ALBERT

Beschreibung: Composite indicators are becoming more relevant for evaluating the performance of water companies from a holistic perspective. Some of them are related with economic aspects, and others focus on social and environmental features. Consequently, a multidimensional evaluation is necessary for handling the great amount of information provided by multiple single indicators of a different nature. This paper presents a two-phase approach to evaluate the sustainability of water companies. First, a partial composite indicator for each dimension (social, environmental, economic) is obtained using multi-criteria decision making (MCDM). Then, a global indicator is obtained, in terms of the values reached in the previous stage for every partial indicator, by means an optimization problem rooted in data envelopment analysis (DEA). Our proposal offers the possibility of analyzing the performance of each water company under each dimension that characterizes the concept of sustainability, as well as a joint assessment including all the dimensions, facilitating the decision-making process. We apply it to evaluate the sustainability of 163 Portuguese water companies. The results show the strengths and weaknesses of each unit and serve as a guideline to decision-makers on the aspects for improving the performance of water utilities.

Beschreibung: This study investigates the preferences of Italian home-owners when choosing a new domestic heating system. The focus is on understanding the influence on consumer choice of a potential label certifying the effect of the heating system on the greenhouse effect. To this end, we designed a survey including a discrete choice experiment and administered it to residents in north-eastern Italy. Our findings reveal that, on average, respondents pay particular attention to the green effect of their purchase. The carbon dioxide reduction label was considered second in terms of importance after cost. Further analysis found that our sample presents three clusters of customers, with intra-cluster homogeneous preferences. The cluster analysis showed that while the initial system costs are considered to varying degrees by the whole sample, the carbon dioxide reduction label was considered important by 79% of respondents (members of clusters 1 and 2). To achieve greater results in reducing the greenhouse effect of the domestic heating sector, a combination of policies should be used simultaneously to achieve greater effectiveness. Our simulations support the hypothesis that policymakers should achieve greater results in terms of reducing the domestic greenhouse gas emissions by applying a combined policy that leverages the importance citizens accord to the different characteristics of a heating system. From our results, the application of a ‘low carbon dioxide ( C O 2 ) emissions’ label will amplify the effect of a subsidy that reduces the initial system costs.

Beschreibung: Underwater deployed sensors nodes are energy-constrained. Therefore, energy efficiency becomes crucial in underwater wireless sensor networks (U-WSNs). The adverse channel corrupts the packets and challenges their reliability. To handle these challenges, two routing schemes are introduced in this paper. They are effective energy and reliable delivery (EERD) and cooperative effective energy and reliable delivery (CoEERD). In EERD, the packets follow single-path routing and the best forwarder node is selected using a weight function such that packets are transferred via the reliable paths with low energy usage. Packet transfer via a single route in EERD has, however, compromised reliability as the undersea links bear harshness and unpredictability. Therefore, the CoEERD scheme adds cooperative routing to EERD, in which a relay node is introduced between a source–destination pair. The destination requests the relay when the packets it gets from the source are corrupted beyond a threshold value. Selection of weight function is unique and considers many factors to ensure low energy usage with reliability while considering nodes for data transfer. This also helps in selecting a single relay node rather than many relays in the conventional cooperative routing model. Based on simulation results, the EERD and CoEERD protocols have improved performance in energy usage, reliable packet transfer and delay.

Beschreibung: This paper presents a numerical investigation of thermal response of mortar panels, incorporating macro-encapsulated paraffin in different forms. Two types of macro capsules were fabricated and tested in this study using an instrumented hot plate device. The experimental results show that macro encapsulated paraffin reduced the temperature and increased time lag in the mortar panels due to the latent heat capacity of paraffin. Finite element models adopting the effective heat capacity method to model phase change effects were able to capture the overall thermal response of panels incorporated with paraffin well. Then, a parametric study was conducted using the validated finite element (FE) modelling technique to investigate the effects of different forms of macro capsules, the quantity of paraffin and the position of macro capsules. It was found that the tube and sphere macro capsules showed similar thermal responses, while the plate shaped capsules may cause a non-uniform temperature distribution in mortar panels. The quantity and position of paraffin have significant effects on the thermal response of the mortal panels. A higher paraffin content results in a significantly longer temperature lag and a lower temperature during the phase transition of paraffin. Furthermore, placing the paraffin away from the heating face can cause a longer temperature lag on the other face, which is desirable for building façade applications.

Beschreibung: Single room ventilation units with heat recovery is one of the ventilation solutions that have been used in renovated residential buildings in Estonia. In multi-story buildings, especially in a cold climate, the performance of units is affected by the stack effect and wind-induced pressure differences between the indoor and the outdoor air. Renovation of the building envelope improves air tightness and the impact of the pressure conditions is amplified. The aim of this study was to predict the air pressure conditions in typical renovated multi-story apartment buildings and to analyze the performance of room-based ventilation units. The field measurements of air pressure differences in a renovated 5-story apartment building during the winter season were conducted and the results were used to simulate whole-year pressure conditions with IDA-ICE software. Performance of two types of single room ventilation units were measured in the laboratory and their suitability as ventilation renovation solutions was assessed with simulations. The results show that one unit stopped its operation as a heat recovery ventilator. In order to ensure satisfactory indoor climate and heat recovery using wall mounted units the pressure difference values were determined and proposed for correct design.

Beschreibung: In order to provide a good theoretical guidance for the development and utilization of weathered phosphorite resources, we investigated the geochemical and mineralogical characteristics of primary and weathered phosphorites. The analysis of trace elements showed that the primary ore has hydrothermal sedimentation effect in the later stage, the weathered ore has obvious residual enrichment and the phosphate ore belongs to clastic lithologic phosphate rock. In addition, through leaching test method, it was shown that rare earth elements are present in fluorapatite in the form of isomorphic substitution, and the proportion of rare earth elements adsorbed on clay and other minerals was likely to be between 2% and 3%. The light rare earth elements are relatively enriched in both primary and weathered phosphorite, and Ce and Eu have obvious negative anomalies. The primary phosphorite is a dolomitic phosphorite containing rare earth elements, which are naturally enriched by weathering, and its weathered ore has obvious residual enrichment, while the deposit was characterized by normal marine sedimentation and hydrothermal action.

Beschreibung: Traditional plug-flow anaerobic reactors (PFRs) are characterized by lacking a mixing system and operating at high total solid concentrations, which limits their applicability for several kinds of manures. This paper studies the performance of a novel modified PFR for the treatment of pig manure, characterized by having an internal sludge mixing system by biogas recirculation in the range of 0.270–0.336 m3 m−3 h−1. The influence on the methane yield of four operating parameters (recirculation rate, hydraulic retention time, organic loading rate, and total solids) was evaluated by running four modified PFRs at the pilot scale in mesophilic conditions. While the previous biodegradability of organic matter by biochemical methane potential tests were between 31% and 47% with a methane yield between 125 and 184 LCH4 kgVS−1, the PFRs showed a suitable performance with organic matter degradation between 25% and 51% and a methane yield of up to 374 LCH4 kgVS−1. Operational problems such as solid stratification, foaming, or scum generation were avoided.

Beschreibung: In the eddy current braking system of high-speed maglev, the peak braking force and the critical speed are key factors determining the performance of eddy current braking force. In this paper, the analytical formula of eddy current braking force is derived by a subdomain method considering the skin effect of the induction plate, and, subsequently, the characteristics of peak braking force and critical speed are analyzed. The analytical model is set up in a 2D Cartesian coordinate system. The Poisson equations in each subdomain are listed by treating the vector magnetic potential as a variable. By combining the boundary conditions between two adjacent subdomains, the expressions of eddy current density and magnetic density in the induction plate are obtained. Then, the analytical formula of the eddy current braking force is obtained by the Ampere force formula. The results of finite-element analysis confirm the validity of the analytical calculation. The methods of improving the performance of eddy current braking force under high speed are proposed by parametric analysis of peak braking force and critical speed, which provides guidance for the design of the eddy current braking system in high-speed maglev.

Beschreibung: This paper proposes an input voltage disturbance suppression control strategy for the unidirectional matrix converter (UMC) with a new modulation scheme enhancing the stability. In the new scheme, the modulation index is directly, rather than reversely, proportional to the instantaneous amplitude of input filter capacitor voltages. Contrary to traditional schemes, the stability of the UMC with this new scheme is even better with the increase of the transferred active power, which is particularly suitable for applications with sinusoidal and balanced input conditions. As to the disturbed input conditions, the new scheme could introduce low-frequency harmonics into output currents. To address this issue, a feedback control strategy of output current amplitude is further proposed to eliminate the additional harmonics. Stability analysis of a UMC with the proposed modulation scheme and feedback control strategy is presented. Experimental results have verified the validity of the proposed control solution.

Beschreibung: The interest in pellets utilization for households heating has been growing significantly in the last several years. However, the pellets need to meet certain quality requirements, including the mechanical durability (DU) index. In the winter seasons, the pellets are very often stored in unheated in-door systems or are transported by trucks over long distances. As a result, the pellets are exposed to external weather factors, including very low temperatures (even freezing ones), which can have a negative impact on the quality parameters of the fuel. There are several parameters affecting mechanical durability, but little is known about the influence of a very low temperature on the pellet properties. The aim of this research was to analyze the influence of freezing temperature storage on the mechanical durability of commercial pellets made of different biomass. The research was carried out in accordance with the international standard for solid biofuels PN-EN ISO 17831-1:2016-02. The samples were investigated under three different conditions: after normal storage conditions (20 °C), after frozen storage conditions (−28 °C) and after the defrosting of the pellets. The results revealed that the freezing process and subsequent defrosting of the pellets only causes a small drop in their mechanical durability in comparison to the normal storage conditions. The highest mechanical durability was established for digestate pellet and pine sawdust pellet, at 99.0 ± 0.1% and 98.7 ± 0.1% respectively (p 〈 0.05). The greatest change of mechanical durability was observed after the defrosting process of pellets, which in the initial stage and at the normal storage temperature were characterized by low mechanical durability. The pellets made of sunflower husk (DU = 87.4%) and coal/straw blend (DU = 96.2%) were distinguished by the highest change in their mechanical durability (ΔDU = 1.7%, p 〈 0.05). Based on the obtained results, it was concluded that the storage of pellets at freezing temperature does not significantly affect their mechanical durability. However, if the mechanical durability decreases, this result is related to pellets with low initial mechanical durability.

Beschreibung: The present study scrutinized the impacts of terrain-induced turbulence on wind turbine blades, examining measurement data regarding wind conditions and the strains of wind turbine blades. Furthermore, we performed a high-resolution large-eddy simulation (LES) and identified the three-dimensional airflow structures of terrain-induced turbulence. Based on the LES results, we defined the Uchida-Kawashima Scale_1 (the U-K scale_1), which is a turbulence evaluation index, and clarified the existence of the terrain-induced turbulence quantitatively. The threshold value of the U-K scale_1 was determined as 0.2, and this index was confirmed to not be dependent on the inflow profile, the influence of the horizontal grid resolution, and the influence of the computed azimuth. In addition, we defined the Uchida-Kawashima Scale_2 (the U-K scale_2), which is a fatigue damage evaluation index based on the measurement data and the design value obtained by DNV GL’s Bladed. DNV GL (Det Norske Veritas Germanischer Lloyed) is a third party certification body in Norway, and Bladed has been the industry standard aero-elastic wind turbine modeling software. Using the U-K scale_2, the following results were revealed: the U-K scale_2 was 0.86 〈 1.0 (within the designed value) in the case of northerly wind, and the U-K scale_2 was 1.60 〉 1.0 (exceeding the designed value) in the case of easterly wind. As a result, it was revealed that the blades of the target wind turbine were directly and strongly affected by terrain-induced turbulence when easterly winds occurred.

Beschreibung: This paper proposes a harmonic compensation control with disturbance rejection function for a standalone inverter. Due to the LC type three-phase three-leg inverter is connected to nonlinear loads, low-order harmonic components appears in the inverter output current. These harmonic current generate harmonic voltage drops when flowing through the filter inductor and the feeder impedance, which causes the output voltage of the inverter distorted. In order to compensate harmonics and produce sinusoidal voltage without additional compensation devices, virtual harmonic impedance method can be added to the fundamental voltage control. Due to the compensation effect of virtual harmonic impedance are very sensitive to the fluctuation of filter inductance. Therefore, inductance variation, as a disturbance in physical system, should be considered. In this paper, linear active disturbance rejection control (LADRC) is proposed in the fundamental voltage control loop to reduce the sensitivity of virtual harmonic impedance and decouple the model. Compared with traditional dual-loop PI control, the proposed strategy has faster dynamic response in control performance and fewer acquisition modules in engineering applications. The whole design process of virtual harmonic impedance and stability analyses of this strategy are provided. The simulation and experiment results show the good performance of the proposed strategy.

Beschreibung: This work explores the possibility to adopt in organic Rankine cycle (ORC) plants mixtures of water (acting as solvent) plus an organic compound (acting as solute) as the working fluid. Initially an evaluation of the thermodynamic properties of the mixtures is performed, in order to assess their properties, and to point out the molar fractions which entail a near-azeotropic behaviour. Four species from three different classes of chemical compounds are investigated: 2,2,2-trifluoroethanol and n-butanol for alcohols, where the first is fluorinated, acetonitrile for nitrile class and 2-methylpyrazine as a heterocyclic aromatic compound. Simultaneously, the thermal stability of the pure substances considered as the possible solute for the mixtures is experimentally investigated in order to estimate the temperature applicability range. The ORC plant performance, from a low-enthalpy geothermal heat source (hot water stream from 100 to 200 °C), adopting the selected mixtures as the working fluid is finally evaluated, and the analysis includes a preliminary discussion on the turbine design; results are compared with respect to the reference case of a hypothetical plant adopting water as the working fluid.

Beschreibung: In this paper, the optimal site and size selection of wind turbines (WTs) is presented considering the maximum allowable capacity constraint with the objective of loss reduction and voltage profile improvement of distribution grids based on particle swarm optimization (PSO as a multi-objective problem using weighted coefficients method. The optimal site, size, and power factor of the WTs are determined using PSO. The proposed method is implemented on 84- and 32-bus standard grids. In this study, PSO algorithm is applied to determine the size, site, and power factor of WTs considering their maximum size constraint (with constraint, variant size) and also not considering their maximum size constraint (without constraint, constant size). The simulation results showed that the PSO is effective to find the site, size, and power factor of WTs optimally in the single and multi-objective problem. The results of this method showed that the power loss is reduced more and voltage profile improved more considering WTs maximum allowable size versus not considering this constraint. Additionally, the multi-objective results showed that there is a compromise between the objectives in the multi-objective WTs site selection and the multi-objective problem solution is a more realistic and accurate approach in comparison with the single-objective problem solution.

Beschreibung: Aiming to maximize the transmission efficiency of inductively coupled power transmission (ICPT) system with the designed output power, a frequency locking method for an ICPT system based on LCC/S compensation topology is proposed in this paper. Firstly, the relationship between compensation component Lf1 and output power was deduced by the lossless model, and the initial value of Lf1 was obtained. Then, considering the system loss, the designed output power and frequency were input into the frequency locking program, and Lf1 and other compensation parameters were dynamically tracked. At the same time, the transmission efficiency of the system was calculated, and the frequency that achieved maximum efficiency was automatically locked when the system met the requirements of the designed output power. Finally, based on the method, the output characteristics of the system were verified by experiments.

Beschreibung: Wind Energy Conversion System (WECS) plays an inevitable role across the world. WECS consist of many components and equipment’s such as turbines, hub assembly, yaw mechanism, electrical machines; power electronics based power conditioning units, protection devices, rotor, blades, main shaft, gear-box, mainframe, transmission systems and etc. These machinery and devices technologies have been developed on gradually and steadily. The electrical machine used to convert mechanical rotational energy into electrical energy is the core of any WECS. Many electrical machines (generator) has been used in WECS, among the generators the Permanent Magnet Synchronous Generators (PMSGs) have gained special focus, been connected with wind farms to become the most desirable due to its enhanced efficiency in power conversion from wind energy turbine. This article provides a review of literatures and highlights the updates, progresses, and revolutionary trends observed in WECS-based PMSGs. The study also compares the geared and direct-driven conversion systems. Further, the classifications of electrical machines that are utilized in WECS are also discussed. The literature review covers the analysis of design aspects by taking various topologies of PMSGs into consideration. In the final sections, the PMSGs are reviewed and compared for further investigations. This review article predominantly emphasizes the conceptual framework that shed insights on the research challenges present in conducting the proposed works such as analysis, suitability, design, and control of PMSGs for WECS.

Beschreibung: Calcium looping is a promising technology to capture CO2 from the process of coal-fired power generation and gasification of coal/biomass for hydrogen production. The decay of CO2 capture activities of calcium-based sorbents is one of the main problems holding back the development of the technology. Taking carbide slag as a main raw material and Ca12Al14O33 as a support, highly active CO2 sorbents were prepared using the hydrothermal template method in this work. The effects of support ratio, cycle number, and reaction conditions were evaluated. The results show that Ca12Al14O33 generated effectively improves the cyclic stability of CO2 capture by synthetic sorbents. When the Al2O3 addition is 5%, or the Ca12Al14O33 content is 10%, the synthetic sorbent possesses the highest cyclic CO2 capture performance. Under harsh calcination conditions, the CO2 capture capacity of the synthetic sorbent after 30 cycles is 0.29 g/g, which is 80% higher than that of carbide slag. The superiority of the synthetic sorbent on the CO2 capture kinetics mainly reflects at the diffusion-controlled stage. The cumulative pore volume of the synthetic sorbent within the range of 10–100 nm is 2.4 times as high as that of calcined carbide slag. The structure of the synthetic sorbent reduces the CO2 diffusion resistance, and thus leads to better CO2 capture performance and reaction rate.

Beschreibung: Renewable energy sources can help the countries to achieve some of the Sustainable Development Goals (SDGs) provided from the recent 2030 Agenda, allowing for clean, secure, reliable and affordable energy. Biomass technology is a relevant renewable energy to contribute to reach a clean and affordable energy production system with important emissions reduction of greenhouse gases (GHG). An innovative technological application of biomass energy consisting of a burner coupled with an external fired gas turbine (EFGT) has been developed for the production of electricity. This paper shows the results of the plant modelling by Aspen Plus environment and preliminary experimental tests; the validation of the proposed model allows for the main parameters to be defined that regulate the energy production plant supplied by woodchips.

Beschreibung: Several window functions are currently applied to improve the performance of the discrete Fourier transform (DFT) harmonic detection method. These window functions exhibit poor accuracy in measuring the harmonic contents of a signal with high-order and weak-amplitude components when the power frequency fluctuates within a small range. In this paper, a minimum side-lobe optimization window function that is aimed at overcoming the abovementioned issue is proposed. Moreover, an improved DFT harmonic detection algorithm based on the six-term minimum side-lobe optimization window and four-spectrum-line interpolation method is proposed. In this context, the minimum side-lobe optimization window is obtained by optimizing the conventional cosine window function according to the optimization rules, and the characteristics of the new proposed window are provided to analyze its performance. Then, the proposed optimization window function is employed to improve the DFT harmonic detection algorithm based on the six-term minimum side-lobe optimization window and four-spectrum-line interpolation method. The proposed technique is used to detect harmonics of an electricity gird in which the six-term minimum side-lobe optimization window is utilized to eliminate the influence of spectrum leakage caused by nonsynchronous sampling of signal processing. The four-spectrum-line interpolation method is employed to eliminate or mitigate the fence effect caused by the inherent measurement error of the DFT method. Simulation experiments in two complex conditions and an experiment test are carried out to validate the improved performance of the proposed window. Results reveal that the six-term minimum side-lode optimization window has the smallest peak side lobe when compared with existing windows, which can effectively reduce the interaction influence of spectrum leakage, improve the measurement accuracy of the DFT harmonic detection method, and meet the standard requirement of harmonic measurement in complex situations.

Beschreibung: Apart from electric vehicles, most internal combustion (IC) engines are powered while burning petroleum-based fossil or alternative fuels after mixing with inducted air. Thereby the operations of mixing and combustion evolve in a turbulent flow environment created during the intake phase and then intensified by the piston motion and influenced by the shape of combustion chamber. In particular, the swirl and turbulence levels existing immediately before and during combustion affect the evolution of these processes and determine engine performance, noise and pollutant emissions. Both the turbulence characteristics and the bulk flow pattern in the cylinder are strongly affected by the inlet port and valve design. In the present paper, large eddy simulation (LES) is appraised and applied to studying the turbulent fluid flow around the intake valve of a single cylinder IC-engine as represented by the so called magnetic resonance velocimetry (MRV) flow bench configuration with a relatively large Reynolds number of 45,000. To avoid an intense mesh refinement near the wall, various subgrid scale models for LES; namely the Smagorinsky, wall adapting local eddy (WALE) model, SIGMA, and dynamic one equation models, are employed in combination with an appropriate wall function. For comparison purposes, the standard RANS (Reynolds-averaged Navier–Stokes) k- ε model is also used. In terms of a global mean error index for the velocity results obtained from all the models, at first it turns out that all the subgrid models show similar predictive capability except the Smagorinsky model, while the standard k- ε model experiences a higher normalized mean absolute error (nMAE) of velocity once compared with MRV data. Secondly, based on the cost-accuracy criteria, the WALE model is used with a fine mesh of ≈39 millions control volumes, the averaged velocity results showed excellent agreement between LES and MRV measurements, revealing the high prediction capability of the suggested LES tool for valve flows. Thirdly, the turbulent flow across the valve curtain clearly featured a back flow resulting in a high speed intake jet in the middle. Comprehensive LES data are generated to carry out statistical analysis in terms of (1) evolution of the turbulent morphology across the valve passage relying on the flow anisotropy map, (2) integral turbulent scales along the intake-charge stream, (3) turbulent flow properties such as turbulent kinetic energy, turbulent velocity and its intensity within the most critical zone in intake-port and along the port length, it further transpires that the most turbulence are generated across the valve passage and these are responsible for the in-cylinder turbulence.

Beschreibung: Electronic load (e-load) is essential equipment for power converter performance test, where a designated load profile is executed. Electronic load is usually implemented with the analog controller for fast tracking of the load profile reference. In this paper, a low-power low-cost electronic load is proposed. MOSFETs (metal-oxide-semiconductor field-effect transistors) are used as the power consumption devices, which are regulated to the active region as controlled current-sink. In order to achieve fast transient response using the low-cost digital signal controller (DSC) PWM peripherals, the interleaving PWM method is proposed to achieve active current ripple mitigation. To obtain the system open-loop gain for current-sink operation, an offline digital system identification method, followed by model reduction, is proposed by applying Pseudo-Random Binary Sequence (PRBS) excitation. Pole-zero cancelation method is used in the control system design and later implemented in a DSC. The prototype is built and tested, in which meaningful testing scenarios under constant current-sink mode, pulse current sink mode, and double line-frequency current mode are verified. The experimental results indicate that the proposed e-load can sink pre-programmed current profile with well-attenuated ripple for static and dynamic load testing, and is applicable to fully digitalized power testing equipment.

Beschreibung: A centrifugal carbon dioxide compressor is a kind of general machine with extensive applications. The geometry of the side chambers of the compressors can be determined by studying the rotor-stator cavity with centripetal through-flow. In this paper, numerical simulations were conducted to predict the characteristics of flow and heat transfer. Three different speeds of rotation and two axial gap widths were considered. The correlations of the core swirl ratios were determined by fitting the results for two axial gap widths. The amounts of the moment coefficients of the disk were predicted. In order to better analyze the temperature field, the radial distributions of the local heat transfer coefficient were numerically investigated. According to the simulation results, the average Nusselt number was found to be dominated by the turbulent flow parameter. It also seemed to be proportional to the moment coefficient at a fixed circumferential Reynolds number.

Beschreibung: The pattern of micro-electricity production of simple two-chamber microbial fuel cells (MFC) was monitored in this study. Piggery wastewater and anaerobic sludge served as fuel and inocula for the MFC, respectively. The output power, including voltage and current generation, of triplicate MFCs was measured using an on-line monitoring system. The maximum voltage obtained among the triplicates was 0.663 V. We also found that removal efficiency of chemical oxygen demand (COD) and biochemical oxygen demand (BOD) in the piggery wastewater was 94.99 and 98.63%, respectively. Moreover, analytical results of Fast Fourier Transform (FFT) demonstrated that the output current comprised alternating current (AC) and direct current (DC) components, ranging from mA to μA.

Beschreibung: When the offshore wind energy industry attempts to develop in cold regions, ice load becomes the main technological challenge for offshore wind turbine foundation design. Dynamic ice loads acting on wind turbine foundations should be calculated in a reasonable way. The scope of this study is to present a numerical model that considers the non-simultaneous ice crushing failure acting on the vertical structure of a wind turbine’s foundation. The local ice crushing force at the contact surface between the ice sheet and structure is calculated. The boundary of the ice sheet is updated at each time step based on the indentation length of the ice sheet according to its structure. Ice loads are validated against two model tests with three different structure models developed by other researchers. The time series of the ice forces derived from the simulation and model tests are compared. The proposed numerical model can capture the main trends of ice–wind turbine foundation interaction. The simulation results agree well with measured data from the model tests in terms of maximum ice force, which is a key factor for wind turbine design. The proposed model will be helpful for assisting the initial design of wind turbine foundations in cold regions.

Beschreibung: The optimum nitrogen concentration for media supplementation and strain dominance are aspects of key importance to the industrial production of ethanol with a view to reducing costs and increasing yields. In this work, these two factors were investigated for four ethanologenic Saccharomyces cerevisiae strains (CLQCA-INT-001, CLQCA-INT-005, CLQCA-10-099, and UCLM 325), selected from the screening of 150 isolates, mostly from Ecuadorian yeast biodiversity. The effect of nitrogen concentration was assessed in terms of cellular growth, glucose consumption and ethanol production, and the yeast strains’ dominance was evaluated in continuous co-fermentation with cellular recycling by mitochondrial DNA analyses. Among the four selected yeast strains under study, CLQCA-INT-005 presented the highest glucose consumption at a nitrogen supplement concentration as low as 0.4 g·L−1, attaining an ethanol yield of up to 96.72% in 24 h. The same yeast strain was found to be highly competitive, showing a dominance of 80% after four cycles of fermentation in co-culture. Thus, CLQCA-INT-005 may be deemed as a very promising candidate to be used both at pilot-plant scale and at industrial scale cellulosic ethanol production.

Beschreibung: In the past decade, the condensation of internal air humidity in automotive headlamps has become more prevalent than ever due to the increased usage of a new light source—LEDs. LEDs emit far less heat than previously-used halogen lamps, which makes them far more susceptible to fogging. This fogging occurs when the internal parts of the headlamp fall to a temperature below the dew point. The front glass is most vulnerable to condensation due to its direct exposure to ambient conditions. Headlamp fogging leads to a decrease in performance and the possibility of malfunctions, which has an impact not only on the functional aspect of the product’s use but also on traffic safety. There are currently several technical solutions available which can determine the effectivity of ventilation systems applied for headlamp defogging. Another approach to this problem may be to use a numerical simulation. This paper proposes a CFD (computational fluid dynamics) simulation with a slightly simplified 3D model of an actual headlamp, which allows simulation of all the phenomena closely connected with fluid flow and phase change. The results were validated by real experiments on a special fogging–defogging test rig. This paper compares three different simulations and their compliance with real experiments.

Beschreibung: The depletion and usage of fossil fuels causes environmental issues and alternative fuels and technologies are urgently required. Therefore, thermal arc water vapor plasma for a fast and robust waste/biomass treatment is an alternative to the syngas method. Waste cooking oil (WCO) can be used as an alternative potential feedstock for syngas production. The goal of this experimental study was to conduct experiments gasifying waste cooking oil to syngas. The WCO was characterized in order to examine its properties and composition in the conversion process. The WCO gasification system was quantified in terms of the produced gas concentration, the H2/CO ratio, the lower heating value (LHV), the carbon conversion efficiency (CCE), the energy conversion efficiency (ECE), the specific energy requirements (SER), and the tar content in the syngas. The best gasification process efficiency was obtained at the gasifying agent-to-feedstock (S/WCO) ratio of 2.33. At this ratio, the highest concentration of hydrogen and carbon monoxide, the H2/CO ratio, the LHV, the CCE, the ECE, the SER, and the tar content were 47.9%, 22.42%, 2.14, 12.7 MJ/Nm3, 41.3% 85.42%, 196.2 kJ/mol (or 1.8 kWh/kg), and 0.18 g/Nm3, respectively. As a general conclusion, it can be stated that the thermal arc-plasma method used in this study can be effectively used for waste cooking oil gasification to high quality syngas with a rather low content of tars.

Beschreibung: Recently, the importance of individual pitch control (IPC) capability in wind turbine systems has been emphasized to achieve the desired power performance and mitigate the aerodynamic imbalance load for the mechanical integrity. Compared to collective pitch control (CPC), which assigns identical pitch angles for all employed blades, IPC is capable of generating other various sets of pitch angles to manipulate the aerodynamic load. Thus, the mechanical elements of wind turbine systems may take advantages from this variation, which allows wind turbines to have lighter designs and longer lifetimes. One of the essential mechanical components in the wind turbine is a primary bearing supporting the blades–rotor–shaft unit, which has not been fully investigated yet among the structural elements in the wind turbine system. In this regard, this research focuses on predicting the bearing life span of a NACA64-A17 two-blade 5-MW wind turbine system for the domains of allowable individual pitch angles by IPC. In particular, under the effect of various wind speeds, a bearing life span was determined based on the average value of load cases—satisfying both appropriate power level and the allowable domain of pitch control angles, which were possibly conveyed by IPC—and the result was compared with the bearing life predicted based on the domain of pitch angles, as generated by the CPC strategy. Consequently, in the ranges of high wind speeds, it was found that the average applied load to the bearing is reduced under the domain of the IPC-based pitch angle, resulting in possibly increasing the life span of the bearing. With the presented results, it is hoped that this work will provide important insights for those that majorly concern designing the primary bearing of the IPC-based wind turbine system.

Beschreibung: The selective catalytic reduction (SCR) methodology is notably recognized as the widely applied strategy for NOX control in exhaust after-treatment technologies. In real SCR systems, complex unsteady turbulent multi-phase flow phenomena including poly-dispersed AdBlue® spray evolve with a wide ranging relative velocity between the droplet phase and carrier gas phase. This results from an AdBlue® spray that is injected into a mixing pipe which is cross-flowing by a hot exhaust gas. To reduce the complexity while gaining early information on the injected droplet size and velocity needed for a minimum deposition and optimal conversion, a single droplet with a specified diameter is addressed to mimic a spray featuring the same Sauter Mean Diameter. For that purpose, effects of turbulent hot cross-flow on thermal decomposition processes of a single AdBlue® droplet are numerically investigated. Thereby, a single AdBlue® droplet is injected into a hot cross-flowing stream within a mixing pipe in which it may experience phase change processes including interaction with the pipe wall along with liquid wall–film and possible solid deposit formation. First of all, the prediction capability of the multi-component evaporation model and thermal decomposition is evaluated against the detailed simulation results for standing droplet case for which experimental data is not available. Next, exploiting Large Eddy Simulation features the effect of hot turbulent co- and cross-flowing streams on the dynamic droplet characteristics and on the droplet/wall interaction is analyzed for various droplet diameters and operating conditions. This impact is highlighted in terms of droplet evaporation time, decomposition efficiency, droplet trajectories and wall–film formation. It turns out that smaller AdBlue® droplet diameter, higher gas temperature and relative velocity lead to shorter droplet life time as the droplet evaporates faster. Under such conditions, possible droplet/wall interaction processes on the pipe wall or at the entrance front of the monolith may be avoided. Since the ammonia (NH3) gas generated by urea decomposition is intended to reduce NOX emission in the SCR system, it is apparent for the prediction of high NOX removal performance that UWS injector system which allows to realize such operating conditions is favorable to support high conversion efficiency of urea into NH3.

Beschreibung: In today’s connected world, there is a tendency of connectivity even in the sectors which conventionally have been not so connected in the past, such as power systems substations. Substations have seen considerable digitalization of the grid hence, providing much more available insights than before. This has all been possible due to connectivity, digitalization and automation of the power grids. Interestingly, this also means that anybody can access such critical infrastructures from a remote location and gone are the days of physical barriers. The power of connectivity and control makes it a much more challenging task to protect critical industrial control systems. This capability comes at a price, in this case, increasing the risk of potential cyber threats to substations. With all such potential risks, it is important that they can be traced back and attributed to any potential threats to their roots. It is extremely important for a forensic investigation to get credible evidence of any cyber-attack as required by the Daubert standard. Hence, to be able to identify and capture digital artifacts as a result of different attacks, in this paper, the authors have implemented and improvised a forensic testbed by implementing a sandboxing technique in the context of real time-hardware-in-the-loop setup. Newer experiments have been added by emulating the cyber-attacks on WAMPAC applications, and collecting and analyzing captured artifacts. Further, using sandboxing for the first time in such a setup has proven helpful.

Beschreibung: Understanding the rheological behavior of cement slurries is important in cement and petroleum industries. In this paper, we study the fully developed flow of a cement slurry inside a wellbore. The slurry is modeled as a non-linear fluid, where a constitutive relation for the viscous stress tensor based on a modified form of the second grade (Rivlin–Ericksen) fluid is used;we also propose a diffusion flux vector for the concentration of particles. The one-dimensional forms of the governing equations and the boundary conditions are made dimensionless and solved numerically. A parametric study is performed to present the effect of various dimensionless numbers on the velocity and the volume fraction profiles.

Beschreibung: In recent years, due to the favorable climate conditions of Iran, the cultivation of rapeseed has increased significantly. The aim of this study was to investigate the possibility of biodiesel production from one genotype of rapeseed (TERI (OE) R-983). An ultrasonic approach was used in order to intensify the reaction. Response surface methodology (RSM) was applied to identify the optimum conditions of the process. The results of this research showed that the conversion of biodiesel was found to be 87.175% under the optimized conditions of a 4.63:1 molar ratio (methanol to oil), 56.50% amplitude, and 0.4 s pulses for a reaction time of 5.22 min. Increasing the operating conditions, such as the molar ratio from 4:1 to 5.5:1, amplitude from 50% to 72.5%, reaction time from 3 min to 7 min, and pulse from 0.4 s to 1 s, increased the FAME (fatty acid methyl esters) yield by approximately 4.5%, 2.3%, 1.2%, and 0.5%, respectively. The properties of the TERI (OE) R-983 methyl ester met the requirements of the biodiesel standard (ASTM D6751), indicating the potential of the produced biodiesel as an alternative fuel.

Beschreibung: Microbes can mediate the precipitation of primary dolomite under surface conditions. Meanwhile, primary dolomite mediated by microbes often contains more Fe2+ than standard dolomite in modern microbial culture experiments. Ferroan dolomite and ankerite have been regarded as secondary products. This paper reviews the process and possible mechanisms of microbial mediated precipitation of primary ferroan dolomite and/or ankerite. In the microbial geochemical Fe cycle, many dissimilatory iron-reducing bacteria (DIRB), sulfate-reducing bacteria (SRB), and methanogens can reduce Fe3+ to Fe2+, while SRB and methanogens can also promote the precipitation of primary dolomite. There are an oxygen respiration zone (ORZ), an iron reduction zone (IRZ), a sulfate reduction zone (SRZ), and a methanogenesis zone (MZ) from top to bottom in the muddy sediment diagenesis zone. DIRB in IRZ provide the lower section with Fe2+, which composes many enzymes and proteins to participate in metabolic processes of SRB and methanogens. Lastly, heterogeneous nucleation of ferroan dolomite on extracellular polymeric substances (EPS) and cell surfaces is mediated by SRB and methanogens. Exploring the origin of microbial ferroan dolomite may help to solve the “dolomite problem”.

Beschreibung: Pyrometallurgical processing of ore from the Zeehan mineral field was performed intermittently between 1896 and 1948, primarily recovering Pb, Ag and Cu. While Zn recovery was attempted at the time, it was unsuccessful using the available technology. Consequently, Zn reported to the slag during the smelting process. Today, the former smelter site consists of two large slag piles (North and South). Using a range of techniques (including X-ray diffractometry, scanning electron microscopy, laser ablation inductively coupled plasma mass spectrometry, and static testing) the geometallurgical and geo-environmental properties of these slag materials (n = 280) were determined. The South and North piles contain on average 15% and 11% Zn, respectively. A range of complex mineral phases were identified, and are dominated by glass, silicates (i.e., monticellite–kirschsteinite and hardystonite), oxides (gahnite and hercynite) and minor sulfides (sphalerite and wurtzite). Microtextural examinations defined nine mineral phases (Glass A, Silicates A to D, Oxides A and B, Sulfides A and B). Zn was concentrated in Sulfide A (26%), Glass A (24%) and the Silicates (43%), while Pb was concentrated in Oxide B (76%), with Sulfide B host to the highest Ag (45%) and Cu (65%). Considering this, recovery of Zn using conventional hydrometallurgical processes (i.e., sulfuric acid leaching) is suitable, however the application of unconventional biohydrometallurgical techniques could be explored, as well re-smelting. These slag materials are classified geo-environmentally as potentially acid forming, with leachate concentrations of Zn, Pb consistently above ANZECC (2000) aquatic ecosystem 80% protection guideline values, and, for the majority of samples, exceedances of Cu, Ni and Cd were also measured. Considering these findings, reprocessing of these historic slags for Zn extraction may provide an economically feasible management option for rehabilitating this historical site.

Beschreibung: New findings of silicate-melt inclusions in two alluvial diamonds (from the Kholomolokh placer, northeastern Siberian Platform) are reported. Both diamonds exhibit a high degree of N aggregation state (60–70% B) suggesting their long residence in the mantle. Raman spectral analysis revealed that the composite inclusions consist of clinopyroxene and silicate glass. Hopper crystals of clinopyroxene were observed using scanning electron microscopy and energy-dispersive spectroscopic analyses; these are different in composition from the omphacite inclusions that co-exist in the same diamonds. The glasses in these inclusions contain relatively high SiO2, Al2O3, Na2O and, K2O. These composite inclusions are primary melt that partially crystallised at the cooling stage. Hopper crystals of clinopyroxene imply rapid cooling rates, likely related to the uplift of crystals in the kimberlite melt. The reconstructed composition of such primary melts suggests that they were formed as the product of metasomatised mantle. One of the most likely source of melts/fluids metasomatising the mantle could be a subducted slab.

Beschreibung: The nature of upper mantle is important to understand the evolution of the South China Sea (SCS); thus, we need better constrains on its mantle heterogeneity. Magma water concentration is a good indicator, but few data have been reported. However, the rarity of glass and melt inclusions and the special genesis for phenocrysts in SCS basalts present challenges to analyzing magmatic water content. Therefore, it is possible to estimate the water variations through the characteristics of partial melting and magma crystallization. We evaluated variations in Fe depletion, degree of melt fractions, and mantle source composition along the fossil spreading ridge (FSR) using SCS basalt data from published papers. We found that lava from the FSR 116.2° E, FSR 117.7° E, and non-FSR regions can be considered normal lava with normal water content; in contrast, lava from the FSR 117° E-carbonatite and 114.9–115.0° E basalts have higher water content and show evidence of strong Fe depletion during the fractional crystallization after elimination of the effects of plagioclase oversaturation. The enriched water in the 117° E-carbonatite basalts is contained in carbonated silicate melts, and that in the 114.9–115.0° E basalts results from mantle contamination with the lower continental crust. The lava from the 117° E-normal basalt has much lower water content because of the lesser influence of the Hainan plume. Therefore, there must be a mantle source compositional transition area between the southwestern and eastern sub-basins of the SCS, which have different mantle evolution histories. The mantle in the west is more affected by contamination with continental materials, while that in the east is more affected by the Hainan mantle plume.

Beschreibung: The large-scale Maoping W–Sn deposit in the Gannan metallogenic belt of the eastern Nanling Range, South China, spatially associated with the Maoping granite pluton, hosts total ore reserves of 103,000 t WO3 and 50,000 t Sn. Two different types of mineralization developed in this deposit: Upper quartz vein-type mineralization, mostly within the Cambrian metamorphosed sandstone and slate, and underneath greisen-type mineralization within the Maoping granite. Cassiterites from both types of mineralization coexist with wolframite. Here we report for the first time in situ U–Pb data on cassiterite and zircon of the Maoping deposit obtained by LA-ICP-MS. Cassiterite from quartz vein and greisen yielded weighted average 206Pb/238U ages of 156.8 ± 1.5 Ma and 156.9 ± 1.4 Ma, respectively, which indicates that the two types of mineralization formed roughly at the same time. In addition, the two mineralization ages are consistent with the emplacement age of the Maoping granite (159.0 ± 1.5 Ma) within error, suggesting a close temporal and genetic link between W–Sn mineralization and granitic magmatism. The two types of mineralization formed at the same magmatic-hydrothermal event. Cassiterite from both types of mineralization shows high Fe, Ta, and Zr contents with a low Zr/Hf ratio, suggesting that the ore-forming fluid should be derived from the highly differentiated Maoping granite pluton. Cassiterite in greisen has higher contents of Nb and Ta but a lower concentration of Ti compared with that in quartz vein, indicating that the formation temperature of greisen-type mineralization is little higher than that of quartz-vein-type mineralization.

Beschreibung: The heat exchanger in a gas instantaneous water heater is a thermal device used for heat transfer from the high-temperature flue gas to the low-temperature water. The fireside corrosion, due to the reaction of acidic condensate formed on the heat exchanger surfaces and its metallic material, is one of the major hazards for gas instantaneous water heaters. This paper focuses on identifying and quantifying the fireside corrosion on the surface of heat exchangers in gas-fired instantaneous water heaters. Durability tests lasting for 2000 cycles were undertaken for five gas-fired instantaneous water heaters, which were different in terms of the heat input and coating of heat exchangers. The corrosion deposits on the surface of the heat exchangers were surveyed by several methods. The results show that the corrosion deposit grew as the test duration increased. The fins of the heat exchanger with a lead coating had been corroded and copper was exposed. Cu4(OH)6SO4 was the main corrosion product of heat exchangers without a lead coating, whereas PbSO4 was the main corrosion product of heat exchangers with a lead coating. The experiments demonstrate that the corrosion rate decreased with the increase of the heat input. The experiments also show that the thermal efficiency of gas instantaneous water heaters decreased by 2.4% to 6% at the end of the test duration.

Beschreibung: Combustion condition monitoring is a fundamental and critical issue that needs to be addressed in the wide-load operation of coal-fired boilers. In this paper, an unsupervised classification framework based on the convolutional auto-encoder (CAE), the principal component analysis (PCA), and the hidden Markov model (HMM) is proposed to monitor the combustion condition with the uniformly spaced flame images, which are collected from the furnace combustion monitoring system. First, CAE is adopted to extract the features from the flame images, which obtain the sparse representations in the images. Then, PCA is applied to project the feature vectors into the orthogonal space for robustness and computation efficiency. Finally, a HMM is built to calculate the corresponding optimal states by learning the temporal behaviors in the compressed representations. A coal combustion adjustment experiment was conducted in a 660 MW opposed-firing boiler, and the sequential 14,400 flame images with three different combustion states were obtained to evaluate the effectiveness of the proposed approach. We tested six different compression dimensions of the latent variable z in the CAE model and ensured that the appropriate compress parameter was 1024. The proposed framework is compared with five other methods: the CAE + Gaussian mixture model (GMM), CAE + Kmean, the CAE + fuzzy c-mean method, CAE + HMM, and the traditional handcraft feature extraction method (TH) + HMM. The results show that the proposed framework has the highest classification accuracy (95.25% for the training samples and 97.36% for the testing samples) and has the best performance in recognizing the semi-stable state (85.67% for the training samples and 77.60% for the testing samples), indicating that the proposed framework is capable of identifying the combustion condition, changing when the combustion deteriorates as the coal feed rate falls.

Beschreibung: Confronting an energy crisis, the government of Ghana enacted a power factor correction policy in 1995. The policy imposes a penalty on large-scale electricity users, namely, special load tariff (SLT) customers of the Electricity Company of Ghana (ECG), whose power factor is below 90%. This paper investigates the impact of this policy on these firms’ power factor improvement by using panel data from 183 SLT customers from 1994 to 1997 and from 2012. To avoid potential endogeneity, this paper adopts a regression discontinuity design (RDD) with the power factor of the firms in the previous year as a running variable, with its cutoff set at the penalty threshold. The result shows that these large-scale electricity users who face the penalty because their power factor falls just short of the threshold are more likely to improve their power factor in the subsequent year, implying that the power factor correction policy implemented by Ghana’s government is effective.

Beschreibung: The phase-out of nuclear energy in Germany will take place in 2022. A site for final disposal of high-level radioactive waste (HLRW) has not yet been chosen, but a site selection process was restarted by the Site Selection Act in 2017. This Act was based on a recommendation by a commission which also advised to follow up the development of deep borehole disposal (DBD) as a possible option for final disposal of HLRW. This paper describes briefly the status of DBD in Germany and if this option is to be pursued in Germany. Although DBD has some merits, it can only be a real option if supported by research and development. The technical equipment for larger boreholes of the required size will only be developed if there is funding and a feasibility test. Furthermore, any DBD concept must be detailed further, and some requirements of the Act must be reconsidered. Therefore, the support of DBD will likely remain at a low level if there are no political changes.

Beschreibung: Life cycle assessment (LCA) is an established method to assess the various environmental impacts associated with all the stages of a building. The goal of this project was to calculate the environmental releases for a whole office building and investigate the contribution in terms of environmental impact for different parts of the building, as well as the impact from different stages of the life cycle. The construction process was followed up during production and the contractors provided real-time data on the input required in terms of building products, transport, machinery, energy use, etc. The results are presented for five environmental impact categories and, as expected, materials that constitute the main mass of the building and the energy used during operation contribute the largest share of environmental impact. It is usually difficult to evaluate the environmental impact of the materials in technical installations due to the lack of data. However, in this study, the data were provided by the contractors directly involved in the construction and can, therefore, be considered highly reliable. The results show that materials for installations have a significant environmental impact for four of the environmental impact categories studied, which is a noteworthy finding.

Beschreibung: The Postmasburg Manganese Field (PMF), Northern Cape Province, South Africa, once represented one of the largest sources of manganese ore worldwide. Two belts of manganese ore deposits have been distinguished in the PMF, namely the Western Belt of ferruginous manganese ores and the Eastern Belt of siliceous manganese ores. Prevailing models of ore formation in these two belts invoke karstification of manganese-rich dolomites and residual accumulation of manganese wad which later underwent diagenetic and low-grade metamorphic processes. For the most part, the role of hydrothermal processes and metasomatic alteration towards ore formation has not been adequately discussed. Here we report an abundance of common and some rare Al-, Na-, K- and Ba-bearing minerals, particularly aegirine, albite, microcline, banalsite, sérandite-pectolite, paragonite and natrolite in Mn ores of the PMF, indicative of hydrothermal influence. Enrichments in Na, K and/or Ba in the ores are generally on a percentage level for most samples analysed through bulk-rock techniques. The presence of As-rich tokyoite also suggests the presence of As and V in the hydrothermal fluid. The fluid was likely oxidized and alkaline in nature, akin to a mature basinal brine. Various replacement textures, particularly of Na- and K- rich minerals by Ba-bearing phases, suggest sequential deposition of gangue as well as ore-minerals from the hydrothermal fluid, with Ba phases being deposited at a later stage. The stratigraphic variability of the studied ores and their deviation from the strict classification of ferruginous and siliceous ores in the literature, suggests that a re-evaluation of genetic models is warranted. New Ar-Ar ages for K-feldspars suggest a late Neoproterozoic timing for hydrothermal activity. This corroborates previous geochronological evidence for regional hydrothermal activity that affected Mn ores at the PMF but also, possibly, the high-grade Mn ores of the Kalahari Manganese Field to the north. A revised, all-encompassing model for the development of the manganese deposits of the PMF is then proposed, whereby the source of metals is attributed to underlying carbonate rocks beyond the Reivilo Formation of the Campbellrand Subgroup. The main process by which metals are primarily accumulated is attributed to karstification of the dolomitic substrate. The overlying Asbestos Hills Subgroup banded iron formation (BIF) is suggested as a potential source of alkali metals, which also provides a mechanism for leaching of these BIFs to form high-grade residual iron ore deposits.

Beschreibung: Mixed cyanobacteria-dominated biofilms, enriched from a tributary of the Mérantaise (France) were used to conduct laboratory experiments in order to understand the relationship between the morphology of carbonate precipitates and the biological activity (e.g., cyanobacterial exopolymeric substances (EPS) production, photosynthetic pH increases). DNA sequencing data showed that the enriched biofilm was composed predominantly of two types of filamentous cyanobacteria that belonged to the Oscillatoriaceae and Phormidiaceae families, respectively. Microscopic analysis also indicated the presence of some coccoid cyanobacteria resembling Gloeocapsa. Analysis of carbonate precipitates in experimental biofilms showed three main morphologies: micro-peloids with different shapes of mesocrystals associated with Oscillatoriaceae filaments and theirs EPS, lamellae of carbonate formed directly on Phormidiaceae filaments, and rhombic sparite crystals wrapped in EPS. All crystals were identified by FT-IR spectroscopy as calcite. Similar structures as those that formed in laboratory conditions were observed in the microbial-tufa deposits collected in the stream. Microscopic and spectroscopic analysis of laboratory and natural samples indicated a close proximity of the cyanobacterial EPS and precipitated carbonates in both. Based on the laboratory experiments, we conclude that the microbial tufa in the stream is in an early stage of formation.

Beschreibung: Considering the manufacturing of automotive components, there exists a dilemma around the substitution of traditional cast iron (CI) with lighter metals. Currently, aluminum alloys, being lighter compared to traditional materials, are considered as a more environmentally friendly solution. However, the energy required for the extraction of the primary materials and manufacturing of components is usually not taken into account in this debate. In this study, an extensive literature review was performed to estimate the overall energy required for the manufacturing of an engine cylinder block using (a) cast iron and (b) aluminum alloys. Moreover, data from over 100 automotive companies, ranging from mining companies to consultancy firms, were collected in order to support the soundness of this investigation. The environmental impact of the manufacturing of engine blocks made of these materials is presented with respect to the energy burden; the “cradle-to-grave approach” was implemented to take into account the energy input of each stage of the component life cycle starting from the resource extraction and reaching to the end-of-life processing stage. Our results indicate that, although aluminum components contribute toward reduced fuel consumption during their use phase, the vehicle distance needed to be covered in order to compensate for the up-front energy consumption related to the primary material production and manufacturing phases is very high. Thus, the substitution of traditional materials with lightweight ones in the automotive industry should be very thoughtfully evaluated.

Beschreibung: To prevent serious shaft deflection disasters under asymmetric mining conditions, it is urgent to solve the problem of designing shaft protection rock pillar (SPRP) sizes in thick soil and thin rock strata. In this paper, based on the parallel mining model and the perpendicular mining model, a dynamic prediction model that can describe the horizontal movement of the shaft was established by the probability integration method and the Knothe time function. Next, according to the measured data of the shaft deflection in the Guotun Coal Mine, a back analysis was used to calculate the prediction parameters that were suitable for the deep soil strata. Based on the mining model, the variation law of the horizontal deflection displacement of the shaft and SPRP size was obtained. The results showed that the final displacements of the shaft under the two ideal mining models were equal, while the parallel mining model was superior to the perpendicular mining model at the initial stage of mining. The horizontal displacement of the shaft head had a nonlinear negative correlation with the SPRP, and the SPRP size in thick soil and thin rock strata calculated by the parallel mining model was more reasonable. For the Guotun Coal Mine, when the soil movement angle was 57.8% of the actual value, the horizontal displacement of the main shaft head was reduced by 87%. The results have important theoretical and practical value in preventing shaft deflection in thick soil and thin rock strata.

Beschreibung: The authors would like to add the following note in the Affiliation Section of their paper published in Energies [...]

Beschreibung: In this study, p-type amorphous silicon oxide (a-SiOx) films are deposited using a radio-frequency inductively-coupled plasma chemical vapor deposition system. Effects of the CO2 gas flow rate on film properties and crystalline silicon heterojunction (HJ) solar cell performance are investigated. The experimental results show that the band gap of the a-SiOx film can reach 2.1 eV at CO2 flow rate of 10 standard cubic centimeters per minute (sccm), but the conductivity of the film deteriorates. In the device simulation, the transparent conducting oxide and contact resistance are not taken into account. The electrodes are assumed to be perfectly conductive and transparent. The simulation result shows that there is a tradeoff between the increase in the band gap and the reduction in conductivity at increasing CO2 flow rate, and the balance occurs at the flow rate of six sccm, corresponding to a band gap of 1.95 eV, an oxygen content of 34%, and a conductivity of 3.3 S/cm. The best simulated conversion efficiency is 25.58%, with an open-circuit voltage of 741 mV, a short-circuit current density of 42.3 mA/cm2, and a fill factor of 0.816%.

Beschreibung: The loading-to-flow diagram is a widely used classical method for the preliminary design of radial turbines. This study improves this method to optimize the design of radial turbines in the early design phase under variable operating conditions. The guide vane outlet flow angle is a key factor affecting the off-design performance of the radial turbine. To optimize the off-design performance of radial turbines in the early design phase, we propose a hypothesis that uses the ratio of the mean velocity of the fluid relative to the rotor passage with respect to the circumferential velocity of the rotor as an indicator to indirectly and qualitatively estimate the rotor loss, as it plays a key role in the off-design efficiency. Theoretical analysis of rotor loss characteristics under different types of variable operating conditions shows that a smaller design value of guide vane outlet flow angle results in a better off-design performance in the case of a reduced mass flow. In contrast, radial turbines with a larger design value of guide vane outlet flow angle can obtain a better off-design performance with increased mass flow. The above findings were validated with a mean-line model method. Furthermore, this study discusses the optimization of the design value of guide vane outlet flow angle based on the matching of rotor loss characteristics with specified variable operating conditions. It provides important guidance for the design optimization of multistage radial turbines with variable operating conditions in compressed air energy storage (CAES) systems.

Beschreibung: This paper explores the alternative roles hydrogen can play in the future European Union (EU) energy system, within the transition towards a carbon-neutral EU economy by 2050, following the latest policy developments after the COP21 agreement in Paris in 2015. Hydrogen could serve as an end-use fuel, a feedstock to produce carbon-neutral hydrocarbons and a carrier of chemical storage of electricity. We apply a model-based energy system analysis to assess the advantages and drawbacks of these three roles of hydrogen in a decarbonized energy system. To this end, the paper quantifies projections of the energy system using an enhanced version of the PRIMES energy system model, up to 2050, to explore the best elements of each role under various assumptions about deployment and maturity of hydrogen-related technologies. Hydrogen is an enabler of sectoral integration of supply and demand of energy, and hence an important pillar in the carbon-neutral energy system. The results show that the energy system has benefits both in terms of CO2 emission reductions and total system costs if hydrogen technology reaches high technology readiness levels and economies of scale. Reaching maturity requires a significant investment, which depends on the positive anticipation of market development. The choice of policy options facilitating visibility by investors is the focus of the modelling in this paper.

Beschreibung: Understanding the details of micro-scale wind fields is important in the development of wind energy. Research has proven that coupling Numerical Weather Prediction (NWP) and Computational Fluid Dynamics (CFD) models is a better approach for micro-scale wind field simulation. The main purpose of this work is to improve the NWP/CFD model performance in two parts: (i) developing a new coupling method that is more suitable for complex terrain between the NWP and CFD models, and (ii) applying a data assimilation system in the CFD model. Regarding part (i), in order to solve the problem of great topographical difference at the domain boundaries between the two models, Cressman interpolation is utilized to impose the NWP model wind on the CFD model boundaries. In part (ii), an assimilation method, nudging, to apply assimilation of observations into the CFD model is explored. Based on the Cressman interpolation coupling method, a preliminary implementation of data assimilation is performed. The results show that the NWP/CFD model with the improved coupling method may capture the details of micro-scale wind fields more accurately. Using data assimilation, the NWP/CFD model performance may be further improved by cooperating observation data.

Beschreibung: This article describes an aging study of a foam-vacuum insulation panel (VIP) composite insulation board installed on a test wall in a natural exposure test facility through a 30-month period. Silica-based VIPs with a polymeric barrier film were used in this study. The study results showed the effectiveness of a VIP-based insulation to reduce the heat gains and losses through a wall compared to regular rigid foam insulation of the same thickness. However, the long-term performance monitoring indicated a gradual decline in the thermal performance of the foam-VIP composite. In addition, one-dimensional numerical models were created to simulate the in situ behavior of the foam-VIP composite. One model utilized constant thermal conductivities of the test wall components and another utilized temperature-dependent thermal conductivities; the latter used measurements of conductivity over temperatures ranging from −15 to 55 °C. The results of the simulations emphasized the need to use both temperature and time-dependent material properties for accurately predicting the long-term performance of VIP-based insulation systems.

Beschreibung: Land use changes have significantly altered the natural environment in which humans live. In urban areas, diminishing air quality poses a large threat to human health. In order to investigate the relationship between land use/cover change (LUCC) and air pollutants of Wuyishan City between 2014–2017, an integrated approach was used by combining remote sensing techniques with a landscape ecology methods. Annual, seasonal, and weekly mean values of air pollutant (SO2, NO2, CO, PM10, O3, PM2.5, black carbon) concentration and atmospheric visibility were calculated to develop a Pearson correlation between LUCC and air pollutants concentration. Results showed an increase in forested areas (1.79%) and water areas (15.89%), with a simultaneous reduction in cultivated land (6.47%), bare land (72.61%), and built-up land (16.03%) from 2014 to 2017. The transition matrix of land use types revealed that (i) forest expansion took place mainly at the expense of cultivated land (13.94%) and bare land (27.48%); and (ii) water area expansion took place mainly at the expense of cultivated land (1.29%) and forests (0.21%). In 2017, the proportion of days with AQI level I (94.52%) was higher than that in 2014 (88.77%). Additionally, the annual average visibility in 2017 (37.42 km) was higher than 2014 (27.46 km). The concentration of SO2, CO, O3, and black carbon was positively correlated with the cultivated land. The concentration of SO2, CO, and black carbon negatively correlated with the increase of forests. PM10, and PM2.5 is negatively correlated with the water area. Visibility was found to be positively correlated with forested area, and negatively correlated with cultivated land. The findings from this study represent a valuable gain in understanding of policies aimed at improving, safeguarding, and monitoring air quality. These results can be used to inform land-use planning decisions in a comprehensive way and could be a valuable tool for LUCC rational management strategies.

Beschreibung: A comparative study regarding the performance of real-scale oil-free centrifugal chillers having the flooded evaporator or falling film evaporator was conducted in this study. The nominal capacity for the test chillers was around 200~230 USRT (US refrigeration ton) (703~809 kW). The compressors of the two chillers were identical and R-134a was used as the working fluid. Both evaporators employed the same enhanced tubes (GEWA-B) to fulfill phase change. Tests were conducted in full, 75%, 50%, and 25% loading. Test results indicate that both chillers contained a comparable system performance with an integrated part-load value of around 8.62~8.63. The overall heat transfer coefficient for the flooded evaporator was appreciably higher (20~40%) than the falling film evaporator. This is because the falling film flowrate was below the threshold value and the heat transfer was dominated by evaporation mode. Yet, the heat transfer performance for the falling film evaporator was further jeopardized due to starvation of the film flowrate (partial dry-out), especially in the middle or bottom of the tube bundle. This phenomenon became even more pronounced at partial loading (25%), whereas the flooded evaporator did not reveal such a performance dip at partial loading.

Beschreibung: This study examines the effect of mixing on the performance of anaerobic digestion of cow manure in Chinese dome digesters (CDDs) at ambient temperatures (27–32 °C) in comparison with impeller mixed digesters (STRs) and unmixed digesters (UMDs) at the laboratory scale. The CDD is a type of household digester used in rural and pre-urban areas of developing countries for cooking. They are mixed by hydraulic variation during gas production and gas use. Six digesters (two of each type) were operated at two different influent total solids (TS) concentration, at a hydraulic retention time (HRT) of 30 days for 319 days. The STRs were mixed at 55 rpm, 10 min/hour; the unmixed digesters were not mixed, and the Chinese dome digesters were mixed once a day releasing the stored biogas under pressure. The reactors exhibited different specific biogas production and treatment efficiencies at steady state conditions. The STR 1 exhibited the highest methane (CH4) production and treatment efficiency (volatile solid (VS) reduction), followed by STR 2. The CDDs performed better (10% more methane) than the UMDs, but less (approx. 8%) compared to STRs. The mixing regime via hydraulic variation in the CDD was limited despite a higher volumetric biogas rate and therefore requires optimization.

Beschreibung: The paper presents a new concept of a vertical axis wind turbine. The idea is focused on small wind turbines, and therefore, the dominating quality is safety. Another important necessary feature is efficient operation at small winds. This implies an application of the drag driven solution such as the Savonius rotor. The presented concept is aimed at reducing the rotor size and the cost of implementation. A new wind turbine solution, its efficiency, and functionality are described. The results of numerical simulations being a proof of the concept are reported. The simulations were followed by wind tunnel tests. Finally several prototypes were built and investigated for a longer period of time. The new wind turbine concept has undergone various testing and implementation efforts, making this idea matured, well proven and documented. A new feature, namely, the wind turbine size reduction at strong winds, or in other words, an increase in the wind turbine size at low winds is the reason why it is difficult to compare this turbine with other turbines on the market. The power output depends not only on the turbine efficiency but also on its varying size.

Beschreibung: The shift from fossil fuel to more renewable electricity generation will require the broader implementation of Demand Side Response (DSR) into the grid. Utility processes in industry are suited for this, having a large thermal time constant or buffer, and large electricity consumption. A widespread utility system in industry is an induced draft evaporative cooling tower. Considering the safety aspect, such a process needs to maintain cooling water temperature within predefined safe boundaries. Therefore, in this paper, two modelling methods for the prediction of the basin temperature of an induced draft evaporative cooling tower are proposed. Both a white box and a black box methodology are presented, based on the physical principles of fluid dynamics and adaptive neuro-fuzzy interference system (ANFIS) modelling, respectively. By analysing the accuracy of both models with a focus to cooling tower fan state changes, i.e., DSR purposes, it is shown that the white box model performs best. Fostering the idea of using such a system for DSR purposes, the concept of design for flexibility is also touched upon, discussing the thermal mass. Pre-cooling, where the temperature of the cooling water basin is lowered before a fan switch off period, was simulated with the white box model. It was shown that beneficial pre-cooling (to lower the temperature peak) is limited in time.

Beschreibung: I would like to take the occasion of writing this newsletter to draw a sort of summary of our publishing activities at Energies and of the results and perspectives [...]

Beschreibung: Microalgae is considered as an excellent potential renewable source of fuel in many forms including powder or slurry. A high percentage of emulsified water in the fuel is reported to reduce diesel engines’ emissions such as NOx, but that will compromise the engine output power. Using microalgae powder as an additive to enhance the emulsified water fuel heating value is the main objective of this work. Diesel engine combustion, vibration, performance and emissions were evaluated for pure cottonseed biodiesel (CS-B100), emulsified water 20% (vol.) in cottonseed biodiesel (CSB-E20) and emulsified water 20% (vol.) containing Fresh Water Microalgae Chlorella Vulgaris (FWM-CV) in cottonseed biodiesel (CSB-ME20). The emulsified water fuels showed a reduction in in-cylinder pressure, vibration, brake power, torque, exhaust gas temperature, CO2 and NOx, while BSFC and O2 were higher than the pure biodiesel (CS-B100). CSB-ME20 produced higher power and torque than CSB-E20 due to the presence of microalgae in the fuel that increased the energy content of the fuel.

Beschreibung: We present a joint 2D inversion approach for magnetotelluric (MT) and gravity data with elastic-net regularization and cross-gradient constraints. We describe the main features of the approach and verify the inversion results against a synthetic model. The results indicate that the best fit solution using the L2 is overly smooth, while the best fit solution for the L1 norm is too sparse. However, the elastic-net regularization method, a convex combination term of L2 norm and L1 norm, can not only enforce the stability to preserve local smoothness, but can also enforce the sparsity to preserve sharp boundaries. Cross-gradient constraints lead to models with close structural resemblance and improve the estimates of the resistivity and density of the synthetic dataset. We apply the novel approach to field datasets from a copper mining area in the northeast of China. Our results show that the method can generate much more detail and a sharper boundary as well as better depth resolution. Relative to the existing solution, the large area divergence phenomenon under the anomalous bodies is eliminated, and the fine anomalous bodies boundary appeared in the smooth region. This method can provide important technical support for detecting deep concealed deposits.

Beschreibung: Ceramic-coated materials used in different engineering sectors are the focus of world-wide interest and have generated a need for inspection techniques that detect very small structural anomalies. Non-destructive testing is increasingly being used to evaluate coating thickness and to test for coating flaws. The main pros of non-destructive testing is that the tested object remains intact and available for continued use afterward. This paper reports on an integrated, non-destructive testing approach that combines infrared thermography and acousto-ultrasonics to evaluate advanced aerospace sandwich structure materials with the aim of exploring any potential for detecting defects of more than one type. Combined, these two techniques successfully detected fabrication defects, including inclusions and material loss.

Beschreibung: Germany has experienced rapid growth in onshore wind capacities over the past two decades. Substantial capacities of offshore wind turbines have been added since 2013. On a local, highly-resolved level, this analysis evaluated if differences in wind speed forecast errors exist for offshore and onshore locations regarding magnitude and variation. A model based on the Extra Trees algorithm is proposed and found to be a viable method to transform local wind speeds and capacities into aggregated wind energy feed-in. This model was used to analyze if offshore and onshore wind power expansion lead to different distributions of day-ahead wind energy forecast errors in Germany. The Extra Trees model results indicate that offshore wind capacity expansion entails an energy forecast error distribution with more frequent medium to high deviations, stemming from larger and more variable wind speed deviations of offshore locations combined with greater geographical concentration of offshore wind turbines and their exposure to high-wind oceanic conditions. The energy forecast error distribution of onshore expansion, however, shows heavier tails and consequently more frequent extreme deviations. The analysis suggests that this can be rooted in the simultaneous over- or underestimation of wind speeds at many onshore locations.

Beschreibung: The intermittency of solar energy resources has brought a big challenge for the optimization and planning of a future smart grid. To reduce the intermittency, an accurate prediction of photovoltaic (PV) power generation is very important. Therefore, this paper proposes a new forecasting method based on the recurrent neural network (RNN). At first, the entire solar power time series data is divided into inter-day data and intra-day data. Then, we apply RNN to discover the nonlinear features and invariant structures exhibited in the adjacent days and intra-day data. After that, a new point prediction model is proposed, only by taking the previous PV power data as input without weather information. The forecasting horizons are set from 15 to 90 min. The proposed forecasting method is tested by using real solar power in Flanders, Belgium. The classical persistence method (Persistence), back propagation neural network (BPNN), radial basis function (RBF) neural network and support vector machine (SVM), and long short-term memory (LSTM) networks are adopted as benchmarks. Extensive results show that the proposed forecasting method exhibits a good forecasting quality on very short-term forecasting, which demonstrates the feasibility and effectiveness of the proposed forecasting model.

Beschreibung: Standardized communication plays an important role in substation automation system (SAS). IEC 61850 is a de-facto standard in SAS. It facilitates smooth communication between different devices located in the substation by achieving interoperability. Generic Object-Oriented Substation Event (GOOSE) and Sample Value (SV) messages developed according to IEC 61850 enable efficient monitoring and operation control of SAS. IEC 61850 is very popular due to its flexible and robust modeling. As the number of critical infrastructures that employed IEC 61850 increases, it is important to study cybersecurity aspects as well. To this end, this paper develops a software framework, S-GoSV (Secure GOOSE and SV), that generates custom GOOSE and Sample Value messages. Furthermore, security features are added to protect them from different security attacks within a substation. IEC 62351-6 specifies digital signatures to achieve node authentication and messages integrity. Therefore, S-GoSV implements RSASSA-PKCS1-v1_5 digital signature algorithm based on RFC 2313. Performance studies show that digital signature algorithms based on RSA signing and verification take long times and do not conform to timing requirements stipulated by IEC 61850 for power system communication. To address this, Message Authentication Code (MAC) based digital signature algorithm, Keyed Hash-Message Authentication Code- Secure Hash Algorithm (HMAC-SHA256), is additionally implemented in S-GoSV framework for securing GOOSE messages.

Beschreibung: In Europe, ethanol is blended with gasoline fuel in 5 or 10% volume (E5 or E10). In USA the blend is 15% in volume (E15) and there are also pumps that provide E85. In Brazil, the conventional gasoline is E27 and there are pumps that offer E100, due to the growing market of flex fuel vehicles. Bioethanol production is usually by means of biological conversion of several biomass feedstocks (first generation sugar cane in Brazil, corn in the USA, sugar beet in Europe, or second-generation bagasse of sugarcane or lignocellulosic materials from crop wastes). The environmental sustainability of the bioethanol is usually measured by the global warming potential metric (GWP in CO2eq), 100 years time horizon. Reviewed values could range from 0.31 to 5.55 gCO2eq/LETOH. A biomass-to-ethanol industrial scenario was used to evaluate the impact of methodological choices on CO2eq: conventional versus dynamic Life Cycle Assessment; different impact assessment methods (TRACI, IPCC, ILCD, IMPACT, EDIP, and CML); electricity mix of the geographical region/country for different factory locations; differences in CO2eq factor for CH4 and N2O due to updates in Intergovernmental Panel on Climate Change (IPCC) reports (5 reports so far), different factory operational lifetimes and future improved productivities. Results showed that the electricity mix (factory location) and land use are the factors that have the greatest effect (up to 800% deviation). The use of the CO2 equivalency factors stated in different IPCC reports has the least influence (less than 3%). The consideration of the biogenic emissions (uptake at agricultural stage and release at the fermentation stage) and different allocation methods is also influential, and each can make values vary by 250%.

Beschreibung: Under the European Union (EU) energy efficiency targets that Romania has assumed, increasing the share of solar energy has been one of the main points to be considered. The most important solar energy resources are found in the lowlands and low hills in southern and south-eastern parts of the country. The current paper is focused on the Romanian Plain, which has the best environmental conditions to support the development of photovoltaic (PV) farms. One hundred and ten PV farms have been identified and mapped which cover a total area of 1393 hectares. Although it provides a clean and sustainable energy source, the related environmental implications of PV farms could be either positive or negative. In this study, some of the main categories of impacts have been selected for identification and analysis of their environmental consequences. Several indicators have been computed: the share of PV farms from the main land use/cover categories and main soil types, and the distance of PV farms to forests, water bodies, or protected areas. The overall results of the study reveal the current and potential impacts of PV farms in order to understand the interactions between the environment and the use of renewable energy sources and further support science-based solutions for sustainable development.

Beschreibung: The water hammer can cause great risks in water supply pipe systems. A surge tank is a kind of general water hammer control device. In order to improve the behavior of the surge tank, a self-adaptive auxiliary control (SAC) system was proposed in this paper. The system can optimize the response of the surge tank according to the transient pressure. The numerical model and the matched boundary conditions were established to simulate the improved surge tank and optimize the SAC system. Then, various transient responses were simulated by the proposed model with different parameters set. The proposed system is validated by comparing the water hammer process in a river-pipe-valve (RLV) system with and without SAC. The results show that the SAC can greatly improve the water hammer control of the pipeline and the water level oscillation of the surge tank. With the SAC system, the required vertical size of the surge tank can be significantly reduced with the desired water hammer control function.

Beschreibung: In order to improve the performance of switched reluctance motor (SRM) systems for photovoltaic (PV) pumps, this paper introduces a new converter topology for SRM with controllable multiple power sources. Only simple switching components need to be added at the front end of the asymmetric half-bridge converter in this topology, which enables the control of multiple power sources. The new PV pump system has four operating modes, which are the PV panel driven mode, battery bank driven mode, dual-source driven mode, and battery charging mode. By adjusting the state of the front-end converter switch, the voltage tracking of PV panel can be achieved, providing a stable bus voltage for the SRM system. By controlling the battery bypass switch, the bus voltage of SRM system can be increased, thereby increasing the system power level. Simulations and experiments based on a four-phase 8/6 SRM demonstrate the effect of the novel converter proposed in this paper.

Beschreibung: Currently, in most countries, the electricity sector is liberalized, and electricity is traded in deregulated electricity markets. In these markets, electricity demand is determined the day before the physical delivery through (semi-)hourly concurrent auctions. Hence, accurate forecasts are essential for efficient and effective management of power systems. The electricity demand and prices, however, exhibit specific features, including non-constant mean and variance, calendar effects, multiple periodicities, high volatility, jumps, and so on, which complicate the forecasting problem. In this work, we compare different modeling techniques able to capture the specific dynamics of the demand time series. To this end, the electricity demand time series is divided into two major components: deterministic and stochastic. Both components are estimated using different regression and time series methods with parametric and nonparametric estimation techniques. Specifically, we use linear regression-based models (local polynomial regression models based on different types of kernel functions; tri-cubic, Gaussian, and Epanechnikov), spline function-based models (smoothing splines, regression splines), and traditional time series models (autoregressive moving average, nonparametric autoregressive, and vector autoregressive). Within the deterministic part, special attention is paid to the estimation of the yearly cycle as it was previously ignored by many authors. This work considers electricity demand data from the Nordic electricity market for the period covering 1 January 2013–31 December 2016. To assess the one-day-ahead out-of-sample forecasting accuracy, Mean Absolute Percentage Error (MAPE), Mean Absolute Error (MAE), and Root Mean Squared Error (RMSE) are calculated. The results suggest that the proposed component-wise estimation method is extremely effective at forecasting electricity demand. Further, vector autoregressive modeling combined with spline function-based regression gives superior performance compared with the rest.

Beschreibung: This paper reports on the optimum conditions for simultaneous hydrogen and butyric acid production from microalgae (Chlorella sp.) using enriched anaerobic mixed cultures as inoculum. The fermentation was objectively carried out under acidogenic conditions to achieve butyric acid for further ABE fermentation in solventogenesis stage. The main effects of initial pH (5 and 7), temperature (35 °C and 55 °C), and substrate concentration (40, 60, 80, and 100 g-VS/L) for hydrogen and butyric acid production were evaluated by using batch fermentation experiment. The major effects on hydrogen and butyric acid production are pH and temperature. The highest production of hydrogen and butyric acid was observed at pH 7 and temperature 35 °C. Using initial Chlorella sp. concentration of 80 g-VS/L or 100 g-VS/L at pH 7 and temperature 35 °C could produce hydrogen with an average yield of 22 mL-H2/g-VS along with high butyric acid production yield of 0.05 g/g-VS, suggesting that microalgae (Chlorella sp.) has potential to be converted directly to butyric acid by using acidogenesis under above optimum conditions.

Beschreibung: The discharge resistor is only used in case of electrical trip to reduce the field current as fast as possible and to minimize the damages produced by the short-circuit current supplied by the synchronous machine. The connection of the discharge resistor is done by opening the field breaker and it implies a large negative voltage in the field winding. This negative voltage is limited to 80% of the winding insulation voltage. On the other hand, in case of a transient de-excitation, at the first moment, the automatic voltage regulator (AVR) reduces the field voltage to the minimum. In case of one-quadrant rectifier type AVR, the minimum voltage is zero and in case of two-quadrant rectifier AVR, the minimum voltage is close to the ceiling voltage with negative polarity. In both cases, the minimum voltages are much smaller than the negative voltage produced by the connection of the discharge resistor. This paper presents a new system that improves the transient de-excitation of synchronous machines using the discharge resistor by an additional static field breaker (SFB). The control of the static field breaker and consequently the connection and disconnection of the discharge resistor is done based on the output field voltage supplied by the AVR. This allows the exciter field current to be reduced in a faster way and continue with the normal operation of the machine after the transient. In this study, the correct operation of the additional static field breaker (SFB) has been validated by computer simulations and experimental test in a 15 MVA generator comprising a commercial one-quadrant rectifier AVR type obtaining excellent results.

Beschreibung: According to the Intergovernmental Panel on Climate Change (IPCC) Fifth Assessment Report in 2013 (IPCC, 2013) [...]

Beschreibung: Removal of calcium and magnesium ions through biomineralization induced by bacteria has been proven to be an effective and environmentally friendly method to improve water quality, but the process and mechanism are far from fully understood. In this study, a newly isolated probiotic Bacillus licheniformis SRB2 (GenBank: KM884945.1) was used to induce the bio-precipitation of calcium and magnesium at various Mg/Ca molar ratios (0, 6, 8, 10, and 12) in medium with 30 g L−1 sodium chloride. Due to the increasing pH and HCO3− and CO32− concentrations caused by NH3 and carbonic anhydrase, about 98% Ca2+ and 50% Mg2+ were precipitated in 12 days. The pathways of bio-precipitation include extracellular and intracellular processes. Biominerals with more negative δ13C values (−16‰ to −18‰) were formed including calcite, vaterite, monohydrocalcite, and nesquehonite with preferred orientation. The nucleation on extracellular polymeric substances was controlled by the negatively charged amino acids and organic functional groups. The intracellular amorphous inclusions containing calcium and magnesium also contributed to the bio-precipitation. This study reveals the process and mechanism of microbial desalination for the removal of calcium and magnesium, and provides some references to explain the formation of the nesquehonite and other carbonate minerals in a natural and ancient earth surface environment.

Beschreibung: DC micro-grid is gaining increasing attention recently due to its highly efficient energy utilization and flexible energy exchange capabilities. In this paper, an air-coupled DC–DC transformer is proposed for the interconnection between the active load and the DC microgrid. The generic problems in an air-coupled power transfer system without ferromagnetic structure are discussed. A bidirectional half-bridge topology is also proposed to suit the characteristics of the stationary load and to realize the bidirectional power transfer between the active DC load and the DC grid. A Hybrid Modulation Method (HMM) is proposed; the small signal model is derived and linear control techniques are applied to the forward power transfer control, and phase model control is applied to the reverse power transfer model. The open-loop system is simulated by PSIM to get the characteristics of the forward and reverse transfer model, and the closed system is built in the MATLAB/SIMULINK to verify the effect of the forward frequency control method and the reverse phase control method. The prototype is built with a dsPIC controller, tests are performed to evaluate the characteristics of the transformer and the power flow control of the bidirectional power transfer.

Beschreibung: Present-day direct injection (DI) diesel engines with a high power density of displacement are not just promoting an expansion in the utilization of high-temperature resistant alloys in pistons yet, in addition, the expanded cylinder air pressures. When the temperature of the diesel engines piston exceeds a certain limit, it assumes a critical role at the start of sprays. The target of the present investigation was to look at the effects of cylinder air pressures (CAP) (10–25 bar) and high hot surface temperatures (HST) (350–450 °C). The ignition delay (ID) of pure diesel and that of diesel with Iftex clean system D (a cetane enhancer) are investigated experimentally. The experiments are performed by using a constant volume combustion chamber (CVCC) with a single hole pintle-type nozzle mounted on its head. A strong dependence of ID on the CAPs and HSTs was observed. A CAP of 25 bar is much inferior to the precombustion pressure of DI diesel engines; however, it is the case that combustion typical features are the same in spite of an inferior CAP, HST, and injection pressure. The ID tends to decrease to very small values with an increase in either of the two parameters. At a CAP of 25 bar, the measured ID of diesel with fuel additive is 45.8% lower than the pure diesel. Further, the ID of diesel with fuel additive at a 300 bar injection pressure and 25 bar CAP decreases at a rate of close to 0.2 ms/bar.

Beschreibung: Coffee grounds are the most significant production waste in the coffee industry and contain about 15% coffee oil. Coffee oil is rich in fatty acids and polyphenols, which have great application potential in the flotation of oxidized minerals. In this study, coffee oil as a green flotation collector for ilmenite was investigated by micro-flotation, zeta potential measurement, and foam stability analysis. The results of zeta potential reveal that both coffee oil and MOH can be adsorbed on the ilmenite surface at pH 6.7, and the chemical adsorption mode is dominant. However, when the pH is 2.8, the adsorption capacity of coffee oil on the ilmenite surface is much larger than that of MOH. The pH value of the pulp has little effect on the foam properties in the coffee oil solution and has a great influence on the foaming performance and foam stability of the MOH solution. When coffee oil is used as a collector, the grade of TiO2 in ilmenite concentrate is increased from 21.68% to 46.83%, and the recovery is 90.22%, indicating that the potential of coffee oil in the application of ilmenite flotation is large.

Beschreibung: The controlled crystallisation of struvite (MgNH4PO4∙6H2O) is a viable means for the recovery and recycling of phosphorus (P) from municipal and industrial wastewaters. However, an efficient implementation of this recovery method in water treatment systems requires a fundamental understanding of struvite crystallisation mechanisms, including the behavior and effect of metal contaminants during struvite precipitation. Here, we studied the crystallisation pathways of struvite from aqueous solutions using a combination of ex situ and in situ time-resolved synthesis and characterization techniques, including synchrotron-based small- and wide-angle X-ray scattering (SAXS/WAXS) and cryogenic transmission electron microscopy (cryo-TEM). Struvite syntheses were performed both in the pure Mg-NH4-PO4 system as well as in the presence of cobalt (Co), which, among other metals, is typically present in waste streams targeted for P-recovery. Our results show that in the pure system and at Co concentrations 〈 0.5 mM, struvite crystals nucleate and grow directly from solution, much in accordance with the classical notion of crystal formation. In contrast, at Co concentrations ≥ 1 mM, crystallisation was preceded by the transient formation of an amorphous nanoparticulate phosphate phase. Depending on the aqueous Co/P ratio, this amorphous precursor was found to transform into either (i) Co-bearing struvite (at Co/P 〈 0.3) or (ii) cobalt phosphate octahydrate (at Co/P 〉 0.3). These amorphous-to-crystalline transformations were accompanied by a marked colour change from blue to pink, indicating a change in Co2+ coordination in the formed solid from tetrahedral to octahedral. Our findings have implications for the recovery of nutrients and metals during struvite crystallisation and contribute to the ongoing general discussion about the mechanisms of crystal formation.

Beschreibung: This paper reports formation and dissociation patterns of methane hydrate in sandstone. Magnetic resonance imaging spatially resolved hydrate growth patterns and liberation of water during dissociation. A stacked core set-up using Bentheim sandstone with dual water saturation was designed to investigate the effect of initial water saturation on hydrate phase transitions. The growth of methane hydrate (P = 8.3 MPa, T = 1–3 °C) was more prominent in high water saturation regions and resulted in a heterogeneous hydrate saturation controlled by the initial water distribution. The change in transverse relaxation time constant, T2, was spatially mapped during growth and showed different response depending on the initial water saturation. T2 decreased significantly during growth in high water saturation regions and remained unchanged during growth in low water saturation regions. Pressure depletion from one end of the core induced a hydrate dissociation front starting at the depletion side and moving through the core as production continued. The final saturation of water after hydrate dissociation was more uniform than the initial water saturation, demonstrating the significant redistribution of water that will take place during methane gas production from a hydrate reservoir.

Beschreibung: Model-free adaptive control (MFAC) builds a virtual equivalent dynamic linearized model by using a dynamic linearization technique. The virtual equivalent dynamic linearized model contains some time-varying parameters, time-varying parameters usually include high nonlinearity implicitly, and the performance will degrade if the nonlinearity of these time-varying parameters is high. In this paper, first, a novel learning algorithm named error minimized regularized online sequential extreme learning machine (EMREOS-ELM) is investigated. Second, EMREOS-ELM is used to estimate those time-varying parameters, a model-free adaptive control method based on EMREOS-ELM is introduced for single-input single-output unknown discrete-time nonlinear systems, and the stability of the proposed algorithm is guaranteed by theoretical analysis. Finally, the proposed algorithm is compared with five other control algorithms for an unknown discrete-time nonlinear system, and simulation results show that the proposed algorithm can improve the performance of control systems.

Beschreibung: In McMurray Formation, steam assisted gravity drainage is used as the primary in-situ recovery technique to recover oil sands. Different geological reservoir settings and long horizontal wells impose limitations and operational challenges on the implementation of steam-assisted gravity drainage (SAGD). The dual-string tubing system is the conventional completion scheme in SAGD. In complex reservoirs where dual-string completion cannot improve the operation performance, operators have adopted flow control devices (FCDs) to improve project economics. FCDs secure more injection/production points along the horizontal sections of the SAGD well pairs, hence, they maximize ultimate bitumen recovery and minimize cumulative steam-oil ratio (cSOR). This paper will focus on the optimization of outflow control devices (OCDs) in SAGD reservoirs with horizontal wellbore undulations. We present the detailed optimization workflow and show the optimization results for various scenarios with well pair trajectory undulation. Comparing the results of the optimized OCDs case with a dual-string case of the same SAGD model shows improvements in steam distribution, steam chamber growth, bitumen production, and net present value (NPV).

Beschreibung: This paper presents a method for online detection of symmetrical components of arbitrarily distorted and biased three-phase input signals. This method is based on Second-Order Generalized Integrators (SOGIs), for which a new tuning based on a gradient search is presented to achieve the fastest possible estimation. Frequency estimation is achieved by a Frequency Locked Loop (FLL) with Gain Normalization (GN) for which an Output Saturation (OS) is applied; this OS guarantees stability of the overall system. Offset detection is implemented by a combination of High-Pass Filter (HPF) and HPF-Amplitude Phase Correction (APC); the HPF filters out any offset, where the APC reconstructs the original offset-free signal. An identical method (APC) can be used for the implemented Low-Pass Filter (LPF) used for noise filtering. The resulting estimates are then used for Harmonic Sequence Detection (HSD) of each harmonic. For the overall system, stability is proven. The estimation performances of the proposed overall system are verified by simulation results. The improvements in tuning and offset detection are compared to standard approaches.

Beschreibung: The integrated energy system coupling multi-type energy production terminal to realize multi-energy complementarity and energy ladder utilization is of great significance to alleviate the existing energy production crisis and reduce environmental pollution. In this paper, the topology of the cold-thermal-electricity integrated energy system is built, and the decoupling method is adopted to analyze the feasible interval of load rate under the strong coupling condition, so as to ensure the “source-load” power balance of the system. Establishing a multi-objective optimization function with the lowest system economic operation and pollution gas emission, considering the attribute differences and energy scheduling characteristics of different energy sources of cold, heat and electricity, and adopting different time scales to optimize the operation of the three energy sources of cold, heat and electricity, wherein the operation periods of electric energy, heat energy and cold energy are respectively 15 min, 30 min and 1 h; The multi-objective problem is solved by standard linear weighting method. Finally, the mixed integer nonlinear programming model is calculated by LINGO solver. In the numerical simulation, the hotel summer front load parameters of Zhangjiakou, China are selected for simulation and compared with a single time scale system. The simulation results show that the multi-time scale system reduces the economic operation cost by 15.6% and the pollution gas emission by 22.3% compared with the single time scale system, it also has a wider feasible range of load rate, flexible time allocation, and complementary energy selection.

Beschreibung: Magnesium borohydride, Mg(BH4)2, and calcium borohydride, Ca(BH4)2, are promising materials for hydrogen storage. Mixtures of different borohydrides have been the subject of numerous researches; however, the whole Mg(BH4)2-Ca(BH4)2 system has not been investigated yet. In this study, the phase stability and the hydrogen desorption were experimentally investigated in the Mg(BH4)2-Ca(BH4)2 system, by means of XRD, ATR-IR, and HP-DSC. Mg(BH4)2 and Ca(BH4)2 are fully immiscible in the solid state. In the mechanical mixtures, thermal decomposition occurs at slightly lower temperatures than for pure compounds. However, they originate products that cannot be identified by XRD, apart from Mg and MgH2. In fact, amorphous phases or mixtures of different poorly crystalline or nanocrystalline phases are formed, leading to a limited reversibility of the system.

Beschreibung: In oxygen steelmaking, the charge calculation strongly depends on hot metal temperature prediction. Although a hot metal temperature drop from the blast furnace in a steel plant may be too complex to be accurately modeled in detail, the combined use of sensors and statistical models can improve temperature estimation and result in better cost, quality and productivity, as well as lower emissions. In order to develop a simple but robust method for hot metal temperature forecasting, the suitability of infrared thermometry and time series forecasting has been studied. Simultaneous infrared thermometer measurement and video recording was used for designing the processing of the thermometer signal. The resulting temperature estimations are in good agreement with disposable thermocouple measurements giving an error of 11 °C with 60% reliability (chances of obtaining a successful output). Conversely, the time series approach was based mainly on the AutoRegressive Integrated Moving Average (ARIMA) model in which five additional process variables were introduced as exogenous predictors, as well as using a moving window of past observations for continuous model training. The resulting error was 15 °C with more than 90% reliability. Combining measuring and modeling approaches reduced the error to 13 °C with 100% reliability, thereby providing a hybrid procedure that has long-term stability and is self-adaptive to varying production scenarios.

Beschreibung: In this study, various treatment methods to increase the reactivity of carbon porous electrodes for alkaline alcoholic fuel cells were investigated with commercially available carbon papers to understand the characteristic electrochemical behaviors of the treated carbon electrodes and to find the best method to enhance the cell performance. Effects of thermal treatment, potassium hydroxide (KOH) treatment, N2 doping, and reaction-area control via a multi-layered structure were compared in the cell-based tests, and a huge improvement in the cell performance (i.e., 64% increase of open circuit voltage (OCV) and 320% increase of max power density) was found from the thermal-treated four-layered carbon porous electrode. The results were compared with those from platinum on carbon (Pt/C)-based cells, and a discussion on the direction of research in the future was conducted. The results of this study are expected to provide key guidelines for alcoholic fuel cell (AFC) developers to develop cost-effective AFC with a carbon electrode.

Beschreibung: To solve the contradiction between handling stability and ride comfort of vehicles with interconnected air suspension system (IASS) and reduce the energy consumption of air suspension with adjustable spring stiffness, a coordinated control for dynamic performance was designed based on the logic of switching interconnection modes and game control for the damper. The control system consists of a switching controller for air suspension interconnection modes and a distribution controller for the damping force. The switching controller determines the optimal air suspension interconnection mode by calculating the vehicle dynamic performance index in real-time. The distribution controller achieves a distribution for optimal damping force based on an infinite time differential game. veDYNA software that is a vehicle dynamics analysis software based on MATLAB/Simulink was used to verify the algorithm, and the accuracy was verified by a bench test. Finally, the results show this coordinated system can significantly improve the ride comfort and restrain the pitching motion. Compared with traditional suspension, the vertical acceleration decreases by 18.32% and the dynamic stroke decreases by more than 10% under the straight condition; the vertical acceleration decreases by 12.24% and the roll angle decreases by 1.26% under the steering condition.

Beschreibung: LLC resonant converters with center-tapped transformers are widely used. However, these converters suffer from a flux walking issue, which causes a larger output ripple and possible transformer saturation. In this paper, a flux-balance control strategy is proposed for resolving the flux walking issue. First, the DC magnetizing current generated due to the mismatched secondary-side leakage inductances, and its effects on the voltage gain are analyzed. From the analysis, the flux-balance control strategy, which is based on the original output-voltage control loop, is proposed. Since the DC magnetizing current is not easily measured, a current sensing strategy with a current estimator is proposed, which only requires one current sensor and is easy to estimate the DC magnetizing current. Finally, a simulation scheme and a hardware prototype with rated output power 200 W, input voltage 380 V, and output voltage 20 V is constructed for verification. The simulation and experimental results show that the proposed control strategy effectively reduces the DC magnetizing current and output voltage ripple at mismatched condition.

Beschreibung: Electromagnetic transients are responsible for overvoltages and overcurrents that can have a negative impact on the insulating elements of the electrical transmission system. In order to reduce the damage caused by these phenomena, it is essential to accurately simulate the effect of transients along transmission lines. Nonuniformities of transmission line parameters can affect the magnitude of voltage transients, thus it is important to include such nonuniformities correctly. In this paper, a frequency domain method to compute transient voltage and current profiles along nonuniform multiconductor transmission lines is described, including the effect of time-varying and nonlinear elements. The model described here utilizes the cascade connection of chain matrices in order to take into consideration the nonuniformities along the line. This technique incorporates the change of parameters along the line by subdividing the transmission line into several line segments, where each one can have different electrical parameters. The proposed method can include the effect of time-dependent elements by means of the principle of superposition. The numerical Laplace transform is applied to the frequency-domain solution in order to transform it to the corresponding time-domain response. The results obtained with the proposed method were validated by means of comparisons with results computed with ATP (Alternative Transients Program) simulations, presenting a high level of agreement.

Beschreibung: Induction motors face various stresses under operating conditions leading to some failure modes. Hence, health monitoring for motors becomes essential. In this paper, we introduce an effective framework for fault diagnosis of 3-phase induction motors. The proposed framework mainly consists of two parts. The first part explains the preprocessing method, in which the time-series data signals are converted into two-dimensional (2D) images. The preprocessing method generates recurrence plots (RP), which represent the transformation of time-series data such as 3-phase current signals into 2D texture images. The second part of the paper explains how the proposed convolutional neural network (CNN) extracts the robust features to diagnose the induction motor’s fault conditions by classifying the images. The generated RP images are considered as input for the proposed CNN in the texture image recognition task. The proposed framework is tested on the dataset collected from different 3-phase induction motors working with different failure modes. The experimental results of the proposed framework show its competitive performance over traditional methodologies and other machine learning methods.

Beschreibung: In this research work, bio-inspired computational heuristic algorithms (BCHAs) integrated with active-set algorithms (ASA) were designed to study integrated economics load dispatch problems with valve point effects involving stochastic wind power. These BCHAs are developed through variants of genetic algorithms based on a different set of routines for reproduction operators in order to make exploration and exploitation in the entire search space for finding the global optima, while the ASA is used for rapid local refinements of the results. The designed schemes are estimated on different load dispatch systems consisting of a combination of thermal generating units and wind power plants with and without valve point loading effects. The accuracy, convergence, robustness and complexity of the proposed schemes has been examined through comparative studies based on a sufficiently large number of independent trails and their statistical observations in terms of different performance indices.

Beschreibung: The recent developments in combining point forecasts of day-ahead electricity prices across calibration windows have provided an extremely simple, yet a very efficient tool for improving predictive accuracy. Here, we consider two novel extensions of this concept to probabilistic forecasting: one based on Quantile Regression Averaging (QRA) applied to a set of point forecasts obtained for different calibration windows, the other on a technique dubbed Quantile Regression Machine (QRM), which first averages these point predictions, then applies quantile regression to the combined forecast. Once computed, we combine the probabilistic forecasts across calibration windows by averaging probabilities of the corresponding predictive distributions. Our results show that QRM is not only computationally more efficient, but also yields significantly more accurate distributional predictions, as measured by the aggregate pinball score and the test of conditional predictive ability. Moreover, combining probabilistic forecasts brings further significant accuracy gains.

Beschreibung: Rising levels of variable renewable energy (VRE) in Australia’s National Electricity Market have been driven by a 20% renewable energy target by 2020. This certificated renewable portfolio standard has successfully driven new investment, allocated risk amongst buy- and sell-side market participants and met overall policy objectives. But a policy vacuum for achieving long-term CO2 emission targets post-2020 has led to sub-national and, potentially, national governments initiating contract-for-differences (CfDs) to drive further investment activity in new plant—with virtually no coordination between the jurisdictions. In a gross pool energy-only market setting, replacing on-market transactions between retailers and generators with off-market transactions between governments and generators may have unintended side-effects vis-à-vis market stability. In this article, an energy-only gross pool is modeled with rising levels of off-market government-initiated CfDs, with a specific focus on spot and forward contract market outcomes. Model results show that as VRE plant enters, coal plant exit, and on-market firm hedge contracts historically supplied by coal plant are progressively replaced by off-market CfDs. In the event, while a tractable equilibrium can be maintained in the spot market, shortages of “primary issuance” hedge contracts emerge in the forward market. Any shortage of hedge contract capacity is likely to raise forward contract price premiums above efficient levels, force price-elastic customers into accepting unwanted spot market exposures and may unintentionally foreclose non-integrated (2nd tier) energy retailers, all of which harms consumer welfare. A wide-ranging program of government CfDs may therefore not be compatible with an energy-only market design.

Beschreibung: The scheme based on direct torque and flux control (DTFC) as well as active flux is a good choice for the interior permanent magnet synchronous motor (IPMSM) sensorless control. The precision of the stator flux observation is essential for this scheme. However, the performance of traditional observers like pure integrator and the low-pass filter (LPF) is severely deteriorated by disturbances, especially dc offset. Recently, a sliding-mode stator flux observer (SMFO) was proposed to reduce the dc offset in the estimated stator flux. However, it cannot eliminate the dc offset totally and will cause the chattering problem. To solve these problems, a novel super-twisting sliding-mode stator flux observer (STSMFO) is proposed in this paper. Compared with SMFO, STSMFO can reduce the chattering and fully eliminate the dc offset without any amplitude and phase compensation. Then, the precision of the stator flux and rotor position can be greatly improved over a wide speed region. The detailed mathematical analysis has been given for comparing it with another three traditional observers. The numerical simulations and experimental testing with an IPMSM drive platform have been implemented to verify the capability of the proposed sensorless scheme.

Beschreibung: The pulse decay test is the main method employed to determine permeability for tight rocks, and is widely used. The testing gas can be strongly adsorbed on the pore surface of unconventional reservoir cores, such as shale and coal rock. However, gas adsorption has not been well considered in analysis pulse decay tests. In this study, the conventional flow model of adsorbed gas in porous media was modified by considering the volume of the adsorbed phase. Then, pulse decay tests of equilibrium sorption, unsteady state and pseudo-steady-state non-equilibrium sorption models, were analyzed by simulations. For equilibrium sorption, it is found that the Cui-correction method is excessive when the adsorbed phase volume is considered. This method is good at very low pressure, and is worse than the non-correction method at high pressure. When the testing pressure and Langmuir volume are large and the vessel volumes are small, a non-negligible error exists when using the Cui-correction method. If the vessel volumes are very large, gas adsorption can be ignored. For non-equilibrium sorption, the pulse decay characteristics of unsteady state and pseudo-steady-state non-equilibrium sorption models are similar to those of unsteady state and pseudo-steady-state dual-porosity models, respectively. When the upstream and downstream pressures become equal, they continue to decay until all of the pressures reach equilibrium. The Langmuir volume and pressure, the testing pressure and the porosity, affect the pseudo-storativity ratio and the pseudo-interporosity flow coefficient. Their impacts on non-equilibrium sorption models are similar to those of the storativity ratio and the interporosity flow coefficient in dual-porosity models. Like dual-porosity models, the pseudo-pressure derivative can be used to identify equilibrium and non-equilibrium sorption models at the early stage, and also the unsteady state and pseudo-steady-state non-equilibrium sorption models at the late stage. To identify models using the pseudo-pressure derivative at the early stage, the suitable vessel volumes should be chosen according to the core adsorption property, porosity and the testing pressure. Finally, experimental data are analyzed using the method proposed in this study, and the results are sufficient.

Beschreibung: As a step towards the diversification of electricity and heat sources, the EU countries suggest the use of biomass. The combustion of biomass poses the problem of the use of ash produced in the process. There are fluctuations in the properties of energetic biomass, which results in high variability of ash obtained by combustion, especially in terms of specific conductivity (EC) (8.1–9.7 mS·cm−1), the total content of components and their bioavailability. The combustion of biomass leads to large fluctuations in the total content of carbon in the ash (13.6%–28.6%). In this way, waste material with very different biological properties and cation exchange capacity is obtained. Ash from the combustion of biomass is an alkalizing material, rich in Ca, K and Mg carbonates (4.5%). The high average bioavailability of Pb (87.4%), Cd (63.1%) and Zn (46.9%) present in the ash is an environmental problem. The mobility of these heavy metals was reduced by half by the addition of bentonite during the process of ash granulation. With high doses of ash (4.4% of the mass of substrate), there is a significant bioaccumulation of Cd in the roots of Begonia semperflorens and Thuja occidentalis (1.0–3.8 mg·kg−1). Another disturbing issue is that during the cultivation of these plants, Cr is bioaccumulated in the roots (0.5–3.8 mg·kg−1).

Beschreibung: Global warming and climate change caused by greenhouse gas (GHG) emissions have rapidly increased the occurrence of abnormal climate events, and both the scale and frequency of geotechnical engineering hazards (GEHs) accordingly. In response, geotechnical engineers have a responsibility to provide countermeasures to mitigate GEHs through various ground improvement techniques. Thus, this study provides a comprehensive review of the possible correlation between GHG emissions and GEHs using statistical data, a review of ground improvement methods that have been studied to reduce the carbon footprint of geotechnical engineering, and a discussion of the direction in which geotechnical engineering should proceed in the future.

Beschreibung: Bauxites in southern France (Provence and Languedoc) have been exploited since the beginning of the last century. Though most of the deposits are now subeconomic or mined-out, these bauxites represent model analogs for other economic bauxites of the world. These Cretaceous karst-type deposits lie directly on Jurassic carbonates, and have been formed through a combination of different processes: in-situ alteration of siliciclastic sediments deposited on carbonate platforms, and reworking of early bauxites in the karst network. In this study, we present preliminary bulk rock geochemical and in-situ laser ablation (LA) -ICP-MS analyses on Al- and Fe-oxy-hydroxides of Provence (Les Baux-de-Provence) and Languedoc (Villeveyrac, Loupian) bauxites, with the aim of evaluating the concentrations of rare earth elements (REEs) and their deportment in these minerals. REEs have total average concentrations of 700 mg/kg in the analyzed samples, which are mostly composed of boehmite, γ-AlO(OH), and Fe-oxy-hydroxides (hematite and goethite). Maximum REEs concentrations are commonly associated with positive Ce anomalies in chondrite-normalized patterns. In contrast with other examples from the literature, it has been observed that high REE concentrations also occur in samples apparently devoid or poor of REE-minerals. In these samples, the total amount of REEs is positively correlated with that of Ga (commonly contained in boehmite). LA-ICP-MS trace element analyses on boehmite and Fe-oxy-hydroxides have shown that while the Al-hydroxide contains the suite of REEs, goethite and hematite are preferentially enriched only in Ce. Considering that Al-hydroxides are digested during the Bayer process, an interesting issue to develop in the future is whether (and how) REEs released during Al-hydroxide digestion could be recovered together with Al from the pregnant leach liquor, as routinely done for Ga.

Beschreibung: In this paper, a power control method is proposed for a buffer-aided relay node (RN) to enhance the energy efficiency of the RN system. By virtue of a buffer, the RN can reserve the data at the buffer when the the channel gain between an RN and a destination node (DN) is weaker than that between SN and RN. The RN then opportunistically forward the reserved data in the buffer according to channel condition between the RN and the DN. By exploiting the buffer, RN reduces transmit power when it reduces the transmit data rate and reserve the data in the buffer. Therefore, without any total throughput reduction, the power consumption of RN can be reduced, resulting in the energy efficiency (EE) improvement of the RN system. Furthermore, for the power control, we devise a simple power control method based on a two-dimensional surface fitting model of an optimal transmit power of RN. The proposed RN power control method is readily and locally implementable at the RN, and it can significantly improve EE of the RN compared to the fixed power control method and the spectral efficiency based method as verified by the rigorous numerical results.

Beschreibung: In this paper, a steady-state matrix analysis method is introduced to analyze the output characteristics of the class-E power amplifier used in a wireless power transfer (WPT) system, which takes the inductance resistance, on-resistance and leakage current of metal-oxide-semiconductor field effect transistor (MOSFET) into account so that the results can be closer to the actual value. On this basis, the parameters of the class-E power amplifier are optimized, and the output power is improved under the premise of keeping the efficiency unchanged. Finally, the output characteristics of the amplifier before and after optimization are compared by an experiment, while the B-field strength around the WPT system is studied through simulation. The experimental results verify the correctness and feasibility of the optimization method based on steady-state matrix analysis.

Beschreibung: Grass from landscape management or from agricultural practices is currently destined mainly for composting, with the production of a valuable product; however, this process demands energy. Anaerobic digestion, instead, represents an energy-positive process that results in the production of fuel, biogas, and a fertilizer, namely digestate. Previous tests for the evaluation of biogas yield from freshly harvested grass gave promising results. However, for a practical exploitation of this resource, appropriate conservation is necessary in order to enable the daily load of digesters while reducing the loss of organic matter. The present work is focused on the evaluation of biogas and methane yield from dried and ensiled grass (without conditioning) in order to assess eventual biogas potential losses in comparison to digested fresh grass. Tests were performed with grass collected from riverbanks (Veneto, Northern Italy) in batch, lab scale digesters. Dry and ensiled grass showed a good potential for exploitation in the anaerobic digestion process, reaching biogas yields of 565.9 and 573.4 NL∙kgVS−1, respectively. Compared to the biogas yield of 639.7 NL∙kgVS−1 of the fresh grass, the conservation treatment determined yield reductions of 11.5% and 10.4% for dried and ensiled grass, respectively. However, considering the methane yields, conservation treatments showed lower reductions, amounting to 4.8% for dry grass and 0.5% for ensiled grass; presumably the higher concentration of organic acids in ensiled grass determined a higher methane content in biogas and the consequently lower reduction of methane yield.