ALBERT

Description: After some brief comments on the measurement of temperature and electrical conductivity in oceanography, the measuring probes suitable for in situ measurements are reviewed. Then the method of measurement is described using an improved model of the so-called bathysonde. This makes possible a continuous recording of temperature, conductivity, and pressure with high accuracy in great depths. Measurements from the Skagerrak and from the Mediterranean are considered. Finally, problems are discussed which arise when evaluating electrical conductivity and temperature from in situ measurements.

Description: Observations of temperature and electrical conductivity by a recording in situ salinometer are discussed in respect oo the physical processes connected with the renewal of North Atlantic deep water. The measured fine structure of the layering suggests that the downward movement of cooled surface water is combined with horizontal mixing down to more than 1000 m depth. This is confirmed by the existence of water elements which have slightly different temperature and salinity. Curves of temperature, conductivity, and salinity and T-S diagrams are shown.

Description: Reviews the major deep-sea expeditions from that of HMS Challenger in 1873 to 1960. Emphasis is on the increasing sophistication of vessels and equipment used, the growth of international cooperation and the proliferation of branches of oceanographic studies. Arctic work by Nansen, Sverdrup, recent Soviet scientists, the Scripps Institution and the Norpac program are mentioned (maps). Vessels used during the period and their activities are tabulated. Two maps show cruises of the Atlantic Polar Front Program Jan-Dec 1958 in the Greenland and Barents Seas

Description: This chapter throws the attention on the methods of sampling the benthos, which has been directed mainly to the operation of the gear at sea and to such other factors as may influence sampling methods. This chapter briefly traces the history of benthos investigations, and then considers how far the instruments now available provide with the quantitative samples. It also shows how advances in other fields, such as radio-position finding, sonar and electronic equipment have increased the precision of our sampling methods. Moreover, sorting and sieving on board ship can be considered and brief mention made of methods of soil analysis and biomass determination. This chapter discusses the two possible approaches for the development of satisfactory quantitative collecting methods. First the improvement of the grab-type of instrument, with particular reference to increasing penetration and the perfection of release gear for the open sea, and second; the development of a wide-core sampler, like the Knudsen sampler, which works satisfactorily in the open sea. Moreover, statistics need to be even more fully applied, where collecting methods justify them, to such problems as the degree and scale of dispersion of individuals.

Description: Fecal excretion of calcium of endogenous origin has been measured in 52 studies in 33 adult human subjects, under full metabolic balance conditions. Endogenous fecal calcium averaged .130 ± .047 Gm. per day, was positively correlated with both fecal calcium and dietary calcium and was inversely correlated with fractional calcium absorption. The regression line relating endogenous fecal calcium with fractional absorption allowed estimates for total intestinal calcium secretion at both zero and 100 per cent absorption; from these estimates it was calculated that approximately 15 per cent of the total intestinal calcium secretion was nonabsorbable even under conditions when dietary calcium was completely absorbed (presumably because it enters the gut caudad of the absorption sites). Total intestinal calcium secretion, calculated so as to allow for this nonabsorbable fraction, averaged .194 ± .073 Gm. per day, and could not be correlated with age, sex, dietary calcium intake, caloric intake, urine calcium, or plasma calcium. A weak correlation with body size (weight, surface area) was observed. The conditions studied were principally disorders of bone, calcium, and parathyroid metabolism, and in most of them total intestinal calcium secretion appeared identical. The sole exception was seen in two studies on a patient with acromegaly, in which total intestinal calcium secretion was over twice the mean value for the remainder of the group.

Description: Highlights • Coupled geomicrobiology and geomechanics to investigate alterations in shales. • Microbial process can alter the mechanics, mineralogy, and microstructure of shales. • Biogeomechanical alterations reduced permeability by 93% and porosity by 38%. • Microfractures in shales can be sealed during biogeomechanical alterations. • Biogeomechanical alterations can enhance CO2 storage security and caprock integrity. Shales have been a major focus of the energy industry over the past few decades. Recently, there is a paradigm shift in the energy industry to low-carbon solutions, such as carbon capture and storage (CCS), to mitigate global warming caused by carbon footprint. The problem of long-term safe and efficient geological CO2 storage (GCS) and caprock integrity are some of the major challenges impeding large-scale CCS application. Here, we investigated how localized and bulk biogeomechanical alterations could potentially impact caprock integrity and CO2 storage in depleted shale reservoirs. We cultivated the shale core samples (containing both artificial-induced and pre-existing natural fractures) with a cultured microbial solution at specific temperature, time, and growth conditions. Subsequently, we obtain the properties of the fractured shale rock samples impacted by this microbial process. We investigate the impact of the mechanical responses due to the microbial process, on the long-term integrity and storage potentials of CO2 in shale reservoirs. Our results suggest that in Eagle Ford, Marcellus, and Niobrara shale formations, microbially-altered local and bulk mechanical properties can enhance the long-term caprock integrity and CO2 storage security by: (1.) Increasing the localized (+19% unconfined compressive strength, −20% Poisson’s ratio, +35% fracture toughness) and bulk (+50% unconfined compressive strength, −13% Poisson’s ratio) mechanical integrity; (2.) Decreasing permeability (−93%) and porosity (−38%); (3.) Altering the clay mineral content (−56%), calcite content (+21%), and morphology; (4.) Occluding microfractures; and (5.) Mitigating any potential leakage to the atmosphere through the caprock. This study considers the heterogeneity of shales, and provide valuable insights and viable assessment in solving the long-term GCS application in depleted hydrocarbon reservoirs.

Description: Highlights • Internal diffusion often controls the releases of flame retardants from microplastics. • Fick's law can describe the releases of additive flame retardants from microplastics. • Effects of temperature, plastic matrix, and particle size can be predicted by models. • Weathering of plastic matrix can greatly accelerate the releases of flame retardants. • Low fluxes of flame retardants released from microplastics pose no risk to ecosystem. The widely occurring debris of plastic materials, particularly microplastics, can be an important source of flame retardants, which are one of the main groups of chemicals added in the production of plastics from polymers. This review provides an overview on the use of flame retardants in plastic manufacturing, the kinetics of their releases from microplastics, the factors affecting their releases, and the potential environmental and ecosystem risk of the released flame retardants. The releases of flame retardants from microplastics typically involve three major steps: internal diffusion, mass transfer across the plastic-medium boundary layer, and diffusion in the environmental medium, while the overall mass transfer rate is commonly controlled by diffusion within the plastic matrix. The overall release rates of additive flame retardants from microplastics, which are dependent on the particle's geometry, can often be described by the Fick's Law. The physicochemical properties of flame retardant and plastic matrix, and ambient temperature all affect the release rate, which can be predicted with empirical and semi-empirical models. Weathering of microplastics, which reduces their particle sizes and likely disrupts their polymeric structures, can greatly accelerate the releases of flame retardants. Flame retardants could also be released directly from the microplastics ingested by aquatic organisms and seabirds, with physical and chemical digestion in the bodies significantly enhancing their release rates. Limited by the extremely slow diffusion in plastic matrices, the fluxes of flame retardants released from microplastics are very low, and are unlikely to pose significant risk to the ecosystem in general. More research is needed to characterize the mechanical, chemical, and biological processes that degrade microplastics and accelerate the releases of flame retardants and to model their release kinetics from microplastics, while efforts should also be made to develop environmentally benign flame retardants to ultimately minimize their risk to the environment and ecosystem.

Description: The ubiquitous use of microplastics and their release into the environment especially the water bodies by anthropogenic/industrial activities are the major resources for microplastic contamination. The widespread and often injudicious use of antimicrobial drugs or antibiotics in various sectors including human health and hygiene, agriculture, animal husbandry and food industries are leading to the release of antibiotics into the wastewater/sewage and other water bodies, particularly in urban setups and thus leads to the antimicrobial resistance (AMR) in the microbes. Microplastics are emerging as the hubs as well as effective carriers of these microbial pathogens beside their AMR-genes (ARGs) in marine, freshwater, sewage/wastewater, and urban river ecosystems. These drug resistant bacteria interact with microplastics forming synthetic plastispheres, the ideal niche for biofilm formations which in turn facilitates the transfer of ARGs via horizontal gene transfer and further escalates the occurrence and levels of AMR. Microplastic-associated AMR is an emerging threat for human health and healthcare besides being a challenge for the research community for effective management/address of this menace. In this review, we encompass the increasing prevalence of microplastics in environment, emphasizing mainly on water environments, how they act as centers and vectors of microbial pathogens with their associated bacterial assemblage compositions and ultimately lead to AMR. It further discusses the mechanistic insights on how microplastics act as hosts of biofilms (creating the plastisphere). We have also presented the modern toolbox used for microplastic-biofilm analyses. A review on potential strategies for addressing microplastic-associated AMR is given with recent success stories, challenges and future prospects.