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  • Other Sources  (116)
  • Univ. Bremen  (66)
  • Copernicus Publications (EGU)  (50)
  • American Institute of Physics (AIP)
  • Institut für Meereskunde
  • Nature Publishing Group (NPG)
  • 2010-2014  (116)
  • 1985-1989
  • 2010  (116)
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  • 2010-2014  (116)
  • 1985-1989
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  • 1
    Publication Date: 2021-03-29
    Description: Lambert, cosmological letters, fixed stars, nebulae, island universe, teleology, teleological, enlightenment, enlightened, romanticism, romantic, hypothesis, physical-teleological, speculation, imagination, stability, solar system, cosmology, astronomy, comet, magic, alchemy, pietism, science, arts, philosophy, Newtonian. - Johann Heinrich Lamberts Cosmological Letters was published 1761 in Augsburg. Lambert tried to expose a theory of the structure of the universe as a whole, that is, a theory that was able to involucrate all sorts of observed celestial bodies, like 'fixed stars' und nebulae. Lambert tackles his task mixing two disciplines, which in principle seem to be incompatible: Newtonian physics and teleology. Lambert's speculative and imaginative way to formulate his hypotheses shows resemblances to the way of making science developed during the romantic period, disagreeing with the methods of enlightenment, movement to which Lambert is usually associated. A central aspect of this thesis is to study Lambert's figure in relation to this two traditions, with the finality to deal with the compression of his ideas in depth, in light of the transition between the enlightened vision of the world and the romantic one.
    Description: thesis
    Keywords: 520 ; TA 100 ; TA 400 ; Theoretische Grundlagen {Astronomie} ; Wissenschaftsgeschichte {Astronomie}
    Language: German
    Type: monograph , publishedVersion
    Format: 302 S.
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  • 2
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    Univ. Bremen
    Publication Date: 2017-06-09
    Description: The different benthic foraminiferal species (epibenthic as well as endobenthic) colonize wide areas of the ocean floor and are widely used for paleoceanographic reconstructions. To improve these reconstructions, it is an important part in research to continuously develop and refine proxies by e.g. improving measuring techniques as well as introducing other species in paleoceanograhpy. The main focus of the presented thesis is a regional examination of the trace element ratios of the rarely used benthic foraminifer Oridorsalis umbonatus and the investigation of their suitability for paleoceanographic applications. Since O. umbonatus is not very abundant in the sediments, it was necessary . as a prerequisite for such studies . to investigate, whether laser ablation ICP-MS can be used for trace element measurements on benthic foraminifera. Therefore, as a first step, trace elements were measured using laser ablation ICP-MS on a set of modern core top samples collected along a depth transect on the continental slope off Namibia at 25.5.S (320 . 2300m water depth; 2.9. to 10.4.C). The Mg/Ca ratios where than calibrated against bottom water temperatures (BWT). The study demonstrates clearly that benthic foraminiferal trace elements can be reliably measured with the laser ablation technique and that the Mg/Ca ratio of O. umbonatus has the potential to be used as a proxy for BWTs...
    Description: thesis
    Keywords: 579.44 ; 579.44 ; UHG 000 ; VXE 000 ; UHG 000 ; VXE 000 ; Paläoozeanologie ; Protozoa {Paläozoologie}
    Language: English
    Type: monograph , publishedVersion
    Format: 81 S.
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  • 3
    Publication Date: 2017-06-09
    Description: In the early 1990`s the first IPCC report stated the effect of anthropogenic CO2 emissions on global warming and John Martin`s Iron Hypothesis (Martin and J.H 1990), relating atmospheric dust deposition, a major source of iron to the surface ocean, to the CO2 concentration in the atmosphere and the last ice age, culminating in the well known sentence Give me (half) a tanker of iron and I’ll give you a new ice age!. Since then, several large-scale in situ Fe fertilisation experiments revealed that in large areas of the ocean, the so called high nutrient low chlorophyll (HNLC) areas, phytoplankton growth is partly limited by depleted Fe conditions (Geider et al. 1994; De Baar and Boyed 2000; Boyd et al. 2007). The ocean receives Fe from upwelling, riverine input, melting icebergs, atmospheric dust input, input from anoxic sediments, hydrothermal vents and direct recycling by organisms(Tovar-Sanchez et al. 2007). However, in HNLC regions the Fe input to surface waters is very low resulting in Fe limitation of phytoplankton growth. Fe is an important nutrient for marine phytoplankton (Geider et al. 1994; Falkowski et al. 1998; Morel and Price 2003), being essential in metabolic reactions like the photosynthetic electron transport and the assimilation of nitrogen. It is also required for the synthesis of chlorophyll (Martin et al. 1988; Maldonado et al. 1999) as well as for the functioning of the enzyme superoxide dismutase which inhibits the breakdown of chlorophyll by superoxide radicals (Coale 1991)...
    Description: thesis
    Keywords: 577.14 ; VJE 000 ; VJC 210 ; VJE 000 ; VJC 210 ; Organische Geochemie ; Geochemie des Meerwassers
    Language: English
    Type: monograph , publishedVersion
    Format: 106 S.
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  • 4
    Publication Date: 2021-03-29
    Description: Mg/Ca ratios in benthic foraminiferal shells are frequently used in paleoceanographic studies to estimate past bottom water temperatures. Apart from temperature, other factors may exert additional influences on foraminiferal Mg/Ca. These include the Mg/Ca ratio of seawater, partial dissolution of shell calcite, salinity, physiological effects, and, probably of capital importance, the carbonate chemistry of seawater. In this context, the seperate effects of temperature and seawater carbonate chemistry on the magnesium incorporation into benthic foraminideral calcite are unraveled and quantified in this thesis...
    Description: thesis
    Keywords: 579.44 ; 579.44 ; 560 ; VXE 000 ; VJE 220 ; VXE 000 ; VJE 220 ; Protozoa {Paläozoologie} ; Geochemie der Fauna
    Language: English
    Type: monograph , publishedVersion
    Format: 88 S.
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  • 5
    Publication Date: 2021-03-29
    Description: Organic-walled dinoflagellate cysts, oxidation, degradation, organic matter. - Species-selective aerobic decomposition affects fossil organic-walled dinoflagellate cyst (dinocyst) records and hence dinocyst-based interpretations of primary productivity and oceanographic conditions. However, since the recognition of dinocyst species sensitive and resistant to oxic degradation (S- and R-cysts, respectively) it has become apparent that R-cysts may still serve as reliable productivity and oceanographic conditions proxies. On the other hand S-cysts provide a way to quantify aerobic degradation of organic matter (OM) and past bottom-water O2 concentrations. OM degradation plays a key role in global carbon cycling and is important for global climate change. Therefore dinocysts are a valuable tool for estimating the rate of diagenetic process. Questions concerning species-selective aerobic degradation still remain and will be adressed here. To obtain information on the rate of S-cyst decomposition, the relationship between S-cyst degradation and O2 concentrations, and the aerobic degradation of extinct dinocyst species, a natural exposure experiment has been conducted and studies of both Quaternary and pre-Quaternary material from sediment cores were executed. The exposure experiment was conducted in the natural setting of the Eastern Mediterranean. During a 15 month exposure period to oxic water masses, concentrations of S-cysts (Brigantedinium spp. and Echinidinium granulatum) decreased by 24 to 57%. However, taxa such as Nematosphaeropsis labyrinthus, Echinidinium aculeatum, Operculodinium israelianum and Impagidinium aculeatum demonstrated a slight increase in concentration, indicating resistance to aerobic degradation. These results show that even short-term exposure to oxygen may cause considerable changes in the dinocyst assemblage ...
    Description: thesis
    Keywords: 560 ; VVA 560 ; VXE 000 ; VVA 560 ; VXE 000 ; Aktuopaläontologie ; Protozoa {Paläozoologie}
    Language: English
    Type: monograph , publishedVersion
    Format: 159 S.
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  • 6
    Publication Date: 2021-03-29
    Description: Marine snow, underwater cameras, particle flux, aggregation, suspended particulate matter, particle transport. - This study focusses on the vertical distribution and transportation pathways of marine particles off NW-Africa with aid of optical methodologies. A profiling camera system and a remotely operated vehicle (ROV) was used for in-situ observations on the distribution, transport processes and sinking behaviour of marine particulate matter. Between the regional areas of investigation Cape Blanc, Dakhla and Cape Bojador significant differences could be observed with respect to distribution and transportation patterns. These differences are primarily related to the different primary production conditions between the investigation areas. Primary production is the most important factor for the abundance of particulate matter, where highest particle concentrations in the entire water column were seen off Cape Blanc. Next to primary production, water depth, currents and density gradients are factors influencing the particle distribution patterns. With respect to the prevailing transport processes, the Cape Blanc region is characterised by vertically orientated transport patterns. In addition to the continuous supply of large, relatively fast sinking particle aggregates a sinking event could be documented for the first time in-situ in the water column. These events deliver huge amounts of particulate matter from the ocean surface ...
    Description: thesis
    Keywords: 551
    Language: English
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  • 7
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    Univ. Bremen
    Publication Date: 2021-03-29
    Description: The dissolution kinetics of gypsum and anhydrite have been measured under various conditions. For gypsum an almost linear rate equation R=ks1(1-c/ceq)n1 is valid, where R is the surface rate, n1 1 is the kinetics order, c is the total calcium concentration at the surface, and ceq the equilibrium concentration with respect to gypsum. For the determination of the entire dissolution kinetics a batch set-up was used. This batch experiment reveals a dissolution rate equation R=ks1(1-c/ceq)n1 which switch close to equilibrium to a nonlinear rate equation R=ks2(1-c/ceq)n2 with n2 4.5. The experimentally observed dissolution rates from the batch experiment could be fitted by only minor variations with a mixed kinetics model. The rotating disk experiment on anhydrite reveals a surface controlled rate equation. For anhydrite the observed experimentally dissolution rates by a batch experiment are described by R=ks(1-c/ceq})n, where ks is the surface rate constant and n 4.2 is the kinetic order. Furthermore, a method for the determination of the rate equation parameters was developed ...
    Description: thesis
    Keywords: 549 ; VJK 000 ; VHB 600 ; VGC 000 ; Experimentelle Geochemie ; Sulfate, Chromate, Molybdate und Wolframate {Mineralogie} ; Mineralchemie
    Language: German
    Type: monograph , publishedVersion
    Format: 120 S.
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  • 8
    Publication Date: 2021-03-29
    Description: Madagascar; Jurassic; Karoo; Gondwana; Breakup; Rift; Microfauna; Macrofauna; Ammonites; Indian Ocean. - The breakup of Gondwana along the former East African Orogen is widely interpreted to have lasted from the Late Palaeozoic to the Callovian. The present study indicates that the Permian-Triassic or Karoo phase of rifting was not responsible for the separation of East- and West-Gondwana, since that rift system failed in the Late Triassic. Instead the breakup of Gondwana occurred in the Late Liassic. The pre-rift phase in the Morondava Basin is represented by the Karoo deposits, and the syn-rift phase is recorded by Toarcian marine shales, locally overlain by Aalenian sandstones. A major Early Bajocian unconformity is interpreted as the breakup unconformity. The initial post-rift or drift phase is represented by the Bajocian-Bathonian carbonates, marls and sandstones of coastal plain environment and a coastal barrier/lagoon complex. During the Bathonian the siliciclastic shoreface system moved basinward. Callovian-Early Kimmeridgian shales with interbedded iron-oolites represent ...
    Description: thesis
    Keywords: 551 ; VAE 500 ; VDB 100 ; VEQ 300 ; Geotektonische Entwicklung der Erdkruste {Geologie} ; Gondwana ; Madagaskar {Geologie}
    Language: English
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  • 9
    Publication Date: 2021-03-29
    Description: Turbulence, ice ridge, polynja, drag coefficient. - Polarstern (PS) cruise ARK XII led into the Laptev Sea and into the Kara Sea. Measurements of atmospheric processes within the polar surface layer were performed by a turbulence probe mounted at the bow crane of the ship.The meteorological conditions during the cruise were characterised by moderate winds and low temperature differences between the atmosphere and the underlying surface.Detailed information about the variation of meteorological parameters and of the surface fluxes were achieved as a function of the surface characteristics. The measurements are used to analyse ...
    Description: thesis
    Keywords: 551.5 ; VAQ 990 ; TYZ 400 ; TVH 500 ; Meereis {Glaziologie} ; Nordpolarmeer {Meteorologie und Klimatologie} ; Temperatur der Wasseroberfläche als meteorol. Element
    Language: German
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  • 10
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    Univ. Bremen
    Publication Date: 2021-03-29
    Description: thesis
    Keywords: 551.9 ; VJE 200 ; VJC 210 ; Geochemie Lebender Materie ; Geochemie des Meerwassers
    Language: English
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  • 11
    Publication Date: 2021-03-29
    Description: thesis
    Keywords: 560 ; VYF 200 ; Pyrrophyceae {Paläobotanik}
    Language: English
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  • 12
    Publication Date: 2021-03-29
    Description: thesis
    Keywords: 551 ; VAQ 990 ; Meereis {Glaziologie}
    Language: German
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  • 13
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    Univ. Bremen
    Publication Date: 2021-03-29
    Description: This thesis describes the adaptive shallow water model PLASMA-FEMmE. It solves on the sphere the shallow water equations, the prototype for partial differential equations in atmospheric modeling, using a semi-implicit semi-Lagrangian time step and linear finite elements. Both statically and dynamically adapted grids created by the grid generator amatos are investigated. The results are compared with those of the predecessor model FEMmE that uses a static uniform grid. The outcome demonstrates the capability of the chosen approach as well as its limits. Grid adaptation can easily be achieved with amatos. No reflexions at the grid interfaces are observed. Though in one test case instabilities are released at the grid interfaces. The numerical errors are reduced without a considerable enhancement of the computational effort in another test case with a well-known analytical solution. In respect to the conservation properties the results are more complicated. Mass conservation can be achieved in one test case with an appropriate static grid. In case of complex flow regimes all conservation properties are weakened during the simulation using dynamic grid adaptation...
    Description: thesis
    Keywords: 532.5 ; 551.46 ; 550 ; Meteorologische Modelle ; Fluiddynamik {Geophysik}
    Language: English
    Type: monograph , publishedVersion
    Format: 135 S.
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  • 14
    Publication Date: 2021-03-29
    Description: The polar ice sheets are unique paleoclimatic archives and play an important role in recent and future climate. The melting of the big freshwater reservoirs will not only increase the global sea level, but will also influence the ocean currents. Therefore, it will be of particular interest to improve the currently available numeric climate models to achieve more accurate statements about climatic change and its consequences. In this work, the evaluation and the different applications of GPS and altimetry data will be described in respect to enhance models. The antarctic area of investigation, Dronning Maud Land (DML), is of particular interest for German polar research, because both the overwintering station Neumayer and the summer station Kohnen are located within it. In the surroundings of these two stations, highly accurate kinematic GPS measurement were made, which will be the basis for the digital elevation model presented here. Because these data are spatially limited, they are supplemened with remotely sensed data. For this purpose, two airborne altimetry data sets and spaceborne laser altimetry data of the Ice, Cloud, and land Elevation Satellite (ICESat) are used...
    Description: thesis
    Keywords: 551.312 ; 551 ; 550 ; TWC 600 ; VAR 980 ; TQI 000 ; TSY 200 ; Geophysikalische Satellitenfernerkundung ; Antarktis {Geophysik}
    Language: English
    Type: monograph , publishedVersion
    Format: 140 S.
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  • 15
    Publication Date: 2021-03-29
    Description: Marine sediments, diagenesis, anoxic environments, paleomagnetism, low-temperature magnetism, magnetic Fe-Ti-Oxides. - Magnetic particles usually occur in very minor concentrations in igneous and sedimentary rocks, soils, volcanic ashes, dusts and even in living organisms. Many of these magnetic grains are capable of carrying a stable permanent magnetization and therefore act as recorders of the recent and ancient Earth's magnetic field. Thus paleomagnetism refers to the study of this remanent magnetization in sedimentary and volcanic rocks through time. From this magnetization, directional intensity information can be recovered concerning the geomagnetic field that prevailed at the sample location at the time of the rock formation. The magnetic parameter on which such paleomagnetic studies are based is the natural remanent magnetization (NRM). In continental margin regions the remanence acquisition process is often complicated by post-depositional modifications of the original magnetic material. After deposition magnetic minerals can be altered or new magnetic phases can be formed. Consequently the original NRM might be obscured or even fully erased. The process of diagenesis and authigenesis may thus seriously compromise paleomagnetic interpretation. Therefore our knowledge of the geomagnetic field behavior based on sediment records from continental margin regions remains limited. To obtain fully reliable information about the geomagnetic field or paleoenvironmental conditions from continental margin regions, the effect of early diagenetic processes occurring after deposition of the sediment must be understood in detail.
    Description: thesis
    Keywords: 551.4686 ; 538.727 ; 550 ; TOT 320 ; VKB 380 ; TSZ 100 ; Paläomagnetismus {Geophysik} ; Sedimente bestimmter Regionen ; Atlantischer Ozean {Geophysik}
    Language: English
    Type: monograph , publishedVersion
    Format: 113 S.
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  • 16
    Publication Date: 2021-03-29
    Description: Anaerobe Oxidation of Methane, AOM, methanotrophy, stable isotope labeling, stable isotope probing, carbon assimilation, flow-through columns, ANME, Seep-SRB, Gullfaks, Tommeliten. - Anaerobic oxidation of methane (AOM) performed by consortia of methanotrophic archaea (ANME) and sulfate reducing bacteria (SRB) is the major sink of methane in marine sediments. This thesis describes methane consumption at two of the most active North Sea cold seeps (Gullfaks, Tommeliten), their microbial community and the resulting lipid biomarker patterns. Experiments in flow-through setups are presented, focusing on physiological parameters of AOM activity such as different methane and sulfate concentrations and on the tolerance of AOM to starvation periods. The roles of inorganic carbon (DIC) and methane as carbon sources for the microbial community performing AOM were examined combining stable isotope probing and lipid biomarker analyses. For archaea substantial uptake of carbon from DIC and methane was found, indicting a novel carbon assimilation pathway. Biomass from SRB was exclusively labeled by DIC indicating a methane dependent, but autotrophic growth consortial SRB.
    Description: thesis
    Keywords: 551.9
    Language: English
    Type: monograph , publishedVersion
    Format: 153 S.
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  • 17
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    Univ. Bremen
    Publication Date: 2021-03-29
    Description: Black Sea, seafloor seepage, mud volcanoes, seeps, fluid migration, gas hydrates, diapirs. - The Black Sea is the worldwide largest anoxic basin with thick gas rich sediments facilitating seafloor seepage, which is widely distributed along the continental slopes of the Black Sea. In two areas, the Sorokin Trough off Crimea and at the continental slope off Batumi (Georgia), the distribution, structure and evolution of two different vent systems and their relation to fluid migration pathways and gas/gas hydrate occurrences have been investigated by means of high resolution multichannel seismic data. In both regions, the distribution of seafloor seepage is controlled by fluid migration along permeable pathways associated with diapiric uplift in the subsurface. In the Sorokin Trough, seepage is expressed by intensive material upflow and the formation of mud volcanoes; offshore Batumi, gas seeps with low material flux dominate. In the Sorokin Trough, most mud volcanoes are associated with near-subsurface mud diapirs. The great morphological variability of the mud volcanoes reflects different driving mechanisms, which depend on the availability of permeable fluid migration pathways and the depositional environment. A 3D seismic dataset images the detailed three-dimensional ...
    Description: thesis
    Keywords: 551.466 ; 550 ; TSZ 100 ; VAT 300 ; VEZ 120 ; TQC 600 ; Atlantischer Ozean {Geophysik} ; Geologie des Meeresboden ; Randmeere {Geologie} ; Tiefseeseismik {Geophysik}
    Language: English
    Type: monograph , publishedVersion
    Format: 154 S.
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  • 18
    Publication Date: 2021-03-29
    Description: Ozone, balloon-borne measurements, atmospheric trace gases, concentration profiles, climate change. - In the frame of this work, a new small-size balloon-borne sonde was developed. A miniature grating spectrometer in the sonde measures simultaneously the solar spectral irradiance at a wide wavelength range from 200 to 850. As a first application, ozone profiles have been determined by measuring the changes in the spectral irradiance, caused by ozone absorption in the Huggins band. The wide spectral coverage of the spectrometer offers the possibility for measurements of other trace gases which absorb within the wavelength range, e.g. NO2 and BrO. The low weight of the new sonde (1.7 kg), the moderate price, and the autonomous portable telemetry system makes it a very versatile tool for satellite validation and for case studies, which requires a high number of launches. The newly developed sonde works well without temperature stabilisation, even so the spectrometer experiences rather large temperature changes (15 - 20 K) during the ascent through the atmosphere. Laboratory measurements were performed in ...
    Description: thesis
    Keywords: 551.5 ; 551.8 ; 550
    Language: English
    Type: monograph , publishedVersion
    Format: 148 S.
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  • 19
    Publication Date: 2021-03-29
    Description: Photooxidants play an important role for the oxidation capacity of the troposphere. The presented work deals with seasonal changes of atmospheric photooxidants like hydrogen peroxide (H2O2), methylhydroperoxide (MHP) and formaldehyde (HCHO). The principal purpose was to follow and quantify the mixing-ratios of these photochemical species for the first time over a complete annual cycle in Antarctica. During two field campaigns at the German Antarctic station Neumayer (overwintering campaign from January 1997 until March 1998 and a shorter campaign from January to March 1999) continuous measurements of atmospheric mixing-ratios were performed. A continuous wet-chemical technique was used for peroxides and formaldehyde sampling and analysis. Species were quantified by fluorescence detection. In order to compare the results and measurements with well-known reaction mechanisms a photochemical box model was applied. The obtained time series show a pronounced seasonal variation with higher values during summer. For the first time atmospheric concentrations of H2O2, MHP and HCHO were documented during polar night in winter. The mixing-ratios were significantly higher than expected due to missing actinic radiation essential for photochemical production. Trajectory analyses and calculations with a three-dimensional model showed that during winter the mixing-ratios of photooxidants are mainly affected by long-range transport in the free troposphere. Investigations during the Antarctic ó́zone hole period ́́show no significant impact of the increased UV-B radiation on the photooxidants. The findings of this work contribute to a better understanding of the photochemistry of the investigated trace gases in the clean troposphere of Antarctica and provide a useful data record for further photochemical modeling.
    Description: thesis
    Keywords: 551.5 ; 551.9 ; 550 ; TYY 200 ; TVA 210 ; Antarktis {Meteorologie und Klimatologie} ; Chemische Zusammensetzung der Atmosphäre {Meteorologie}
    Language: German
    Type: monograph , publishedVersion
    Format: 176 S.
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  • 20
    Publication Date: 2021-03-29
    Description: Besides measurements of atmospheric trace gases and laboratory studies of chemical reactions, modelling has been recognised to be of increasing importance to improve our knowledge of the atmosphere and the capabilities of photochemical models. Main scope of this work was the development of a photochemical atmospheric model, which was especielly designed for the interpretation of Differential Optical Absorption measurments (DOAS). This model has been used to improve our knowledge of atmospheric chemistry. For example, for the first time it was possible to demonstrate that a significant amount of IO in a range of 0.65 to 0.8 pptv is present in the stratosphere in the polar region (Ny-Alesund,Spitzbergen). Moreover it has been shown that such amounts of stratospheric IO lead to an additional Ozone loss in the range of 10 % in cold arctic winters.
    Description: thesis
    Keywords: 551.5 ; 550 ; TUA 700 ; TVA 210 ; Verfahren zur Untersuchung der freien Atmosphäre {Meteorologie} ; Chemische Zusammensetzung der Atmosphäre {Meteorologie}
    Language: German
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  • 21
    Publication Date: 2021-03-29
    Description: Ozone profile retrieval, ERS-2, GOME, FURM, ozone decline, Northern hemisphere. - Measurements of stratospheric ozone over the Northern hemisphere forthe winter/spring periods of 1997 to 2000 taken with the GOMEinstrument were used to derive the chemical ozone depletion inside thepolar vortex. GOME onboard the ERS-2 satellite measures radiationcoming from the Earth in the UV/vis spectral range.To discern the chemical depletion from dynamical influences, a modelwas developed to calculate vortex averaged diabatic descent ratesusing the radiative transfer model MIDRAD and the FURM ozoneprofiles. The permeability of the Arctic vortex was analysed by usingthe trajectory model TANGO in conjunction with a reverse domainfilling algorithm, developed within the framework of this thesis.The chemical ozone ...
    Description: thesis
    Keywords: 551.5 ; 550 ; TUA 850 ; TVA 210 ; TY 100 ; Satellitenmeteorologie ; Chemische Zusammensetzung der Atmosphäre {Meteorologie} ; Nördliche Hemisphäre {Meteorologie und Klimatologie}
    Language: German
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  • 22
    Publication Date: 2021-03-29
    Description: Sea ice is a very important component of the climate system. While the Arctic sea ice extent has retreated during the past 20 years, it has remained constant in the Antarctic. In order to better understand the role of sea ice in the climate system in the context of global warming currently used coupled Atmosphere-Ocean Global Circulation Models have to be improved. This requires to know the sea ice concentration C for a long period for both hemispheres and at the best possible spatial resolution. Currently used methods to obtain C like the NASA Team (NT) algorithm are based on data acquired by the Special Sensor Microwave/Imager (SSM/I) at 19 and 37GHz. The SEA LION (SL) algorithm presented here allows to infer C from the polarization P at 85GHz taking advantage of the higher spatial resolution at this frequency. However, the decrease of P caused by the weather influence leads to an overestimation of C. Therefore, P is corrected using a radiative transfer model and atmospheric data taken from Numerical Weather Prediction models and/or derived from SSM/I measurements. The various sea ice and snow properties are considered calculating monthly sea ice tie points. The average standard deviation of C derived with the SL algorithm is 12% for C 〈 50% and below 5% for C 〉 90%. The SL ice edge agrees within 10km with the one evident in VIS/IR images. The SL ice concentration gradient across the marginal ice zone (MIZ) agrees much better with the one evident in SAR images compared to results of the NT algorithm. Using the higher spatial resolution at 85GHz the SL algorithm allows to detect smaller open water areas than known algorithms. A major limitation of the SL algorithm arises from the quality of atmospheric data needed for the weather correction. A spatial resolution of these data lower than the 85GHz SSM/I channels and/or a time lag larger than half an hour between both data sets can cause relative errors above 100%, particulary in the cloud-covered parts of the MIZ.
    Description: thesis
    Keywords: 550.28 ; 551.31 ; 550 ; TWH 500 ; TWC 100 ; Einfluss von Eis {Klimatologie} ; Instr. Ergebn. zu Klimaänderungen und Klimaschwankungen
    Language: English
    Type: monograph , publishedVersion
    Format: 186 S.
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  • 23
    Publication Date: 2021-03-29
    Description: Ozone chemistry, tracer measurements, radiometry, airborne,submillimeterwave, Arctic, stratosphere. - The Airborne Submillimeter Radiometer (ASUR) is a passive heterodyne instrument using a superconducting detector with an instrumental frequency range from 604.3 to 662.3 GHz.Operating onboard an aircraft to avoid absorption by tropospheric water vapor key species of the stratospheric ozone chemistry can be detected for a vertical altitude range from 15 to 55 km. In the winter 1999/2000 the ASUR instrument participated in the THESEO 2000/SOLVE project onboard the NASA research aircraft DC-8. Three deployments were carried ...
    Description: thesis
    Keywords: 551.5 ; 550 ; TUA 800 ; TVA 210 ; TYY 100 ; Radarmeteorologie ; Chemische Zusammensetzung der Atmosphäre {Meteorologie} ; Arktis {Meteorologie und Klimatologie}
    Language: German
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  • 24
    Publication Date: 2021-03-29
    Description: thesis
    Keywords: 551.5 ; 550 ; TUA 850 ; TUA 500 ; TVA 210 ; Satellitenmeteorologie ; Meteorologische Modelle ; Chemische Zusammensetzung der Atmosphäre {Meteorologie}
    Language: German
    Type: monograph , publishedVersion
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  • 25
    Publication Date: 2021-03-29
    Description: WSDW, water mass spreading, numerical model, lagrangian trajectories, Weddell Scotia Confluence. - The deep Scotia Sea is filled with ventilated Weddell Sea Deep Water (WSDW). This in turn is an essential contributor to the ventilation of the World Ocean abyss. A primitive equation, hydrostatic, ocean general circulation model (BRIOS1.1) with terrain-following coordinate is used to investigate the water mass export from the Weddell Sea. The model is circumpolar focusing on the Weddell Sea, with particularly high resolution (2̃0 km) in the DOVETAIL area. The northern limb of the Weddell Gyre exhibits an eastward Weddell Sea Deep Water transport across 44ʿW of 24 Sv. Export rates of Weddell Sea Deep Water through gaps in theSouth Scotia Ridge are estimated to be 6.4 Sv with a semi-annual cycle of ± 0.6 Sv, which can be correlated to atmospheric cyclone activity and Weddell Gyre strength. Sensitivity studies considering extreme sea ice conditions in the Weddell Sea show higher (lower) exports in years of minimum (maximum) winter sea ice extent. This can be attributed to the local change of the surface stress achieved by wind and ice. Lagrangian ...
    Description: thesis
    Keywords: 910 ; QGZ 420 ; UKG 200 ; Physische Geographie der Antarktis ; Teilfragen {Regionale Ozeanologie, Südpolarmeer}
    Language: German
    Type: monograph , publishedVersion
    Format: 142 S.
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  • 26
    Publication Date: 2021-03-29
    Description: Carbon export; SeaWiFS; variability; upwelling; Atlantic Ocean; chlorophyll filament; SeaWiFS; SST. - The North Atlantic off NW Africa is characterized by the trade wind induced upwelling of cold and nutrient rich waters. As one of most strongest eastern boundary upwelling areas it is marked by low sea surface temperature and high bio-production, both subject to strong seasonal and interannual variations.Satellite measurements of sea surface temperature (SST) and chlorophyll-a (Chl-a) in the upper water-column were used to (a) recognize the upwelling of deep water and its distribution and mixing in the surface, (b) identify the development of phytoplankton blooms and (c) provide further insights in the characteristics of its variations.Measurements of surface Chl-a were compared to deep-sea fluxes of organic carbon in order to determine the relationship between both parameters and to further calculate the export of Corg and the export variation strength.The off-shore extension of SST-defined upwelling from 1988 through 1999 between 18ʿ and 25ʿN shows maxima in January and May/June with an average area of 140,000 km2 (standard deviation of 20,000 km2). Minima in August exhibit an extension of 43,000 km2 (15,000 km2 standard deviation). A correlation between ...
    Description: thesis
    Keywords: 910 ; UKB 100 ; Nordatlantik {Regionale Ozeanologie}
    Language: English
    Type: monograph , publishedVersion
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  • 27
    Publication Date: 2021-03-29
    Description: Thermohaline circulation, variability, energy and moisture balance model, paleoceanography. - Freshening of high latitude surface water can change the large scale oceanic transport of heat and salt. Consequently, atmospheric and sea ice perturbations over the deep water production sites excite a large scale response establishing an oceanic t̀̀eleconnection'' with time scales of years to centuries. To study these feed-backs, an atmospheric energy and moisture balance model (EMBM), predicting the heat and fresh water fluxes at the surface, and a thermodynamic sea ice model were constructed and coupled to the GFDL ocean model MOM2. The heat and moisture transports by transient eddies in the EMBM are parameterized by diffusion. The coupled model reproduces many aspects of today's oceanic circulation. The most interesting features of the coupled model are the sensitivity of the thermohaline circulation to changes in the configuration, the multidecadal variability in the ocean-sea ice system, and the behaviour of the thermohaline circulation during transitions between glacial and interglacial periods. A very strong thermohaline circulation develops in the coupled system that is not evident in the stand-alone ocean model. An interesting aspect of this behaviour is the existence of a maximum strength in the overturning. Beyond this maximum, evaporation in the subtropics cannot balance the northward salt-transport. As a result, the watermasses over the deep water production sites become fresher, leading to a collapse of the thermohaline circulation. The associated changes in the sea ice cover prevent the system to recover. ...
    Description: thesis
    Keywords: 551.6 ; 550 ; QDC 200 ; Synoptische Klimageographie ; Wärme- und Strahlungshaushalt der Atmosphäre {Meteorologie} ; Statistische Klimatologie und Klimatologische Modelle ; Klimaänderungen
    Language: German
    Type: monograph , publishedVersion
    Format: 132 S.
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  • 28
    Publication Date: 2021-03-29
    Description: This study focuses on the interactions between climate and ice sheets in order to obtain a better understanding of the processes involved. Two periods in the geological past are explored; the Middle Miocene and the mid-Pliocene. For both periods, foraminiferal oxygen-isotope records from deep-sea sediment cores as well as stratigraphical data, suggest a global sea-level lowering. The magnitude of these reductions in sea level indicate large-scale ice-sheet build-up. However, the origin of these events and even the geographic locations of the ice sheets, are still under discussion. The ice sheet-climate model developed in this study provides a tool to test some of the hypotheses brought forward to explain the ice-sheet expansion events. It describes the Antarctic ice sheet and is forced by a climate component based on energy and mass balances. Further more, the model computes the oxygen-isotopic composition of the ice-sheet, thereby providing the possibility to compare numerical results directly to deep-sea sediment records. Numerical experiments focus on the interactions between atmospheric CO2, temperature, ice volume (sea-level equivalent) and the isotopic composition of sea water...
    Description: thesis
    Keywords: 551.69 ; 551 ; 550 ; TWC 600 ; VAR 980 ; Paläoklimatologie ; Antarktis {Glazialgeologie}
    Language: English
    Type: monograph , publishedVersion
    Format: 137 S.
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  • 29
    Publication Date: 2021-03-29
    Description: The Late BarremianLate Aptian interval was characterised by several major changes in the ocean/climate system related to the onset of the Mid-Cretaceous greenhouse world. North Africansedimentary deposits offer excellent archives of the ecological changes on the southern Tethyscontinental margin during this time interval. In the present phD thesis sedimentology, palaeontology,biostratigraphy, chemostratigraphy, and geochemistry are combined to reconstruct the palaeoenvironmental evolution and sea-level changes of the Tunisian carbonate platform margin.Respect is paid to major palaeoceanographic and palaeoclimatic events including the late Early Aptian Oceanic Anoxic Event 1a (OAE 1a) and two time intervals associated with widespread carbonate platform drowning in the early- and mid-Late Aptian. The last chapter deals with the cephalopod fauna of the platform margin. Results of the detailed regional investigations are compared to global marine palaeoenvironments and discussed in a broad geological context...
    Description: thesis
    Keywords: 551.77 ; 551 ; 550 ; TWC 600 ; VKB 372 ; VEN 130 ; VDH 300 ; Paläoklimatologie ; Karbonatische Sedimentgesteine ; Tunesien {Geologie} ; Kreide
    Language: English
    Type: monograph , publishedVersion
    Format: 160 S.
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  • 30
    Publication Date: 2021-03-29
    Description: ICP-MS, Time of Flight, laser ablation, solid and liquid samples, ice cores, Antarctica, mineral dust, trace element analysis. - The analysis of the inorganic composition of climatic archives provides proxies for climate reconstruction. For many applications commercially available inductively coupled plasma quadrupole mass spectrometry (ICP-Q-MS) systems are used for investigations. One aim of this thesis was to test the laser ablation (LA)-ICP-Q-MS method for the analysis of different sample matrices (polar ice cores, bivalves, frozen lake sediment cores). The main limitation of LA-ICP-Q-MS measurements is the number of analysed isotopes, especially for point scan analysis of embedded particles in the ice matrix and the analysis of growth bands of bivalve shells. Analysing as many isotopes as possible is of interest to deduce e.g. the corresponding source region of embedded particles in the ice matrix. The quasi-simultaneous detection of several isotopes of transient signals is realised in ICP-Time of Flight-MS (ICP-TOF-MS) systems. The applicability of the newly developed ICP-TOF-MS system for ice core analysis in climatic research was explored in this thesis. With the present experimental setup the analysis of trace elements in ice core samples is only possible for liquid samples. The accuracy and precision compares to well established ICP-Q-MS systems. Using the Aridus II as sample introduction system the signal sensitivity was 2-10 times lower for the ICP-TOF-MS compared to ICP-Q-MS systems. Calibration studies and investigation of reference materials showed that the calibration range is limited to an order of magnitude of about 10exp4 to 10exp5 except for m/z ratios between 23 amu and 72 amu where it is even lower. The observed ...
    Description: thesis
    Keywords: 551.6 ; VJA 240 ; TWC 100 ; TWC 500 ; VAR 980 ; Spektroskopische Verfahren {Geochemie} ; Instr. Ergebn. zu Klimaänderungen und Klimaschwankungen ; Klimaschwankungen und Klimaänderungen im Quartär ; Antarktis {Glazialgeologie}
    Language: English
    Type: monograph , publishedVersion
    Format: 185 S.
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  • 31
    Publication Date: 2021-03-29
    Description: Sea-ice, Finite Element Sea-Ice Model, Kalman Filter, Data Assimilation. - The Arctic region is sensitive to climate change. Since the Arctic sea-ice cover influences the surface heat budget of the Earth the observed sea-ice decline is seen as an indication of global warming. Furthermore, the dynamics of sea ice plays an important role for the sea-ice mass distribution in the Arctic, for the production of dense, cold, and salty water in the Arctic Ocean, which contributes to the thermohaline circulation, and also for the freshwater budget of the Nordic Seas. Thus, a realistic description of sea-ice motion is important to draw conclusions for the mass transport and sea-ice mass distribution. The Finite-Element Sea-Ice Model simulates the large-scale physical sea-ice processes like the sea-ice growth and circulation realistically. The model domain covers the entire Arctic Ocean and its marginal seas. Together with the Singular Evolutive Interpolated Kalman (SEIK) Filter and remotely sensed sea-ice drift observations this sea-ice model is applied for data assimilation to investigate details of the sea-ice dynamics. So far, drift assimilation has been carried out to analyze and modify only the drift field with subsequent computation of the advection or redistribution of ice mass which corresponds more to the physical model behavior than a statistical analysis that the SEIK Filter provides. The sea-ice drift data assimilation with the SEIK Filter achieves drift modification and furthermore changes in the two other sea-ice variables concentration and thickness. The modifications of these "unobserved variables" (within the meaning of data assimilation) are validated and it is found that they are in good agreement for at least 2 months for the sea-ice thickness and even 4 months for the sea-ice concentration which is the longest period examined. The drift improvement is achieved due to the sea-ice concentration and ...
    Description: thesis
    Keywords: 551 ; 550 ; VAQ 990 ; VAQ 500 ; TVH 100 ; TOY 000 ; Meereis {Glaziologie} ; Gletscherbewegung und Gletscherschwankungen ; Wärme- und Strahlungshaushalt der Atmosphäre {Meteorologie} ; Energiebilanzen in der Geodynamik {Geophysik}
    Language: German
    Type: monograph , publishedVersion
    Format: 141 S.
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  • 32
    Publication Date: 2021-03-29
    Description: Tectonics, marine geophysics, plate-tectonic reconstruction, new zealand, antarctica, seismic refraction/wide-angle reflection, Gondwana break-up. - The last supercontinent fell into pieces with the break-up of Gondwana. In this context, the separation of the microcontinent of New Zealand from Antarctica is a jigsaw puzzle of many pieces. Its parts lay at the convergent margin of East Gondwana, which changed into a divergent margin within a geologically short time. That is why the microcontinent of New Zealand experienced different tectonic regimes and phases of the Wilson cycle. Although it is a good object of investigation due to its changing history, remarkably little is known about the submerged parts of the microcontinent. Knowledge of the magmatic-tectonic development of the submarine plateaux such as Campbell Plateau and Chatham Rise will improve the understanding of the processes that led to the late Gondwana break-up, and, in turn, lead to better reconstructions of East Gondwana, as Zealandia is a key piece in plate-kinematic reconstructions of this part of Gondwana. The central part of this thesis deals with the separation process of Zealandia from Antarctica leading to an improved reconstruction of New Zealand with emphasis on the submarine plateaux. Bounty Trough separating Chatham Rise from Campbell Plateau, and the Great South Basin separating Campbell Plateau from the South Island are investigated with seismic refraction and reflection methods. They are interpreted jointly with magnetic and gravity data. The results of crustal thickness modelling based on satellite gravity data are combined with existing information about crustal thickness of Zealandia. With these data ...
    Description: thesis
    Keywords: 551.136 ; 550 ; TST 000 ; Ozeanien {Geophysik} ; Pazifischer Ozean {Geophysik} ; Geotektonische Entwicklung der Erdkruste {Tektonik}
    Language: German
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  • 33
    Publication Date: 2021-03-29
    Description: Dinoflagellate cysts, paleoceanography, paleoenvironment, Late Quaternary, Norwegian-Greenland Sea. - Dinoflagellate cysts have been investigated in nine short sediment cores as well as two long sediment cores from the Norwegian-Greenland Sea and the North Atlantic to reconstruct the surface water paleoenvironment of the last climatic cycle and the Holocene. Holocene sea-surface temperatures and salinities during summer and winter and the extent of sea-ice cover were reconstructed. On the Rockall Plateau, higher cyst concentrations indicating favourable conditions and increased productivity only occur during parts of stage 5, 4-2, and the Holocene. Only sparse occurrences of dinocysts have been observed in the Norwegian-Greenland Sea before 10000 yr BP. Later, high abundances of O. centrocarpum and N. labyrinthus indicate the increased inflow of relatively warm Atlantic. A change in dominance of these species as well as a distinct increase in cyst concentrations marks the onset of the recent circulation system. In the Norwegian Sea, O. centrocarpum dominates the assemblages since about 7000 yr BP, while assemblages in the Iceland and the Greenland Sea are more complex due to the influence of different surface currents.
    Description: thesis
    Keywords: 560
    Language: German
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  • 34
    Publication Date: 2021-03-29
    Description: Slope stability, submarine slides, Svalbard, Arctic Ocean, Sophia Basin. - With increasing interest in slope stability issues on continental shelves the causes and trigger mechanism of submarine slides get more and more into the scientific focus. Within the ESF EUROMARGINS project 'Slope Stabilities on Europe's passive continental Margin' (SPACOMA) sediment dynamics of megaslides along the passive continental margin north of Svalbard have been investigated. The study concentrated on identification and sedimentological characterisation of megafailure events, their dating and interpretation in relation to paleoceanography and climate history of the Svalbard archipelago. Integrated interpretation of multibeam bathymetric, sediment-penetrating acoustic (PARASOUND) and seismic data shows a multiple slope failure on the northern European continental margin, north of Spitsbergen. One huge submarine slide has been identified which was first described by Cherkis et al. (1999) - the Yermak Slide (later named Hinlopen/Yermak Megaslide). The extent of the Hinlopen/Yermak Megaslide has been revised based on new acoustic and detailed bathymetric data. Details from the side's internal structure give evidence for one main slide event followed by repeated minor events. The first slide event occurred during MIS 3 around 30 cal. kyr. BP and was characterised by highly dynamic and rapid evacuation of ca. 1.250 kmÃÂđ of sediment from the lower to the upper part of the shelf slope. During this megaslide event, headwalls up to 1600 m have been created and ca. 1150 kmÃÂđ material from hemipelagic sediments and from the lower preexisting trough mouth fan has been entrained and transported into the semi-enclosed Sophia Basin. This megaslide was followed by a secondary evacuation of debris material to the Nansen Basin accomplished by funnelling of the debris through the Littke Channel between Polarstern Seamount and the adjacent continental slope. The main slide debris is overlain by a set of fining-upwards sequences as evidence for the associated suspension cloud and ...
    Description: thesis
    Keywords: 551.307 ; 551.69 ; 551 ; Nordatlantische Polarinseln {Geologie} ; Sedimente bestimmter Regionen ; Sonstige Sedimentationsprozesse ; Paläoklimatologie
    Language: English
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  • 35
    Publication Date: 2021-03-29
    Description: Sea ice, surface emissivity, emitting layer temperature, temperature profile, microwave radiometry. - Polar regions play a key role in the global climate. The information on atmospheric parameters in these regions is sparse. Among the polar surfaces, sea ice varies in extent and physical properties with region and season and so does the surface emissivity. In the present study a method to retrieve the emissivity is applied over two selected regions in the Arctic, one covered by first-year ice and the other by multiyear ice and it investigates the application of them in the improvement of temperature profile retrieval ver sea ice. The retrieval of surface emissivity is done by combining simulated brightness temperatures with the satellite measured brightness temperature. In order to determine the surface emissivity of sea ice, the observations of the microwave instruments amsu (Advanced Microwave Sounding Unit) and amsr-e (Advanced Microwave Scanning Radiometer- Earth Observing System) are used. Determination of emissivity requires the knowledge of the temperature of the emitting layer. The penetration depth of microwaves in sea ice varies between millimeters and decimeters depending on the frequency and micro-physical structure. A year-round observation of temperature profiles of sea ice from the Surface Heat Budget of the Arctic Ocean (sheba) campaign at a first-year and a multiyear ice site is used to derive a set of coefficients a and b to linearly relate ...
    Description: thesis
    Keywords: 551.343 ; VAQ 990 ; VAQ 100 ; Meereis {Glaziologie} ; Gletscheruntersuchungen im Allgemeinen
    Language: English
    Type: monograph , publishedVersion
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  • 36
    Publication Date: 2021-03-29
    Description: Reflection seismics, sediment drifts, bottom currents. - The region south of South Africa has been a crucial gateway for large scale Thermohaline Circulations since late Eocene times. Here, three of the most important currents for maintaining the global heat exchange, namely the warm and surface related Agulhas Current (AC), and the cold and denser North Atlantic Deep Water (NADW) as well as the Atlantic Bottom Water (AABW), flow around South Africa. Due to the special tectonic and geologic situation, a huge amount of the deep and bottom water masses that flow around South Africa have to pass the narrow Agulhas Passage, located between the South African continental shelf and the submarine Agulhas Plateau. As a result, the sedimentary infill of the Transkei Basin, which is located east of the Agulhas Plateau, has been predominantly influenced by NADW and AABW activity since ~36 Ma. Via the analysis of this sedimentary infill, a palaeo current reconstruction of (proto-) NADW and (proto-) AABW revealed changing flow paths and flow strengths since then. These variations in current attributes were triggered by large scale effects, such as the opening of the Tasman Gateway and the Drake Passage in the Late Eocene, or the closure of the Isthmus of Panama in the Pliocene. A more detailed analysis of the Transkei Basin's depocentre locations and interface outlines resulted in a palaeo flow path reconstruction for this region. Moreover, palaeo climate conditions from the Late Cretaceous were partially reconstructed ...
    Description: thesis
    Keywords: 551.462 ; 551.69 ; 550 ; TSZ 100 ; Atlantischer Ozean {Geophysik}
    Language: German
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  • 37
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    Univ. Bremen
    Publication Date: 2021-03-29
    Description: Ice, microstructures, subgrain boundaries, recrystallization, flow, deformation. - The primary objective of this thesis is the investigation of microstructures obtained from samples from the EPICA Dronning Maud Land ice core from Antarctica. The goal is to gain understanding of deformation processes an deformation-related recrystallization mechanisms using these structures. The structures are visualized with the new microstructure mapping method using the preferred sublimation along defect regions in the crystal. This method enables observation in high resolution as well as overview over a significant sample volume. In order to provide unambiguous proof of their deformational origin and to offer interpretation and characterization, experimental reproduction of the microstructural features are performed using creep tests. Subgrain boundaries and grain-boundary morphology are identified as the most direct effects of deformation and recrystallization processes, which are still easily observable. They can be used additionally to the conventional parameters (grain size, crystal-orientation distribution) to determine these mechanisms. Different sbugrain-boundary types observed in experimentally deformed samples as well as in natural ice indicate several formation processes. Results obtained from this new and novel data suggest a profound reconsideration of the classical tripartition of recrystallization regimes described in the literature in ice sheets. Instead, dynamic recrystallization in two of its forms (rotation recrystallization and strain-induced migration recrystallization) dominates the microstructure evolution in all depth regions of the EDML ice core. Results of systematic microstructure analysis of creep-test samples demonstrate ...
    Description: thesis
    Keywords: 551.312 ; 548.842 ; 551 ; 550 ; VAE 140 ; VAQ 100 ; Gesteinsdeformation {Strukturgeologie} ; Gletscheruntersuchungen im Allgemeinen
    Language: German
    Type: monograph , publishedVersion
    Format: 129 S.
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  • 38
    Publication Date: 2021-03-29
    Description: The hyperspectral UV-vis-NIR spectrometer SCIAMACHY will be launched aboard the European satellite Envisat. Its limb measurements will provide vertically resolved profiles of trace gases and other atmospheric parameters. No retrieval algorithms and radiative transfer models have been established for these measurements yet.In this thesis, a unique, fast radiative transfer model for UV-vis-NIR limb radiances has been developed, implemented, and validated. It takes into account the sphericity of the atmosphere and up to two orders of scattering and surface reflection. The weighting functions for all parameters are calculated from analytical formulae. A realistic instrument model with field-of-view integration and signal-to-noise computation and retrieval algorithms have also been implemented. All have been combined in the new program package SCIARAYS. The package has been applied for the characterisation of the limb measurements in several ways:The simulated weighting functions agree well with those due to full multiple scattering. Thus they may be used to calculate theoretical precision estimates and averaging kernels. In conformance with this, test retrievals with approximate weighting functions converge correctly. Therefore, the approximate weighting functions of SCIARAYS are well suited for retrievals from SCIAMACHYś limb measurements.Detailed theoretical retrieval precisions have been calculated for SCIAMACHYś trace gas targets. The conclusion is that a UV-vis-NIR limb sensor like SCIAMACHY is well suited for studying the vertical structure of the stratosphere and also of the upper troposphere above cloud top.Further investigations show that the vertical resolution of retrievals from SCIAMACHYś limb measurements can be improved beyond its geometrical limits. As a trade-off for better vertical resolution, the retrieval precision gets worse. Thus O3 profile features with 1km vertical extent will be detectable with a precision of 20-30%.
    Description: thesis
    Keywords: 551.5 ; 550.28 ; 550 ; TUA 850 ; TQI 000 ; TVA 210 ; Satellitenmeteorologie ; Geophysikalische Satellitenfernerkundung ; Chemische Zusammensetzung der Atmosphäre {Meteorologie}
    Language: English
    Type: monograph , publishedVersion
    Format: 247 S.
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  • 39
    Publication Date: 2021-03-29
    Description: GIS, Geoinformatik, Spatial Theory, Face Intersection, Polygon Clipping, Diagramatic Reasoning. - A Geographic Information System (GIS) is used to handle, analyse and visualize ‘facts’ of the ‘real world’. These ‘facts’ are assumed to be spatial in the sense that they are located at the earth’s surface. The first chapter outlines that the recent success of applied GIS is based on this ‘real world’ approach, which conforms to the tradition of geography as a scientific discipline. While most GIS-applications are pragmatically oriented in solving ‘real-world-problems’, each attempt to implement ‘spatial theories’ of GIS ends up in the well known geographical dilemma ...
    Description: thesis
    Keywords: 910 ; QBD 700 ; Geoinformationssysteme {Geographie}
    Language: German
    Type: monograph , publishedVersion
    Format: 162 S.
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  • 40
    Publication Date: 2021-03-29
    Description: Deep-sea fan, early diagenesis, susceptibility, anaerobic oxidation of methane, black shale, anoxia, oceanic anoxic event, trace elements, iron, phosphorus, sediment source, redox changes, enrichment factors, sequential extraction. - In the context of present-day changes of atmo-, hydro-, geo- and biosphere processes, there is growing interest to decipher rapid paleoenvironmental changes in the geological past. Marine deposits provide valuable insights into paleoenvironmental conditions that prevailed during their deposition, if we know how to read the respective signals in the sedimentary record. However, caution is demanded as primary signals of past environmental conditions can be altered by postdepositional diagenetic processes. In the presented work, we will show the potentials, but also limitations of inorganic geochemical proxies to record signals of abrupt paleoenvironmental shifts in the terrestrially dominated Late Quaternary deposits of the Zambesi deep-sea fan (SE African margin), and in a fully marine Late Cretaceous black shale succession on Demerara Rise (NW South American margin).
    Description: thesis
    Keywords: VAT 200 ; VJB 322 ; VAT 200 ; VJB 322 ; Meeresablagerungen {Geologie} ; Geochemie der ozeanischen Sedimente
    Language: German
    Type: monograph , publishedVersion
    Format: 127 S.
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  • 41
    Publication Date: 2021-03-29
    Description: Carbon, Upwelling, Namibia, shelf, sediments. - This PhD thesis is an essential component of the 'Namibia Gas' (NAMIBGAS) project, which aims to improve the understanding of the rate and fluxes of hydrogen sulfide and methane to the sediment surface and into the water column on the Namibian shelf, which is one of the most productive upwelling systems on Earth. Organic matter degradation in the sediment drives hydrogen sulfide production, the maintenance of anoxia, and methane formation. Therefore, the primary aims of the thesis are to study carbon transformation processes within the sediment, determine the reactivity of organic carbon in the sediment and, investigate the control of microbial community structure and activity by the amount and accessibility of carbon sources. The emphasis is on linking microbial community structure (identity) to their function (activity) to provide new insights into the microbial ecology that controls carbon turnover in these upwelling sediments. By studying the stepwise degradation of organic carbon a complete process overview of organic carbon mineralization could be obtained. Firstly, the diagenetic transformation of dissolved organic carbon (DOC), in particular dissolved carbohydrates, was studied by using both biogeochemical methods and molecular techniques. The bulk sediment composition, pore water chemistry, polysaccharide hydrolysis rates, 35S-sulfate reduction rates, and the abundance of active bacteria involved in the initial and terminal processes of organic carbon degradation within the top 15 cm of the sediment from two sampling stations were determined (Chapter 2). Secondly, the diversity of bacteria from the same ...
    Description: thesis
    Keywords: 551 ; VAT 270 ; VGE 500 ; Flachsee-Sedimente {Geologie} ; Biomineralisation
    Language: English
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  • 42
    Publication Date: 2021-03-29
    Description: High-resolution climate reconstruction, North Sea, annual banded proxy, Arctica islandica. - Until now, there has been no published documentation of North Sea year-to-year climate variability during the last 8000 to 10000 years. High-resolution instrumental time series of climatic and environmental data for the North Sea and the adjacent North Atlantic are only available for the last decades or a century at best. Long term paleoclimatic reconstructions in higher latitudes have been predominantly undertaken using land-based annually banded archives, such as trees, varves, glaciers, and speleothems. A suitable long-term environmental archive with annual may be provided by CaCO3-skeletons of long-lived marine invertebrates. This study evaluates whether recent and subfossil shells of the long-lived bivalve Arctica islandica from the North Sea carry feasible information on Holocene climatic and oceanographic conditions. I compared modern shells of Arctica islandica from two very different habitats, a near-coastal shallow site (German Bight) and a northerly, more central, deep site (Fladen Ground). From the latter, subfossil shells were analysed, also. This study demonstrates that Arctica from both sites provides suitable archives of marine environmental conditions in the form of (i) variations in annual shell ...
    Description: thesis
    Keywords: 560 ; TWC 500 ; VAR 990 ; VXM 200 ; VZZ 120 ; Klimaschwankungen und Klimaänderungen im Quartär ; Meeresräume {Glazialgeologie} ; Lamellibranchiata {Paläozoologie} ; Randmeere {Paläontologie}
    Language: English
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  • 43
    Publication Date: 2021-03-29
    Description: Calanus simillimus, Rhincalanus gigas, grazing, biogeochemistry, biogenic silica. - The role of copepod grazing, particularly of Calanus simillimus and Rhincalanus gigas, in the biogeochemical cycles of silicon (Si) and carbon (C) in the Antarctic Circumpolar Current (ACC) of the Southern Ocean is investigated. The two grazers show differences in feeding behavior before and in response to a diatom bloom stimulated by in situ iron fertilization. The continuously high feeding activity of C. simillimus on diatoms is conducive to enhance the export of primary produced C and Si. The grazing impact of this key species is high enough to influence population dynamics in the microplankton communities of the ACC. In the pre-bloom situation, R. gigas fulfils most of its carbon requirement through grazing on detritus and thereby effectively reduces the vertical fecal flux produced by C. simillimus. It is proposed that a Copepod-Retention-System for organic material is put in place by the copepod community under High Nutrient Low Chlorophyll (HNLC) conditions. Prey switching by R. gigas from detritus to diatoms in the bloom situation lifts the grazing check on the detritus flux and enables loss of particulate C and Si from the surface layer with fast sinking fecal pellets. Results from dissolution experiments indicate that the enclosure of biogenic silica (BSi) in copepod fecal pellets prevents the dissolution of diatom frustules. Diatoms submitted to grazing of copepods and krill (Euphausia superba) dissolved 4 to 26 times slower than un-grazed controls.
    Description: thesis
    Keywords: 560 ; VJE 220 ; Geochemie der Fauna
    Language: English
    Type: monograph , publishedVersion
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  • 44
    Publication Date: 2021-03-29
    Description: Volcanology, volcanic rift zones, Madeira, fluid inclusions, thermobarometry, geochemistry, geochronology. - Madeira and the Desertas Islands show two well-developed volcanic rift zones which intersect near the eastern tip of Madeira (São Lourenço peninsula). To examine a possible genetic link, volcanic structures, rock ages and rock compositions were investigated at the Desertas and São Lourenço. Barometric data derived from fluid inclusions and clinopyroxene-melt compositions indicate fractionation at multiple levels within the mantle beneath the rift zones, followed by temporary magma stagnation within the crust. Depths of crustal stagnation beneath São Lourenço and the Desertas differ significantly, and there is no evidence for a shallow magma reservoir feeding both rifts. This suggests that Madeira and the Desertas have separated magma supply systems. 40Ar/39Ar age determinations revealed that Desertas volcanism lasted from 〉5.1 to 1.9 Ma overlapping in age with the shield phase of Madeira. Eruptive quiescence between 4 and 2.5 Ma at São Lourenço coincides with the main period of volcanism on the Desertas. Major and trace elements and ...
    Description: thesis
    Keywords: 551 ; VAD 600 ; VAD 700 ; VAE 840 ; VEF 139 ; Paläovulkanismus {Geologie} ; Regionaler Vulkanismus {Geologie} ; Rifts {Geologie} ; Balearen un Pityusen {Geologie}
    Language: English
    Type: monograph , publishedVersion
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  • 45
    Publication Date: 2021-03-29
    Description: thesis
    Keywords: 551 ; VAQ 990 ; Meereis {Glaziologie}
    Language: English
    Type: monograph , publishedVersion
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  • 46
    Publication Date: 2020-10-05
    Description: Coccolithophores, a major group of the nanophytoplankton, belong to the class Prymnesiophyceae.The cells of coccolithophores are typically surrounded by layer(s) of calcium carbonate plates, the coccoliths. Certain coccolithophores can be assigned to particular water masses or to photic zone characteristics and, therefore, single species as well as whole assemblages can be used as oceanographical indicators for the present and the past. Due to their ocean wide distribution, their large contribution to the fine grained carbonate ooze of the deep sea, their ability to photosynthesize and to calcificate they play an important role in the global carbon cycle...
    Description: thesis
    Keywords: 579.17 ; 577.7 ; 577.15 ; 579.82 ; 560 ; VJI 000 ; VU 000 ; VU 000 ; VJI 000 ; Geobiologie ; Geochemische Kreislaufmodelle
    Language: English
    Type: monograph , publishedVersion
    Format: 151 S.
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  • 47
    Publication Date: 2021-03-29
    Description: thesis
    Keywords: 560 ; TWC 600 ; VYF 200 ; VYA 500 ; VWH 300 ; VDH 320 ; Paläoklimatologie ; Pyrrophyceae {Paläobotanik} ; Paläökologie {Paläobotanik} ; Kreide {Stratigraphische Paläontologie} ; Oberkreide
    Language: English
    Type: monograph , publishedVersion
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  • 48
    Publication Date: 2021-03-29
    Description: The marine carbonate pump includes the production of calcium carbonate, CaCO3 by marine organisms and its subsequent transport to depth. The balance between carbonate production in surface waters and dissolution and accumulation in sediments influences the surface water CO2 concentration and thus the oceanś capacity to take up atmospheric CO2.Models are developed to investigate on calcium carbonate dissolution in the oceanic water column. Model results yield that dissolution in zooplankton guts contributes a significant portion of the proposed carbonate loss. Dissolution fueled by the respiration of organic matter in marine snow aggregates is very sensitive to the size and settling velocity of the aggregate, which determines the boundary layer thickness and the stability of an undersaturated microenvironment. The constraints set by field data yield that the chemical gradients between the aggregate and the bulk seawater are too small to enable significant carbonate dissolution. Furthermore, the role of the carbonate pump in regulating atmospheric pCO2 on glacial to interglacial timescales is investigated ...
    Description: thesis
    Keywords: 551.9 ; VJI 000 ; Geochemische Kreislaufmodelle
    Language: English
    Type: monograph , publishedVersion
    Format: 132 S.
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  • 49
    Publication Date: 2021-03-29
    Description: The major objective of the study is to investigate how near-surface sediment structures and other geological aspects control the nature and occurrence of cold fluid seepage. Mainly high resolution multichannel seismic data and swatch bathymetry data were used to study nearsurface seismostratigraphy, structure and seismic fluid-indicating features in two different fluid seepage provinces: Campeche Knolls, southern Gulf of Mexico and the frontal Makran, offshore Pakistan. The two areas have fundamentally different tectonic settings: The Campeche Knolls, southern Gulf of Mexico represents a passive margin influenced by salt tectonism, while the frontal Makran is the most basinward part of the Makran accretionary prism, characterized by plate subduction, sediment accretion, thrust faulting and development of sediment imbricate slices. However, they share quite a few similarities in shallow sediment structures and fluid seepage patterns...
    Description: thesis
    Keywords: 551.23 ; 553.28 ; 550 ; TSZ 100 ; VAE 880 ; TSZ 200 ; Atlantischer Ozean {Geophysik} ; Passive und aktive Kontinentalränder {Geologie} ; Indischer Ozean {Geophysik}
    Language: English
    Type: monograph , publishedVersion
    Format: 125 S.
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  • 50
    Publication Date: 2021-03-29
    Description: Deformation, shear zone, granular, micromechanic, numerical model, discrete element method, distinct element method. - This thesis was inspired by the lack of detailed (i.e. particle scale) knowledge concerning deformation processes of mechanically weak sediments, especially intrinsically weak layers on the basal shear plane of submarine landslides. It has been known for some time that many different parameters influence shear strength and localization features. This is true not only for sediments, but also for other kinds of weak layers, such as fault gouge. These parameters include for example mineralogy (e.g. smectite, illite, quartz), sediment composition (clay, silt), sediment structure and texture (microfabric), grain size distribution, excess pore pressure, magnitude of effective stress, and deformation history. However, to date it has not been possible to rank or to quantify the influence of each of these parameters. The main goal of this study is to analyze the influence of some of these parameters and, if possible, rank and quantify them. Standard methods to examine shear strength of sediments and fault gouge are various geotechnical shear experiments. In these, a sample is sheared under defined conditions and resulting coefficient of friction, void ratio change, and other meaningful parameters are analyzed. Unfortunately, it is not possible to 'look' inside a shear box during a test and to analyze grain deformation behaviour on a microscopic scale. Therefore, this study employs a different approach to specifically address the problem of microscopic deformation processes. Here, a numerical modelling technique, the Discrete Element Method (DEM), is used. The DEM is a numerical tool based on the ...
    Description: thesis
    Keywords: 551.8 ; VAE 130 ; VAE 130 ; Geomechanik
    Language: English
    Type: monograph , publishedVersion
    Format: 138 S.
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  • 51
    Publication Date: 2021-03-29
    Description: During the last years and decades issues related to the physics and chemistry of the Earthś atmosphere have attracted much scientific and public interest. The most important problems are stratospheric ozone loss and the ò̀zone hole ́́above Antarctica, global warming and climate change, and tropospheric air pollution. The understanding of the impact of human activities on the Earthś atmosphere requires measurements on a global scale. These enable the spatial and temporal variability of the atmospheric constituents to be investigated. Recently efforts have been made to establish a global observation system comprising satellite instruments and ground-based networks. To process data supplied by the instruments which belong to the global observation system, the development of radiative transfer models and retrieval algorithms is essential. This thesis contributes to the development of the radiative transfer models and retrieval algorithms intended to interprete measurements of the spectral radiance scattered in the atmosphere or transmitted through the atmosphere in UV-Vis-NIR spectral region performed by a new-generation remote sensing satellite spectrometer SCIAMACHY. In this study, main problems of radiative transfer through a spherical planetary atmosphere compared to a plane-parallel atmosphere are investigated. An efficient spherical radiative transfer model intended to simulate SCIAMACHY limb measurements was developed and validated. The model can also be used for the interpretation of measurements performed by other space-borne instruments as well as to compute air mass factors for ground-based measurements. An approximate approach allowing the simulation of limb measurements to be substantially accelerated was developed and its accuracy was investigated. Furthermore, a numerical radiative transfer model intended to simulate SCIAMACHY occultation measurements was developed and then coupled with an appropriate selected inverse technique.
    Description: thesis
    Keywords: 551.5 ; 550.28 ; 550 ; TQI 000 ; Geophysikalische Satellitenfernerkundung
    Language: English
    Type: monograph , publishedVersion
    Format: 150 S.
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  • 52
    Publication Date: 2021-03-29
    Description: Giant shear processes shaped Africa's southern margin during the breakup of the supercontinent Gondwana. They acted along a more than 1000 km long transform fault, whose remnant structure the Agulhas-Falkland Fracture Zone stretches today from the Falkland Plateau to the southeastern margin of Africa. A study of the processes which initiated such a long-offset transform fault and acted during their active phase is essential to understand how this sheared margin developed. Africa’s southern margin is not only one of the best examples to study the sharp continent-ocean-transition zones, the marginal ridge, fracture zone, and basin structures usually associated with transform margins, but it provides the unique opportunity to study how excessive magmatic processes acted which formed a Large Igneous Province at a sheared margin. In this thesis, I use seismic refraction, seismic reflection data and plate-tectonic reconstructions to investigate the structure and dynamics of this margin. These are ideal methods as they lead to high-quality velocity-depth models showing the present-day structure across the margin and provide timing and geometries by means of plate kinematics...
    Description: thesis
    Keywords: 550 ; TSR 000 ; TSZ 200 ; VAE 880 ; VAE 890 ; VER 100 ; VEZ 200 ; Südafrika {Geophysik} ; Indischer Ozean {Geophysik} ; Passive und aktive Kontinentalränder {Geologie} ; Ozeanische Kruste {Tektonik} ; Republik Südafrika {Geologie} ; Indischer Ozean {Geologie}
    Language: English
    Type: monograph , publishedVersion
    Format: 157 S.
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  • 53
    Publication Date: 2021-03-29
    Description: Im ersten Kapitel erfolgt nach der Zielsetzung und Motivation für die vorliegende Dissertation eine kurze geographische Beschreibung des Arktischen Ozeans und dessen tektonischer Entwicklung.Das Augenmerk gilt dabei dem ca. 1800 km langen Gakkel-Rücken, der sich von der Nordküste Grönlands bis zum Schelf der Laptewsee erstreckt und die Grenze zwischen Nordamerikanischer und Eurasischer Platte bildet. Die Spreizungsgeschwindigkeiten dieses Rückensystems, welche für geowissenschaftliche Untersuchungen von besonderer Bedeutung sind, betragen nur etwa einen Zentimeter pro Jahr und sind damit die langsamsten weltweit. Eine kurze Vorstellung von geophysikalischen und geodätischen Messverfahren zeigt, wie man zu solchen präzisen Spreizungsraten gelangt. Im Anschluss erfolgt eine kurze Beschreibung der Arctic Mid-Ocean Ridge Expedition (AMORE), welche die Forschungsschiffe Healy (USA) und Polarstern (Deutschland) im Sommer 2001 in den zentralen Arktischen Ozean und zum Nordpol führte. Die Sonarmessdaten und Bodenproben, die auf der AMORE-Expedition gesammelt und in dieser Arbeit ausgewertet wurden, stammen hauptsächlich aus dem ca. 32 000 km2 großen Gebiet entlang des Gakkel-Rückens (7°W85°E, 82°N87°N), zum Teil aber auch aus dem Amundsen- und Nansen-Becken. In Kapitel Zwei werden hydroakustische Grundlagen erläutert, die für das Verständnis dieser Arbeit unabdingbar sind und auf die später zurückgegriffen wird. Nach der Beschreibung von physikalischen Größen und Verhältnissen, der Wellengleichung, der Ausbreitung von Unterwasserschall und der Reflexion und Rückstreuung von Schallwellen am Meeresboden erfolgt eine Formulierung der Sonargleichung ...
    Description: thesis
    Keywords: 551.46 ; TQD 800 ; TSZ 100 ; VAT 300 ; Georadar {Geophysik} ; Atlantischer Ozean {Geophysik} ; Geologie des Meeresboden
    Language: German
    Type: monograph , publishedVersion
    Format: 231 S.
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  • 54
    Publication Date: 2021-03-29
    Description: Antarctica represents a key component in the investigation of the geological history and reconstruction of the supercontinents Rodinia and Gondwana. Remnants of the formation and disintegration of these former land masses can be found, although great uncertainties remain in the location of tectonic boundaries beneath the ice sheet of Antarctica due to general lack of outcrops and the limited amount of geological data. Space and airborne measurements are the only possibility to obtain comprehensive spatial data coverage of geophysical data over the extensive large polar areas. Common knowledge of the geological framework displays three major tectonic events which formed Dronning Maud Land (DML): the Grenvillian Orogen (1.1 Ga) build up Rodinia, the Pan-African-Antarctic Orogen (EAAO, 500 Ma) rose in the supercontinent Gondwana and finally the breakup of Gondwanaland, at around 180 Ma...
    Description: thesis
    Keywords: 526.7 ; 559 ; 538.87 ; 550 ; TSY 200 ; Antarktis {Geophysik} ; Aerogeophysik
    Language: English
    Type: monograph , publishedVersion
    Format: 174 S.
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  • 55
    Publication Date: 2021-03-29
    Description: Integrated studies of conjugate margins provide important constraints for the sequence of events of synrift tectonic and magmatic processes. The northeast Greenland margin is investigated based on seismic refraction data acquired across the continent ocean transition zone between the Jan Mayen and Greenland fracture zones. Transects of seismic velocity models reveal a clear segmentation of the margin, which is compatible with the potential field data. A crucially important observation is a thick high velocity lower crustal body which clearly decreases northwards. Excessive magmatism is inferred to have occurred during long-term rifting in the south, while reduced syn-rift intrusions account for the norhtern magma-starved margin. Asymmetries and variations across the adjacent and conjugate East Greenland and Norwegian margins, are controversially discussed in terms of the origin of the lower crustal body and magnetic spreading anomalies. Three hypothetical scenarios for the timing and formation of the high velocity lower crustal body are presented. A comprehensive subsidence analysis is established which quantifies the amount of magmatic underplating.
    Description: thesis
    Keywords: 551.136 ; VAE 880 ; TSY 100 ; VBM 000 ; VAE 880 ; TSY 100 ; VBM 000 ; Passive und aktive Kontinentalränder {Geologie} ; Arktis {Geophysik} ; Geologische Interpretation geophysikalischer Beobachtungen
    Language: English
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  • 56
    Publication Date: 2021-03-29
    Description: Antarctica, Dronning Maud Land, anisotropy, seismic anisotropy, shear wave splitting, receiver functions, moho, moho depth, crust, upper mantle, refraction seismic, gravity, 3D-gravity, igmas, bouguer anomaly, seismology. - The area of investigation, Dronning Maud Land (DML), comprises with the Weddell Sea and the Lazarev Sea approximately the region between 15 degrees W and 15 degrees E longitude and 68 degrees and 75 degrees latitude - a surface area of more than 1.500.000 qkm. Three major events formed the present-day geology and tectonic settings of DML: (1) the Grenvillian Orogeny, ca. 1.1 Ga ago, caused by the formation of the supercontinent Rhodinia, (2) the Panafrican Orogeny 500 Ma ago, forming the supercontinent Gondwana due to the collison of West and East Gondwana, and (3) the break-up of Gondwana 180 Ma ago, which started in the present-day Lazarev Sea. Seismological, refraction seismic and aerogravity data-sets form the basis of this thesis. The combination of these data-sets allows to investigate the structural composition and the spatial variation of the lithospheric thickness. The latter is essential for the determination of the regional geoid, which is the main objective of the VISA-project. Within the framework of this project airborne measurements of the potential field as well as ice-penetrating radar and GPS-measurements have been carried out. Moreover, seismographic stations were temporarily deployed in various parts of DML. Despite their very short operation time, applications of seismological methods to the recorded teleseismic events yielded conclusions about the structure and dynamic of the deeper subsurface. By analyses of seismic anisotropy, which investigates the splitting of shear waves traversing an anisotropic medium (so-called shear wave splitting) conclusions ...
    Description: thesis
    Keywords: 551.1 ; 550 ; TSY 200 ; Antarktis {Geophysik}
    Language: German
    Type: monograph , publishedVersion
    Format: 150 S.
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  • 57
    Publication Date: 2021-03-29
    Description: Radiocarbon, reservoir age, ocean circulation, projection age, top-to-bottom age, B-P age. - In paleoceanography and paleoclimatology radiocarbon is frequently used to date carbonaceous samples of the past 50,000 years and as a proxy to reconstruct circulation states of the ocean. Temporal variations of the atmospheric radiocarbon concentration, caused by a varying radiocarbon production rate or changes in the global carbon cycle, lead to dating uncertainties and also limit the usability of radiocarbon as an oceanographic proxy. In order to analyze and correct the influence of varying atmospheric radiocarbon on the ocean, radiocarbon has been included as a tracer to a global climate model (University of Victoria Earth System Climate Model). This model was forced by the reconstructed atmospheric radiocarbon production rate, to predict differences between atmospheric and marine radiocarbon age, the so-called reservoir age, spatially and temporally.
    Description: thesis
    Keywords: 551.701 ; 550 ; Geochronologie einzelner Regionen ; Holozän ; Isotopengeologie ; Geochemische Kreislaufmodelle
    Language: German
    Type: monograph , publishedVersion
    Format: 124 S.
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  • 58
    Publication Date: 2021-03-29
    Description: Seismic, marine, walvis ridge, bottom currents, climatic events. - The history of sedimentation and current activities at the northeastern flank of Walvis Ridge is investigated by a correlation of multichannel seismic data collected during R/V Meteor Cruise M49/1 in early 2001 with borehole measurements of Ocean Drilling Project (ODP) Leg 208. During Meteor Cruise M 49/1 multi-frequency seismic data were collected using two different seismic sources, in a quasi simultaneous mode in order to get best possible penetration and resolution of the sub-surface structures. Walvis Ridge divides the southeastern Atlantic Ocean into two basins, the Angola Basin to the north and the Cape Basin to the south. It is well known as an impassable barrier for bottom waters which separates Antarctic Bottom Waters (AABW) widely distributed in the Cape Basin from North Atlantic Depth Waters (NADW) in the Angola Basin. The sediments of the northeastern flank of Walvis Ridge are characterized by mostly undisturbed sequences of Cenozoic sediments, with varying thickness of ~150 m at the edge of the Angola Basin and ~450 m at the axis of the ridge. A correlation of seismic data with borehole data was accomplished by calculating synthetic seismograms using GRA density measurements of the cores and an averaged velocity model. This 'simple' event modeling allows to assign ages to the seismic reflectors and to identify key horizons/boundaries like the E/O and the K/T boundaries as well as the ELMO event and deposits of the PETM, representing Cenozoic climatic events. The seismic pattern of these target horizons shows similar properties at the different sites indicating their regional distribution. A special static correction in addition to standard seismic processing steps resulted in high quality high resolution deep sea Watergun images. A comparison between the seismic images and the magnetic core ...
    Description: thesis
    Keywords: 551.69 ; 551.462 ; 551 ; 550 ; Tiefseeseismik {Geophysik} ; Atlantischer Ozean {Geophysik} ; Geologische Bohrungen in einzelnen Regionen ; Teilgebiete {Atlantischer Ozean: Geologie} ; Marine Sedimente einzelner Meere und Ozeane {Geologie} ; Paläoklimatologie
    Language: English
    Type: monograph , publishedVersion
    Format: 133 S.
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  • 59
    Publication Date: 2021-03-29
    Description: Microwave remote sensing, polarimetry, radiometer, WindSat, passive. - Measurements from spaceborne microwave radiometers, such as the Scanning Multichannel Microwave Radiometer (SMMR), the Special Sensor Microwave/Imager (SSM/I) and the Advanced Microwave Scanning Radiometer (AMSR), are found to be useful in estimating various earth surface geophysical quantities, e.g. soil moisture and vegetation characteristics over land, snow water equivalent for snow covers and sea ice concentration. All these instruments have measured only the vertical and horizontal polarization component of the brightness temperature (Tb ). WindSat is the first spaceborne radiometer to provide fully polarimetric measurements of the earthÃ
    Description: thesis
    Keywords: 551.5 ; TUA 800 ; TVK 100 ; Radarmeteorologie ; Windmessungen und Beobachtungsergebnisse im Allg. {Meteorologie}
    Language: English
    Type: monograph , publishedVersion
    Format: 122 S.
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  • 60
    Publication Date: 2021-03-29
    Description: Thermochronology, Fission track, (U-Th)/He, 40Ar/39Ar,Mozambique, Gondwana, supercontinent dispersal. - Results of thermochronometric investigations comprising 40Ar/39Ar hornblende and biotite, titanite and apatite fission track (FT) and apatite (U-Th)/He dating on 102 basement rock samples from northern Mozambique record a cooling and denudation history since Early Palaeozoic times. In the north Mozambican sector, these results place new temporal and geometric constraints on the initial rift and subsequent drift configuration during the Gondwana supercontinent dispersal as well as on the post break-up evolution of the sheared margin of central East Africa. Furthermore, they highlight the influence exerted by ductile basement structures of Pan-African age on the loci of tectonically active zone and associated denudation since the Late Palaeozoic. 40Ar/39Ar hornblende and biotite ages range from c. 542 Ma to 456 Ma and c. 448 Ma to 428 Ma, respectively. They record the cooling from the latest Pan-African metamorphic imprint, presumably related to the formation of the Namama Thrust Belt at c. 550-500 Ma, at slow rates of about 11Âʿ 7ÂʿC/Ma from 525ÂʿC to 305ÂʿC in Early to Late Ordovician times. Locally, the thermal influences of syn- to post-tectonic granitoid / pegmatite emplacements at about 500-450 Ma delayed cooling. Widespread basement cooling to 〈 350ãA°C occurred in Late Ordovician to Early Silurian times. The titanite fission track ages fall into two age groups of c. 378 Ma to 327 Ma and c. 284 Ma to 219 Ma. Very slow cooling since the Late Ordovician/Early Silurian at rates of 〈 1ãA°C/Ma to below 275 ãA« 25ãA°C in the Late Devonian/Early Carboniferous is deduced from the older titanite FT ages. It is related to decreasing denudation in ...
    Description: thesis
    Keywords: 551.701 ; 556 ; 551 ; 550 ; VBN 500 ; Geochronologie einzelner Regionen im allgemeinen
    Language: English
    Type: monograph , publishedVersion
    Format: 265 S.
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  • 61
    Publication Date: 2021-03-29
    Description: Diagenesis, Rock magnetism, Marine sediments. - Sediments and sedimentary rocks are important sources for paleomagnetic studies of the geomagnetic field behaviour and of environmental changes. These studies are greatly dependent on the reliable extraction of the detrital magnetic signal. Overprinting of this signal by reductive diagenetic processes, where iron-bearing minerals are dissolved and secondary (magnetic) sulphide minerals form, jeopardizes the validity of such investigations. It is therefore necessary to be aware of the possible presence of diagenetic/authigenic magnetic phases, i.e. greigite, and their influence on the paleomagnetic signal. A chemical remanent magnetisation (CRM) due to these phases can obscure the detrital magnetic signal. It remains to be shown how primary detrital minerals may survive dissolution under these conditions, and by which mechanisms secondary (magnetic) sulphide minerals are formed.
    Description: thesis
    Keywords: 538.7 ; 552.5 ; 550 ; TOT 310 ; VKB 323 ; TOT 310 ; VKB 323 ; Gesteinsmagnetismus {Geophysik} ; Sedimentphysik
    Language: English
    Type: monograph , publishedVersion
    Format: 118 S.
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  • 62
    Publication Date: 2021-03-29
    Description: Sediment transport, high productivity, submarine canyon, submarine slide, excess pore-pressure, weak layers, slope failure. - The study investigates processes of mass sediment transport in two geologically unique Atlantic margins influenced by high primary productivity, i.e. the Mauritanian and Uruguayan margins. Whereas the Mauritanian margin is dominated by hyper-arid conditions, the Uruguayan margin, on the other hand, is dominated by fluvial sediment inputs. Investigations of the Mauritanian margin are centred on two major features, i.e. the Cap Timiris Canyon and the Mauritania Slide Complex, using combined analyses of hydroacoustic and high resolution multi-channel seismic (MCS) data. An area offshore Uruguay, which is dominated by extensive slope instabilities and mass sediment transport, was also investigated with high resolution MCS data. Results of the study suggest ...
    Description: thesis
    Keywords: 551 ; 551 ; 550 ; Atlantischer Ozean {Geophysik} ; Marine Sedimentation {Geologie}
    Language: German
    Type: monograph , publishedVersion
    Format: 130 S.
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  • 63
    Publication Date: 2021-03-29
    Description: Madagascar, Gondwana, thermochronology. - Titanite and apatite fission track (FT) thermochronology on 127 basement and 18 sedimentary rock samples from central and southern Madagascar record a complex cooling and denudation history since the Early Palaeozoic. Titanite FT analyses gave ages ranging between 483 Ma and 266 Ma. Apatite FT ages vary between 460 Ma and 79 Ma. Samples from Late Carboniferous to Jurassic sediments from the Morondava basin gave apatite FT ages ranging between 462 Ma and 184 Ma. FT data argues for reactivation of several Late Neoproterozoic/Early Cambrian ductile shear zones pre-dating the initial opening of the Morondava basin during the Late Carboniferous. Apatite FT data indicate that the subsequent Mesozoic rift evolution was accompanied with an eastward migration of areas of fast cooling. During Mesozoic times the Morondava basin had a greater eastward extension. Detrital apatite FT data derived from the outcropping Sakoa Group imply that after the Late Carboniferous deposition these rocks were covered by 2-4 km of sedimentary rocks. The final separation of Madagascar and East Africa during the Jurassic influenced mainly samples in southwest Madagascar, where basement regions and also former basin regions were exhumed. Combined Titanite FT and structural data argue for a minor tectono-thermal influence of the Marion hot spot during the Madagascar-India separation. However, apatite FT ages and modelled cooling paths indicate that the break-up during the Cretaceous was associated with a denudation amount of ~4 km crustal section along a narrow stripe parallel to the present eastern continental margin.
    Description: thesis
    Keywords: 551,701 ; 550 ; VBN 500 ; VBN 200 ; VEQ 300 ; VBN 500 ; VBN 200 ; VEQ 300 ; Geochronologie einzelner Regionen im allgemeinen ; Radiometrische Altersbestimmung ; Madagaskar {Geologie}
    Language: English
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  • 64
    Publication Date: 2021-03-29
    Description: Nonsteady-state Diagenesis, Equatorial Atlantic, Rock-magnetic and Geochemical Multiproxy Approach, XRF Core Scanner, Fe Redox, Magnetite Dissolution. - This thesis investigates 25 Late Quaternary sediment records from the central Equatorial Atlantic by rock magnetic, geochemical and stratigraphical methods. The work was performed in the framework of the Collaborative Research Center 261 ‘The South Atlantic in the Late Quaternary: Reconstruction of Material Budgets and Current Systems’ funded by the Deutsche Forschungsgemeinschaft. The main objective was to analyze and distinguish terrigenous and diagenetic proxysignatures, in particular of rock magnetic parameters. All cores were correlated and dated on basis of their carbonate, iron and rock magnetic records. Magnetite coarsening and partial depletion was observed in glacial organic-rich layers, most intensely during oxygen isotope stages 6, 10 and 12. Non-magnetic and magnetic iron mineral enrichments were found below and at former and active Fe(II) / Fe(III) redox boundaries. Various new proxies quantifying magnetite reduction (ratio of Fe to magnetic susceptibility, ratio of non-ferrimagnetic to total magnetic susceptibility) and authigenesis (ratio of Fe to magnetic susceptibility) were established and found to be highly sensitive indicators of past redox conditions. Comparing these signals with the organic carbon records, it was shown, that rock magnetic, carbon and carbonate records in most parts ...
    Description: thesis
    Keywords: 551.9 ; 538.7 ; 551.46 ; 551 ; 550 ; TOT 320 ; TSZ 100 ; VKB 380 ; VDI 200 ; VEZ 100 ; VAT 240 ; Paläomagnetismus {Geophysik} ; Atlantischer Ozean {Geophysik} ; Sedimente bestimmter Regionen ; Quartär ; Atlantischer Ozean {Geologie} ; Marine Sedimente einzelner Meere und Ozeane {Geologie}
    Language: English
    Type: monograph , publishedVersion
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  • 65
    Publication Date: 2021-03-29
    Description: Paleoceanography, Climate, Marine Productivity, Terrigenous Input, High-frequent Cyclicities, LGM, Holocene, XRF Core Scanner. - The goal of this thesis is to reconstruct, with high spatial resolution, the influence of coastal upwelling and terrigeneous input on the magnitude and composition of sediment accumulation off NW Africa, and to investigate how this influence has varied through the last glacial and interglacial periods. To achieve dense coverage for paleoceanographic reconstruction in the investigation area, a large number of sediment cores has been analyzed with rapid and non-destructive core-logging systems. The results of this thesis show that even the small region of the Canary Islands can be separated into several areas, with each reflecting its own sediment characteristics. Recent remote sensing images of chlorophyll concentration reflecting the present upwelling conditions are mirrored by the accumulation rates of the underlying sediment. The variation and distribution of the sediment accumulation rates in the past provides information about paleoceanographic features, such as upwelling conditions and sea-level fluctuations. The contribution of terrigeneous material to the marine sediments can be separated into eolian and a fluvial portions. Three characteristic areas ...
    Description: thesis
    Keywords: 551.46 ; 550.28 ; 550 ; VAT 240 ; TSZ 100 ; VAT 240 ; TSZ 100 ; Marine Sedimente einzelner Meere und Ozeane {Geologie} ; Atlantischer Ozean {Geophysik}
    Language: English
    Type: monograph , publishedVersion
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  • 66
    Publication Date: 2021-03-29
    Description: thesis
    Keywords: 551.5 ; 550 ; TYY 100 ; TVA 210 ; Arktis {Meteorologie und Klimatologie} ; Chemische Zusammensetzung der Atmosphäre {Meteorologie}
    Language: English
    Type: monograph , publishedVersion
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  • 67
    Publication Date: 2013-01-31
    Type: Article , PeerReviewed
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  • 68
    Publication Date: 2013-01-31
    Description: Here we make an initial step toward the development of an ocean assimilation system that can constrain the modelled Atlantic Meridional Overturning Circulation (AMOC) to support climate predictions. A detailed comparison is presented of 1° and 1/4° resolution global model simulations with and without sequential data assimilation, to the observations and transport estimates from the RAPID mooring array across 26.5° N in the Atlantic. Comparisons of modelled water properties with the observations from the merged RAPID boundary arrays demonstrate the ability of in situ data assimilation to accurately constrain the east-west density gradient between these mooring arrays. However, the presence of an unconstrained "western boundary wedge" between Abaco Island and the RAPID mooring site WB2 (16 km offshore) leads to the intensification of an erroneous southwards flow in this region when in situ data are assimilated. The result is an overly intense southward upper mid-ocean transport (0–1100 m) as compared to the estimates derived from the RAPID array. Correction of upper layer zonal density gradients is found to compensate mostly for a weak subtropical gyre circulation in the free model run (i.e. with no assimilation). Despite the important changes to the density structure and transports in the upper layer imposed by the assimilation, very little change is found in the amplitude and sub-seasonal variability of the AMOC. This shows that assimilation of upper layer density information projects mainly on the gyre circulation with little effect on the AMOC at 26° N due to the absence of corrections to density gradients below 2000 m (the maximum depth of Argo). The sensitivity to initial conditions was explored through two additional experiments using a climatological initial condition. These experiments showed that the weak bias in gyre intensity in the control simulation (without data assimilation) develops over a period of about 6 months, but does so independently from the overturning, with no change to the AMOC. However, differences in the properties and volume transport of North Atlantic Deep Water (NADW) persisted throughout the 3 year simulations resulting in a difference of 3 Sv in AMOC intensity. The persistence of these dense water anomalies and their influence on the AMOC is promising for the development of decadal forecasting capabilities. The results suggest that the deeper waters must be accurately reproduced in order to constrain the AMOC.
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  • 69
    Publication Date: 2013-01-31
    Description: Since April 2004 the RAPID array has made continuous measurements of the Atlantic Meridional Overturning Circulation (AMOC) at 26° N. Two key components of this system are Ekman transport zonally integrated across 26° N and western boundary current transport in the Florida Straits. Whilst measurements of the AMOC as a whole are somewhat in their infancy, this study investigates what useful information can be extracted on the variability of the Ekman and Florida Straits transports using the decadal timeseries already available. Analysis is also presented for Sverdrup transports zonally integrated across 26° N. The seasonal cycles of Florida Straits, Ekman and Sverdrup transports are quantified at 26° N using harmonic analysis of annual and semi-annual constituents. Whilst Sverdrup transport shows clear semi-annual periodicity, calculations of seasonal Florida Straits and Ekman transports show substantial interannual variability due to contamination by variability at non-seasonal frequencies; the mean seasonal cycle for these transports only emerges from decadal length observations. The Florida Straits and Ekman mean seasonal cycles project on the AMOC with a combined peak-to-peak seasonal range of 3.5 Sv. The combined seasonal range for heat transport is 0.40 PW. The Florida Straits seasonal cycle possesses a smooth annual periodicity in contrast with previous studies suggesting a more asymmetric structure. No clear evidence is found to support significant changes in the Florida Straits seasonal cycle at sub-decadal periods. Whilst evidence of wind driven Florida Straits transport variability is seen at sub-seasonal and annual periods, a model run from the 1/4° eddy-permitting ocean model NEMO is used to identify an important contribution from internal oceanic variability at sub-annual and interannual periods. The Ekman transport seasonal cycle possesses less symmetric structure, due in part to different seasonal transport regimes east and west of 50 to 60° W. Around 60% of non-seasonal Ekman transport variability occurs in phase section-wide at 26° N and is related to the NAO, whilst Sverdrup transport variability is more difficult to decompose.
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  • 70
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    Copernicus Publications (EGU)
    In:  [Talk] In: EGU General Assembly 2010, 02.05.-07.05.2010, Vienna, Austria ; p. 4913 .
    Publication Date: 2013-02-18
    Type: Conference or Workshop Item , NonPeerReviewed
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  • 71
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    Copernicus Publications (EGU)
    In:  Biogeosciences (BG), 7 (8). pp. 2379-2396.
    Publication Date: 2012-07-06
    Description: The rugged submarine topography of the Azores supports a diverse heterozoan association resulting in intense biotically-controlled carbonate-production and accumulation. In order to characterise this cold-water (C) factory a 2-year experiment was carried out in the southern Faial Channel to study the biodiversity of hardground communities and for budgeting carbonate production and degradation along a bathymetrical transect from the intertidal to bathyal 500 m depth. Seasonal temperatures peak in September (above a thermocline) and bottom in March (stratification diminishes) with a decrease in amplitude and absolute values with depth, and tidal-driven short-term fluctuations. Measured seawater stable isotope ratios and levels of dissolved nutrients decrease with depth, as do the calcium carbonate saturation states. The photosynthetic active radiation shows a base of the euphotic zone in ~70 m and a dysphotic limit in ~150 m depth. Bioerosion, being primarily a function of light availability for phototrophic endoliths and grazers feeding upon them, is ~10 times stronger on the illuminated upside versus the shaded underside of substrates in the photic zone, with maximum rates in the intertidal (−631 g/m2/yr). Rates rapidly decline towards deeper waters where bioerosion and carbonate accretion are slow and epibenthic/endolithic communities take years to mature. Accretion rates are highest in the lower euphotic zone (955 g/m2/yr), where the substrate is less prone to hydrodynamic force. Highest rates are found – inversely to bioerosion – on down-facing substrates, suggesting that bioerosion may be a key factor governing the preferential settlement and growth of calcareous epilithobionts on down-facing substrates. In context of a latitudinal gradient, the Azores carbonate cycling rates plot between known values from the cold-temperate Swedish Kosterfjord and the tropical Bahamas, with a total range of two orders in magnitude. Carbonate budget calculations for the bathymetrical transect yield a mean 266.9 kg of epilithic carbonate production, −54.6 kg of bioerosion, and 212.3 kg of annual net carbonate production per metre of coastline in the Azores C factory.
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  • 72
    Publication Date: 2019-09-23
    Description: A simple prognostic tool for gas hydrate (GH) quantification in marine sediments is presented based on a diagenetic transport-reaction model approach. One of the most crucial factors for the application of diagenetic models is the accurate formulation of microbial degradation rates of particulate organic carbon (POC) and the coupled formation of biogenic methane. Wallmann et al. (2006) suggested a kinetic formulation considering the ageing effects of POC and accumulation of reaction products (CH4, CO2) in the pore water. This model is applied to data sets of several ODP sites in order to test its general validity. Based on a thorough parameter analysis considering a wide range of environmental conditions, the POC accumulation rate (POCar in g/m2/yr) and the thickness of the gas hydrate stability zone (GHSZ in m) were identified as the most important and independent controls for biogenic GH formation. Hence, depth-integrated GH inventories in marine sediments (GHI in g of CH4 per cm2 seafloor area) can be estimated as: GHI=a ·POCar·GHSZb ·exp(−GHSZc/POCar/d)+e with a = 0.00214, b = 1.234, c = −3.339, d = 0.3148, e = −10.265. The transfer function gives a realistic first order approximation of the minimum GH inventory in low gas flux (LGF) systems. The overall advantage of the presented function is its simplicity compared to the application of complex numerical models, because only two easily accessible parameters need to be determined.
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  • 73
    Publication Date: 2012-07-06
    Description: Iron is a key micronutrient for phytoplankton growth in the surface ocean. Yet the significance of volcanism for the marine biogeochemical iron-cycle is poorly constrained. Recent studies, however, suggest that offshore deposition of airborne ash from volcanic eruptions is a way to inject significant amounts of bio-available iron into the surface ocean. Volcanic ash may be transported up to several tens of kilometers high into the atmosphere during large-scale eruptions and fine ash may stay aloft for days to weeks, thereby reaching even the remotest and most iron-starved oceanic regions. Scientific ocean drilling demonstrates that volcanic ash layers and dispersed ash particles are frequently found in marine sediments and that therefore volcanic ash deposition and iron-injection into the oceans took place throughout much of the Earth's history. Natural evidence and the data now available from geochemical and biological experiments and satellite techniques suggest that volcanic ash is a so far underestimated source for iron in the surface ocean, possibly of similar importance as aeolian dust. Here we summarise the development of and the knowledge in this fairly young research field. The paper covers a wide range of chemical and biological issues and we make recommendations for future directions in these areas. The review paper may thus be helpful to improve our understanding of the role of volcanic ash for the marine biogeochemical iron-cycle, marine primary productivity and the ocean-atmosphere exchange of CO2 and other gases relevant for climate in the Earth's history.
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  • 74
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    Copernicus Publications (EGU)
    In:  Biogeosciences (BG), 7 . pp. 2159-2190.
    Publication Date: 2019-09-23
    Description: We review here the available information on methane (CH4) and nitrous oxide (N2O) from major marine, mostly coastal, oxygen (O2)-deficient zones formed both naturally and as a result of human activities (mainly eutrophication). Concentrations of both gases in subsurface waters are affected by ambient O2 levels to varying degrees. Organic matter supply to seafloor appears to be the primary factor controlling CH4 production in sediments and its supply to (and concentration in) overlying waters, with bottom-water O2-deficiency exerting only a modulating effect. High (micromolar level) CH4 accumulation occurs in anoxic (sulphidic) waters of silled basins, such as the Black Sea and Cariaco Basin, and over the highly productive Namibian shelf. In other regions experiencing various degrees of O2-deficiency (hypoxia to anoxia), CH4 concentrations vary from a few to hundreds of nanomolar levels. Since coastal O2-deficient zones are generally very productive and are sometimes located close to river mouths and submarine hydrocarbon seeps, it is difficult to differentiate any O2-deficiency-induced enhancement from in situ production of CH4 in the water column and its inputs through freshwater runoff or seepage from sediments. While the role of bottom-water O2-deficiency in CH4 formation appears to be secondary, even when CH4 accumulates in O2-deficient subsurface waters, methanotrophic activity severely restricts its diffusive efflux to the atmosphere. As a result, an intensification or expansion of coastal O2-deficient zones will probably not drastically change the present status where emission from the ocean as a whole forms an insignificant term in the atmospheric CH4 budget. The situation is different for N2O, the production of which is greatly enhanced in low-O2 waters, and although it is lost through denitrification in most suboxic and anoxic environments, the peripheries of such environments offer most suitable conditions for its production, with the exception of enclosed anoxic basins. Most O2-deficient systems serve as strong net sources of N2O to the atmosphere. This is especially true for coastal upwelling regions with shallow O2-deficient zones where a dramatic increase in N2O production often occurs in rapidly denitrifying waters. Nitrous oxide emissions from these zones are globally significant, and so their ongoing intensification and expansion is likely to lead to a significant increase in N2O emission from the ocean. However, a meaningful quantitative prediction of this increase is not possible at present because of continuing uncertainties concerning the formative pathways to N2O as well as insufficient data from key coastal regions.
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  • 75
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    Copernicus Publications (EGU)
    In:  Nonlinear Processes in Geophysics, 17 (1). pp. 37-47.
    Publication Date: 2017-10-24
    Description: The role played by wind-forced anticyclones in the vertical transport and mixing at the ocean mesoscale is investigated with a primitive-equation numerical model in an idealized configuration. The focus of this work is to determine how the stratification impacts such transport. The flows, forced only at the surface by an idealized wind forcing, are predominantly horizontal and, on average, quasigeostrophic. Inside vortex cores and intense filaments, however, the dynamics is strongly ageostrophic. Mesoscale anticyclones appear as "islands" of increased penetration of wind energy into the ocean interior and they represent the maxima of available potential energy. The amount of available potential energy is directly correlated with the degree of stratification. The wind energy injected at the surface is transferred at depth through the generation and subsequent straining effect of Vortex Rossby Waves (VRWs), and through near-inertial internal oscillations trapped inside anticyclonic vortices. Both these mechanisms are affected by stratification. Stronger transfer but larger confinement close to the surface is found when the stratification is stronger. For weaker stratification, vertical mixing close to the surface is less intense but below about 150 m attains substantially higher values due to an increased contribution of both VRWs, whose time scale is on the order of few days, and of near-inertial motions, with a time scale of few hours.
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  • 76
    Publication Date: 2019-09-23
    Description: We present the first application of Stochastic Heterogeneity Mapping based on the band-limited von Kármán function to a seismic reflection stack of a Mediterranean water eddy (meddy), a large salt lens of Mediterranean water. This process extracts two stochastic parameters directly from the reflectivity field of the seismic data: the Hurst number, which ranges from 0 to 1, and the correlation length (scale length). Lower Hurst numbers represent a richer range of high wavenumbers and correspond to a broader range of heterogeneity in reflection events. The Hurst number estimate for the top of the meddy (0.39) compares well with recent theoretical work, which required values between 0.25 and 0.5 to model internal wave surfaces in open ocean conditions based on simulating a Garrett-Munk spectrum (GM76) slope of −2. The scale lengths obtained do not fit as well to seismic reflection events as those used in other studies to model internal waves. We suggest two explanations for this discrepancy: (1) due to the fact that the stochastic parameters are derived from the reflectivity field rather than the impedance field the estimated scale lengths may be underestimated, as has been reported; and (2) because the meddy seismic image is a two-dimensional slice of a complex and dynamic three-dimensional object, the derived scale lengths are biased to the direction of flow. Nonetheless, varying stochastic parameters, which correspond to different spectral slopes in the Garrett-Munk spectrum (horizontal wavenumber spectrum), can provide an estimate of different internal wave scales from seismic data alone. We hence introduce Stochastic Heterogeneity Mapping as a novel tool in physical oceanography.
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  • 77
    Publication Date: 2013-01-31
    Description: We study the contribution of eastern-boundary density variations to sub-seasonal and seasonal anomalies of the strength and vertical structure of the Atlantic Meridional Overturning Circulation (AMOC) at 26.5° N, by means of the RAPID/MOCHA mooring array between April 2004 and October 2007. The major density anomalies are found in the upper 500 m, and they are often coherent down to 1400 m. The densities have 13-day fluctuations that are apparent down to 3500 m. The two strategies for measuring eastern-boundary density – a tall offshore mooring (EB1) and an array of moorings on the continental slope (EBH) – show little correspondence in terms of amplitude, vertical structure, and frequency distribution of the resulting basin-wide integrated transport fluctuations, implying that there are significant transport contributions between EB1 and EBH. Contrary to the original planning, measurements from EB1 cannot serve as backup or replacement for EBH: density needs to be measured directly at the continental slope to compute the full-basin density gradient. Fluctuations in density at EBH generate transport variability of 2 Sv rms in the AMOC, while the overall AMOC variability is 4.8 Sv rms. There is a pronounced deep-reaching seasonal cycle in density at the eastern boundary, which is apparent between 100 m and 1400 m, with maximum positive anomalies in spring and maximum negative anomalies in autumn. These changes drive anomalous southward upper mid-ocean flow in spring, implying maximum reduction of the AMOC, and vice-versa in autumn. The amplitude of the seasonal cycle of the AMOC arising from the eastern-boundary densities is 5.2 Sv peak-to-peak, dominating the 6.7 Sv peak-to-peak seasonal cycle of the total AMOC. Our analysis suggests that the seasonal cycle in density may be forced by the strong near-coastal seasonal cycle in wind stress curl.
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  • 78
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    Copernicus Publications (EGU)
    In:  Earth System Science Data, 2 . pp. 177-187.
    Publication Date: 2019-09-23
    Description: Water column data of carbon and carbon-relevant hydrographic and hydrochemical parameters from 188 cruises in the Arctic Mediterranean Seas, Atlantic and Southern Ocean have been retrieved and merged in a new data base: the CARINA (CARbon IN the Atlantic) Project. These data have gone through rigorous quality control (QC) procedures so as to improve the quality and consistency of the data as much as possible. Secondary quality control, which involved objective study of data in order to quantify systematic differences in the reported values, was performed for the pertinent parameters in the CARINA data base. Systematic biases in the data have been tentatively corrected in the data products. The products are three merged data files with measured, adjusted and interpolated data of all cruises for each of the three CARINA regions (Arctic Mediterranean Seas, Atlantic and Southern Ocean). Ninety-eight cruises were conducted in the "Atlantic" defined as the region south of the Greenland-Iceland-Scotland Ridge and north of about 30° S. Here we report the details of the secondary QC which was done on the total dissolved inorganic carbon (TCO2) data and the adjustments that were applied to yield the final data product in the Atlantic. Procedures of quality control – including crossover analysis between stations and inversion analysis of all crossover data – are briefly described. Adjustments were applied to TCO2 measurements for 17 of the cruises in the Atlantic Ocean region. With these adjustments, the CARINA data base is consistent both internally as well as with GLODAP data, an oceanographic data set based on the WOCE Hydrographic Program in the 1990s, and is now suitable for accurate assessments of, for example, regional oceanic carbon inventories, uptake rates and model validation.
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  • 79
    Publication Date: 2012-12-10
    Description: The chemical characterization of filter high volume (HV) and Berner impactor (BI) samples PM during RHaMBLe (Reactive Halogens in the Marine Boundary Layer) 2007 shows that the Cape Verde aerosol particles are mainly composed of sea salt, mineral dust and associated water. Minor components are nss-salts, OC and EC. The influence from the African continent on the aerosol constitution was generally small but air masses which came from south-western Europe crossing the Canary Islands transported dust to the sampling site together with other loadings. The mean mass concentration was determined for PM10 to 17 μg/m3 from impactor samples and to 24.2 μg/m3 from HV filter samples. Non sea salt (nss) components of PM were found in the submicron fractions and nitrate in the coarse mode fraction. Bromide was found in all samples with much depleted concentrations in the range 1–8 ng/m3 compared to fresh sea salt aerosol indicating intense atmospheric halogen chemistry. Loss of bromide by ozone reaction during long sampling time is supposed and resulted totally in 82±12% in coarse mode impactor samples and in filter samples in 88±6% bromide deficits. A chloride deficit was determined to 8% and 1% for the coarse mode particles (3.5–10 μm; 1.2–3.5 μm) and to 21% for filter samples. During 14 May with high mineral dust loads also the maximum of OC (1.71μg/m3) and EC (1.25 μg/m3) was measured. The minimum of TC (0.25 μg/m3) was detected during the period 25 to 27 May when pure marine air masses arrived. The concentrations of carbonaceous material decrease with increasing particle size from 60% for the ultra fine particles to 2.5% in coarse mode PM. Total iron (dust vs. non-dust: 0.53 vs. 0.06 μg m3), calcium (0.22 vs. 0.03 μg m3) and potassium (0.33 vs. 0.02 μg m3) were found as good indicators for dust periods because of their heavily increased concentration in the 1.2 to 3.5 μm fraction as compared to their concentration during the non-dust periods. For the organic constituents, oxalate (78–151 ng/m3) and methanesulfonic acid (MSA, 25–100 ng/m3) are the major compounds identified. A good correlation between nss-sulphate and MSA was found for the majority of days indicating active DMS chemistry and low anthropogenic influences.
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  • 80
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    Copernicus Publications (EGU)
    In:  Biogeosciences (BG), 7 . pp. 723-751.
    Publication Date: 2019-09-23
    Description: The future behaviour of the global ocean as a sink for CO2 is significant for climate change, but it is also important to understand its past by quantifying anthropogenic CO2 (Cant) in the ocean today. Unfortunately, this is complicated by the difficulty of deconvoluting Cant from the natural, unperturbed carbon cycle. Nonetheless, a range of techniques have been devised that perform this separation using the information implicit in other physical, biogeochemical and artificial ocean tracers. One such method is the TrOCA approach, whose parameterisation is derived from relationships between biogeochemical tracers within watermasses defined by age tracers such as CFC-11. TrOCA has a number of methodological advantages, and has been shown to be plausible, relative to other methods, in a number of studies. Here we examine the TrOCA approach by using it to deconvolute the known distribution of Cant from an ocean general circulation model (OGCM) simulation of the industrial period (1864–2004). TrOCA is evaluated at local, regional and global scales, with an emphasis on the wider applicability of the parameterisations derived at these scales. Our work finds that the published TrOCA parameterisation performs poorly when extrapolated beyond its calibration region, either with observational data or (especially) model output. Optimising TrOCA parameters using model output as a synthetic dataset leads to some small improvements, but the resulting TrOCA variants still perform poorly. Furthermore, there are large ranges on the optimised TrOCA parameters suggesting that a "universal" TrOCA parameterisation is not achieveable.
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  • 81
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    Copernicus Publications (EGU)
    In:  Atmospheric Chemistry and Physics, 10 (8). pp. 3891-3899.
    Publication Date: 2019-01-21
    Description: Iron is a key limiting micro-nutrient for marine primary productivity. It can be supplied to the ocean by atmospheric dust deposition. Volcanic ash deposition into the ocean represents another external and so far largely neglected source of iron. This study demonstrates strong evidence for natural fertilisation in the iron-limited oceanic area of the NE Pacific, induced by volcanic ash from the eruption of Kasatochi volcano in August 2008. Atmospheric and oceanic conditions were favourable to generate a massive phytoplankton bloom in the NE Pacific Ocean which for the first time strongly suggests a connection between oceanic iron-fertilisation and volcanic ash supply.
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  • 82
    Publication Date: 2019-01-21
    Description: Very short-lived halocarbons are significant sources of reactive halogen in the marine boundary layer, and likely in the upper troposphere and lower stratosphere. Quantifying ambient concentrations in the surface ocean and atmosphere is essential for understanding the atmospheric impact of these trace gas fluxes. Despite the body of literature increasing substantially over recent years, calibration issues complicate the comparison of results and limit the utility of building larger-scale databases that would enable further development of the science (e.g. sea-air flux quantification, model validation, etc.). With this in mind, thirtyone scientists from both atmospheric and oceanic halocarbon communities in eight nations gathered in London in February 2008 to discuss the scientific issues and plan an international effort toward developing common calibration scales (http://tinyurl.com/c9cg58). Here, we discuss the outputs from this meeting, suggest the compounds that should be targeted initially, identify opportunities for beginning calibration and comparison efforts, and make recommendations for ways to improve the comparability of previous and future measurements.
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  • 83
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    Copernicus Publications (EGU)
    In:  Biogeosciences (BG), 7 . pp. 2327-2337.
    Publication Date: 2012-11-07
    Description: The conversion of fixed nitrogen to N2 in suboxic waters is estimated to contribute roughly a third to total oceanic losses of fixed nitrogen and is hence understood to be of major importance to global oceanic production and, therefore, to the role of the ocean as a sink of atmospheric CO2. At present heterotrophic denitrification and autotrophic anammox are considered the dominant sinks of fixed nitrogen. Recently, it has been suggested that the trophic nature of pelagic N2-production may have additional, "collateral" effects on the carbon cycle, where heterotrophic denitrification provides a shallow source of CO2 and autotrophic anammox a shallow sink. Here, we analyse the stoichiometries of nitrogen and associated carbon conversions in marine oxygen minimum zones (OMZ) focusing on heterotrophic denitrification, autotrophic anammox, and dissimilatory nitrate reduction to nitrite and ammonium in order to test this hypothesis quantitatively. For open ocean OMZs the combined effects of these processes turn out to be clearly heterotrophic, even with high shares of the autotrophic anammox reaction in total N2-production and including various combinations of dissimilatory processes which provide the substrates to anammox. In such systems, the degree of heterotrophy (ΔCO2:ΔN2), varying between 1.7 and 6, is a function of the efficiency of nitrogen conversion. On the contrary, in systems like the Black Sea, where suboxic N-conversions are supported by diffusive fluxes of NH4+ originating from neighbouring waters with sulphate reduction, much lower values of ΔCO2:ΔN2 can be found. However, accounting for concomitant diffusive fluxes of CO2, ratios approach higher values similar to those computed for open ocean OMZs. Based on our analysis, we question the significance of collateral effects concerning the trophic nature of suboxic N-conversions on the marine carbon cycle.
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  • 84
    Publication Date: 2019-09-23
    Description: Recent suggestions to slow down the increase in atmospheric carbon dioxide have included ocean fertilization by addition of the micronutrient iron to Southern Ocean surface waters, where a number of natural and artificial iron fertilization experiments have shown that low ambient iron concentrations limit phytoplankton growth. Using a coupled carbon-climate model with the marine biology's response to iron addition calibrated against data from natural iron fertilization experiments, we examine biogeochemical side effects of a hypothetical large-scale Southern Ocean Iron Fertilization (OIF) that need to be considered when attempting to account for possible OIF-induced carbon offsets. In agreement with earlier studies our model simulates an OIF-induced increase in local air-sea CO2 fluxes by about 60 GtC over a 100-year period, which amounts to about 40% of the OIF-induced increase in organic carbon export. Offsetting CO2 return fluxes outside the region and after stopping the fertilization at 1, 7, 10, 50, and 100 years are quantified for a typical accounting period of 100 years. For continuous Southern Ocean iron fertilization, the return flux outside the fertilized area cancels about 8% of the fertilization-induced CO2 air-sea flux within the fertilized area on a 100-yr timescale. This "leakage" effect has a similar radiative impact as the simulated enhancement of marine N2O emissions. Other side effects not yet discussed in terms of accounting schemes include a decrease in Southern Ocean oxygen levels and a simultaneous shrinking of tropical suboxic areas, and accelerated ocean acidification in the entire water column in the Southern Ocean on the expense of reduced globally averaged surface water acidification. A prudent approach to account for the OIF-induced carbon sequestration would account for global air-sea CO2 fluxes rather than for local fluxes into the fertilized area only. However, according to our model, this would underestimate the potential for offsetting CO2 emissions by about 20% on a 100 year accounting timescale. We suggest that a fair accounting scheme applicable to both terrestrial and marine carbon sequestration has to be based on emission offsets rather than on changes in individual carbon pools.
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  • 85
    Publication Date: 2019-09-23
    Description: Rising atmospheric CO2 is acidifying the surface ocean, a process which is expected to greatly influence the chemistry and biology of the future ocean. Following the development of iron-replete phytoplankton blooms in a coastal mesocosm experiment at 350, 700, and 1050 μatm pCO2, we observed significant increases in dissolved iron concentrations, Fe(II) concentrations, and Fe(II) half-life times during and after the peak of blooms in response to CO2 enrichment and concomitant lowering of pH, suggesting increased iron bioavailability. If applicable to the open ocean this may provide a negative feedback mechanism to the rising atmospheric CO2 by stimulating marine primary production.
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  • 86
    Publication Date: 2012-07-06
    Description: The response of the coccolithophore Emiliania huxleyi to rising CO2 concentrations is well documented for acclimated cultures where cells are exposed to the CO2 treatments for several generations prior to the experiment. The exact number of generations required for acclimation to CO2-induced changes in seawater carbonate chemistry, however, is unknown. Here we show that Emiliania huxleyi's short-term response (26 h) after cultures (grown at 500 μatm) were abruptly exposed to changed CO2 concentrations (~190, 410, 800 and 1500 μatm) is similar to that obtained with acclimated cultures under comparable conditions in earlier studies. Most importantly, from the lower CO2 levels (190 and 410 μatm) to 750 and 1500 μatm calcification decreased and organic carbon fixation increased within the first 8 to 14 h after exposing the cultures to changes in carbonate chemistry. This suggests that Emiliania huxleyi rapidly alters the rates of essential metabolical processes in response to changes in seawater carbonate chemistry, establishing a new physiological "state" (acclimation) within a matter of hours. If this relatively rapid response applies to other phytoplankton species, it may simplify interpretation of studies with natural communities (e.g. mesocosm studies and ship-board incubations), where often it is not feasible to allow for a pre-conditioning phase before starting experimental incubations.
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  • 87
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    Copernicus Publications (EGU)
    In:  Biogeosciences (BG), 7 (3). pp. 1109-1116.
    Publication Date: 2012-11-12
    Description: The physiological performance of two coccolithophore species, Emiliania huxleyi and Coccolithus braarudii, was investigated during long-term exposure to elevated pCO2 levels. Mono-specific cultures were grown over 152 (E. huxleyi) and 65 (C. braarudii) generations while pCO2 was gradually increased to maximum levels of 1150 μatm (E. huxleyi) and 930 μatm (C. braarudii) and kept constant thereafter. Rates of cell growth and cell quotas of particulate organic carbon (POC), particulate inorganic carbon (PIC) and total particulate nitrogen (TPN) were determined repeatedly throughout the incubation period. Increasing pCO2 caused a decrease in cell growth rate of 9% and 29% in E. huxleyi and C. braarudii, respectively. In both species cellular PIC:TPN and PIC:POC ratios decreased in response to rising pCO2, whereas no change was observed in the POC:TPN ratios of E. huxleyi and C. braarudii. These results are consistent with those obtained in shorter-term high CO2 exposure experiments following abrupt pertubations of the seawater carbonate system and indicate that for the strains tested here a gradual CO2 increase does not alleviate CO2/pH sensitivity.
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  • 88
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    Copernicus Publications (EGU)
    In:  Biogeosciences (BG), 7 (9). pp. 2915-2923.
    Publication Date: 2019-09-23
    Description: CO2/pH perturbation experiments were carried out under two different pCO2 levels (39.3 and 101.3 Pa) to evaluate effects of CO2-induced ocean acidification on the marine diatom Phaeodactylum tricornutum. After acclimation (〉20 generations) to ambient and elevated CO2 conditions (with corresponding pH values of 8.15 and 7.80, respectively), growth and photosynthetic carbon fixation rates of high CO2 grown cells were enhanced by 5% and 12%, respectively, and dark respiration stimulated by 34% compared to cells grown at ambient CO2. The half saturation constant (Km) for carbon fixation (dissolved inorganic carbon, DIC) increased by 20% under the low pH and high CO2 condition, reflecting a decreased affinity for HCO3– or/and CO2 and down-regulated carbon concentrating mechanism (CCM). In the high CO2 grown cells, the electron transport rate from photosystem II (PSII) was photoinhibited to a greater extent at high levels of photosynthetically active radiation, while non-photochemical quenching was reduced compared to low CO2 grown cells. This was probably due to the down-regulation of CCM, which serves as a sink for excessive energy. The balance between these positive and negative effects on diatom productivity will be a key factor in determining the net effect of rising atmospheric CO2 on ocean primary production.
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  • 89
    Publication Date: 2019-09-23
    Description: The potential impact of rising carbon dioxide (CO2) on carbon transfer from phytoplankton to bacteria was investigated during the 2005 PeECE III mesocosm study in Bergen, Norway. Sets of mesocosms, in which a phytoplankton bloom was induced by nutrient addition, were incubated under 1× (~350 μatm), 2× (~700 μatm), and 3× present day CO2 (~1050 μatm) initial seawater and sustained atmospheric CO2 levels for 3 weeks. 13C labelled bicarbonate was added to all mesocosms to follow the transfer of carbon from dissolved inorganic carbon (DIC) into phytoplankton and subsequently heterotrophic bacteria, and settling particles. Isotope ratios of polar-lipid-derived fatty acids (PLFA) were used to infer the biomass and production of phytoplankton and bacteria. Phytoplankton PLFA were enriched within one day after label addition, whilst it took another 3 days before bacteria showed substantial enrichment. Group-specific primary production measurements revealed that coccolithophores showed higher primary production than green algae and diatoms. Elevated CO2 had a significant positive effect on post-bloom biomass of green algae, diatoms, and bacteria. A simple model based on measured isotope ratios of phytoplankton and bacteria revealed that CO2 had no significant effect on the carbon transfer efficiency from phytoplankton to bacteria during the bloom. There was no indication of CO2 effects on enhanced settling based on isotope mixing models during the phytoplankton bloom, but this could not be determined in the post-bloom phase. Our results suggest that CO2 effects are most pronounced in the post-bloom phase, under nutrient limitation.
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  • 90
    Publication Date: 2020-10-20
    Description: The uptake of anthropogenic CO2 by the oceans has led to a rise in the oceanic partial pressure of CO2, and to a decrease in pH and carbonate ion concentration. This modification of the marine carbonate system is referred to as ocean acidification. Numerous papers report the effects of ocean acidification on marine organisms and communities but few have provided details concerning full carbonate chemistry and complementary observations. Additionally, carbonate system variables are often reported in different units, calculated using different sets of dissociation constants and on different pH scales. Hence the direct comparison of experimental results has been problematic and often misleading. The need was identified to (1) gather data on carbonate chemistry, biological and biogeochemical properties, and other ancillary data from published experimental data, (2) transform the information into common framework, and (3) make data freely available. The present paper is the outcome of an effort to integrate ocean carbonate chemistry data from the literature which has been supported by the European Network of Excellence for Ocean Ecosystems Analysis (EUR-OCEANS) and the European Project on Ocean Acidification (EPOCA). A total of 185 papers were identified, 100 contained enough information to readily compute carbonate chemistry variables, and 81 data sets were archived at PANGAEA – The Publishing Network for Geoscientific & Environmental Data. This data compilation is regularly updated as an ongoing mission of EPOCA.
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  • 91
    Publication Date: 2012-07-06
    Description: Ancient Lake Ohrid is a steep-sided, oligotrophic, karst lake that was tectonically formed most likely within the Pliocene and often referred to as a hotspot of endemic biodiversity. This study aims on tracing significant lake level fluctuations at Lake Ohrid using high-resolution acoustic data in combination with lithological, geochemical, and chronological information from two sediment cores recovered from sub-aquatic terrace levels at ca. 32 and 60m water depth. According to our data, significant lake level fluctuations with prominent lowstands of ca. 60 and 35m below the present water level occurred during Marine Isotope Stage (MIS) 6 and MIS 5, respectively. The effect of these lowstands on biodiversity in most coastal parts of the lake is negligible, due to only small changes in lake surface area, coastline, and habitat. In contrast, biodiversity in shallower areas was more severely affected due to disconnection of today sublacustrine springs from the main water body. Multichannel seismic data from deeper parts of the lake clearly image several clinoform structures stacked on top of each other. These stacked clinoforms indicate significantly lower lake levels prior to MIS 6 and a stepwise rise of water level with intermittent stillstands since its existence as water-filled body, which might have caused enhanced expansion of endemic species within Lake Ohrid.
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  • 92
    Publication Date: 2019-09-23
    Description: CO2 emissions are leading to an acidification of the oceans. Predicting marine community vulnerability towards acidification is difficult, as adaptation processes cannot be accounted for in most experimental studies. Naturally CO2 enriched sites thus can serve as valuable proxies for future changes in community structure. Here we describe a natural analogue site in the Western Baltic Sea. Seawater pCO2 in Kiel Fjord is elevated for large parts of the year due to upwelling of CO2 rich waters. Peak pCO2 values of 〉230 Pa (〉2300 μatm) and pHNBS values of 〈7.5 are encountered during summer and autumn, average pCO2 values are ~70 Pa (~700 μatm). In contrast to previously described naturally CO2 enriched sites that have suggested a progressive displacement of calcifying auto- and heterotrophic species, the macrobenthic community in Kiel Fjord is dominated by calcifying invertebrates. We show that blue mussels from Kiel Fjord can maintain control rates of somatic and shell growth at a pCO2 of 142 Pa (1400 μatm, pHNBS = 7.7). Juvenile mussel recruitment peaks during the summer months, when high water pCO2 values of ~100 Pa (~1000 μatm) prevail. Our findings indicate that calcifying keystone species may be able to cope with surface ocean pHNBS values projected for the end of this century when food supply is sufficient. However, owing to non-linear synergistic effects of future acidification and upwelling of corrosive water, peak seawater pCO2 in Kiel Fjord and many other productive estuarine habitats could increase to values 〉400 Pa (〉4000 μatm). These changes will most likely affect calcification and recruitment, and increase external shell dissolution.
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  • 93
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    Copernicus Publications (EGU)
    In:  Biogeosciences (BG), 7 . pp. 3915-3919.
    Publication Date: 2020-10-16
    Description: Ocean acidification, as a consequence of increasing marine pCO2, may have severe effects on the physiology of marine organisms. However, experimental studies remain scarce, in particular concerning fish. While adults will most likely remain relatively unaffected by changes in seawater pH, early life-history stages are potentially more sensitive – particularly the critical stage of fertilization, in which sperm motility plays a central role. In this study, the effects of ocean acidification (decrease of pHT to 7.55) on sperm motility of Baltic cod, Gadus morhua, were assessed. We found no significant effect of decreased pH on sperm speed, rate of change of direction or percent motility for the population of cod analyzed. We predict that future ocean acidification will probably not pose a problem for sperm behavior, and hence fertilization success, of Baltic cod.
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  • 94
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    Copernicus Publications (EGU)
    In:  Biogeosciences (BG), 7 . pp. 3095-3108.
    Publication Date: 2012-07-06
    Description: A shallow-water area in the Santa Barbara Channel, California, known collectively as the Coal Oil Point seep field, is one of the largest natural submarine hydrocarbon emission areas in the world. Both gas and oil are seeping constantly through a predominantly sandy seabed into the ocean. This study focused on the methanotrophic activity within the surface sediments (0–15 cm) of the permeable seabed in the so-called Brian Seep area at a water depth of ~10 m. Detailed investigations of the sediment biogeochemistry of active gas vents indicated that it is driven by fast advective transport of water through the sands, resulting in a deep penetration of oxidants (oxygen, sulfate). Maxima of microbial methane consumption were found at the sediment-water interface and in deeper layers of the sediment, representing either aerobic or anaerobic oxidation of methane, respectively. Methane consumption was relatively low (0.6–8.7 mmolm−2 d−1) in comparison to gas hydratebearing fine-grained sediments on the continental shelf. The low rates and the observation of free gas migrating through permeable coastal sediments indicate that a substantial proportion of methane can escape the microbial methane filter in coastal sediments.
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  • 95
    Publication Date: 2019-09-23
    Description: Dimethylsulfoniopropionate (DMSP) is produced in surface seawater by phytoplankton. Phytoplankton culture experiments have shown that nanoeucaryotes (NANO) display much higher mean DMSP-to-Carbon or DMSP-to-Chlorophyll (Chl) ratios than Prochlorococcus (PRO), Synechococcus (SYN) or diatoms (DIAT). Moreover, the DMSP-lyase activity of algae which cleaves DMSP into dimethylsulfide (DMS) is even more group specific than DMSP itself. Ship-based observations have shown at limited spatial scales, that sea surface DMS-to-Chl ratios (DMS:Chl) are dependent on the composition of phytoplankton groups. Here we use satellite remote sensing of Chl (from SeaWiFS) and of Phytoplankton Group Dominance (PGD from PHYSAT) with ship-based sea surface DMS concentrations (8 cruises in total) to assess this dependence on an unprecedented spatial scale. PHYSAT provides PGD (either NANO, PRO, SYN, DIAT, Phaeocystis (PHAEO) or coccolithophores (COC)) in each satellite pixel (1/4° horizontal resolution). While there are identification errors in the PHYSAT method, it is important to note that these errors are lowest for NANO PGD which we typify by high DMSP:Chl. In summer, in the Indian sector of the Southern Ocean, we find that mean DMS:Chl associated with NANO + PHAEO and PRO + SYN + DIAT are 13.6±8.4 mmol g−1 (n=34) and 7.3±4.8 mmol g−1 (n=24), respectively. That is a statistically significant difference (P〈0.001) that is consistent with NANO and PHAEO being relatively high DMSP producers. However, in the western North Atlantic between 40° N and 60° N, we find no significant difference between the same PGD. This is most likely because coccolithophores account for the non-dominant part of the summer phytoplankton assemblages. Meridional distributions at 22° W in the Atlantic, and 95° W and 110° W in the Pacific, both show a marked drop in DMS:Chl near the equator, down to few mmol g−1, yet the basins exhibit different PGD (NANO in the Atlantic, PRO and SYN in the Pacific). In tropical and subtropical Atlantic and Pacific waters away from the equatorial and coastal upwelling, mean DMS:Chl associated with high and low DMSP producers are statistically significantly different, but the difference is opposite of that expected from culture experiments. Hence, in a majority of cases PGD is not of primary importance in controlling DMS:Chl variations. We therefore conclude that water-leaving radiance spectra obtained simultaneously from ocean color sensor measurements of Chl concentrations and dominant phytoplankton groups can not be used to predict global fields of DMS.
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  • 96
    Publication Date: 2019-09-23
    Description: Anthropogenic emissions of nitrogen (N) to the atmosphere have been strongly increasing during the last century, leading to greater atmospheric N deposition to the oceans. The North Atlantic subtropical gyre (NASTG) is particularly impacted. Here, upwind sources of anthropogenic N from North American and European sources have raised atmospheric N deposition to rates comparable with N2 fixation in the gyre. However, the biogeochemical fate of the deposited N is unclear because there is no detectable accumulation in the surface waters. Most likely, deposited N accumulates in the main thermocline instead, where there is a globally unique pool of N in excess of the canonical Redfield ratio of 16 N:1 phosphorus (P). To investigate this depth zone as a sink for atmospheric N, we used a biogeochemical ocean transport model and year 2000 nutrient deposition data. We examined the maximum effects of three mechanisms that may transport excess N from the ocean surface to the main thermocline: physical transport, preferential P remineralization of sinking particles, and nutrient uptake and export by phytoplankton at higher than Redfield N:P ratios. Our results indicate that atmospheric deposition may contribute 13-19% of the annual excess N input to the main thermocline. Modeled nutrient distributions in the NASTG were comparable to observations only when non-Redfield dynamics were invoked. Preferential P remineralization could not produce realistic results on its own; if it is an important contributor to ocean biogeochemistry, it must co-occur with N2 fixation. The results suggest that: 1) the main thermocline is an important sink for anthropogenic N deposition, 2) non-Redfield surface dynamics determine the biogeochemical fate of atmospherically deposited nutrients, and 3) atmospheric N accumulation in the main thermocline has long term impacts on surface ocean biology.
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  • 97
    Publication Date: 2013-03-18
    Description: The sea-surface microlayer (SML) is located within the boundary between the atmosphere and hydrosphere. The high spatial and temporal variability of the SML's properties, however, have hindered a clear understanding of interactions between biotic and abiotic parameters at or across the air-water interface. Among the factors changing the physical and chemical environment of the SML, wind speed is an important one. In order to examine the temporal effects of minimized wind influence, SML samples were obtained from the coastal zone of the southern Baltic Sea and from mesocosm experiments in a marina to study naturally and artificially calmed sea surfaces. Organic matter concentrations as well as abundance, (3)H-thymidine incorporation, and the community composition of bacteria in the SML (bacterioneuston) compared to the underlying bulk water (ULW) were analyzed. In all SML samples, dissolved organic carbon and nitrogen were only slightly enriched and showed low temporal variability, whereas particulate organic carbon and nitrogen were generally greatly enriched and highly variable. This was especially pronounced in a dense surface film (slick) that developed during calm weather conditions as well as in the artificially calmed mesocosms. Overall, bacterioneuston abundance and productivity correlated with changing concentrations of particulate organic matter. Moreover, changes in the community composition in the field study were stronger in the particle-attached than in the non-attached bacterioneuston. This implies that decreasing wind enhances the importance of particle-attached assemblages and finally induces a succession of the bacterial community in the SML. Eventually, under very calm meteorological conditions, there is an uncoupling of the bacterioneuston from the ULW.
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  • 98
    Publication Date: 2015-01-15
    Description: Emissions of sulphur hexafluoride (SF6), one of the strongest greenhouse gases on a per molecule basis, are targeted to be collectively reduced under the Kyoto Protocol. Because of its long atmospheric lifetime (estimated as 800 to 3200 years), the accumulation of SF6 in the atmosphere is a direct measure of its global emissions. Examination of our extended data set of globally distributed high-precision SF6 observations shows an increase in SF6 abundance from near zero in the 1970s to a global mean of 6.7 ppt by the end of 2008. In-depth evaluation of our long-term data records shows that the global source of SF6 decreased after 1995, most likely due to SF6 emission reductions in industrialised countries, but increased again after 1998. By subtracting those emissions reported by Annex I countries to the United Nations Framework Convention of Climatic Change (UNFCCC) from our observation-inferred SF6 source leaves a surprisingly large gap of more than 7080% of non-reported SF6 emissions in the last decade. This suggests a strong under-estimation of emissions in Annex I countries and underlines the urgent need for independent atmospheric verification of greenhouse gases emissions accounting.
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  • 99
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    Copernicus Publications (EGU)
    In:  Atmospheric Measurement Techniques, 3 (3). pp. 557-567.
    Publication Date: 2019-09-23
    Description: The recently increasing development of whole sky imagers enables temporal and spatial high-resolution sky observations. One application already performed in most cases is the estimation of fractional sky cover. A distinction between different cloud types, however, is still in progress. Here, an automatic cloud classification algorithm is presented, based on a set of mainly statistical features describing the color as well as the texture of an image. The k-nearest-neighbour classifier is used due to its high performance in solving complex issues, simplicity of implementation and low computational complexity. Seven different sky conditions are distinguished: high thin clouds (cirrus and cirrostratus), high patched cumuliform clouds (cirrocumulus and altocumulus), stratocumulus clouds, low cumuliform clouds, thick clouds (cumulonimbus and nimbostratus), stratiform clouds and clear sky. Based on the Leave-One-Out Cross-Validation the algorithm achieves an accuracy of about 97%. In addition, a test run of random images is presented, still outperforming previous algorithms by yielding a success rate of about 75%, or up to 88% if only "serious" errors with respect to radiation impact are considered. Reasons for the decrement in accuracy are discussed, and ideas to further improve the classification results, especially in problematic cases, are investigated.
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  • 100
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    Copernicus Publications (EGU)
    In:  Biogeosciences (BG), 7 (5). pp. 1615-1624.
    Publication Date: 2020-03-19
    Description: With the accumulation of anthropogenic carbon dioxide (CO2), a proceeding decline in seawater pH has been induced that is referred to as ocean acidification. The ocean's capacity for CO2 storage is strongly affected by biological processes, whose feedback potential is difficult to evaluate. The main source of CO2 in the ocean is the decomposition and subsequent respiration of organic molecules by heterotrophic bacteria. However, very little is known about potential effects of ocean acidification on bacterial degradation activity. This study reveals that the degradation of polysaccharides, a major component of marine organic matter, by bacterial extracellular enzymes was significantly accelerated during experimental simulation of ocean acidification. Results were obtained from pH perturbation experiments, where rates of extracellular α- and β-glucosidase were measured and the loss of neutral and acidic sugars from phytoplankton-derived polysaccharides was determined. Our study suggests that a faster bacterial turnover of polysaccharides at lowered ocean pH has the potential to reduce carbon export and to enhance the respiratory CO2 production in the future ocean.
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