ALBERT

Beschreibung: Ice-rafted fossils of late Cretaceous and Tertiary age were detected in Pleistocene-Pliocene glacially influenced sediments of the Vdring Plateau, eastern Norwegian Sea. The ice-rafted associations contain frequent Inoceramus (Bivalvia) prisms and rare occurrences of both benthic and planktonic foraminifers of Miocene, Oligocene, and Maastrichtian to Campanian age. As source areas, shallow outcrops on the Norwegian Continental Shelf as well as the Greenland Shelf and the North and Baltic Seas have to be considered.

Beschreibung: Eocene to Holocene sediments from Ocean Drilling Program (ODP) Site 647 (Leg 105) in the southern Labrador Sea, approximately 200 km south of the Gloria Drift deposits, were investigated for their biogenic silica composition. Three sections of different diagenetic alteration products of primary siliceous components could be distinguished: (1) opal-A was recorded in the Miocene and the early Oligocene time intervals with strongly corroded siliceous skeletons in the Miocene and mostly well preserved biogenic opal in the early Oligocene; (2) opal-CT precipitation occurs between 250-440 meters below seafloor (mbsf) (earliest Oligocene to late Eocene); (3) between 620-650 mbsf (early/middle Eocene), biogenic opal was transformed to clay minerals by authigenesis of smectites. Using accumulation rates of biogenic opal, paleoproductivity was estimated for the early Oligocene to late Eocene interval. A maximum productivity of biogenic silica probably occurred between 35.5 and 34.5 Ma (early Oligocene). No evidence for opal sedimentation during most of middle Eocene was found. However, at the early/middle Eocene boundary (around 52 Ma), increased opal fluxes were documented by diagenetic alteration products of siliceous skeletons.

Beschreibung: Ocean Drilling Program Leg 104 recovered sediments containing calcareous nannofossils of latest Oligocene to Holocene age from the Voring Plateau in the Norwegian-Greenland Sea. The section drilled is virtually the most complete and detailed sedimentary sequence yet obtained from such a high latitude North Atlantic location. Due to unfavorable paleoclimatic conditions, the nannofossil assemblages observed are generally of low diversity and poorly preserved. A limited nannofossil biostratigraphy can still be formulated, although many of the standard low-latitude zonal markers are absent in the area of study. An important aspect of the Norwegian-Greenland Sea is the response of the sediments to the onset and variability of glaciation in the area. The sediments deposited since the onset of Northern Hemisphere glaciation consist of alternating carbonate- (and nannofossil-) rich interglacial sediments and carbonate-poor glacial sediments. The glacial sediments also contain ice-rafted debris, including reworked Cretaceous and older Cenozoic nannofossils. The reworked nannofossils were most likely deposited by ice-rafting from the area to the south with minor contributions of reworked material from exposed shelf areas near Norway and from fault-exposed outcrops of upthrust Cretaceous rocks in the area.

Beschreibung: During Ocean Drilling Program Leg 105, 11 holes were drilled in the Labrador Sea and Baffin Bay. Site 645 in Baffin Bay was drilled to a depth of 1147 meters below seafloor (mbsf); planktonic foraminifers were recovered in the upper 110.3 m and in a short interval between 283.8 and 293.5 mbsf. Low species diversity and the lack of species with short stratigraphic ranges inhibited establishment of a planktonic foraminifer biostratigraphic framework at Site 645. Holes 646B and 647A in the Labrador Sea were drilled to depths of 766.7 and 716.6 mbsf, respectively. Although the observed assemblages in the Labrador Sea holes were of low diversity, the first and last occurrences of several age-diagnostic species, when integrated with paleomagnetic stratigraphy, allowed the establishment of a high-latitude Miocene to Holocene planktonic foraminifer biochronology. To determine the relative timing of planktonic foraminifer datum events in the eastern North Atlantic and the Labrador Sea, this biochronology is compared with the temperate-subpolar biozonation of Weaver and Clement (1986, doi:10.1016/0377-8398(86)90033-2). The late Miocene dextral-to-sinistral coiling change in Neogloboquadrina atlantica was observed -1.6 m.y. earlier at Site 646 than at any other site in the Atlantic. The first appearance datums (FAD) of Globorotalia margaritae, Globorotalia puncticulata, Globorotalia inflata, and the last appearance datum (LAD) of N. atlantica are isochronous with their reported ages in the eastern North Atlantic, but the FADs of Globorotalia truncatulinoides and the modern, encrusted form of Neogloboquadrina pachyderma are diachronous.

Beschreibung: Authigenic carbonates were recovered in lower to middle Eocene claystones at Ocean Drilling Program Site 647 in the Labrador Sea. Detailed chemical, petrographic, and X-ray investigations reveal that these diagenetic carbonates have a complex mineralogical composition. At least five different carbonate phases are identified: calcium-rich rhodochrosite, rhodochrosite, manganosiderite, siderite, and calcite. Manganese carbonates are the dominant carbonate phases formed throughout the section. Textural analyses show two major generations of carbonate formation. Early cementation of micritic carbonate in burrow structures was followed by carbonate cementation forming microsparry to sparry crystals. At approximately 620 meters below seafloor (mbsf), three concretions of iron carbonates occur, which indicates a special pore-water chemistry. Thin section analyses from this level show (1) several generations of diagenetic carbonates, (2) widespread secondary cavity formation in burrow structures, and (3) various cement precipitations in voids. We suggest that this level represents a hiatus or highly condensed sequence, as indicated by (1) the low carbonate content in host sediments, (2) carbonate dissolution reflected by the high ratio of benthic to planktonic foraminifers, and (3) complex diagenetic alteration in the carbonate concretions. Iron and manganese enrichments observed in lithologic Unit IV may have been derived from a hydrothermal source at the adjacent, then active, Labrador Sea mid-ocean ridge. Authigenic smectites forming numerous pseudomorphs of siliceous microfossils are precipitated in burrow structures. We propose that diagenetic smectite formation from biogenic opal and iron oxyhydroxide (analogous to smectite formation in surface sediments of the East Pacific area) occurred in the Labrador Sea during the early and middle Eocene.

Beschreibung: Geochemical analyses of the middle Eocene through lower Oligocene lithologic Unit IIIC (260-518 meters below seafloor [mbsf]) indicate a relatively constant geochemical composition of the detrital fraction throughout this depositional interval at Ocean Drilling Program (ODP) Site 647 in the southern Labrador Sea. The main variability occurs in redox-sensitive elements (e.g., iron, manganese, and phosphorus), which may be related to early diagenetic mobility in anaerobic pore waters during bacterial decomposition of organic matter. Initial preservation of organic matter was mediated by high sedimentation rates (36 m/m.y.). High iron (Fe) and manganese (Mn) contents are associated with carbonate concretions of siderite, manganosiderite, and rhodochrosite. These concretions probably formed in response to elevated pore-water alkalinity and total dissolved carbon dioxide (CO2) concentrations resulting from bacterial sulfate reduction, as indicated by nodule stable-isotope compositions and pore-water geochemistry. These nodules differ from those found in upper Cenozoic hemipelagic sequences in that they are not associated with methanogenesis. Phosphate minerals (carbonate-fluorapatite) precipitated in some intervals, probably as the result of desorption of phosphorus from iron and manganese during reduction. The bulk chemical composition of the sediments differs little from that of North Atlantic Quaternary abyssal red clays, but may contain a minor hydrothermal component. The silicon/ aluminum (Si/Al) ratio, however, is high and variable and probably reflects original variations in biogenic opal, much of which is now altered to smectite and/or opal CT. An increase in the sodium/potassium (Na/K) ratio in the upper Eocene corresponds to the beginning of coarsergrained feldspar flux to the site, possibly marking the onset of more vigorous deep currents. Although the Site 647 cores provide a nearly complete high-resolution, high-latitude Eocene-Oligocene record, the high sedimentation rate and somewhat unusual diagenetic conditions have led to variable alteration of benthic foraminifers and fine-fraction carbonate and have overprinted the original stable-isotope records. Planktonic foraminifers are less altered, but on the whole, there is little chance of sorting out the nature and timing of environmental change on the basis of our stable-isotope analyses.

Beschreibung: The abundance and composition of the upper Cenozoic terrigenous coarse-sand fraction (250 µm-2 mm) at ODP Sites 642, 643, and 644 were investigated to date the onset of significant ice-rafting in the Norwegian Sea, establish the regional chronology of ice-rafting, and determine the relative importance of global vs. regional controls on ice-rafting in this area. The first input of ice-rafted debris (IRD) occurs at approximately 2.9 Ma, with significant ice-rafting beginning at about 2.5 Ma. IRD abundances increase significantly in sediments younger than 0.9 Ma at all three holes, indicating climatic deterioration in the late Pleistocene. Differences in the timing of this IRD increase between holes result from regional patterns of IRD supply and surface circulation. Variations in IRD sources and dispersal patterns may also explain the slightly higher background level of IRD abundance at Hole 642B, a seaward site. Major peaks in the generalized IRD records from the Norwegian Sea are tentatively correlated to glacial stages or glacial-to-interglacial transitions in the globally defined oxygen isotope record. This correlation indicates the effect of global conditions on the regional climate of the Norwegian Sea, although the detailed IRD records at these sites are also affected by local/regional processes (e.g., circulation patterns and source area differences).

Beschreibung: Sediment composition and rate of deposition are the primary factors responsible for determining the spatial distribution of geotechnical properties on the Wring Plateau. Grain size and depth of burial have no significant influence. Vertical and lateral changes in geotechnical properties are associated with vertical and lateral composition changes in which biogenic silica is the most important variable. Anomalous trends of decreasing density and increasing porosity and water content with depth are associated with increasing silica content downsection. Void ratios, inferred in-situ permeability, and change in void ratio during consolidation testing are relatively high in siliceous sediments and tend to increase as the biogenic silica content increases. Portions of the section are overconsolidated, probably as a result of changes in sediment accumulation rates. However, the higher permeabilities of siliceous sediments may also be a factor influencing consolidation state.