ALBERT

Beschreibung: Comprehensive hydrogeochemical studies have been conducted in the Campi Flegrei volcanic aquifer since late 20th century due to the volcanic unrest. In the last decade, groundwater samples were grouped based on the dominant anion species (i.e. bicarbonate, sulfate and chloride) to explain the general hydrogeochemical processes. In this article, 44 groundwater samples are collected from Campi Flegrei aquifer to geochemically and spatially capture the main characteristics of the groundwater body. The hierarchical clustering algorithm is then performed on proportion of bicarbonate, sulfate and chloride, and the optimum number of clusters are determined regarding the results of deep hydrogeochemical investigations published in the past. The collected samples are categorized in the following groups: (1) bicarbonate-rich groundwater; (2) chlorine-rich groundwater; (3) sulfate-rich groundwater; and (4) mixed groundwater. The first group (As = 158.2 ± 169 μg/l, electric conductivity = 1,732.1 ± 1,086 μS/cm and temperature = 25.6 ± 8 ◦C) is mainly derived from poor arsenic meteoric water, but there is significant thermal/seawater contribution in the second one (As = 1,457.8 ± 2,210 μg/l, electric conductivity = 20,118.3 ± 11,139 μS/cm and temperature = 37.1 ± 20 ◦C). Interaction of the bicarbonate-rich groundwater and hydrothermal vapors gives rise to the sulfate-rich groundwater (As = 847.2 ± 679 μg/l, electric conductivity = 3,940.0 ± 540 μS/cm and temperature = 82.8 ± 3 ◦C) around Solfatara volcano. The mixed groundwater (As = 451.4 ± 388 μg/l, electric conductivity = 4,482.9 ± 4,027 μS/cm and temperature = 37.1 ± 16 ◦C) is observed where the three main groundwater groups undergo a mixing process, depending on the hydrogeology of the volcanic aquifer. Contrary to the bicarbonate- and sulfate-rich groundwater, the chlorine-rich and mixed groundwater generally occurs at low piezometric levels (approximately 〈1 m above sea level) near the coastline. The hierarchical cluster analysis provides more information about the volcanic aquifer, particularly when compositional data analysis is applied to study hydrogeochemistry of the homogeneous groundwater groups and to uncover the relationships between variables. Addressing compositional nature of data is recommended in the future studies for developing new tools that help deeper understanding of groundwater evolution in volcanic aquifers and identifying promising precursors of volcanic eruption.

Beschreibung: Published

Beschreibung: 106922

Beschreibung: 4V. Processi pre-eruttivi

Beschreibung: 2IT. Laboratori analitici e sperimentali

Beschreibung: JCR Journal

Beschreibung: Archaeological sites are extremely vulnerable to the impacts of weather-related events, which may lead to irreparable damages to cultural heritage. Here an assessment of the debris-flow hazard for the UNESCO site of Roman Villa del Casale (Italy) is carried out, through a combination of historical analyses, field surveys, geomorphological and hydrological investigations and two-dimensional hydraulic numerical modelling, all performed at river catchment scale. Historical analyses reveal that the site has been hit by several landslides in the far and recent past. This is presently confirmed by the high level of exposure to the impact of rain-triggered debris-flow events, due to the position of the Villa at a closure section of the related river basin and to the hydro- geomorphological characteristics of the basin itself. By applying the proposed approach, a scenario analysis is carried out. Results allow one to highlight the dynamics of the impact of debris flows, thanks to space and time- dependent maps about deposition areas, water depth and speed values, and to identify the most vulnerable archaeological elements within the study site. The numerical simulations are also used to test the efficiency of the existing hydraulic defense systems and to support the implementation of an early warning system for the site protection. Here, we also synthetize the design of the architecture of the wireless monitoring network, the sensor technology adopted to develop an effective real time environmental monitoring system and management plat-form, to construct a Wireless Sensor Network (WSN) - early warning and reporting system, which can be applied as a prevention measure.

Beschreibung: Published

Beschreibung: 102509

Beschreibung: 7A. Geofisica per il monitoraggio ambientale

Beschreibung: JCR Journal

Beschreibung: Innovations in virtual reality (VR) technology have led to exciting possibilities in teaching earth sciences, allowing students to experience complex geological sites that, due to cost and logistical reasons, they would not normally be able to experience. The need for high quality online digital learning resources and blended learning was brought to the forefront during the SARS-CoV-2 pandemic, as courses with a traditional physical field work component were forced to move online and provide alternatives to students. While it is unlikely that virtual field trips (VFT) would be accepted by students as a replacement of real-world fieldwork moving out of the pandemic, research shows promise that using IVR experiences can lead to enhanced learning outcomes in geosciences, warranting its inclusion on the curricula. This paper presents the outputs of a project to improve student learning in complex geological environments using VR. Here we outline a workflow that was developed to collect high resolution imagery using remote sensing to create digital outcrop models (DOM) of complex geological sites. Using this framework, this paper will then explore the use of VR for an investigation of the Husavik Triple Junction, a complex structural site in northern Iceland, explaining how the drone data was converted to a 3D DOM and demonstrating how VR can be used to simulate real world field mapping. Finally, we describe how these IVR activities have been integrated into taught modules at postgraduate level and discuss how the use of IVR experiences can complement existing geoscience curriculum design.

Beschreibung: Erasmus+ Key Action 2 funded project 2017-1-UK01-KA203-036719 3DTeLC-Bringing the 3Dworld into the classroom: a new approach to Teaching, Learning and Communicating the science of geohazards in terrestrial and marine environments coordinated by M. Whitworth. (https://ec.europa.eu/programmes/erasmus-plus/projects/eplus-projectdetails/#project/2017-1-UK01-KA203-036719and http://www.3dtelc.com) and the MIUR Project ACPR15T4_00098–Argo3D, coordinated by A. Tibaldi (http://argo3d.unimib.it/).

Beschreibung: Published

Beschreibung: 104681

Beschreibung: 1TM. Formazione

Beschreibung: JCR Journal

Beschreibung: A representative fluid sampling of surface geothermal manifestations and its analytical data quality assurance and quality control (QA/QC) are challenging aspects of understanding the geothermal reservoir processes. To achieve these goals, an interlaboratory test for the chemical analyses of ten water samples: one synthetic water, two lake waters (i.e., duplicated), one stream water, and six water samples from two geothermal wells of Los Azufres Geothermal field (LAGF), Michoacan, Mexico, was conducted. The geothermal wells were sampled at four points: (1) total discharge of condensed fluid at the wellhead, (2) separate liquid condensed in the well separator, (3) flushed liquid at the weir box, and (4) separated vapor condensed at the well-separator (data taken from Verma et al., 2022). Sixteen laboratories from ten countries reported their results. The pH, electrical conductivity, Ca2+, Li+, SO4 2 B, and Si-total measurements were 8.35 ± 0.04, 12.25 ± 0.53 mS/cm, 25 ± 1 mg/l, 18 ± 1 mg/l, 569 ± 33 mg/l, 320 ± 21 mg/l, and 20.5 ± 0.7 mg/l, which are close to the conventional true values, 8.40, 12.31 mS/cm, 23 mg/l, 19 mg/l, 647 mg/l, 330 mg/l, and 20.0 mg/l, respectively. Analytical errors for major ions, Na+, Cl

Beschreibung: Published

Beschreibung: 105477

Beschreibung: 2IT. Laboratori analitici e sperimentali

Beschreibung: JCR Journal

Beschreibung: © The Author(s), 2022. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Wiebe, P., Baumgartner, M., Copley, N., Lawson, G., Davis, C., Ji, R., & Greene, C. Does predation control the diapausing stock of Calanus finmarchicus in the Gulf of Maine? Progress In Oceanography, 206, (2022): 102861, https://doi.org/10.1016/j.pocean.2022.102861.

Beschreibung: The variability of zooplankton populations is controlled by external and internal forcing, with the former being principally large-scale changes in circulation, and the latter being driven by in situ growth, competition, and predation. Assessing the relative importance of these forcings is challenging and requires analyses of multifaceted observational data. As part of the U.S. GLOBEC Georges Bank program, a series of cruises were conducted in fall 1997, 1998, and 1999 to survey diapausing populations of Calanus finmarchicus and their predators in Wilkinson, Jordan, and Georges Basins of the Gulf of Maine. Station and underway sampling were conducted using net (1 m2 MOCNESS) and bioacoustic (BIOMAPER-II) systems, respectively, to acquire vertically stratified data for zooplankton biomass, taxonomic, size, and life-stage composition, together with associated environmental data. The results show that the autumn diapausing C. finmarchicus abundance was much lower in 1998 than in 1997 or 1999, even though the overall zooplankton biomass levels were comparable between the three years. The size frequency distribution of the diapausing individuals had a bi-modal pattern in 1997 and 1999, but a single mode in 1998, indicating the demise of an early cohort of the diapausing stock. The relative biomass and computed energy demand of potential invertebrate predators (euphausiids, decapods, medusae, and siphonophores) was found to be higher in 1998 and could account for the missing C. finmarchicus cohort. Evidence collected from this study supports the hypothesis that local predation has the potential to control the diapausing stock of C. finmarchicus in the Gulf of Maine.

Beschreibung: RJ received support from the Northeast US Shelf Long Term Ecological Research (NES-LTER) project (NSF OCE-1655686) and the US MBON Gulf of Maine project to NERACOOS (NOPP award NA19NOS0120197 and BOEMUMaine Cooperative Agreement M19AC00022) for analyzing the size data and working on the manuscript. Research support was provided by the US GLOBEC Georges Bank Program through the CILER Cooperative Agreement NA-67RJO148 (NOAA Coastal Ocean Program).

Beschreibung: This article has been accepted for publication in Geophysical Journal International ©: The Authors 2022. Published by Oxford University Press on behalf of the Royal Astronomical Society. All rights reserved. Uploaded in accordance with the publisher's self-archiving policy.

Beschreibung: Defining the regional variability of minimum magnitude for earthquake detection is crucial for planning seismic networks. Knowing the earthquake detection magnitude values is fundamental for the optimal location of new stations and to select the priority for reactivating the stations of a seismic network in case of a breakdown. In general, the assessment of earthquake detection is performed by analysing seismic noise with spectral or more sophisticated methods. Further, to simulate amplitude values at the recording sites, spectral methods require knowledge of several geophysical parameters including rock density, S-wave velocity, corner frequency, quality factor, site specific decay parameter and so on, as well as a velocity model for the Earth's interior. The simulation results are generally expressed in terms of Mw and therefore a further conversion must be done to obtain the values of local magnitude (ML), which is the parameter commonly used for moderate and small earthquakes in seismic catalogues. Here, the relationship utilized by a seismic network to determine ML is directly applied to obtain the expected amplitude [in mm, as if it were recorded by a Wood–Anderson (WA) seismometer] at the recording site, without any additional assumptions. The station detection estimates are obtained by simply considering the ratio of the expected amplitude with respect to the background noise, also measured in mm. The seismic noise level for the station is estimated starting from four waveforms (each signal lasting 1 min) sampled at various times of the day for a period of one week. The proposed method is tested on Italian seismic events occurring in 2019 by using the locations of 16.879 earthquakes recorded by 374 stations. The first results indicate that by evaluating the station noise level with 5-s windows, a representative sample of the variability in expected noise level is generated for every station, even if only 4 min of signal per day over a week of recordings is used. The method was applied to define the detection level of the Italian National Seismic Network (RSN). The RSN detection level represents a reference for the definition and application of guidelines in the field of monitoring of subsurface industrial activities in Italy. The proposed approach can be successfully applied to define the current performance of a local seismic network (managed by private companies) and to estimate the expected further improvements, requested to fulfil the guidelines with the installation of new seismic stations. This method has been tested in Italy and can be reproduced wherever the local magnitude ML, based on synthetic WA records, is used.

Beschreibung: Published

Beschreibung: 1283–1297

Beschreibung: 4T. Sismicità dell'Italia

Beschreibung: JCR Journal

Beschreibung: Carbon captured and stored in sediments and soils from vegetated tidal wetlands (mangroves, saltmarshes, freshwater and brackish marshes), where the rates of organic carbon accumulation (OC) from multiple sources is high, constitutes an active fraction of the global carbon sink (Wang et al., 2021). However, a global inventory of this coastal ‘blue carbon’ remains a challenge, as observations of accumulation rates and stock in vegetated tidal wetlands are labor intensive, expensive, scarce, and unevenly distributed, with few sediment records even for relatively well-studied temperate areas in the Northern Hemisphere (Beaumont et al., 2014). Recent reviews (Duarte et al., 2005, Wilkinson et al., 2018) report a mean carbon accumulation rate of 151 g C m yr for saltmarshes (maximum 1720 g C m yr), 41.4 g C m yr for lagoons (maximum 340 g C m yr), and 62.9 g C m yr for coastal wetlands (maximum 335.8 g C m yr) exceeding the mean burial rate of estuaries and continental shelves (17–45 g C m yr ). The accumulation of ‘blue carbon’ stored in soil and sediments within tidal wetlands, is sensitive to rapidly changing climate factors (e.g. temperature, rainfall, sea level rise, and inundation frequency), and non-climatic anthropogenic drivers (e.g. subsidence from groundwater extraction, reduction of sediment supply due to river damming, and land use change) (Pendleton et al., 2012, Macreadie et al., 2013, Arriola, 2017, Kelleway et al., 2017, Simpson et al., 2017, Ewers Lewis et al., 2018, Ruiz-Fernández et al., 2018, Cuellar-martinez et al., 2019, Macreadie and Saintilan, 2019, Negandhi et al., 2019, Rogers et al., 2019). Fast rates of relative sea level rise (RSLR) and low sediment supply are the main drivers of vertical drowning in tidal wetlands (Mariotti and Carr, 2014, Fagherazzi et al., 2020). A global review suggests that between 60 and 91% of saltmarshes will be drawing under the IPPC predicted rates of sea-level rise (Crosby et al., 2016). Carbon stable isotopic composition ( C) and C/N analysis have been used as tracers to distinguish between OC derived from autochthonous C3 and C4 saltmarsh vascular vegetation (i.e. coastal blue carbon; C 12‰ to −30‰, C/N 5.80 to 41.10; Khan et al., 2015b), and allochthonous sources including fluvial and marine particulate organic matter (POM) derived from freshwater or marine phytoplankton (C 12‰ to −30‰, C/N 5 to 9; Lamb et al., 2006), as well as past sea level indicators in coastal vegetated​ habitats in North West Europe (Wilson, 2017). Data on the spatial and historical changes of OC sources and accumulation coupled with long-term time series of climatic factors are limited for vegetated tidal wetlands in the Mediterranean, which make it hard to assess the response of OC accumulation to relative sea-level rise (RSLR) in this region. Sea level observations from satellite altimetry showed an increase in absolute sea level of 2.6 ± 0.28 mm yr across the Mediterranean Sea during the period 1993–2015, and low-lying coastal areas will be prone to marine flooding according to projections for the 21st century (Moatti and Thiébault, 2016). To better understand the spatial and temporal changes in OC accumulation and sources and assess the influence of SST and RSLR, we measured the stable isotopic composition ( C) and accretion rates in sediment records, applied the MixSIAR model to estimate the OC sources, and analyzed Sea Surface Temperature (SST) and Sea Level (SL) climatic data sets in two different tidal wetland habitats: (i) an impacted habitat affected by strong landscape and anthropogenic alterations, and (ii) an undegraded saltmarsh habitat, within a coastal lagoon (Pialassa Baiona) located in the northwestern Adriatic Sea (Mediterranean Sea).

Beschreibung: Published

Beschreibung: 102439

Beschreibung: 4A. Oceanografia e clima

Beschreibung: JCR Journal

Beschreibung: © The Author(s), 2022. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Clark, S., Hubbard, K., Ralston, D., McGillicuddy, D., Stock, C., Alexander, M., & Curchitser, E. Projected effects of climate change on Pseudo-nitzschia bloom dynamics in the Gulf of Maine. Journal of Marine Systems, 230, (2022): 103737, https://doi.org/10.1016/j.jmarsys.2022.103737.

Beschreibung: Worldwide, warming ocean temperatures have contributed to extreme harmful algal bloom events and shifts in phytoplankton species composition. In 2016 in the Gulf of Maine (GOM), an unprecedented Pseudo-nitzschia bloom led to the first domoic-acid induced shellfishery closures in the region. Potential links between climate change, warming temperatures, and the GOM Pseudo-nitzschia assemblage, however, remain unexplored. In this study, a global climate change projection previously downscaled to 7-km resolution for the Northwest Atlantic was further refined with a 1–3-km resolution simulation of the GOM to investigate the effects of climate change on HAB dynamics. A 25-year time slice of projected conditions at the end of the 21st century (2073–2097) was compared to a 25-year hindcast of contemporary ocean conditions (1994–2018) and analyzed for changes to GOM inflows, transport, and Pseudo-nitzschia australis growth potential. On average, climate change is predicted to lead to increased temperatures, decreased salinity, and increased stratification in the GOM, with the largest changes occurring in the late summer. Inflows from the Scotian Shelf are projected to increase, and alongshore transport in the Eastern Maine Coastal Current is projected to intensify. Increasing ocean temperatures will likely make P. australis growth conditions less favorable in the southern and western GOM but improve P. australis growth conditions in the eastern GOM, including a later growing season in the fall, and a longer growing season in the spring. Combined, these changes suggest that P. australis blooms in the eastern GOM could intensify in the 21st century, and that the overall Pseudo-nitzschia species assemblage might shift to warmer-adapted species such as P. plurisecta or other Pseudo-nitzschia species that may be introduced.

Beschreibung: This research was funded by the National Science Foundation (Grant Number OCE-1840381), the National Institute of Environmental Health Sciences (Grant Number 1P01ES028938), the Woods Hole Center for Oceans and Human Health, and the Academic Programs Office of the Woods Hole Oceanographic Institution.

Beschreibung: Here we discussed the results of the first geochemical investigation of the fluids (groundwater and the associated gases) emerging in the southwest of Yazd Province. We carried out two surveys, one in July 2019 and the second in September 2019s, in the region of the Gariz aquifer (central Iran).Wefocused our attention to 1) the chemistry of thewater (major and minor constituents coupled to the stable isotopes of oxygen and hydrogen), 2) the chemical composition of dissolved gases in water together with 3) the isotopic composition of Helium (3He/4He) and 4) the dissolved carbon in water (δ13CTDIC). Hydrogen and oxygen isotope values of groundwater display a fairly narrow range and indicate that the waters are of meteoric origin. On the base of the major ions chemistry, the bulk of the water samples are classified as Ca-HCO3, Ca\\Cl and Na\\Cl types. The groundwater chemistry is mainly influenced by the interaction with CO2-rich fluids, leakage of chlorinated saline water into the alluvial aquifer, and silicate dissolution. High dissolved carbon contents, mainly as bicarbonate ion, reflect the noticeable interaction of the groundwater with CO2-rich fluids. CO2 is the dominant gaseous component in most samples and its amount is always greater with respect to a water in equilibrium with the atmosphere (Air Saturated Water, ASW). Such excess of CO2 contents (more than 730 cc/l STP) dissolved in groundwater also supports the presence of a deep source of CO2-rich gas. The computed δ13C(CO2) in equilibriumwith the groundwater highlight a mixing in different proportion between an inorganic deep sourced CO2 (13C-enriched) and organic CO2 (13C-depleted). We also used the helium isotopes as a tools to figure out the origin of helium in the aquifer (air vs. mantle, and crust). The collected samples show a contribution of mantle-derived He in the Gariz aquifer up to (~45%) and the crust suggesting that at regional scale the tectonic discontinuities had a connectionwith the mantle or magmatic intrusions migrated through the crust transporting mantle volatiles to shallowcrustal layers. However, we cannot infer the timing of this possible magmatism at depth in the complex tectonic evolution of the area.

Beschreibung: Ministry of Science, Research and Technology of Iran

Beschreibung: Published

Beschreibung: 107324

Beschreibung: 1TR. Georisorse

Beschreibung: JCR Journal

Beschreibung: The needs of society and the emerging blue economy require access and integration of data and information for the construction of dedicated products. A “transparent and accessible ocean” is one of the key objectives of the Ocean Decade 2021–30. In this context, marine infrastructures become significant components of a global knowledge environment, enabling environmental assessment and providing the necessary data for scientifically valid actions to protect and restore ocean health, to use marine resources in a sustainable way. The data is collected, analyzed, organized, and used by people and their good use/reuse can be obtained with social practices, technological and physical agreements aimed at facilitating collaborative knowledge, decision-making, inference. The vision is a digital ocean data ecosystem made up of multiple, interoperable, and scalable components. The huge amount of data and the resulting products can drive the development of new knowledge as well as new applications and services. Predictive capabilities that derive from the digital ecosystem enable the implementation of services for real-time decision-making, multihazard warning systems, and advance marine space planning. The chapter develops following the progressive complexity and information content of products deriving from oceanic data: data cycle and data collections, data products, oceanic reanalysis. The chapter discusses the new challenges of data products and the complexity of deriving them.

Beschreibung: Published

Beschreibung: 197-280

Beschreibung: 4A. Oceanografia e clima

Beschreibung: © The Author(s), 2021. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Clark, S., Hubbard, K. A., McGillicuddy Jr, D. J., Ralston, D. K., & Shankar, S. Investigating Pseudo-nitzschia australis introduction to the Gulf of Maine with observations and models. Continental Shelf Research, 228, (2021): 104493, https://doi.org/10.1016/j.csr.2021.104493.

Beschreibung: In 2016, an unprecedented Pseudo-nitzschia australis bloom in the Gulf of Maine led to the first shellfishery closures due to domoic acid in the region's history. In this paper, potential introduction routes of P. australis are explored through observations, a hydrodynamic model, and a Lagrangian particle tracking model. Based on particle tracking experiments, the most likely source of P. australis to the Gulf of Maine was the Scotian Shelf. However, in 2016, connectivity between the Scotian Shelf and the bloom region was not significantly different from the other years between 2012 and 2019, nor were temperature conditions more favorable for P. australis growth. Observations indicated changes on the Scotian Shelf in 2016 preceded the introduction of P. australis: increased bottom salinity and decreased surface salinity. The increased bottom salinity on the shelf may be linked to anomalously saline water observed near the coast of Maine in 2016 via transport through Northeast Channel. The changes in upstream water mass properties may be related to the introduction of P. australis, and could be the result of either increased influence of the Labrador Current or increased outflow from the Gulf of St. Lawrence. The ultimate source of P. australis remains unknown, although the species has previously been observed in the eastern North Atlantic, and connectivity across the ocean is possible via a subpolar route. Continued and increased monitoring is warranted to track interannual Pseudo-nitzschia persistence in the Gulf of Maine, and sampling on the Scotian Shelf should be conducted to map upstream P. australis populations.

Beschreibung: This research was funded by the National Science Foundation (Grant Number OCE-1840381), the National Institute of Environmental Health Sciences (Grant Number 1P01ES028938), the Woods Hole Center for Oceans and Human Health, and the Academic Programs Office of the Woods Hole Oceanographic Institution.