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  • 1
    Digitale Medien
    Digitale Medien
    Springer
    Water, air & soil pollution 93 (1997), S. 395-408 
    ISSN: 1573-2932
    Schlagwort(e): air pollution ; pine bark ; sulphur ; pH ; conductivity ; heavy metals
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Energietechnik
    Notizen: Abstract Sulphur and heavy metal deposition in northern Finland (= in Lapland) and the Kola Peninsula were surveyed using Scots pine bark samples. Sulphur concentrations in bark close to the Kola smelters were on an average twice as high as on the Finnish side of the border. The Cu and Ni concentrations near the smelters were almost 100-fold the mean values in northern Finland. There was a marked decrease in the sulphur and heavy metal concentrations with increasing distance from the emission sources. The effects of emission from the Kola Peninsula were evident in Finland only close to the border, especially in the eastern parts of Inari (NE corner of Lapland) where the Cu and Ni concentrations were 2- to 6-fold those in western Lapland. The sulphur and heavy metal concentrations in most of northern Finland were low. However were the concentrations of Cr in bark in the SW corner of Lapland considerably high, due to the emissions from the Tornio refined steel plants.
    Materialart: Digitale Medien
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  • 2
    Digitale Medien
    Digitale Medien
    Springer
    Water, air & soil pollution 93 (1997), S. 409-417 
    ISSN: 1573-2932
    Schlagwort(e): CO2 evolution ; heavy metals ; loading effect ; metal equivalent
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Energietechnik
    Notizen: Abstract In a laboratory study the effects on soil respiration of trace metals (Ni, Cd, Cu, Mn, Pb, Zn) added at loading rates ranging from 0 to 1000μg g−1 were determined. Differences in toxicity with respect to the type of metal salt added were also evaluated. The inhibitory effect on soil respiration differed considerably among the heavy metals and increased with the increasing loading rate. No linear relationships were found between the degree of inhibition and the levels of total and available metals. Toxicity evaluation at 20 and 50% inhibition of soil respiration showed Cu as the most toxic and Mn as the most tolerable metal. A ‘metal equivalent’ was calculated as the sum of the amounts of the available metals weighted to their relative toxicity with respect to the least toxic one: Mn equivalent=Mn+1.9Pb+2.1Ni+2.5Zn+6.7Cd+6.7Cu. The ionic potential of the heavy metals was found to be positively related to the percent inhibition of soil respiration. Chlorides and sulphates appeared to depress soil respiration more than nitrates, the latter counter-balancing the toxic effect of the heavy metals.
    Materialart: Digitale Medien
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  • 3
    Digitale Medien
    Digitale Medien
    Springer
    Water, air & soil pollution 94 (1997), S. 85-98 
    ISSN: 1573-2932
    Schlagwort(e): soil ; pollution ; heavy metals ; smelters ; factoranalysis
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Energietechnik
    Notizen: Abstract A combined statistical and computergraphic approach is proposed for apportionment and attribution of soil contaminants in complex areas. The field test site lies north of Swansea, south Wales and contains two major pollutant sources, an active nickel refiner and (4 km away) the site of major base metal smelting in the nineteenth century (the Lower Swansea Valley reclamation study area). Soil samples (70 samples, 0–15 cm) were collected on a regular grid of 1000 m interval. They were extracted using 0.05 M diammonium EDTA and the extracts analysed for Cd, Co, Cu, Fe, Mn, Ni, Pb and Zn. Soil pH and %organic content were also determined. Factor analysis yielded three groups which explained 73.8% of the data variance (1: Cd, Cu, %OM, Pb, Zn, Ni; 2: Cd, Zn, Mn, pH; 3: Cu, Mn, Co, Ni, Fe). Isoline plots were classifiable into the same three groups. It was concluded that factor 3 contained those elements associated with smelter emissions, factor 1 with contamination from the Lower Swansea Valley and in factor 2 pedogenetic processes control the occurrence of the elements.
    Materialart: Digitale Medien
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  • 4
    Digitale Medien
    Digitale Medien
    Springer
    Water, air & soil pollution 99 (1997), S. 255-263 
    ISSN: 1573-2932
    Schlagwort(e): heavy metals ; sediments ; pollution ; resuspension ; release processes ; bioavailability ; anthropogenic ; metal ; residual inetal ; geochemical phases
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Energietechnik
    Notizen: Abstract The space-time distribution of some pollutants (Cu, Ph, Zn, Cd, Fe, Mn, V, Ni, Cr) in the sludge of the canals of Venice was studied. The contamination levels were comparable to, or higher, than those measured in the most polluted sediments of the Lagoon of Venice Sediments were collected by two different sampling techniques I ) collection of sediment cores (upper 5 cm) by a syringe-type corer, 2) collection by traps, placed on the bottom of the canal Traps pennitted the sampling of sediments essentially resuspended by overlying water turbulence This sediment fraction is subjected to variations of its physicochemical parameters (principally change of redox conditions) and therefore to pollutant exchange at the water/sediment interface The metals principally exchanged during sediment resuspension were Cd, Pb, Zn and Cu These metals have principally an anthropogenic origin and are bound to the most labile geochemical phases of the sediment (such as sulphides), which can be oxidised during sediment resuspension, releasing metals into the water Fe, Cr and Ni were only partially exchanged, while Mn and V were generally not exchanged, a significant fraction of these metals is of natural origin and is bound to the most refractory phases of the sediment.
    Materialart: Digitale Medien
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  • 5
    Digitale Medien
    Digitale Medien
    Springer
    Water, air & soil pollution 95 (1997), S. 399-423 
    ISSN: 1573-2932
    Schlagwort(e): fractionation ; redistribution ; saturation ; kinetics ; heavy metals
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Energietechnik
    Notizen: Abstract Solid-phase transformations of Cd, Cu, Cr, Ni and Zn, added as soluble salts at several levels to two arid-zone soils, were studied over a period of one year. The soils were maintained under a saturated-paste regime and sampled periodically. A selective sequential dissolution procedure was employed to determine the changes in metal distribution among six operationally defined solid-phase fractions. A function, Uts was introduced to measure the fractional attainment of equilibrium of the soils following a perturbation. The direction and rate of redistribution of the added metals in the soils were affected by the nature of the metal, the soil properties and the metal loading level. Cd added to the soils was transferred from the exchangeable (EXC) into the carbonate (CARB) fraction. When soluble Cu, Cr, Ni and Zn were added at low loading levels, metals were transferred from the reducible oxides(RO) bound and easily reducible oxides (ERO) bound fractions and the EXC fraction, into the CARB fraction. However, at the higher loading level, metals were transferred from the EXC and CARB fractions into the organic matter bound (OM), ERO and RO fractions. The Uts function approached lower values as incubation continued but remained removed from 1. The overall flux of metals among fractions was the combined result of the readjustment of the metals in the native soil to changing conditions due to saturation, and the transfer of added soluble metals to the less labile fractions.
    Materialart: Digitale Medien
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  • 6
    ISSN: 1573-2932
    Schlagwort(e): Acari ; bioindicators ; Gamasida ; heavy metals ; Oribatida ; Scots pine forest
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Energietechnik
    Notizen: Abstract The soil mites were investigated in the areas covered with dead needles in young Scots pine forests (plant associationLeucobryo-Pinetum), polluted by a copper smelting works at Głogów, and in a control plot. The concentration of heavy metals, mainly copper and lead, was the lowest in the control plot, and increased towards the pollution source. A high concentration of these metals reduced the density of mites and species number of Oribatida and Gamasida, while small concentrations were associated with the increasing abundance of mites and species number of Oribatida. Among mites, the following categories were distinguished: a) sensitive to heavy metals, b) sensitive to a high concentration, but tolerant of small concentrations, and c) tolerant of these metals. The changed vertical distribution of mites in the most polluted soil was also observed, due to accumulation of heavy metals in the Of/h horizon.
    Materialart: Digitale Medien
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  • 7
    Digitale Medien
    Digitale Medien
    Springer
    Water, air & soil pollution 99 (1997), S. 651-659 
    ISSN: 1573-2932
    Schlagwort(e): River sediments ; biofilms ; organic micropollutants ; heavy metals ; temporal variations ; biosorption ; accumulation processes
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Energietechnik
    Notizen: Abstract In a partly urbanized catchment to the south of Trier, Germany, short term variations in river sediment compounds as well as the bioaccumulation of pollutants on surface associated microbial coatings (biofilms) were investigated weekly during a period of six months. Concentrations of selected heavy metals (Cu, Zn, Pb), polycyclic aromatic hydrocarbons (PAH), polychlorinated biphenyls (PCB) and for microbial characterisation protein, carbohydrate and uronic acid were analyzed. Sorption processes on biofilms were determined by temporal variations in pollutants and microbial parameters and through the comparison of sorbed substances in biofilms and sediments. The results show, that sorption events on biofilms play an important and dynamic role in spring and summer for transport and accumulation of the investigated pollutants in the aquatic environment. The amount of pollutants sorbed on sediment particles is not only dependent on the particulate bound or solved pollutants in the river water, but is strongly controlled by the changing conditions of the biofilms.
    Materialart: Digitale Medien
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  • 8
    ISSN: 1573-1642
    Schlagwort(e): decomposition ; heavy metals ; litterbags ; nitrification ; nitrogen mineralization ; urbanization
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Architektur, Bauingenieurwesen, Vermessung , Energietechnik
    Notizen: Abstract We investigated litter mass loss and soil nitrogen (N)-transformation rates in oak stands along a 130-km, urban-rural transect originating in New York City to examine the relationship between changes in these parameters and previously documented differences in soil temperature, heavy metal and total salt concentrations, and soil biota. Reference litter from a rural site was placed in litterbags, and rates of mass loss and changes in N concentration in litter residues were measured over a 6-month period. Net N-mineralization and nitrification rates were measured in A horizon soils using laboratory incubations under constant moisture and temperature. Both mass loss (76%) and N release (65%) from litterbags reached their maximum in urban stands, whereas net N-mineralization rates were 2.3-fold higher than in rural A horizon soils. Litter fragmentation by earthworms and higher soil temperatures are potential causes of the higher mass loss rates observed in urban stands. The higher releases of N measured in the urban litterbags could be a result of their faster mass loss rates, exogenous inputs of N from atmospheric deposition, a relatively low heterotrophic demand for N, or a combination of these factors. The results of this study suggest that in comparison with rural stands, urban forests are characterized by comparatively high rates of litter decomposition, and may also be characterized by comparatively high rates of N mineralization. Additional studies are needed to test whether these effects are common to urban environments in general.
    Materialart: Digitale Medien
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  • 9
    Digitale Medien
    Digitale Medien
    Springer
    Water, air & soil pollution 96 (1997), S. 61-71 
    ISSN: 1573-2932
    Schlagwort(e): allotment gardens ; dustfall ; ground water ; heavy metals ; oil refinery ; soil ; vegetables
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Energietechnik
    Notizen: Abstract In the period 1984–1990 the following vegetables were grown: red beet, carrot and parsley in four allotment gardens of Płock city (Central Poland), situated near the refinery and petrochemical works. Cadmium, lead, copper, chromium, zinc and manganese concentrations were determined in the leaves and roots of vegetables. The heavy metal accumulation in the soil, dustfall (measure of air pollution), and ground water was determined. The quality of the vegetable yield, notably of the leaves, was low. This was mainly due to the excessive chromium and cadmium content in the leaves. Accumulation of heavy metals was relatively low in the soil, rather high in the ground water and variable in the dust.
    Materialart: Digitale Medien
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  • 10
    Digitale Medien
    Digitale Medien
    Springer
    Water, air & soil pollution 96 (1997), S. 1-16 
    ISSN: 1573-2932
    Schlagwort(e): heavy metals ; pollution ; sandy soils ; zinc smelter
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Energietechnik
    Notizen: Abstract Sandy soils, in the border area of Belgium and the Netherlands (the Kempen region), are heavily contaminated by atmospheric deposition of cadmium and zinc from nearby smelters. Groundwater contamination by leaching from these low retention soils is subject of study. There are reports of high cadmium and zinc concentrations in groundwater in the area, but in most cases the direct sources are unknown. In an attempt to predict present or future risk of groundwater contamination by soil leaching, metal binding processes (retardation) were studied that are specific for these soil types under the existing acidifying conditions. From four fields nine contaminated profiles were sampled and analyzed for cadmium and zinc. Average concentrations of 131 μg g-1 zinc and 1.6 μg g-1 cadmium with maximum values of 2989 μg g-1 respectively 16.3 μg g-1 were found. In addition pH and contents of organic matter, aluminium, iron, and manganese were determined. The relative importance of these soil parameters for metal retardation is derived from the profiles. The data show that organic matter is the most important soil component for binding cadmium and zinc. Adsorption of cadmium and zinc on aluminium, iron and manganese (hydr) oxides appears to be of minor importance at low pH (〈5.5).
    Materialart: Digitale Medien
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  • 11
    Digitale Medien
    Digitale Medien
    Springer
    Water, air & soil pollution 96 (1997), S. 1-16 
    ISSN: 1573-2932
    Schlagwort(e): heavy metals ; pollution ; sandy soils ; zinc smelter
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Energietechnik
    Notizen: Abstract Sandy soils, in the border area of Belgium and the Netherlands (the Kempen region), are heavily contaminated by atmospheric deposition of cadmium and zinc from nearby smelters. Groundwater contamination by leaching from these low retention soils is subject of study. There are reports of high cadmium and zinc concentrations in groundwater in the area, but in most cases the direct sources are unknown. In an attempt to predict present or future risk of groundwater contamination by soil leaching, metal binding processes (retardation) were studied that are specific for these soil types under the existing acidifying conditions. From four fields nine contaminated profiles were sampled and analyzed for cadmium and zinc. Average concentrations of 131μg g−1 zinc and 1.6μg g−1 cadmium with maximum values of 2989μg g−1 respectively 16.3μg g−1 were found. In addition pH and contents of organic matter, aluminium, iron, and manganese were determined. The relative importance of these soil parameters for metal retardation is derived from the profiles. The data show that organic matter is the most important soil component for binding cadmium and zinc. Adsorption of cadmium and zinc on aluminium, iron and manganese (hydr) oxides appears to be of minor importance at low pH (〈5.5).
    Materialart: Digitale Medien
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  • 12
    Digitale Medien
    Digitale Medien
    Springer
    Water, air & soil pollution 96 (1997), S. 39-59 
    ISSN: 1573-2932
    Schlagwort(e): acid mine drainage ; heavy metals ; jarosite ; soils ; Sweden
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Energietechnik
    Notizen: Abstract The discharge of acidic mine drainage waters onto a hillslope in Dalarna, central Sweden, has lead to the contamination of the podzol soils with Cu, Fe, Ni, Pb, Zn and sulfate. Samples from contaminated and reference soils have been collected for chemical and mineralogical analyses. Jarosite is identified by x-ray diffraction analysis as a precipitate in the upper horizons (A, E, B) of the contaminated soils, where the soil acidity (pHKCl∼2.6) promotes jarosite stability. The sequential chemical extraction of soil samples indicates that, in the reference A horizon, Cu, Pb, Ni and Zn are bound primarily to cation exchange sites and organic matter. In the A horizon of the contaminated soils closest to the rock dump, metal partitioning is dominated by the Fe oxide fractions, despite the high organic matter content; Pb is almost completely bound to crystalline Fe oxides, possibly adsorbed to Fe oxides or occuring in a jarosite solid solution. In the reference B and C horizons, Cu, Ni and Zn are primarily adsorbed/coprecipitated in the Fe oxide fractions, while Pb remains with a large fraction bound to organic matter. In the Fe-rich B horizon of the contaminated soils, the partitioning of the metals in cation exchange sites and to organic matter has greatly increased relative to the reference soils, resulting from the mobilization of organo-metal complexes down the profile.
    Materialart: Digitale Medien
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  • 13
    Digitale Medien
    Digitale Medien
    Springer
    Water, air & soil pollution 96 (1997), S. 61-71 
    ISSN: 1573-2932
    Schlagwort(e): allotment gardens ; dustfall ; ground water ; heavy metals ; oil refinery ; soil ; vegetables
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Energietechnik
    Notizen: Abstract In the period 1984–1990 the following vegetables were grown: red beet, carrot and parsley in four allotment gardens of Płock city (Central Poland), situated near the refinery and petrochemical works. Cadmium, lead, copper, chromium, zinc and manganese concentrations were determined in the leaves and roots of vegetables. The heavy metal accumulation in the soil, dustfall (measure of air pollution), and ground water was determined. The quality of the vegetable yield, notably of the leaves, was low. This was mainly due to the excessive chromium and cadmium content in the leaves. Accumulation of heavy metals was relatively low in the soil, rather high in the ground water and variable in the dust.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 14
    ISSN: 1573-2932
    Schlagwort(e): heavy metals ; TNR ; stream sediments ; Suquía River
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Energietechnik
    Notizen: Abstract The Suquía is a semiarid (rainfall, 700-900 mm y-1), medium-size (7700 km2) riversystem located in central Argentina. Its mountainous upper catchment includes pristine areas aswell as a variety of human settlements and a reservoir lake. A large city (Córdoba, ca. 1.3million inhabitants) and a terminal hypersaline lake are included in the middle and lower basin.Total non-residual (TNR) heavy metals (Pb, Cu, Ni, Zn, Mn, and Fe) have been determined inriver bed sediments in two seasons (spring and autumn), seeking to establish the factors whichcontrol the temporal and spatial variability. The major findings were: a) concentrations of TNRmetals were, in general, higher during springtime than during autumn, particularly downstreamfrom the city of Córdoba; b) organic matter played a significant role as a controlling factorwherever it defined reducing conditions, lowering the concentrations of Mn and Fe hydrousoxides; c) a higher organic load (e.g., downstream the city) and more pronounced reducingconditions could be the causes for the increased Fe concentration, probably precipitated assulfides; d) organic matter exhibited a closer correlation with some TNR metals in autumn,probably caused by a larger capacity for complexation in the biologically-processed organicdebris; and, e) the existence of pristine areas in the drainage basin allowed for the calculation ofenrichment factors (EF) which show the significance of several environmental impacts in theSuquía system.
    Materialart: Digitale Medien
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  • 15
    Digitale Medien
    Digitale Medien
    Springer
    Water, air & soil pollution 93 (1997), S. 395-408 
    ISSN: 1573-2932
    Schlagwort(e): air pollution ; pine bark ; sulphur ; pH ; conductivity ; heavy metals
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Energietechnik
    Notizen: Abstract Sulphur and heavy metal deposition in northern Finland (= in Lapland) and the Kola Peninsulawere surveyed using Scots pine bark samples. Sulphur concentrations in bark close to the Kolasmelters were on an average twice as high as on the Finnish side of the border. The Cu and Niconcentrations near the smelters were almost 100-fold the mean values in northern Finland. Therewas a marked decrease in the sulphur and heavy metal concentrations with increasing distancefrom the emission sources. The effects of emissions from the Kola Peninsula were evident inFinland only close to the border, especially in the eastern parts of Inari (NE corner of Lapland)where the Cu and Ni concentrations were 2- to 6-fold those in western Lapland. The sulphur andheavy metal concentrations in most of northern Finland were low. However were theconcentrations of Cr in bark in the SW corner of Lapland considerably high, due to the emissionsfrom the Tornio refined steel plants.
    Materialart: Digitale Medien
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  • 16
    Digitale Medien
    Digitale Medien
    Springer
    Water, air & soil pollution 93 (1997), S. 409-417 
    ISSN: 1573-2932
    Schlagwort(e): CO2 evolution ; heavy metals ; loading effect ; metal equivalent
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Energietechnik
    Notizen: Abstract In a laboratory study the effects on soil respiration of trace metals (Ni, Cd, Cu, Mn, Pb, Zn)added at loading rates ranging from 0 to 1000 µg g-1 were determined. Differences intoxicity with respect to the type of metal salt added were also evaluated. The inhibitory effect onsoil respiration differed considerably among the heavy metals and increased with the increasingloading rate. No linear relationships were found between the degree of inhibition and the levels oftotal and available metals. Toxicity evaluation at 20 and 50% inhibition of soil respiration showedCu as the most toxic and Mn as the most tolerable metal. A ‘metal equivalent’ was calculated asthe sum of the amounts of the available metals weighted to their relative toxicity with respect tothe least toxic one: Mn equivalent = Mn + 1.9Pb + 2.1Ni + 2.5Zn + 6.7Cd + 6.7Cu. The ionicpotential of the heavy metals was found to be positively related to the percent inhibition of soilrespiration. Chlorides and sulphates appeared to depress soil respiration more than nitrates, thelatter counter-balancing the toxic effect of the heavy metals.
    Materialart: Digitale Medien
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  • 17
    Digitale Medien
    Digitale Medien
    Springer
    Water, air & soil pollution 93 (1997), S. 93-108 
    ISSN: 1573-2932
    Schlagwort(e): straw ash ; ashes ; bottom ash ; fly ash ; biofuel ; cereal straw ; rape straw ; straw combustion ; fertilizer ; plant nutrients ; heavy metals
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Energietechnik
    Notizen: Abstract The composition of 79 samples of straw ash from seven heating plants in Sweden wasanalysed with the aim of evaluating straw ash as a fertilizer and liming agent. The variation in ashcomposition was explained mainly by ash fraction (bottom ash vs. fly ash) and straw type (wheat,barley, rye, rape) but also by heating plant. Compared with concentrations of Zn, Pb and Cd inbottom ash, levels in fly ash were 10-90 times higher. Fly ash also contained more Cu and Kcompared with bottom ash. The Cd/P ratio was 0.03 in bottom ash and 0.6 g Cd/kg P in fly ash.Ash from rape straw had a higher Ca content and liming effect compared with ash from cerealstraw; e.g., the liming effect of rape ash was more than three times higher than that of wheat ash.The liming effect varied between 3.5 and 44% CaO and depended mainly on the Ca content. Theaverage P content was 1.7% (0.2-4.4%), with slightly higher concentration in rape ash than inwheat ash. The potential for using straw ash as a fertilizer and liming agent is discussed. Compared withcommercial fertilizers the use of bottom ash as a P fertilizer results in a lower addition of Cd.However, the total heavy metal content of straw ash poses a potential problem.
    Materialart: Digitale Medien
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  • 18
    ISSN: 1573-2932
    Schlagwort(e): heavy metals ; TNR ; stream sediments ; Suquía River
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Energietechnik
    Notizen: Abstract The Suquía is a semiarid (rainfall, 700–900 mm y−1), medium-size (7700 km2) river system located in central Argentina. Its mountainous upper catchment includes pristine areas as well as a variety of human settlements and a reservoir lake. A large city (Córdoba, ca. 1.3 million inhabitants) and a terminal hypersaline lake are included in the middle and lower basin. Total non-residual (TNR) heavy metals (Pb, Cu, Ni, Zn, Mn, and Fe) have been determined in river bed sediments in two seasons (spring and autumn), seeking to establish the factors which control the temporal and spatial variability. The major findings were: a) concentrations of TNR metals were, in general, higher during springtime than during autumn, particularly downstream from the city of Córdoba; b) organic matter played a significant role as a controlling factor wherever it defined reducing conditions, lowering the concentrations of Mn and Fe hydrous oxides; c) a higher organic load (e.g., downstream the city) and more pronounced reducing conditions could be the causes for the increased Fe concentration, probably precipitated as sulfides; d) organic matter exhibited a closer correlation with some TNR metals in autumn, probably caused by a larger capacity for complexation in the biologically-processed organic debris; and, e) the existence of pristine areas in the drainage basin allowed for the calculation of enrichment factors (EF) which show the significance of several environmental impacts in the Suquía system.
    Materialart: Digitale Medien
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  • 19
    Digitale Medien
    Digitale Medien
    Springer
    Water, air & soil pollution 94 (1997), S. 85-98 
    ISSN: 1573-2932
    Schlagwort(e): soil ; pollution ; heavy metals ; smelters ; factor analysis
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Energietechnik
    Notizen: Abstract A combined statistical and computergraphic approach is proposed for apportionment and attribution of soil contaminants in complex areas. The field test site lies north of Swansea, south Wales and contains two major pollutant sources, an active nickel refiner and (4 km away) the site of major base metal smelting in the nineteenth century (the Lower Swansea Valley reclamation study area). Soil samples (70 samples, 0–15 cm) were collected on a regular grid of 1000 m interval. They were extracted using 0.05 M diammonium EDTA and the extracts analysed for Cd, Co, Cu, Fe, Mn, Ni, Pb and Zn. Soil pH and %organic content were also determined. Factor analysis yielded three groups which explained 73.8% of the data variance (1: Cd, Cu, %OM, Pb, Zn, Ni; 2: Cd, Zn, Mn, pH; 3: Cu, Mn, Co, Ni, Fe). Isoline plots were classifiable into the same three groups. It was concluded that factor 3 contained those elements associated with smelter emissions, factor 1 with contamination from the Lower Swansea Valley and in factor 2 pedogenetic processes control the occurrence of the elements.
    Materialart: Digitale Medien
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  • 20
    Digitale Medien
    Digitale Medien
    Springer
    Water, air & soil pollution 94 (1997), S. 361-372 
    ISSN: 1573-2932
    Schlagwort(e): heavy metals ; contamination ; mobilization ; cadmium ; soil
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Energietechnik
    Notizen: Abstract Analysis of spatial distribution of sewage-sludge born cadmium on the experimental plot revealed positive correlation of total cadmium and organic matter. Soil pH fluctuated randomly on the field. ‘Bioavailable’ concentrations, as determined by NH4-acetate extraction, were closely correlated to the total cadmium levels, and only negligible effects of pH and/or organic matter fluctuations were recorded. Desorption model using modified Freundlich isotherm was applied to predict risks of cadmium solubilization at different conditions. Simulations revealed that the organic matter content within the ranges found at the experimental field cannot support a proper immobilization of cadmium at pH-range observed at the field. The phenomenon was explained by ineffective care for the soil in the past.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 21
    Digitale Medien
    Digitale Medien
    Springer
    Water, air & soil pollution 94 (1997), S. 361-372 
    ISSN: 1573-2932
    Schlagwort(e): heavy metals ; contamination ; mobilization ; cadmium ; soil
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Energietechnik
    Notizen: Abstract Analysis of spatial distribution of sewage-sludge born cadmium on the experimental plot revealed positive correlation of total cadmium and organic matter. Soil pH fluctuated randomly on the field. ‘Bioavailable’ concentrations, as determined by NH4-acetate extraction, were closely correlated to the total cadmium levels, and only negligible effects of pH and/or organic matter fluctuations were recorded. Desorption model using modified Freundlich isotherm was applied to predict risks of cadmium solubilization at different conditions. Simulations revealed that the organic matter content within the ranges found at the experimental field cannot support a proper immobilization of cadmium at pH-range observed at the field. The phenomenon was explained by ineffective care for the soil in the past.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 22
    Digitale Medien
    Digitale Medien
    Springer
    Water, air & soil pollution 99 (1997), S. 615-622 
    ISSN: 1573-2932
    Schlagwort(e): Near-shore sediments ; heavy metals ; bioindicators ; bivalves ; benthic populations ; multivariate analysis ; multiple regression analysis ; predictive models
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Energietechnik
    Notizen: Abstract Copper, lead, cadmium, zinc, chromium, manganese, iron and nickel were determined in near-shore sediments in the harbour of Trieste (Northern Adriatic), in an area highly exposed to urban and industrial wastes, where severe alteration of benthic population was observed. A typical bivalve of this area,Corbula gibba, was used as bioindicator of sea-bottom pollution. Multivariate statistical analysis of the chemical data interpret concentrations and distributions of heavy metals in these sediments, attesting anthropogenic source for Cu, Pb, Cd and Zn. Using labile fractions of heavy metals in sediments as ‘predictors’, and length or bionnass of the bivalve as dependent variables, we obtained, by a multiple regression procedure, a predictive model showing the influence of metals on this benthic organism of this polluted area.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 23
    Digitale Medien
    Digitale Medien
    Springer
    Water, air & soil pollution 95 (1997), S. 119-131 
    ISSN: 1573-2932
    Schlagwort(e): geochemical investigations ; geochemical validation ; heavy metals ; ICP-AES ; environmental monitoring
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Energietechnik
    Notizen: Abstract A little known alternative to highcost environmental analysis, especially in Europe, is the use of commercially available, lowcost exploration geochemical laboratory analysis. To test for suitable accuracy and precision, both indicated parameters were monitored during several sample runs for environmental examinations at a selected commercial geochemical laboratory using various digestive methods and ICP-AES (Inductively Coupled Plasma Atomic Emission Spectrometry). By evaluating duplicate samples and repeated measurements of internal standards and comparing the results with precision needed for environmental investigations, exploration geochemical analysis is found to be more than adequate for most elements and digestive methods in environmental applications. Accuracy is highest for total digestion ICP-AES analysis, with expectedly greater error margins for aqua regia digestion. Lowcost exploration geochemical analysis is an inexpensive analytical tool for screening, detailed investigations and monitoring of contaminated sites.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 24
    Digitale Medien
    Digitale Medien
    Springer
    Water, air & soil pollution 95 (1997), S. 399-423 
    ISSN: 1573-2932
    Schlagwort(e): fractionation ; redistribution ; saturation ; kinetics ; heavy metals
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Energietechnik
    Notizen: Abstract Solid-phase transformations of Cd, Cu, Cr, Ni and Zn, added as soluble salts at several levels to two arid-zone soils, were studied over a period of one year. The soils were maintained under a saturated-paste regime and sampled periodically. A selective sequential dissolution procedure was employed to determine the changes in metal distribution among six operationally defined solid-phase fractions. A function,U ts was introduced to measure the fractional attainment of equilibrium of the soils following a perturbation. The direction and rate of redistribution of the added metals in the soils were affected by the nature of the metal, the soil properties and the metal loading level. Cd added to the soils was transferred from the exchangeable (EXC) into the carbonate (GARB) fraction. When soluble Cu, Cr, Ni and Zn were added at low loading levels, metals were transferred from the reducible oxides(RO) bound and easily reducible oxides (ERO) bound fractions and the EXC fraction, into the CARB fraction. However, at the higher loading level, metals were transferred from the EXC and CARB fractions into the organic matter bound (OM), ERO and RO fractions. TheU ts function approached lower values as incubation continued but remained removed from 1. The overall flux of metals among fractions was the combined result of the readjustment of the metals in the native soil to changing conditions due to saturation, and the transfer of added soluble metals to the less labile fractions.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 25
    Digitale Medien
    Digitale Medien
    Springer
    Water, air & soil pollution 96 (1997), S. 39-59 
    ISSN: 1573-2932
    Schlagwort(e): acid mine drainage ; heavy metals ; jarosite ; soils ; Sweden
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Energietechnik
    Notizen: Abstract The discharge of acidic mine drainage waters onto a hillslope in Dalarna, central Sweden, has lead to the contamination of the podzol soils with Cu, Fe, Ni, Pb, Zn and sulfate. Samples from contaminated and reference soils have been collected for chemical and mineralogical analyses. Jarosite is identified by x-ray diffraction analysis as a precipitate in the upper horizons (A, E, B) of the contaminated soils, where the soil acidity (pHKCl ∼ 2.6) promotes jarosite stability. The sequential chemical extraction of soil samples indicates that, in the reference A horizon, Cu, Pb, Ni and Zn are bound primarily to cation exchange sites and organic matter. In the A horizon of the contaminated soils closest to the rock dump, metal partitioning is dominated by the Fe oxide fractions, despite the high organic matter content; Pb is almost completely bound to crystalline Fe oxides, possibly adsorbed to Fe oxides or occuring in a jarosite solid solution. In the reference B and C horizons, Cu, Ni and Zn are primarily adsorbed/coprecipitated in the Fe oxide fractions, while Pb remains with a large fraction bound to organic matter. In the Fe-rich B horizon of the contaminated soils, the partitioning of the metals in cation exchange sites and to organic matter has greatly increased relative to the reference soils, resulting from the mobilization of organo-metal complexes down the profile.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 26
    Digitale Medien
    Digitale Medien
    Springer
    Water, air & soil pollution 96 (1997), S. 185-201 
    ISSN: 1573-2932
    Schlagwort(e): Avenidas basin ; Pachuca mines ; hydrochemistry ; hydrochemical facies ; heavy metals ; groundwater
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Energietechnik
    Notizen: Abstract Groundwater in the Rio de las Avenidas sub-basin corresponds to the bicarbonate-sodium and bicarbonate-calcium hydrochemical facies, which result from the mineralization of water passing through alkaline rocks (andesites) which prevail in this basin. However, the presence of high concentrations of Na+ and K+ reveals the existence of an external inflow of these elements: the registered mean values are respectively 94.3 and 19.0 ppm, with the Tèllez and Tizayuca areas standing out with reported values of up to 142 ppm. As for the concentration of soluble water cations, we find in decreasing order: Na+, Ca2+, Mg2+, K+, along with the anions HCO3 −, Cl−, SO4 2−, CO3 −, which combine to form the NaHCO3, NaCl, Ca(HCO3)2, MgSO4 and KCl salts. The presence of biological contaminants, P and detergents in the groundwater indicates that it may have been contaminated by waste water. In addition to the contaminants mentioned above, large quantities of Pb, B, Zn, Fe, Mn, Cr, Co were detected and although Fe, Pb, Zn, B, and Mn are closely related to the local lithology, the high concentrations of these elements along with the occurrence of Co, Cr, Cd, and Ni confirm the gradual degradation of the aquifers in the sub-basin. The water temperature indicates the existence of low temperature thermal processes in the area.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 27
    Digitale Medien
    Digitale Medien
    Springer
    Water, air & soil pollution 96 (1997), S. 185-201 
    ISSN: 1573-2932
    Schlagwort(e): Avenidas basin ; Pachuca mines ; hydrochemistry ; hydrochemical facies ; heavy metals ; groundwater
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Energietechnik
    Notizen: Abstract Groundwater in the Rio de las Avenidas sub-basin corresponds to the bicarbonate-sodium and bicarbonate-calcium hydrochemical facies, which result from the mineralization of water passing through alkaline rocks (andesites) which prevail in this basin. However, the presence of high concentrations of Na+ and K+ reveals the existence of an external inflow of these elements: the registered mean values are respectively 94.3 and 19.0 ppm, with the Tèllez and Tizayuca areas standing out with reported values of up to 142 ppm. As for the concentration of soluble water cations, we find in decreasing order: Na+, Ca2+, Mg2+, K+,along with the anions HCO3 -, Cl-, SO4 2-, CO3 -, which combine to form the NaHCO3, NaCl, Ca(HCO3 2, MgSO4 and KCl salts. The presence of biological contaminants, P and detergents in the groundwater indicates that it may have been contaminated by waste water. In addition to the contaminants mentioned above, large quantities of Pb, B, Zn, Fe, Mn, Cr, Co were detected and although Fe, Pb, Zn, B,and Mn are closely related to the local lithology, the high concentrations of these elements along with the occurrence of Co, Cr, Cd, and Ni confirm the gradual degradation of the aquifers in the sub-basin. The water temperature indicates the existence of low temperature thermal processes in the area.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 28
    ISSN: 1573-2932
    Schlagwort(e): Acari ; bioindicators ; Gamasida ; heavy metals ; Oribatida ; Scots pine forest
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Energietechnik
    Notizen: Abstract The soil mites were investigated in the areas covered with dead needles in young Scots pine forests (plant association Leucobryo-Pinetum), polluted by a copper smelting works at Głogów, and in a control plot. The concentration of heavy metals, mainly copper and lead, was the lowest in the control plot, and increased towards the pollution source. A high concentration of these metals reduced the density of mites and species number of Oribatida and Gamasida, while small concentrations were associated with the increasing abundance of mites and species number of Oribatida. Among mites, the following categories were distinguished: a) sensitive to heavy metals, b) sensitive to a high concentration, but tolerant of small concentrations, and c) tolerant of these metals. The changed vertical distribution of mites in the most polluted soil was also observed, due to accumulation of heavy metals in the Of/h horizon.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 29
    Digitale Medien
    Digitale Medien
    Springer
    Water, air & soil pollution 99 (1997), S. 255-263 
    ISSN: 1573-2932
    Schlagwort(e): heavy metals ; sediments ; pollution ; resuspension ; release processes ; bioavailability ; anthropogenic metal ; residual metal ; geochemical phases
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Energietechnik
    Notizen: Abstract The space-time distribution of some pollutants (Cu, Pb, Zn, Cd, Fe, Mn, V, Ni, Cr) in the sludge of the canals of Venice was studied. The contamination levels were comparable to, or higher, than those measured in the most polluted sediments of the Lagoon of Venice. Sediments were collected by two different sampling techniques: 1) collection of sediment cores (upper 5 cm) by a syringe-type corer; 2) collection by traps, placed on the bottom of the canal. Traps permitted the sampling of sediments essentially resuspended by overlying water turbulence. This sediment fraction is subjected to variations of its physicochemical parameters (principally change of redox conditions) and therefore to pollutant exchange at the water/sediment interface. The metals principally exchanged during sediment resuspension were Cd, Pb, Zn and Cu. These metals have principally an anthropogenic origin and are bound to the most labile geochemical phases of the sediment (such as sulphides), which can be oxidised during sediment resuspension, releasing metals into the water. Fe, Cr and Ni were only partially exchanged, while Mn and V were generally not exchanged; a significant fraction of these metals is of natural origin and is bound to the most refractory phases of the sediment.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 30
    Digitale Medien
    Digitale Medien
    Springer
    Water, air & soil pollution 93 (1997), S. 93-108 
    ISSN: 1573-2932
    Schlagwort(e): straw ash ; ashes ; bottom ash ; fly ash ; biofuel ; cereal straw ; rape straw ; straw combustion ; fertilizer ; plant nutrients ; heavy metals
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Energietechnik
    Notizen: Abstract The composition of 79 samples of straw ash from seven heating plants in Sweden was analysed with the aim of evaluating straw ash as a fertilizer and liming agent. The variation in ash composition was explained mainly by ash fraction (bottom ash vs. fly ash) and straw type (wheat, barley, rye, rape) but also by heating plant. Compared with concentrations of Zn, Pb and Cd in bottom ash, levels in fly ash were 10–90 times higher. Fly ash also contained more Cu and K compared with bottom ash. The Cd/P ratio was 0.03 in bottom ash and 0.6 g Cd/kg P in fly ash. Ash from rape straw had a higher Ca content and liming effect compared with ash from cereal straw: e.g., the liming effect of rape ash was more than three times higher than that of wheat ash. The liming effect varied between 3.5 and 44% CaO and depended mainly on the Ca content. The average P content was 1.7% (0.2–4.4%), with slightly higher concentration in rape ash than in wheat ash. The potential for using straw ash as a fertilizer and liming agent is discussed. Compared with commercial fertilizers the use of bottom ash as a P fertilizer results in a lower addition of Cd. However, the total heavy metal content of straw ash poses a potential problem.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 31
    Digitale Medien
    Digitale Medien
    Springer
    Water, air & soil pollution 99 (1997), S. 615-622 
    ISSN: 1573-2932
    Schlagwort(e): Near-shore sediments ; heavy metals ; bioindicators ; bivalves ; benthic populations ; multivariate analysis ; multiple regression analysis ; predictive models
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Energietechnik
    Notizen: Abstract Copper, lead, cadmium, zinc, chromium, manganese, iron and nickel were determined in near-shore sediments in the harbour of Trieste (Northern Adriatic), in an area highly exposed to urban and industrial wastes, where severe alteration of benthic population was observed. A typical bivalve of this area, Corbula gibba, was used as bioindicator of sea-bottom pollution. Multivariate statistical analysis of the chemical data interpret concentrations and distributions of heavy metals in these sediments, attesting anthropogenic source for Cu, Pb, Cd and Zn. Using labile fractions of heavy metals in sediments as 'predictors', and length or biomass of the bivalve as dependent variables, we obtained, by a multiple regression procedure, a predictive model showing the influence of metals on this benthic organism of this polluted area.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 32
    Digitale Medien
    Digitale Medien
    Springer
    Water, air & soil pollution 99 (1997), S. 651-659 
    ISSN: 1573-2932
    Schlagwort(e): River sediments ; biofilms ; organic micropollutants ; heavy metals ; temporal variations ; biosorption ; accumulation processes
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Energietechnik
    Notizen: Abstract In a partly urbanized catchment to the south of Trier, Germany, short term variations in river sediment compounds as well as the bioaccumulation of pollutants on surface associated microbial coatings (biofilms) were investigated weekly during a period of six months. Concentrations of selected heavy metals (Cu, Zn, Pb), polycyclic aromatic hydrocarbons (PAH), polychlorinated biphenyls (PCB) and for microbial characterisation protein, carbohydrate and uronic acid were analyzed. Sorption processes on biofilms were determined by temporal variations in pollutants and microbial parameters and through the comparison of sorbed substances in biofilms and sediments. The results show, that sorption events on biofilms play an important and dynamic role in spring and summer for transport and accumulation of the investigated pollutants in the aquatic environment. The amount of pollutants sorbed on sediment particles is not only dependent on the particulate bound or solved pollutants in the river water, but is strongly controlled by the changing conditions of the biofilms.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 33
    Digitale Medien
    Digitale Medien
    Springer
    Water, air & soil pollution 95 (1997), S. 119-131 
    ISSN: 1573-2932
    Schlagwort(e): geochemical investigations ; geochemical validation ; heavy metals ; ICP-AES ; environmental monitoring
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Energietechnik
    Notizen: Abstract A little known alternative to highcost environmental analysis, especially in Europe, is the use of commercially available, lowcost exploration geochemical laboratory analysis. To test for suitable accuracy and precision, both indicated parameters were monitored during several sample runs for environmental examinations at a selected commercial geochemical laboratory using various digestive methods and ICP-AES(Inductively Coupled Plasma Atomic Emission Spectrometry). By evaluating duplicate samples and repeated measurements of internal standards and comparing the results with precision needed for environmental investigations, exploration geochemical analysis is found to be more than adequate for most elements and digestive methods in environmental applications. Accuracy is highest for total digestion ICP-AES analysis, with expectedly greater error margins for aqua regia digestion. Lowcost exploration geochemical analysis is an inexpensive analytical tool for screening, detailed investigations and monitoring of contaminated sites.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 34
    Digitale Medien
    Digitale Medien
    Springer
    Environmental monitoring and assessment 48 (1997), S. 285-296 
    ISSN: 1573-2959
    Schlagwort(e): herring gulls ; heavy metals ; selenium ; feathers ; bioindicator ; mercury ; lead ; cadmium ; chromium ; manganese
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Energietechnik
    Notizen: Abstract With increasing interest in assessing the health or well-being ofcommunities and ecosystems, birds are being used asbioindicators. Coloniallynesting species breed mainly in coastal areas that are alsopreferred for humandevelopment, exposing the birds to various pollutants. Inthis paper concentrations of heavy metal and selenium in the feathers ofHerring Gulls(Larus argentatus) nesting in several colonies fromMassachusetts toDelaware are reported. There were significant differencesamong colonies forall metals, with metal concentrations being two to nearly fivetimes higher atsome colonies than others. Selenium showed the leastdifference, and cadmium showed the greatest difference among sites. Concentrations of lead werehighest at Prall‘s Island; mercury was highest at Shinnecock,Huckleberry andHarvey, and manganese was highest at Captree.
    Materialart: Digitale Medien
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  • 35
    Digitale Medien
    Digitale Medien
    Springer
    Environmental monitoring and assessment 46 (1997), S. 279-287 
    ISSN: 1573-2959
    Schlagwort(e): Delaware Bay ; eggs ; horseshoe crab ; heavy metals ; muscle
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Energietechnik
    Notizen: Abstract Lead, mercury, cadmium, chromium and manganese concentrations were measured in the eggs of horseshoe crabs (Limulus polyphemus) from 1993, 1994 and 1995; and from chelicera muscle in 1995 from Delaware Bay. Metal concentrations in the eggs represent levels derived from females. In eggs, mercury levels were below 100 ppb or were non-dectable; cadmium levels were generally low in 1993 and 1995 but were relatively higher in 1994; lead levels in eggs decreased from 558 ppb in 1993 to 87 ppm in 1995; selenium increased from 1993 to 1995; chromium decreased from 1993 to 1995; and manganese generally decreased. Leg muscles had significantly lower levels of all metals than eggs, except for mercury.
    Materialart: Digitale Medien
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  • 36
    Digitale Medien
    Digitale Medien
    Springer
    Environmental monitoring and assessment 47 (1997), S. 89-108 
    ISSN: 1573-2959
    Schlagwort(e): heavy metals ; ions ; New Brunswick ; precipitation ; snowpack ; soils ; vegetables
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Energietechnik
    Notizen: Abstract Concentrations of heavy metals and major ions were measured in precipitation, snowpack, garden soils and vegetables from urban and rural sites in New Brunswick in Atlantic Canada. Atmospheric loading of mercury, lead, cadmium, arsenic, strontium, and vanadium need further assessment. Vanadium concentrations in precipitation, snowpack, soils and vegetables showed an urban influence. Vanadium concentrations in the snowpack ranged between 〈2.0 ppb at 50 kilometers from the city center to 31.4 ppb in the city. Concentrations of all heavy metals in urban soils were less than CCME remediation guidelines but selected metals exceeded the assessment benchmark non-regulatory guidelines. Major ions were consistently higher in event precipitation than the snowpack. The order of ion elution from the snowpack was NO3 〉 SO4 〉 NH4 〉 H 〉 Mg 〉 Cl 〉 Na 〉 K. Hydrogen ion equivalents were highest in the snowpack and precipitation from urban samples. Mean hydrogen ion concentrations ranged from 11 to 22 μeq L-1 in the snowpack compared with 18 to 41 μeq L-1 in event precipitation.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 37
    Digitale Medien
    Digitale Medien
    Springer
    Environmental monitoring and assessment 47 (1997), S. 135-152 
    ISSN: 1573-2959
    Schlagwort(e): bioindicator ; heavy metals ; moss
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Energietechnik
    Notizen: Abstract The use of different moss species – Hylocomium splendens,Pleurozium schreberi, Eurhynchium angustirete, Sphagnum and Rhytidiadelphus – was tested for the investigation of atmosphericheavy metal deposition. Maps representing heavy metal depositionpattern in Lithuania are presented for Cd, Cr, Cu, Fe, Ni, Pb and V.The most suitable species for heavy metal deposition studies was Hylocomium splendens in which the concentrations of metalswere found to be up to 25% higher than in other species. Interspeciesand interelemental comparison was also performed. Several well definedlocal pollution sources were identified.
    Materialart: Digitale Medien
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  • 38
    ISSN: 1573-3017
    Schlagwort(e): red wood ant ; phosphoa denine nucleotides ; enzyme patterns ; heavy metals ; tolerance
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Energietechnik
    Notizen: Abstract Biochemical and physiological effects of prolonged feeding of the ant Formica aquilonia, in natural conditions with excess of cadmium or mercury, were studied. In all developmental stages metals caused the time-dependent increase of AMP, parallel with a decrease of ATP and the pool size of adenylates. This was reflected by a low adenylate energy charge (AEC) index and accompanied by an inhibition of ATPases. Despite the fall in the adenylate pool of workers, the levels of adenylate energy charge confirmed their ability to maintain energetic balance. Prolonged access to food highly contaminated with Cd, or Cd with Hg, diminished these adaptive abilities, but pre-adaptive reactions (not correlated with the metal load) were induced. Activity patterns of enzymes involved in energy metabolism showed metal dependent inhibitory effects, but repeated contamination evoked some compensatory mechanisms, both in workers and in the pupal stage from the next generations. Cadmium (indirectly) stimulated the esterases and free radical scavengers. Compensatory mechanisms were insufficient in insects contaminated with both Hg and Cd, even causing family disappearance, through increased mortality and migration to other colonies. Compensatory mechanisms expressed by the adult workers appeared to be of a phenotypic origin
    Materialart: Digitale Medien
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