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  • Articles  (7)
  • AMS dating
  • Precipitation
  • Springer  (5)
  • Cambridge University Press  (2)
  • American Institute of Physics (AIP)
  • Periodicals Archive Online (PAO)
  • 2020-2023  (4)
  • 1970-1974  (3)
  • 1935-1939
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  • Articles  (7)
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  • 1
    Publication Date: 2022-07-20
    Description: © The Author(s), 2022. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Light, C., Arbic, B., Martin, P., Brodeau, L., Farrar, J., Griffies, S., Kirtman, B., Laurindo, L., Menemenlis, D., Molod, A., Nelson, A., Nyadjro, E., O’Rourke, A., Shriver, J., Siqueira, L., Small, R., & Strobach, E. Effects of grid spacing on high-frequency precipitation variance in coupled high-resolution global ocean–atmosphere models. Climate Dynamics, (2022): 1–27, https://doi.org/10.1007/s00382-022-06257-6.
    Description: High-frequency precipitation variance is calculated in 12 different free-running (non-data-assimilative) coupled high resolution atmosphere–ocean model simulations, an assimilative coupled atmosphere–ocean weather forecast model, and an assimilative reanalysis. The results are compared with results from satellite estimates of precipitation and rain gauge observations. An analysis of irregular sub-daily fluctuations, which was applied by Covey et al. (Geophys Res Lett 45:12514–12522, 2018. https://doi.org/10.1029/2018GL078926) to satellite products and low-resolution climate models, is applied here to rain gauges and higher-resolution models. In contrast to lower-resolution climate simulations, which Covey et al. (2018) found to be lacking with respect to variance in irregular sub-daily fluctuations, the highest-resolution simulations examined here display an irregular sub-daily fluctuation variance that lies closer to that found in satellite products. Most of the simulations used here cannot be analyzed via the Covey et al. (2018) technique, because they do not output precipitation at sub-daily intervals. Thus the remainder of the paper focuses on frequency power spectral density of precipitation and on cumulative distribution functions over time scales (2–100 days) that are still relatively “high-frequency” in the context of climate modeling. Refined atmospheric or oceanic model grid spacing is generally found to increase high-frequency precipitation variance in simulations, approaching the values derived from observations. Mesoscale-eddy-rich ocean simulations significantly increase precipitation variance only when the atmosphere grid spacing is sufficiently fine (〈 0.5°). Despite the improvements noted above, all of the simulations examined here suffer from the “drizzle effect”, in which precipitation is not temporally intermittent to the extent found in observations.
    Description: Support for CXL’s effort on this project was provided by a Research Experiences for Undergraduates (REU) supplement for National Science Foundation (NSF) grant OCE-1851164 to BKA, which also provided partial support for PEM. In addition, BKA acknowledges NSF grant OCE-1351837, which provided partial support for AKO, Office of Naval Research grant N00014-19-1-2712 and NASA grants NNX17AH55G, which also provided partial support for ADN, and 80NSSC20K1135. JTF’s participation, and the SPURS-II buoy data, were funded by NASA grants 80NSSC18K1494 and NNX15AG20G.
    Keywords: Precipitation ; High-frequency precipitation ; Numerical modeling ; High-resolution models ; Coupled ocean-atmosphere models
    Repository Name: Woods Hole Open Access Server
    Type: Article
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  • 2
    Publication Date: 2021-11-26
    Description: Integrating palaeoclimatological proxies and historical records, which is necessary to achieve a more complete understanding of climate impacts on past societies, is a challenging task, often leading to unsatisfactory and even contradictory conclusions. This has until recently been the case for Italy, the heart of the Roman Empire, during the transition between Antiquity and the Middle Ages. In this paper, we present new high-resolution speleothem data from the Apuan Alps (Central Italy). The data document a period of very wet conditions in the sixth c. AD, probably related to synoptic atmospheric conditions similar to a negative phase of the North Atlantic Oscillation. For this century, there also exist a significant number of historical records of extreme hydroclimatic events, previously discarded as anecdotal. We show that this varied evidence reflects the increased frequency of floods and extreme rainfall events in Central and Northern Italy at the time. Moreover, we also show that these unusual hydroclimatic conditions overlapped with the increased presence of "water miracles" in Italian hagiographical accounts and social imagination. The miracles, performed by local Church leaders, strengthened the already growing authority of holy bishops and monks in Italian society during the crucial centuries that followed the "Fall of the Roman Empire". Thus, the combination of natural and historical data allows us to show the degree to which the impact of climate variability on historical societies is determined not by the nature of the climatic phenomena per se, but by the culture and the structure of the society that experienced it.
    Description: Published
    Description: 25
    Description: 5A. Ricerche polari e paleoclima
    Description: JCR Journal
    Keywords: Precipitation ; Roman Empire ; miracles ; Social feedbacks ; Cultural change ; climate change
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 3
    Publication Date: 2022-10-26
    Description: © The Author(s), 2021. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in [Schiller, C. M., Whitlock, C., Elder, K. L., Iverson, N. A., & Abbott, M. B. Erroneously old radiocarbon ages from terrestrial pollen concentrates in Yellowstone Lake, Wyoming, USA. Radiocarbon, 63(1), (2021): 321-342, https://doi.org/10.1017/RDC.2020.118.
    Description: Accelerator mass spectrometry (AMS) dating of pollen concentrates is often used in lake sediment records where large, terrestrial plant remains are unavailable. Ages produced from chemically concentrated pollen as well as manually picked Pinaceae grains in Yellowstone Lake (Wyoming) sediments were consistently 1700–4300 cal years older than ages established by terrestrial plant remains, tephrochronology, and the age of the sediment-water interface. Previous studies have successfully utilized the same laboratory space and methods, suggesting the source of old-carbon contamination is specific to these samples. Manually picking pollen grains precludes admixture of non-pollen materials. Furthermore, no clear source of old pollen grains occurs on the deglaciated landscape, making reworking of old pollen grains unlikely. High volumes of CO2 are degassed in the Yellowstone Caldera, potentially introducing old carbon to pollen. While uptake of old CO2 through photosynthesis is minor (F14C approximately 0.99), old-carbon contamination may still take place in the water column or in surficial lake sediments. It remains unclear, however, what mechanism allows for the erroneous ages of highly refractory pollen grains while terrestrial plant remains were unaffected. In the absence of a satisfactory explanation for erroneously old radiocarbon ages from pollen concentrates, we propose steps for further study.
    Description: This research was supported by NSF Grant No. 1515353 to C. Whitlock and sampling in Yellowstone National Park was conducted under permits YELL-SCI-0009 and YELL-SCI-5054.
    Keywords: AMS dating ; Chronology ; Contamination ; Paleoecology ; Pine
    Repository Name: Woods Hole Open Access Server
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  • 4
    Publication Date: 2022-10-26
    Description: © The Author(s), 2019. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Roberts, Mark L., Elder, Kathryn L., Jenkins, William J., Gagnon, Alan R., Xu, Li, Hlavenka, Joshua D., & Longworth, Brett E. C-14 Blank Corrections for 25-100 mu G samples at the National Ocean Sciences AMS Laboratory. Radiocarbon, 61(5), (2019): 1403-1411, Doi: 10.1017/RDC.2019.74.
    Description: Replicate radiocarbon (14C) measurements of organic and inorganic control samples, with known Fraction Modern values in the range Fm = 0–1.5 and mass range 6 μg–2 mg carbon, are used to determine both the mass and radiocarbon content of the blank carbon introduced during sample processing and measurement in our laboratory. These data are used to model, separately for organic and inorganic samples, the blank contribution and subsequently “blank correct” measured unknowns in the mass range 25–100 μg. Data, formulas, and an assessment of the precision and accuracy of the blank correction are presented.
    Description: This work is supported by a Cooperative Agreement (OCE-1755125) with the U.S. National Science Foundation.
    Keywords: AMS ; AMS dating ; Blank corrections
    Repository Name: Woods Hole Open Access Server
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Journal of molecular evolution 4 (1974), S. 85-97 
    ISSN: 1432-1432
    Keywords: Enantiomers ; Optical Activity ; Precipitation ; DL-Asparagine ; Enrichment of Enantiomers ; Asymmetry
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Summary The paper presents some experiments which were aimed at the demonstration of enrichment of enantiomer substances by precipitation from saturated racemic solutions. As a working hypothesis we searched for a possible very small “asymmetry effect” that might by observable during precipitation if the solubilities of enantiomer components were affected. Crystallization of a small fraction out of a bulk of racemate would lead to an amplification of an elementary effect which by itself would have escaped any direct experimental verification. We chose DL-asparagine-monohydrate in aqueous solution as the system to be investigated. — Of particular interest is the result that below 7.5 °C the yield of D-asparagine seems to exceed that of L-asparagine in the precipitate, while above 8 °C the opposite is true. This qualitative result is confirmed by extrapolation of experimental data gained from precipitation of non-racemic asparagine solutions — at least for a crystallization temperature of 0 °C.
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  • 6
    ISSN: 1432-0827
    Keywords: Amorphous ; Apatite ; Electron Microscopy ; Crystallization ; Precipitation ; Calcium
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Medicine , Physics
    Description / Table of Contents: Résumé Du phosphate de calcium amorphe (ACP) sèché peut se présenter sous forme discoide ou sphérique. Les particules discoides sont plus fréquents dans les specimens d'ACP sèché, isolés immédiatement après précipitation. Les formes sphériques dominent dans les specimens sèchés provenant de suspensions plus âgés. Les particules discoides résultent de la dessication de l'échantillon. Les sphères peuvent aussi se produire pendant la dessication, mais s'observent aussi dans la solution. Les disques et les sphères ont une origine commune sous la forme d'un agrégat d'ACP hautement hydraté de morphologie inconnue. La formation d'apatite cristallin en solution est intimement associée avec l'ACP. Les premiers cristaux apparaissent à la surface des sphères amorphes et en contact avec les disques amorphes. En cas de sphères, les cristaux initiaux augmentent de taille et forment de nouveaux cristaux par nucléation secondaire jusqu'à ce que les sphères soient enrobées par l'apatite. Cependant, lorsque la transformation est totale, l'apatite ne remplit pas l'espace occupé préalablement par les sphères amorphes dissoutes. Ces observations ne confirment pas le concept d'une conversion d'un état solidein situ dans ce cas mais suggèrent une transition hétérophasique d'un processus de translocation ionique par l'intermédiaire d'une solution. La production de cristaux dans les disques amorphes suggère que l'apatite peut aussi se former directement du précurseur dans la solution.
    Abstract: Zusammenfassung Getrocknetes amorphes Calciumphosphat (ACP) kann scheiben- und kugelförmig auftreten. Die scheibenförmigen Partikel herrschen in getrockneten ACP-Proben vor, welche direkt nach der Fällung isoliert wurden. Die kugeligen Formen herrschen in trockenen Proben aus älteren Suspensionen vor. Die Scheibenbildung ist ein Ergebnis des Trocknungsvorganges. Kugelige Formen können beim Trocknungsvorgang ebenfalls auftreten, sie sind aber in der nativen Suspension ebenfalls anwesend. Scheiben- und Kugelformen scheinen einen gemeinsamen Vorläufer in der Lösung zu haben, welcher ein hochhydratisiertes ACP-Aggregat unbekannter Morphologie zu sein scheint. Die Bildung von kristallinem Apatit in der Lösung steht in engem Zusammenhang mit ACP. Die ersten Kristalle erscheinen auf der Oberfläche der amorphen Kugeln und in Kontakt mit den amorphen Scheiben. Die ursprünglichen Kristalle auf den Kugeloberflächen nehmen an Größe zu und bilden durch sekundäre Nukleation weitere Kristalle, bis die Kugeln in Apatit eingehüllt werden. Wenn die Umwandlung abgeschlossen ist, füllt jedoch das Apatit den Platz nicht aus, der vorher von den aufgelösten amorphen Kugeln eingenommen wurde. Diese Beobachtungen bekräftigen die Auffassung einerin situ-Umwandlung in den festen Zustand bei dem beschriebenen Falle nicht, sondern deuten auf eine heterophasischen Übergang, welcher durch einen lösungsbedingten Ionenverschiebungs-Prozeß gefördert wird. Das Auftreten von Kristallen in den amorphen Scheiben deutet darauf hin, daß sich Apatit auch direkt aus dem Lösungsvorläufer bilden kann.
    Notes: Abstract Dried amorphous calcium phosphate (ACP) can exist in discoidal and spheroidal forms. The disk-shaped particles are most prominent in dried ACP specimens isolated immediately following precipitation. The spherical forms become dominant in dried specimens taken from older suspensions. The disk-like morphology is a result of sample drying. Spherules can also arise during the drying step but are present in the native suspension as well. Both the disks and spherules appear to have a common solution progenitor in the form of a highly hydrated ACP aggregate of unknown morphology. The formation of crystalline apatite in solution is intimately connected with ACP. The first crystals appear on the surface of the amorphous spherules and in contact with the amorphous disks. In the case of the spherules, the initial crystals increase in size and generate additional crystals by secondary nucleation until the spherules become enveloped by apatite. However, when conversion is completed, the apatite does not fill appreciably the space previously occupied by the dissolved amorphous spherules. These observations do not support the concept of anin situ solid state conversion in this case, but indicate a heterophase transition supported by a solution-mediated ion translocation process. The occurrence of crystals in the amorphous disks suggest that apatite can also form directly from the solution progenitor.
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  • 7
    Electronic Resource
    Electronic Resource
    Springer
    Calcified tissue international 10 (1972), S. 82-90 
    ISSN: 1432-0827
    Keywords: Calcium ; Phosphate ; Precipitation ; Kinetics ; Chemistry
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Medicine , Physics
    Description / Table of Contents: Résumé La cinétique de la formation et de la transformation des précipités de phosphate de calcium, obtenus en mélangeant de volumes égaux de solutions à 6×10−3 M de calcium total et/ou phosphate total est étudiée à 25°C. Les solutions de phosphate sont préajustées à un pH de 7.4. Les changements de pH et de turbidité des solutions sont suivis simultanément en fonction du temps. Les précipités sont isolés à des intervalles de temps variables et caractérisés par diverses méthodes physico-chimiques. Initialement un précipité avec un rapport molaire Ca/P de 1.5, amorphe aux rayons X et en diffraction électronique, est formé. Le spectre IR indique la présence de PO 4 3− et de HPO 4 2− . Après une période métastable, on observe la précipitation d'un matériel cristallin dans ou sur la phase amorphe. Vingt quatre heures après préparation de l'échantillon les précipités présentent surtout les caractères du phosphate octocalcique.
    Abstract: Zusammenfassung Die Kinetik der Bildung und Transformation von Calciumphosphat-Niederschlägen wurde bei 25°C untersucht. Es wurden dazu gleiche Volumen von Lösungen gemischt, bei einer Konzentration von 6×10−3M totales Calcium und/oder totales Phosphat. Die Phosphatlösungen wurden zuerst auf pH 7,4 eingestellt. Veränderungen des pH und Trübung der Lösungen wurden gleichzeitig als eine Funktion der Zeit aufgezeichnet. Niederschläge wurden in verschiedenen Zeitintervallen isoliert und mit verschiedenen physiko-chemischen Methoden charakterisiert. Am Anfang wurde ein Niederschlag mit einem molaren Ca/P-Verhältnis von 1,5, im Röntgenbild und in der Elektronendiffraktion amorph, gebildet. Infrarotspektren deuteten die Anwesenheit von PO 4 3− - und HPO 4 2− -Ionen an. Nach einer metastabilen Periode erfolgte ein Niederschlag aus kristallinem Material innerhalb oder auf der amorphen Substanz. 24 Std nach der Herstellung der Proben zeigten die Niederschläge in der Hauptsache die Charakteristiken von Octocalciumphosphat.
    Notes: Abstract The kinetics of the formation and transformation of calcium phosphate precipitates obtained by mixing equal volumes of solutions, 6×10−3 M in total calcium and/or total phosphate was investigated at 25°. The phosphate solutions were preadjusted to pH 7.4. Changes of the pH and turbidity of the solutions were followed simultaneously as a function of time. Precipitates were isolated at various time intervals and characterized by different physicochemical methods. Initially a precipitate with a molar Ca/P ratio of 1.5, amorphous to X-ray and electron diffraction was formed. IR spectra indicated the presence of PO 4 3− and HPO 4 2− ions. After a period of metastability, precipitation of a crystalline material within or upon the amorphous matter occurred. Twenty four hours after sample preparation the precipitates showed mainly the characteristics of octacalcium phosphate.
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