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  • General Chemistry  (2,428)
  • Polymer and Materials Science  (1,190)
  • 2000-2004  (378)
  • 1980-1984
  • 1960-1964  (2,347)
  • 1925-1929  (893)
  • 2000  (378)
  • 1962  (2,347)
  • 1928  (893)
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  • 2000-2004  (378)
  • 1980-1984
  • 1960-1964  (2,347)
  • 1925-1929  (893)
Year
  • 1
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 6 (1962), S. S23 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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  • 2
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    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 6 (1962), S. S24 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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  • 3
    Electronic Resource
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    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 6 (1962), S. 600-604 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The steady-state flow of viscose in a capillary tube viscometer was investigated to determine the rheological properties of this fluid as a function of cellulose concentration and molecular weight. It was found that the flow consistency index increased with increasing cellulose content at constant molecular weight. The flow behavior index was not affected under these conditions. At constant cellulose content, the flow behavior index was found to decrease as the molecular weight of the cellulose molecule was increased. Steady-state velocity profiles for viscose flowing in a round tube under laminar conditions are also presented as a function of the flow behavior index.
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  • 4
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    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 6 (1962), S. S25 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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  • 5
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    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 6 (1962), S. S27 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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  • 6
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    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 6 (1962), S. S28 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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  • 7
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    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 6 (1962), S. S29 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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  • 8
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    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 6 (1962), S. 98-102 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: An apparatus for polyvinyl chloride thermal degradation under isothermal conditions and in a controlled atmosphere is described with precision. Continuous measurement of loss of weight of the sample under degradation and, at the same time, continuous titration of hydrochloric acid evolved, can be carried out. The apparatus consists essentially of a magnetically equilibrated Ugine-Eyraud balance, in which runs a purified gas stream that picks up volatile products in an argentimetric titration cell, coupled to a titrimeter and recorder. Total precision of simultaneous measurements is 1%. An example of the experimental results is given.
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  • 9
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    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 6 (1962), S. S1 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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  • 10
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    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 6 (1962), S. 103-110 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: For a commercial polyvinyl chloride (PVC), polymerized in suspension, decomposition kinetics were studied in a nitrogen atmosphere and isothermal conditions, from 150 to 250°C., by measuring simultaneously loss of hydrochloric acid and loss of weight. Below 200°C., hydrochloric acid is the only volatile product freed; reaction is zero order and activation energy is 20 kcal./mole HCl. Active centers are mainly end chains of unsaturated structures. The reaction is terminated by mutual destruction of radicals, creating crosslinks. Above 200°C., when the degree of dehydrochlorination is high enough, a minor difference is observed between loss of weight and hydrochloric acid loss. The reaction is autoaccelerated and can be classified as a degenerated branching chain reaction. It is suggested that activation of irregular structures, initially present or created during the course of the reaction, and thus responsible for autocatalysis, provides active centers for chain dehydrochlorination. Some of these structures are active at temperatures lower than that of their formation. Each kind of structure is believed to be at the origin of a radical zero-order chain reaction; its activation energy depends on its type. The reaction chains are terminated by inactivate irregular structures.
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  • 11
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    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 6 (1962), S. S2 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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  • 12
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    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 6 (1962), S. S5 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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  • 13
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    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 6 (1962), S. 121-121 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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  • 14
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    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 6 (1962), S. 122-129 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: This paper describes European use of glued construction for structural joints in aircraft. It discusses the important considerations in design and strength analysis of stiffened compression and shear panels and considers aspects of detail design in bonded structures.
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  • 15
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    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 6 (1962), S. 130-135 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Essentially the entire surface of the U. S. Air Force B-58 supersonic bomber is aluminum-bonded panel construction. Primary as well as secondary structural bonded panels were designed and manufactured to operate under demanding service conditions which include high stress, subzero temperature, high temperature, and severe acoustical vibration. Smooth surfaces are an additional requirement at subsonic and supersonic speeds. These requirements demanded that bonded joints in the B-58 be carefully designed and thoroughly evaluated. Joints in the B-58 were designed by “empirical procedures,” established for a specific adhesive syetem. Large numbers of test panels were required to confirm panel integrity and establish allowables for design. The development and adoption of accurate theoretical technique for predicting joint streqgths has been pursued and can be expected to reduce both the cost and the amount of testing required to achieve reliable deign with adhesives.
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  • 16
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    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 6 (1962), S. 136-144 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: In this paper the subject of peel is divided into two parts: (1) A mathematical determination of peeling stresses in an adhesive bond due to the applied peeling loads which leads to a mathematical definition of “peel strength.” (2) A review of suitable peel test methods examined in the light of this definition. Employing the assumption that the adhesive bond behaves as an ideal homogeneous elastic material under load, the classical derivation of the deflection of a loaded beam on an elastic foundation is applied to the calculation of peel strength of a metal adhesive. This theory results in a mathematical definition of peel strength and offers a reasonable explanation of the effects of the important variables such as metal and adhesive thickness and strength properties and provides a basis for the comparison and evaluation of the few testing methods presently in use.
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  • 17
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    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 6 (1962), S. 145-149 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Loading a lap joint in tension causes the adherends to increase their tensile stress over the nominal because of the bending produced by the offset of the joint. Knowing the configuration of the joint and the tensile stress, the stress distribution in the adherends outside the joint can be determined. The theory, with resulting equations, is based on the assumption that the adherends act like a plate bent to a cylindrical surface. If the bending of the adherends is eliminated by the use of a double overlap joint, the stress distribution in the adhesive can be determined. This analysis is based on existing mathematical findings of the load distribution in riveted joints. The resulting equations have been proven experimentally by the use of the photo stress technique, and can be applied to adhesively bonded, soldered, brazed, welded, and under certain conditions, riveted joints.
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  • 18
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    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 6 (1962), S. 150-154 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: If an adhesive joint is to be strong and permanent its adherend surfaces must be treated at least to remove oil, dirt, and dust. In addition, control of surface roughness, oxide formations, and sometimes adsorbed water is required. Deposition of chromium atoms or TiO2 is indicated for electron donor metals surfaces, and treatments may be useful to protect the adhesive from the adherend or vice versa, or to make their structures more congenial.
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  • 19
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    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 6 (1962), S. 155-160 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Structural adhesives are one of the more important developments in the adhesives field because they make possible bonded assemblies in lightweight structures which take full advantage of the strengths of the materials used. Structural adhesives can be divided into two classes. One class consists of hard brittle resins typified by unmodified epoxy adhesives which have high shear and tensile strengths but low peel strength. The second class consists of a combination of resins resulting in a more ductile type of adhesive which has high peel strength along with high shear and tensile strength. One application is described here in which an epoxy adhesive is used in a design which minimizes peel forces and which causes failure of the bonded assembly in the metal. The evaluation of this design showed it to be successful.
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  • 20
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    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 6 (1962), S. 166-175 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: This paper discusses the technology of adhesives employed in printed circuitry. The chemical types of adhesives are described and their general characteristics are given. Typical printed circuit processes are used to spotlight the demands placed on the adhesives. Test methods and requirements peculiar to printed circuitry are discussed in detail, and particular emphasis is placed on those properties which will not be too obvious to the adhesives technologist unfamiliar with circuitry. Secondary applications of adhesives in printed circuitry are touched on briefly, and mention is made of bonding methods in use or under development which do not employ adhesives. Numerous literature references are given.
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  • 21
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    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 6 (1962), S. 161-165 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Although considerable research has been conducted to establish the performance of various adhesives under different conditions of service, much remains to be done. Of great importance are basic studies of the mechanisms of deterioration of adhesives in joints under known conditions so that reliable short-term performance tests may be devised to determine the expected performance of adhesives under various service conditions. Such research needs will undoubtedly be increased in importance by the continued introduction of new adhesives of different chemical types. In all probability, the nature of the adherend influences not only initial adhesion but also subsequent joint performance. Most experience reported here on permanence of joints has been gained with wood, but research on metal adhesives is also reviewed.
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  • 22
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    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 6 (1962), S. 176-183 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Special adhesives for bonding of unvulcanized and vulcanized elastomers are discussed. Major emphasis is placed on adhesives and conditions for bonding of vulcanized elastomers. The decline of brass plating is reviewed. Various methods of adhesion testing are discussed and illustrated. Available organic polymer based adhesives will produce high strength bonds to a wide variety of unvulcanized olefinic elastomers. A single coat adhesive has been developed which provides “maximum performance adhesive bonds” to a variety of unvulcanized elastomers. Factors affecting bonding and “bondability index” for the common elastomers are described. The bonding of vulcanized elastomers is a more difficult task. Present adhesives require mechanical or chemical modification of the surface of the elastomer. Brute force tactics used in conjunction with epoxy-polyamide, phenolic-polyvinyl formal, or nitrilephenolic systems have performed well in some applications. The quality of these bonds, however, does not equal those produced to unvulcanized elastomers. With cooperation of the users, the adhesive suppliers are developing newer, more effective products to meet the challenge of the advanced polymers and increasingly severe environments in which they are used.
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  • 23
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    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 6 (1962), S. 184-192 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: (1) The prognosis for adhesives uieful up to an hour at 1000°F., in air, is good. (2) Organic adhesives based on phenolic and silicone-phenolic resins are more capable than expected of usefulness at 1000°F. (3) Preparation of semiinorganic adhesives by reaction of heat stable organic polymers with inorganic reagents is feasible. (4) The prospect appears excellent for the achievement of adhesives to be used for 1000 hr. at 500°F., in air, on steel. (5) Despite research on 2000°F. adhesives, effort is still urgently needed on materials for use at lower temperatures. (6) Perhaps the area with the most serious shortage of information and research is the development and testing of adhesives for use at 180-500°F. for periods of three to five years. Both military and civilian agencies are planning the construction of supersonic transports which need such structural adhesives.
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  • 24
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    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 6 (1962), S. 193-197 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Methods by which synthetic adhesives can be cured at ambient temperatures are covered. The alkyl cyanoacrylates, epoxies, and MPL monomers can be cured, with little shrinkage, to obtain metal adhesive bonds which compare favorably to those obtained by high temperature modes of curing. An investigation by which novolac epoxies were rendered more flexible with accompanying increases in the temperature and salt spray resistance is described.
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  • 25
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    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 6 (1962), S. 204-209 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The advantages to be derived from the use of structural adhesives are discussed. Specific developments are cited to illustrate the effectiveness of adhesives in ordnance materiel. Problems peculiar to ordnance applications are discussed. The strengths of adhesive bonds as determined by “static” and “dynamic” conditions are compared, and the importance of proper joint geometry is illustrated.
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  • 26
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    Journal of Applied Polymer Science 6 (1962), S. 198-203 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Rapid technological advancements have contributed to the increasing application of adhesives. Because of these accomplishments, because of continuing materials research and process development activities, and because of their inherent advantages, adhesives have a great potential for the future. Requirements for the future impose a severe challenge on developmental capabilities. More severe structural requirements and environmental conditions may be expected. Because of increasing complexity and costs, there are requirements for significantly higher orders of reliability and lower fabrication costs. Improvements in bonding processes and development of comparatively new techniques are desirable. Test methods require further development and standardization - especially nondestructive methods. Continuing work in collecting and reporting pertinent information, especially on properties and design parameters for adhesive bonding is helping to advance the utilization of adhesives. Current trends indicate that adhesives are progressing from the realm of “art” to science, a factor which should substantially aid in advancing the future potential for adhesives.
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  • 27
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    Materials and Corrosion/Werkstoffe und Korrosion 13 (1962), S. 699-701 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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    Materials and Corrosion/Werkstoffe und Korrosion 13 (1962), S. 702-703 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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    Materials and Corrosion/Werkstoffe und Korrosion 13 (1962), S. 707-709 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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    Materials and Corrosion/Werkstoffe und Korrosion 13 (1962), S. 730-730 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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    Materials and Corrosion/Werkstoffe und Korrosion 13 (1962), S. 730-730 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
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  • 34
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
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    Materials and Corrosion/Werkstoffe und Korrosion 13 (1962), S. 731-731 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Materials and Corrosion/Werkstoffe und Korrosion 13 (1962) 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 37
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    Materials and Corrosion/Werkstoffe und Korrosion 13 (1962), S. 742-745 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 38
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    Materials and Corrosion/Werkstoffe und Korrosion 13 (1962), S. XXXI 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 39
    ISSN: 1434-193X
    Keywords: Triplet recombination ; Electron transfer ; Radical ions ; Photochemistry ; Terpenes ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: ---The triphenypyrylium tetrafluoroborate (TPT)-sensitized reactions of several terpene donor molecules, including sabinene (1), α-phellandrene (4), α-terpinene (5) and γ-terpinene (6) give rise to significantly different products than reactions induced by other electron-transfer sensitizers, such as 1,4-dicyanobenzene (DCB). The divergent reactions require decidedly different key intermediates; the products obtained with TPT can be explained by dissociative recombination of the intermediate radical-radical cation pair in the triplet state, generating donor-derived biradicals.
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  • 40
    ISSN: 1434-193X
    Keywords: Azides ; Cleavage reactions ; Cycloadditions ; Nitrogen heterocycles ; Polycycles ; Ring expansion ; Synthetic methods ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: ---2-Alkyl-1-methylquinazolinium hexafluorophosphates 9 are deprotonated by sodium or potassium hydride to afford solutions of 2-alkylidenedihydroquinazolines 10, which were investigated by NMR spectroscopy. Trapping with methanesulfonyl azide (5a) of 10 in situ or subsequent treatment with trifluoromethanesulfonyl azide (5b) gives mixtures of colourless (15) and intensely yellow N-sulfonylimino-1,4-benzodiazepines 16 along with products due to cleavage of the exocyclic double bond of 10, viz. 11 and 13. The ethylidene compound 10b yields the bicyclic products 18 and 19, apparently by complex sequences of reactions that are triggered by removal of the acidic proton at C-2 of 16b and 16f. The structures of the products are based on spectroscopic evidence and X-ray diffraction analyses performed on 15b, 16d, 16e, and 19.
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  • 41
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    Liebigs Annalen 2000 (2000), S. 1589-1593 
    ISSN: 1434-193X
    Keywords: Azaallenium ions ; Azaallylium ions ; Iminium ion ; Kinetics ; Linear Free Energy Relationships ; Ab initio calculations ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: ---The rate constants for the reactions of the 2-azaallenium ion 1b+, the 2-azaallylium ion 2a+ and the iminium ion 3+ with different nucleophiles were determined by 1H NMR spectroscopy. By correlation with the Linear Free Enthalpy Relationship (LFER) lg k20°C = s (E + N), developed by Mayr and Patz, the electrophilicity parameters E(1b+) = -3.7, E(2a+) ≍ -16 and E(3+) = -10.43 were obtained. They show that the relative reactivities of these ions are approximately 1012:1:106. Quantum chemical calculations (ab initio, DFT) of the methyl anion affinities for the ions 1b+,2a+ and3+ are in agreement with the experimental E values. The X-ray structure of 3+·CF3SO3- is reported for the first time; it shows no strong interaction between the cation and the anion.
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  • 42
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    Liebigs Annalen 2000 (2000), S. 1595-1601 
    ISSN: 1434-193X
    Keywords: Oxazoline N-oxide ; Cycloadditions ; Cycloadditions ; Lactams ; Thienamycin ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: ---[3+2] Cycloaddition between a camphor-derived oxazoline N-oxide 9 and the γ,δ-unsaturated enamino ester 11 afforded the single adduct 6. A stereoselective reduction of the enamino ester side chain allowed the control of the absolute configuration of the two additional asymmetric centres. Nitrogen protection and oxidative hydrolysis of the resulting product 13, followed by further functional group manipulations, led to the β-lactam derivative 1, a known precursor of the β-methylthienamycin derivative2a.
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  • 43
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    Liebigs Annalen 2000 (2000), S. 1603-1607 
    ISSN: 1434-193X
    Keywords: Boron ; Cyclotrimerizations ; Nitrogen heterocycles ; Macrocycles ; Subphthalocyanines ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: ---The regioselective preparation of ortho-substituted subphthalocyanides was achieved employing 3-substituted phthalonitrile derivatives as starting materials. A mechanistic proposal has been outlined.Supporting information for this article is available on the WWW under //http://www.wiley-vch.de/contents/jc_2046/2000/99525_s.pdf or from the author.
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  • 44
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    Liebigs Annalen 2000 (2000), S. 1609-1615 
    ISSN: 1434-193X
    Keywords: Terpenoids ; Natural products ; Total synthesis ; Cyclizations ; Rearrangements ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: ---A new route for the synthesis of 2,7- and 7-functionalized labdanes starts from (R)-carvone (1). 11-Nordrim-7-en-9-one (15) is an appropriate starting material for the total synthesis of hispanone (21), a biologically active furolabdane isolated from the Mediterranean medicinal plant Ballota saxatilis.
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  • 45
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    Liebigs Annalen 2000 (2000), S. 1623-1626 
    ISSN: 1434-193X
    Keywords: Iridoid glucoside ; (8S)-Kingiside ; (8S)-Loganin ; (8S)-7-Ketologanin ; Asymmetric synthesis ; Natural products ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: ---The tetraacetyl derivative 8 of the naturally occurring kingiside (8a) was prepared from aucubin (1). Intermediates in the synthesis were (8S)-tetraacetyl loganin (6) and (8S)-tetraacetyl-7-ketologanin (7), whose free (8R)-epimers occur in many different plants (Caprifoliaceae, Loganiaceae). The 13C NMR spectrum allows the structure to be unequivocally identified.
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  • 46
    ISSN: 1434-193X
    Keywords: Tetrakis(dimethylamino)naphthalenes ; Basicity ; Hydrogen bonds ; Cyclicvoltammetry ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: ---For comparison to the recently described 2,3,6,7-tetrakis(dimethylamino)naphthalene (1) the three isomers 2,3, and 4 were synthesized. The basicities of this group of isomers are strongly dependent upon the different mutual orientations of the pairs of dimethylamino substituents: only the isomers 3 and, partially, 4, both with dimethylamino groups in adjacent peri-positions of the naphthalene, are strong “proton sponges”. For the isomers 1 and 2 with the same number and kind of twofold dimethylamino substituents in neighbouring ortho-positions, however, no significant basicity increase is observed. To explain this difference between the two groups of isomers it is suggested that in the ortho-pairs of 1 and 2 the C-N bonds diverge considerably, leading to an increased N···N distance and consequently to less stable [N···H···N]+ hydrogen bonds in contrast to the parallel C-N bonds in the peri-substituted isomers 3 and 4. X-ray crystal structure analyses of the bases and of some of the salts derived therefrom were solved and are discussed. Cyclic voltammetry indicates that 1 to 4 are strong electron donors, reacting easily to radical cations or dications which with suitable acids have been obtained as salts.
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  • 47
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    Liebigs Annalen 2000 (2000), S. 1677-1683 
    ISSN: 1434-193X
    Keywords: Radicals ; Cyclizations ; Pyridinethione ; Tetrahydrofurans ; Asymmetric synthesis ; Thiazolethione ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: ---The trisubstituted functionalized tetrahydrofurans 10, 11, 16, 18, and 19 were photochemically prepared from 2,3-syn- and 2,3-anti-configuredN-(3-benzoyloxy-5-hexen-2-oxy)thiazole-2(3H)-thione anti-6, pyridinethiones 7, anti-8, and BrCCl3. The formation of tetrahydrofurans was achieved by an efficient and highly regioselective alkoxyl radical cyclization (5-exo-trig). The 2,3-anti substituted intermediates 9 and 12 cyclize stereoselectively whereas a 2,3-syn-configured O-radical affords both possible diastereomeric addition products in equal amounts. The cyclized tetrahydrofuryl methyl radicals were trapped with the bromine atom donor BrCCl3 to afford the bromomethyl-substituted cyclic ethers 10, 11, 18, and 19 in excellent yields. The utility of this reaction was stressed by conversion of one of the newly prepared tetrahydrofurans in a two-step synthesis into (+)-allo-muscarine (+)-20.Supporting information for this article is available on the WWW under //http://www.wiley-vch.de/contents/jc_2046/2000/99590_s.pdf or from the author.
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  • 48
    ISSN: 1434-193X
    Keywords: Thioketones ; Thiocarbonyl ylides ; Cycloadditions ; Cycloreversions ; Sulfur heterocycles ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: ---Reactions of diaryl thioketones with diazomethane at room temperature afford 4,4,5,5-tetraaryl-1,3-dithiolanes; the scope of this surprising 2:1 interaction has been studied for decades (Schönberg Reaction). The clue to the mechanism was our observation that the stoichiometry is 1:1 at -78 °C, and 2,5-dihydro-2,2-diaryl-1,3,4-thiadiazoles are formed as primary [2+3] cycloadducts. They lose N2 at -45 °C in first-order reactions generating diaryl thioketone S-methylides which can be intercepted by thioketones (→1,3-dithiolanes), multiple CC bonds, or acids HX. In the absence of trapping reagents, the elusive intermediates either dimerize furnishing 2,2,3,3-tetraaryl-1,4-dithianes or give rise to 2,2-diarylthiiranes by electrocyclization. Beyond thiobenzophenone and diazomethane, our main model reaction, the studies involve fluorene-9-thione, 4,4-dimethoxy- and 4,4-dichlorothiobenzophenone. The ring of 2,5-dihydro-2,2-diphenyl-1,3,4-thiadiazole (8) is opened by LDA at -78 °C and derivatives of anion 12 are obtained. - In summa: The Schönberg reaction consists of two 1,3-dipolar cycloadditions, linked by a 1,3-dipolar cycloreversion.
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  • 49
    ISSN: 1434-193X
    Keywords: Conjugation ; Boron ; Sensors ; Cyclic voltammetry ; Polymers ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: ---New electropolymerizable aromatic compounds (i.e. pyrrole, thiophene, aniline) bearing boronic acid and ester substituents have been synthesized and their electrochemical behavior has been investigated. Functionalized polythiophene and polypyrrole films could be anodically generated in acetonitrile, whereas the polyaniline derivative was electroformed in an acidic aqueous solution. The electrochemical responses of some of these materials were changed when fluoride ions were added to the electrolytic solutions. The strongest modifications, caused by binding of fluoride by the immobilized boron, were observed for the polypyrrole derivative in hydroorganic media.
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  • 50
    ISSN: 1434-193X
    Keywords: Heterocycles ; Zinc ; Palladium ; Catalysts ; Sulfur ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: ---Organozinc halides derived from Grignard reagents behave differently in their reaction with ethyl (±±)-(2RS,3SR)-tetrahydro-4-methylene-2-phenyl-3-(phenylsulfonyl)furan-3-carboxylate (3) according to the hybridisation of the carbon ligand. During the development of short multi-component reactions for the synthesis of diverse functionalized ethyl 2,5-dihydrofuran-3-carboxylates it was discovered that aryl and vinyl zinc halides undergo clean reaction with 3 in the presence of Pd(PPh3)4. In contrast, when alkyl zinc halides are reacted with 3 in the presence of Pd(PPh3)4, reductive desulfonation of 3 is observed. Remarkably, in the absence of a transition metal catalyst, the allylic substitution of 3 with alkyl zinc halides proceeds cleanly and in moderate to good yield.
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  • 51
    ISSN: 1434-193X
    Keywords: Self-assembly ; Vapor-pressure osmometry ; Resorcin[4]arenes ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: ---Resorcin[4]arene tetracarboxylic acids 5,6 (A) and resorcin[4]arene tetrapyridines 2,3 (P) self-assemble in chloroform solution to form stable heterotopic AP dimers. Data from NMR titration and dilution experiments, as well as from vapor-pressure osmometry (VPO), indicate that the AP dimer is formed with an association constant greater than 107 M-1. Solid-solution extraction experiments are indicative of the formation of a 2:1 trimer (A2P), while self-associated homotopic species (A2 and A3) can be detected by NMR and VPO. Analysis of the heterotopic noncovalent assembly process over a range of compositions shows that these other species are much less stable than the AP heterodimer, which is the exclusive species at an A/P concentration ratio of 1:1 (〉 99.7% of the total at 10 mM).
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  • 52
    ISSN: 1434-193X
    Keywords: Sulfoxides ; β-Amino sulfones ; Mannich type reaction ; Lithium perchlorate ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: ---The LiClO4-mediated one-pot reaction of aldehydes with (trimethylsilyl)dialkyl amines and the lithium salt of sulfoxides or sulfones, affords the corresponding β-(dialkylamino) sulfoxides and β-(dialkylamino) sulfones in high yields. The aminosulfoxidation reaction of aliphatic or aromatic aldehydes lacks diastereoselectivity, but the diastereomeric sulfoxides can be separated by HPLC or column chromatography for further use.
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  • 53
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    Liebigs Annalen 2000 (2000), S. 1741-1744 
    ISSN: 1434-193X
    Keywords: Bridged pyranose derivatives ; Ring enlargement ; Carbenes ; Glycosides ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: ---Addition of dichlorocarbene to the glycal (±±)-2 followed by cyclopropyl-allyl rearrangement leads to the chloro-2H-pyran (±±)-4. Oxidation of (±±)-4 and reduction of the obtained hydroxypyranone (±±)-5 gave the methyl pyranoside (±±)-6. The relative configuration of (±±)-6 was established by X-ray structural analysis of the corresponding acetate (±±)-7. The synthesis of the optically active starting materials (+)-2 and (-)-2 is also reported.
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  • 54
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    Liebigs Annalen 2000 (2000), S. 1745-1758 
    ISSN: 1434-193X
    Keywords: CMP-Neu5Ac analogues ; Enzyme inhibitors ; Substrate analogues ; Transition state analogues ; Transferases ; Carbohydrates ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: ---Quinic acid was transformed into phosphitamides 16, 25, and 36, which could be readily linked to 5′-O-unprotected cytidine derivative 17. Ensuing oxidation of the obtained phosphite triesters with tBuO2H and hydrogenolytic de-O-benzylation furnished the corresponding phosphate diesters 18, 26, and 38. Base catalyzed removal of acetyl protecting groups, and methyl ester hydrolysis furnished CMP-Neu5Ac analogues 1d, 1e, and 2. Quinic acid was also transformed into 1,2-unsaturated diallyl α-hydroxymethyl-phosphate derivatives (R)- and (S)-46, which on reaction with cytidine phosphitamide 47 afforded the phosphite triesters. Subsequent oxidation with tBuO2H and then treatment with NEt3 gave phosphate diester derivatives (R)- and (S)-48. Deallylation, acetyl group removal, and methyl ester hydrolysis furnished (R)- and (S)-3, respectively. Treatment of (R)- and (S)-48 with DBU as a base led to acetic acid elimination, thus yielding, after de-O-allylation, acetyl group cleavage, and ester hydrolysis, diene derivative (E)-4. Donor substrate analogues 1d and 1e exhibited good α(2-6)-sialyltransferase inhibition (Ki: 2.0·10-4 and 2.0·10-5 M). However, transition state analogues (R)-, and particularly (S)-3 showed excellent inhibition properties (Ki: 1.6·10-6 and 2.7·10-7 M).
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  • 55
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    Liebigs Annalen 2000 (2000), S. 1759-1765 
    ISSN: 1434-193X
    Keywords: Cyclitols ; Aminocyclitols ; Glycosidase inhibitors ; α-Mannosidase inhibitors ; Deoxygenation ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: ---Three deoxy derivatives 2-4 of the α-mannosidase inhibitor mannostatin A (1) were synthesized, and their inhibition of Jack bean α-mannosidase was evaluated in order to elucidate the roles of each of the three hydroxyl groups of the inhibitor. The 1- and 2-deoxy derivatives 2 and 3 retained some inhibitory activity, although reduced by a factor of about 100 relative to the parent, whereas it was completely lost with the 3-deoxy derivative 4. Structure and activity relationships are discussed in the light of these findings.
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  • 56
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    Liebigs Annalen 2000 (2000), S. 1767-1772 
    ISSN: 1434-193X
    Keywords: Circular dichroism ; Conformation analysis ; s-Triazines ; Chiral auxiliaries ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: ---CD data of the optically pure 2-[(R)-1-(9-anthryl)ethylamino]-4-chloro-6-[(R)-1-(1-naphthyl)ethylamino]-1,3,5-triazine, 2[(R)-1-(9-anthryl)ethylamino]-4,6-bis[(R)-1-(1-naphthyl)ethylamino]-1,3,5-triazine, 2,4-bis[(R)-1-(9-anthryl)ethylamino]-6-chloro-1,3,5-triazine are presented. The analysis of the CD spectra by means of the nonempirical DeVoe approach has afforded the complete conformational characterisation of the three s-triazine derivatives, allowing us to establish how the conformation of these derivatives depends on the nature of the substituent 1-arylethylamino groups.
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  • 57
    ISSN: 1434-193X
    Keywords: Cycloadditions ; Carbenes ; Nitrones ; Nitrilimines ; Pyrazolines ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: ---The reaction of tert-butylalkynyl chromium Fischer carbene complex 1 with nitrones 2 affords β-enamino-ketoaldehydes 4 by the light-promoted rearrangement of the corresponding [3+2] cycloadduct carbene complexes 3. On the other hand, [3+2] cycloaddition of chiral nonracemic Fischer alkenyl carbene complexes 19 with nitrilimines 10 yields enantiomerically pure Δ2-pyrazolines with high regio- and diastereoselectivity.
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  • 58
    ISSN: 1434-193X
    Keywords: Asymmetric synthesis ; Zinc ; Transition structures ; QM/MM computations ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: ---Trimethylsilyl substitutions of the fenchyl alcohols [(1R,2R,4S)-exo-(2-Ar)-1,3,3-trimethylbicyclo[2.2.1]heptan-2-ol, Ar = 2-methoxyphenyl (1) and Ar = 2-(dimethylaminomethyl)phenyl (2)] yield the chiral ligands 3 [Ar = 2-methoxy-3-(trimethylsilyl)phenyl] and 4 [Ar = 2-(dimethylaminomethyl)3-(trimethylsilyl)phenyl]. Increased reactivities and enantioselectivities in diethylzinc additions to benzaldehyde are obtained from 3 (63% ee R) and 4 (93% ee S), relative to 1 (26% ee S) and 2 (73% ee S). X-ray crystal structures of 3 and of its methylzinc complex 3-Zn reveal out-of-plane bending of the methoxy groups as major geometrical consequences of the trimethylsilyl substitutions. Analyses of QM/MM ONIOM μ-O transition-structure models for 1, 2, 3, and 4 show that trimethylsilyl-induced distortions of methoxy and of dimethylaminomethyl groups explain the observed increased enantioselectivities.
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  • 59
    ISSN: 1434-193X
    Keywords: Palladium ; exo-π-Allylpalladium complexes ; Allylic alkylation ; Spiro compounds ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: ---The palladium(0)-catalyzed alkylation of 2,3-bis(acetoxymethyl)bicyclo[2.2.1]hepta-2,5-diene 1 with malonate-type enolates as nucleophiles is investigated. A monoalkylated product is formed first, and undergoes (depending on the nucleophile used) a second intramolecular reaction leading to spirocyclopropane-annulated bicyclo[2.2.1]heptene derivatives 5. The formation of endo spirobicyclic cyclopropanes adducts as major isomer is rationalized by assuming formation of an intermediate exo-(π-allyl)palladium complex.
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  • 60
    ISSN: 1434-193X
    Keywords: Ketones ; Reductions ; Micelles ; Cobalt ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: ---Operationally simple and environmentally benign procedures have been developed to selectively reduce different α,β-unsaturated ketones, 4,4-dimethylcyclohex-2-ene-1-one (1), isophorone (2), benzylideneacetone (3), chalcone (4) by NaBH4 or by the system NaBH4 + CoCl2. Alternative reaction media to the extensively used MeOH have been explored, and new procedures take advantage of the acceleration and chemoselectivity induced by water or by aqueous micellar solutions. It was possible to selectively and quantitatively afford pure products of 1,2 and of 1,4 reduction as well as the totally reduced compounds (yield and selectivity 〉 90%) by simple changes in the experimental conditions.
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  • 61
    ISSN: 1434-193X
    Keywords: C-Glycosides ; Conformation analysis ; Molecular dynamics ; Selectins ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: ---The conformational behavior of the C-glycosyl analogue of sialyl-α-(2→3)-galactose, synthesized as a glycosidase inhibitor, has been studied using a combination of NMR spectroscopy (J and NOE data) and molecular dynamics calculations. The obtained results show that the population distribution of conformers with respect to the orientation about the pseudo-glycosidic linkages is mainly controlled by steric interactions. This is in contrast to findings made for O-glycosides. In these natural compounds, the conformational behavior about the glycosidic linkage Φ is mainly governed by the exo-anomeric effect.
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  • 62
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    Liebigs Annalen 2000 (2000), S. 1815-1820 
    ISSN: 1434-193X
    Keywords: Asymmetric synthesis ; Palladium-catalysed couplings ; Palladacycles ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: ---Chiral C2-symmetric N-benzylazetidines have been conveniently prepared from optically pure anti-1,3-diols without loss of enantiomeric purity. N-Debenzylation led to the corresponding N-unsubstituted azetidines, which were then subjected to palladium-catalysed coupling reactions with aryl bromides to afford chiral N-arylazetidines. (R,R)-N-Benzyl-2,4-dimethylazetidine has been employed in the synthesis of a new cyclopalladated complex, which can be used, for instance, as a chiral recognition agent for phosphorus ligands.
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  • 63
    ISSN: 1434-193X
    Keywords: Cyclizations ; Spiro compounds ; Nucleosides ; Isomerizations ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: ---Syntheses of the spiro nucleosides 2′-deoxyhydantocidin 3a and its 1′-epimer 3b are described. The newly developed route involves a Horner-Wadsworth-Emmons condensation of the phosphonate 16 with the erythrose derivative 15 affording a mixture of six isomers which was fully assigned by NMR spectroscopy. The mixture was directly converted into the final compounds in an efficient base-catalyzed cyclization reaction. A base-catalyzed interconversion between the two isomers was observed.
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  • 64
    ISSN: 1434-193X
    Keywords: Benzodiazepines ; Heterocycles ; Azeto[1,2-a]-1,5-benzodiazepines ; Cyclizations ; Cycloadditions ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: ---The reaction of o-phenylenediamine (4) with one, two or three equivalents of p-substituted 3-dimethylaminopropiophenone hydrochlorides 5a-e was studied. 4-Aryl-2,3-dihydro-1H-1,5-benzodiazepine derivatives 6a-e were obtained in good yields, along with the 1:2-adducts 7c-e and the unexpected 1:3-adducts rac-8c-e. The type of adduct formed is determined by the molar ratio of the reactants 4 and 5 and by the nature of the substituent in the para position of the propiophenone 5.
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    ISSN: 1434-193X
    Keywords: Cup-shaped PAHs ; Host-guest compounds ; Host-guest chemistry ; Cyclizations ; Semiempirical calculations ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: ---Cyclotrimerisation of benzo-polycyclic bromostannylalkenes 8a-d with Cu(NO3)2·3H2O in THF affords benzotri(benzonorbornadienes) 3a-d as a mixture of the syn and anti isomers. The ratio of syn to anti is close to the 1:3 statistical value in most cases (i.e. in cyclotrimers 3a,b,d), but highly in favour of the anti isomer in 3c, where steric hindrance by the methoxy groups plays an important role in the stereochemistry of the cyclotrimerisation. The substrates for the cyclotrimerisation, i.e. the bromostannyl alkenes 8a-d, were prepared from bromoalkenes 7a-d by treatment with base (LDA) and quenching with trimethyltin chloride. In turn, bromoalkenes 7a-d were prepared from alkenes 5a-d by radical bromination-elimination. The reaction conditions used were designed to minimise Wagner-Meerwein rearrangements that would lead to unwanted bromo isomers. The cup-shaped syn cyclotrimers 3a-d exhibit high electron density within the cavity as determined by AM1 semiempirical calculations of their electrostatic potential surfaces and are valuable substrates for supramolecular chemistry. As an example, it is shown that fullerene C60 is drawn into solution in acetonitrile by complexation with both the syn and anti trimer of benzonorbornadiene 3a.
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    Materials and Corrosion/Werkstoffe und Korrosion 13 (1962) 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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    Materials and Corrosion/Werkstoffe und Korrosion 13 (1962), S. 14-20 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Description / Table of Contents: The behaviour of synthetic chemical fibres used for technical fabricsSynopsis of the range of synthetic chemical fibres. - Applications of the technical fabrics manufactured from them. - Description of the stresses to which the technical fabrics are exposed, the kinds of damage thereby encountered, and the means of preventing or reducing such damage.
    Notes: Übersicht über die synthetischen Chemiefasern - Einsatzgebiete der daraus hergestellten technischen Gewebe - Beschreibung der Beanspruchungen, denen die technischen Gewebe ausgesetzt sind, der Schädigungen, die hierbei auftreten und wie man sie verhindern bzw. reduzieren kann.
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    Materials and Corrosion/Werkstoffe und Korrosion 13 (1962), S. 29-33 
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    Keywords: Chemistry ; Polymer and Materials Science
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    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Morphological structure and formation of cracks in crystallizing macromolecular materialsAfter a brief survey of present-day knowledge of morphological structures (laminations, fibrels and spherulites), the author discusses the tests carried out to obtain some knowledge about the internal crack system of macro-molecular materials with the aid of permeation and diffusion measurements on terylene films as a function of the degree of crystallisation and of temperature. It is found that, with careful thermal and mechanical treatment, it is quite possible to avoid the formation of major continuous cracks and a corresponding degree of corrosion proneness.Cracks may occur if the crystallisation process is continued for too long a time at too high temperatures. In this case, microscopic examinations or X-ray crystal density methods may be applied. The last section deals with tests carried out to explore the formation of cracks in coarse-crystalline iso-tactic polypropylene, caused by wetting agents. Cracks are found to occur partly already during crystallisation, and partly during the subsequent cooling; they occur in the direction of the spherulite radii as well as along the grain boundaries.
    Notes: Nach einem kurzen Überblick über die heutigen Kenntnisse der morphologischen Strukturen (Lamellen, Fibrillen und Sphärolithe) werden die Versuche besprochen, und mit Hilfe von Permeations- und Diffusionsmessungen an Terylenfilmen in Abhängigkeit vom Kristallisationsgrade und der Temperatur einen Einblick in das innere Rißsystem won makromolekularen Werkstoffen zu bekommen. Es zeigt sich, daß man bei schonender thermischer und mechanischer Behandlung eine gröbere durchgehende Rißbildung u. entsprechende Korrosionsanfälligkeit durchaus vermeiden werden kann.Kristallisiert man zu lange bei zu hohen Temperaturen so tritt Rißbildung auf. Hier kommen dann mikroskopische Untersuchungen sowie solche der kontinuierlichen Röntgenkleinwinkelstreuung in Frage. Im letzten Abschnitt werden Versuche über die durch Netzmittel induzierte Rißbildung in grobkristallinen isotaktischen Polypropylen besprochen. Risse entstehen teils schon während der Kristallisation, teils beim darauffolgenden Abkühlen sowohl in Richtung der Sphärolithradien wie entlang der Korngrenzen.
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    Materials and Corrosion/Werkstoffe und Korrosion 13 (1962), S. 41-45 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Materials and Corrosion/Werkstoffe und Korrosion 13 (1962), S. 45-53 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Materials and Corrosion/Werkstoffe und Korrosion 13 (1962), S. 53-53 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Materials and Corrosion/Werkstoffe und Korrosion 13 (1962), S. 55-55 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Materials and Corrosion/Werkstoffe und Korrosion 13 (1962), S. 55-55 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Materials and Corrosion/Werkstoffe und Korrosion 13 (1962), S. 57-57 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Materials and Corrosion/Werkstoffe und Korrosion 13 (1962), S. 59-63 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Materials and Corrosion/Werkstoffe und Korrosion 13 (1962), S. 83-92 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: The mechanical properties of metallic materials at low temperaturesKnowledge of the behaviour of metallic materials subjected to mechanical stresses at low temperatures is gaining in importance. Especially in refrigeration technology, e. g. in connection with the liquefaction, storage and transport of gases, one tries to use materials which, while being as inexpensive as possible, retain their strength properties even under unfavourable stress conditions at low temperatures. Under such conditions, both the deformation resistance and the variables characterizing the deformability depend on the crystal structure. It has been possible to achieve a great expansion in the use o f non-alloyed structural steels through the application a1 a special metallurgical treatment of the melts, e. g. through reduction of the quantity of gas dissolved. The range of application of these steels which, depending on the strain and on the possible consequences of fractures, reaches as far as -50° C, is followed by the range of heat-treated alloyed steels which goes down to -120° C. For even lower temperatures, austenitic steels can be used. Because fo their anisotropic behaviour, especially at low temperatures, cast iron/carbon alloys such as cast steel are more fracture-prone than hot-processed materials, unless the irregularities in the stress absorption capacity are largely overcome by suitable annealing treatments. Whilst, in particular, non-alloyed cast iron tends to show, at low temperatures, a reduction in strength when exposed to sudden stresses, both copper and aluminium alloys retain their high impact strength even at very low temperatures.
    Notes: Die Kenntnisse des Verhaltens metallischer Werkstoffe bei mechanischen Beanspruchungen bei tiefen Temperaturen gewinnt zunehmend an Bedeutung. Vor allem in der Kältetechnik, z. B. im Zusammenhang mit der Verflüssigung, Lagerung und Beförderurng von Gasen ist man bestrebt, mit möglichst billigen Werkstoffen, die auch unter ungünstigen Beanspruchungsbedingungen bis zu tiefen Temperaturen ihre Zähigkeitseigenschaften behalten, auszukommen. Bei tiefen Temperaturen sind sowohl die den Formänderungswiderstand sowie die die Formänderungsfähigkeit kennzeichnenden Größen von der Kristallstruktur abhängig. Die Verwendung unlegierter Baustähle konnte durch besondere metallurgische Behandlung der Schmelzen, z. B. durch Verminderung der gelösten Gasmengen sehr erweitert werden. An den Verwendungsbereich dieser Stäuhle, der je nach Anstrengung und Gefährlichkeit eventueller Bruchauswirkungen bis -50° C reicht, schließt sich der der vergüteten, legierten Stähle für Temperaturen bis -120° C; für noch tiefere Temperaturen schließt sich das Gebiet der Anwendung austenitischer Stähle an. Gegossene Eisen-Kohlenstoff-Legierungen sind, wie z. B. Stahlguß, wegen des anisotropen Verhaltens besonders bei tiefen Temperaturen bruchempfindlicher als warmverarbeitete Werkstoffe, wenn nicht durch entsprechende Glühbehandlungen die Ungleichmäßigeiten in der Beanspruchungsfähigkeit des Kleingefüges weitgehend behoben werden Während besonders unlegiertes Gußeisen bei tiefen Temperaturen Zähigkeitsverminderungen bei plötzlich wirkenden Beanspruchungen aufweist, sind sowohl Kupfer-, als auch Aluminium-Legierungen bis zu tiefsten Temperaturen sehr schlagzähe.
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    Materials and Corrosion/Werkstoffe und Korrosion 13 (1962), S. 101-105 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Materials and Corrosion/Werkstoffe und Korrosion 13 (1962), S. 95-100 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Materials and Corrosion/Werkstoffe und Korrosion 13 (1962), S. 106-110 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Materials and Corrosion/Werkstoffe und Korrosion 13 (1962), S. 116-122 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Materials and Corrosion/Werkstoffe und Korrosion 13 (1962), S. 123-123 
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    Materials and Corrosion/Werkstoffe und Korrosion 13 (1962), S. 126-127 
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    Materials and Corrosion/Werkstoffe und Korrosion 13 (1962), S. III 
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    Materials and Corrosion/Werkstoffe und Korrosion 13 (1962), S. 129-132 
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    Materials and Corrosion/Werkstoffe und Korrosion 13 (1962), S. 157-160 
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    Materials and Corrosion/Werkstoffe und Korrosion 13 (1962), S. 151-157 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Description / Table of Contents: The progress of condensation in the testor (Kesternich) cabinet and the dependence of condensation on the properties of the tested materialCondensation in the tested cabinet proceeds in principle as follows: (a)Rapid increase to a first maximum, which depends on the tested material, and in the case of the same material on the thickness of the test piece.(b)Slowly rising undulated curve, the maxima of which coincide with the temperature maxima on the surface of the test piece and those of the period of regulation. The rate of increase is hardly dependent on the material and its thickness. The amplitude of the waves increases with increasing heat capacity of the material.Condensation ist stronger on metal than on glass and organic coatings; stranger on zinc than on cadmium.No influence of the roughness of the surface could be detected. The influence of the material on the condensation confirms previous results by Tammann.
    Notes: Die Betauung im Testergerät verlauft grundsätzlich wie folgt: (a)Rascher Anstieg zu einem ersten Maximum, dessen Höhe von der Art des Werkstoffes und bei gleichem Werkstoff von der Blechdicke abhangig ist.(b)Langsamer ansteigender Wellenzug, dessen Maxima mit Ternperaturmaxima der Blechoberfläche und der Regelungsperiode zusammenfallen. Die Steigung ist von der Werkstoffart und der Dicke wenig abhängig. Die Amplitude der Wellen nimmt mit steigender Wärmekapazitat zu.Metalle werden stärker betaut als Glas und organische Überzüge, Zink stärker als Cadmium.Ein Einfluß der Rauhtiefe war nicht festzustellen. Die gefundene Werkstoff- abhängigkeit der Betauung steht mit früheren Ergebnissen von Tammann in Einklang.
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    Materials and Corrosion/Werkstoffe und Korrosion 13 (1962), S. 143-150 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Description / Table of Contents: Causes of scale formationContinuous operation of many appliances is impeded by scale formation which is most frequently encountered on heat transmitting surfaces. The present article deals with crystalline scale formed by dissolved substances on metallic materials.A theoretical section, dealing with the influence on scale formation of such factors as pressure, temperature, extraneous matter, flow velocity and condition of the solid surface, is followed by the description of experimental investigations.The phenomenon investigated as a model is the crystallisation in radioactively marked CaSo4 solution (Ca45 and S35, respectively). The experiments show, in keeping with the theory, that macroscope scale can only appear when the solution is over-saturated. There are no essential differences as between corrosive and non-corrosive materials, the formation of blisters on the solid surface tends to promote scale formation. In this connection, the roughness of the solid surface is likewise of importance. The experimental results give rise to certain practical conclusions.
    Notes: Durch die Verkrustung, die insbesondere and wärmeübertragenden Oberflächen auftritt, ist ein Dauerbetrieb mancher Apparate nur begrenzt möglich. Die vorliegende Arbeit behandelt kristalline Krusten, wie sie sich aus gelösten Stoffen an metallischen Werkstoffen bilden.Nach einem theoretischen Abschnitt, in dem der Einfluß des Druckes, der Temperature, fremder Stoffe, der Strömungsgeschwindigkeit der Lösung sowie der Zustand der festen Oberfläche auf die Krustenbildung diskutiert wird, werden experimentelle Untersuchungen beschrieben.Als Modellvorgang ist die Kristallisation aus radioaktiv markierten CaSo4- Lösungen (45Ca bzw. 35S) untersucht, Die Versuche zeigen in Übereinstimmung mit der Theorie, daß makroskopische Krusten erst bei einer übersättigten Lösung entstehen können. Wesentliche Unterschiede liegen zwischen korrodierenden und nicht korrodierenden Werkstoffen vor. Blasenbildung an der festen Oberfläche erhöht die Krustenbildung. Hierbei ist auch die Rauhigkeit der festen Oberfläche von Bedeutung. Aus den Versuchsergebnissen werden schließlich Folgerungen fü die Praxis gezogen.
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    Materials and Corrosion/Werkstoffe und Korrosion 13 (1962), S. 175-182 
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    Materials and Corrosion/Werkstoffe und Korrosion 13 (1962), S. 186-186 
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    Materials and Corrosion/Werkstoffe und Korrosion 13 (1962), S. 187-188 
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    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
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  • 99
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 13 (1962), S. V 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
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  • 100
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 13 (1962), S. 209-211 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Influence of dry heat and of cold and hot water on wood laminatesInvestigations have been carried out on the influence of dry heat and of cold and hot water on the dynamic modulus of elasticity, on the volumetric stability, and on the weight of plywood obtained through glueing different types of tropical woods with synthetic resins.
    Notes: Untersucht und geklärt wurde der Einfluß van trockener Wärme sowie von Kalt- und Warmwasser auf den dynamischen Elastizitätsmodul, die Volumenbeständigkeit und auf das Gewicht van Sperrholz, das durch Verklebung verschiedener exotischer Hölzer mit Kunstharz erhalten wurde.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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