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  • Inorganic Chemistry  (2,068)
  • Cell & Developmental Biology  (242)
  • Industrial Chemistry  (217)
  • Spacecraft Design, Testing and Performance  (39)
  • 1960-1964  (1,118)
  • 1950-1954
  • 1930-1934  (802)
  • 1920-1924  (646)
  • 1915-1919
  • 1961  (1,118)
  • 1932  (802)
  • 1922  (646)
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  • 1960-1964  (1,118)
  • 1950-1954
  • 1930-1934  (802)
  • 1920-1924  (646)
  • 1915-1919
Year
  • 1
    Publication Date: 2019-05-11
    Description: A method for approximating the vacuum motions of spinning rigid symmetrical bodies with varying spin rates and inertias has been completed. The analysis includes the effects of time varying thrust misalignments, mass unbalance, and jet damping. Results are given in the form of equations for space referenced Euler angles, flight-path angles, body referenced attitude rates, and earth-referenced vehicle-trajectory coordinates. The method consists of dividing the problem into intervals during which the time-dependent variables are assumed constant at their mean interval value. In order to check this procedure, solutions for various interval sizes are compared with solutions obtained with numerical methods. Although the method is somewhat lengthy for accurate hand computation in most cases, it is readily programed for machine solutions. Probably more important, the general solutions give insight into the separate effects of the variables and, in many cases, can be quickly used to determine the approximate ranges of the variables required for the desired solution to a given problem. In this respect, equations for determining maximum wobble have been derived for certain input conditions. The method has been shown to compare closely with the numerical solutions of two sample problems. The sample problems also illustrated the relatively large effect of pitch and yaw jet damping on body motions.
    Keywords: Spacecraft Design, Testing and Performance
    Type: NASA-TR-R-115
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  • 2
    Publication Date: 2019-07-20
    Description: The analysis includes non-constant spin rates and inertias and considers the effects of time-varying thrust misalignments, mass unbalance, and jet damping. The method was developed for bodies having small trans verse angular velocities. Results are presented in the form of equations for space-referenced Euler angles, flight-path angles, body-referenced attitude rates, and earth-referenced vehicle-trajectory coordinates. Also, equations for maximum wobble have been derived for certain input conditions. Comparisons with numerical solutions are included for two sample problems.
    Keywords: Spacecraft Design, Testing and Performance
    Type: NASA-TR-R-115
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  • 3
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    In:  Other Sources
    Publication Date: 2019-07-12
    Description: Landing characteristics were investigated using dynamic models. The landing speeds for several let-down systems are simulated. Demonstrations include: (1) the vertical landing of parachute-supported capsules on water; (2) reduction of landing acceleration by shaping the impact surface for water entry; (3) problems created by horizontal velocity due to wind; (4) the use of energy absorbers (yielding metal legs or torus bags) for land or water landings; (5) problems associated with horizontal land landings; (6) the use of a paraglider to aid in vehicle direction control; (7) a curved undersurface to serve as a skid-rocker to convert sinking-speed energy into angular energy; (8) horizontal-type landing obtained with winged vehicles on a hard runway; (9) the dangers of high-speed water landings; and (10) the positive effects of parachute support for landing winged vehicles.
    Keywords: Spacecraft Design, Testing and Performance
    Type: L-600
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  • 4
    Publication Date: 2019-07-12
    Description: A preliminary investigation has been conducted to determine the effects of jet blast, at low ambient pressures, on a surface covered with loose particles. Tests were conducted on configurations having from one to four nozzles at 0, 10, 20, and 30 degree cant angles and heights of 2 and 4 inches above the particle-covered surface.
    Keywords: Spacecraft Design, Testing and Performance
    Type: L-671
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  • 5
    Publication Date: 2019-08-17
    Description: An investigation w a s made i n the Langley Unitary Plan wind tunnel o determine the effects of fin area and the effects of antennas and w iring tunnels on the static longitudinal and lateral stability of a 0 .10- scale model of a three- stage configuration of the Scout vehicle. The tests were performed at Mach numbers of 2.29, 2.96, 3.96, and 4. 65 6 and at Reynolds numbers of about 3.5 X 10 per foot.
    Keywords: Spacecraft Design, Testing and Performance
    Type: NASA-TN-D-711 , L-1269
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  • 6
    Publication Date: 2019-08-17
    Description: An analytical study has been made to determine the effects of mass-loading variations and onboard rotating machinery on a hypothetical earth-satellite space station, rotating to provide an artificial gravity equal to one-fourth of that at the earth's surface. Attempts were also made to damp out or minimize undesirable motions by using mass shifts, constant-rate inertia wheels, or jet-reaction moments. Results obtained indicate that the shifting of masses within the rotating space station could bring about large roll oscillations (plus or minus 100 degrees) or even continuous rolling motions if the craft is rotating about the axis of intermediate moment of inertia. The pitch angles obtained were generally small (less than plus or minus 1 degree). The amplitudes of the roll and pitch oscillations are dependent upon the angle of displacement of the greatest principal axis of inertia from the initial spin axis. In attempting to damp out or minimize undesirable motions, it was found that a constant-rate inertia wheel located on and rotating about the axis about which the craft is rotating (Z-axis) was beneficial in keeping the roll angles relatively small, provided it had a sufficient amount of angular momentum. It was also found that the use of jet-reaction moments was very satisfactory for damping undesirable motions in that the roll oscillations could be damped.
    Keywords: Spacecraft Design, Testing and Performance
    Type: NASA-TN-D-803 , L-1406
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  • 7
    Publication Date: 2019-08-17
    Description: The effects of solar radiation pressure on the motion of an artificial satellite are obtained, including the effects of the intermittent acceleration which results from the eclipsing of the satellite by the earth. Vectorial methods have been utilized to obtain the nonlinear equations describing the motion, and the method of Kryloff-Bogoliuboff has been applied in their solution.
    Keywords: Spacecraft Design, Testing and Performance
    Type: NASA-TN-D-1063
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  • 8
    Publication Date: 2019-08-17
    Description: This report considers the use of single-degree-of-freedom integrating gyros as torque sources for precise control of satellite attitude. Some general design criteria are derived and applied to the specific example of the Orbiting Astronomical Observatory. The results of the analytical design are compared with the results of an analog computer study and also with experimental results from a low-friction platform. The steady-state and transient behavior of the system, as determined by the analysis, by the analog study, and by the experimental platform agreed quite well. The results of this study show that systems using integrating gyros for precise satellite attitude control can be designed to have a reasonably rapid and well-damped transient response, as well as very small steady-state errors. Furthermore, it is shown that the gyros act as rate sensors, as well as torque sources, so that no rate stabilization networks are required, and when no error sensor is available, the vehicle is still rate stabilized. Hence, it is shown that a major advantage of a gyro control system is that when the target is occulted, an alternate reference is not required.
    Keywords: Spacecraft Design, Testing and Performance
    Type: NASA-TN-D-1073 , A-443
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  • 9
    Publication Date: 2019-08-17
    Description: Reentry trajectories, including computations of convective and radiative stagnation-point heat transfer, have been calculated by using equations for a point-mass reentry vehicle entering the atmosphere of a rotating, oblate earth. Velocity was varied from 26,000 to 45,000 feet per second; reentry angle, from the skip limit to -20 deg; ballistic drag parameter, from 50 to 200. Initial altitude was 400,000 feet. Explicit results are presented in charts which were computed for an initial latitude of 38 deg N and an azimuth of 90 deg from north. A method is presented whereby these results may be made valid for a range of initial latitude and azimuth angles.
    Keywords: Spacecraft Design, Testing and Performance
    Type: NASA-TN-D-968 , L-1750
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  • 10
    Publication Date: 2019-08-14
    Description: Problems which the solid propellant rocket engineer will encounter in designing for long-term storage in a radiation environment are discussed. A summary of present knowledge of the radiation environment is given. Mechanisms of radiation degradation and its effects on tensile properties of propellant binders are discussed qualitatively. Data from a program of irradiation of several propellants is presented. Properties of two of the propellants were changed significantly by doses of the order of 4 x 10(exp 6) rads.
    Keywords: Spacecraft Design, Testing and Performance
    Type: JPL-TR-32-234
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  • 11
    Publication Date: 2019-08-14
    Description: On 1 February 1958 at 0348 U.T. earth satellite 1958 Alpha (Explorer I) was launched from Cape Canaveral. This satellite contained a Geiger Muller tube for the measurement of the flux of energetic charged particles, and detectors for determining the micrometeorite flux and satellite temperature (see Figure 1), The high power transmitter and its associated instrumentation operated until partial exhaustion of the transmitter batteries on 12 February 1958. The transmitter reappeared briefly on 24 February, The low power system operated properly until about 0700 U,T, on 16 March, at which time the batteries powering the G.M. tube circuits became exhausted. During the operating time a large amount of data was recorded by a network of seventeen receiving stations. A sampling of early recordings was reduced and analyzed as they arrived from the receiving stations. These data, in conjunction with data from the first few orbits of 1958 Gamma (Explorer III), resulted in the announcement on 1 May 1958 of the region of high intensity radiation surrounding the earth (Van Allen, 1958), The detailed, complete reduction of the 1958 Alpha data has now been completed, This paper is a tabulation of all the data received from this satellite. It consists primarily of two parts. The first part is the master recording log on which are listed all recordings of the satellite signals obtained by the receiving station network. The actual data tabulation is contained in part two.
    Keywords: Spacecraft Design, Testing and Performance
    Type: SUI-61-3, VOL. I
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  • 12
    Publication Date: 2019-08-15
    Description: Methods based on oblique - and normal-shock relationships and the continuity of mass flow through suitably chosen volume elements between the shock and body were developed t o predict shock envelopes about two types of vehicles being considered for atmosphere entry. One type is a high-drag capsule shape. The other type is essentially a slender tri- angular wing capable of providing high lift or high drag, depending on the angle of attack. Predicted and measured shock envelopes were compared f o Mach number range of 3 to 15 for vehicles at high angles of attack; good agreement was found. Most of the available experimental data were in a speed and temperature range in which no important real-gas effects occurred.
    Keywords: Spacecraft Design, Testing and Performance
    Type: NASA-TN-D-860 , A-491
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  • 13
    Publication Date: 2019-08-15
    Description: Small pyrex glass spheres, representative of stoney meteoroids, were fired into 2024-T3 aluminum alclad multiple-sheet structures at velocities to 11,000 feet per second to evaluate the effectiveness of multisheet hull construction as a means of increasing the resistance of a spacecraft to meteoroid penetrations. The results of these tests indicate that increasing the number of sheets in a structure while keeping the total sheet thickness constant and increasing the spacing between sheets both tend to increase the penetration resistance of a structure of constant weight per unit area. In addition, filling the space between the sheets with a light filler material was found to substantially increase structure penetration resistance with a small increase in weight. An evaluation of the meteoroid hazard to space vehicles is presented in the form of an illustrative-example for two specific lunar mission vehicles, a single-sheet, monocoque hull vehicle and a glass-wool filled, double-sheet hull vehicle. The evaluation is presented in terms of the "best" and the "worst" conditions that might be expected as determined from astronomical and satellite measurements, high-speed impact data, and hypothesized meteoroid structures and compositions. It was observed that the vehicle flight time without penetration can be increased significantly by use of multiple-sheet rather than single-sheet hull construction with no increase in hull weight. Nevertheless, it is evident that a meteoroid hazard exists, even for the vehicle with the selected multiple-sheet hull.
    Keywords: Spacecraft Design, Testing and Performance
    Type: NASA-TN-D-1039 , A-463
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  • 14
    Publication Date: 2019-08-15
    Description: An analysis was made of the guidance of a space vehicle approaching the earth at supercircular velocity through an entrance corridor containing a desired perigee altitude. Random errors were assumed in the measurement of velocity and flight-path angle and in obtaining the desired thrust impulse. The method described in NASA Technical Note D-191 of scheduling corrections at different values of the angle between perigee and the vehicle's position vector and a slight modification of this method were investigated as a means of correcting perigee altitude when the vehicle's predicted position was at programmed correction points not within a specified deadband about the desired perigee altitude. The study showed that modifying the angular method of NASA Technical Note D-191 by adding another correction near the initial point did not improve the efficiency and accuracy of the angular method. It was found that in some cases the use of a correction procedure which included a deadband could be more costly in total corrective velocity than a procedure which neglected the deadband. This was especially true if a large degree of confidence was required in the total corrective velocity. It was apparent from the results that a correction with a deadband limit in the guidance scheme was more sensitive to the initial conditions, the corrective procedure, the deadband, and the degree of confidence required than a correction without a deadband limit.
    Keywords: Spacecraft Design, Testing and Performance
    Type: NASA-TN-D-957 , L-1661
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  • 15
    Publication Date: 2019-08-15
    Description: Euler's dynamic equations were linearized and solved analytically. Analytical expressions which relate angular motions to spin-rate and inertia distributions were obtained and found to be in good agreement with machine solutions of the nonlinear equations for the case of a rectangular-pulse pitching-moment disturbance. Consideration was given to the effects produced by having artificial damping in the system.
    Keywords: Spacecraft Design, Testing and Performance
    Type: NASA-TR-R-83
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  • 16
    Publication Date: 2019-07-12
    Description: On 10 June 1961, 33 tests of the aerodynamic response of the McDonnell model Mercury capsule were conducted. Variables included spin, different parachute tethers, and the addition of baffles.
    Keywords: Spacecraft Design, Testing and Performance
    Type: L-463
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  • 17
    Publication Date: 2019-07-12
    Description: Model tests have been made to determine the landing-impact characteristics of a parachute-supported reentry capsule that had a compliable metal structure as a load-alleviating device. A 1/6-scale dynamic model having compliable aluminum-alloy legs designed to give a low onset rate of acceleration on impact was tested at flight-path angles of 90 degrees (vertical) and 35 degrees, at a vertical velocity of 30 ft/sec (full scale), and at contact attitudes of 0 degrees and +/-30 degrees. Landings were made on concrete, sand, and water.
    Keywords: Spacecraft Design, Testing and Performance
    Type: L-606
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  • 18
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    In:  CASI
    Publication Date: 2019-08-15
    Description: A preliminary study is made of some problems associated with the sending of an instrumented probe close to the Sun for the purpose of gathering and telemetering back to Earth information concerning solar phenomena and circumsolar space. The problems considered are primarily those relating to heating and to launch requirements. A nonanalytic discussion of the communications problem of a solar-probe mission is presented to obtain order-of-magnitude estimates of the output and weight of an auxiliary power supply which might be required. From the study it is believed that approaches to the Sun as close as about 4 or 5 million miles do not present insuperable difficulties insofar as heating and communications are concerned. Guidance requirements, in general, do not appear to be stringent. However, in terms of current experience, velocity requirements may be large. It is found, for example, that to achieve perihelion distances between the orbit of Mercury and the visible disc of the Sun, total burnout velocities ranging between 50,000 and 100,000 feet per second are required.
    Keywords: Spacecraft Design, Testing and Performance
    Type: NASA-TN-D-783 , A-439
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  • 19
    Publication Date: 2019-08-15
    Description: Systems using inertia wheels are evaluated in this report to determine their suitability for precise attitude control of a satellite and to select superior system configurations. Various possible inertia wheel system configurations are first discussed in a general manner. Three of these systems which appear more promising than the others are analyzed in detail, using the Orbiting Astronomical Observatory as an example. The three systems differ from each other only by the method of damping, which is provided by either a rate gyro, an error-rate network, or a tachometer in series with a high-pass filter. An analytical investigation which consists of a generalized linear analysis, a nonlinear analysis using the switching-time method, and an analog computer study shows that all three systems are theoretically capable of producing adequate response and also of maintaining the required pointing accuracy for the Orbiting Astronomical Observatory of plus or minus 0.1 second of arc. Practical considerations and an experimental investigation show, however, that the system which uses an error-rate network to provide damping is superior to the other two systems. The system which uses a rate gyro is shown to be inferior because the threshold level causes a significant amount of limit-cycle operation, and the system which uses a tachometer with a filter is shown to be inferior because a device with the required dynamic range of operation does not appear to be available. The experimental laboratory apparatus used to investigate the dynamic performance of the systems is described, and experimental results are included to show that under laboratory conditions with relatively large extraneous disturbances, a dynamic tracking error of less than plus or minus 0.5 second of arc was obtained.
    Keywords: Spacecraft Design, Testing and Performance
    Type: NASA-TN-D-691 , A-418
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  • 20
    Publication Date: 2019-08-15
    Description: A re-entry space vehicle development program, such as Project Apollo, requires a knowledge of the variability of atmospheric density from the surface of the earth to re-entry altitude (120 km). This report summarizes the data on density given in the most recent literature on the subject. The range of atmospheric density with respect to the ARDC 1959 Model Atmosphere is determined and shown graphically. From the surface to 30 km altitude abundant information on density is available. From 30 to 90 km altitude the summarized reports of observations made at a limited number of stations have been used. Between 90 and 120 km altitude the density is somewhat speculative, there being but few measurements available. Therefore, the qualitative values for the variability of density above 30 km must be considered tentative. Variations of atmospheric density by latitude and seasons made it necessary to develop a family of curves rather than a single profile. Three curves are presented to show the range of density deviation versus altitudes with respect to the ARDC 1959 Model Atmosphere. Each curve is used for a specific latitude range and season.
    Keywords: Spacecraft Design, Testing and Performance
    Type: NASA-TN-D-612
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  • 21
    Publication Date: 2019-08-15
    Description: Two systems of formulas are presented for the determination of the long period perturbations caused by the Sun and the Moon in the motion of an artificial satellite. The first system can be used to determine the lunar effect for all satellites. The second method is more convenient for finding the lunar effect for close satellites and the solar effect for all satellites. Knowledge of these effects is essential for determining the stability of the satellite orbit. The basic equations of both systems are arranged in a form which permits the use of numerical integration. The two theories are more accurate and more adaptable to the use of electronic machines than the analytical developments obtained previously.
    Keywords: Spacecraft Design, Testing and Performance
    Type: NASA-TN-D-1041
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  • 22
    Publication Date: 2019-08-15
    Description: Experimental data were obtained from the Explorer VIII satellite on five parameters pertinent to the problem of the interaction of space vehicles with an ionized atmosphere. The five parameters are: photoemission current due to electrons emitted from the satellite surfaces as a result of solar radiation; electron and positive ion currents due to the diffusion of charged particles from the medium to the spacecraft; the vehicle potential relative to the medium, and the ambient electron temperature. Included in the experimental data is the aspect dependence of the photoemission and diffusion currents. On the basis of the observations, certain characteristics of the satellite's plasma sheath are postulated.
    Keywords: Spacecraft Design, Testing and Performance
    Type: NASA-TN-D-1064
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  • 23
    Publication Date: 2019-08-15
    Description: An investigation has been made of the use of on-off reaction jets for precision attitude control of a satellite. Since a symmetrical vehicle is assumed, only single-axis control needs to be considered. The responses to initial disturbances and also limit-cycle characteristics for several systems have been evaluated. Calculated results indicate that realistic values of settling time and fuel consumption for the example considered can be obtained. The performance of a given system depends on the characteristics of the error detector used. In cases where the detector output was saturated for a relatively low error input, the settling time deteriorated when a lead network was used to provide damping. This deterioration could be eliminated if a separate rate signal to produce vehicle rate limiting were available. As an alternate approach, two systems were investigated which used a timed sequence of torques and could operate with a detector output of very small linear range. Although the performance of these systems was poorer than that of the lead network system without detector saturation, the performance was better than that of the lead network system with low values of detector saturation. The effects on limit-cycle characteristics of hysteresis, lead network constants, dead zone, and thrust time delays were also investigated.
    Keywords: Spacecraft Design, Testing and Performance
    Type: NASA-TN-D-1040 , A-498
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  • 24
    Publication Date: 2019-08-15
    Description: A reevaluation of the Vanguard program objectives in January 1957 resulted in the production of the Vanguard I Satellite, a 6.44-inch-diameter, 3.25-pound sphere with six equally spaced solar cell clusters and six equally spaced antennas mounted on its surface. Experiment requirements necessitated the development of a mechanism to separate the satellite from the third-stage rocket. On the basis of the existing standard separation mechanism, a strap pull-pin girth-ring arrangement was developed. Both the satellite and the separation mechanism were fully tested prior to flight. Successful orbiting and flight operation proved the adequacy of the design.
    Keywords: Spacecraft Design, Testing and Performance
    Type: NASA-TN-D-495
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  • 25
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    In:  CASI
    Publication Date: 2019-08-15
    Description: The Cloud Cover Satellite flown in Vanguard vehicles SLV-3 and SLV-4 required a spin rate of 55 r.p.m. when entering orbit. Since the third-stage rocket was spin-stabilized in flight, and because other considerations required that the satellite remain attached long enough to acquire more than the desired 55 r.p.m., a satellite spin-reduction mechanism was developed. Although the mechanisms functioned properly in both flights, the desired spin rate was not achieved owing to uncontrollable flight effects. These effects make the prediction of satellite spin rates after a long pre-separation coasting period extremely difficult. To meet future requirements a control system is needed which can orient a payload according to a predetermined scheme and maintain that orientation for the desired period.
    Keywords: Spacecraft Design, Testing and Performance
    Type: NASA-TN-D-496
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  • 26
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    In:  CASI
    Publication Date: 2019-08-15
    Description: Early in the Vanguard program it became apparent that a thoroughly reliable means of separating the satellite packages from the third-stage rocket would be required. A completely self -contained standard mechanism was developed with redundant firing circuits for use on both test vehicles and satellite-launching vehicles. A change in the experimental objectives of the test-vehicle payload units necessitated modification of some of the standard separation mechanisms. A strap, pull-pin, girth-ring separation device was developed which employed the basic actuation of the standard mechanisms. Evidence of residual burning of the third stage made it necessary to delay separation longer than the time designed into the long-delay separation device. The standard separation mechanism was modified and integrated with the satellite command receiver system so that a ground command after third-stage burnout would cause separation. Flight performance of the various separation mechanisms proved their reliability; they performed without failure in all Vanguard launchings.
    Keywords: Spacecraft Design, Testing and Performance
    Type: NASA-TN-D-497
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  • 27
    Publication Date: 2019-08-15
    Description: This study includes a consideration of the design philosophy for an automatic terminal guidance system, a derivation of guidance equations required, and an outline of the general type of instrumentation necessary to provide the essential information. A control system for a sample vehicle is analyzed. A representative case, rendezvous with a satellite in circular orbit at 400 nautical miles, was examined. Terminal-stage nominal burning times of 200 and 400 seconds were used. For the 200-second case, initial errors in circumferential displacement of +/- 25,000 feet, in radial displacement of 7,000 to -9,000 feet, and in lateral displacement of +/- 20,000 feet were within the capabilities of the system. Velocity errors of 300 to -400 ft/sec in the circumferential direction, 180 to -200 ft/sec in the radial direction, and velocity offsets of at least 20 (+/- 800 ft/sec) in the lateral direction could also be handled. The 400-second case was capable of correcting larger errors, but limits were not determined. The dependence of required characteristic velocity on initial errors was determined and it was found that increases over the nominal terminal-stage characteristic velocity of the order of 15 percent covered most of the previously mentioned in-plane errors. The requirements were more severe for cases with lateral velocity offsets. A simplified set of guidance equations was tested and produced only slight variations in performance. Overall velocity requirements and mass ratios were determined for terminal-stage burning times of 100, 200, 300, and 400 seconds and for a range of transfer angles by using exact calculations for the terminal stage and an impulsive launching velocity. These results indicated that the shortest burning time consistent with the launch guidance errors expected gave the best mass ratio.
    Keywords: Spacecraft Design, Testing and Performance
    Type: NASA-TN-D-923 , L-1522
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  • 28
    Publication Date: 2019-08-15
    Description: An experimental investigation has been made to determine the magnetic deceleration of a closed-end cylinder rotating in a magnetic field by use of opposed ball and socket air bearing support. The theories of smythe and Hooper were compared with the experimental data for aluminum cylinders with fineness ratios of 9:1, 4:1, and 2:l and a wall thickness of 0.254 centimeter and one cylinder with a fineness ratio of 6:1 and a wall thickness of 0.508 centimeter. A method is outlined by which the magnetic damping coefficient for the spinning motion of a body of revolution may be determined experimentally. The theory of Smythe for a thin-walled cylinder predicts values greater than experimental results for fineness ratios of less than 6:l. Hooper's theory is in agreement with the experimental results through-out the range of fineness ratios tested. A utilization of the magnetic damping to prevent overspeeding of a flywheel used in a satellite orientation system is discussed.
    Keywords: Spacecraft Design, Testing and Performance
    Type: NASA-TN-D-749 , L-1307
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  • 29
    Publication Date: 2019-08-15
    Description: The Project Echo communications experiment employed large, steerable,transmitting and receiving antennas at the ground terminals. It was necessary that these highly directional antennas be continuously and accurately pointed at the passing satellite. This paper describes a new type of special purpose data converter for directing narrow-beam communication antennas on the basis of predicted information. The system is capable of converting digital input data into real-time analog voltage commands with a dynamic accuracy of +/- 0.05 degree, which meets the requirements of the present antennas.
    Keywords: Spacecraft Design, Testing and Performance
    Type: NASA-TN-D-1137 , Bell System Technical Journal; 40; 4
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  • 30
    Publication Date: 2019-08-15
    Description: An investigation has been made of point return of a vehicle with a lift-to-drag ratio of 1/2, returning from a lunar mission. It was found that the available longitudinal and lateral range allowed considerable tolerances in entry conditions for a point return. Longitudinal range capability for a vehicle that was allowed to skip to an altitude not exceeding 400 miles was about 3-1/2 times greater than the range capability of a vehicle that was restricted to remain in the atmosphere after entry. Longitudinal range is very sensitive to changes in both velocity and flight-path angle at the bottom of the first pull-out and at exit. An investigation showed that after a skip a vehicle could be placed in a circular orbit for a relatively modest weight penalty. A skip maneuver was found to have no effect on lateral range when the roll was initiated at a velocity near satellite speed after the vehicle had re-entered the atmosphere. However, when the roll was initiated at the earliest possible time along the undershoot boundary, lateral range was increased by a factor of about 2-1/2. The tolerable errors in time of arrival and in inclination of the orbital plane at point of entry were greater for the skip trajectory than for the no-skip trajectory.
    Keywords: Spacecraft Design, Testing and Performance
    Type: NASA-TN-D-1142 , A-553
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  • 31
    Publication Date: 2019-08-15
    Description: A study of the principal flight parameters at booster separation was conducted to find the effect of each on the weight of the payload boosted into an earth orbit along a zero drag gravity turn trajectory. The parameters considered include Mach number (3 to 9), flight-path angle (10 deg to 55 deg), altitude (90,000 and 350,000 ft), inert weight ratio (0.05 to 0.15), and thrust-weight ratio (1.5 to 2.5), with a specific impulse of 289 seconds. Both transfer ellipse and direct orbit trajectories were considered. With either trajectory method, payload weight was highest for low initial flight-path angles and high initial Mach numbers. Of course, high initial Mach numbers require greater energy expenditures from the booster. Changes in initial altitude had little effect on payload weight, and only small gains were evident when thrust-weight ratio was increased.
    Keywords: Spacecraft Design, Testing and Performance
    Type: NASA-TN-D-1069 , A-521
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  • 32
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    In:  CASI
    Publication Date: 2019-08-15
    Description: The Vanguard satellites and component parts were balanced within the specified limits by using a Gisholt Type-S balancer in combination with a portable International Research and Development vibration analyzer and filter, with low-frequency pickups. Equipment and procedures used for balancing are described; and the determination of residual imbalance is accomplished by two methods: calculation, and graphical interpretation. Between-the-bearings balancing is recommended for future balancing of payloads.
    Keywords: Spacecraft Design, Testing and Performance
    Type: NASA-TN-D-498 , D-498
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  • 33
    Publication Date: 2019-08-15
    Description: A study has been made of a method for controlling the trajectory of a high-drag low-lift entry vehicle to a desired longitude and latitude on the surface of a rotating earth. By use of this control technique the vehicle can be guided to the desired point when the present position and heading of the vehicle are known and the desired longitude and latitude are specified. The present study makes use of a single reference trajectory and an estimate of the lift and side-force capabilities of the vehicle. This information is stored in a control-logic system and used with linear control equations to guide the vehicle to the desired destination. Results are presented of a number of trajectory studies which describe the operation of the control system and illustrate its ability to control the vehicle trajectory to the desired landing area.
    Keywords: Spacecraft Design, Testing and Performance
    Type: NASA-TN-D-954 , L1660
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  • 34
    Publication Date: 2019-08-15
    Description: A study was conducted to determine the feasibility of a satellite attitude fine-control system using the interaction of the earth's magnetic field with current-carrying coils to produce torque. The approximate intensity of the earth's magnetic field was determined as a function of the satellite coordinates. Components of the magnetic field were found to vary essentially sinusoidally at approximately twice orbital frequency. Amplitude and distortion of the sinusoidal components were a function of satellite orbit. Two systems for two-axis attitude control evolved from this study, one using three coils and the other using two coils. The torques developed by the two systems differ only when the component of magnetic field along the tracking line is zero. For this case the two-coil system develops no torque whereas the three-coil system develops some effective torque which allows partial control. The equations which describe the three-coil system are complex in comparison to those of the two-coil system and require the measurement of all three components of the magnetic field as compared with only one for the two-coil case. Intermittent three-axis torquing can also be achieved. This torquing can be used for coarse attitude control, or for dumping the stored momentum of inertia reaction wheels. Such a system has the advantage of requiring no fuel aboard the satellite. For any of these magnetic torquing schemes the power required to produce the magnetic moment and the weight of the coil seem reasonable.
    Keywords: Spacecraft Design, Testing and Performance
    Type: NASA-TN-D-1068 , A-474
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  • 35
    Publication Date: 2019-08-16
    Description: Exploratory tests have been conducted with several conceptual radiative heat shields of composite construction. Measured transient temperature distributions were obtained for a graphite heat shield without insulation and with three types of insulating materials, and for a metal multipost heat shield, at surface temperatures of approximately 2,000 F and 1,450 F, respectively, by use of a radiant-heat facility. The graphite configurations suffered loss of surface material under repeated irradiation. Temperature distribution calculated for the metal heat shield by a numerical procedure was in good agreement with measured data. Environmental survival tests of the graphite heat shield without insulation, an insulated multipost heat shield, and a stainless-steel-tile heat shield were made at temperatures of 2,000 F and dynamic pressures of approximately 6,000 lb/sq ft, provided by an ethylene-heated jet operating at a Mach number of 2.0 and sea-level conditions. The graphite heat shield survived the simulated aerodynamic heating and pressure loading. A problem area exists in the design and materials for heat-resistant fasteners between the graphite shield and the base structure. The insulated multipost heat shield was found to be superior to the stainless-steel-tile heat shield in retarding heat flow. Over-lapped face-plate joints and surface smoothness of the insulated multi- post heat shield were not adversely affected by the test environment. The graphite heat shield without insulation survived tests made in the acoustic environment of a large air jet. This acoustic environment is random in frequency and has an overall noise level of 160 decibels.
    Keywords: Spacecraft Design, Testing and Performance
    Type: NASA-TN-D-897 , L-1524
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  • 36
    Publication Date: 2019-08-16
    Description: A general calculation is given for the earth's albedo input to a spherical satellite, with the assumption that the earth can be considered a diffusely reflecting sphere. The results are presented in general form so that appropriate values for the solar constant and albedo of the earth can be used as more accurate values become available. The results are also presented graphically; the incident power is determined on the assumption that the mean solar constant is 1.353 x 10( exp 6) erg/(sq cm.sec) and the albedo of the earth is 0.34.
    Keywords: Spacecraft Design, Testing and Performance
    Type: NASA-TN-D-1099
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  • 37
    Publication Date: 2019-08-16
    Description: Observations of the Echo I balloon satellite have been compared with a theory including the following perturbing effects: (1) solar radiation pressure; (2) lunar and solar gravitation; (3) second, third, and fourth harmonics of the earth's gravitational potential; and (4) atmospheric drag. With a set of orbital elements at the 26th day of the lifetime of the satellite, it was possible to match the observational data to 180 days with root mean square residuals as follows: Delta-a = 17.9 km, Delta-e = 0.0021, Delta-i = 0.0177 deg., Delta-omega = 1.1231 deg., Delta-Omega = 0.4821 deg., Delta-perigee height = 7.50 km. No differential correction has been applied as yet. Values of atmospheric density between 1500 and 930 km, assuming neutral drag effects only, have been inferred from the orbital data. The connection between solar activity and drag is also examined. As the Echo I perigee height continues to oscillate between 900 and 1500 km, more valuable orbital data will be obtained and atmospheric properties will be deduced. Further refinements in the mathematical model, especially in a time-dependent model atmosphere, should bring a substantial reduction in the residuals of the observations.
    Keywords: Spacecraft Design, Testing and Performance
    Type: NASA-TN-D-1124
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  • 38
    Publication Date: 2019-08-15
    Description: An experimental investigation was made of the landing characteristics of a 1/9-scale dynamic model of a lenticular-shaped reentry vehicle having extendible tail panels for control after reentry and for landing control (flare-out). The landing tests were made by catapulting a free model onto a hard-surface runway and onto water. A "belly-landing" technique in which the vehicle was caused to skid and rock on its curved undersurface (heat shield), converting sinking speed into angular energy, was investigated on a hard-surface runway. Landings were made in calm water and in waves both with and without auxiliary landing devices. Landing motions and acceleration data were obtained over a range of landing attitudes and initial sinking speeds during hard-surface landings and for several wave conditions during water landings. A few vertical landings (parachute letdown) were made in calm water. The hard-surface landing characteristics were good. Maximum landing accelerations on a hard surface were 5g and 18 radians per sq second over a range of landing conditions. Horizontal landings on water resulted in large violent rebounds and some diving in waves. Extreme attitude changes during rebound at initial impact made the attitude of subsequent impact random. Maximum accelerations for water landings were approximately 21g and 145 radians per sq second in waves 7 feet high. Various auxiliary water-landing devices produced no practical improvement in behavior. Reduction of horizontal speed and positive control of impact attitude did improve performance in calm water. During vertical landings in calm water maximum accelerations of 15g and 110 radians per sq second were measured for a contact attitude of -45 deg and a vertical velocity of 70 feet per second.
    Keywords: Spacecraft Design, Testing and Performance
    Type: NASA-TN-D-940 , L-1676
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  • 39
    Publication Date: 2019-08-27
    Description: This document is a compilation of papers presented at a Conference on the Medical Results of the First U.S. Manned Suborbital Space Flight. This conference was held by the NASA, in cooperation with the National Institutes of Health and the National Academy of Sciences, at the U.S. Department of State Auditorium on June 6, 1961. The papers were prepared by representatives of the NASA Space Task Group in collaboration with personnel from various Department of Defense medical installations, the University of Pennsylvania, and McDonnell Aircraft Corporation.
    Keywords: Spacecraft Design, Testing and Performance
    Type: NASA-TM-X-68523 , HQ-E-DAA-TN52321 , Conference on the Medical Results of the First U.S. Manned Suborbital Space Flight; Jun 06, 1961; Washington, DC; United States
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  • 40
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    Berichte der deutschen chemischen Gesellschaft 94 (1961), S. 58-61 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Das Mononatriumsalz der Glycin-N-methylensulfonsäure wurde dargestellt. An Hand von Titrationskurven wurde gezeigt, daß diese im pH-Bereich von 6 bis 8.5 bei 20° in wenigen Minuten in Glycin und Hydroxymethansulfonsäure zerfällt, bei pH 9-10 erfolgt wieder Sulfomethylierung.
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  • 41
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    Berichte der deutschen chemischen Gesellschaft 94 (1961), S. 96-102 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die cis-trans-isomeren 1-Isopropyl-cyclohexanole-(3) wurden erstmalig rein gewonnen. Der in der Literatur beschriebene Weg liefert ein 94% cis-Form enthaltendes Gemisch. Durch Reduktion von 1-Isopropyl-cyclohexanon-(3) entstehen nach den verschiedenen Verfahren, von denen LiAlH4 als am meisten stereospezifisches Reagenz 95% cis-Form liefert, die Isomeren in unterschiedlichen Mengenverhältnissen. Die Trennung der Isomeren erfolgte durch Destillation. In ihren Eigenschaften unterscheiden sie sich am auffälligsten durch die Dielektrizitätskonstanten; ihre Viskositäten sind ungewöhnlich hoch. Die Äthanolyse der p-Toluolsulfonate verläuft ein wenig rascher als die der cis-trans-isomeren 1-Methyl-cyclohexanol-(3)-Derivate; es bildet sich dabei aus der cis-Form weniger, aus der trans-Form mehr Kohlenwasserstoff als dort.
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  • 42
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    Berichte der deutschen chemischen Gesellschaft 94 (1961), S. 102-106 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: äthylenoxyd setzt sich mit Alkaliphosphiden des Typs MePR2 unter Bildung entsprechender β-Hydroxyäthyl-phosphine, HOCH2.CH2PR2, um. Sie liefern mit Ausnahme des β-Hydroxyäthyl-dicyclohexylphosphins die für tert. Phosphine charakteristischen Additionsreaktionen. Obwohl sich die β-Hydroxyäthylgruppe nicht benzoylieren läßt, kann sie nach Zerevttinow und infrarot-spektroskopisch nachgewiesen werden. Die Konstitution des β-Hydroxyäthyl-diphenylphosphins wird auf chemischem Wege ermittelt.
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  • 43
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    Berichte der deutschen chemischen Gesellschaft 94 (1961), S. 164-168 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Unter dem Einfluß einer UV-Bestrahlung können aus den Hexacarbonylen des Chroms, Molybdäns und Wolframs, welche in Piperidin oder in einem geeigneten Mischlösungsmittel mit diesem gelöst sind, die Verbindungen Cr(CO)5Pip, Cr(CO)4Pip2, Mo(CO)5Pip, Mo(CO)4Pip2, W(CO)5Pip und W(CO)4Pip2 erhalten werden. Analog gelingt es, Cr(CO)5N(C2H5)3 und W(CO)5N(C2H5)3 herzustellen. Triphenylamin konnte photochemisch nicht mit Chromhexacarbonyl zur Reaktion gebracht werden.
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  • 44
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    Berichte der deutschen chemischen Gesellschaft 94 (1961), S. 220-225 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Aktives Silicium erhält man als dunkelbraunes, pyrophores Pulver im Gemisch mit Calciumchlorid durch Einwirkung von 1 Mol. Cl2 auf eine Suspension von CaSi2 in CCl4 bei 20-40°. Durch Umsetzung mit einem weiteren Mol. Cl2 entsteht daraus bei 40-600 braunrotes bis ziegelrotes Siliciummonochlorid. Mit Wasser wie mit Methanol reagieren beide Stoffe unter Feuererscheinung. Es sind sog. Lepidoide, d. h. Feststoffe mit Lamellenstruktur, welche die größte innere Oberfläche besitzen, die möglich ist.
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    Berichte der deutschen chemischen Gesellschaft 94 (1961), S. 241-247 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Einwirkung von Fluorenyl-(9)-natrium (oder von Fluoren und Natriumäthylat) auf Flavon führt zum o-Hydroxy-ω-phenyl-ω-fluorenyliden-propiophenon (IV).
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  • 46
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    Berichte der deutschen chemischen Gesellschaft 94 (1961) 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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  • 47
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    Berichte der deutschen chemischen Gesellschaft 94 (1961), S. 320-322 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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  • 48
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    Berichte der deutschen chemischen Gesellschaft 94 (1961), S. 343-348 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Chinasäure und Shikimisäure lassen sich in schwach saurer wäßriger Lösung mit Sauerstoff bei Gegenwart eines Platinkatalysators oxydieren. Der dehydrierende Angriff erfolgt bei Chinasäure an der axialen Hydroxylgruppe unter Entstehung von 5-Dehydro-chinasäure. Shikimisäure ist in der vorliegenden Halbsesselform unter wesentlich milderen Bedingungen oxydierbar. Der dehydrierende Angriff erfolgt an der quasiaxialen Hydroxylgruppe unter Bildung von 5-Dehydro-shikimisäure.
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  • 49
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    Berichte der deutschen chemischen Gesellschaft 94 (1961), S. 368-373 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Bei der Übertragung der bekannten Reaktion von Carbonylverbindungen mit Acetylensalzen auf aromatische Thioketone wurden Substanzen erhalten, die ganz oder teilweise entschwefelt sind. Eine Anlagerung des Acetylids wurde nicht beobachtet.
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  • 50
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    Berichte der deutschen chemischen Gesellschaft 94 (1961), S. 398-406 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Bei UV-Bestrahlung einer Lösung der Hexacarbonyle M(CO)6 in Cyclohexan unter Luftausschluß entsteht primär eine angeregte Molekel {M(CO)6};ast;, welche sofort in {M(CO)5} und CO dissoziiert. In einer Dunkelreaktion rekombiniert {M(CO)5} mit CO quantitativ zu M(CO)6. Bestrahlt man unter Durchleiten von Stickstoff, so wird CO zum Teil ausgetrieben; nach Abbruch der Bestrahlung ist eine kleine, aber endliche Konzentration von instabilem {M(CO)5} vorhanden, welches sich langsam disproportioniert.  -  Bei Zusatz eines Donators D wird das intermediär gebildete {M(CO)5} unter Bildung der isolierbaren Verbindung M(CO)5D abgefangen.  -  Die Quantenausbeute ψ der photo-chemischen Reaktion, bezogen auf den totalen Quantenfluß der Strahlungsquelle zur Zeit t=0, ergab für Cr(CO)6, Mo(CO)6 und W(CO)6 den Wert ψ=0.39±0.03.  - Der Einfluß des Donators, der Konzentration von M(CO)6 und des Lösungsmittels auf die CO-Abspaltung werden diskutiert.
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  • 51
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    Berichte der deutschen chemischen Gesellschaft 94 (1961), S. 158-163 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Darstellung von D-Glucosiden, vor allem der α-Reihe, wurde an weiteren 1-Acyl-D-glucosen untersucht. Einige kinetische Messungen wurden bei dieser Reaktion durchgeführt.
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  • 52
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    Berichte der deutschen chemischen Gesellschaft 94 (1961), S. 151-157 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Alkyl-o-kresyl-thioäther wurden mit Paraformaldehyd und Zinkchlorid in die entsprechenden p-Chlormethyl-Derivate übergeführt. In diesen wurde das Chlor durch Umsetzung mit Piperidin bzw. Pyridin durch den Piperidino bzw. Pyridinorest, durch Umsetzung mit Kaliumhydrogensulfid durch den Mercaptorest ersetzt, während durch Sommelet-Reaktion 2-Methyl-4-alkylmercapto-benzaldehyde erhalten wurden.
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    Berichte der deutschen chemischen Gesellschaft 94 (1961), S. 216-220 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die 2.4-Dinitrophenylhydrazon-hydrochloride der β-Aminoaldehyde werden erhalten durch Reduktion von N-Methylaniliden, Indoliden und Carbazoliden der entsprechenden β-Aminosäuren mit Lithiumaluminiumhydrid.
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  • 54
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: D-Glucose, D-Galaktose, D-Mannose und 4.6-Benzal-α-D-glucose reagierten mit 2-Mercapto-äthylamin unter Bildung von Thiazolidin-Derivaten. Der Konstitutionsbeweis wurde durch Desulfurierung der Acetate mit Raney-Nickel erbracht, die zu den entsprechenden Hexitderivaten führte. Der Glucosederivat III entstehende I-[N-äthyl-acetamino]-2.3.4.5.6-penta-O-acetyl-1-desoxy-D-sorbit (IV) wurde auf einem unabhängigen Wege aus 1-äthylamino-1-desoxy-D-glucose erhalten.
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  • 55
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    Berichte der deutschen chemischen Gesellschaft 94 (1961), S. 263-265 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es werden die Umsetzungen von Pyridyl-(2)-acetonitril mit Benzal-acetophenon, 2-Pyridal-acetophenon, Benzal-aceton zu den entsprechenden δ-Ketonitrilen beschrieben.
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  • 56
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    Berichte der deutschen chemischen Gesellschaft 94 (1961), S. 174-185 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Durch Bromanlagerung geschützte Allylalkohole werden mit POCl3 phosphoryliert und nach Reduktion zu Allylphosphaten über Allylphosphorsäureamide in Allylpyrophosphate umgewandelt. Die dargestellten Pyrophosphate des γ.γ-Dimethyl-allylalkohols und Geraiols erwiesen sich auch in enzymatischen Versuchen als Zwischenprodukte der biologischen Terpensynthese.
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  • 57
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    Berichte der deutschen chemischen Gesellschaft 94 (1961), S. 229-233 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Höhermolekulare, konstitutions- und molekulareinheitliche Phenol-Formaldehyd-Kondensate (Mehrkernverbindungen im Molekulargewichtsbereich von 200 bis 760) mit mehreren Hydroxygruppen können mit 2.4-Dinitro-fluorbenzol mit guten Ausbeuten zu Dinitrophenyläthern umgesetzt werden. Mehrkernverbindungen, in denen p-Stellungen zu phenolischen Hydroxylen nicht substituiert sind, kuppeln mit Benzoldiazoniumchlorid, ohne daß Spaltungen von Methylenbrücken beobachtet wurden.
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  • 58
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    Berichte der deutschen chemischen Gesellschaft 94 (1961), S. 248-253 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Das farblose o-Hydroxy-ω-phenyl-ω-fluorenyliden-propiophenon (I) löst sich in Toluol/Piperidin mit rotvioletter Farbe. Diese Lösungen sind in der Wärme sehr schwach farbig und tief rotviolett in der Kälte. Die Ursachen der reversiblen Thermochromie werden besprochen und Analoge von I dargestellt. Die roten Lösungsfarben von I und von 2-Phenyl-indandion-(1.3) in Dimethylsulfoxyd werden diskutiert.
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    Berichte der deutschen chemischen Gesellschaft 94 (1961), S. 751-757 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Ausgehend vom Diacetyl-(+)-weinsäure-methylester-chlorid (IV) wurden Derivate des Diacetyl-l-threuronsäure-methylesters und der L-Threonsäure dargestellt. Der aus IV mit Diazomethan erhältliche L-threo-Di-O-acetyl-5-diazo-5-desoxy-4-pentulonsäure-(1)-methylester (VII) läßt sich in verschiedene Derivate der L-threo-4-Pentulonsäure verwandeln. Die durch UV-Licht katalysierte WOLFF-sche Umlagerung von VII führt zum L-threo-2.3-Diacetoxy-glutarsäure-dimethylester.
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    Berichte der deutschen chemischen Gesellschaft 94 (1961), S. 786-789 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: LiBH4 und NaBH4 reagieren mit Jod in organischen Lösungsmitteln unter Bildung von Borjodid, Alkalijodid, Jodwasserstoff und Wasserstoff; mit Jodwasserstoff erhält man Alkalijodid, Diboran und Wasserstoff. NaBH4 ist gegen Brom bis 80° resistent.
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    Berichte der deutschen chemischen Gesellschaft 94 (1961), S. 312-319 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Cr(CO)6 und Mo(CO)6 werden durch NaBH4 in flüssigem Ammoniak bei 60° im Einschlußrohr zu zweikernigen Carbonylmetallaten, Na2 [Cr2(CO)10] und Na2[o2(CO)10], reduziert. Die Reaktionsvorgänge und das Verhalten der beiden Verbindungen werden beschrieben.
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    Berichte der deutschen chemischen Gesellschaft 94 (1961), S. 118-124 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Darstellung verschiedener O- und N-Methylderivate des Leukopterins (I) wird beschrieben. Der Vergleich der UV-Absorptionsspektren deutet darauf hin, daß im Leukopterin sämtliche Hydroxygruppen in der Lactamkonfiguration vorliegen. Die Dissoziationssequenz der aciden H-Atome im 2-Amino-4.6.7-trioxo-hexahydropteridin kann Spektren im Sinne von N-8, N-3, N-5 abgeleitet werden.
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    Berichte der deutschen chemischen Gesellschaft 94 (1961), S. 132-142 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Diphenylweinsäure-dinitril (II) und Diphenylweinsäure-diamid (III) werden nach verbesserten Methoden gewonnen. Das Diamid III wird mit Eisessig unter innermolekularer Umlagerung und Spaltung der Kohlenstoffkette in das rote ungewöhnlich stabile 2-Benzoyl-5-phenyl-imidazolon-(4) (IV) übergeführt, dessen Strukturaufklärung beschrieben wird. Aus III lassen sich ferner eine Reihe 2.3.4-substituierter Derivate des 5-Oxo-pyrrolins darstellen.
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    Berichte der deutschen chemischen Gesellschaft 94 (1961), S. 169-173 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: o-Diacetyl-benzol wurde aus o-Phthalaldehyd über Bis-[α-hydroxy-äthyl]-benzol in etwa 50-proz. Ausbeute dargestellt.
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    Keywords: Chemistry ; Inorganic Chemistry
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    Topics: Chemistry and Pharmacology
    Notes: Das Verfahren zur Synthese von 3.4-Dihydro-isochinolin-Derivaten durch Ringschluß der aus β-Halogenalkyl-benzol und elektrophilen Metallhalogenid-Nitril-Komplexen erhaltenen Nitriliumsalze wird jetzt zur Darstellung des 3.4-Dihydro-papaverins und verwandter Verbindungen angewandt. Zu diesem Zweck werden verschiedenen alkoxysubstituierte β-Halogenalkyl-benzole eingesetzt. Die Ergebnisse stimmen mit der früheren Interpretation überein.
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    Berichte der deutschen chemischen Gesellschaft 94 (1961), S. 450-456 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Für die Thionylamine typisch sind IR-Banden bei 1150 und 1300/cm. Die Abhängigkeit der Lage und Intensität der ersten Bande von der Konstitution bei Thionylanilinen stimmt mit den Erwartungen überein, die aus der Struktur der NSO-Gruppe folgen.
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    Berichte der deutschen chemischen Gesellschaft 94 (1961), S. 509-514 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Hypoborsäure-tetrakis-dialkylamide, B2(NR2)4, entstehen bei der Reduktion von Bis-dialkylamino-borchloriden mit Natrium-Kalium-Legierung. Sie reagieren mit Alkoholen unter Bildung von Hypoborsäure-estern, B2(OR)4, die von Wasser zu Hypoborsäure hydrolysiert werden.
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    Berichte der deutschen chemischen Gesellschaft 94 (1961), S. 515-523 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Von 5 stereoisomeren Konduriten (A, B, C, E und F) ausgehend, werden über deren Epoxyde 7 stereoisomere Bromdesoxyinosite synthetisiert. Deren Druckhydrierung ergibt 5 stereoisomere Desoxyinosite, die als Pentaacetate identifiziert werden. 4 davon sind neue Stereoisomere, deren Konfigurationen aus dem Reaktionsverlauf diskutiert werden.
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    Berichte der deutschen chemischen Gesellschaft 94 (1961), S. 527-537 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Tosyl- bzw. Phthalyl-aminosäuren gehen mit überschüssigem asymm. Dichlordimethyläther in die entsprechenden Chloride, Carbobenzoxy-aminosäuren in die N-Carboxyanhydride über. Mit molaren Mengen Dichlormethyl-alkyl-äthern erhält man bei Gegenwart von HCl-bindenden Mitteln die gemischten Anhydride von Acylaminosäuren und Orthoameisensäureester (III). Die Reaktionen dieser Verbindungen sowie Umsetzungen einiger polyfunktioneller Aminosäurederivate mit asymm. Dichlordimethyläther werden beschrieben.
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    Berichte der deutschen chemischen Gesellschaft 94 (1961), S. 544-550 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Aus Ameisensäureestern erhält man bei Umsetzung mit Phosphorpentachlorid in guten Ausbeuten Dichlormethyl-alkyl-äther. - Die Reaktion von 2-Äthoxy-4.5-benzodioxolan, einem cyclischen Orthoameisensäureester, mit PCl5 wird beschrieben. - Kohlensäureesterdichloride (III) sind nur in der aromatischen Reihe existenzfähig. Ein allgemein anwendbares Darstellungsverfahren und einige Reaktionen dieser Verbindungsklasse werden beschrieben.
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    Berichte der deutschen chemischen Gesellschaft 94 (1961), S. 628-633 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Umsetzung von Methylestern mehrfach ungesättigter Fettsäuren mit überschüssigem Quecksilber(II)-acetat in Methanol führt zu vollständiger Methoxymercurierung der Doppelbindungen. Für Linolsäure-methylester werden die Geschwindigkeitskonstanten beider Anlagerungsstufen mitgeteilt. Die Trennung von Fettsäuremethylestern unterschiedlichen Sättigungsgrades gelingt ohne Isomerisierungen durch vollständige Bildung ihrer Quecksilberaddukte, Säulenchromatographie und Regenerierung der Ester.
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    Berichte der deutschen chemischen Gesellschaft 94 (1961), S. 322-328 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Tribenzylpyrophosphat (III, R = C6H5·CH2) ist ein Veresterungsreagenz und reagiert mit Alkoholen, Aminen und Säuren ausschließlich in der Weise, daß die Monoesterhälfte des Moleküls übertragen wird, es entstehen also Derivate des Mono-benzylphosphats.
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    Berichte der deutschen chemischen Gesellschaft 94 (1961), S. 337-343 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wurde das Assoziationsverhalten verschieden konstituierter α-und β-Mercaptoketone in Tetrachlorkohlenstoff als Lösungsmittel untersucht. Aus der Konzentrationsabhängigkeit der Integralabsorptionen der SH-Valenzbande bei 2560/ cm konnten nach der Methode von Spurr und Byers die Gleichgewichtskonstanten der Dimerenbildung ermittelt werden. Aus den Ergebnissen folgt, daß die primären Mercaptoketone am stärksten, die sekundären schwächer und die tertiären am schwächsten assoziiert sind, ferner, daß die Assoziationsneigung innerhalb homologer Reihen mit zunehmender Kettenlänge abnimmt. Der Unterschied im Assoziationsverhalten zwischen α- und β-Mercaptoketonen ist gering. Im Hinblick auf die Fähigkeit einiger Mercaptoketone, in cyclische Dithiane überzugehen, kann angenommen werden, daß den Zweierassoziaten eine Ringstruktur zugrunde liegt.
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    Berichte der deutschen chemischen Gesellschaft 94 (1961), S. 373-387 
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    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Anthrachinon-monoanil und 2.6-Dimethyl-benzochinon-monoanil-(4) werden mit verschiedenen Alkinkomponenten an der Carbonylgruppe mono-äthiniert. Die bei der katalytischen Hydrierung dieser Äthinierungsprodukte entstehenden Verbindungen werden untersucht. Mit Alkinolen setzt sich Anthrachinon-monoanil zu Diolen um, deren monovalente Reduktion unter gleichzeitiger Verseifung der Anilgruppe zu Kumulenen mit Anthronyliden-Rest führt.
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    Berichte der deutschen chemischen Gesellschaft 94 (1961), S. 412-414 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Konfiguration der beiden diastereomeren Racemate des Phenyl-piperidyl-(2)-carbinols wurde bewiesen und eine Methode zur Darstellung des threo-Racemats erythro-Racemat beschrieben.
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    Berichte der deutschen chemischen Gesellschaft 94 (1961), S. 431-437 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Das mit Essigester aus Fichtenbast gewonnene Glucosidgemisch wurde an einer Polyamidsäule in sieben Fraktionen aufgetrennt. Mit der Isolierung zweier isomerer Piceatannol-monoglucoside, zweier isomerer Dihydropicea-tannol-monoglucoside, eines Trihydroxytetralin-glucosides, eines Quercetinglucosides und des Piceatannols sind insgesamt etwa 80% der im Essigesterextrakt enthaltenen Polyphenole identifiziert worden.
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    Berichte der deutschen chemischen Gesellschaft 94 (1961), S. 438-441 
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    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Aus dem Essigesterextrakt des Fichtenbastes wurde nach säulenchromatographischer Auftrennung an Polyamid ein Glucosid erhalten, dessen Aglucon als ein 1.2.4-Trihydroxy-5.6.7.8-tetrahydro-naphthalin identifiziert werden konnte.
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    Berichte der deutschen chemischen Gesellschaft 94 (1961), S. 491-498 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wird die Synthese einer Reihe von acylierten und partiell acylierten 1-Mesitoyl-β-D-glucopyranosen (1-[2.4.6-Trimethyl-benzoyl]-β-D-glucopyranosen) beschrieben. — Die Umsetzung von einzelnen dieser Verbindungen in Methanol mit Methansulfonsäure wird hinsichtlich der Glucosidbildung untersucht.
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    Berichte der deutschen chemischen Gesellschaft 94 (1961), S. 825-831 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: 5.6-Dihydro-4H-pyrane und 4.5-Dihydro-furane setzen sich je nach Substitution mit N-Brom-succinimid (NBS) zu unterschiedlichen Reaktionsprodukten um. 3-Carbalkoxy-dihydropyrane und -furane werden in Allylstellung bromiert. 2-Carbalkoxy-dihydropyrane addieren aus Nebenreaktionen entstandenen Bromwasserstoff 3-Carboxy-dihydropyrane reagieren zu 3-Brom-5.6-dihydro-pyranen.
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    Berichte der deutschen chemischen Gesellschaft 94 (1961), S. 840-841 
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    Keywords: Chemistry ; Inorganic Chemistry
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    Topics: Chemistry and Pharmacology
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    Berichte der deutschen chemischen Gesellschaft 94 (1961), S. 847-850 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
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    Topics: Chemistry and Pharmacology
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    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Im Anschluß an frühere Untersuchungen über Organomangan- und -rheniumpentacarbonyle RM(CO)5 (M = Mn, Re; R = Alkyl, Aryl, Acyl) konnten weitere Manganverbindungen dieses Typs dargestellt werden. Auf Grund des Vergleichs der Dipolmomente sowie von IR-aktiven C—O-Valenzfrequenzen werden die Bindungsverhältnisse verschiedener Mangan- und Rheniumpenta-carbonyle diskutiert.
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    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Aus zahlreichen Vertretern der Familie der Umbelliferen werden neue, äußerst instabile Polyinketone isoliert. Die Struktur des Falcarinons (III), des Falcarin-dions (XI) und des Falcarinolons (XII) wird aufgeklärt. Das Falcarinon (III) kommt auch in Vertretern anderer Familien vor.
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    Berichte der deutschen chemischen Gesellschaft 94 (1961), S. 976-989 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die durch Bortrifluorid katalysierte Umlagerung von Alkyl-trichloracetimidaten (I, R = CCl3, R′ = Alkyl, R″ = H) zu N-substituierten Säureamiden verläuft über einen ionischen Mechanismus. Bei Trichloracetimidaten sekundärer oder tertiärer Alkohole wird teilweise oder vollständige Eliminierung beobachtet. Methylallyl-trichloracetimidate werden teilweise isomerisiert, das Isomeren-verhältnis erlaubt Rückschlüsse auf den Reaktionsmechanismus; in Gegenwart von Benzol entstehen Allylbenzole.
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    Berichte der deutschen chemischen Gesellschaft 94 (1961), S. 1015-1025 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Darstellung und Eigenschaften der im Titel genannten β-Alanine werden beschrieben. Für ein Zwischenprodukt wird die Struktur als Cyclobutenylcarbinol bewiesen.
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    Berichte der deutschen chemischen Gesellschaft 94 (1961), S. 1046-1050 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Li-Acetylid wird an Benztropon und substituierte Benztropone angelagert. Chemisches Verhalten und IR-Spektren der Reaktionsprodukte lassen eindeutig auf die 1-Äthinyl-benztropol-Struktur schließen. Die hergestellten Substanzen sind mit Ausnahme des 1-Äthinyl-2.7-diphenyl-benztropols-(1) äußerst kurzlebig und neigen zur Polymerisation.
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    Berichte der deutschen chemischen Gesellschaft 94 (1961), S. 766-780 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wird über Bildung und Umsetzungen von zwei Typen von Olefin-Palladium(II)-chlorid-Komplexen berichtet sowie über ihre Rolle bei den verschiedenen Reaktionsmöglichkeiten ungesättigter Verbindungen mit Palladium(II)-chlorid.
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    Berichte der deutschen chemischen Gesellschaft 94 (1961), S. 1151-1153 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die LiAlH4-Reduktion von Zeorinon zu epi-Zeorin sowie die Darstellung von Anhydrozeorinin und Acetyl-epi-zeorinin werden beschrieben.
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    Berichte der deutschen chemischen Gesellschaft 94 (1961), S. 1161-1172 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Stabile, intensiv blaue Lösungen entstehen unter Ausschluß von Sauerstoff a) in Kaliumthiocyanat-Schmelzen bei 250-450° durch thermische Dissoziation von KSCN, bei der Einwirkung von Schwefeldampf oder flüssigem Schwefel und beim Zerfall von K2S2, K2S4 und Na2S2O3, b) durch Zerfall von K2S2, K2S3 und K2S4 in Dimethylsulfoxid bei 20-100°. - In den genannten Fällen tritt in sehr geringer Konzentration ein weder Stickstoff noch Sauerstoff enthaltendes Molekül oder lon des Schwefels im Gleichgewicht auf, das durch ein steiles Extinktionsmaximum bei ΰ = 16.5.103/cm (ε 〉 16000) chrakterisiert wird; eine zweite Substanz ähnlicher Art mit einem Extinktionsmaximum bei ΰ = 24.103/cm wurde unterhalb von 250° als Zwischenprodukt nachgewiesen. Die gleichen Extinktionsmaxima entstehen auch beim Zerfall von S7NH in Dimethylsulfoxid. - Lösungen von Kaliumselenocyanat in KSCN-Schmelzen zeigen ein analoges Extinktionsmaximum bei ΰ = 12.5.103/cm.
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    Berichte der deutschen chemischen Gesellschaft 94 (1961), S. 3056-3059 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Darstellung und Charakterisierung von Methyläthyl-, Methyl-n-propyl-, Methyl-n-butyl-und Methylphenylphosphin sowie die entsprechenden Phosphinsäurechloride werden beschrieben.
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    Berichte der deutschen chemischen Gesellschaft 94 (1961), S. 3085-3094 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Bei der Dehydrierung von 4-Methyl-Δ1.3.5(10)-19-nor-cholestatrien (I) mit Chloranil in siedendem p-Xylol entsteht in einer Ausbeute von 38% 8.3′-Dimethyl-3′-isooctyl-Δ1′-1.2-cyclopentadieno-phenanthren (II), dessen Konstitution durch Selendehydrierung des Hydrierungsproduktes zum 8.3′-Dimethyl-1.2-cyclopenteno-phenanthren (IV) und durch Oxydation mit Ozon bzw. Osmiumtetroxyd bewiesen werden konnte. Kohlenwasserstoffe mit 1.2-Cyclopentadienophenanthren-Struktur, die auch bei der Chloranil-Dehydrierung von Cholesterin entstehen, stellen einen neuen, bisher unbekannten Dehydrierungstyp von Steroiden dar.
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    Berichte der deutschen chemischen Gesellschaft 94 (1961), S. 3094-3109 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Wanderung der 13-ständigen angularen Methylgruppe bei der Chloranil-Dehydrierung von Steroiden in die 3′-Stellung der entstehenden Δ1′-1.2-Cyclopentadieno-phenanthren-Verbindungen wird dadurch bewiesen, daß der Umlagerungsschritt vor der Dehydrierung durchgeführt wird: 17-Methyl-17-äthyl-Δ5.13-18-nor-androstadienol-(3β) (III) und Δ5-Pregnenol-(3β) (V) liefern identische (-)-3′-Methyl-3′-äthyl-Δ1′-1.2-cyclopentadieno-phenanthrene mit und ohne Methylgruppe in 5-Stellung (VII und VI), womit zugleich das Schicksal der 10-ständigen angularen Methylgruppe der Steroide geklärt ist: sie wandert entweder in die 5-Stellung der Dehydrierungsprodukte oder sie wird abgespalten.
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  • 93
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    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 94 (1961), S. 3128-3134 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Kinetik des homogenen Isotopenaustausches zwischen Cyclohexylchlorid und 36Cl-markiertem Lithiumchlorid wurde in wasserfreiem Dimethylsulfoxyd bei 110-140° untersucht.  -  Die Austauschreaktion verläuft bimolekular (SN2-Reaktion). Nach ARRHENIUS ergibt sich für die Temperaturabhängigkeit der Geschwindigkeitskonstanten k2 der Ausdruck \documentclass{article}\pagestyle{empty}\begin{document}$$ k_2 = 3.2 \cdot 10^{11} \cdot {\rm exp( - 27}{\rm .2} \cdot 10^3 /1.9867 \cdot T)[l/{\rm Mol} \cdot \sec $$\end{document} Der relativ große Wert für die Aktivierungsenergie (E = 27.2 ± 0.9 [kcal/Mol]) läßt sich auf die Ringstruktur des Cyclohexylchlorids zurückführen.
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  • 94
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    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 94 (1961), S. 3147-3150 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Bei der Umsetzung des Trimethylammonium-methylid-LiBr-Komplexes mit Benzoylchlorid in Tetrahydrofuran oder Tetrahydrofuran/Äther entsteht Trimethylphenacylammoniumsalz und dessen Enol-O-Benzoylverbindung.
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  • 95
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Synthese des DL-Desoxy-nupharidins wird beschrieben. Von den acht möglichen Racematen wurden 6 isoliert und chromatographisch getrennt. Durch die Bestimmung der Konfiguration der vier isomeren 1.7-Dimethyl-chinolizidine und der vier 1.7-Dimethyl-chinolizidone-(4) sowie durch die Untersuchung der Stereochemie der Hydrierung und Reduktion von Dehydrochinolizidinen gelingt eine eindeutige konfigurative Zuordnung der isomeren Desoxynupharidine.
    Additional Material: 4 Ill.
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  • 96
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    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 94 (1961), S. 3223-3226 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Oximierung von Ketonen in wasserfreiem, flüssigem Fluorwasserstoff wird als erstes Beispiel einer nucleophilen C—N-Kondensation in diesem Medium beschrieben.
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  • 97
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    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 94 (1961), S. 3251-3254 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Triäthylphosphit läßt sich ohne Katalysator durch Erhitzen auf 250° in Äthanphosphonsäure-diäthylester umlagern. Natriumdiäthylphosphit reagiert mit Dimethylsulfat ausschließlich zu Methanphosphonsäure-diäthylester. Die Reaktionen werden mit den analogen Umsetzungen der entsprechenden Schweflig-säurederivate verglichen. Es wird ein Verfahren zur qualitativen Trennung von phosphoriger Säure und Äthanphosphonsäre angegeben.
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  • 98
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    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 94 (1961), S. 3260-3275 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Während — wie bereits bekannt - Cyclononin und Cyclooctin isolierbare Kohlenwasserstoffe sind, ließen sich trotz vielfacher Bemühungen anderer Autoren die niederhomologen Cycloalkine nicht in substantia fassen. Eigene Versuche an Bishydrazonen der zugehörigen Cycloalkan-dione, die mit Quecksilberoxyd behandelt wurden, bestätigten das.  -  Daß diese Cycloalkine kurzlebig auftreten, konnte bei Wiederholung der Oxydationsreaktionen in Gegenwart von 2.5-Diphenyl-3.4-benzofuran sowie Phenylazid festgestellt werden. Die zu erwartenden Addukte wurden isoliert und in ihrer Struktur aufgeklärt. Die sinkenden Ausbeuten an Abfangprodukten legen den Schluß nahe, daß die Stabilitäten des Cycloheptins, Cyclohexins und Cyclopentins infolge der mit fallender Ringgröße wachsenden Spannung abnehmen.
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  • 99
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    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 94 (1961), S. 3287-3292 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Epoxyde können an reaktionsfähige Doppelbindungssysteme unter Bildung von Heterocyclen angelagert werden.  -  An Hand einer neu aufgefundenen Umlagerung wird versucht, den Mechanismus zu deuten.
    Additional Material: 2 Tab.
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  • 100
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    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 94 (1961), S. 3293-3297 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Synthese der genannten Anomeren erfolgte durch Benzylidierung und Glykosidierung des N-Formyl-D-glucosamins und alkalische Hydrolyse der N-Formyl-Gruppe.
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