ALBERT

Description: Coarse-fraction studies of sediments recovered during ODP Leg 104 are used to reconstruct paleoclimatic and paleoceanographic environments on a time scale of 0.1 to 0.5 m.y. for the past 20 Ma. These investigations suggest that relatively warm climates and isolated deep water conditions prevailed prior to 13.6 Ma and between 5.6-4.8 Ma. The first major deep water outflow from the Norwegian-Greenland Sea into the North Atlantic took place at about 13.6 Ma. Progressive cooling linked to increased deep water renewal in the Norwegian-Greenland Sea appears to have occurred between 13.6-5.6 Ma and 4.8-3.1 Ma. A major onset of ice-rafted debris is recorded at 2.56 Ma. Terrigenous coarsefraction components show important fluctuations with two major peaks during the past 0.8 Ma.

Description: Ice-rafted fossils of late Cretaceous and Tertiary age were detected in Pleistocene-Pliocene glacially influenced sediments of the Vdring Plateau, eastern Norwegian Sea. The ice-rafted associations contain frequent Inoceramus (Bivalvia) prisms and rare occurrences of both benthic and planktonic foraminifers of Miocene, Oligocene, and Maastrichtian to Campanian age. As source areas, shallow outcrops on the Norwegian Continental Shelf as well as the Greenland Shelf and the North and Baltic Seas have to be considered.

Description: Molecular and isotope compositions of headspace and total (free + sorbed) hydrocarbon gases from drilled cores of the three ODP Leg 104 Sites 642, 643, and 644 of the Voring Plateau are used to characterize the origin and distribution of these gases in Holocene to Eocene sediments. Only minor amounts of methane were found in the headspace (0.1 to 〈 0.001 vol%). Although methane through propane are present in all of the total gas samples, different origins account for the concentration and composition variations found. Site 643 at the foot of the outer Voring Plateau represents a geological setting with poor hydrocarbon generating potential, (sediments with low TOC and maturity overlying oceanic basement). Correspondingly, the total gas concentrations are low, typical for background gases (yield C1 - 4 = 31 to 232 ppb, C1/C2+ = 0.6 to 4; delta13C(CH4) -22 per mil to -42 per mil) probably of a diagenetic origin. Holocene to Eocene sediments, which overlie volcanic units, were drilled on the outer Vdring Plateau, at Holes 642B and D. Similar to Site 643, these sediments possess a poor hydrocarbon generating potential. The total gas character (yield C1 - 4 = 20 to 410 ppb; C1/C2+ = 1.7 to 13.3; delta13C(CH4) ca. -23 per mil to -40 per mil) again indicates a diagenetic origin, perhaps with the addition of some biogenic gas. The higher geothermal gradient and the underlying volcanics do not appear to have any influence on the gas geochemistry. The free gas (Vacutainer TM) in the sediments at Site 644 are dominated by biogenic gas (C1/C2+ 〉 104; delta13C(CH4) -77 per mil). Indications, in the total gas, of hydrocarbons with a thermogenic signature (yield C1 - 4 = 121 to 769 ppb, C1/ C2+ = 3 to 8; delta13C(CH4) = -39 per mil to -71 per mil), could not be unequivocally confirmed as such. Alternatively, these gases may represent mixtures of diagenetic and biogenic gases.

Description: Ocean Drilling Program Leg 104 recovered sediments containing calcareous nannofossils of latest Oligocene to Holocene age from the Voring Plateau in the Norwegian-Greenland Sea. The section drilled is virtually the most complete and detailed sedimentary sequence yet obtained from such a high latitude North Atlantic location. Due to unfavorable paleoclimatic conditions, the nannofossil assemblages observed are generally of low diversity and poorly preserved. A limited nannofossil biostratigraphy can still be formulated, although many of the standard low-latitude zonal markers are absent in the area of study. An important aspect of the Norwegian-Greenland Sea is the response of the sediments to the onset and variability of glaciation in the area. The sediments deposited since the onset of Northern Hemisphere glaciation consist of alternating carbonate- (and nannofossil-) rich interglacial sediments and carbonate-poor glacial sediments. The glacial sediments also contain ice-rafted debris, including reworked Cretaceous and older Cenozoic nannofossils. The reworked nannofossils were most likely deposited by ice-rafting from the area to the south with minor contributions of reworked material from exposed shelf areas near Norway and from fault-exposed outcrops of upthrust Cretaceous rocks in the area.

Description: The abundance and composition of the upper Cenozoic terrigenous coarse-sand fraction (250 µm-2 mm) at ODP Sites 642, 643, and 644 were investigated to date the onset of significant ice-rafting in the Norwegian Sea, establish the regional chronology of ice-rafting, and determine the relative importance of global vs. regional controls on ice-rafting in this area. The first input of ice-rafted debris (IRD) occurs at approximately 2.9 Ma, with significant ice-rafting beginning at about 2.5 Ma. IRD abundances increase significantly in sediments younger than 0.9 Ma at all three holes, indicating climatic deterioration in the late Pleistocene. Differences in the timing of this IRD increase between holes result from regional patterns of IRD supply and surface circulation. Variations in IRD sources and dispersal patterns may also explain the slightly higher background level of IRD abundance at Hole 642B, a seaward site. Major peaks in the generalized IRD records from the Norwegian Sea are tentatively correlated to glacial stages or glacial-to-interglacial transitions in the globally defined oxygen isotope record. This correlation indicates the effect of global conditions on the regional climate of the Norwegian Sea, although the detailed IRD records at these sites are also affected by local/regional processes (e.g., circulation patterns and source area differences).

Description: Sedimentary extractable organic matter was analyzed at three ODP Leg 104 sites in the Norwegian Sea. Organic carbon content ranged from less than 0.1% to a maximum of 1.8%. Extractable organic matter content and unresolved complex mixture concentrations were low and randomly distributed. Low levels of aliphatic (branched and normal) and aromatic hydrocarbons were detected in all of the sediments analyzed. Total aliphatic and aromatic hydrocarbon concentrations ranged from 176 to 3,214 and 6 to 820 ppb, respectively. The concentrations of individual aliphatic (n-C15 to n-C32) and aromatic (two- to five-ring) hydrocarbons were generally less than 50 ppb and less than 10 ppb, respectively. No significant trend with sub-bottom depth was observed in either bulk organic matter or individual hydrocarbon concentrations. The predominant source of Cenozoic sedimentary hydrocarbons is concluded to be ice-rafted debris from the adjacent continent. All sites contain a mixture of recycled, mature petroleum-related and terrestrially derived hydrocarbons.

Description: Sediment composition and rate of deposition are the primary factors responsible for determining the spatial distribution of geotechnical properties on the Wring Plateau. Grain size and depth of burial have no significant influence. Vertical and lateral changes in geotechnical properties are associated with vertical and lateral composition changes in which biogenic silica is the most important variable. Anomalous trends of decreasing density and increasing porosity and water content with depth are associated with increasing silica content downsection. Void ratios, inferred in-situ permeability, and change in void ratio during consolidation testing are relatively high in siliceous sediments and tend to increase as the biogenic silica content increases. Portions of the section are overconsolidated, probably as a result of changes in sediment accumulation rates. However, the higher permeabilities of siliceous sediments may also be a factor influencing consolidation state.