ALBERT

Description: Using the fault plane mechanisms of the shallow earthquakes occurring along the Hellenic arc and the extent of the intermediate seismic belt, we make a quantitative estimate of the relative motion occurring between the Hellenic arc and the adjacent sea floor. This estimate is then used to evaluate the deformation in the Aegean area and to reconstruct the pattern of motion over the Eastern Mediterranean region for the last 13 m.y. It is shown that this pattern is compatible with the neotectonic and seismicity studies in Aegea. We then discuss the dynamics of the area and propose that, since Serravallian-Tortonian time, Aegea has been spreading gravitationally in front of the southwestward advancing Turkey. The reasons for this gravitational spreading are discussed.

Description: Data gathered by recent “Islas Orcadas” cruises reveal the seafloor spreading pattern for a region south of the Agulhas/Falkland fracture zone system. The presence of a magnetic anomaly bight about the Agulhas Plateau indicates that the Agulhas Plateau may have developed at the site of a tectonic plate triple junction during the Late Cretaceous. A westward jump in the seafloor spreading center during the Late Maestrichtian (anomaly 34−31) reduced the offset across the Falkland/Agulhas fracture zone system and resulted in the formation of two conjugate aseismic ridges here described as the Meteor and Islas Orcadas Rises. The magnetic lineation pattern in the Agulhas Basin suggests that a tectonic plate (Malvinas Plate) existed during Campanian to Maestrichtian times. Relative rates of motion are calculated for Antarctica, South America, and Africa for the Late Cretaceous.

Description: This chapter discusses the carbon turnover, calcification, and growth in coral reefs. Carbon turnover within a total reef community is a function of two distinct, biochemically interacting cycles. The first is the metabolic cycle consisting of the photosynthetic fixation of CO2 and the release of CO2 by respiration and decomposition processes. Superimposed on this are the direct incorporation of organic compounds (dissolved or particulate; living or non-living) originating outside the reef systems (in the adjacent ocean waters), and the loss of organic compounds from the reef system into the out-flowing water. The second is the inorganic carbonate cycle involving the biological and non-biological precipitation and dissolution of carbonates. Superimposed on this is the loss of particulate carbonates in suspension in the out-flowing water. The main chemical component of a coral-reef system is calcium carbonate, which occurs either as high-Mg calcite, aragonite, or low-Mg calcite. The mean calcification values in various environments at One Tree Reef are presented in the chapter. These data may be converted to an implied vertical growth rate potential assuming that accrual is dominantly aragonite (density = 2.89 g cm–3) and that there is 50% porosity after normal compaction.

Description: A tsunami earthquake is defined as a shock which generates extensive tsunamis but relatively weak seismic waves. A comparative study is made for the two recent tsunami earthquakes, and a subduction mechanism near a deep-sea trench is discussed. These two earthquakes occurred at extremely shallow depths far off the coasts of the Kurile Islands and of eastern Hokkaido on October 20, 1963, and on June 10, 1975, respectively. Both can be regarded as an aftershock of the preceding larger events. Their tsunami heights and seismic wave amplitudes are compared with those of the preceding events. The results show that the time constants involved in the tsunami earthquakes are relatively long but not long enough to explain the observed disproportionality between the tsunamis and the seismic waves. The process times are estimated to be less than 100 s. The spatio-temporal characteristics of the two events suggest that they represent a seaward and upward extension of the rupture associated with a great earthquake which did not break the free surface at the coseismic stage. The amplitude and phase spectra of long-period surface waves and the long-period P waveforms indicate that this extension of the rupture did not take place entirely along the lithospheric interface emerging as a trench axis. It rather branched upward from the interface in a complex way through the wedge portion at the leading edge of the continental lithosphere. This wedge portion consists in large part of thick deformable sediments. A large vertical deformation and hence extensive tsunamis result from such a branching process. A shallowest source depth, steepening of rupture surfaces, and a deformable nature of the source region all enhance generation of tsunamis. The wedge portion ruptured by a tsunami earthquake is usually characterized by a very low seismic activity which is presumably due to ductility of the sediments. We suggest that this portion fractures in a brittle way to generate a tsunami earthquake when it is loaded suddenly by the occurrence of a great earthquake and that otherwise it yields slowly. Upward branching of the rupture from the lithospheric interface produces permanent deformation of the free surface which is relative uplift landward and relative subsidence trenchward of the zone of surface break. This surface break zone geomorphologically corresponds to the lower continental slope between the deep-sea terrace and the trench. Such a mode of permanent deformation seems to be consistent with a rising feature of the outer ridge of the deep-sea terrace and a depressional feature of the trench. This consistency implies a causal relationship between great earthquake activities and geomorphological features near the trench.

Description: A tsunami earthquake is defined as a shock which generates extensive tsunamis but relatively weak seismic waves. A comparative study is made for the two recent tsunami earthquakes, and a subduction mechanism near a deep-sea trench is discussed. These two earthquakes occurred at extremely shallow depths far off the coasts of the Kurile Islands and of eastern Hokkaido on October 20, 1963, and on June 10, 1975, respectively. Both can be regarded as an aftershock of the preceding larger events. Their tsunami heights and seismic wave amplitudes are compared with those of the preceding events. The results show that the time constants involved in the tsunami earthquakes are relatively long but not long enough to explain the observed disproportionality between the tsunamis and the seismic waves. The process times are estimated to be less than 100 s. The spatio-temporal characteristics of the two events suggest that they represent a seaward and upward extension of the rupture associated with a great earthquake which did not break the free surface at the coseismic stage. The amplitude and phase spectra of long-period surface waves and the long-period P waveforms indicate that this extension of the rupture did not take place entirely along the lithospheric interface emerging as a trench axis. It rather branched upward from the interface in a complex way through the wedge portion at the leading edge of the continental lithosphere. This wedge portion consists in large part of thick deformable sediments. A large vertical deformation and hence extensive tsunamis result from such a branching process. A shallowest source depth, steepening of rupture surfaces, and a deformable nature of the source region all enhance generation of tsunamis. The wedge portion ruptured by a tsunami earthquake is usually characterized by a very low seismic activity which is presumably due to ductility of the sediments. We suggest that this portion fractures in a brittle way to generate a tsunami earthquake when it is loaded suddenly by the occurrence of a great earthquake and that otherwise it yields slowly. Upward branching of the rupture from the lithospheric interface produces permanent deformation of the free surface which is relative uplift landward and relative subsidence trenchward of the zone of surface break. This surface break zone geomorphologically corresponds to the lower continental slope between the deep-sea terrace and the trench. Such a mode of permanent deformation seems to be consistent with a rising feature of the outer ridge of the deep-sea terrace and a depressional feature of the trench. This consistency implies a causal relationship between great earthquake activities and geomorphological features near the trench.

Description: Microbial decomposition of organic matter in recent sediments of the Landsort Deep—an anoxic basin of the central Baltic Sea—resulted in the formation of a characteristic assemblage of authigenic mineral precipitates of carbonates, sulfides. phosphates and amorphous silica, The dominant crystalline phases are a mixed Mn-carbonate [(Mn0.85Ca0.10Mg0.05)CO3]. Mn-sulfide [MnS] and Fecarbonate [FeCO3]. Amorphous Fe-sulfide [FeS]. Mn-phosphate [Mn3(PO4)2] and a mixed Fe-Ca-phosphate [(Fe0.86Ca0.14)3(PO4)2] were identified by their chemical compositions only. The variability in composition of these solid phases and their mode of occurrence as a co-existing assemblage constrains the conditions and solution composition from which they precipitated. Estimates of activities for dissolved Fe. Mn. PO4, CO3 and S in equilibrium with such an assemblage are close to those found in recent anoxic interstitial water-sediment systems. It is important to have detailed knowledge of the composition and stability conditions of these solid precipitates in order to refine stoichiometric models of interstitial nutrient regeneration in anoxic sediments.

Description: Goban Spur lies on the continental margin of northwest Europe, southwest of Ireland. It is a marginal plateau underlain by Hercynian granites and Palaeozoic sediments, which form large horsts, grabens and tilted fault blocks with a trend that is approximately parallel to the main Celtic/Armorican Shelf edge. The spur is thought to be a westward continuation of the buoyant Cornubian Ridge, and is bounded to the north and south by large fault lines which probably represent reactivation of Hercynian structural trends. The continental basement is further divided longitudinally into a low-lying outer zone (Intermediate Zone) and a high inner region (Goban Spur proper). The ocean/continent boundary is thought to lie at the outer edge of the Intermediate Zone, Sea-floor spreading anomalies immediately west of the Intermediate Zone suggest that the adjacent ocean crust was created prior to anomaly 33 (say at ca. 90 m.y. B.P.). The sedimentary sequence on Goban Spur can be subdivided into four layers which can be tentatively correlated with the stratigraphic succession on the Meriadzek Terrace (IPOD sites). Such a correlation suggests that the lowermost sediment layer (?Jurassic-Albian) represents a tectono-sedimentary rift infill, and that Layers 2–4 (Upper Cretaceous to Quaternary) were deposited during slow epeirogenic downwarping of the plateau and that the sedimentary processes involved both draping and strong current moulding. The relatively buoyant nature of Inner Goban Spur has inhibited the accumulation of a thick post-rifting sedimentary sequence (700–1000 m), and has shielded the Intermediate Zone from downslope mass movements of material. This has resulted in the accumulation of an anomalously thin post-rift stage outer margin sediment prism (ca. 1000 m) compared to most continent rises (up to 10 km).

Description: A bathymetric map of the deep-sea floor off southeastern Africa shows the Agulhas Plateau to be separated from the continental margin of southeastern Africa by a narrow (50 km) elongate depression, the Agulhas Passage, which acts as a deep-water connection between the Agulhas and Transkei basins. Three regionally developed sediment layers occur in the deep (〉 4500 m) Transkei Basin/Agulhas Passage area. With the aid of a simple ocean crust sinking/carbonate compensation level (CCL) model these layers are related to the sedimentation history of the area. The model suggests that acoustic basement (Horizon X) represents Lower Cretaceous limestones draped over oceanic basement, and that this is overlain by an acoustically transparent sequence of pelagic/terrigenous material (Horizon A) that was deposited during a lengthy period (95 m.y.) beneath the carbonate compensation level. Post-Late Miocene sedimentation (Horizons B and C) has probably taken place above the CCL. Local sedimentation has always been influenced by strong sea-floor currents, but since middle Palaeogene times these currents have operated on a regional scale and have generated numerous large ridge and billow-like bed forms.

Description: One hundred and five new heat flow measurements in the Gulf of California support the premise that conductive heat loss is not the only mode by which heat is lost from a sea floor spreading center, even in an area with thick sediment cover. Theoretical estimates suggest that the average heat flow in the Guaymas and Farallon basins should be at least 11 μcal/cm2 s (HFU) (325 mW/m2). Outside a 30-km-wide zone centered on the central troughs, the heat flow values measured are reasonably uniform but average only 4.3±0.2 HFU (180±10 mW/m2). Although the high sedimentation rate may depress the measured heat flow, the effect probably does not exceed 15%. Some heat, particularly in the smaller basins, may be lost to the adjacent cooler continental blocks. The discrepancy between the measured and predicted heat losses, which is at least 30%, may be due to the discharge of thermal waters, through the thinner sediment cover in the central troughs or along active faults.

Description: The structural evolution of the northwestern Iberian margin has been reconstructed from the results of IPOD drill site 398, as well as from numerous dredgings and a dense network of seismic profiles. During the Mesozoíc the margin first underwent two consecutive extensional phases interpreted as the result of two episodes of rifting in the Atlantic. Then during Eocene, subsidence was interrupted by compression and related deformation caused by subduction of oceanic sea floor of the Bay of Biscay beneath the Iberian Peninsula. Present day marginal banks are interpreted as blocks of the older passive margin uplifted during early Tertiary as a result of that subduction. Fault escarpments provide opportunities to sample older sediments and basement by dredging.

Description: The olivine melilitite diatemes of the Swabian Alb, frequently compared with kimberlite diatremes, are discussed in terms of hydrogeological setting, internal structure and juvenile fraction. The hydrogeological conditions of the Swabian Alb at the time of diatreme emplacement were characterized by copious amounts of groundwater within the sedimentary cover of the basement. Subsequently to the eruptions groundwater accumulated within the maars of the larger diatremes forming fresh‐water lakes as also happened nearby in the Steinheim and Ries impact craters. The diatremes reveal subsidence structures composed of large wall‐rock blocks, subaerially deposited pyroclastic beds, and well‐bedded reworked pyroclastic debris which accumulated on the floor of the fresh‐water crater lakes. The latter fact implies availability of groundwater at the time the diatremes formed. The juvenile fraction is developed in the shape of spherical to ovoid nucleated autoliths of ash to lapilli size that are macroscopically nearly devoid of vesicles. The autoliths are interpreted as the product of water vapor explosions which took place when rising olivine melilitite magma contacted groundwater and was fragmented into magma droplets. The droplets were rapidly chilled and thus preserved their shape. Because of the hydrogeological data, the diatreme structure, and the chilled nature of the autoliths a phreatomagmatic origin of the Swabian diatremes is suggested.

Description: The olivine melilitite diatemes of the Swabian Alb, frequently compared with kimberlite diatremes, are discussed in terms of hydrogeological setting, internal structure and juvenile fraction. The hydrogeological conditions of the Swabian Alb at the time of diatreme emplacement were characterized by copious amounts of groundwater within the sedimentary cover of the basement. Subsequently to the eruptions groundwater accumulated within the maars of the larger diatremes forming fresh‐water lakes as also happened nearby in the Steinheim and Ries impact craters. The diatremes reveal subsidence structures composed of large wall‐rock blocks, subaerially deposited pyroclastic beds, and well‐bedded reworked pyroclastic debris which accumulated on the floor of the fresh‐water crater lakes. The latter fact implies availability of groundwater at the time the diatremes formed. The juvenile fraction is developed in the shape of spherical to ovoid nucleated autoliths of ash to lapilli size that are macroscopically nearly devoid of vesicles. The autoliths are interpreted as the product of water vapor explosions which took place when rising olivine melilitite magma contacted groundwater and was fragmented into magma droplets. The droplets were rapidly chilled and thus preserved their shape. Because of the hydrogeological data, the diatreme structure, and the chilled nature of the autoliths a phreatomagmatic origin of the Swabian diatremes is suggested.

Description: An estimate of average river particulate matter (RPM) composition was bàsed on analyses of more than 40 elements in the Amazon, Congo, Ganges, Magdalena, Mekong, Parana and Orinoco rivers, to which were added literature data for 13 other major world rivers, covering the whole spectrum of morphoclimatic features. Geographic variations of major elements in RPM are mostly linked to weathering types and to the balance between weathering rate and river transport. As a result of chemical erosion, Al, Fe and Ti are enriched in RPM with respect to the average parent rock, while Na, Ca, Mg and Sr are strongly depleted. These figures are directly related to the relative importance of dissolved and particulate transport in rivers; this has been computed for each of 40 elements. In order to study weathering on a global scale, the total observed elemental fluxes (dissolved + particulate) have been computed and compared to theoretical ones. The latter were derived from the elemental content in the average parent rock and the total quantity of weathered material, computed from the Al ratio in RPM and in parent rock. Observed and theoretical fluxes are balanced for the less mobilized elements (rare earths, Co, Cr, Cs, Fe, Mn, Rb, Si, Th, Ti, U and V) for which no enrichment relative to Al is noted in RPM, and for B, Ba, Ca, K, Mg, Na, Sr which are relatively depleted in RPM due to their high dissolved transport. Additional fluxes have been found for Br, Sb, Pb, Cu, Mo, Zn and are possible also for Ni and P. This is reflected by marked enrichments in RPM relative to Al for the poorly or moderately dissolved transports (Pb, Cu, Zn). Several hypotheses involving either the natural origin (volcanic dust, marine aerosols, geochemical fractionation) or the artificial origin (worldwide pollution) are discussed to explain these discrepancies, assuming river transport and weathering either to be in a steady state on a global scale or not. However, none of them can fully account for these additional fluxes. It is most likely that these excesses have multiple origins, anthropogenic or natural or both. The comparison between RPM and deep-sea clay compositions emphasizes the prime influence of river input on oceanic sedimentation of Si, Al, Fe, Ti, lanthanides, Sc, Rb, V, etc. A few elements such as Zn, Sb, occur in excess in RPM as compared to deep-sea clays; in order to balance this excess, a remobilization of these elements out of the sediment can be considered. Finally, the enrichment of Co, Cu, Mn and Ni in deep-sea clays compared to RPM is discussed and attributed to several sources and processes.

Description: We present a plate kinematic evolution of the South Atlantic which is based largely on the determination of the equatorial fracture zone trends between the African and South American continental margins. Four main opening phases are dated by oceanic magnetic anomalies, notably MO, A34, and A13, and are correlated with volcanism and tectonic events on land around the South Atlantic Ocean. The Ceara and Sierra Leone rises are probably of oceanic origin and were created 80 m.y. ago or later in their present-day positions with respect to South America and Africa.

Description: This paper concerns the linear response of the ocean to forcing at a specified frequency and wave number in the absence of mean currents. It discusses the details of the forcing function, the general properties of the equations of motion, and possible simplifications of these equations. Two representations for the oceanic response to forcing are described in detail. One solution is in terms of the normal modes of the ocean. The vertical structure of these modes corresponds to that of the barotropic and baroclinic modes; their latitudinal structure corresponds to that of inertia‐gravity and Rossby waves. These waves are eigenfunctions of Laplace's tidal equations (LTE) with the frequency as eigenvalue. The description in terms of vertically standing modes is particularly useful if the forcing is nonlocal, because only these modes can propagate into undisturbed regions. The principal result is that it is extremely difficult for baroclinic (but not barotropic) disturbances to propagate horizontally away from a forced region. Instabilities of the Gulf Stream excite disturbances that are confined to the immediate neighborhood of the current; disturbances due to instabilities of equatorial currents do not propagate far latitudinally. A second representation of the oceanic response to forcing is in terms of vertically propagating, or vertically trapped, latitudinal modes. These modes are eigenfunctions of LTE with the equivalent depth h (not the frequency) as eigenvalue. Both positive and negative eigenvalues h are necessary for completeness. The modes with h 〉 0 consist of an infinite set of inertia‐gravity waves and a finite set of Rossby waves which either propagate vertically or form vertically standing modes. The latitudinally gravest modes are equatorially trapped and have been observed in the Atlantic and Pacific oceans. The modes with h 〈 0 are necessary to describe the oceanic response to nonresonant forcing. In the vertical this response attenuates with increasing distance from the forcing region. Because of the shallowness of the ocean the large eastward traveling atmospheric cyclones in mid‐latitudes and high latitudes force a response down to the ocean floor. Interaction with the bottom topography will result in smaller‐scale disturbances and will affect the frequency spectrum of the response when bottom‐trapped waves are excited.

Description: Thick sediments (maximum of at least 4900 m) infill the Natal Valley, which lies between the coast of South Africa/Mozambique and the Mozambique Ridge. Eight physiographic provinces are recognised in the valley, and their boundaries can be related to well-defined sediment thickness or facies discontinuities within the basin infill. The acoustic stratigraphy of the area is established by reference to two regionally developed reflecting horizons, which, on the basis of previously published borehole and seismic data, are tentatively identified as mid-Cretaceous (McDuff) and mid-Cainozoic (Angus) hiatuses or important facies boundaries. Sedimentation began in the Natal Valley before mid-Cretaceous times and since then sediment dispersion has been strongly influenced by the disposition of large basement (? volcanic) highs: the approximately NE—SW Almirante Leite and Naudé ridges, and the larger N—S Mozambique Ridge. There is abundant evidence that sedimentation in the vicinity of these ridges has been current-controlled since at least mid-Cainozoic (Angus) times. The two main terrigenous sediment input points have been the Tugela and Limpopo rivers, which have large sediment cones adjacent to their mouths.

Description: An intensive three-dimensional survey of the Antarctic Polar Front was made in the Drake Passage in March 1976. The front, which was imbedded within one of the high-velocity cores of the circumpolar current, is viewed as a water mass boundary demarking the northern extent of near-surface antarctic waters. Within the front, water masses are observed to intrude, one above the other, with characteristic vertical scales of 50–100 m. The intrusions are horizontally anisotropic, being elongated in the alongstream direction and constrained primarily to the upper 800 m of the front. The spatial and temporal persistence of the variability is examined through the analysis of continuous vertical profiles of horizontal velocity, temperature, salinity, and oxygen with discrete sampling of nutrients. Analysis of the velocity data showed the mean current flowing to the NNE with speeds of the order of 30–40 cm s−1 in the upper 600 m, with temporal variability over a 28-hour ‘yo-yo’ due primarily to internal gravity waves. The thermohaline variability was not internal wave induced but rather was associated with nearly isentropic advection of different water masses across the front. Cold fresh and warm salty intrusions did not conserve potential density, however, and double-diffusive transfers are strongly suggested as being crucial to an understanding of the dynamics of the intrusions. Applying a model (Joyce, 1977) for lateral mixing we estimate poleward temperature and salinity fluxes due to interleaving of 0.086°C cm s−1 and 0.069‰ cm s−1, respectively. If these values are typical, interleaving could play a significant role in large-scale balance of salt and, to a lesser extent, heat for the Southern Ocean.

Description: Five separate exposures of oceanic basalts were dredged in the vicinity of the Peru-Chile Trench between 9° and 27°S latitude. Each dredge is dominated by abundant pillow basalts. Approximately ten of the most unaltered, glassy and fine-grained samples were selected for detailed chemical and petrographic analyses from each dredge area. All basalts recovered in the Peru-Chile Trench are olivine and quartz-normative tholeiites that are believed to have formed at the now extinct Galapagos Rise 30–50 m.y. ago. Detailed chemical analyses of the basalts, including major and selected trace and rare earth elements, indicate that considerable compositional variability exists both within each of the dredged areas as well as between areas. Most of the inherent chemical variability observed within particular basement sections appears consistent with the concept of temporal evolution of magma bodies at a former spreading center by shallow-level fractional crystallization involving primarily plagioclase and olivine. In contrast, important chemical differences between the dredged areas suggest compositional heterogeneities in the mantle source regions. Our results indicate that although shallow-level fractionation has brought about large changes in composition of basalts in each area, compositional trends are distinct and appear to reflect original mantle-derived compositional differences.

Description: Thirty-four ash layers of Pleistocene and Pliocene age from DSDP Site 192, northwestern Pacific Ocean, have been subjected to detailed chemical and optical study to evaluate: (1) the chemical and optical variability in glass shards from deep-sea ash layers, and (2) secondary changes brought about by prolonged exposure to seawater. Glass shards from approximately half of the ash layers studied were found to have uniform compositions which approach the precision of the microprobe chemical analyses, whereas the remainder are compositionally diverse (e.g., SiO2, variations of 5–15% among shards from the same ash layer) and appear to be the eruptive products of compositionally zoned magma chambers. Optical studies of glass shards confirm the absence of devitrification or the formation of pervasive secondary alteration products. By contrast, chemical studies suggest that the glass shards have experienced progressive hydration with possible minor ion exchange of K, Mg, Ca and Si. The hydration occurs rapidly and leads to a rather uniform water content of 4.5–5% after several hundred thousands of years exposure to seawater. Step-wise heating dehydration experiments, optical effects, and published'oxygen isotope studies indicate that the water of hydration is incorporated uniformly within the glass. Systematic chemical differences between electron microprobe analyses of glass shard interiors and corresponding bulk chemical study by atomic absorption lead us to postulate that glass shard margins have undergone a minor chemical exchange with major cations in seawater. They have gained 0.10–0.20 wt. % K20, MgO, and CaO while losing a corresponding amount of Si2O. Although the glass shards from DSDP Site 192 are hydrated and may have experienced subtle, surficial ion exchange, we stress that they are the most chemically representative samples available of magmas that were explosively erupted from volcanic arcs.

Description: The usually high concentrations of Zn, Pb, Cd, and Cu in the most recently accreted portions of ferromanganese nodules from the western Baltic Sea are thought to reflect increased metal input due to anthropogenic mobilization. If so, the point of increase represents a time horizon within the structure of the nodule. Similar trace metal distributions of radiometrically dated sediments from the same area suggest that the ferromanganese nodules have grown in thickness between 0.02 and 0.16 mm yr−1. From this growth rate anthropogenic Zn flux to the nodule surface was calculated to be 80 mg m−2 yr−1.

Description: Petrographic examination of amygdules and veins associated with moderately altered pillow basalts dredged from the Peru Trench has revealed that a consistent pattern of mineral crystallization has occurred. This sequence is: (1) green, weakly pleochroic clay (R.I. 〉 1.56); (2) dark yellowish brown, non-pleochroic clay (R.I. 〉 1.56); (3) light yellowish brown to colorless, fibrous, weakly pleochroic clay (R.I. 〈 1.56); and (4) calcite or celadonite. Chemical and X-ray diffraction analyses suggest that all clay mineral amygdule and vein fillings are dominated by intimate mixtures of an Fe-rich saponite and nontronite with very small admixtures of serpentine and illite. It is argued that sequential mineral fillings of fractures and vesicles may provide significant information about the chemistry of circulating interstitial fluids. For the pillow basalts studied the first-formed clays were enriched in nontronite, thereby suggesting Fe-rich fluids. These in turn were followed by saponite-rich clays and calcite. The change from Fe-and Mg-rich fluids to dominantly Ca-rich fluids is thought to correspond to a change from mafic mineral alteration to plagioclase alteration in the pillow basalts. An increase in the Fe3+/Fe2+ ratio of clays toward the centers of vesicles may indicate a change toward a more oxidizing environment of alteration.

Description: Deep‐sea drilling in the Antarctic region (Deep‐Sea Drilling Project legs 28, 29, 35, and 36) has provided many new data about the development of circum‐Antarctic circulation and the closely related glacial evolution of Antarctica. The Antarctic continent has been in a high‐latitude position since the middle to late Mesozoic. Glaciation commenced much later, in the middle Tertiary, demonstrating that near‐polar position is not sufficient for glacial development. Instead, continental glaciation developed as the present‐day Southern Ocean circulation system became established when obstructing land masses moved aside. During the Paleocene (t = ∼65 to 55 m.y. ago), Australia and Antarctica were joined. In the early Eocene (t = ∼55 m.y. ago), Australia began to drift northward from Antarctica, forming an ocean, although circum‐Antarctic flow was blocked by the continental South Tasman Rise and Tasmania. During the Eocene (t = 55 to 38 m.y. ago) the Southern Ocean was relatively warm and the continent largely nonglaciated. Cool temperate vegetation existed in some regions. By the late Eocene (t = ∼39 m.y. ago) a shallow water connection had developed between the southern Indian and Pacific oceans over the South Tasman Rise. The first major climatic‐glacial threshold was crossed 38 m.y. ago near the Eocene‐Oligocene boundary, when substantial Antarctic sea ice began to form. This resulted in a rapid temperature drop in bottom waters of about 5°C and a major crisis in deep‐sea faunas. Thermohaline oceanic circulation was initiated at this time much like that of the present day. The resulting change in climatic regime increased bottom water activity over wide areas of the deep ocean basins, creating much sediment erosion, especially in western parts of oceans. A major (∼2000 m) and apparently rapid deepening also occurred in the calcium carbonate compensation depth (CCD). This climatic threshold was crossed as a result of the gradual isolation of Antarctica from Australia and perhaps the opening of the Drake Passage. During the Oligocene (t = 38 to 22 m.y. ago), widespread glaciation probably occurred throughout Antarctica, although no ice cap existed. By the middle to late Oligocene (t = ∼30 to 25 m.y. ago), deep‐seated circum‐Antarctic flow had developed south of the South Tasman Rise, as this had separated sufficiently from Victoria Land, Antarctica. Major reorganization resulted in southern hemisphere deep‐sea sediment distribution patterns. The next principal climatic threshold was crossed during the middle Miocene (t = 14 to 11 m.y. ago) when the Antarctic ice cap formed. This occurred at about the time of closure of the Australian‐Indonesian deep‐sea passage. During the early Miocene, calcareous biogenic sediments began to be displaced northward by siliceous biogenic sediments with higher rates of sedimentation reflecting the beginning of circulation related to the development of the Antarctic Convergence. Since the middle Miocene the East Antarctic ice cap has remained a semipermanent feature exhibiting some changes in volume. The most important of these occurred during the latest Miocene (t = ∼5 m.y. ago) when ice volumes increased beyond those of the present day. This event was related to global climatic cooling, a rapid northward movement of about 300 km of the Antarctic Convergence, and a eustatic sea level drop that may have been partly responsible for the isolation of the Mediterranean basin. Northern hemisphere ice sheet development began about 2.5–3 m.y. ago, representing the next major global climatic threshold, and was followed by the well‐known major oscillations in northern ice sheets. In the Southern Ocean the Quaternary marks a peak in activity of oceanic circulation as reflected by widespread deep‐sea erosion, very high biogenic productivity at the Antarctic Convergence and resulting high rates of biogenic sedimentation, and maximum northward distribution of ice‐rafted debris.

Description: Several types of abyssal bedforms have been discovered during surveys with a deeply towed instrument package at water depths of 1.5–6 km in the Pacific and Atlantic Oceans. Cores and current-meter records obtained at the same sites provide data for interpreting their dynamics. Wave and current ripples are best portrayed in bottom photographs, but medium-scale bedforms, including sand waves, mud waves and erosional furrows, are described by interpreting high-resolution side-looking sonar records. The largest examples affect surface-ship echograms, though their shape and structure can seldom be resolved without near-bottom observations. Wave ripples are common on the slopes of seamounts and ridges, while current ripples and sand waves occur beneath some fast thermohaline currents whose beds are shallower than the foraminiferal compensation depth. Depositional and erosional bedforms in cohesive sediment have been found beneath the deepest thermohaline currents; they may be restricted to areas where the flow is unusually steady in direction.

Description: Many occurrences of mineral resources in ocean water, on the ocean floor and in its deeper parts have long been well-known. This is readily understandable, because numerous ancient mineral products which are exploited on land were originally formed in marine milieus as far back as the Precambrian , e.g., marine sedimentary iron ores, rock salt, potassium, phosphate and manganese , as well as petroleum and natural gas. This book deals with ores in sediments, and in sedimentary and volcanic rocks. According to the Concise Oxford Dictionary (Fowler and Fowler , 1964), ore is defined as "solid native mineral aggregate from which valuable constituents not necessarily metal may be usefully extracted". Therefore , in tllis chapter only mineral resources of inorganic origin in ocean water and on the ocean floor are discussed and not those of organic derivation, although the existence of petroleum, natural gas and, to some extent, of coal in the subsurface of the ocean shelves is of greater economic importance. The amount of oil and gas produced in 1969 represented more than 90% by value of all mineral resources obtained from the oceans and ocean floors. Ore deposits in bed-rock formations of the shelf region, such as those which are exploited near Cornwall (England) and Newfoundland for example, are also irrelevant, as these are merely extensions of discoveries on the nearby mainland. The purpose of this chapter is to give a general review of the (inorganic) mineral resources of the oceans and the ocean floors . In this respect, not only are the economically important products which are already in use discussed, but also those materials which, in their oceanic environment, can become of economic value in the near or more remote future. For a better understanding of the existence of such materials, some deposits have also had to be reviewed which will not become of economic value . Since some contributions in this book are specifically dedicated to Recent marine ferromanganese deposits and Recent phosphorite deposits, these mineral resources are only briefly discussed in tllis chapter. (For details on Recent marine and lacustrine manganese deposits see Chapters 7 and 8 by Glasby/Read and by Callender/Bowser, respectively, in Volume 7.) The litarature on the mineral (inorganic) resources of the oceans and ocean floors is extremely extensive, so that a choice had to be made and, therefore, the bibliography added to this chapter consists mainly of recent publications.

Description: Published geological and geophysical data are reviewed. The Walvis Ridge is a complex linear feature made up of three parts of unequal lengths and differing basement morphologies: an eastern sector composed of rugged, subparallel basement ridges; a low-lying central sector with subdued basement morphology; and a western sector consisting of seamounts and guyots (including Tristan da Cunha and Gough islands). Rock samples and geophysical data suggest that the Ridge is composed of alkali basalt which becomes progressively older eastwards. Gravity data indicate that at least parts of the ridge are in local isostatic equilibrium. A mantle plume mechanism of formation is rejected in favour of a centre of abnormally high volcanic activity on the spreading ridge axis. The location of this centre, whose relative movement has been southwards, is determined by fracture zones crossing the spreading ridge axis.

Description: Observations of the temporal and spatial distribution of N2O in solution are not yet sufficient to permit quantitative assessment of the role of the ocean in the budget of atmospheric N2O. Consideration of the global nitrogen cycle suggests that the land should be the primary source of N2O. The gas is removed in the atmosphere by photolysis and by reaction with O(1D), and there may be additional sinks in the ocean.

Description: The Cape Verde Islands are emerged portions of a Mesozoic-Cenozoic volcanic accretion in the form of a westward-opening horseshoe along fracture zones converging from the mid-Atlantic ridge toward Africa. An interior abyssal plain slopes westward, increasing in depth from 2.7 to 4.5 km. The plain is underlain by low relief on acoustic basement that is associated with a 300-gamma negative magnetic anomaly. The flanks of the Sal-Maio ridge appear bounded by large-displacement normal faults; superficial slumping is common. The trends of magnetic anomalies are linear N-S north of the islands and less linear within the islands and may change coincident with E-W bathymetric trends south of the islands. A triangular pattern of reversed refraction lines 200–250 km long along the north and east ridges and NW-SE across the interior abyssal plain indicated 2–3 km of semiconsolidated sediments underlain by 3–6 km of basalt and 6–8 km of plutonic rocks. The depth of the Moho is between 16 and 17 km. A deep NW-SE trending fault intersects the Sal-Maio ridge near Boa Vista. The consistent depth to Moho and the regional Bouguer anomaly indicate lack of local relief at the base of the crust. The crustal load of the entire archipelago is regionally adjusted.

Description: A complete set of linearly independent relationships among the different cross spectral components obtained from pairs of moored instruments is derived which can be utilized to test whether or not the observed fluctuations within the internal wave frequency band represent a field of propagating internal waves. A further complete set of relationships is derived which enables to test whether or not the internal wave field is horizontally isotropic and (or) vertically symmetric. These relations are compared with corresponding relations for alternative models (standing internal wave modes, three-dimensional isotropic turbulence) and their capability to discriminate between the various models is investigated. The tests are applied to a set of data for which it is found that the observed fluctuations are consistent with both propagating and standing internal waves whereas isotropic turbulence must be rejected for the most part of the internal wave frequency band.

Description: Food production is affected by climate and by climate change. The indices for climate change may be recognized in long-term systematic observations of oceanic water columns at selected referential sites. The Mediterranean Sea, as part of the global oceanic circulation system, may be sensitive to climatic variation and may have an influence upon climate. The establishment of international referencestations for the Mediterranean area is suggested.

Description: A model for interstitial silica concentrations is derived, incorporating biological mixing of sediments. This model predicts concentrations and gradients and can account for the observed geographical variations in interstitial silica on the basis of a dynamic balance between solution of silica particles and diffusion from the sediments. The flux of particulate biogenous silica into the sediments is confirmed as an important parameter controlling interstitial silica concentrations. Biological mixing of sea floor sediments also has an important influence on interstitial composition by modifyirig the depth at which dissolving particles react. Faster mixing raises the interstitial concentration. The rate at which siliceous particles dissolve also plays a role; the slower they dissolve, the greater the interstitial silica concentration. Measurements on near‐bottom waters of the Atlantic show no consistent gradients in dissolved silica, but antarctic bottom water seems significantly more variable in the benthic boundary layer than in the water mass above or in the benthic zone of North Atlantic deep water.

Description: Biological mixing in deep‐sea sediments is described in terms of a time‐dependent eddy diffusion model where mixing takes place to a depth L at constant eddy diffusivity D. The differential equation that describes this model has been solved for an impulse source of tracer delivered to the plane surface that forms the top of the mixed layer. The solution then serves as a Green's function, which can be used to determine the distribution of tracer in depth and in time for a surface input of tracer specified as any arbitrary function of time. The characteristic properties of the solution are dependent on the dimensionless parameter D/Lυ, where υ is the sedimentation rate. If D/Lυ is greater than 10, the surface layer becomes homogeneous, and the model is identical to the homogeneous layer model proposed by Berger and Heath (1968). If D/Lυ is less than 0.1, little mixing can take place before the sediments are buried, and so the surface concentration propagates downward into the sediments with little dispersion. For all values of D/Lυ the weighted mean depth of the concentration distribution is the depth at which an impulse source would be found in the sediment if no mixing had taken place. The microtektite data of Glass (1969, 1972) and Glass et al. (1973) indicate that abyssal sediments are mixed from the surface to a maximum mixing depth that ranges between 17 and 40 cm below the surface. Mixing occurs at rates between 1 and 100 cm2 kyr−1. Higher mixing rates may occur nearer the surface, but microtektite distributions cannot be used to estimate these rates in the presence of the deeper, slower mixing. Estimates for D based on dimensional analysis of sediment reworking rates for nearshore organisms (103–106 cm2 kyr−1) are used to predict abyssal mixing rates between 1 and 103 cm2 kyr−1 by invoking the assumption that mixing is proportional to biomass. Plutonium distributions in deep‐sea sediments (Noshkin and Bowen, 1973) indicate abyssal mixing rates ranging from 100 to 400 cm2 kyr−1.