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  • 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas  (5)
  • Elsevier  (5)
  • American Geophysical Union (AGU)
  • Cell Press
  • MDPI Publishing
  • Springer Nature
  • Springer Science + Business Media
  • 2010-2014  (5)
  • 2010  (5)
Collection
Publisher
Years
  • 2010-2014  (5)
Year
  • 1
    Publication Date: 2020-11-13
    Description: The main effect of magma-carbonate interaction on magma differentiation is the formation of a silica-undersaturated, alkali-rich residual melt. Such a desilication process was explained as the progressive dissolution of CaCO3 in melt by consumption of SiO2 and MgO to form diopside sensu stricto. Magma chambers emplaced in carbonate substrata, however, are generally associated with magmatic skarns containing clinopyroxene with a high Ca-Tschermak activity in their paragenesis. Data are presented from magma-carbonate interaction experiments, demonstrating that carbonate assimilation is a complex process involving more components than so far assumed. Experimental results show that, during carbonate assimilation, a diopside-hedenbergite-Ca-Tschermak clinopyroxene solid solution is formed and that Ca-Tschermak/diopside and hedenbergite/diopside ratios increase as a function of the progressive carbonate assimilation. Accordingly, carbonate assimilation reaction should be written as follows, taking into account all the involved magmatic components: CaCO3solid+SiO2melt+MgOmelt+FeOmelt+Al2O3melt → (Di-Hd-CaTs)sssolid+CO2fluid The texture of experimental products demonstrates that carbonate assimilation produces three-phases (solid, melt, and fluid) whose main products are: i) diopside-hedenbergite-Ca-Tschermak clinopyroxene solid solution; ii) silica-undersaturated CaO-rich melt; and iii) C-O-H fluid phase. The silica undersaturation of the melt and, more importantly, the occurrence of a CO2-rich fluid phase, must be taken into account as they significantly affect partition coefficients and the redox state of carbonated systems, respectively.
    Description: TRIGS Project “Sixth Framework Programme of the European Commission and to the New and Emerging Science and Technology Pathfinder". Project FIRB MIUR “Development of innovative technologies for the environmental protection from natural events”.
    Description: Published
    Description: 503-514
    Description: 3V. Proprietà chimico-fisiche dei magmi e dei prodotti vulcanici
    Description: JCR Journal
    Description: open
    Keywords: carbonate assimilation ; skarns ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
    Publication Date: 2017-04-04
    Description: The 2002–03 flank eruption of Etna was characterized by two months of explosive activity that produced copious ash fallout, constituting a major source of hazard and damage over all eastern Sicily. Most of the tephra were erupted from vents at 2750 and 2800 m elevation on the S flank of the volcano, where different eruptive styles alternated. The dominant style of explosive activity consisted of discrete to pulsing magma jets mounted by wide ash plumes, which we refer to as ash-rich jets and plumes. Similarly, ash-rich explosive activity was also briefly observed during the 2001 flank eruption of Etna, but is otherwise fairly uncommon in the recent history of Etna. Here, we describe the features of the 2002–03 explosive activity and compare it with the 2001 eruption in order to characterize ash-rich jets and plumes and their transition with other eruptive styles, including Strombolian and ash explosions, mainly through chemical, componentry and morphology investigations of erupted ash. Past models explain the transition between different styles of basaltic explosive activity only in terms of flow conditions of gas and liquid. Our findings suggest that the abundant presence of a solid phase (microlites) may also control vent degassing and consequent magma fragmentation and eruptive style. In fact, in contrast with the Strombolian or Hawaiian microlite-poor, fluidal, sideromelane clasts, ash-rich jets and plumes produce crystal-rich tachylite clasts with evidence of brittle fragmentation, suggesting that high groundmass crystallinity of the very top part of the magma column may reduce bubble movement while increasing fragmentation efficiency.
    Description: Published
    Description: 110-122
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Description: JCR Journal
    Description: reserved
    Keywords: Etna ; basaltic explosive activity ; ash-rich jet and plume ; tachylite ; sideromelane ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 3
    Publication Date: 2017-04-04
    Description: Magmatic processes triggering eruptions at Campi Flegrei caldera (southern Italy) and their relationships with the widespread emissions of fluids and caldera unrest episodes, are poorly constrained. The 4.1 ka B.P. Agnano–Monte Spina eruption, the reference event for a future large-size explosive eruption at Campi Flegrei, was investigated to shed light, through melt inclusion and isotope analyses, on the geochemical processes operating in the plumbing system. Chemical and isotopic data on whole rocks and glasses suggest that at least two magma batches mixed during the course of the eruption. Melt inclusion data highlight the pre-eruption storage conditions of two magmatic end-members. One end-member is like the less differentiated (shoshonitic) Campi Flegrei erupted magma, while the other could be a residual of the Neapolitan Yellow Tuff magma. Mixing between these two components was driven by a large gas phase which sustained the ascent of magmas of deep provenance. The H2O and CO2 contents in pyroxene-hosted melt inclusions yield entrapment pressures between 107 and 211 MPa, corresponding to depths between 4 and 8 km. The degassing trends reveal two extreme patterns. One pattern, already documented in the literature, is the volatile signature of poorly differentiated magmas ascending from more than 8 km depth, while the other is related to a gas-dominated magma, flushed by a CO2-rich gas phase partly released from the deep reservoir. This study provides a conceptual frame for unrest phases at Campi Flegrei, such as the 1982–84 event. Uplift phases can be related to closed-system ascent of magmas and fluids from more than 8 km depth, and their emplacement at shallow levels. This leads the shallow system to store, and then progressively release, the accumulated gas. In this view, both unrest episodes and eruptions could be strongly influenced by both the achievement of a critical upper limit of gas storage in the shallow magmatic reservoir and the stress and fracturing state of the roof rocks. The present results help to constrain the pre-eruptive conditions expected at Campi Flegrei caldera in case of a future large-size eruptive event.
    Description: In press
    Description: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Description: 4.3. TTC - Scenari di pericolosità vulcanica
    Description: JCR Journal
    Description: reserved
    Keywords: Sr and Nd isotopes ; Melt inclusions ; Gas flushing ; Magma mixing ; Bradyseismic crises ; Explosive eruptions ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 4
    Publication Date: 2017-04-04
    Description: Pantelleria Island, located in the Sicily Channel Rift Zone (Italy), is the type locality for the peralkaline rhyolitic rocks called pantellerites. In the last 50 ka, after the large Green Tuff caldera-forming eruption, volcanic activity at Pantelleria has consisted of effusive and explosive eruptions mostly vented inside and along the rim of the caldera and producing silicic lava flows, lava domes and poorly dispersed pantelleritic pumice fall deposits. Basaltic cinder cones and lava flows are only present outside the caldera in the NW sector of the island. The most recent basaltic (Cuddie Rosse, 20 ka) and pantelleritic (Cuddia Randazzo and Cuddia del Gallo, 6 ka) pyroclastic products were sampled to investigate magmatic volatile contents through the study of melt inclusions. The melt inclusions in pyroxene and olivine phenocrysts of Cuddie Rosse scoriae have an alkali basalt composition. The dissolved volatiles comprise 0.9–1.6 wt.% H2O, several hundred ppm of CO2, 1600–2000 ppm of sulphur and 500–900 ppm of chlorine. The water–carbon dioxide couple gives a confining pressure 2 kbar prior to the eruption. This result indicates that episodes of magma ponding and crystallization occurred in the upper crust prior to eruption. The melt inclusions in feldspar, fayalite and aenigmatite phenocrysts of Cuddia del Gallo and Cuddia Randazzo pumice have a pantelleritic composition (Agpaitic Indices 1.3–2.1), up to 4.4 wt.% H2O, 8700 ppm Cl, 6000 ppm F, and CO2 below the detection limit. Sulphur averaging 420 ppm has been measured in Cuddia Randazzo melt inclusions. These data indicate relatively high volatile contents for these low-energy Strombolian-type eruptions. Melt inclusions in Cuddia del Gallo pumice show the most evolved composition (Agpaitic Indices 2–2.1) and the highest volatile content, in agreement with fluid saturation conditions in the magma chamber prior to the eruption. This implies a confining pressure of 1 kbar for the top of the pantelleritic reservoir. The composition of melt inclusions and mineralogical assemblage of Cuddia Randazzo pumice indicate that it has a lower evolutionary degree (Agpaitic Indices 1.3–1.8) and lower pre-eruptive Cl and H2O contents than Cuddia del Gallo pumice. An increase in pressure due to the exsolution of volatiles in the upper part of the pantelleritic reservoir may have triggered the Cuddia del Gallo explosive eruption. Evidence of widespread pre-eruptive mingling between trachytes and pantellerites suggests that the intrusion of trachytic magma into the pantelleritic reservoir likely played a major role in destabilizing the magma system just prior to the Cuddia Randazzo event.
    Description: In press
    Description: 2.3. TTC - Laboratori di chimica e fisica delle rocce
    Description: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Description: JCR Journal
    Description: reserved
    Keywords: Pantelleria ; peralkaline ; volatiles ; melt inclusions ; eruptive style ; 04. Solid Earth::04.04. Geology::04.04.05. Mineralogy and petrology ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 5
    Publication Date: 2017-04-04
    Description: The compositional variation of clinopyroxene and the partitioning ofmajor elements between clinopyroxene and melt are estimated as a function of the cooling rate. Clinopyroxenes were crystallized under variable cooling regimes (15, 9.4, 3, 2.1, and 0.5 °C/min from1250 down to 1000 °C) and at isothermal conditions of 1000 °C from a basaltic composition at a pressure of 500 MPa under anhydrous and hydrous (H2O=1.3 wt.%) conditions. The clinopyroxene chemistry shows that, as the cooling rate increases, crystals are progressively depleted in Ca,Mg, Fe2+ and Si and enriched inNa, Fe3+, Al (mainlyAlIV), and Ti. Di andHd versus CaTs and CaFeTs forma continuous binary solid solution characterized by higher amounts of tschermakitic componentswith increasing cooling rate. Two parameters (DH=Di+Hd and TE=CaTs+CaFeTs+En) are calculated to describe the effect of cooling rate on the clinopyroxene composition. The variation of DH/TE with increasing cooling rate evidences the kinetic process induced by rapid cooling in basic rocks under hydrous and anhydrous conditions. Dynamic crystallization conditions affect the partitioning of major elements between clinopyroxene and melt; with increasing cooling rate, the value of crystal–melt partition coefficient departs from that obtained at the isothermal condition. However, in spite of these variations, the values of cpx–meltKdFe–Mg remain almost constant. Therefore, the Fe2–Mg exchange between clinopyroxene and melt is not suitable to prove the (dis)equilibrium conditions in basaltic coolingmagmas, giving rise to possiblemismatches in the application of thermobarometers. The results of our study are consistentwith that observed at themargin of dikes or inthe exterior portions of lavas, where the cooling rate is maximized and disequilibrium compositions of clinopyroxene have been found.
    Description: Published
    Description: 302-312
    Description: 2.3. TTC - Laboratori di chimica e fisica delle rocce
    Description: JCR Journal
    Description: reserved
    Keywords: cooling rate ; clinopyroxene ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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