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  • Chemical Engineering  (1,749)
  • 04. Solid Earth::04.06. Seismology::04.06.09. Waves and wave analysis  (6)
  • Wiley-Blackwell  (1,755)
  • 2010-2014  (6)
  • 1960-1964  (1,166)
  • 1955-1959  (583)
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Year
  • 1
    Publication Date: 2020-12-15
    Description: Seismogram envelopes recorded at Campi Flegrei caldera show diffusive characteristics as well as steep amplitude increases in the intermediate and late coda, which can be related to the presence of a non-uniformly scattering medium. In this paper, we first show the results of a simulation with a statistical model considering anisotropic scattering interactions, in order to match coda-envelope duration and shape.We consider as realistic parameters for a volcanic caldera the presence of large square root velocity fluctuations (10 per cent) and two typical correlation lengths for such an heterogeneous crust, a = 0.1 and 1 km. Then, we propose the inclusion of a diffusive boundary condition in the stochastic description of multiple scattering, in order to model intermediate and late coda intensities, and particularly the sharp intensity peaks at some stations in the caldera. Finally, we show that a reliable 2-D synthetic model of the envelopes produced by earthquakes vertically sampling a small region can be obtained including a single drastic change of the scattering properties of the volcano, that is, a caldera rim of radius 3 km, and sections varying between 2 and 3 km. These boundary conditions are diffusive, which signifies that the rim must have more scattering potential than the rest of the medium, with its diffusivity 2–3 orders of magnitude lower than the one of the background medium, so that the secondary sources on its interface(s) could enhance coda intensities. We achieve a good first-order model of high-frequency (18 Hz) envelope broadening adding to the Monte Carlo solution for the incident flux the secondary source effects produced by a closed annular boundary, designed on the caldera rim signature at 1.5 km depth. At lower frequencies (3 Hz) the annular boundary controls the intermediate and late coda envelope behaviour, in a way similar to an extended diffusive source. In our interpretation, the anomalous intensities observed at several stations and predicted by the final Monte Carlo solutions are mainly due to the diffusive transmission reflection from a scattering object of increased scattering power, and are controlled by its varying thickness.
    Description: This work was carried out under the HPC-Europa2 project (project number: 228398) with the support of the European Commission Capacities Area-Research Infrastructures Initiative. We thank the whole staff at EPCC (Edinburgh Parallel Computing Centre) in Edinburgh and particularly Dr. Adam Carter for their help in both developing and parallelizing the code. The challenging comments and suggestions of the editor and two anonymous reviewers helped both in focusing the aim and in overcoming the strong limits of a previous version of the paper.
    Description: Published
    Description: 1102–1119
    Description: 3.1. Fisica dei terremoti
    Description: JCR Journal
    Description: restricted
    Keywords: Numerical solutions; ; Seismic anisotropy; ; Seismic attenuation ; Seismic tomography ; Wave scattering and diffraction ; Calderas ; 04. Solid Earth::04.06. Seismology::04.06.09. Waves and wave analysis
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 2
    Publication Date: 2017-04-04
    Description: Local and regional seismicity jointly recorded by two dense small aperture arrays, one installed at surface and one at 1.3 km depth, constitutes an interesting data set useful for coda observations. Applying array techniques to earthquakes recorded at the two arrays we measure slowness, backazimuth and correlation coefficient of the coherent coda wave signals in five frequency bands in the range 1–10 Hz. Slowness distributions show marked differences between surface and underground, with slow signals at surface (slowness greater than 1.0 s km−1) that are not observed underground. We interpret these coherent signals as surface waves produced by the interaction of body waves with the free surface characterized by rough topography. The backazimuth values measured in the frequency bands centred at 1.5 and 3 Hz are almost uniformly distributed between 0 and 360◦, while those measured at higher frequencies show different distributions between surface and underground. On the contrary, the earthquake envelopes show very similar coda shapes between surface and underground recordings, with an almost constant coda-amplitude ratio (between 4 and 8) in a wide frequency range.
    Description: Published
    Description: 367-371
    Description: 1.1. TTC - Monitoraggio sismico del territorio nazionale
    Description: JCR Journal
    Description: restricted
    Keywords: Coda waves ; Wave scattering and diffraction ; Wave propagation ; 04. Solid Earth::04.06. Seismology::04.06.09. Waves and wave analysis
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 3
    Publication Date: 2017-04-04
    Description: In this work, we present regional maps of the inverse intrinsic quality factor (Qi −1), the inverse scattering quality factor (Qs −1) and total inverse quality factor (Qt −1) for the volcanic environment of Deception Island (Antarctica). Our attenuation study is based on diffusion approximation, which permits us to obtain the attenuation coefficients for every single couple source-receiver separately. The data set used in this research is derived from an active seismic experiment using more than 5200 offshore shots (air guns) recorded at 32 onshore seismic stations and four ocean bottom seismometers. To arrive at a regional distribution of these values, we used a new mapping technique based on a Gaussian space probability function. This approach led us to create ‘2-D probabilistic maps’ of values of intrinsic and scattering seismic attenuation. The 2-D tomographic images confirm the existence of a high attenuation body below an inner bay of Deception Island. This structure, previously observed in 2-D and 3-D velocity tomography of the region, is associated with a massive magma reservoir. Magnetotelluric studies reach a similar interpretation of this strong anomaly. Additionally, we observed areas with lower attenuation effects that bear correlation with consolidated structures described in other studies and associated with the crystalline basement of the area. Our calculations of the transport mean-free path and absorption length for intrinsic attenuation gave respective values of ≈950 m and 5 km, which are lower than the values obtained in tectonic regions or volcanic areas such as Tenerife Island. However, as observed in other volcanic regions, our results indicate that scattering effects dominate strongly over the intrinsic attenuation.
    Description: This work has been partially supported by the Spanish project Ephestos, CGL2011–29499-C02–01, by the EU project EC-FP7 MEDiterranean SUpersite Volcanoes (MED-SUV), by the Basque Government researcher training program BFI09.277 and by the Regional project ‘Grupo de Investigaci´on en Geof´ısica y Sismolog´ıa de la Junta de Andaluc´ıa, RNM104.’ Edoardo del Pezzo was partly supported by DPC-INGV projects UNREST SPEED and V2 (Precursori).
    Description: Published
    Description: 1957-1969
    Description: 3.1. Fisica dei terremoti
    Description: 3.6. Fisica del vulcanismo
    Description: JCR Journal
    Description: restricted
    Keywords: Seismic attenuation; ; Seismic tomography ; Volcano seismology ; Wave scattering and diffraction ; Wave propagation ; 04. Solid Earth::04.06. Seismology::04.06.07. Tomography and anisotropy ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology ; 04. Solid Earth::04.06. Seismology::04.06.09. Waves and wave analysis
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 4
    Publication Date: 2017-04-04
    Description: The peculiar source characteristics of long-period seismic events (time persistency of the source, low-frequency peaks in the source spectrum, absence of high-frequency radiation) prevent the formation of a definite high-frequency coda in the seismograms. In contrast, this is well formed in volcano–tectonic quakes. For this reason, the widely used duration magnitude scale that is based on the proportionality between the energy and the coda duration cannot be used for long-period estimation. In observatory practice, the long-period magnitude is sometimes estimated using the same duration magnitude scale, leading to confusing results. In this report, we show a new method to estimate the magnitude of long-period events that generally occur for volcanoes, with some application examples from data for Mt Etna (Italy), Colima Volcano (Mexico) and Campi Flegrei (Italy).
    Description: Published
    Description: 911-919
    Description: 3.1. Fisica dei terremoti
    Description: JCR Journal
    Description: restricted
    Keywords: Earthquake source observations; ; Volcano monitoring ; Volcano seismology ; 04. Solid Earth::04.06. Seismology::04.06.03. Earthquake source and dynamics ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology ; 04. Solid Earth::04.06. Seismology::04.06.09. Waves and wave analysis
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 5
    Publication Date: 2017-04-04
    Description: The coda normalization method is one of the most used methods in the inference of attenuation parameters Qα and Qβ . Since, in this method, the geometrical spreading exponent γ is an unknown model parameter, the most part of studies assumes a fixed γ , generally equal to 1. However γ and Q could be also jointly inferred from the non-linear inversion of codanormalized logarithms of amplitudes, but the trade-off between γ and Q could give rise to unreasonable values of these parameters. To minimize the trade-off between γ and Q, an inversion method based on a parabolic expression of the coda-normalization equation has been developed. The method has been applied to the waveforms recorded during the 1997 Umbria-Marche seismic crisis. The Akaike criterion has been used to compare results of the parabolic model with those of the linear model, corresponding to γ = 1. A small deviation from the spherical geometrical spreading has been inferred, but this is accompanied by a significant variation of Qα and Qβ values. For almost all the considered stations, Qα smaller than Qβ has been inferred, confirming that seismic attenuation, in the Umbria-Marche region, is controlled by crustal pore fluids.
    Description: Published
    Description: 1726-1731
    Description: 3.1. Fisica dei terremoti
    Description: JCR Journal
    Description: restricted
    Keywords: Seismic attenuation ; coda normalization method ; 04. Solid Earth::04.06. Seismology::04.06.09. Waves and wave analysis
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 6
    Publication Date: 2017-04-04
    Description: The complex volcanic system of Tenerife Island is known to have a highly heterogeneous character, as recently confirmed by velocity tomography.We present new information derived from intrinsic quality factor inverse maps (Qi −1), scattering quality factor inverse maps (Qs −1) and total quality factor inverse maps (Qt −1) obtained for the same region. The data set used in this work is the result of the analysis of an active seismic experiment carried out, using offshore shots (air guns) recorded at over 85 onshore seismic stations. The estimates of the attenuation parameters are based on the assumption that the seismogram energy envelopes are determined by seismic energy diffusion processes occurring inside the island. Diffusion model parameters, proportional to Qi −1 and to Qs −1, are estimated from the inversion of the energy envelopes for any source–receiver couple. They are then weighted with a new graphical approach based on a Gaussian space probability function, which allowed us to create ‘2-D probabilistic maps’ representing the space distribution of the attenuation parameters. The 2-D images obtained reveal the existence of a zone in the centre of the island characterized by the lowest attenuation effects. This effect is interpreted as highly rigid and cooled rocks. This low-attenuation region is bordered by zones of high attenuation, associated with the recent historical volcanic activity. We calculate the transport mean free path obtaining a value of around 4 km for the frequency range 6–12 Hz. This result is two orders of magnitude smaller than values calculated for the crust of the Earth. An absorption length between 10 and 14 km is associated with the average intrinsic attenuation parameter. These values, while small in the context of tectonic regions, are greater than those obtained in volcanic regions such as Vesuvius or Merapi. Such differences may be explained by the magnitude of the region of study, over three times larger than the aforementioned study areas. This also implies deeper sampling of the crust, which is evidenced by a change in the values of seismic attenuation. One important observation is that scattering attenuation dominates over the intrinsic effects, Qi being at least twice the value of Qs.
    Description: This work has been partially supported by the Spanish project Ephestos, CGL2011-29499-C02-01, by the EU project EC-FP7 MEDiterranean SUpersite Volcanoes (MED-SUV), by the Basque Government researcher training program BFI09.277 and by the Regional project ‘Grupo de Investigaci´on en Geof´ısica y Sismolog´ıa de la Junta de Andaluc´ıa, RNM104’. EdP has been partly supported by DPC-INGV projects UNREST SPEED and V2 (Precursori).
    Description: Published
    Description: 1942-1956
    Description: 3.1. Fisica dei terremoti
    Description: 3.3. Geodinamica e struttura dell'interno della Terra
    Description: JCR Journal
    Description: restricted
    Keywords: Seismic attenuation ; ; Seismic tomography; ; Volcano seismology ; Wave propagation. ; 04. Solid Earth::04.06. Seismology::04.06.07. Tomography and anisotropy ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology ; 04. Solid Earth::04.06. Seismology::04.06.09. Waves and wave analysis
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  • 7
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 8
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    AIChE Journal 10 (1964), S. 135-135 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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  • 9
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    AIChE Journal 10 (1964), S. 5-10 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 10
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    AIChE Journal 10 (1964), S. 16-25 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 11
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    AIChE Journal 10 (1964), S. 35-38 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 12
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    AIChE Journal 10 (1964), S. 67-67 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 13
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    AIChE Journal 10 (1964), S. 79-82 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 14
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    AIChE Journal 10 (1964), S. 106-110 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 15
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    AIChE Journal 10 (1964), S. 110-114 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
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  • 16
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    AIChE Journal 10 (1964), S. 130-131 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 17
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    AIChE Journal 10 (1964), S. 274-275 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 18
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    AIChE Journal 10 (1964), S. 277-281 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 19
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    AIChE Journal 10 (1964), S. 91-97 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 20
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    AIChE Journal 10 (1964), S. 293-297 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Constant pressure diffusion rates of hydrogen through Vycor porous glass were measured in nitrogen and neon systems. The experimental diffusivities are less than those predicted by the random pore model indicating that this model may not be satisfactory for a low porosity material such as Vycor. Interpreted in terms of an assembly of parallel pores the data suggest a tortuosity factor of approximately 2.4.Rate data for the ortho-para hydrogen reaction were also measured at -196°C. and 1 atm. The catalyst 2% nickel/Vycor was found to have pore properties (area, mean pore size, pore volume) similar to that of plain Vycor. Predicted effectiveness factors using the experimental diffusion data were in good agreement with values determined experimentally. The latter were evaluated from rate measurements on both pellet and particles (58 μ mean diameter).
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  • 21
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    AIChE Journal 10 (1964), S. 309-315 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A computational method has been developed for obtaining the solution to a class of optimization problems by the combined use of the maximum principle and a maximum (or minimum) seeking technique on the analogue computer. Various maximum seeking techniques can be used for this method. However if the random search technique is used, this computational method has the advantage of being able to investigate a large number of operating (or controlling) variables.The calculation procedure is essentially a trial-and-error procedure which is alternately integration and maximum seeking operations. The variables over which the system is to be optimized are approximated by a finite number of straight line segments n. Thus the maximum (or minimum) of the Hamiltonian function which is obtained by the maximum principle need only be obtained at n + 1 points along the optimization path (or trajectory).To illustrate the use of the method the optimum operating variable profiles (or gradients) in a tubular chemical reactor were computed.The present method, in addition to making it easier to investigate systems with a moderate number of state variables, can be used to solve problems with almost any kind of constraints and performance index encountered in ordinary optimum design problems. It offers some possibilities for on-line optimizing control of a process. A special purpose analogue computer could be built for this use.
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  • 22
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    AIChE Journal 10 (1964), S. 351-356 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 23
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    AIChE Journal 10 (1964), S. 364-368 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 24
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    AIChE Journal 10 (1964), S. 369-373 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 25
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    AIChE Journal 10 (1964), S. 388-392 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 26
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    AIChE Journal 10 (1964), S. 403-407 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 27
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    AIChE Journal 10 (1964), S. 416-417 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
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    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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    AIChE Journal 10 (1964), S. 420-422 
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    Keywords: Chemistry ; Chemical Engineering
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    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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    AIChE Journal 10 (1964), S. 134-135 
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    Keywords: Chemistry ; Chemical Engineering
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  • 30
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    AIChE Journal 10 (1964), S. 595-597 
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    Keywords: Chemistry ; Chemical Engineering
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  • 31
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    AIChE Journal 10 (1964), S. 595-595 
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    Keywords: Chemistry ; Chemical Engineering
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  • 32
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    AIChE Journal 10 (1964), S. 448-455 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The linearized equations of diffusion in a multicomponent system with flow and chemical reaction are shown to reduce to a set of equivalent binary diffusion equations.The concentrations and fluxes in a multicomponent system are described by linear combinations of appropriate solutions to the binary diffusion equation for steady and unsteady diffusion and convective mass transfer, laminar or turbulent.The rate of transfer of each component in a nonreacting n component system is a linear combination of the n-1 independent driving forces with proportionality constants which depend upon the multicomponent diffusion coefficients and appropriate binary mass transfer coefficients, while the concentration profile of each component is a linear combination of appropriate binary concentration profiles with proportionality constants which depend upon the multicomponent diffusion coefficients and the characteristic displacement from equilibrium of each component.The linearized theory is exact for small changes in concentration but needs further testing when the concentration changes and fluxes are large.
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  • 33
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    AIChE Journal 10 (1964), S. 475-482 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 34
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    AIChE Journal 10 (1964), S. 471-474 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The solutions of amines and water are in several respects among the most interesting that have been studied. They give some of the most perfect examples of lower consolute temperatures with fast breaking, almost flat solubility curves near the critical solution point. Their heat and entropy of solution are very high, and with few other solutions do the thermodynamic properties show greater sensitivity to molecular structure.The activity coefficients for these solutions are inordinately difficult to fit with equations such as the Margules, Redlich-Kister, etc., requiring as many as six constants. It has been found however that some of the properties can be correlated in terms of structural parameters which are measures of the steric and inductive contribution of the substituent groups. A very good correlation of the heat of solution at infinite dilution of amines in water is given. An equation of the Margules type employing orthogonal polynomials is given for which the constants are similarly correlated. Five six-carbon atom amines at 10°C. are included in the latter correlations, and the activity coefficients of all of these are represented in terms of two structural parameters.
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    AIChE Journal 10 (1964), S. 509-517 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A study was made of nucleate boiling bubble dynamics in saturated distilled water for various reduced gravity fields. The nucleation occurred on a very smooth horizontal nickel surface at low heat fluxes. Since because of the smooth surface finish only a few nucleation sites were active, it was possible to photograph individual bubbles that were not interfered with by adjacent bubble columns. Data were taken at seven different gravity fields in the range from 1.4 to 100% of earth gravity by placing the apparatus on a counterwieghted falling platform. Measurements were made of bubble departure diameters and frequencies, growth rates, contact angles, base circle diameters, and rise velocities. Comparisons were made to determine whether the measured gravity dependence of these quantities was in agreement with that predicted by correlations in the literature.
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    AIChE Journal 10 (1964), S. 517-523 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: In the absence of turbulent fluctuations the main effect of a velocity gradient on the floc properties is a rearrangement of particles within the floc producing a more dense floc structure. When the suspension is sufficiently dilute that floc-floc collisions are negligible, the limits on the floc diameter are (1 + α)5/3 〈 (Df/Dp) ≤ (1 + α)2, where α is the ratio of the volume of fluid immobilized in the floc structure to volume of solids in the floc structure as determined from hindred-settling measurements. These results set an upper limit on the floc size.Under turbulent flow conditions the principle mechanism leading to floc rupture is pressure differences on opposite sides of the floc which cause bulgy deformation and rupture. The breakup of the floc is resisted by the yield stress τy and is promoted by an increase in the energy dissipation per unit mass of fluid ∊. Because the energy dissipation per unit mass is at a maximum near the pipe wall, the floc size is at a minimum in this same region.By application of the concepts of local isotropy, the floc size is found to be proportional to (τy9/∊5)1/2once the turbulent intensity is sufficient to overcome the yield stress. In the wall region the floc diameter is proportional to (du/dr)3 (τy9/∊8)1/2.
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    AIChE Journal 10 (1964), S. 524-529 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The purpose of this study was to develop the use of semibatch operation of a recirculation reactor in kinetic studies. Ethylene hydrogenation over a supported copper catalyst was studied experimentally. In semibatch operation one of the reactants is fed at the rate necessary to hold the total pressure in the reactor constant. In ethvlene hydrogenation the reaction rate is directly equal to the feed rate, and the kinetics can be studied at constant partial pressure of either of the reactants. Since ethane is inert, this technique permitted the study of reaction rate as a function of one variable at a time.Although ethylene hydrogenation has been studied extensively, there is not general agreement regarding the kinetics over a copper catalyst. The results are themselves of interest because they indicate the reasons for the apparently conflicting data in the literature.
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    AIChE Journal 10 (1964), S. 548-550 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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    AIChE Journal 10 (1964), S. 551-557 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: To test the importance of visco-elastic properties of non-Newtonian fluids in an oscillatory system of low frequency the dynamic characteristics of a series of non-Newtonian fluids were studied in oscillating manometers. The manometer fluid behavior was simulated on a digital computer by numerically integrating the axial component of the equation of motion. In the simulation cone and plate steady state rheological data were represented mathematically with the Sisko rheological model. Good agreement between simulation and experimental data was obtained. This agreement implies that steady state rheological models can be utilized in the description of unsteady state non-Newtonian systems where the characteristic period of the system is many times greater than the relaxation and retardation times of the fluid. When this characteristic period approaches these times, then rheological models which incorporate viscoelastic terms explicitly probably should be used.
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    AIChE Journal 10 (1964), S. 584-596 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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    AIChE Journal 10 (1964), S. 584-600 
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    AIChE Journal 10 (1964), S. 586-589 
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    Keywords: Chemistry ; Chemical Engineering
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    AIChE Journal 10 (1964), S. 274-274 
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    AIChE Journal 10 (1964), S. 269-273 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A method is presented for solving the basic energy expression for the temperature distribution for turbulent heat transfer in a circular conduit with a digital computer. The method assumes a knowledge of the velocity distribution, the eddy conductivity term as a function of the radial position, and a constant wall temperature. For illustrative purposes only a dimensionless expression is derived from Reichardt's relationship which gives the eddy conductivity term as a function of radial position with Reynolds and Prandtl numbers as parameters.Incorporated in the computer program is Richardson's three-point extrapolation formula which permits the determination of a more accurate eigenvalue from three previously computed values which were obtained by using three different values of the reduced radial increment. Agreement with the Crank-Nicholson method is quite good, although the method with eigenvalues is considered to be superior. Eigenvalues determined from the analytical solution of the energy expression for the laminar flow case and those computed by the numerical method are in excellent agreement. This is indicative of the accuracy and reliability of the proposed numerical method.
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    AIChE Journal 10 (1964), S. 278-284 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
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    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Outline below is a method for simplification of the solution of diffusion problems involving irreversible first-order reactions. It permits writing the concentration profiles for reactive systems in terms of those for nonreactive systems of the same geometry and similar boundary conditions. The method is valid where fluid flow patterns and concentration boundary conditions are time independent and where the assumptions of constant density and mass diffusivity are acceptable. The useful results of this development are summarized in Equations (31) through (33) and represent a generalization of an earlier development by P. V. Danckwerts (1).
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    AIChE Journal 10 (1964), S. 652-655 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The kinetics of reduction of ferrous oxide with hydrogen were studied in a 1½-in. diameter isothermal batch fluidized reactor. The effects of mass velocity and pressure on the reduction path were investigated over the ranges 5.3 to 19.2 moles/sq.ft.hr. and 1.3 to 5.4 atm. at 1,000° and 1,300°F. The results are correlated by means of instantaneous oxygen balances on the assumptions that there are no oxygen concentration gradients in the solid phase, that the distribution of residence times for the gas flow is represented closely by assuming complete mixing, and that the reduction rate is controlled at the oxide-metal interface. The rate of reduction increased with increasing pressure and mass velocity. An excellent correlation was obtained for the program at 1,000°F. At 1,300°F. sintering and grain growth of the product layer complicated the reduction process, and a correlation was not obtained. Application of the results to the design of commercial fluidized-reduction processes is discussed qualitatively.
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    AIChE Journal 10 (1964), S. 303-308 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Four different flow regimes may be identified during transport of dilute suspensions of solid particles through horizontal pipes by liquids in turbulent flow as the velocity is varied. The regimes may be characterized by the distribution of solids in the channel. In two of the regimes the bulk of the material is immediately adjacent to the bottom of the channel and is clumped up either into transverse waves (dunes or islands) with a reproducible periodicity or into longitudinal waves (long stria). The definition of the other two regimes is somewhat more arbitrary but may qualitatively be described as heterogeneous or homogeneous flow. Extensive studies of the conditions under which transverse and longitudinal waves occurred, when combined with results of previous studies, showed that all four of these flow regimes may be conveniently represented on a single diagram in which the terminal-settling velocity divided by the friction velocity and the Reynolds number on particle diameter and friction velocity are the coordinates. Because the particle Reynolds number based on the terminal-settling velocity can be uniquely defined as an additional parametre on such a diagram the particular flow behavior for any given combination of system and particle characteristics can be readily determined.
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    AIChE Journal 10 (1964), S. 339-344 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
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    AIChE Journal 10 (1964), S. 330-339 
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    Keywords: Chemistry ; Chemical Engineering
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    Notes: Significant changes in heat and momentum transfer rates can be caused by finite interfacial velocities and external field forces. This study considers the nonlinear problem of combined free and forced convection in vertical and horizontal two-dimensional conduits with finite transverse velocity.Similarity transformations for the temperature function have been found which reduce the energy, momentum, continuity, and state equations for these configurations to nonlinear systems of two coupled ordianary differential euqations. These equations are solved by approximate methods to give Nusselt numbers and friction factors as well as velocity and temperature profiles.Stream to wall temperature differences increase with suction and decrease with injection. The effects of interfacial velocity on temperature profiles and heat transfer increase dramatically with Prandtl number. Because blowing and suction strongly affect temperature profiles they substantially modify natural convection effects in vertical flows. Suction creates steeper transverse temperature gradients and accentuates buoyancy effects in vertical flows. Conversely injection flattens temperature profiles and thus decreases the influence of buoyancy on the velocity field.
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    AIChE Journal 10 (1964), S. 373-379 
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    Keywords: Chemistry ; Chemical Engineering
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    AIChE Journal 10 (1964), S. 774-780 
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    Keywords: Chemistry ; Chemical Engineering
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    AIChE Journal 10 (1964), S. 398-402 
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    AIChE Journal 10 (1964), S. 415-430 
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    AIChE Journal 10 (1964), S. 418-426 
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    Keywords: Chemistry ; Chemical Engineering
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    AIChE Journal 10 (1964), S. 430-430 
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    AIChE Journal 10 (1964), S. 435-435 
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    AIChE Journal 10 (1964), S. 804-809 
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    AIChE Journal 10 (1964), S. 819-826 
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    AIChE Journal 10 (1964), S. 836-842 
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    AIChE Journal 10 (1964), S. 848-854 
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    Notes: The results of two investigations are reported. Air bubbles were formed at orifices submerged beneath each of fourteen liquids. The surface tension of the liquids varied from 17.8 to 72.4 dynes/cm., and the viscosities ranged from 0.436 to 713 centipoise. In the first investigation, air bubbles were formed at orifices at various angles of inclihation. Orifice diameters ranging from 0.159 to 0.396 cm. were employed. The air-flow rate was varied from 0.1 to 100 cc. (at standard conditions)/sec. The results were obtained with two different apparatuses by three independent investigators.In the second investigation, the effect of the velocity of a liquid flowing past a horizontal, submerged orifice on the formation of air bubbles was determined. Liquid velocities ranging from 0.34 to 2.5 cm/sec., which spanned the region of laminar flow, were employed. Orifice diameters ranged from 0.15875 to 0.3175 cm., air-flow rates from 0.5 to 100 cc/sec. (at standard conditions).It was found that the bubble formation observed in each of these investigations could be correlated with the physical variables of the system by the application of Newton's second law of motion to the bubble at the instant just prior to its release from the orifice.
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    AIChE Journal 10 (1964), S. 755-758 
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    AIChE Journal 10 (1964), S. 483-486 
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    AIChE Journal 10 (1964), S. 775-783 
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    AIChE Journal 10 (1964), S. 776-792 
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    AIChE Journal 10 (1964), S. 817-819 
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    AIChE Journal 10 (1964), S. 562-567 
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    AIChE Journal 10 (1964), S. 580-583 
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    AIChE Journal 10 (1964), S. 584-592 
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    AIChE Journal 10 (1964), S. 597-597 
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    AIChE Journal 10 (1964), S. 896-901 
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    AIChE Journal 10 (1964), S. 920-924 
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    AIChE Journal 10 (1964), S. 913-919 
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    Notes: The calculus of variations, dynamic programing, and Pontryagin's maximum principle all are methods for optimzing serial decision processes, the kind associated with multistage operations having no recycle or bypass. Addition of recycle to a serial process makes it cyclic, and branching structures can be built up by connecting serial ones. The concept of cut state makes possible the decomposition of cyclic and branched systems into serial ones solvable by serial procedures. Under favorable circumstances cut states can be directed to their optimum values by efficient optimum seeking methods, which is not possible for ordinary state variables. These method are worthwhile only for loops having at least three stages, and the treatment of converging branches is more complicated than for diverging ones. Visualization of the various system structures is aided by functional diagrams. Definitions and nomenclature are developed for continued research on optimization of macrosystems by serial techniques.
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    AIChE Journal 10 (1964), S. 2-2 
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    AIChE Journal 10 (1964), S. 133-133 
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    AIChE Journal 10 (1964), S. 135-137 
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 137-137 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 81
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    AIChE Journal 10 (1964), S. 26-30 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 82
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    AIChE Journal 10 (1964), S. 144-144 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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  • 83
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    AIChE Journal 10 (1964), S. 147-147 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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  • 84
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    AIChE Journal 10 (1964), S. 194-197 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 85
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    AIChE Journal 10 (1964), S. 227-232 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 9 Ill.
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  • 86
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    AIChE Journal 10 (1964), S. 238-245 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 4 Ill.
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  • 87
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    AIChE Journal 10 (1964), S. 260-265 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The point of inversion of a water-in-oil type of dispersion to an oil-in-water type is investigated for several water-oil systems by studying the volume ratios of the phases in relation to their physical properties. The point of inversion for each system of an immiscible organic liquid and water and organic liquid mixture and water is obtained by varying the phase-volume ratios and determining the type of dispersion after complete mixing. The effects of temprature, interfacial tension, and density are found to have no correlation generally applicable to the systems studied. A volume-viscosity relationship is found to exist within limits. This correlation is that the phase-volume ratio at the point of inversion is equal to the square root of the ratio of teh viscosities of the respective phases at the interface. The theoretical aspects of this relationship are studied along with its limitations.
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  • 88
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 130-144 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 89
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    AIChE Journal 10 (1964), S. 155-159 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 5 Ill.
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  • 90
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    AIChE Journal 10 (1964), S. 180-186 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Unusual heat transfer phenomena have been observed between solid surfaces and fluids near their thermodynamic critical point. To understand better these phenomena temperature and velocity profiles and local heat transfer coefficients were measured for turbulent flow of carbon dioxide in a tube at 1,075 lb/sq. in. abs. (pc = 1,071). The results indicate a severe flattening of the radial temperature profiles, a maximum in the velocity profile between the wall and the tube axis, and a maximum in h' when the bulk fluid temperature passes through the transposed critical temperature.The results can be explained qualitatively by considering the variation with temperature of thermal conductivity near the tube wall and specific heat in the turbulent core.
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  • 91
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    AIChE Journal 10 (1964), S. 197-202 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 7 Ill.
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  • 92
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    AIChE Journal 10 (1964), S. 187-193 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Turbulent mixing of a dye solution injected at the center of a pipe was studied by means of a new light probe developed for the measurement of concentration fluctuations were made both along the axial distance and across the pipe. The concentration fluctuations persisted longer at the center-line region than anywhere else; this suggested the use of the decay of intensity at the center as an upper limit. Approximately 99% of the initial intensity decayed within 7.5 ft. (30 L/d). The concentration spectra along the axial distance indicated that the eddies initially undergo a scalar energy cascade. Because of the huge difference in the kinematic viscosity and molecular diffusivities the concentration spectra extend much farther toward high wave numbers than the velocity spectrum. Apparently a state of imbalance resulted between the supply of small eddies and their dissipation; this was marked by the appearance of a small hump in the spectra. The phenomenological approximations of Corrsin and of Beek and Miller could be used for the practical problem of predicting the decay of the intensity of the concentration fluctuations or mixing in the pipe geometry studied.
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  • 93
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 202-205 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
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  • 94
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    AIChE Journal 10 (1964), S. 206-213 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The adiabatic, evaporating, two-phase flow of steam and water in horizontal pipe including the critical flow was successfully described by a system of nonlinear differential equations which include different phase velocities, fluid acceleration, wall shear forces, interface shear forces, and mass and energy transfer between the phases. The solution of the differential equations by the method of Runge-Kutta was facilitated with a high-speed digital computer. Experimental data were obtained which included void fraction measurement by X-ray attenuation and showed that the theoretical equations described the complex flow phenomena to ± 10% when radial temperature gradients were small. Design charts based on the numerical solution of the theoretical equations are presented for rapid evaluation of the flow variables for the system steam-water including critical flow for inlet pressures from 30 to 150 lb./sq.in.abs., mass flow rates per unit area from 300 to 1,000 lb./sq. ft. sec., and L/D ratios from 25 to 1,000. The critical flow is defined as the maximum flow rate for a given pressure at the point of initial vaporization and L/D ratio.
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  • 95
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964) 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 96
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 418-419 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
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  • 97
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 3-3 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 98
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 11-15 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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    AIChE Journal 10 (1964), S. 38-43 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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    AIChE Journal 10 (1964), S. 52-55 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 6 Ill.
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