rock; Description; DOWNWIND-H; Dredge; Dredge, chain bag; DRG; DRG_C; DWHD72; Elevation of event; Event label; FANB01BD; FANBD-25D; FANFARE-B; GC; Gravity corer; Horizon; Latitude of event; Longitude of event; NOAA and MMS Marine Minerals Geochemical Database; NOAA-MMS; Northern_Holiday; North-West Pacific Ocean; NTHL02HO-010PH; NTHL-10; Pacific Ocean; Sample code/label; Sample ID; Spencer F. Baird; Uniform resource locator/link to image; Wired profile sonde; WP
    Type: Dataset
    Format: text/tab-separated-values, 16 data points
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  • 31
    Publication Date: 2023-08-28
    Keywords: Deposit type; DEPTH, sediment/rock; Description; Elevation of event; GC; Gravity corer; Indian Ocean; Latitude of event; Longitude of event; Method/Device of event; NOAA and MMS Marine Minerals Geochemical Database; NOAA-MMS; Position; Quantity of deposit; Sample ID; Sediment type; Size; Substrate type; Vityaz (ex-Mars); Vityaz-31; VITYAZ4575
    Type: Dataset
    Format: text/tab-separated-values, 8 data points
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  • 32
    Publication Date: 2023-08-28
    Description: This collection of data on manganese nodules on the floor of the Pacific Ocean represents all the information that was available to the authors in May, 1964. It is compiled from both published references and original data. No attempt is made here to generalize or to speculate on the origin of the manganese or associated elements further discussion of these aspects of the subject may be had by reference to the literature.
    Keywords: ALB-13; ALB-173; ALB-31; Albatross (1882-1921); Albatross1899-1900; Albatross1904-1905; ALBTR-13; ALBTR-173; ALBTR-31; ALBTR-4660; ALBTR-4662; ALBTR-4676; ALBTR-4681; ALBTR-4685; ALBTR-4701; ALBTR-4711; ALBTR-4721; CARN_Revelle_46; CARN_Revelle_78; CARN7-150; CARN7-86; CARN-Cruise7; Carnegie; CASC-5D; CASCADIA; CHA-299; CHA-302; Challenger1872; CHIN02BD; CHIN02BD-016G; CHINOOK; CHNK-16G; CHUB01BD; CHUB01BD-002G; CHUB01BD-034G; CHUB-2; CHUB-34; CHUB5; CHUBASCO; Core; CORE; DNWB0ABD; DNWB0ABD-016G; DNWB0ABD-017G; DNWB0ABD-019G; DNWB0BBD; DNWB0BBD-037G; DNWB0BBD-040G; DNWB0BBD-043G; DNWB0BBD-048G; DNWB0BBD-052G; DNWB0BBD-054G; DNWB0BBD-055G; DNWB0BBD-056G; DNWB0DBD; DNWB0DBD-147GB; DNWH0AHO-004H; DNWH0BHO-034G; DNWH0DHO-092H; DOWNWIND-B1; DOWNWIND-B2; DOWNWIND-B4; DOWNWIND-H; Dredge; Dredge, rock; DRG; DRG_R; DWBD1; DWBD2; DWBD4; DWBD5; DWBD7; DWBG147B; DWBG16; DWBG17; DWBG19; DWBG37; DWBG40; DWBG43; DWBG48; DWBG52; DWBG54; DWBG55; DWBG56; DWBG78; DWHD15; DWHD16; DWHD47; DWHD55; DWHD72; DWHG34; DWHH4; DWHH92; Eastern Basin, Pacific Ocean; Epce; GC; Grab; GRAB; Gravity corer; H.M.S. Challenger (1872); Horizon; MDPC02HO-MP-025F-1; MDPC02HO-MP-033D; MDPC03HO-MP-043A; MIDPAC; MPC-25F-1; MPC-33D; MPC-43A; NAGA; NAGA8C; NOAA and MMS Marine Minerals Geochemical Database; NOAA-MMS; North-East Pacific Ocean; Pacific Ocean; SIO-DX-1; Spencer F. Baird; Stranger; TRAWL; Trawl net; V15; V15-126; Vema; Vityaz (ex-Mars); Vityaz-29; VITYAZ4239-TR; VITYAZ4289-TR
    Type: Dataset
    Format: application/zip, 3 datasets
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  • 33
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    In:  Supplement to: Skornyakova, Nadezhda S; Andrushchenko, Polina F; Fomina, Lidiya S (1964): Chemical composition of the Pacific ocean's iron-manganese concretions. Deep Sea Research and Oceanographic Abstracts, 11(1), 93-104, https://doi.org/10.1016/0011-7471(64)91086-1
    Publication Date: 2023-08-28
    Description: One the most interesting features of ocean sedimentation is the manganese formations on the surface of the ocean floor in some areas. These are especially widespread in the Pacific Ocean as concretions, grains, and crusts on rock fragments and bedrock outcrops. Iron-manganese concretions are the most abundant as they completely cover about 10% of the bottom of the Pacific Ocean where there are ore concentrations. The concretions occupy from 20-50% of the bottom and up to 80-90% on separate submarine rises. Such concretions are found in different types of bottom deposits, from abyssal red clays to terrigenous muds, but they occur most widely in red clays and quite often in carbonate muds. Their shape and their dimensions are very diverse and change from place to place, from station to station, varying from 0.5-20 cm. They may be oval, globular, reniform, or slaggy and often they are fiat or isometric concretions of an indefinite shape. The concretions generally have nuclei of pumice, basalt fragments, clayey and tuffaceous material, sharks' teeth, whale ossicles, and fossil sponges. Most concretions have concentric layers, combined with dendritic ramifications of iron and manganese oxides.
    Keywords: DNWB0ABD; DOWNWIND-B1; DOWNWIND-H; Dredge; DRG; DWBD15; DWBD4; DWHD47; DWHD72; GC; Gravity corer; Horizon; Mariana Basin, Pacific Ocean; NOAA and MMS Marine Minerals Geochemical Database; NOAA-MMS; Northwestern Basin, Pacific Ocean; OKEAN; Okean Grab; Pacific Ocean; Spencer F. Baird; TRAWL; Trawl net; VITYAZ; Vityaz (ex-Mars); Vityaz-25; Vityaz-29; VITYAZ3150-TR; VITYAZ3631-GR-1; VITYAZ3729-GC-1; VITYAZ3802-TR; VITYAZ3899-GR-1; VITYAZ3996-TR; VITYAZ4074-TR; VITYAZ4084-GR-1; VITYAZ4090-TR; VITYAZ4104-TR; VITYAZ4191-TR; VITYAZ4217-TR; VITYAZ4265-TR; VITYAZ4281-TR; VITYAZ4331-GR-1; VITYAZ4351-GR; VITYAZ4359-GR-1; VITYAZ4362-GR-1; VITYAZ4370-TR
    Type: Dataset
    Format: application/zip, 3 datasets
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  • 34
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    In:  Supplement to: SCRIPPS Institution of Oceanography (1963): LUSIAD Expedition, May 1962-August 1963, List of sediment cores and dredge hawls, R/V Argo and R/V Horizon. Scripps Institution of Oceanography, UC San Diego, unpublished, 29 pp, https://www.ngdc.noaa.gov/mgg/curator/data/argo/lusiad/lusiad_expedition_report.pdf
    Publication Date: 2023-08-28
    Description: The cores and dredges described in this report were taken on the LUSIAD Expedition from May 1962 until August 1963 by the Scripps Institution of Oceanography from both the R/V Argo and the R/V Horizon. A total of 310 cores and dredges were recovered and are available at Scripps for sampling and study.
    Keywords: Argo; Atlantic Ocean; Comment; Coral Sea; D2; D3; D4; D5; Date/Time of event; Deposit type; Depth, bottom/max; DEPTH, sediment/rock; Depth, top/min; Description; Dredge; DRG; Elevation of event; Event label; GC; Gravity corer; Horizon; Indian Ocean; Java Sea; Latitude of event; Longitude of event; LSDA; LSDA-013D; LSDA-102G; LSDA-119G; LSDA-121G; LSDA-122G; LSDA-123G; LSDA-124G; LSDA-125G; LSDA-126G; LSDA-131G; LSDA-132P; LSDA-132PG; LSDA-134P; LSDA-138G; LSDA-138V; LSDA-139GB; LSDA-140G; LSDA-145PB; LSDA-145PGA; LSDA-145PGB; LSDA-147PG; LSDA-148G; LSDA-155V; LSDA-157V; LSDA-162G; LSDA-179D; LSDA-194G; LSDA-199D; LSDA-219D; LSDA-222D; LSDH; LSDH-022G; LSDH-022V; LSDH-023G; LSDH-034V; LSDH-035V; LSDH-036V; LSDH-038G; LSDH-042V; LSDH-045G; LSDH-046V; LSDH-053G; LSDH-054G; LSDH-055V; LSDH-063G; LSDH-078P; LSDH-085G; LSDH-086G; LSDH-087P; LSDH-089PG; LSDH-089V; LSDH-090P; LSDH-090PG; LSDH-093P; LSDH-093PG; LSDH-093V; LSDH-095G; LSDH-099G; LSDH-100G; LSDH-100V; LSDH-102G; LUSIAD-A; LUSIAD-H; NOAA and MMS Marine Minerals Geochemical Database; NOAA-MMS; Pacific Ocean; PC; Piston corer; Position; Quantity of deposit; Sample ID; Sediment type; Size; Substrate type; Uniform resource locator/link to image
    Type: Dataset
    Format: text/tab-separated-values, 633 data points
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  • 35
    Publication Date: 2023-08-28
    Keywords: Aluminium oxide; Calcium oxide; Carbon, organic, total; DEPTH, sediment/rock; Description; GC; Gravity corer; Indian Ocean; Iron oxide, Fe2O3; Iron oxide, FeO; Magnesium oxide; Manganese oxide; Niobium (V) oxide; NOAA and MMS Marine Minerals Geochemical Database; NOAA-MMS; Phosphorus pentoxide; Potassium oxide; Sample ID; Silicon dioxide; Sodium oxide; Tantalum (V) oxide; Thorium; Titanium dioxide; Vanadium; Vityaz (ex-Mars); Vityaz-31; VITYAZ4575; Wet chemistry
    Type: Dataset
    Format: text/tab-separated-values, 34 data points
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  • 36
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    PANGAEA
    In:  Scripps Institution of Oceanography, UC San Diego
    Publication Date: 2023-09-25
    Keywords: CARR2_2D; CARR2_4D; CARR2_5G; CARR2_6D; CARR2_9D; CARROUSEL2; Deposit type; DEPTH, sediment/rock; Description; Dredge; DRG; Event label; GC; Gravity corer; Identification; NOAA and MMS Marine Minerals Geochemical Database; NOAA-MMS; Pacific Ocean; Position; Quantity of deposit; Sediment type; Spencer F. Baird; Substrate type; Uniform resource locator/link to image; Visual description
    Type: Dataset
    Format: text/tab-separated-values, 31 data points
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  • 37
    Publication Date: 2023-07-10
    Keywords: Aptenodytes forsteri; Catharacta skua; Chionis alba; Comment; Daption capensis; DATE/TIME; Diomedea exulans exulans; Eudyptes chrysolophus; Fulmarus glacialoides; Halobaena caerulea; Larus dominicanus; LATITUDE; LONGITUDE; Macronectes giganteus; Oceanites oceanicus; Pachyptila desolata; Pagodroma nivea; Phalacrocorax atriceps; Pygoscelis adeliae; Pygoscelis antarctica; Pygoscelis papua; Sterna vittata; Thalassoica antarctica; Visual observation; Weddell_Sea_Region; Weddell Sea
    Type: Dataset
    Format: text/tab-separated-values, 859 data points
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  • 38
    Publication Date: 2023-07-10
    Keywords: Aptenodytes forsteri; Catharacta skua; Chionis alba; Daption capensis; DATE/TIME; Diomedea chrysostoma; Diomedea exulans exulans; Diomedea melanophris; Fulmarus glacialoides; Halobaena caerulea; LATITUDE; LONGITUDE; Macronectes giganteus; Oceanites oceanicus; Pachyptila desolata; Pagodroma nivea; Phoebetria fusca; Phoebetria palpebrata; Pterodroma macroptera macroptera; Pygoscelis adeliae; Pygoscelis antarctica; Thalassoica antarctica; Visual observation; Weddell_Sea_Region; Weddell Sea
    Type: Dataset
    Format: text/tab-separated-values, 456 data points
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  • 39
    Publication Date: 2024-05-15
    Keywords: ALB-13; ALB-173; ALB-31; Albatross (1882-1921); Albatross1899-1900; Albatross1904-1905; ALBTR-13; ALBTR-173; ALBTR-31; ALBTR-4660; ALBTR-4662; ALBTR-4676; ALBTR-4681; ALBTR-4685; ALBTR-4701; ALBTR-4711; ALBTR-4721; Aluminium; Atomic emission spectroscopy (AES); Barium; Bismuth; Boron; Cadmium; Calcium; Calculated from mass/volume; Calculated from weight loss after ignition at 450 °C; CARN_Revelle_46; CARN_Revelle_78; CARN7-150; CARN7-86; CARN-Cruise7; Carnegie; CASC-5D; CASCADIA; CHA-299; CHA-302; Challenger1872; CHIN02BD; CHIN02BD-016G; CHINOOK; CHNK-16G; Chromium; CHUB01BD; CHUB01BD-002G; CHUB01BD-034G; CHUB-2; CHUB-34; CHUB5; CHUBASCO; Cobalt; Copper; Core; CORE; DEPTH, sediment/rock; Description; DNWB0ABD; DNWB0ABD-016G; DNWB0ABD-017G; DNWB0ABD-019G; DNWB0BBD; DNWB0BBD-037G; DNWB0BBD-040G; DNWB0BBD-043G; DNWB0BBD-048G; DNWB0BBD-052G; DNWB0BBD-054G; DNWB0BBD-055G; DNWB0BBD-056G; DNWB0DBD; DNWB0DBD-147GB; DNWH0AHO-004H; DNWH0BHO-034G; DNWH0DHO-092H; DOWNWIND-B1; DOWNWIND-B2; DOWNWIND-B4; DOWNWIND-H; Dredge; Dredge, rock; DRG; DRG_R; DWBD1; DWBD2; DWBD4; DWBD5; DWBD7; DWBG147B; DWBG16; DWBG17; DWBG19; DWBG37; DWBG40; DWBG43; DWBG48; DWBG52; DWBG54; DWBG55; DWBG56; DWBG78; DWHD15; DWHD16; DWHD47; DWHD55; DWHD72; DWHG34; DWHH4; DWHH92; Eastern Basin, Pacific Ocean; Epce; Event label; Gallium; GC; Grab; GRAB; Gravity corer; H.M.S. Challenger (1872); Horizon; Identification; Iron; Lanthanum; Lead; Loss on ignition; Magnesium; Manganese; MDPC02HO-MP-025F-1; MDPC02HO-MP-033D; MDPC03HO-MP-043A; MIDPAC; Molybdenum; MPC-25F-1; MPC-33D; MPC-43A; NAGA; NAGA8C; Nickel; NOAA and MMS Marine Minerals Geochemical Database; NOAA-MMS; North-East Pacific Ocean; Pacific Ocean; Page(s); Phosphorus; Potassium; Sample code/label; Scandium; Sediment type; Shape; Silicon; Silver; SIO-DX-1; Size; Sodium; Spencer F. Baird; Stranger; Strontium; Thallium; Thorium; Titanium; TRAWL; Trawl net; Uranium; Vanadium; Vityaz (ex-Mars); Vityaz-29; VITYAZ4239-TR; VITYAZ4289-TR; Water content, wet mass; Ytterbium; Yttrium; Zinc; Zirconium
    Type: Dataset
    Format: text/tab-separated-values, 1930 data points
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  • 40
    Publication Date: 2024-05-15
    Keywords: ALB-31; Albatross (1882-1921); Albatross1899-1900; ALBTR-31; Aluminium; Barium; Boron; Calcium; Calculated from mass/volume; CARN_Revelle_46; CARN_Revelle_78; CARN7-150; CARN7-86; CARN-Cruise7; Carnegie; CASC-5D; CASCADIA; Chromium; Cobalt; Copper; Core; CORE; DEPTH, sediment/rock; Description; DNWB0BBD; DNWB0BBD-037G; DNWH0AHO-004H; DOWNWIND-B2; DOWNWIND-H; Dredge; DRG; DWBG37; DWBG78; DWHD55; DWHH4; Epce; Event label; Gallium; GC; Gravity corer; Horizon; Identification; Iron; Lead; Magnesium; Manganese; Molybdenum; NAGA; NAGA8C; Nickel; NOAA and MMS Marine Minerals Geochemical Database; NOAA-MMS; North-East Pacific Ocean; Pacific Ocean; Phosphorus; Potassium; Sediment type; Shape; Silicon; SIO-DX-1; Size; Sodium; Spencer F. Baird; Stranger; Strontium; Sulfur, total; Thallium; Tin; Titanium; TRAWL; Trawl net; V15; V15-126; Vanadium; Vema; Vityaz (ex-Mars); Vityaz-29; VITYAZ4239-TR; Water content, wet mass; X-ray fluorescence (XRF); Zinc; Zirconium
    Type: Dataset
    Format: text/tab-separated-values, 257 data points
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  • 41
    Publication Date: 2024-05-15
    Keywords: Aluminium; Barium; Calcium; Calculated from mass/volume; Cobalt; Copper; DEPTH, sediment/rock; Description; Dredge, rock; DRG_R; Event label; Horizon; Identification; Inductively coupled plasma atomic emission spectroscope (ICP-AES); Iron; Lead; Magnesium; Manganese; MDPC02HO-MP-025F-1; MDPC03HO-MP-043A; MIDPAC; Molybdenum; MPC-25F-1; MPC-43A; Nickel; NOAA and MMS Marine Minerals Geochemical Database; NOAA-MMS; Pacific Ocean; Phosphorus; Potassium; Sediment type; Shape; Silicon; Sodium; Strontium; Titanium; TRAWL; Trawl net; Vityaz (ex-Mars); Vityaz-29; VITYAZ4239-TR; Water content, wet mass; X-ray fluorescence (XRF); Zinc
    Type: Dataset
    Format: text/tab-separated-values, 49 data points
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  • 42
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    PANGAEA
    In:  EPIC3Manchester Literay and Philosophical Society, Bremerhaven, PANGAEA, 106, pp. 22-45
    Publication Date: 2019-07-17
    Repository Name: EPIC Alfred Wegener Institut
    Type: PANGAEA Documentation , notRev
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  • 43
    Publication Date: 2015-10-29
    Repository Name: EPIC Alfred Wegener Institut
    Type: PANGAEA Documentation , notRev
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  • 44
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    PANGAEA
    In:  EPIC3Transactions of the Dumfriesshire ..., Bremerhaven, PANGAEA
    Publication Date: 2019-07-17
    Repository Name: EPIC Alfred Wegener Institut
    Type: PANGAEA Documentation , notRev
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  • 45
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    PANGAEA
    In:  EPIC3Bremerhaven, PANGAEA
    Publication Date: 2019-07-17
    Repository Name: EPIC Alfred Wegener Institut
    Type: PANGAEA Documentation , notRev
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  • 46
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    PANGAEA
    In:  EPIC3ACTA SOCIETATIS BOTANICORUM POLONTAE Vol. XXXII Nr 1., Bremerhaven, PANGAEA
    Publication Date: 2019-07-17
    Repository Name: EPIC Alfred Wegener Institut
    Type: PANGAEA Documentation , notRev
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  • 47
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    PANGAEA
    In:  EPIC3Bremerhaven, PANGAEA
    Publication Date: 2015-11-13
    Repository Name: EPIC Alfred Wegener Institut
    Type: PANGAEA Documentation , notRev
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  • 48
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    PANGAEA
    In:  EPIC3Ergänzungsheft Reihe A (8°), Nr. 5 zur Deutschen Hydrographischen Zeitschrift, Deutsches Hydrographisches Institut, Hamburg., Bremerhaven, PANGAEA
    Publication Date: 2019-07-17
    Repository Name: EPIC Alfred Wegener Institut
    Type: PANGAEA Documentation , notRev
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  • 49
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    PANGAEA
    In:  EPIC3LUNDS UNIVERSITETS ÄRSSKRIFT. N.F. Avd. 2. Bd 59. Nr 7., Bremerhaven, PANGAEA
    Publication Date: 2019-07-17
    Repository Name: EPIC Alfred Wegener Institut
    Type: PANGAEA Documentation , notRev
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  • 50
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Poly-L-proline in the molecular weight range 50,000-90,000 has been synthesized from L-proline-N-carboxyanhydride. The molecular weight obtained is dependent on the initiator concentration. The rate constants for the polymerization have been determined by measuring the CO2 evolution. By observation of rotation during the polymerization, it is possible to deduce the conformation of the polymer in the polymerization solution. It is concluded that the immediate product of the polymerization is neither pure form I nor pure form II. The differences between form I and form II of poly-L-proline have been further characterized by measurements of their ultraviolet rotatory dispersion and their ultraviolet spectra.
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  • 51
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The base-catalyzed hydrolysis rate of the cationic esters obtained by quaternization of N,N,N′,N′-tetramethylethylenediamine with phenylbromoacetate was studied in buffers and in solutions of partially neutralized polymeric acids. The polyanions were found to be powerful inhibitors of the reaction. This effect was interpreted as due to the association of the ester with the polyanion, from which the catalytically active hydroxyl groups are repelled. It is shown that kinetic data may be interpreted by a procedure similar to the Lineweaver-Burk plot to yield the reactivity of the bound ester and the dissociation constant of the polymer-ester complex.
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  • 52
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A series of high molecular weight copolypeptides of L-proline and sarcosine have been synthesized. Experimental evidence is presented which indicates that the products are true copolymers rather than mixtures of homopolymers. In contrast to poly-L-proline I, a copolymer of L-proline-sarcosine I containing approximately 50% sarcosine is soluble in water. Two molecular conformations of the copolymers, similar to those found for polyproline, have been characterized by means of infrared spectroscopy and optical rotatory dispersion. The residue rotation of L-proline has been obtained from the copolymers and is -250°.
    Additional Material: 5 Ill.
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  • 53
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Biopolymers 2 (1964), S. 1-8 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The results of electrophoresis experiments on aqueous solutions of native and thermally denatured DNA are reported. A significant decrease of the electrophoretic mobility has been observed following thermal denaturation, which under suitable conditions gives rise to a resolution into two peaks of 1 : 1 mixtures in the electrophoretic pattern. This result is entirely consistent with the previously reported increase of the activity coefficient of sodium counterions following thermal denaturation. The hypothesis that thermal denaturation of calf thymus DNA induces a large decrease of charge density on the macroion which has been ascribed to the population of more extended conformations of the chains in the disordered region of the molecule is therefore further confirmed.
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  • 54
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The kinetics of the depolymerization of native dextran in dilute hydrochloric acid at different temperatures has been followed by measurements of M̄w, M̄n, [η], 〈ρ2〉1/2, and S. The data allow the correlation of the various parameters of the total hydrolyzate at various degrees of depolymerization. At a first approximation the results conform to a random splitting of a statistical, branched polymer.
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  • 55
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The γ-ethyl-L-glutamate NCA polymerization initiated by di-n-butyl and di-isopropyl amine was studied. The experimental kinetic curves show an autocatalytic portion with 25-30% conversion, followed by a pseudo first-order region which extends up to at least 85-90%. In this linear region, the reaction order appears to be 0.5 in initiator with both amines. High degrees of polymerization and high reaction rates were observed. These results are similar to those obtained in the γ-benzyl-L-glutamate NCA polymerization initiated by sodium methoxide.
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  • 56
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The dielectric constant and the electric birefringence of poly-γ-benzyl-L-glutamate in ethylene dichloride-dichloroacetic acid mixtures have been measured as functions of the solvent composition. These properties undergo a marked decrease with the addition of a small amount of dichloroacetic acid, as well as an abrupt change accompanying the helix-coil transition in the vicinity of 75 vol.-% dichloroacetic acid. The former is attributed to the apparent diminution of the dipole moment of helical poly-γ-benzyl-L-glutamate molecule, which may be due to the protonation of terminal amide groups.
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  • 57
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Biopolymers 2 (1964) 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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  • 58
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The polymerization of γ-benzyl-L-glutamate NCA initiated by n-hexylamine in DMF proceeds with two successive propagation rates whose ratio is about 1.5. The onset of the increase in rate of propagation occurred at a DPn of 7-14, which was independent of initiator to anhydride ratio and anhydride concentration and not a result of anhydride impurities. The increase in rate is likely a result of a conformational change in the polymer at a DPn of 7-14.
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  • 59
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Biopolymers 2 (1964), S. 147-161 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The NCAs of the N-benzyl derivatives of β-alanine, β-DL-aminobutyric acid, and β-DL-aminoisobutyric acid (nonplanar six-membered rings) were prepared by reacting the corresponding N-chloroformyl derivatives, obtained on reaction of the N-benzyl amino acids with phosgene, with triethylamine. Contrary to the others, the NCA of N-benzyl-β-alanine polymerized readily on heating in vacuo or in solution, using n-hexylamine or methanolic sodium methoxide as initiators. With n-hexylamine the molecular weights of the polymers obtained in benzene, dioxan, and dimethylsulfoxide, were in accordance with DP = [NCA]/[Initiator], as was found with conventional five-membered ring NCAs of α-amino acids. With sodium methoxide initiation, DPs of the polymers obtained were smaller than the (NCA)/[Initiator] ratio, contrary to what was found previously with α-amino acid NCAs. The possibility that stereochemical factors are responsible for the differences in polymerization activity of various. N-alkyl β as well as α amino acid NCAs is discussed.
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  • 60
  • 61
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Biopolymers 2 (1964), S. 231-236 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The electrophoretic mobility of DNA in the presence of tetramethylammonium and alkali metal ion chlorides has been studied as a function of ionic strength. Each cation exhibits a characteristic behavior in accord with the idea that the order of inter-action with DNA is Li+ 〉 Na+ 〉 K+ 〉 TMA+. The application of theories of the electrophoresis of polyelectrolytes is discussed, leading to an attempt to calculate the fractional charge per DNA phosphorus from the mobility data. Over the range 0.05-0.4M a constant and unique value of the DNA charge is obtained in the presence of each cation. Values of the zeta potential and of the friction factor per monomer unit are also calculated.
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  • 62
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Biopolymers 2 (1964), S. 135-146 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A simple quantitative theory of inactivation of transforming DNA has been formulated. It is based on the idea that genetic recombination of the molecule of transforming DNA with the bacterial genome is possible only, from the point mutation of the gene up to the nearest hit or point of damage on the corresponding DNA molecule. Our data and the data of other authors on the kinetics of inactivation by HNO2 or U.V. light or both are consistent with these theoretical predictions. Theoretical predictions were made concerning the extent of reactivation by fusion mid annealing of damaged DNA with a diluting genetically inactive DNA. These estimates have been reasonably confirmed by our experimental results.
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  • 63
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Biopolymers 2 (1964), S. 15-25 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: In order to study the effect of glucose substitution on the sedimentation velocities of the T-even phage DNA's, T2 and T2*, and T6 and T6* bacteriophages were grown with H3and P32 labeling. Zone sedimentation of the DNA's isolated from these phagea showed that the glucosylated DNA's from both T2 and T6 sediment faster than the nonglucosylated molecules. Nonglucosylated DNA from TG and T2 phages sedimented with the same velocity, suggesting that the molecules of these phages are of the same length.
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  • 64
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    Biopolymers 2 (1964), S. 43-49 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: We report a simple method for measuring partial specific volumes, of polymers in dilute solutions with an accuracy of 3 parts per thousand. This method has been applied to 7 polypeptides in 4 organic solvents. The residue volumes deduced from these data are compared to those calculated by a differential method. The discrepancy is generally of the order of 1.5%.
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  • 65
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    Biopolymers 2 (1964), S. 283-286 
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    Keywords: Chemistry ; Polymer and Materials Science
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  • 66
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    Biopolymers 2 (1964) 
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    Keywords: Chemistry ; Polymer and Materials Science
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  • 67
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    Topics: Chemistry and Pharmacology
    Notes: It is shown that the formation of the three-strand poly (A + 2U) complex is accompanied by a decrease in optical absorbance at 280 mμ, while the format ion of poly (A + U) is not. This difference makes it possible to demonstrate that in dilute solutions (∼10-4 monomolar), a 1 : 1 mixture of poly A and poly U always forms poly (A + U) at room temperature. At higher temperatures in solutions containing more than about 0.2M sodium ion, poly (A + U) is converted to poly (A + 2U) and free poly A. These results are consistent with the observations reported by Miles and Frazier, using infrared absorption spectra, at much higher polymer concentrations. It is concluded that most of the physicochemical studies of 1 : 1 mixtures of poly A and poly U in dilute aqueous solution refer to the two-stranded species.A simple thermodynamic analysis is developed to explain the two- to three-strand conversion, and with the use of a “phase diagram” showing conditions of stability of the various poly A-poly U structures as a function of salt and temperature, it is possible to estimate the value of the enthalpy of formation of poly (A + 2U).
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  • 68
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    Biopolymers 2 (1964), S. 337-347 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Using a chromatographic technique, the adsorption of the polyribonucleotides s-RNA and poly-A provided with tri-n-butylammonium ions from an aqueous solution on to the surface of polymeric hydrocarbon granules has been demonstrated. The aqueous solution from which adsorption takes place is the aqueous phase which results on agitating together n-butanol (100), water (130), tri-n-butylamine (10), n-butyl ether (10), and glacial acetic acid (2.5) (parts by volume). Microporous polyethylene granules, microporous fluorinated polyethylene granules, and solid grains of polyethylene powder have been employed as adsorbents. The adsorbed polyribonucleotides could be eluted by aqueous solutions of sodium chloride, urea, or triethylammonium acetate. s-RXA with tri-n-butylammonium counterions could also be adsorbed on polymethacrylic acid in tri-n-butylammonium form and eluted therefrom with aqueous urea solutions. It is considered that the adsorption from aqueous solution of polyribonucleotides with tri-n-butylammonium counterions on polymeric hydrocarbon surfaces is mediated by hydrophobic bond formation. Van der Waals forces may also contribute to the bonding. It is suggested that studies on the adsorption of polynucleotides provided with counterions: possessing nonpolar groups at an aqueous solution-polymeric hydrocarbon interlace may permit the elaboration of experimental systems to serve as models for the evaluation of the role of hydrophobic and van der Waals bonding forces in the interaction of polynucleotides with cell membrane surfaces.
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  • 69
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    Biopolymers 2 (1964), S. 395-398 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
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    Topics: Chemistry and Pharmacology
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  • 70
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    Biopolymers 2 (1964), S. 361-380 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Deoxyribonucleic acids (DNA's) extracted from several biological sources have been studied by means of the flow dichroism method, using the transparent coaxial cylinder apparatus. This study has two purposes: (1) to make clear the hydrodynamic behavior of the DNA chain, and the regularity in the orientation of purine and phrimidine bases about the molecular axis; and (2) to develop this particular flow dichroism method as an established device for the study of chain regularity of DNA and other chain polymers. The velocity gradient dependence of dichroism agrees well, to a first approximation, with the behavior of a model of a hydrodynamically equivalent ellipsoid in revolution. Differences between theoretical and empirical curves have been tentatively ascribed to the flexibility of the chain under consideration. Two kinds of data, 1 lie rotary diffusion coefficient and internal dichroism, have been evaluated by a graphical device in which the double logarithmic plots of reduced dichroism and velocity gradient of flow are compared with the theoretical curve. The data obtained have shown good reproducibility for DNA samples prepared by the same method from the same biological source. However, a remarkable difference in internal dichroism and rotary diffusion constant has been observed between DNA groups of different biological origin. The difference may be caused by fragmentation of DNA during the deproteinization procedure, bill the possibility that some of these differences originate in the biological source of the DNA cannot be denied. Orientation of purine and phrimidine bases in aqueous solution is found to be quite regular in direction, as predicted by the Watson-Crick model. Dichroic spectra have shown that the direction of the oscillator dipole corresponding to the 260 mμ absorption band has a different angular relationship to the helical axis than the oscillator dipole for the 220 mμ band.
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  • 71
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    Biopolymers 2 (1964), S. 381-393 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Topics: Chemistry and Pharmacology
    Notes: A study of the super helical structure of synthetic polypeptides, such as poly-γ-benzyl-D (or L)-glutamate (PBDG or PBLG) was carried out. The PEG was dissolved in dimethylformamide (DMF). The solution was either allowed to remain at room temperature for a long time or poured into some fatty acid, such as formic acid, acetic acid, propionic acid, or caprylic acid. Whether the polymer precipitated slowly or rapidly depended upon the aging of the solution or the nature of the acid used. The precipitated gels revealed the coiled coil fibrils, but the feature and degree of coiling varied, depending upon the length of aging or the nature of the acid used for precipitation. After a short aging of the solution, there was no helical structure in the gels. After long aging, very fine-coiled coil macrofibrils or small spindle-like fibrils were obtained. The macrofibrils consisted of the spindle-like fibrils which in turn consisted of microfibrils (diam. 60-70A.). When using the fatty acid precipitation very fine to medium fine super helices were obtained. Extremely fine super helices were obtained in propionic acid. In these gels the PBG chains have an α-helical conformation. When PMLG-DCA solution was stored for a long time, another type of precipitation was obtained, one giving evidence of so-called cross-β crystallization and no coiled coil fibrils. The precipitation of cross-β fibrils was obtained when the concentration of the solution was above 8%.
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  • 72
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    Biopolymers 2 (1964) 
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    Keywords: Chemistry ; Polymer and Materials Science
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  • 73
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    Biopolymers 2 (1964), S. 399-413 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Titration studies of the 1 : 1 helical polynucleotide complex of polyinosinic acid and polycytidylic acid reveal that these two polymers form a complex when the polycytidylic acid is protonated near pH 3. Sedimentation studies show that the protonated complex also has a 1 : 1 stoichiometry. However, the protonated complex is more stable than the unprotonated neutral complex as judged by its thermal stability. The molecular structure of the protonated complex is not the same as the neutral form. Study of the kinetics of the reaction of the protonated complex with formaldehyde suggests that the amino group of cytosine is involved in hydrogen bonds which hold the polynucleotide strands together.
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  • 74
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    Biopolymers 2 (1964), S. 415-444 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Topics: Chemistry and Pharmacology
    Notes: The protein sequences now known have been reconstructed as a kind of intriguing logical-mathematical puzzle using information about fragments of the molecules. We wish to show that the reconstruction can be done systematically by repeating a series of elementary operations on these same data governed by a set of well-defined rules. The completely automatic reconstruction of polymer sequences by a high speed digital computer using these operations and rules is demonstrated.
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  • 75
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    Topics: Chemistry and Pharmacology
    Notes: The mechanism of the renaturation of DNA molecules is examined on the basis of the bimolecular interaction of Gaussian chain polymers. In the nucleus formation by hydrogen bonding in segment-segment interaction, two types of interchain interaction, that is, one between complementary chains and one between noncomplementary chains, and one noncomplementary intrachain interaction are considered to be, in competition. Several previously observed characteristics of the renaturation process are displayed by this simple model. In particular it accounts for the dependence of the extent of renaturation on the heterogeneity, molecular weight, and radius of gyration of DNA, and of the ratios of the reaction rates between complementary and noncomplementary segments. Among these variables the ratio of reaction rates has shown to have a quite specific value, as high as the order of 104, which favors the complementary-strand interaction. This very great bias in favor of complementary strand interaction emphasizes that the renaturation phenomena displays the same character of biological specificity that is associated with enzyme-substrate interaction or antigen-antibody interaction. Moreover, since DNA is a good example of a one-dimensional system, it seems to provide a suitable clue for pursuing the analysis of pattern recognition at the macromolecular level.
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  • 76
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    Biopolymers 2 (1964), S. 463-481 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The polymerization of DL-β-Phenylalanine N-carboxy anhydride adsorbed on polysarcosine dimethylamide has been studied further. This unusual reaction, which is analogous kinetically to reactions catalyzed by enzymes, was called the “chain-effect.” For polymerization of N-carboxy anhydrides by this mechanism it is necessary that the initiating polymer should possess an adsorption site and a terminal base group. The effect is shown to occur with simple compounds such as amino acid dimethylamides but not with poly-L-proline due to the inability of this polymer to adsorb the anhydride. From a study of the reaction of block copolymers of L-proline and sarcosine with DL-β-phenylalanine it is concluded that the relative positions of the adsorption site and terminal base group do not greatly influence the reaction rate, but the accessibility of the adsorption sites is an important factor determining the reactivity of polysarcosine dimethylamides of various degrees of polymerization (n). At high values of n the polymer exists in a coiled form and only those sites close to the terminal base group participate in the reaction. Initial rate studies give a detailed description of the early stage of the chain-effect polymerization. With these data and by use of analog computer techniques the complete reaction has been studied. It is concluded that the poly-DL-β-phenylalanine block produced is not permanently attached to the polysarcosine chain by hydrogen bonds during its formation but that an equilibrium exists between the polysarcosine and the poly-DL-phenylalanine blocks.
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  • 77
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    Topics: Chemistry and Pharmacology
    Notes: Del Re's method for the study of saturated compounds has been adapted so as to deal with the σ-framework of conjugated molecules. This modified procedure is used in evaluating the σ-contribution to the dipole moments of the nucleic bases and of the A-T and G-C base pairs and also to the free energy change in the tautomeric, equilibria of the bases. Associated with an appropriate Hückel method for evaluating the π-contribution, the results obtained predict a small resultant moment for A-T versus a large moment for G-C. The energy calculations predict the keto and amino forms of the bases to be the most stable forms and cytosine to be the most easily involved in tautomeric shift to the rare form.
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  • 78
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    Biopolymers 2 (1964) 
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    Keywords: Chemistry ; Polymer and Materials Science
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  • 79
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    Topics: Chemistry and Pharmacology
    Notes: Temperature jump measurements employing optical rotation to follow transients show an upper limit of 10μsec. on the half time of the helix-random coil relaxation in poly-α, L-glutamic acid. No relaxations are observed under conditions where the polymer exists in completely helical or completely random coil form. Assuming that the helix-coil transition can be described kinetically as a pure growth process, expressions for the relaxation time are derived for three special cases. A comparison is made between the rate of the helix-coil transition and the rate of imide proton exchange.
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  • 80
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    Biopolymers 2 (1964), S. 501-501 
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    Keywords: Chemistry ; Polymer and Materials Science
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  • 81
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    Biopolymers 2 (1964), S. 561-574 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Topics: Chemistry and Pharmacology
    Notes: Numerical calculations have been done on the exciton spectrum of a schematic model of a linear polymer. The model consists of a random sequence of two kinds of subunit whose energy levels and transition moments are almost, but not quite, the same. The orders of magnitude of parameters are taken from DNA, but the full helical geometry has not been considered. Results are given for the density of energy levels, the dipole transition strength per unit energy, and the distribution of excitation energy along the polymer in individual states. A number of localized exciton states were found.
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    Biopolymers 1 (1963), S. 1-1 
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  • 83
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    Biopolymers 1 (1963), S. 25-32 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Topics: Chemistry and Pharmacology
    Notes: The grand-partition-function theory of the preceding paper is used to derive expressions for the number of base pairs bonded in DNA with explicit consideration of the copolymeric nature of the DNA. The following features of the DNA molecule are taken into account: (1) the DNA's from different sources have different ratios of a-t and g-c pairs; (2) the a-t pair is weaker than the g-c pair; (3) the nearest-neighbor frequencies of the two kinds of base pairs are nonrandom; (4) the stacking energies (nearest-neighbor energies) of the various combinations of pairs may be different. An ensemble is constructed in which the features (1) through (4) are introduced by means of statistical weights on the various pairs and combinations of pairs, and an expression for the corresponding partition function is written. Expressions are derived for the number of bonded base pairs and the number of helical sequences.
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    Biopolymers 1 (1963) 
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    Keywords: Chemistry ; Polymer and Materials Science
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  • 85
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    Topics: Chemistry and Pharmacology
    Notes: A method is described for formation of hydroxamic acids by direct coupling, in aqueous medium, of hydroxylamine hydrochloride and the sodium salt of a carboxylic acid. The reaction is mediated by a water-soluble carbodiimide, 1-cyclohexyl-3-[2-morpholinyl-(4)-ethyl]-carbodiimide metho-p-toluene sulfonate. Using model compounds, the production of α-, β- and γ-acyl hydroxamic acids was studied. Hydroxamic acid derivatives of α-polyglutamic and γ-polyglutamic acids were also prepared. Dinitro-phenylhydroxamate derivatives were prepared and subjected to Lossen rearrangement, and the reaction mixtures hydrolyzed. Analysis showed that α-polyglutamic acid yielded as many molecules of α,γ-diaminobutyric acid as there had been glutamic acid residues in the form of the dinitrophenylhydroxamate, and gave rise to no ammonia and succinic semialdehyde. In contrast, γ-polyglutamic acid yielded exactly twice the molar quantity of ammonia as there had been glutamic acid residues in the form of dinitrophenylhydroxamate, and also gave rise to significant quantity of succinic semi-aldehyde but no α,γ-diaminobutyric acid. Since production of the latter is characteristic of α-glutamyl hydroxamates and production of the former is associated with γ-glutamyl hydroxamates, the results indicated that the side-chain carboxyl groups of either polymer retained their identities during formation of the hydroxamic acid derivative, and no interchange had occurred between α- and γ-carboxyl groups. These methods were then used to establish that gelatin of ichthyocol contains (per 1000 total residues) at least 20 residues of glutamic acid in γ-peptide linkage. Due to the incomplete dinitrophenylation of the hydroxamic acid derivative of the protein, gelatin of calf skin collagen gave a lower figure of 10 such linkages per 1000 total amino acid residues-a value which must be considered a minimum value. These results show that γ-glutamyl peptide bonds exist in collagen.
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  • 86
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    Keywords: Chemistry ; Polymer and Materials Science
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    Topics: Chemistry and Pharmacology
    Notes: A statistical thermodynamic treatment of thermally induced helix-coil transitions is formulated with the matrix method for an (ensemble) of system(s) in which one strand of a double helix consists of a homopolymeric polynucleotide and the other strand comprises a number of complementary oligonucleotides. Each oligonucleotide is considered to be completely bound to the longer chain when in the helical configuration and completely free from it when in the randomly coiled configuration. The case of partial binding; i.e., “dangling,” is treated in a later paper. Taken into account in both cases are intrachain “stacking” interactions between nearest neighbor residues and interchain hydrogen bonding.An approximate treatment of the characteristic equation of the formulation indicates that the reciprocal of the transition temperature (1/T0) is a linear function of the reciprocal of the degree of polymerization (D.P.) of the oligonucleotides. In the same approximation, 1/T0 is also a linear function of the negative logarithm of the absolute activity of the oligonucleotides. Transition curves obtained by exact calculation on a computer are presented for various degrees of polymerization of both the oligo- and polynucleotides. These curves show a sharpening of the transition with increasing D.P. of the long chain and the aforementioned reciprocal D.P. dependence of 1/T0.
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    Biopolymers 1 (1963), S. 171-182 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Topics: Chemistry and Pharmacology
    Notes: The dielectric dispersion of polyglutamic acid (PGA) was studied in the pH range of 4-9.8. Three different dispersion curves were obtained. Above pH 6.0, where PGA has a random coil configuration, the dielectric dispersion is characterized by a large dielectric increment (ca. 450) and a relaxation time of 10-12.7 × 10-6 sec. Between pH 6.0 and 5.0, where PGA is in a transitional state with small viscosity, a dispersion curve with very small dielectric increment and also small relaxation time was observed. Below pH 5.0, where PGA has a helical configuration, the dispersion is characterized by a relaxation time of 10-12 × 10-6 sec. and a dielectric increment of about 120. The dipole moment of coil and helical forms of PGA were calculated by using Allgen's equation, and qualitative discussions of these dielectric properties are presented.
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    Biopolymers 1 (1963), S. 193-208 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Topics: Chemistry and Pharmacology
    Notes: Ultaviolet absorption spectra down to 185 mμ are presented for a number of nucleic acids and synthetic polynucleotides in the helical and random forms, and of their constituent mononucleotides, as well as the corresponding nucleosides and free bases. A short wavelength absorption band is in all cases observed with a maximum varying between about 187 and 201 mμ. These bands are more intense than those near 260 mμ. The helical polymers show a hypochromic effect in this region of a somewhat similar magnitude to that in the 260 mμ region. Other spectral phenomena accompanying denaturation and degradation are described.
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    Biopolymers 1 (1963), S. 209-229 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Topics: Chemistry and Pharmacology
    Notes: The inactivation of sRNA by reaction with formaldehyde has been reported as it occurs under various conditions giving differing amounts of secondary structure. The theory of inactivation of an active macromolecule by a chemical reaction is developed. Results obtained with a partially melted out secondary structure show that formaldehyde inactivates sRNA by a single reaction at any one of about ten sites, while reaction at other sites does not affect the activity of the sRNA. In the presence of Mg++ at neutral pH, a large proportion of the active molecules are completely protected against inactivation. From the correlation between the amount of secondary structure and the difficulty of inactivation, it is shown that at least a portion of the secondary structure of sRNA is essential to its amino acid acceptor ability. A comparison of results of various workers shows that formaldehyde does not alter RNA as drastically as other reagents and thus enables more discrimination between sites of reaction which are essential and those which are not essential to biochemical activity.
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    Biopolymers 1 (1963), S. 295-295 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Topics: Chemistry and Pharmacology
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  • 91
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    Keywords: Chemistry ; Polymer and Materials Science
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    Topics: Chemistry and Pharmacology
    Notes: Infrared absorption and x-ray diffraction measurements have been made of D,L-copoly-γ-benzylglutamate fibers (cast from dioxane solutions) with various D/L ratios and with various degrees of polymerization. It was found that each chain of these copolymers consists of a random coil portion and an α-helix portion and that the conformation of the latter is similar to the α-helix of pure poly-γ-benzyl-L-glutamate. It was also found that the fraction of the α-helix portion increases with the degree of polymerization of the copolymer. A simplified polymerization mechanism has been proposed for mixtures of D- and L-amino acid N-carboxyanhydrides. A model of the molecular conformation of the D,L-copolypeptide chains derived from this proposed polymerization mechanism is in good agreement with infrared, x-ray, and other measurements. Based on the results of these observations, we discuss the number of L- or D-residues linked in succession that is required for initiating the formation of an α-helix during the course of polymerization.
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  • 92
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Poly-L-proline I and II, polyphydroxy-L-proline II, polysarcosine, and collagen, as well as two model amides have been examined by far ultraviolet spectrophotometry. Absorption spectral data are presented. Neither in solution nor in oriented films of poly-L-proline I and II is there any indication of excition resonance splitting of the peptide absorption band. In collagen there is some, in the poly-L-prolines only minimal, hypochromicity. These observations, at least in poly-L-proline II, run counter to theory. Optical rotatory dispersion measurements in the ultraviolet indicate simple dispersion in collagen and poly-L-proline II down to at least 232 mμ. The Cotton effect (trough at 233 mμ) observed in α-helical polypeptides and proteins is absent. The implications of these findings are discussed.
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  • 93
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    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The helix - coil transition of poly-L-glutamic acid (PGA) in aqueous solutions was followed by volume changes, ΔV, and also differential refractive indices, Δn. The increase in ΔV or decrease in Δn upon mixing the sodium salt of PGA with dilute HCl gave three straight lines between pH 7 and 4, the two breaks corresponding to the transition zone observed by other physical methods. For the reaction: —COO- + H+ → —CO-OH, ΔV per mole of H+ bound was 11.4 and 11.1 ml. in 0.01 and 0.2M NaCl solutions, respectively. An additional conformational change of about 0.5-1 ml. per amino acid residue was observed for the reaction: coil → helix, after taking electrostatic interaction into consideration. This was probably due to the release of the water of hydration at the amide linkages when the polypeptide coil is converted into the α-helix, or even the occurrence of voids in the polypeptide chain as a result of imperfect packing of the atoms, although the origin of this volume change is still not fully understood at the present time. The volume changes as calculated from Δn by assuming a constant polarizability of the polymer was found to be higher for the association reaction than those mentioned above. On the other hand, the calculated ΔV for the transition was in fair agreement with those by direct measurements.
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  • 94
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Dye-macromolecule complexes provide good models for the study of the effects of coupling between chromophores. In addition to modifications of the visible and UV absorption spectra of the dyes at small interchromophore distances, very efficient energy transfer has been demonstrated at longer distances. The probability of nonradiative transition increases with the number of excitation transfers so that an array of oscillators close to one another becomes nonfluorescent. The insertion of a dye molecule, acting as a trap for the excitation energy, in the highly ordered system of chromophores constituted by the purine and pyrimidine bases of native DNA has given results supporting the intercalation model of Lerman and providing an experimental approach to the problem of the path length of energy migration in the DNA molecule. The average excitation path length seems to be of the order of only ten base pairs, a result which can explain the lack of fluorescence of the DNA.
    Additional Material: 9 Ill.
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  • 95
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Biopolymers 1 (1963), S. 473-495 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The sedimentation, diffusion, and osmotic behavior of poly-L-lysine hydrochloride is examined over a wide range of ionic strengths and in solutions which range in relative composition from a swamping excess of added salt (suppression of charge effect) to salt-free solutions (maximum effect). The charge effect is found to essentially obey the theoretical treatment proposed in Part I of this work. The frictional coefficient of the macroion in salt-free solutions is comparable to that of the fully stretched chain. In excess of salt the friction is appreciably smaller, its magnitude not varying greatly with ionic strength. The molecular weight is determined osmotically and also from diffusion-sedimentation, with the charge effect suppressed by addition of salt or eliminated through the use of non-ionized forms of the polymer; a reasonable agreement is obtained between the methods. The influence of small ions on sedimentation is also examined. The secondary salt effect is found to be much smaller than that predicted theoretically; on the other hand, the substitution of different counterions in the absence of secondary salt effect gives rise to changes of the expected magnitude.
    Additional Material: 8 Ill.
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  • 96
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Biopolymers 1 (1963), S. 500-502 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 97
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Poly-β-hydroxybutyric acid has been isolated from two bacterial sources by two different procedures. Molecular weight and intrinsic viscosity for the two samples were vastly different. This was blamed on degradation occurring during polymer isolation. An optical rotatory dispersion curve for the high molecular weight sample showed a sharp increase in specific rotation at wavelengths less than 450mμ. From this fact and the reported optical activity of the monomer it is concluded that the polymer is stereo-regular. X-ray examination of the “native” and “regenerated” polymer yielded the same crystalline pattern. Electron diffraction and x-ray data on single crystals of the polymer indicate a fiber repeat of 5.9 A. The value can only be reconciled with some kind of helical conformation in the solid state.
    Additional Material: 8 Ill.
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  • 98
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: It has been suggested previously that water is a nearly indifferent solvent for amylose on the basis that the exponent a of the Mark-Houwink equation is very nearly 0.50 and the second virial coefficient A2 is extremely small. It is shown that such solutions do not show the expected precipitation on cooling and the temperature coefficient of the intrinsic viscosity is small and negative. It is suggested that water is both an indifferent and a nearly athermal solvent for this polymer. Various lines of evidence suggest the polymer to exist as a very stiff coil in this and in other solvents. Variations in the intrinsic viscosity and radius of gyration in various solvents show the importance of skeletal effects in addition to the usual osmotic effects. Application of the Porod-Kratky wormlike coil model leads to unreasonably short persistence lengths if the contour length is based on a fully extended conformation but large and reasonable values of the order 40-70 A. if it is assumed that the basic conformation is the helical one observed in various amylose complexes in the crystalline state. As was previously known, the specific optical rotation decreases sharply in aqueous solutions above approximately pH 12. Accompanying this change in rotation there is first a decrease, then an increase in intrinsic viscosity. This later behavior is strikingly reminiscent of the known behavior of polyglutamic acid in the pH-dependent transition from helix to coil. It is concluded that the conformation is that of a stiff coil with essentially helical backbone contour in neutral solution, and the decrease in rotation and in intrinsic viscosity at high pH results from a partial breakdown of the helical structure with a concomitant increase in backbone flexibility. The increase in viscosity and radius of gyration in extreme alkaline solution is probably due to a polyelectrolyte expansion of the polymer coil. Some other miscellaneous observations which are in accord with this model are also pointed out.
    Additional Material: 8 Ill.
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  • 99
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Biopolymers 2 (1964) 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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  • 100
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Biopolymers 2 (1964), S. 9-14 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A calculation based upon Gorin's equation for the electrophoresis of a rigid cylinder is used to compare the available results of electrophoresis and membrane equilibrium experiments on DNA. The distribution of chloride ions across a membrane impermeable to DXA is considered. For a reasonable choice of parameters, agreement within about 2% is obtained between the values calculated from electrophoresis and the results of membrane equilibrium studies over a twenty-fold range of NaCl concentration.
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