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  • Polymer and Materials Science  (1,464)
  • Humans
  • 1975-1979
  • 1955-1959  (1,464)
  • 1958  (870)
  • 1955  (594)
Collection
Publisher
Years
  • 1975-1979
  • 1955-1959  (1,464)
Year
  • 1
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 6 (1955), S. 463-463 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 2
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    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 6 (1955), S. 463-464 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 3
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    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 6 (1955), S. 464-467 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 4
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    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 6 (1955), S. 48-51 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 5
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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  • 6
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    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 6 (1955), S. 53-55 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 7
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    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 6 (1955), S. 55-56 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 8
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    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 6 (1955), S. 63-71 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: On Alternating-Current-CorrosionLaboratory-experiments on the destruction of iron-electrodes being charged with direct and alternating and indulatory currents are communicated. The results are compared with the theory. Conclusions for the practice of stray-current-corrosion are drawn.The experiences of electric works concerning the destruction of earth-circuits made of different metals are related. The apparent influence of stray-current-charges on earth-circuits is explained. According to the obtained results the author recommends a prohibition of coppermade-earth-circuits.
    Notes: Es wird von Laboratoriumsversuchen über die Zerstörung von Eisenelektroden bei Gleichstrom-, Wechselstrom- und Mischstrom-Belastung berichtet. Die Versuchsergebnisse werden mit der Theorie verglichen und Schlußfolgerungen für die Praxis der Streustromkorrosion gezogen.Es wird sodann zu praktischen Erfahrungen it Zerstörung von Erdern aus verschiedenem Material in Elektrizitätswerksbetrieben übergegangen und eine Deutung des scheinbaren Einflusses der Streustrombelastung auf Erder gegeben.Auf Grund dieser Ergebnisse wird ein Verbot der Verwendung von Kupfer als Baumaterial empfohlen.
    Additional Material: 17 Ill.
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  • 9
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    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 6 (1955), S. 72-80 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: The To-Day State of Phosphatizing on Iron and Non-Ferrous-MetalsPhosphatizing is a electrochemical, cathodically controlled process. The author developed mathematical lawfulness for the formation and decomposition of phosphate-covers which was proved by experiments. The porosity of the covers was determined to be 0.3% of the total surface. Because of their high porosity phosphate-covers are used only in combination of oils, lacquers or varnishes. The methods of phosphatizing are discribed in detail. According to the composition of the phosphatizing bath or the intensity of treatment, thinner or thicker covers are obtained. Thick covers of more than 100 mg/100 cm2 (on nails, screws, etc.) are oiled while thin covers of 25-75 mg/100 cm2 are bottoms for painting.Phosphate-covers do not only serve protection against corrosion but also the decrease of friction of sliding surfaces of machines. These covers of manganese and iron phosphate are applied in combination with lubricants.Phosphatizing is of big importance to the cold-working of iron and steel e. g. to deep-drawing. This method invented by Fr. Singer has been applied in Germany. Later than 1947 it was introduced in Great-Britain and the USA.
    Notes: Der Phosphatierungsprozeß ist ein elektrochemischer, kathodisch gesteuerter Vorgang. Für die Kinetik der Bildung und Zerstörung der Phosphatschichten wurden von w. Machu mathematische Gesetzmäßigkeiten abgeleitet und experimentell bewiesen. Die Porosität der Phosphatschichten wurde zu 0.3% der Gesamtfläche ermittelt. Wegen dieser verhältnismäßig hohen Porosität werden die Phosphatüberzüge nur in Verbindung mit Ölen, Lacken oder Anstrichen verwendet. Die Verfahren der Phosphatierung werden im einzelnen beschrieben.Je nach Zusammensetzung des Phosphatierungsbades oder der Behandlungsintensität erhält man dickere oder dünnere Überzüge. Dicke Schichten von über 100 mg/dm2 für Nägel, Schrauben u. dgl. werden geölt, während die dünnen Schichten von 25-75 mg/dm2 die Grundlage von Anstrichen bilden.Neben dem Korrosionsschutz dienen die Phosphatüberzüge auch zur Verminderung der Reibung von aufeinandergleitenden Maschinenteilen. Diese Schichten aus Mangan- und Eisenphosphaten werden in Verbindung mit Schmiermitteln angewendet.Neben Hilfsmittel bei der Kaltbearbeitung von Eisen und Stahl, z.B. Beim Tiefziehen, ist die Phosphatierung von besonderer Bedeutung. Dieses von Fr. Singer 1935 erfundene und in Deutschland angewendete Verfahren wurde erst nach 1947 in USA und in England eingeführt.
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  • 10
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    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 6 (1955), S. 105-110 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 11
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    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 6 (1955), S. 110-112 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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  • 12
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 13
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    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 6 (1955), S. 112-112 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 14
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    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 6 (1955), S. I 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 15
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    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 6 (1955) 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 16
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    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 6 (1955), S. 113-117 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Corrosion and Heat of ActivationThe rate of corrosion of water and vapor on iron follows the Arrhenius equation. \documentclass{article}\pagestyle{empty}\begin{document}$$k = k_m \cdot e^{ - \frac{Q}{{R \cdot T}}}$$\end{document} as proved by experiments. The heat of activation Q depends on the nature of the material and the phases of the water and of the dissolved electrolytes. The Author refers to similar interpretations by Matthaes on the corrosion of aluminium and of steel caused by different corrosive agents and tries to explain deviations of this rule.
    Notes: Es wird nachgewiesen, daß die Geschwindigkeit des Angriffes von Wasser und Dampf auf Eisen der Gleichung von Arrhenius \documentclass{article}\pagestyle{empty}\begin{document}$$k = k_m \cdot e^{ - \frac{Q}{{R \cdot T}}}$$\end{document} folgt. Die Aktivierungswärme Q ist von der Art des Werkstoffes, den Phasen des Wassers und von den im Wasser gelösten Elektrolyten abhängig. Auf ähnliche Versuchsauswertungen von Matthaes über den Angriff auf Aluminium und verschiedener Angriffsmittel auf Stahl wird, hingewiesen. Es wird versucht, Abweichungen von der Gesetzmäßigkeit zu deuten.
    Additional Material: 8 Ill.
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  • 17
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    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 6 (1955), S. 141-145 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 18
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    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 6 (1955), S. 146-148 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 19
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    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 6 (1955), S. 149-151 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 20
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    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 6 (1955), S. 136-141 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: The Mechanism of the Decomposition of Hydrogen-Peroxide on Metallic LeadThe potentials of the galvanic cells Pb/Pt and Pb/Ag in electrolytes containing 0,01-0,4 mols of H2O2 were plotted against time. The obtained results allow to draw conclusions on the mechanism of the catalytic decomposition of H2O2 on lead.The decomposition of H2O2 on metallic lead in 0,01-0,25 molar solutions of H2O2 at 20, 40 and 60°C temperature is characterized by a period of induction. The effect does not occur at higher concentrations of H2O2. If the specimen is preliminarily dipped into a 0,1 molar solution of H2O2 at 20°C temperature for 30 min. no period of induction occures. The decomposition under these conditions is a reaction of zero order.By the effect of H2O2 on freshly precipitated Pb(OH)2 a number of higher leadoxides are produced. Their general formula is PbOn where n is a number between 2 und 3.Experiments on the influence of the state of the surface on the corrosion of lead are discussed.
    Notes: Der Wasserstoffsuperoxyd-Zerfall auf metallischen Blei wurde elektrochemisch und kinetisch verfolgt, wobei die ständige Änderung der Bleioberfläche durch einige Kontaktsubstanzen, die der 0,01 bis 0,4 mol-H2O2-Lösung zugesetzt wurden, durch Potential-Zeit-Messungen, mittels einer Platin- und Silber-Hilfselektrode verfolgt wurde.Der Wasserstoffsuperoxyd-Zerfall auf metallischem Blei bei 20, 40 und 60°C in 0,01 bis 0,25 mol H2O2-Lösung ist durch eine Induktionsperiode gekennzeichnet, die jedoch bie höheren Konzentrationen vollständig verschwindet. Wird die Bleiprobe vor dem Eintauchen in die H2O2-Versuchslösung in einer 0,1 mol-H2O2-Lösung etwa 30 min bei 20°C behandelt, so verschwindet die Induktionsperiode. Die Zerfallreaktion läuft dann als Reaktion nullter Ordnung ab. Durch Einwirkung von H2O2 auf frisch vorbereitetes Pb(OH)2 entsteht eine Reihe höherer Bleioxyde der allgemeinen Formel PbOn, wo n Werte zwischen 2-3 darstellen kann.
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  • 21
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    Materials and Corrosion/Werkstoffe und Korrosion 6 (1955), S. 152-153 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 22
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    Materials and Corrosion/Werkstoffe und Korrosion 6 (1955), S. 154-156 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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    Materials and Corrosion/Werkstoffe und Korrosion 6 (1955), S. 157-157 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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    Materials and Corrosion/Werkstoffe und Korrosion 6 (1955), S. 158-158 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Materials and Corrosion/Werkstoffe und Korrosion 6 (1955), S. 159-161 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Materials and Corrosion/Werkstoffe und Korrosion 6 (1955), S. 162-162 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Materials and Corrosion/Werkstoffe und Korrosion 6 (1955), S. 163-163 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
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    ISSN: 0947-5117
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    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
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    Materials and Corrosion/Werkstoffe und Korrosion 6 (1955), S. 163-163 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Materials and Corrosion/Werkstoffe und Korrosion 6 (1955), S. 164-164 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Materials and Corrosion/Werkstoffe und Korrosion 6 (1955), S. 202-204 
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    Materials and Corrosion/Werkstoffe und Korrosion 6 (1955), S. 220-220 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Materials and Corrosion/Werkstoffe und Korrosion 6 (1955), S. I 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Materials and Corrosion/Werkstoffe und Korrosion 6 (1955) 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Materials and Corrosion/Werkstoffe und Korrosion 6 (1955), S. 221-222 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Materials and Corrosion/Werkstoffe und Korrosion 6 (1955), S. 275-275 
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    Keywords: Chemistry ; Polymer and Materials Science
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    ISSN: 0947-5117
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    Materials and Corrosion/Werkstoffe und Korrosion 9 (1958), S. 1-4 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Synthetic Rubber Products for Protection against CorrosionIn the chemical and similar industries reaction vessels, pipe lines etc. are covered preferably by genuine or synthetic high polymers. The methods being used nowadays to achieve protection against corrosion are very numerous. The covers are made of buna, perbunan, neoprene, butyl rubber, hypalon and hycar. Covers of these materials can be vulcanized. They are resistant to sulfuric acid, acetic acid, potassium hydroxide, chlorine etc. The connection between metal and cover must be totally homogeneous. Otherwise serious interruptions of work might occur. The synthetic high polymers will have to be applied according to certain directions. The techniques of mixing and working and vulcanization are determining the quality of the covers.There are the brass, Dartex and Desmodur methods as well as the silicone covers and the hypalon cermections.Being vulcanised the densisity of the covers is tested by means of an inductive machine. The testing voltage amounts to 2000 volts corresponding to a spark gap of 20 mm.
    Notes: In der chemischen und den verwandten Industrieen werden Reaktionsgefäße, Rohrleitungen und dgl. vorzugsweise mit natürlichen oder synthetischen Hochpolymeren belegt. Die Verfahren, die beute als Korrosionsschutz angewendet werden, sind sehr mannigfaltig. Solche Schutzbeläge werden hergestellt:Aus Buna, Perbunan, Neoprene, Butylkautschuk, Siliconkautschuk, Hypalon, Hycar.Diese Beläge sind vulkanisierbar und beständig gegen:Schwefelsäure, Salzsäure, Flußsäure, Essigsäure, Kalilauge, Chlor usw.Die Verbindung zwischen Metall und Schutzbelag muß vollständig homogen sein, da sonst im Betrieb erhebliche Störungen auftreten können. Die synthetischen Hochpolymere müssen nach ganz bestimmten Vorschriften der Verarbeitung eingesetzt werden. Die Technik der Mischungen, die Verarbeitung und schließlich die Vulkanisation sind für die Güte der Beläge ausschlaggebend.Man kennt das Messingverfahren, das Dartex-Verfahren, das Desmodur-Verfahren, die Siliconbeläge und die Hypalon-Bindungen.Die fertigen Beläge werden nach der Vulkanisation mit einem Induktionsapparat auf Dichtigkeit geprüfl. Die Prüfung erfolgt bei 2000 V-Spannung, die etwa einer Funkenstrecke von 20 min entspricht.
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    Materials and Corrosion/Werkstoffe und Korrosion 9 (1958), S. 65-68 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Materials and Corrosion/Werkstoffe und Korrosion 9 (1958), S. 73-75 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: On the Inhibition of the Corrosion of Buried IronThere is a report on some laboratory experiments on the inhibition of the corrosion of buried iron. The results are explained by means of the influences of the physical properties of the soil upon the suppression of the iron corrosion by the inhibitors Na2CrO4, NaNO2 and sodium benzoate.The results allow to recommend the application of inhibitors for uncovered ironpipes.
    Notes: Es wird über Laboratoriumsversuche über die Inhibition der Eisenkorrosion im Boden berichtet. Die Versuchsergebnisse werden gemeinsam mit den physikalischen Eigenschaften des Bodens bezüglich der Unterbindung der Eisenkorrosion im Boden durch die Inhibitoren: Na2CrO4, NaNO2 und Na-benzoat ausgewertet. Auf Grund dieser Ergebnisse wird eine Empfehlung für die Verwendung von Inhibitoren für den Korrosionsschutz von blanken Eisenrohren im Erdreich gegeben.
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    Materials and Corrosion/Werkstoffe und Korrosion 9 (1958), S. 87-96 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Materials and Corrosion/Werkstoffe und Korrosion 9 (1958), S. 111-119 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Materials and Corrosion/Werkstoffe und Korrosion 9 (1958), S. 130-132 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
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    Materials and Corrosion/Werkstoffe und Korrosion 9 (1958), S. 150-152 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
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    Materials and Corrosion/Werkstoffe und Korrosion 9 (1958), S. 133-146 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: The Methods of Testing CorrosionFor a useful application of materials it is necessary to know their resistance to corrosion and the effects of the protective measurements. Corrosion tests in shop experience are very long termed and the condition of attack are influenced by difficulty attainable, natural modifications so that no reproducible results are gained. Laboratory experiments are necessary to characterize the chemical properties of materials under constant and reproducible conditions in shorter time. The conditions of testing must be adapted to those of practice if useful results shall be obtained.The atmosphere is the most important agent which influences the wear of materials. There is a description of several testing methods which have been developed to imitate climatic conditons. In every case it seems to be useful to indicate the resistance to corrosion not only from the results of a single testing method. Several methods working on different bases should be selected and according to their results you can apply the materials concerned.
    Notes: Für den zweckmäßigen Einsatz der Werkstoffe sind Angaben über seine Korrosionsbeständigkeit und gegebenenfalls auch über die korrosionsschützende Wirkung von Schutzverfahren nötig. Korrosionsversuche in der Praxis erfordern jedoch häufig sehr lange Zeiten und die Angriffsbedingungen sind vielfach einem natürlichen, schwer erfaßbaren Wechsel unterworfen, so daß keine reproduzierbaren Ergebnisse erhalten werden. Laboratoriumsversuche sind deshalb nötig, um die chemischen Eigenschaften der Werkstoffe in kürzeren Zeiten bei gleichartigen, reproduzierbaren Prüfbedingungen kennzeichnen zu können. Die Prüfbedingungen im Laboratorium müssen aber den praktischen Beanspruchungen angepaßt sein, wenn auswertbare Ergebnisse erhalten werden sollen.Eine der wichtigsten Beanspruchungen der Werkstoffe beim praktischen Gebrauch ist die Atmosphäre. Um klimatische Bedingungen im Laboratorium nachzuahmen, sind verschiedenartige Prüfverfahren entwickelt, die im einzelnen beschrieben werden. In jedem Falle erscheint es zweckmäßig, die Korrosionsbeständigkeit nicht nur auf Grund des Verhaltens eines Prüfverfahrens anzugeben, sondern mehrere Prüfverfahren mit unterschiedlichen Bedingungen zu wählen und nach den Ergebnissen dieser Prüfungen die Werkstoffe in der Praxis einzusetzen.
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    Materials and Corrosion/Werkstoffe und Korrosion 9 (1958), S. 340-341 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Materials and Corrosion/Werkstoffe und Korrosion 9 (1958), S. 341-341 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Materials and Corrosion/Werkstoffe und Korrosion 9 (1958), S. 341-341 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Materials and Corrosion/Werkstoffe und Korrosion 9 (1958), S. 407-408 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Materials and Corrosion/Werkstoffe und Korrosion 9 (1958), S. 401-405 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Materials and Corrosion/Werkstoffe und Korrosion 9 (1958), S. 383-390 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: The Rest Potentials and the Cathodic Polarizations of Active Chrome and a Chrome Iron Alloy in Sulfuric AcidThe cathodic polarization curves and the rest potentials of active chrome and a chrome iron alloy (25,6 pct chrome) were measured in dependance of the pH-value of the electrolyte. The behavior of the rest potential deviates from that of the hydrogen electrode. By means of the factors α and β they can be explained for the deposition of hydrogen as well as for the dissolution of metal. The equation of the rest potential is \documentclass{article}\pagestyle{empty}\begin{document}$$ {\rm V}_{\rm o} = {\rm B} - \frac{{0,058}}{{2\,\alpha + \beta }} \cdot {\rm p}_{\rm H} $$\end{document} where B is a constant factor. The sum 2 α - β is usually greater than 1.In the range of the pH-values investigated the cathodic polarization curves of the deposition of hydrogen are parallel. The exchange currents calculated from the logarithmic representation of the polarization curves rise with increasing concentration of the acid and increasing content of chrome in the alloy. The evaluation of the experimental results was carried out according to theroretical principles which had been applied successfully before.
    Notes: An aktivem Chrom und einer Eisen Chrom-Legierung mit 25,6%; Cr wurden in Abhängigkeit vom pH-Wert die Ruhepotentiale gemessen und kathodische Polarisationskurven aufgenommen. Die Ruhepotentiale zeigen ein gegenüber der reversiblen Wasserstoffelektrode abweichendes Verhalten, das mit Hilfe der Durchtrittsfaktoren α und ß für die H2-Entwicklung und für die Metallauflösung gedeutet werden kann. Es gilt für das Ruhepotential \documentclass{article}\pagestyle{empty}\begin{document}$$ {\rm V}_{\rm o} = {\rm B} - \frac{{0,058}}{{2\,\alpha + \beta }} \cdot {\rm p}_{\rm H} $$\end{document} mit B =const. Die Summe 2α+β ist in der Regel 〉 1.Die kathodischen Polarisationskurven der H2-Entwicklung verlaufen im untersuchten pH-Bereich parallel. Die aus der logarithmischen Darstellung ermittelten Ausgleichsströme, die der Korrosion entsprechen, steigen mit wachsender Säure-konzentration und mit wachsendem Cr-Gehalt der Eisen-Chrom-Legierung stark an. Die Auswertung der Versuchsergebnisse erfolgte nach den in letzter Zeit mit gutem Erfolg verwendeten kinetischen Ansätze.
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    Materials and Corrosion/Werkstoffe und Korrosion 9 (1958), S. 409-409 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Materials and Corrosion/Werkstoffe und Korrosion 6 (1955) 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Materials and Corrosion/Werkstoffe und Korrosion 6 (1955), S. 1-1 
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    Materials and Corrosion/Werkstoffe und Korrosion 6 (1955), S. 2-6 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Description / Table of Contents: Corrosion Inhibitors in Petroleum Refinery ServiceChemical Inhibitors play a role of increasing importance in the prevention of corrosion in refinery service. After a brief discussion of the theory underlying the effectiveness of corrosion inhibitors, the author reports considerations which must govern the choice of a particular additive for individual application. Progress in the field of anodic, cathodic, and organic inhibitors is reported. Among the former, chromates and nitrites are widely used, especially with waters of low oxygen content. The use of insufficient inhibitors is more harmful than no inhibitor at all, and minimum proper concentration must be carefully determined. Drawbacks of anodic inhibitors exist in hard waters and in the treatment of potable water. In such cases, the purpose is often better served by cathodic inhibitors (e. g. glassy phosphates and calcium bicarbonate). Organic inhibitors are relatively new and open up a vast and promising new field. Special interest attaches to the recent development of sodium benzoate and of organic amines in this service.
    Notes: Chemische Hemmstoffe (Inhibitoren) haben auf dem Gebiete der Korrosionsverhütung in der Erdölraffinerie steigende Bedeutung erlangt. Nach einer kurzen Erörterung der Theorie, die der Wirkung der Hemmstoffe zu Grunde liegt, berichtet der Verfasser über die Gesichtspunkte, die bei der Wahl eines Hemmstoffes im Einzelfalle zu berücksichtigen sind. Es werden die Fortschritte aufgezeigt, die auf dem Gebiete der anodischen kathodischen und organischen Hemmstoffe erzielt wurden. Als anodische Hemmstoffe kommen vorwiegend Chromate und Nitrite zur Anwendung, insbesondere bei Wasser von geringem Sauerstoffgehalt. Dabei ist zu beachten, daß die Anwendung von ungenügenden Mengen Hemmstoff schädlicher ist als überhaupt kein Hemmstoff, weshalb die anzuwendenden Mindestkonzentrationen sorgfältig zu ermitteln sind. Auch besitzen die anodischen Hemmstoffe Nachteile bei Behandlung von hartem Wasser und von Trinkwasser. In solchen Fällen sind kathodische Hemmstoffe, wie glasige Phosphate und Calciumbicarbonat, oft vorzuziehen. Organische Hemmstoffe sind verhältnismäßig neu und eröffnen ein vielseitiges und aussichtsreiches Anwendungsgebiet. Besonderes Interesse verdienen in dieser Hinsicht Natriumbenzoat und organische Amine.
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    Description / Table of Contents: The Influence of Periodic Ventilation on the Soil Corrossion of AluminiumThe Elements I : Platinium  -  damp soil  -  Aluminium and II: rough-surfaced Aluminium  -  damp soil  -  smooth-surfaced Aluminium demonstrate that Aluminium behaves either actively or passively in accordance with the degree of saturation of the soil by water. An increase in the water content of the soil causes an increase in the activity of the Aluminium in the Element I and in the activity of the smooth-surfaced Aluminium in Element II. The Aluminium suddenly becomes passive when the saturation point is reached.The ratio of the water to Air (Oxygen) in the soil determines the rate of corrosion for Aluminium in soil. Electrolytes (NaCl, KCl, MgCl2,) du not affect the type of corrosion. If the soil is in an atmosphere of Nitrogen, the Aluminium in the Element always remains passive.Periodic saturation of the soil with water was followed by corresponding periodic variation in the character of the corrosion.
    Notes: In den Elementen I: Pt/feuchter Boden/Al bzw. 11: A1 rauh/feuchter Boden/Al glatt zeigt Aluminium ein aktives bzw. passives Verhalten, und zwar in Abhängigkeit vom Sättigungsgrad des Bodens an Wasser. Mit zunehmendem Wassergehalt des Bodens wächst die Aktivität des Aluminiums im Element I bzw. die Aktivität des glatten Aluminiums im Element II. Bei Erreichung des Sättigungszustandes wird das Aluminium plötzlich passiv.Maßgebend für die Korrosionsgeschwindigkeit des Aluminiums im Boden ist das Verhältnis der Wasser zur Luft (Sauerstoff) im Roden, während Elektrolyte (NaCl. KCl, MgCl2) den Korrosionstyp nicht beeinflussen. Befindet sich der Boden in einer Stickstoffatmosphäre, so verhält sich das Aluminium in den untersuchten Elementen durchweg passiv.Zeitlich erfolgende periodische Sättigung des Bodens mit Wasser war von periodischen Schwankungen des Korrosionsverhaltens begleitet.
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    Keywords: Chemistry ; Polymer and Materials Science
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    Materials and Corrosion/Werkstoffe und Korrosion 6 (1955), S. I 
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    Materials and Corrosion/Werkstoffe und Korrosion 6 (1955), S. 87-89 
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    Materials and Corrosion/Werkstoffe und Korrosion 6 (1955), S. 90-90 
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    Materials and Corrosion/Werkstoffe und Korrosion 6 (1955), S. I 
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    Materials and Corrosion/Werkstoffe und Korrosion 6 (1955), S. 199-201 
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    Materials and Corrosion/Werkstoffe und Korrosion 6 (1955), S. 169-180 
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    Description / Table of Contents: The Deformability of Anodically Oxidised Pure AluminiumThe influence of the various coating methods on the deformability of anodically oxidised semifinished products and especially the tendency of the oxidelayers to crack under tensile and deepening wear were investigated and explained by means of numerous, partly new, methods of demonstration.Anodically produced oxide layers in combination with the Duffek-coloringmethod are a valuable aid to detect local only inaccurately calculable tensions and areas of tension in mechanically stressed parts of construction especially those made of light metal.
    Notes: Untersucht und geklärt wurde der Einfluß der verschiedenen Schichtbildungsverfahren auf die Umformbarkeit anodisch oxydierter Halbzeuge, insbesondere auf die Neigung der Oxydschicht zum Reißen unter zügiger und tiefender Beanspruchung, mit Hilfe zahlreicher, zum Teil neuer Nachweisverfahren. Anodisch erzeugte Oxydschichten stellen in Verbindung mit dem Duffek-Einfärbeverfahren ein wertvolles Hilfsmittel zum Nachweis örtlicher, der Rechnung nur unsicher zugänglicher Spannungen und Spannungsfelder in mechanisch beanspruchten Konstruktionsteilen, insbesondere solchen aus Leichtmetall, dar.
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    Materials and Corrosion/Werkstoffe und Korrosion 6 (1955), S. 205-207 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Materials and Corrosion/Werkstoffe und Korrosion 6 (1955), S. 262-264 
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    Materials and Corrosion/Werkstoffe und Korrosion 6 (1955), S. 265-267 
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    Materials and Corrosion/Werkstoffe und Korrosion 6 (1955), S. 270-271 
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    Materials and Corrosion/Werkstoffe und Korrosion 6 (1955), S. 268-269 
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    Materials and Corrosion/Werkstoffe und Korrosion 6 (1955), S. 271-272 
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    Materials and Corrosion/Werkstoffe und Korrosion 6 (1955), S. 273-274 
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    Materials and Corrosion/Werkstoffe und Korrosion 6 (1955), S. 276-278 
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    Materials and Corrosion/Werkstoffe und Korrosion 6 (1955), S. 278-280 
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    Materials and Corrosion/Werkstoffe und Korrosion 6 (1955), S. 280-280 
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    Materials and Corrosion/Werkstoffe und Korrosion 6 (1955), S. 287-294 
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    Description / Table of Contents: The Effects of Moisture and Heat on the Pressure Elastic Behavior of Crude aud Oilimpregnated PressboardIn a greater series of investigations the effects of the various factors of their methods of production like compenents, surface structure, degree of fineness and calender pressure as well as the factors of their working up like moisture and heat on the pressure elastic behavior of commercial crude and oilimpregnated as well as of special-cellulose-products were researched.
    Notes: Im Rahmen einer größeren Untersuchung wurde der Einfluß der verschiedensten herstellungstechnischen Faktoren, wie Aufbaustoffe, Oberflächenbeschaffenheit, Mahlungsgrad und Kalanderdruck sowie der verschiedensten verarbeitungstechnischen Faktoren, wie Wärme und Feuchtigkeit auf das druckelastische Verhalten von rohen und ölimprägnierten handelsüblichen sowie Spezial-Cellulose-Produkten geklärt.
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    Materials and Corrosion/Werkstoffe und Korrosion 6 (1955), S. 294-296 
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    Description / Table of Contents: On the Passive and Active Behavior of Lead in SoilsThe conditions of the corrosion of lead in soils are derivated and mathematically formulated in dependence of the „water-air-contents-ration“. The loss of weight of active lead follows an exponential law while that of passive lead follows a linear law.Lead shows passive behavior in numerous soils. It turns active by means of HCO3-ions. The metal behaves passive in soils under carbon dioxide atmosphere.
    Notes: Die Bedingungen nach denen die Korrosion von Blei im Boden in Abhängigkeit von dem Verhältniswert „Wasser zu Bodenluft“ verläft, werden abgeleitet und mathematisch formuliert. Im aktiven Zustand verläuft der Gewichtsverlust nach einer Exponential-, im passiven Zustand nach einer linearen Funktion.Blei, zeigt in verschiedenen Böden ein passives Verhalten das durch HCO3-Ionen in ein aktives übergehen kann. In einem einer Kohlensäureatmosphäre ausgesetztem Boden verhält sich Blei passiv.
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    Materials and Corrosion/Werkstoffe und Korrosion 6 (1955), S. 297-300 
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    Materials and Corrosion/Werkstoffe und Korrosion 6 (1955), S. 282-287 
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    Description / Table of Contents: Acid-Resisting Steels in the Production of Wood-VinegarThe chemical wear of steel by the production of wood-vinegar is bigger than that by the production of vinegar of fermentation. It is caused by the content of homologous acids and empyreumatic substances.A steel alloyed with Cr 18%, Ni 10% and Mo 2% failed at places of biggest wear though generally used for this acetic acid. Improvement was attempted by steels of higher Cr and Ni contents. The best results were achieved by a steel alloyed with 27% of Cr, 4,5% of Ni and 1,5% of Mo which has been employed in the Swedish cellulose-industry. According to laboratory-experiments this steel is completely resistant over the whole range of concentration and temperature up to the boiling point. It consists of very little austenit and displays greater temper. Nevertheless it can be welded and worked up easily.
    Notes: Die chemische Beanspruchung in der Holzessigindustrie ist größer als die in der Gärungsfabrikation, was durch Gehalte an homologen Säuren und empyrheumatischen Stoffen bedingt ist.Ein Stahl mit 18% Cr, 10% Ni und 2% Mo, der im allgemeinen für diese Essigsäure Verwendung findet, versagte an den Stellen stärkster Beanspruchung in Holzessigsäure. Es wurde daher versucht, durch Erhöhung des Cr- und Ni-Gehaltes eine Verbesserung zu erzielen.Die besten Ergebnisse wurden mit einem bereits in der schwedischen Zellulosefabrikation verwendeten Stahl mit 27% Cr, 4,5% Ni und 1,5% Mo erreicht, der nach den Laboratoriumsversuchen im gesamten Konzentrations-Temperaturbereich bis zum Siedepunkt voll beständig ist.Dieser Stahl besteht nur zum geringen Teil aus Austenit und weist daher eine größere Härte auf. Trotzdem ist er gut verarbeitbar und läßt sich auch befriedigend schweißen.
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    Materials and Corrosion/Werkstoffe und Korrosion 6 (1955), S. 307-308 
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    Materials and Corrosion/Werkstoffe und Korrosion 6 (1955), S. 309-311 
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