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  • Springer  (14)
  • American Geophysical Union
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  • 2000-2004
  • 1995-1999  (14)
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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Biogeochemistry 44 (1999), S. 119-134 
    ISSN: 1573-515X
    Keywords: atmospheric ; cloud water ; deposition ; ecosystem ; fixed nitrogen ; volcano
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Geosciences
    Notes: Abstract Precipitation, dry deposition, and cloud water deposition of fixed nitrogen (nitrate and ammonium ions) were measured on the Island of Hawaii. The first two were small N inputs, averaging 0.6±0.2 and 0.15±0.08 kg N ha-1 yr- 1 respectively. We estimate cloud water deposition to be 8–22 kg inorganic N ha-1 yr-1. If an estimate of organic N is included, it may be as high as 50 kg N ha-1 yr-1. Additionally, cloud water deposition is of hydrological significance as it comprised 37% of the total water input. Cloud water interception was certainly lower in the past, as the developing ecosystem would have had less collection surface area. Cloud water samples that were associated with volcanic haze events were very concentrated in NO3- and constituted 60% of the annual cloud water N deposition. This NO3- probably originated from atmospheric N fixed thermally at the hot lava surface or from an interaction between lava and the ocean. If volcanically influenced samples are excluded from the analysis, the resulting cloud water deposition would have been 4–9 kg N ha-1 yr-1. The Pacific Ocean and Kilauea volcano may have a profound impact on the development of this terrestrial ecosystem, as sources of fixed nitrogen.
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  • 2
    ISSN: 1573-515X
    Keywords: cloud water ; deposition ; ecosystem ; fixed nitrogen ; nutrients ; volcano
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Geosciences
    Notes: Abstract Hawaiian montane ecosystems developing on recent tephra deposits contain more fixed nitrogen than conventional sources can explain. Heath and Huebert (1999) demonstrated that cloud water interception is the mechanism by which this extra nitrogen is deposited, but could not identify its source. We show here that atmospheric dinitrogen is fixed at the surface of active lava flows, producing concentrations of NO which are higher than those found in most urban rush hour air pollution. Over a period of hours this NO is blown away from the island and oxidized to nitrate. Interruptions in the trade wind flow can return this nitrate to the island to be deposited in cloud water. Thus, fixation on active lava flows is able to provide nitrogen to developing ecosystems on flows emplaced earlier.
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  • 3
    ISSN: 1573-515X
    Keywords: cloud water ; deposition ; ecosystem ; fixed nitrogen ; nutrients ; volcano
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Geosciences
    Notes: Abstract Hawaiian montane ecosystems developing on recent tephra deposits contain more fixed nitrogen than conventional sources can explain. Heath and Huebert (1999) demonstrated that cloud water interception is the mechanism by which this extra nitrogen is deposited, but could not identify its source. We show here that atmospheric dinitrogen is fixed at the surface of active lava flows, producing concentrations of NO which are higher than those found in most urban rush hour air pollution. Over a period of hours this NO is blown away from the island and oxidized to nitrate. Interruptions in the trade wind flow can return this nitrate to the island to be deposited in cloud water. Thus, fixation on active lava flows is able to provide nitrogen to developing ecosystems on flows emplaced earlier.
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Biogeochemistry 44 (1999), S. 119-134 
    ISSN: 1573-515X
    Keywords: atmospheric ; cloud water ; deposition ; ecosystem ; fixed nitrogen ; volcano
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Geosciences
    Notes: Abstract Precipitation, dry deposition, and cloud water deposition of fixed nitrogen (nitrate and ammonium ions) were measured on the Island of Hawaii. The first two were small N inputs, averaging 0.6±0.2 and 0.15±0.08 kg N ha−1 yr−1 respectively. We estimate cloud water deposition to be 8–22 kg inorganic N ha−1 yr−1. If an estimate of organic N is included, it may be as high as 50 kg N ha−1 yr−1. Additionally, cloud water deposition is of hydrological significance as it comprised 37% of the total water input. Cloud water interception was certainly lower in the past, as the developing ecosystem would have had less collection surface area. Cloud water samples that were associated with volcanic haze events were very concentrated in NO 3 − and constituted 60% of the annual cloud water N deposition. This NO 3 − probably originated from atmospheric N fixed thermally at the hot lava surface or from an interaction between lava and the ocean. If volcanically influenced samples are excluded from the analysis, the resulting cloud water deposition would have been 4–9 kg N ha−1 yr−1. The Pacific Ocean and Kilauea volcano may have a profound impact on the development of this terrestrial ecosystem, as sources of fixed nitrogen.
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Environmental monitoring and assessment 58 (1999), S. 201-212 
    ISSN: 1573-2959
    Keywords: biomonitoring ; deposition ; metal smelter ; moss ; serial elution procedure
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Heavy metal concentrations in Hylocomium splendens collected around a metal smelter in Latvia showed very high concentrations of Zn (〉200 μg/g), and elevated concentrations of Pb (38.3 μg/g) and Cu (18.3 μg/g). In an attempt to better evaluate the potential toxicity of the high Zn concentrations, a serial elution method was used to determine the concentrations of zinc in intercellular, extracellular exchangeable cell wall, intracellular, and particle fractions. The intercellular Zn concentrations represent the water soluble component of the total concentrations, and were low with no clear trends. Zn concentrations in the extra- and intracellular and particle fractions decreased exponentially from the pollutant source. Intracellular Zn concentrations in moss close to the emission source are within the range considered to be potentially toxic, from other single element exposure studies. The proportion of Zn in the relatively insoluble particle fraction, which is least associated with environmental risk, was greater closer to the pollution source, reaching 〉 30% in the oldest Hylocomium splendens segments.
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  • 6
    ISSN: 1573-2932
    Keywords: critical load ; deposition ; heavy metals ; persistent organic pollutants ; soil quality ; water quality
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract In the pilot study ESQUAD the impact of atmospheric deposition of three heavy metals (cadmium, copper and lead) and two persistent organic pollutants (benzo(a)-pyrene and lindane) on the quality of European soils and seawater has been calculated. Calculations have been made of atmospheric transport and deposition using a detailed emissions database for Europe. This enabled deposition maps to be produced to a resolution of approximately 50 km. The distribution of pollutant concentrations in forest soils was calculated for each grid cell using a database of soil property parameters in Europe. For the North Sea, a model was used to map long-term concentrations in water and sediment, which are due to atmospheric deposition and other, non-atmospheric sources. The model calculations allowed detailed comparisons of deposition fluxes and concentrations of the substances studied with critical loads and environmental quality threshold values, including critical loads. Although significant uncertainties were identified, the study gives insight in how threshold exceedance rates in Europe relate to pollutant type, threshold type, environmental compartment and chemophysical phase (adsorbed, dissolved). For all pollutants and for all compartments exceedances were calculated for at least some of the quality thresholds that were chosen.
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  • 7
    Electronic Resource
    Electronic Resource
    Springer
    Water, air & soil pollution 115 (1999), S. 167-182 
    ISSN: 1573-2932
    Keywords: pesticides ; atmospheric transport ; modelling ; deposition
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Modelling of atmospheric transport and deposition of pesticides is presented and discussed. Modelling on regional scale builds on the existing knowledge gained in other air pollution fields. An overview of current modelling studies on transport and deposition on a regional scale (typically 30-3000 km) is given. From these studies it is concluded that the models are capable in simulating the spatial distribution of the concentrations and depositions. However, large uncertainties are present in this type of modelling and are for the greater part induced by the uncertainty in the emissions and subsequently in the exchange process parameterisations and the physicochemical properties needed in the parameterisations. Many more measurement data are needed to validate the models.
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  • 8
    ISSN: 1573-2932
    Keywords: atmospheric transport ; surface exchange ; deposition ; pesticides
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The current knowledge on atmospheric transport and deposition of pesticides is reviewed and discussed by a working group of experts during the Workshop on Fate of pesticides in the atmosphere; implications for risk assessment, held in Driebergen, the Netherlands, 22-24 April, 1998. In general there is a shortage of measurement data to evaluate the deposition and re-emission processes. It was concluded that the mechanisms of transport and dispersion of pesticides can be described similarly to those for other air pollution components and these mechanisms are rather well-known. Large uncertainties are present in the exchange processes at the interface between air and soil/water/vegetation. In all process descriptions the uncertainty in the physicochemical properties play an important role. Particularly those in the vapour pressure, Henry's law constant and its temperature dependency. More accurate data on physicochemical properties and particularly the temperature dependencies is needed.
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  • 9
    ISSN: 1573-2932
    Keywords: acari ; alkaline ; deposition ; epiphytes ; Gamasida ; Oribatida ; Scots pine forest
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The effect of alkaline deposition produced by the ‘Kujawy’ cement and lime factory in Bielawy, Poland, on the mites in young Scots pine forests (plants class Vaccinio-Piceetea) was investigated. The concentration of calcium in tree bark and epiphytes, which provide a habitat for mites, as well as in soil was the lowest in the control plot, and increased in the direction of the factory. A high concentration of calcium correlated with an absence of lichens from tree bark, but a medium concentration was associated with a higher species number of lichens. The density of arboreal mites and the species number of Oribatida were the highest in the control plot and decreased when getting closer to the factory. In a highly contaminated plot, the density of soil mites was lower, while in a medium contaminated plot it was higher than in the control plot. In the contaminated plots, the species number of soil Oribatida and Gamasida was lower than in the control plot, except in a least contaminated plot where the number of gamasid species was higher than in the control plot. Some species were sensitive to calcium, others were sensitive to a high concentration but tolerated medium and small concentrations of this element, and yet others tolerated calcium. The arboreal mites reacted to alkaline deposition more distinctly than soil mites.
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  • 10
    ISSN: 1573-2932
    Keywords: anthropogenic sources ; deposition ; fossil fuels ; particulates ; precipitation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Precipitation was collected on an event basis from July 1994 to August 1995 at towns around the capital Dhaka of Bangladesh. The major chemical components were determined by atomic absorption spectrophotometry, UV-Visible spectrophotometry and ion selective electrode method. The concentrations of nitrate and sulphate were found to be below the minimum detection limit of 1.0 mg L- 1; the concentrations of Cl-, Na+, K+, Ca+2, Mg+2 and NH4+ ranged from 〈1.0–3.03, 0.14–1.70, 0.04–0.37, 0.04–1.30, 〈0.02–0.20 and 〈0.10–2.33 mg L-1, respectively. The values of pH and conductivity ranged from 4.80–6.74 and 3.3–37.5 μS cm-1, respectively.
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  • 11
    Electronic Resource
    Electronic Resource
    Springer
    Water, air & soil pollution 112 (1999), S. 1-19 
    ISSN: 1573-2932
    Keywords: circular flume ; deposition ; flocculation ; harbour mud
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The deposition and floc formation of fine sediment from Port Stanley harbour were investigated using a rotating circular flume. Seasonal effects, storage time and shear stress were varied. Biological activity was monitored as an aid to explain the results. Sample storage in the flume resulted in increased flocculation for the two fines samples. A sample with a higher percentage of silt did not flocculate to the same extent as the finer samples. Flocculation was also influenced by the presence of bacteria; however further investigation is required to determine their relative importance compared to the presence of fines.
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  • 12
    ISSN: 1573-2932
    Keywords: canopy resistance ; deposition ; emission ; micro-meterological approach ; nitrogen
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The present study aims to establish the annual NH3 deposition to an inland heathland in Denmark using a micro-meterological approach with passive wind-vane flux samplers. The integrating samplers were replaced at weekly intervals from May 1995 to May 1996. The average concentration, 2.05 μg m-3 at the heathland is at a moderate level when compared to heathlands in other parts of Europe. The average deposition velocity was 0.83 cm s-1 which is within the range of depositon velocities found for other heathlands in Europe. The average canopy resistance was found to be relatively high, 61 s -1. The measurements yielded a total NH3-N deposition of 2.4 (± 0.9) kg ha-1 yr-1 with a data coverage of 71% for 1995/1996. In 40% of this time the flux is regarded as zero because the flux is not significant different from zero. In 60% of this time the significant fluxes varied from –0.052 μg m-2 s-1 (deposition equal 16.4 kg N ha-1 yr-1) to 0.089 μg m-2 s-1 (emission equal 28.2 kg N ha-1 yr-1). The method is only able to direct measure significant fluxes down to the equivalence of 0.010 μg m-2 s-1 (approximately 3.2 kg ha-1 yr-1). Therefore the exact deposition cannot be determined by the applied method at very low deposition sites such as a coastal heathland in Denmark. In a high-deposition area as in the central Netherlands the method gave significant fluxes with a 100% data coverage for a two month period.
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  • 13
    ISSN: 1573-2932
    Keywords: atmospheric fate ; atmospheric transport ; deposition ; emission ; long-range transport ; pesticides ; registration ; remote area ; risk assessment ; transformation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The Health Council of the Netherlands organised an international workshop on the fate of pesticides in the atmosphere and possible approaches for their regulatory environmental risk assessment. Approximately forty experts discussed what is currently known about the atmospheric fate of pesticides and major gaps in our understanding were identified. They favoured a tiered approach for assessing the environmental risks of atmospheric dispersion of these chemicals. In the first tier a pesticide's potential for emission during application, as well as its volatilisation potential should be assessed. Estimates of the former should be based on the application method and the formulation, estimates of the latter on a compound's solubility in water, saturated vapour pressure and octanol/water partition coefficient. Where a pesticide's potential for becoming airborne exceeds critical values, it should be subjected to a more rigorous second tier evaluation which considers its toxicity to organisms in non-target areas. This evaluation can be achieved by calculating and comparing a predicted environmental concentration (PEC) and a predicted no-effect concentration (PNEC). By applying an extra uncertainty factor the PNEC can be provisionally derived from standard toxicity data that is already required for the registration of pesticides. Depending on the distance between the source and the reception area, the PEC can be estimated for remote areas using simple dispersion, trajectory type models and for nearby areas using common dispersion models and standard scenarios of pesticide use. A pesticide's atmospheric transport potential is based on factors such as its reaction rate with OH radicals. It should be used to discriminate between those compounds for which only the risks to nearby ecosystems have to be assessed, and those for which the risks to remote ecosystems also have to be determined. The participants were of the opinion that this approach is, in principle, scientifically feasible, although the remaining uncertainties are substantial. Further field and laboratory research is necessary to gain more reliable estimates of the physico-chemical properties of pesticides, to validate and improve environmental fate models and to validate the applicability of standard toxicity data. This will increase both the accuracy of and our confidence in the outcome of the risk assessment.
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  • 14
    Electronic Resource
    Electronic Resource
    Springer
    Water, air & soil pollution 115 (1999), S. 21-70 
    ISSN: 1573-2932
    Keywords: atmospheric transport ; current-use pesticides ; deposition ; field measurements ; long-range transport ; monitoring ; organochlorine pesticides ; pesticides ; rainwater
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Recently, evidence has accumulated that the extensive use of modern pesticides results in their presence in the atmosphere at many places throughout the world. In Europe over 80 current-use pesticides have been detected in rain and 30 in air. Similar observations have been made in North America. The compounds most often looked for and detected are the organochlorine insecticide lindane and triazine herbicides, especially atrazine. However, acetanilide and phenoxyacid herbicides, as well as organophosphorus insecticides have also frequently been found in rain and air. Concentrations in air normally range from a few pg/m3 to many ng/m3. Concentrations in rain generally range from a few ng/L to several µg/L. In fog even higher concentrations are observed. Deposition varies between a few mg/ha/y and more than 1 g/ha/y per compound. However, these estimates are usually based on the collection and analysis of (bulk) precipitation and do not include dry particle deposition and gas exchange. Nevertheless, model calculations, analysis of plant tissue, and first attempts to measure dry deposition in a more representative way, all indicate that total atmospheric deposition probably does not normally exceed a few g/ha/y. So far, little attention has been paid to the presence of transformation products of modern pesticides in the atmosphere, with the exception of those of triazine herbicides, which have been looked for and found frequently. Generally, current-use pesticides are only detected at elevated concentrations in air and rain during the application season. The less volatile and more persistent ones, such as lindane, but to some extent also triazines, are present in the atmosphere in low concentrations throughout the year. In agricultural areas, the presence of modern pesticides in the atmosphere can be explained by the crops grown and pesticides used on them. They are also found in the air and rain in areas where they are not used, sometimes even in remote places, just like their organochlorine predecessors. Concentrations and levels are generally much lower there. These data suggest that current-use pesticides can be transported through the atmosphere over distances of tens to hundreds, and sometimes even more than a thousand kilometres. The relative importance of these atmospheric inputs varies greatly. For mountainous areas and remote lakes and seas, the atmosphere may constitute the sole route of contamination by pesticides. In coastal waters, on the other hand, riverine inputs may prevail. To date, little is known about the ecological significance of these aerial inputs.
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