ISSN:
1572-9605
Schlagwort(e):
Superconductivity
;
Bi2Sr2Ca2Cu3O y
;
microwave absorption
;
critical temperature
Quelle:
Springer Online Journal Archives 1860-2000
Thema:
Elektrotechnik, Elektronik, Nachrichtentechnik
,
Physik
Notizen:
Abstract By the magnetically modulated microwave absorption method (MAMMA) we observed the modifications induced by different calcination temperatures (between 830°C and 870°C) on the 2223 phase formed in a system sintered at (855±5)°C with the starting composition Bi1.7Pb0.3Sr2Ca2Cu3O y . The presence of the 2223 phase in almost distinct states (consequently, multiple 2223 phases) in the same sample was observed. As the calcination temperature was increased up to 850°C, the highest temperature state of the 2223 phase intensified. Higher calcination temperatures resulted in the enhancement of other lower-temperature states. The homogeneity of the 2223 phase was greatly improved by annealing the samples at, 800°C for 5 min in a flowing nitrogen atmosphere. We labeled as “metastable” the lower-temperature states having excess oxygen, which, by easily losing the supplementary oxygen under the above annealing procedure, were shifted to higher temperatures.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1007/BF00727548
Permalink