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  • 1
    Publication Date: 2015-08-04
    Description: This paper presents design and testing of a shell-encapsulated solar collector which can be used in north area of China for wall-amounting installation. The designed solar collector is based on the combination of a novel compound curved surface concentrator and an aluminum concentric solar receiver, which is contained in a glass evacuated-tube. As there is no perforative joint between the double-skin glass evacuated-tube and the aluminum concentric solar receiver, the difficulty of vacuum keeping for a glass-metal joint is avoided. The cavity shell provides an additional thermal insulation to reduce heat loss of the designed solar collector. The working principle of the compound curved surface concentrator is described. The ray-tracing results are given to show the effect of deviation angle of the concentrator on its optical efficiency, hence determining its maximum acceptance angle. A prototype of the designed solar collector has been constructed and tested under the sunny winter weather condition. The experimental results indicate that the hot water temperature higher than 80°C with a daily average efficiency of about 45~50% has been achieved at the average ambient temperature below 0°C, so the designed solar collector can produce hot water at a useful temperature in winter.
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  • 2
    Publication Date: 2015-08-05
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  • 3
    Publication Date: 2015-08-05
    Description: A novel all-glass evacuated tube collector manifold header with an inserted tube is proposed in this paper which makes water in all-glass evacuated solar collector tube be forced circulated to improve the performance of solar collector. And a dynamic numerical model was presented for the novel all-glass evacuated tube collector manifold header water heater system. Also, a test rig was built for model validation and comparison with traditional all-glass evacuated tube collector. The experiment results show that the efficiency of solar water heater with a novel collector manifold header is higher than traditional all-glass evacuated tube collector by about 5% and the heat transfer model of water heater system is valid. Based on the model, the relationship between the average temperature of water tank and inserted tube diameter (water mass flow) has been studied. The results show that the optimized diameter of inserted tube is 32 mm for the inner glass with the diameter of 47 mm and the water flow mass should be less than 1.6 Kg/s.
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  • 4
    Publication Date: 2015-08-05
    Description: The performance of a dual-function solar collector (DFSC) that can work as either water heater or air heater depending on seasonal requirement is investigated via both experimental and numerical approaches in this paper. The numerical results are well consistent with the experimental results. Daily efficiency of the thermosiphon system with DFSC is more than 55% in water heating mode and the instantaneous air heating efficiency of the collector reaches 60%. The effects of inner parameters on the thermal efficiency of the collector are analyzed by numerical simulations of the operation of DFSC in two working modes. It is found that the depths of the two air channels in DFSC have an optimal range suitable for both working modes. The thickness of back insulation should be no less than 0.06 m to prevent heat loss via backboard, and the diameter and number of copper tubes show notable effect on the efficiency of DFSC in water heating mode but slight effect in air heating mode.
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  • 5
    Publication Date: 2015-08-13
    Description: Concentrator solar cells that operate at high solar concentration level must be cooled. In this paper, direct liquid immersion cooling of triple-junction solar cells (InGaP/InGaAs/Ge) is proposed as a heat dissipation solution for dense-array high concentrating photovoltaic (HCPV) systems. The advantages of triple-junction CPV cells immersed in a circulating dielectric liquid and dish HCPV technology are integrated into a CPV system to improve the system electrical conversion efficiency. An analytical model for the direct liquid-immersed solar receiver with triple-junction CPV cells is presented. The main outputs of the model are the components temperatures of the receiver and the system electrical efficiency. The influence of concentration factor, mass flow rate, and inlet liquid temperature on the operating temperature of the triple-junction CPV cells and the system electrical conversion efficiency are discussed. It is shown that the system electrical conversion efficiency is very high for a wide range of operating conditions. The three operating parameters have a major effect on the operating temperature of the triple-junction CPV cells and, by extension, system output power. The flow rate selection should match concentration factor to keep the triple-junction CPV cells temperature lower and increase the electrical conversion efficiency of the dense-array HCPV system.
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  • 6
    Publication Date: 2015-08-04
    Description: Solar aided coal-fired power generation system (SACFPGS) combines solar energy and traditional coal-fired units in a particular way. This study mainly improves the solar thermal storage system. Genetic algorithm is used to optimize the SACFPGS. The best integration approach of the system, the collector area, and the corresponding thermal storage capacity to replace each high-pressure extraction are obtained when the amount of coal saving in unit solar investment per hour is at its largest. System performance before and after the improvement is compared. Results show that the improvement of the thermal storage system effectively increases the economic benefit of the integrated system.
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  • 7
    Publication Date: 2015-08-04
    Description: A spectral selectivity surface for both solar heating and radiative cooling was proposed. It has a high spectral absorptivity (emissivity) in the solar radiation band and atmospheric window band (i.e., 0.2~3 μm and 8~13 μm), as well as a low absorptivity (emissivity) in other bands aside from the solar radiation and atmospheric window wavelengths (i.e., 3~8 μm or above 13 μm). A type of composite surface sample was trial-manufactured combining titanium-based solar selective absorbing coating with polyethylene terephthalate (TPET). Sample tests showed that the TPET composite surface has clear spectral selectivity in the spectra of solar heating and radiation cooling wavelengths. The equilibrium temperatures of the TPET surface under different sky conditions or different inclination angles of surface were tested at both day and night. Numerical analysis and comparisons among the TPET composite surface and three other typical surfaces were also performed. These comparisons indicated that the TPET composite surface had a relative heat efficiency of 76.8% of that of the conventional solar heating surface and a relative temperature difference of 75.0% of that of the conventional radiative cooling surface, with little difference in cooling power.
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  • 8
    Publication Date: 2015-08-05
    Description: In this paper, taking Lushan West Sea highway green rest area in Jiangxi Province of China as the case study, the suitable types, applicability, advantages, and effective methods of solar lighting technologies for highway rest area were determined based on the analysis of characteristics of highway green rest area. It was proved that solar lighting technologies including the natural light guidance system, solar LED lighting, and maximizing natural light penetration were quite suitable for highway rest area in terms of lighting effects and energy and economic efficiency. The illuminance comparison of light guidance system with electrical lighting was made based on the on-site experiment. Also, the feasibility of natural light guidance system was well verified in terms of the lighting demand of the visitor centre in the rest area by the illuminance simulation analysis. The evaluation of the energy saving, economic benefits, and environmental effects of solar lighting technologies for highway rest area was, respectively, made in detail. It was proved that the application of solar technology for green lighting of highway rest facilities not only could have considerable energy saving capacity and achieve high economic benefits, but also make great contributions to the reduction of environment pollution.
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  • 9
    Publication Date: 2015-06-09
    Description: We demonstrate an innovative CIGS-based solar cells model with a graded doping concentration absorber profile, capable of achieving high efficiency values. In detail, we start with an in-depth discussion concerning the parametrical study of conventional CIGS solar cells structures. We have used the wxAMPS software in order to numerically simulate cell electrical behaviour. By means of simulations, we have studied the variation of relevant physical and chemical parameters—characteristic of such devices—with changing energy gap and doping density of the absorber layer. Our results show that, in uniform CIGS cell, the efficiency, the open circuit voltage, and short circuit current heavily depend on CIGS band gap. Our numerical analysis highlights that the band gap value of 1.40 eV is optimal, but both the presence of Molybdenum back contact and the high carrier recombination near the junction noticeably reduce the crucial electrical parameters. For the above-mentioned reasons, we have demonstrated that the efficiency obtained by conventional CIGS cells is lower if compared to the values reached by our proposed graded carrier concentration profile structures (up to 21%).
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  • 10
    Publication Date: 2015-06-09
    Description: Microcrystalline silicon (μc-Si:H) thin-film solar cells are processed on glass superstrates having both micro- and nanoscale surface textures. The microscale texture is realised at the glass surface, using the aluminium-induced texturing (AIT) method, which is an industrially feasible process enabling a wide range of surface feature sizes (i.e., 700 nm–3 μm) of the textured glass. The nanoscale texture is made by conventional acid etching of the sputter-deposited transparent conductive oxide (TCO). The influence of the resulting “double texture” on the optical scattering is investigated by means of atomic force microscopy (AFM) (studying the surface topology), haze measurements (studying scattering into air), and short-circuit current enhancement measurements (studying scattering into silicon). A predicted enhanced optical scattering efficiency is experimentally proven by a short-circuit current enhancement of up to 1.6 mA/cm2 (7.7% relative increase) compared to solar cells fabricated on a standard superstrate, that is, planar glass covered with nanotextured TCO. Enhancing the autocorrelation length (or feature size) of the AIT superstrates might have the large potential to improve the μc-Si:H thin-film solar cell efficiency, by reducing the shunting probability of the device while maintaining a high optical scattering performance.
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  • 11
    Publication Date: 2015-06-09
    Description: We study the electrical and the optical behavior of HIT solar cell by means of measurements and optoelectrical simulations by TCAD simulations. We compare the HIT solar cell with a conventional crystalline silicon solar cell to identify the strengths and weaknesses of the HIT technology. Results highlight different mechanisms of electrical and optical efficiency losses caused by the presence of the amorphous silicon layer. The higher resistivity of the a-Si layers implies a smaller distance between the metal lines that causes a higher shadowing. The worst optical coupling between the amorphous silicon and the antireflective coating implies a slight increase of reflectivity around the 600 nm wavelength.
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  • 12
    Publication Date: 2015-06-09
    Description: The hydrogenated amorphous silicon (a-Si:H)/hydrogenated microcrystalline silicon (c-Si:H) double p-type window layer has been developed and applied for improving microcrystalline silicon-germanium p-i-n single-junction thin-film solar cells deposited on textured SnO2:F-coated glass substrates. The substrates of SnO2:F, SnO2:F/c-Si:H(p), and SnO2:F/a-Si:H(p) were exposed to H2 plasma to investigate the property change. Our results showed that capping a thin layer of a-Si:H(p) on SnO2:F can minimize the Sn reduction during the deposition process which had H2-containing plasma. Optical measurement has also revealed that a-Si:H(p) capped SnO2:F glass had a higher optical transmittance. When the 20 nm c-Si:H(p) layer was replaced by a 3 nm a-Si:H(p)/17 nm c-Si:H(p) double window layer in the cell, the conversion efficiency () and the short-circuit current density () were increased by 16.6% and 16.4%, respectively. Compared to the standard cell with the 20 nm c-Si:H(p) window layer, an improved conversion efficiency of 6.19% can be obtained for the cell having a-Si:H(p)/c-Si:H(p) window layer, with  = 490 mV,  = 19.50 mA/cm2, and FF = 64.83%.
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  • 13
    Publication Date: 2015-08-04
    Description: Atomic layer deposition was used to coat CdS photoanodes with 7 nm thick TiO2 films to protect them from photocorrosion during photoelectrochemical water splitting. Photoelectrochemical measurements indicate that the TiO2 coating does not provide full protection against photocorrosion. The degradation of the film initiates from small pinholes and shows oscillatory behavior that can be explained by an Avrami-type model for photocorrosion that is halfway between 2D and 3D etching. XPS analysis of corroded films indicates that a thin layer of CdS remains present on the surface of the corroded photoanode that is more resilient towards photocorrosion.
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  • 14
    Publication Date: 2015-08-04
    Description: A new trough solar concentrator which is composed of multiple reflection surfaces is developed in this paper. The concentrator was analyzed firstly by using optical software. The variation curves of the collecting efficiency affected by tracking error and the deviation angle were given out. It is found that the deviation tolerance for the collector tracking system is about 8 degrees when the receiver is a 90 mm flat. The trough solar concentrators were tested under real weather conditions. The experiment results indicate that, the new solar concentrator was validated to have relative good collecting efficiency, which can be more than 45 percent when it operated in more 145°C. It also has the characteristics of rdust, wind, and snow resistance and low tracking precision requirements.
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  • 15
    Publication Date: 2015-08-04
    Description: Several studies have found that the decrease of photovoltaic (PV) cell temperature would increase the solar-to-electricity conversion efficiency. Water type PV/thermal (PV/T) system was a good choice but it could become freezing in cold areas of Northern China. This paper proposed a simple combination of common-used PV panel and heat pipe, called PV-heat pipe (PV-HP) solar collector, for both electrical and thermal energy generation. A simplified one-dimensional steady state model was developed to study the electrical and thermal performance of the PV-HP solar collector under different solar radiations, water flow rates, and water temperatures at the inlet of manifold. A testing rig was conducted to verify the model and the testing data matched very well with the simulation values. The results indicated that the thermal efficiency could be minus in the afternoon. The thermal and electrical efficiencies decreased linearly as the inlet water temperature and water flow rate increased. The thermal efficiency increased while the electrical efficiency decreased linearly as the solar radiation increased.
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  • 16
    Publication Date: 2015-08-10
    Description: Construction and characterization of an inflatable mirror prototype made out of flexible polymeric membranes are being presented. Surfaces were curved by imposing a slight excess of air pressure. Lightweighted, lowcost, and commercially available materials were selected in order to produce solar concentration elements at competitive prices. In this sense, large-area, image-forming mirrors with low optical acuity were achieved by concentration purposes. Optical characterization of the mirror’s shape at a given pressure or curvature radius was done by means of a structuredlight technique with a resolution of 0.1 mm finding a conical shape acquired by the inflated mirror as the best approximation. Concentration ratio achieved for a focal length of 5068 mm was of 25.1 suns, making a promising approach for lowering initial investment costs in applications such as hot-water, parabolic dish with Stirling engines, or concentrated photovoltaic electricity generation.
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  • 17
    Publication Date: 2015-08-27
    Description: Green synthesis of metallic particles has become an economic way to improve and protect the environment by decreasing the use of toxic chemicals and eliminating dyes. The synthesis of metal particles is gaining more importance due to its simplicity, rapid rate of synthesis of particles, and environmentally friendly. The present work aims to report a novel and environmentally friendly method for the synthesis of iron particles using deoiled Pimenta dioica L. Merrill husk as support. The indigo carmine removal efficiency by ozonation and catalyzed ozonation is also presented. Synthesized materials were characterized by N2 physisorption and scanning electron microscopy (SEM/EDS). By UV-Vis spectrophotometry the removal efficiency of indigo carmine was found to be nearly 100% after only 20 minutes of treatment under pH 3 and with a catalyst loading of 1000 mgL−1. Analytical techniques such as determination of the total organic carbon content (TOC) and chemical oxygen demand (COD) showed that iron particles supported on deoiled Pimenta dioica L. Merrill husk can be efficiently employed to degrade indigo carmine and achieved a partial mineralization (conversion to CO2 and H2O) of the molecule. From the results can be inferred that the prepared biocomposite increases the hydroxyl radicals generation.
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  • 18
    Publication Date: 2015-08-27
    Description: The individual methods of disinfection peracetic acid (PAA) and UV radiation and combined process PAA/UV in water (synthetic) and sanitary wastewater were employed to verify the individual and combined action of these advanced oxidative processes on the effectiveness of inactivation of microorganisms indicators of fecal contamination E. coli, total coliforms (in the case of sanitary wastewater), and coliphages (such as virus indicators). Under the experimental conditions investigated, doses of 2, 3, and 4 mg/L of PAA and contact time of 10 minutes and 60 and 90 s exposure to UV radiation, the results indicated that the combined method PAA/UV provided superior efficacy when compared to individual methods of disinfection.
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  • 19
    Publication Date: 2015-06-02
    Description: The big advantage of LED is the flexible spectral design to make white light using different color mixing schemes. Recently, the color mixing of RGB LEDs is mostly done by sealing all three chips at single package and regulated the mix ratio of these three colors to produce the color of light. And, by changing the LEDs array alignment, RGB chips can achieve overlapping colors of light and create the fun of changing colors in light mixing. Therefore, the purpose of this study is to propose an innovative technique of light mixing. By applying the mechanism design, a RGB light mixing mechanism is produced. Each of the RGB LEDs lamp-type is installed on the couple link of the three mechanisms, respectively. By driving a crank makes the couple link and an output link to produce the relative motion, this will result in the fact that the RGB lamps can project lights on the same plane in order to obtain the color mixing. Unlike mixing technique by control system, this design generates light mixing and changes of color with the synchronized driving of three mechanisms, thus achieving the dazzling perception of single-color lights or mixing of multiple colors for creating ambience of a space.
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  • 20
    Publication Date: 2015-05-28
    Description: We report on the photodegradation of diclofenac (DCF) by hydrothermal anatase nanocrystals either free or immobilized in porous silica matrix (TS) in connection to the type and amount of reactive oxygen species (ROS), in order to have deeper insight into their role in the photocatalysis and to provide an effective tool to implement the DCF mineralization. TiO2 and TS exhibit a remarkable efficiency in the DCF abatement, supporting that the utilization of anatase nanoparticles with the highly reactive , , and exposed surfaces can be an effective way for enhancing the photooxidation even of the persistent pollutants. Furthermore, the hydrothermal TiO2, when immobilized in silica matrix, preserves its functional properties, combining high photoactivity with an easy technical use and recovery of the catalyst. The catalysts performances have been related to the presence of OH•, , and species by electron paramagnetic resonance spin-trap technique. The results demonstrated that the ROS concentration increases with the increase of photoactivity and indicated a significant involvement of in the DCF degradation. The efficacy of TiO2 when immobilized on a silica matrix was associated with the high ROS life time and with the presence of singlet oxygen, which contributes to the complete photomineralization of DCF.
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  • 21
    Publication Date: 2016-08-01
    Description: The aim of this work was to couple physical-chemical approaches with photocatalysis to reduce by a simple, inexpensive way the organic load of olive mill wastewater (OMW), mandatorily prior to the final discharge. Before irradiation, different sorbents were tested to remove part of the organic fraction, monitored by measuring chemical oxygen demand (COD) and polyphenols (PP). Different low-cost, safe materials were tested, that is, Y zeolite (ZY), montmorillonite, and sepiolite. Considerable decrease of organic load was obtained, with the highest abatement (40%) provided by ZY (10 g L−1 in 1 : 10 OMW). Use of the three sorbents, in particular ZY, was convenient compared to commercial activated carbons. UV light photocatalytic tests, performed using P25 TiO2 on ZY-treated OMW, yielded quantitative remediation (ca. 90%). Also solar light provided significative results, PP being lowered by 74% and COD by 56%. Sol-gel anatase TiO2 and N-doped anatase TiO2 were also tested, obtaining good results, around 80% PP and 40% COD. Finally, an integrated approach was experimented by ZY-supported anatase TiO2 (TiO2@ZY). This photoreactive sorbent allowed one-pot treatment of OMW significative abatements of PP (77%) and COD (39%) with only 1 g L−1 material, under solar light.
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  • 22
    Publication Date: 2016-08-03
    Description: Molybdenum (Mo) thin films are widely used as rear electrodes in copper indium gallium diselenide (CIGS) solar cells. The challenge in Mo deposition by magnetron sputtering lies in simultaneously achieving good adhesion to the substrates while retaining the electrical and optical properties. Bilayer Mo films, comprising five different thickness ratios of a high pressure (HP) deposited bottom layer and a low pressure (LP) deposited top layer, were deposited on 40 cm × 30 cm soda-lime glass substrates by DC magnetron sputtering. We focus on understanding the effects of the individual layer properties on the resulting bilayer Mo films, such as microstructure, surface morphology, and surface oxidation. We show that the thickness of the bottom HP Mo layer plays a major role in determining the micromechanical and physical properties of the bilayer Mo stack. Our studies reveal that a thicker HP Mo bottom layer not only improves the adhesion of the bilayer Mo, but also helps to improve the film crystallinity along the preferred [] direction. However, the surface roughness and the porosity of the bilayer Mo films are found to increase with increasing bottom layer thickness, which leads to lower optical reflectance and a higher probability for oxidation at the Mo surface.
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  • 23
    Publication Date: 2016-08-01
    Description: Three hydrocalumite-like compounds in a Ca/Al ratio of 2 containing nitrate and acetate anions in the interlaminar region were prepared by a simple, economic, and environmentally friendly method. The solids were characterized by X-ray powder diffraction (XRD), thermogravimetric (TG) analysis, nitrogen adsorption-desorption at −196°C, scanning electron microscopy (SEM), infrared spectroscopy (FTIR), and UV-Vis Diffuse Reflectance Spectroscopy (DRS). The catalytic activity of the calcined solids at 700°C was tested in the photodegradation of 2,4-dichlorophenoxyacetic acid (2,4-D) where 57% degradation of 2,4-D (40 ppm) and a mineralization percentage of 60% were accomplished within 150 minutes. The photocatalytic properties were attributed to mayenite hydration, since the oxide ions in the cages are capable of reacting with water to form hydroxide anions capable of breaking down the 2,4-D molecules.
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  • 24
    Publication Date: 2016-06-21
    Description: Photovoltaic (PV) energy is one of the most important energy sources since it is clean and inexhaustible. It is important to operate PV energy conversion systems in the maximum power point (MPP) to maximize the output energy of PV arrays. An MPPT control is necessary to extract maximum power from the PV arrays. In recent years, a large number of techniques have been proposed for tracking the maximum power point. This paper presents a comparison of different MPPT methods and proposes one which used a power estimator and also analyses their suitability for systems which experience a wide range of operating conditions. The classic analysed methods, the incremental conductance (IncCond), perturbation and observation (P&O), ripple correlation (RC) algorithms, are suitable and practical. Simulation results of a single phase NPC grid connected PV system operating with the aforementioned methods are presented to confirm effectiveness of the scheme and algorithms. Simulation results verify the correct operation of the different MPPT and the proposed algorithm.
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  • 25
    Publication Date: 2016-06-21
    Description: Concentrated sunlight that is transmitted by fiber optics has been used for generating electricity, heat, and daylight. On the other hand, multijunction photovoltaic cells provide high efficiency for generating electricity from highly concentrated sunlight. This study deals with designing and simulating a high-efficiency coupler, employing a mathematical model to connect sunlight with fiber optics for multiple applications. The coupler concentrates and distributes irradiated light from a primary concentrator. In this study, a parabolic dish was used as the primary concentrator, a coupler that contains nine components called a compound truncated pyramid and a cone (CTPC), all of which were mounted on a plate. The material of both the CTPC and the plate was BK7 optical glass. Fiber optics cables and multijunction photovoltaic cells were connected to the cylindrical part of the CTPC. The fibers would transmit the light to the building to provide heat and daylight, whereas multijunction photovoltaic cells generate electricity. Theoretical and simulation results showed high performance of the designed coupler. The efficiency of the coupler was as high as , whereas the rim angle of the dish increased to an optimum angle. Distributed sunlight in the coupler increased the flexibility and simplicity of the design, resulting in a system that provided concentrated electricity, heat, and lighting for residential buildings.
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  • 26
    Publication Date: 2016-06-21
    Description: Water-soluble graphitic hollow carbon nanorods (wsCNRs) are exploited for their light-driven photochemical activities under outdoor sunlight. wsCNRs were synthesized by a simple pyrolysis method from castor seed oil, without using any metal catalyst or template. wsCNRs exhibited the light-induced photochemical degradation of methylene blue used as a model pollutant by the generation of singlet oxygen species. Herein, we described a possible degradation mechanism of methylene blue under the irradiation of visible photons via the singlet oxygen-superoxide anion pathway.
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  • 27
    Publication Date: 2016-06-22
    Description: Solar panels have become attractive in order to generate and supply electricity in commercial and residential applications. Their increased module efficiencies have caused not only a massive production but also a sensible drop on sale prices. Methods of characterization, instrumentation for in situ measurements, defect monitoring, process control, and performance are required. A temperature characterization method by means of thermograph analysis is exposed in this paper. The method was applied to multicrystalline modules, and the characterization was made with respect to two different variables, first a thermal transient and second a characterization with respect to the current. The method is useful in order to detect hot spots caused by mismatch conditions in electrical parameters. The description, results, and limitations of the proposed method are discussed.
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  • 28
    Publication Date: 2016-06-24
    Description: Fe-doped TiO2 (Fe/TiO2) film photocatalyst was prepared by sol-gel and dip-coating process to extend its photoresponsivity to the visible spectrum. To promote the CO2 reduction performance with the photocatalyst, some types of base materials used for coating Fe/TiO2, which were netlike glass fiber and Cu disc, were investigated. The characterization of prepared Fe/TiO2 film coated on netlike glass fiber and Cu disc was analyzed by SEM and EPMA. In addition, the CO2 reduction performance of Fe/TiO2 film coated on netlike glass disc, Cu disc, and their overlap was tested under a Xe lamp with or without ultraviolet (UV) light, respectively. The results show that the concentration of produced CO increases by Fe doping irrespective of base material used under the illumination condition with UV light as well as that without UV light. Since the electron transfer between two overlapped photocatalysts is promoted, the peak concentration of CO for the Fe/TiO2 double overlapping is approximately 1.5 times as large as the Fe/TiO2 single overlapping under the illumination condition with UV light, while the promotion ratio is approximately 1.1 times under that without UV light.
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  • 29
    Publication Date: 2016-05-27
    Description: The internal impedances of different dye-sensitized solar cell (DSSC) models were analyzed by electrochemical impedance spectrometer (EIS) with an equivalent circuit model. The Nyquist plot was built to simulate the redox reaction of internal device at the heterojunction. It was useful to analyze the component structure and promote photovoltaic conversion efficiency of DSSC. The impedance of DSSC was investigated and the externally connected module assembly was constructed utilizing single cells on the scaled-up module. According to the experiment results, the impedance was increased with increasing cells connected in series. On the contrary, the impedance was decreased with increasing cells connected in parallel.
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  • 30
    Publication Date: 2016-07-26
    Description: This paper identifies the partial shading problem of a PV module using the one-diode model and simulating the characteristics exhibiting multiple-peak power output condition that is similar to a PV array. A modified particle swarm optimization (PSO) algorithm based on the suggested search-agent deployment, retracking condition, and multicore operation is proposed in order to continuously locate the global maximum power point for the PV system. Partial shading simulation results for up to 16 modules in series/parallel formats are presented. A distributed PV system consisting of up to 8 a-silicon thin film PV panels and also having a dedicated DC/DC buck converter on each of the modules is tested. The converter reaches its steady state voltage output in 10 ms. However for MPPT operation, voltage, and current measurement interval is set to 20 ms to avoid unnecessary noise from the entire electric circuit. Based on the simulation and experiment results, each core of the proposed PSO operation should control no more than 4 PV modules in order to have the maximum tracking accuracy and minimum overall tracking time. Tracking for the global maximum power point of a distributed PV system under various partial shading conditions can be done within 1.3 seconds.
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  • 31
    Publication Date: 2016-07-29
    Description: This paper discusses the utilisation of PV systems for electric vehicles charging for transportation requirements of smart cities. The gap between PV power output and vehicles charging demand is highly variable. Therefore, there is a need for additional support from a public distribution grid or a storage device in order to handle the residual power. Long term measurement data retrieved from a charging station for 15 vehicles equipped with a PV system were used in the research. Low and high irradiation seasons influenced the PV output. The charging demand of electric vehicles varied over the course of a year and was correlated to weather conditions. Therefore, the sizing and performance of a supportive storage device should be evaluated in a statistical manner using long period observations.
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  • 32
    Publication Date: 2015-05-14
    Description: Hexagonal wurtzite pure ZnO and BiOBr-ZnO composites were synthesized by facile hydrothermal method. The amount of BiOBr as dopant was adjusted from 5 wt.% to 75 wt.%, and correspondingly the morphologies and crystal structures of the as-prepared composites were measured and discussed. Specifically, according to XRD patterns and SEM images, the main crystalline structure of ZnO was not destroyed after doping, but growth of ZnO crystals was inhibited by doping BiOBr. Meanwhile, the optical properties of the composites were measured by the diffuse reflectance spectra (DRS). The band gap of composites was also calculated using the classical Tauc equation and it was found to be around 3.0 eV. In the test of photocatalytic activation, the ZnO-BiOBr photocatalysts exhibited high photocatalytic efficiencies in the degradation of Rhodamine B (RhB) under visible-light irradiation. It was ascribed to not only the small size of crystalline, but also the reduction in the recombination rate of the photogenerated carriers for the enhancement effect of p-n heterojunction. This work sheds light on improving the photocatalytic performance by establishing the heterojunction and contributes to the development of a commercially competitive photocatalyst.
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  • 33
    Publication Date: 2015-04-28
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  • 34
    Publication Date: 2015-02-06
    Description: The photocatalytic degradation of indigo carmine (IC) dye in the presence of titanium dioxide under different conditions was reported. Several factors which interfere with the photodegradation efficiency as catalyst concentration, pH, initial concentration of dye, presence of inorganic anions, temperature, and the addition of hydrogen peroxide were studied under artificial irradiation with a 125 W mercury vapor lamp. Additionally, the catalyst supported on glass spheres was used for the photocatalytic degradation of the dye present in several types of waters in a CPC solar pilot plant. The photocatalytic products, carboxylic acids, and and were followed during IC mineralization. Formate, acetate, and oxalate were detected in real MWWTP secondary effluent. The mineralization efficiency was of 42 and 21% using in suspension and supported TiO2, respectively. In order to evaluate biological effects, Eisenia andrei earthworms were used as a model organism. No significant difference () of weight was observed in the earthworm submitted to different concentrations of IC and its photoproducts. The photocatalytic degradation of IC on TiO2 supported on glass spheres suffered strong influence of the water matrix; nevertheless the method has the enormous advantage that it eliminates the need for the final catalyst removal step, reducing therefore the cost of treatment.
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  • 35
    Publication Date: 2015-04-20
    Description: This paper proposes an integrated photovoltaic (PV) and proton exchange membrane fuel cell (PEMFC) system for continuous energy harvesting under various operating conditions for use with a brushless DC motor. The proposed scheme is based on the incremental conductance (IncCond) algorithm combined with the sliding mode technique. Under changing atmospheric conditions, the energy conversion efficiency of a PV array is very low, leading to significant power losses. Consequently, increasing efficiency by means of maximum power point tracking (MPPT) is particularly important. To manage such a hybrid system, control strategies need to be established to achieve the aim of the distributed system. Firstly, a Matlab/Simulink based model of the PV and PEMFC is developed and validated, as well as the incremental conductance sliding (ICS) MPPT technique; then, different MPPT algorithms are employed to control the PV array under nonuniform temperature and insolation conditions, to study these algorithms effectiveness under various operating conditions. Conventional techniques are easy to implement but produce oscillations at MPP. Compared to these techniques, the proposed technique is more efficient; it produces less oscillation at MPP in the steady state and provides more precise tracking.
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  • 36
    Publication Date: 2015-04-21
    Description: In photocatalysis, the recombination of electron-hole pairs is generally regarded as one of its most serious drawbacks. The synthesis of various composites with heterojunction structures has increasingly shed light on preventing this recombination. In this work, a BiOBr-Bi2WO6 photocatalytic heterojunction semiconductor was synthesized by the facile hydrothermal method and applied in the photocatalytic degradation process. It was determined that both reaction time and temperature significantly affected the crystal structure and morphologies of the photocatalysts. BiOBr (50 at%)-Bi2WO6 composites were prepared under optimum synthesis conditions (120°C for 6 h) and by theoretically analyzing the DRS results, it was determined that they possessed the suitable band gap (2.61 eV) to be stimulated by visible-light irradiation. The photocatalytic activities of the as-prepared photocatalysts were evaluated by the degradation of Rhodamine B (RhB) under visible-light irradiation. The experimental conditions, including initial concentration, pH, and catalyst dosage, were explored and the photocatalysts in this system were proven stable enough to be reused for several runs. Moreover, the interpreted mechanism of the heterojunction enhancement effect proved that the synthesis of a heterojunction structure provided an effective method to decrease the recombination rate of the electron-hole pairs, thereby improving the photocatalytic activity.
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  • 37
    Publication Date: 2016-03-25
    Description: The performance of a solar assisted heat pump dryer integrated with biomass furnace has been designed and evaluated for drying red chillies, and drying kinetics of red chillies were evaluated. The red chillies were dried from 22 kg with moisture content of 4.26 db to moisture content of 0.08 db which needed 11 hours, with the average drying chamber temperature, drying chamber relative humidity, and an air mass flow rate of 70.5°C, 10.1%, and 0.124 kg/s, respectively, while the open sun drying needed 62 hours. Compared to open sun drying, this dryer yielded 82% saving in drying time. The drying rate, the specific moisture extraction rate, and thermal efficiency of the dryer were estimated in average to be about 1.57 kg/h, 0.14 kg/kWh, and 9.03%, respectively. Three mathematical models, the Newton, Henderson-Pabis, and Page models, were fitted to the experimental data on red chillies dried by solar assisted heat pump dryer integrated with biomass furnace and open sun drying. The performance of these models was evaluated by comparing the coefficient of determination (), mean bias error (MBE), and root mean-square error (RMSE). The Page model gave the best results for representing drying kinetics of red chillies.
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  • 38
    Publication Date: 2016-04-04
    Description: A novel modeling tool for calculation of central receiver concentrated flux distributions is presented, which takes into account drift effects. This tool is based on a drift model that includes different geometrical error sources in a rigorous manner and on a simple analytic approximation for the individual flux distribution of a heliostat. The model is applied to a group of heliostats of a real field to obtain the resulting flux distribution and its variation along the day. The distributions differ strongly from those obtained assuming the ideal case without drift or a case with a Gaussian tracking error function. The time evolution of peak flux is also calculated to demonstrate the capabilities of the model. The evolution of this parameter also shows strong differences in comparison to the case without drift.
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  • 39
    Publication Date: 2016-04-08
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  • 40
    Publication Date: 2015-12-28
    Description: The purpose of this study was to evaluate the photostability of inclusion complexes of the histamine antagonist loratadine (LORA) with -, -, and -cyclodextrins (CDs). Accordingly, binary drug-CD complexes were prepared using the coevaporation method at 1 : 1, 1 : 2, and 1 : 3 stoichiometric ratios, which were characterized by thermal analysis. Subsequently, solutions of the complexes at 500 μg mL−1 in HCl 0.1 M were subjected to irradiation in a photostability chamber for 12 hours, and the content of the remaining active ingredient was quantified by means of high-performance liquid chromatography. It is possible to observe the presence of two products originating from photodegradation (P1 and P2), which were identified in solutions of loratadine with - and -CD. By means of statistical analysis, we conclude that the drug:-CD and drug:-CD (1 : 1) complexes proved to be more efficient in the photostability assay, obtaining a nonsignificant level of degradation and full recovery of LORA.
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  • 41
    Publication Date: 2016-02-09
    Description: Design, construction, and evaluation of a cylindrical-trough solar concentrator with 1.3 m aperture, 2.15 m length, and 0.54 m focal length, with heat-pipe or vacuum tube receiver and one axis tracking system, are presented. Design performance was tested under ASHRAE standard 93-1986 (RA 91). The concentrator system is lightweight and inexpensive since it was made of polymeric membranes and was pneumatically inflated to acquire its cylindrical shape achieving good optical quality. Further implementation of a flat and a cylindrical extension of the concentrating mirror as secondary mirrors was incorporated into the concentrator design in order to compensate for seasonal variations of collected radiation. Total initial investment of $163.30 or $58.5/m2 and efficiencies ranging from 33 to 25% for 25 up to 65°C show an excellent cost-performance ratio. Construction, costs, and efficiencies obtained by us and developed by other groups are compared to emphasize the high cost/benefit ratio and efficiencies of this approach.
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  • 42
    Publication Date: 2015-12-30
    Description: An optimized fabrication of bulk-heterojunction solar cells (BHJ SCs) based on previously reported diketopyrrolopyrrole donor, ethyl-hexylated DPP(TBFu)2, as well as two new DPP(TBFu)2 derivatives with ethyl-hexyl acetate and diethyl acetal solubilizing side-chains and PC60BM as an acceptor is demonstrated. Slow gradual annealing of the solar cell causing the effective donor-acceptor reorganization, and as a result higher power conversion efficiency (PCE), is described. By replacing a hole transporting layer PEDOT:PSS with MoO3 we obtained higher PCE values as well as higher thermal stability of the anode contact interface. DPP(TBFu)2 derivative containing ethyl-hexyl acetate solubilizing side-chains possessed the best as-cast self-assembly and high crystallinity. However, the presence of ethyl-hexyl acetate and diethyl acetal electrophilic side-chains stabilizes HOMO energy of isolated DPP(TBFu)2 donors with respect to the ethyl-hexylated one, according to cyclic voltammetry.
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  • 43
    Publication Date: 2016-01-05
    Description: The biggest problems of our time are environmental pollution and the reduction of fossil fuel resources. In recent years, photovoltaic (PV) has started to be used efficiently in order to produce electrical energy from solar energy throughout the world. In this study, a wheat mover machine taking its energy with PV technology transformation from the sun was designed supported by smart sensors. The designed vehicle was tested in two wheat fields in Sivas in Turkey. It was seen that daily average sunshine rates were not lower than 700 Watt/m2 during the testing dates and time. The amounts of electrical charge used to mow 5 m2 and 50 m2 areas are obtained as 500 mAh and 3395 mAh, respectively. Also maximum power is calculated from used PV panel as 26.15 Watt during the day of the experiments. The range of solar radiation intensity is found 4.5 kWh/m2/day at the studied kWh which was 0.140 USD on the date of November 2015. This system is 94.5% more economic than conventional mowers over an area of 1000 m2.
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  • 44
    Publication Date: 2016-01-06
    Description: The mean cost price of electricity in Burkina Faso at the end of the last quarter of 2012 was 158 FCFA/kWh for a country where more than 46% of the population lives below the national poverty threshold. To look for solution to that problem, the resort to photovoltaic solar energy is justified for that country. The purpose of this study is to promote the integration of both technical and economical surveys in solar energy preliminary projects in Ouagadougou. To reach that, investigations were carried out in some households and attention was paid from the calibration of the domestic electric meters. Energy demands collected within each household allow us to design a corresponding solar kit through optimization rules. An estimate was edited and financial viability study for each household was also carried out thereafter. In this study, only households using the national electricity network calibration meter on their disadvantage favorably answered to all financial indicators and appear as the only one that could profit from such project. This work is helpful to note that photovoltaic solar energy still stays at a primitive level of competitiveness compared to conventional energy resources for small systems in Ouagadougou.
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  • 45
    Publication Date: 2016-01-12
    Description: Multiwall carbon nanotubes (MWCNTs) were modified by acids (H2SO4 : HNO3) for generating active groups on the nanotube surface. Unmodified- and modified-carbon nanotubes were coated on the conductive glass and conductive plastic substrates by a slurry paste method, and they were used as the counter electrodes (CEs) of dye-sensitized solar cells (DSSCs). Scanning electron microscopy reveals that carbon nanotubes are evenly deposited on the conductive glass. The efficiency of the glass based DSSCs of unmodified- and modified-carbon nanotubes and Pt CEs is ~4.73%, ~5.66%, and ~6.08%, respectively. The efficiency of the plastic based DSSCs of the unmodified- and modified-carbon nanotubes CEs is ~0.80% and ~2.11%, respectively. The voltammogram and electrochemical impedance spectroscopy results suggest that the superior performance of the modified-carbon nanotubes DSSCs is attributable to the high electrocatalytic activity and the low charge-transfer resistance of the modified-carbon nanotubes film over the unmodified-carbon nanotubes film.
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  • 46
    Publication Date: 2019
    Description: In this work, we studied the effect of TiO2 sensitization with dry biomass extracted of cyanobacteria on the degradation of methylene blue dye (AM). Cyanobacterial cultures isolated from water samples were collected from the swamp of Malambo in Colombia; two main genera of cyanobacteria were identified, and they were cultivated with BG-11 culture medium. The concentrations of chlorophyll a in the exponential and stationary phases of growth were measured; the phycobilin content was quantified by spectrophotometry. Thin films of TiO2 were deposited by a doctor blade method, and they were sensitized by wet impregnation. Furthermore, a methylene blue (MB) photodegradation process was studied under visible light irradiation on the cyanobacterial biomass sensitized TiO2 material (TiO2/sensitizer); besides, the pseudo-first-order model was used to obtain kinetic information about photocatalytic degradation. The results showed that the BG-11+ treatment reported a higher amount of dry biomass and phycobiliproteins. After the sensitization process, the TiO2/sensitizer thin films showed a significant red shift in the optical activity; besides the thin film roughness decreasing, the TiO2/sensitizer showed photocatalytic activity of 23.2% under visible irradiation, and besides, the kinetic () constant for TiO2/sensitizer thin films was 3.1 times greater than the value of TiO2 thin films. Finally, results indicated that cyanobacterial biomass is a suitable source of natural sensitizers to be used in semiconductor sensitization.
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  • 47
    Publication Date: 2019
    Description: Constant exposure of a photovoltaic (PV) panel to sunlight causes it to overheat and, consequently, its rated efficiency decreases leading to a drop in its generated power. In this study, a PV panel was tested under standard test conditions in a halogen lamp solar simulator at different solar irradiance values. The PV panel was then fitted with heat dissipating fins and measured under identical test parameters; thereafter, repurposed materials such as high-density polyethylene (HDPE) and plastic bags were, separately, added to the PV panel with fitted heat-extraction fins and the performance was evaluated again. Passively cooling the PV panel with fins and repurposed materials resulted in a 22.7% drop in the PV panel’s temperature, while an 11.6% increase in power output occurred at 1000 W m-2. Utilizing repurposed waste materials in PV cooling improves a panel’s efficiency and saves the environment from the ecological effects of dumping these materials.
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  • 48
    Publication Date: 2019
    Description: Double modifications of TiO2 by doping with WO3 and by dispersing on a SiO2 support were made by the one-pot sol-gel method. Doping with W shifts the TiO2 band gap energy from 3.2 eV to around 3.06 eV. The surface area of the supported W-TiO2/SiO2 material was significantly increased, by approximately 3 times, in comparison to the bare TiO2. The photocatalytic activities of the catalysts were evaluated in the degradation reaction of p-nitrophenol in aqueous solution and basic medium. After 240 min of photodegradation, more than approximately 99% p-nitrophenol could be mineralized with the most active W-TiO2/SiO2 catalyst. Under UV irradiation, p-nitrophenol was initially photodegraded into hydroquinone and benzosemiquinone intermediates, which were further degraded into smaller fragments such as organic carboxylic acids and finally completely mineralized. A proposed photoreaction mechanism was presented based on the key roles of the surface hydroxyl species and superoxide radicals such as O2- and ⋅OH, together with W6+/W5+ couples and e-/h+ pairs in the catalysts in the p-nitrophenol photodegradation. The one-pot sol-gel synthesis method was proven to be effective to obtain W-TiO2/SiO2 catalyst with large surface area and high photocatalytic activity, and it can be also used for the preparation of other heterogeneous catalysts.
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  • 49
    Publication Date: 2018
    Description: In this study, an exergy analysis of two kinds of solar-driven cogeneration systems consisting of solar collectors and an organic Rankine cycle (ORC) is presented for series mode and parallel mode. Three kinds of solar collectors are considered: flat-plate collectors (FPC), evacuated tube collectors (ETC), and parabolic trough collectors (PTC). This study mainly compares the exergy output of the two kinds of solar cogeneration systems under different temperatures of the return heating water and different inlet temperatures of the solar collectors. This study shows that, from the perspective of or , the parallel mode is superior to the series mode. From the perspective of , the parallel mode is superior to the series mode when the solar collector is FPC; however, the series mode is superior to the parallel mode when the solar collector is PTC. When the solar collector is ETC, the result depends on the temperature of the return heating water. When the temperature of the return heating water is low (below 46°C), the series mode is better, and when the temperature of the return heating water is high (above 46°C), the parallel mode is better.
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  • 50
    Publication Date: 2018
    Description: Pharmaceuticals are present in an aquatic environment usually in low (ng/L) concentrations. Their continuous release can lead to unwanted effects on the nontarget organisms. The main points of their collection and release into the environment are wastewater treatment plants. The wastewater treatment plants should be upgraded by new technologies, like advanced oxidation processes (AOPs), to be able to degrade these new pollutants. In this study, the degradation of albendazole (ALB), a drug against parasitic helminths, was investigated using four UV-based AOPs: UV photolysis, UV photocatalysis (over TiO2 film), UV + O3, and UV + H2O2. The ranking of the degradation process degree of the ALB and its degradation products for studied processes is as follows: UV photolysis 
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  • 51
    Publication Date: 2018
    Description: The energy scenario today is focused on the development and usage of solar cells, especially in the paradigm of clean energy. To readily create electron and hole pairs, solar cells utilize either photoactive or photosensitive components. A bulk heterojunction (BHJ) is a nanolayer consisting of donor and acceptor components with a large interpenetrated acceptor and donor contact area. In this context, a mix of P3HT and PCBM offers novelty for its use as an acceptor as well as a donor. In the work presented here, we address the mechanism of modelling and characterization of a BHJ-based polymer solar cell. Here, a new design of BHJ polymer solar cells have been designed, modelled, using Silvaco TCAD in the Organic Solar module, and matched with an already assembled device having similar features. Using this model, we have been able to estimate key parameters for the modelled devices, such as the short-circuit current density, open-circuit voltage, and fill factor with less than 0.25 error index compared to the fabricated counterpart, paving the way for fabless polymer solar cell design and optimization.
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  • 52
    Publication Date: 2018
    Description: This work undertakes both simulation and experimental studies of a new design of a photovoltaic thermal solar air collector (PV/T). In order to improve the thermal and electrical performances for a specific application, the analytical expressions for thermal parameters and efficiency are derived by developing an energy balance equation for each component of the PV/T air collector. This type of hybrid collector can be applied in the facades of buildings. The electricity and heat produced will satisfy the energy needs of the buildings, while ensuring an aesthetic view of its facades. A typical prototype was designed, constructed, and implemented in the applied research unit on renewable energies in Ghardaia, situated in the south of Algeria. This region has semiarid characteristics. Results obtained by an experimental test are presented and compared to those predicted through simulation. Results include the temperature of each component of the PV/T collector and air temperature at the inlet and outlet of the channel. It has been found that the theoretical results predicted by the developed mathematical model, for instance, outlet temperature, agree with those found through experimental work.
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  • 53
    Publication Date: 2018
    Description: Mismatching operating conditions negatively affect the extracted energy in photovoltaic (PV) systems. They may also lead to dangerous localized heating phenomena (hot spots) that can cause, in turn, accelerated ageing and reduced reliability. Since the adoption of bypass diodes or smart active switches does not prevent the occurrence of hotspots, it is necessary to investigate alternative strategies. A promising solution is represented by the proper regulation of the operating point of the PV cells in the current vs. voltage (-) or power vs. voltage (-) planes when mismatching conditions occur. In particular, in this paper, the existence of operating points allowing a suitable compromise between maximization of the extracted power and minimization of thermal stresses, due to hot spots, is experimentally evidenced. Experimental results highlighting the link existing between the operating point in the - plane and the PV cell temperature distribution under uniform and mismatching operating conditions are presented and discussed. On the basis of the obtained experimental results, it is possible to state that, when mismatching conditions occur, it is mandatory to properly choose the operating point: the global maximum power point may not be the best operating point. Hence, it is crucial to gain information about the eventual occurrence of mismatching conditions in order to be able to properly choose the best operating point. Therefore, another crucial aspect that is evidenced in this paper is represented by the fact that the detection of the occurrence of mismatching conditions, based on the analysis of the shape of the - and/or - characteristics, is effective only if the analysis is carried out for both positive and negative voltages.
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  • 54
    Publication Date: 2018
    Description: Highly light scattering structures have been generated in a poly(ethylene terephthalate) (PET) film using a CO2 laser. The haze, and in some cases the transparency, of the PET films have been improved by varying the processing parameters of the laser (namely, scanning velocity, laser output power, and spacing between processed tracks). When compared with the unprocessed PET, the haze has improved from an average value of 3.26% to a peak of 55.42%, which equates to an absolute improvement of 52.16% or a 17-fold increase. In addition to the optical properties, the surfaces have been characterised using optical microscopy and mapped with an optical profilometer. Key surface parameters that equate to the amount and structure of surface roughness and features have been analysed. The CO2 laser generates microstructures at high speed, without affecting the bulk properties of the material, and is inherently a chemical-free process making it particularly applicable for use in industry, fitting well with the high-throughput, roll to roll processes associated with the production of flexible organic photovoltaic devices.
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  • 55
    Publication Date: 2019
    Description: The large and continuous use of fossil fuels as a primary energy source has led to several environmental problems, such as the increase of the greenhouse effect. In order to minimize these problems, attention has been drawn to renewable energy production. Solar energy is an attractive candidate as renewable source due to its abundance and availability. For this, it is necessary to develop devices able to absorb sunlight and convert it into fuels or electricity in a economical, technical and sustainable way. The so-called artificial photosynthesis has called the attention of researchers due to the possibility of using solar photocatalysts in converting water and CO2 into fuels. This manuscript presents a review of the recent developments of hybrid systems based on molecular photocatalysts immobilized on semiconductor surfaces for solar fuel production through water oxidation and CO2 reduction and also discusses the current challenges for the potential application of these photocatalyst systems.
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  • 56
    Publication Date: 2018
    Description: This study is aimed at providing a comparison between fuzzy systems and convectional P&O for tracking MPP of a PV system. MATLAB/Simulink is used to investigate the response of both algorithms. Several weather conditions are simulated: (i) uniform irradiation, (ii) sudden changing, and (iii) partial shading. Under partial shading on a PV panel, multipeaks appeared in - characteristics of the panel. Simulation results showed that a fuzzy controller effectively finds MPP for all weather condition scenarios. Furthermore, simulation results obtained from the FLC are compared with those obtained from the P&O controller. The comparison shows that the fuzzy logic controller exhibits a much better behavior.
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  • 57
    Publication Date: 2019
    Description: Buildings consume large amounts of energy, and their transformation from energy users to producers has attracted increasing interest in the quest to help optimize the energy share, increasing energy efficiency and environmental protection. The use of energy-efficient materials is among the proposed approaches to increase the building’s energy balance, thus increasing the performance of building facades. Semitransparent building-integrated photovoltaic (BIPV), being one of the technologies with the potential to increase a building’s energy efficiency, is considered as a feasible method for renewable power generation to help buildings meet their own load, thus serving dual purposes. Semitransparent BIPV integration into buildings not only displaces conventional building facade materials but also simultaneously generates energy while retaining traditional functional roles. The awareness in improving building energy efficiency has increased as well as the awareness in promoting the use of clean or renewable energy technologies. In this study, semitransparent BIPV technology is reviewed in terms of energy generation, challenges, and ways to address limitations which can be used as a reference for the BIPV stakeholders.
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  • 58
    Publication Date: 2019
    Description: Based on the examination of the efficiency of solar plants, this study focuses on three main plants: a photovoltaic (PV) plant, a concentrated solar power (CSP) plant, and a hybrid PV/CSP plant. The modelling of the three plants has been implemented to evaluate the influence of design parameters (orientation angles, solar multiple (SM), thermal energy storage capacity (TES), and fraction of hybridization) on them. Several simulations have been recreated and discussed in details to study the optimal configuration of the two first plants and the profitability of the PV/CSP plants for Ouarzazate (Morocco) location. The findings demonstrate that the optimal orientation angles and TES/SM, respectively, affect the performances of PV and CSP plants, and they also reveal that PV/CSP systems have the benefits to increase the annual energy produced, reduce the cost, and offer a high dispatchability to supply a baseload. The implementing of optimal PV/CSP plant has a great economic impact on Ouarzazate city.
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  • 59
    Publication Date: 2019
    Description: Ternary nickel-cobalt lithium aluminate LiNiCoAlO2 (NCA, ) is an essential cathode material with many vital advantages, such as lower cost and higher specific capacity compared with lithium cobaltate and lithium iron phosphate materials. However, the noticeably irreversible capacity and reduced cycle performance of NCA cathode materials have restricted their further development. To solve these problems and further improve the electrochemical performance, numerous research studies on material modification have been conducted, achieving promising results in recent years. In this work, the progress of NCA cathode materials is examined from the aspects of surface coating and bulk doping. Furthermore, future research directions for NCA cathode materials are proposed.
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  • 60
    Publication Date: 2019
    Description: In this work, the effect of DIM on the PCE and photostability of PCDTBT:PC71BM PSCs was investigated. DIM is an effective additive in a BHJ PCDTBT:PC71BM solar cell since it fulfills the requirement of a selective PC71BM dissolution. PCE of the device based on PCDTBT:PC71BM processed with DIM is higher than that of the reference device. In terms of the device stability, the PSCs processed with DIM showed poor stability at longer light exposure time. For the device without DIM especially as the light exposure time was increased, the device stability was better because the PCDTBT could be shielded from air by an aggregated PC71BM layer. For the PCDTBT:PC71BM device processed with DIM, the results obtained from measurement indicates that it has a lower recombination rate. The result from IS measurement shows that for pristine PCDTBT:PC71BM devices with 3% DIM, the active layer resistance is lower compared to the device without DIM. However, after irradiating the device for 5 hr, the resistance of the device processed with DIM is higher and it is consistent with decreased PCE of the aged device.
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  • 61
    Publication Date: 2019
    Description: The aim of this work is to study the behaviour of a silicon solar cell under the irradiation of different fluences of high-energy proton radiation (10 MeV) and under constant multispectral illumination. Many theoretical et experimental studies of the effect of irradiation (proton, gamma, electron, etc.) on solar cells have been carried out. These studies point out the effect of irradiation on the behaviour of the solar cell electrical parameters but do not explain the causes of these effects. In our study, we explain fundamentally the causes of the effects of the irradiation on the solar cells. Taking into account the empirical formula of diffusion length under the effect of high-energy particle irradiation, we established new expressions of continuity equation, photocurrent density, photovoltage, and dynamic junction velocity. Based on these equations, we studied the behaviour of some electronic and electrical parameters under proton radiation. Theoretical results showed that the defects created by the irradiation change the carrier distribution and the carrier dynamic in the bulk of the base and then influence the solar cell electrical parameters (short-circuit current, open-circuit voltage, conversion efficiency). It appears also in this study that, at low fluence, junction dynamic velocity decreases due to the presence of tunnel defects. Obtained results could lead to improve the quality of the junction of a silicon solar cell.
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  • 62
    Publication Date: 2019
    Description: TiO2/SiO2 nanoparticles with 3, 5, and 10 molar percent of silica, were synthesized by hydrothermal method and characterized by SEM, TEM, N2 adsorption-desorption isotherms, X-ray diffraction, and Raman and UV-Vis spectroscopy. While pristine TiO2 thermally treated at 500°C presents a surface area of 36 m2 g-1 (±10 m2 g-1), TiO2/SiO2 containing 3, 5, and 10 molar percent of silica present surface areas of 93, 124, and 150 m2 g-1 (±10 m2 g-1), respectively. SiO2 is found to form very small amorphous domains well dispersed in the TiO2 matrix. X-ray diffraction and Raman spectroscopy data show that anatase-to-rutile phase transition temperature is delayed by the presence of SiO2, enabling single-anatase phase photoanodes for DSSCs. According to the measurements, photoanodes with 3% of SiO2 result in improved efficiency, which is mainly related to increased surface area and dye loading. In addition, the results suggest a gain in photocurrent related to the passivation of defects by SiO2.
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  • 63
    Publication Date: 2019
    Description: Umuokpo Amumara is a village with an estimated population of 9,000 people and about 800 households located in the eastern region of Nigeria in West Africa. This village has no access to power grids for over a decade of existence. Umuokpo, by virtue of its location 5°2735.9N 7°1960.0E, on the average receives about 6 hours of sunlight with a daily average irradiance of 6.12 kWh/m2. The solar energy can be tapped and harnessed to generate quality electricity for this small village. Since the wind speed is low (ranging between 3.0 m/s and 3.5 m/s), the wind resource cannot be incorporated into the design. The average load demand of the village is 9.422 MWh/day with a peak load of 1.3 MW. This paper is aimed at designing a small hybrid power system that can generate sustainable electricity for the village from renewable energy sources. The design also considers a backup diesel generator and an energy storage system. The designed system consists of a 2,750 kW solar photovoltaic (PV), a 21,600 kWh battery storage, a 1,500 kW power electronic converter, and a 1,000 kW diesel generator. The simulation suggests that the proposed system can adequately meet the electricity needs of the village. A sensitivity analysis is also carried out on the system to observe its behavior with varying levels of irradiation and load.
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  • 64
    Publication Date: 2019
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  • 65
    Publication Date: 2019
    Description: Aluminum acetylacetonate-based AlOx thin films were introduced as a low-cost, high-quality passivation layers for crystalline silicon solar cells. Films were formed by a spin coating method on p-type silicon substrates at 450°C in ambient air, O2, or water vapor (H2O/O2) for 15 or 120 min. XPS analysis confirms the AlOx formation and reveals a high intensity of interfacial SiOx at the AlOx/Si interface of processed wafers. Ambient H2O/O2 was found to be more beneficial for the activation of introduced AlOx passivation films which offers high lifetime improvements with a low thermal budget. Carrier lifetime measurements provides that symmetrically coated wafers reach 119.3 μs and 248.3 μs after annealing in ambient H2O/O2 for 15 min and 120 min, respectively.
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  • 66
    Publication Date: 2015-06-15
    Description: In order to simplify process procedure and improve conversion efficiency (η), we present new steps of laser opening and one-step POCl3 diffusion to fabricate selective emitter (SE) solar cells, in which heavily doped regions (HDR) and lightly doped regions (LDR) were formed simultaneously. For HDR, we divided six cells into two groups for POCl3 diffusion with sheet resistance () of 40 Ω/sq (for group A) and 50 Ω/sq (for group B). The dry oxidation duration at a temperature of 850°C was 18, 25, and 35 min for the 3 different cells in each group. This created six SE samples with different pairings for the HDR and LDR. The optimal cell (sample SE2) with values of 40/81 Ω/Sq in HDR/LDR showed the best η of 16.20%, open circuit voltage () of 612.52 mV, and fill factor (FF) of 75.83%. The improvement ratios are 1.57% for η and 14.32% for external quantum efficiency (EQE) as compared with those of the two-step diffusion process of our previous study. Moreover, the one-step laser opening process and omitting the step of removing the damage caused by laser ablation especially reduce chemistry pollution, thus showing ecofriendly process for use in industrial-scale production.
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  • 67
    Publication Date: 2015-06-17
    Description: This paper presents a new maximum power point tracking (MPPT) method based on the measurement of temperature and short-circuit current, in a simple and efficient approach. These measurements, which can precisely define the maximum power point (MPP), have not been used together in other existing techniques. The temperature is measured with a low cost sensor and the solar irradiance is estimated through the relationship of the measured short-circuit current and its reference. Fast tracking speed and stable steady-state operation are advantages of this technique, which presents higher performance when compared to other well-known techniques.
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  • 68
    Publication Date: 2015-06-17
    Description: Solar panels, which have become a good choice, are used to generate and supply electricity in commercial and residential applications. This generated power starts with the solar cells, which have a complex relationship between solar irradiation, temperature, and output power. For this reason a tracking of the maximum power point is required. Traditionally, this has been made by considering just current and voltage conditions at the photovoltaic panel; however, temperature also influences the process. In this paper the voltage, current, and temperature in the PV system are considered to be a part of a sliding surface for the proposed maximum power point tracking; this means a sliding mode controller is applied. Obtained results gave a good dynamic response, as a difference from traditional schemes, which are only based on computational algorithms. A traditional algorithm based on MPPT was added in order to assure a low steady state error.
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  • 69
    Publication Date: 2015-06-17
    Description: This paper presents a dynamic reconfiguration method for electrical connections in a Series-Parallel connected photovoltaic array under partial shading conditions. It is desirable to extract the maximum energy from the array, but it does not occur in situations where the modules have different points of operation caused by shading. The proposed method is then characterized by the maintenance of the PV array dimensions, that is; no module is removed or added to the array. Furthermore, the control algorithm is based on the Rough Sets Theory, which allows the fast and efficient implementation of a control system, comprising rules that identify the system optimal configuration.
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  • 70
    Publication Date: 2015-06-17
    Description: Maximum power point tracking (MPPT) for photovoltaic (PV) arrays is essential to optimize conversion efficiency under variable and nonuniform irradiance conditions. Unfortunately, conventional MPPT algorithms such as perturb and observe (P&O), incremental conductance, and current sweep method need to iterate command current or voltage and frequently operate power converters with associated losses. Under partial overcast conditions, tracking the real MPP in multipeak P-I or P-V curve model becomes highly challenging, with associated increase in search time and converter operation, leading to unnecessary power being lost in the MPP tracking process. In this paper, the noted drawbacks in MPPT-controlled converters are addressed. In order to separate the search algorithms from converter operation, a model parameter identification approach is presented to estimate insolation conditions of each PV panel and build a real-time overall P-I curve of PV arrays. Subsequently a simple but effective global MPPT algorithm is proposed to track the MPP in the overall P-I curve obtained from the identified PV array model, ensuring that the converter works at the MPP. The novel MPPT is ultrafast, resulting in conserved power in the tracking process. Finally, simulations in different scenarios are executed to validate the novel scheme’s effectiveness and advantages.
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  • 71
    Publication Date: 2015-06-17
    Description: The effect of piezoelectric polarization on GaN-based light emitting diodes (LEDs) with different kinds of prestrain layers between the multiple quantum wells (MQWs) and n-GaN layer is studied and demonstrated. Compared with the conventional LED, more than 10% enhancement in the output power of the LED with prestrain layer can be attributed to the reduction of polarization field within MQWs region. In this study, we reported a simple method to provide useful comparison of polarization fields within active region in GaN-based LEDs by using temperature-dependent electroluminescence (EL) measurement. The results pointed out that the polarization field of conventional LED was stronger than that of the others due to larger variation of the wavelength transition position (i.e., blue-shift change to red-shift) from 300 to 350 K, and thus the larger polarization field must be effectively screened by injecting more carriers into the MQWs region.
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  • 72
    Publication Date: 2015-06-17
    Description: A reinforcement learning-based maximum power point tracking (RLMPPT) method is proposed for photovoltaic (PV) array. By utilizing the developed system model of PV array and configuring the environment for the reinforcement learning, the proposed RLMPPT method is able to observe the environment state of the PV array in the learning process and to autonomously adjust the perturbation to the operating voltage of the PV array in obtaining the best MPP. Simulations of the proposed RLMPPT for a PV array are conducted. Experimental results demonstrate that, in comparison to an existing MPPT method, the RLMPPT not only achieves better efficiency factor for both simulated weather data and real weather data but also adapts to the environment much fast with very short learning time.
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  • 73
    Publication Date: 2015-06-17
    Description: Quasi-monocrystal ZnO film grown using the hydrothermal growth method is used for the fabrication of Cu2O/ZnO heterojunction (HJ) ultraviolet photodetectors (UV-PDs). The HJ was formed via the sputtering deposition of p-type Cu2O onto hydrothermally grown ZnO film (HTG-ZnO-film). The effect of annealing temperature in the nitrogen ambient on the photoluminescence spectra of the synthesized ZnO film was studied. The optoelectronic properties of Cu2O/ZnO film with various Cu2O thicknesses (250–750 nm) under UV light (365 nm; intensity: 3 mW/cm2) were determined. The UV sensitivity of the HTG-ZnO-film-based UV-PDs and the sputtered ZnO-film-based UV-PDs were 55.6-fold () and 8.8-fold (), respectively. The significant gain in sensitivity ( = 630%) of the proposed ZnO-film-based device compared to that for the device based on sputtered film can be attributed to the improved photoelectric properties of quasi-monocrystal ZnO film.
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  • 74
    Publication Date: 2015-06-17
    Description: This paper proposes a new type of variable fractional-order incremental conductance algorithm (VFOINC), combined with extenics variable step size (EVSS) control into the maximum power point tracking (MPPT) design for photovoltaic power systems. At the beginning of maximum power tracking, the fractional-order number is selected as 1; the good transient tracking characteristic of traditional incremental conductance method is used. When the maximum power point is approached, the fractional-order number is selected as variable fractional order; the curve profile of in fractional order is used to approximate, so that the system has good tracking effect in transient and steady states. The experimental and simulation results show that, compared with traditional incremental conductance method (INC) and fractional-order incremental conductance method (FOINC), this method has better MPPT effect.
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  • 75
    Publication Date: 2015-06-17
    Description: The smart grid and distributed generation based on renewable energy applications often involve the use of information and communication technology (ICT) coupled with advanced control and monitoring algorithms to improve the efficiency and reliability of the electrical grid and renewable generation systems. Photovoltaic (PV) systems have been recently applied with success in the fields of distributed generation due to their lower environmental impact where the electrical energy generation is related to the amount of solar irradiation and thus the angle of incident ray of the sun on the surface of the modules. This paper introduces an integration of ICTs in order to achieve the maximum power point tracking (MPPT) using a biaxial solar tracking system for PV power applications. To generate the references for the digital control of azimuth and elevation angles a Global Positioning System (GPS) by satellites is used which enables acquiring the geographic coordinates of the sun in real-time. As a total integration of the system a communication platform based on the 802.15.4 protocol for the wireless sensor networks (WSNs) is adopted for supervising and monitoring the PV plant. A 2.4 kW prototype system is implemented to validate the proposed control scheme performance.
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  • 76
    Publication Date: 2015-06-19
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  • 77
    Publication Date: 2015-10-14
    Description: This paper presents a model for predicting hourly solar radiation data using daily solar radiation averages. The proposed model is a generalized regression artificial neural network. This model has three inputs, namely, mean daily solar radiation, hour angle, and sunset hour angle. The output layer has one node which is mean hourly solar radiation. The training and development of the proposed model are done using MATLAB and 43800 records of hourly global solar radiation. The results show that the proposed model has better prediction accuracy compared to some empirical and statistical models. Two error statistics are used in this research to evaluate the proposed model, namely, mean absolute percentage error and root mean square error. These values for the proposed model are 11.8% and −3.1%, respectively. Finally, the proposed model shows better ability in overcoming the sophistic nature of the solar radiation data.
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  • 78
    Publication Date: 2015-10-21
    Description: Fractal analysis of free bases porphyrins was computed on atomic force microscopy (AFM) micrographs using two different methods: the correlation function method and the variable length scale method. The correlation function method provides fractal dimension only for short scale range; results indicate that only few images have fractal properties for short ranges; for the rest of them, no fractal dimension was found using the correlation function method. The variable length scale method occur information for long range scaling. All samples have fractal properties at higher scaling range. For three samples the correlation function method leads to the same fractal dimension as the variable length scale method and scaling ranges for both methods overlap. Results show the necessity to use both methods to describe the fractal properties of AB3  meso-porphyrins that may be used to predict their relative cell localization. In order to emphasize the influence of fractal and textural properties the results regarding their self-similarity and texture/morphology were further compared with their behavior in biological assessment, that is, functionality of some Jurkat cell lines.
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  • 79
    Publication Date: 2015-10-21
    Description: We investigate the photocatalytic activity of Cu doped NaNbO3 powder sample prepared by the modified polymer complex method. The photocatalytic activity of hydrogen evolution from methanol aqueous solution was improved by Cu 2.6 at% doping. The photocatalytic degradation of rhodamine B (RhB) under visible light irradiation was enhanced in comparison with pristine NaNbO3. Cu introduction improved the adsorption property of NaNbO3, judging from the Fourier transform infrared spectra. Moreover, the ultraviolet light excitation in Cu doped sample would accelerate the mineralized process.
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  • 80
    Publication Date: 2015-03-27
    Description: In this study, for the first time in the literature, solar assisted cooler with misting system established on an arbor with an area of 24 m2 and georeferenced in Elazig (38.6775° N, 39.1707° E), Turkey, is presented. Here, we present a system that reduces interior temperature of the arbor while increasing humidity. Also, the system generates required electricity with a solar photovoltaic module to power pressurized water pump through an inverter and stores it in a battery for use when there is no sunlight. The model of the photovoltaic module was implemented using a Matlab program. As a result of being an uncomplicated system, return on investment for the system is 3.7 years.
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  • 81
    Publication Date: 2016-06-28
    Description: Currently, standard semitransparent photovoltaic (PV) modules can largely replace architectural glass installed in the windows, skylights, and facade of a building. Their main features are power generation and transparency, as well as possessing a heat insulating effect. Through heat insulation solar glass (HISG) encapsulation technology, this study improved the structure of a typical semitransparent PV module and explored the use of three types of high-reflectivity heat insulation films to form the HISG building-integrated photovoltaics (BIPV) systems. Subsequently, the authors analyzed the influence of HISG structures on the optical, thermal, and power generation performance of the original semitransparent PV module and the degree to which enhanced performance is possible. The experimental results indicated that the heat insulation performance and power generation of HISGs were both improved. Selecting an appropriate heat insulation film so that a larger amount of reflective solar radiation is absorbed by the back side of the HISG can yield greater enhancement of power generation. The numerical results conducted in this study also indicated that HISG BIPV system not only provides the passive energy needed for power loading in a building, but also decreases the energy consumption of the HVAC system in subtropical and temperate regions.
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  • 82
    Publication Date: 2016-06-28
    Description: Photovoltaic (PV) generators suffer from fluctuating output power due to the highly fluctuating primary energy source. With significant PV penetration, these fluctuations can lead to power system instability and power quality problems. The use of energy storage systems as fluctuation compensators has been proposed as means to mitigate these problems. In this paper, the behavior of PV power fluctuations in Northern European climatic conditions and requirements for sizing the energy storage systems to compensate them have been investigated and compared to similar studies done in Southern European climate. These investigations have been performed through simulations that utilize measurements from the Tampere University of Technology solar PV power station research plant in Finland. An enhanced energy storage charging control strategy has been developed and tested. Energy storage capacity, power, and cycling requirements have been derived for different PV generator sizes and power ramp rate requirements. The developed control strategy leads to lesser performance requirements for the energy storage systems compared to the methods presented earlier. Further, some differences on the operation of PV generators in Northern and Southern European climates have been detected.
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  • 83
    Publication Date: 2016-07-05
    Description: Recent research and development of clean energy have become essential due to the global climate change problem, which is caused largely by fossil fuels burning. Therefore, biodiesel, a renewable and ecofriendly biofuel with less environmental impact than diesel, continues expanding worldwide. The process for biodiesel production involves a significant energy demand, specifically in the methanol recovery stage through a flash separator and a distillation column. Traditionally, the energy required for this process is supplied by fossil fuels. It represents an opportunity for the application of renewable energy. Hence, the current study presents a system of thermal energy storage modeled in TRNSYS® and supported by simulations performed in ASPEN PLUS®. The aim of this research was to supply solar energy for a methanol recovery stage in a biodiesel production process. The results highlighted that it is feasible to meet 91% of the energy demand with an array of 9 parabolic trough collectors. The array obtained from the simulation was 3 in series and 3 in parallel, with a total area of 118.8 m2. It represents an energy saving of 70 MWh per year.
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  • 84
    Publication Date: 2016-08-15
    Description: Solar energy conversion is an object of continuous research, focusing on improving the energy efficiency as well as the structure of photovoltaic cells. With efficiencies continuously increasing, state-of-the-art PV cells offer a good solution to harvest solar energy. However, they are still lacking the flexibility and conformability to be integrated into common objects or clothing. Moreover, many sun-exposed surface areas are textile-based such as garments, tents, truck coverings, boat sails, and home or outdoor textiles. Here, we present a new textile-based dye-sensitized solar cell (DSC) which takes advantage from the properties inherent to fabrics: flexibility, low weight, and mechanical robustness. Due to the necessary thermostability during manufacturing, our DSC design is based on heat-resistant glass-fiber fabrics. After applying all needed layers, the overall structure was covered by a transparent and simultaneously conductive protective film. The light and still flexible large-area devices (up to 6 cm2 per individual unit) are working with efficiencies up to 1.8% at 1/5 of the sun. Stability tests assure no loss of photovoltaic activity over a period of at least seven weeks. Therefore, our technology has paved the way for a new generation of flexible photovoltaic devices, which can be used for the generation of power in the mentioned applications as well as in modern textile architecture.
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  • 85
    Publication Date: 2016-08-22
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  • 86
    Publication Date: 2016-06-30
    Description: Shunting is one of the key issues in industrial silicon solar cells which degrade cell performance. This paper presents an approach for investigation of the performance degradation caused by the presence of ohmic extended shunts at various locations in industrial silicon solar cells. Location, nature, and area of the shunts existing in solar cells have been examined by lock-in infrared thermography (LIT). Based on LIT images and experimental dark I-V curves of solar cell, shunted cell has been modeled, from which loss in fill factor and efficiency due to the specific shunt has been obtained. Distributed diode modeling approach of solar cell has been exploited for obtaining simulation results which were supported by experimental measurements. The presented approach is useful to estimate performance reduction due to specific shunts and to quantify losses, which can help in improving the efficiency of solar cell during production by tackling the shunt related problems based on the level of severity and tolerance.
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  • 87
    Publication Date: 2016-07-01
    Description: Solar photovoltaic (PV) energy sources are rapidly gaining potential growth and popularity compared to conventional fossil fuel sources. As the merging of PV systems with existing power sources increases, reliable and accurate PV system identification is essential, to address the highly nonlinear change in PV system dynamic and operational characteristics. This paper deals with the identification of a PV system characteristic with a switch-mode power converter. Measured input-output data are collected from a real PV panel to be used for the identification. The data are divided into estimation and validation sets. The identification methodology is discussed. A Hammerstein-Wiener model is identified and selected due to its suitability to best capture the PV system dynamics, and results and discussion are provided to demonstrate the accuracy of the selected model structure.
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  • 88
    Publication Date: 2016-07-04
    Description: An atmospheric pressure chemical vapor deposition (AP-CVD) system has been newly developed for boron silicate glass (BSG) film deposition dedicating to solar cell manufacturing. Using the system, thermal boron diffusion from the BSG film is investigated and confirmed in terms of process stability for surface property before BSG deposition and BSG thickness. No degradation in carrier lifetime is also confirmed. A boron diffusion simulator has been newly developed and demonstrated for optimization of this process. Then, the boron thermal diffusion from AP-CVD BSG is considered to be the suitable method for N-type silicon solar cell manufacturing.
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  • 89
    Publication Date: 2016-07-05
    Description: Energy supply together with the data management is one of the key challenges of our century. Specifically, to decrease the climate change effects as energy requirement increases day by day poses a serious dilemma. It can be adequately reconciled with innovative data management in (renewable) energy technologies. The new environmental-friendly planning methods and investments that are discussed by researchers, governments, NGOs, and companies will give the basic and most important variables in shaping the future. We use modern data mining methods (SOM and -Means) and official governmental statistics for clustering cities according to their consumption similarities, the level of welfare, and growth rate and compare them with their potential of renewable resources with the help of Rapid Miner 5.1 and MATLAB software. The data mining was chosen to make the possible secret relations visible within the variables that can be unpredictable at first sight. Here, we aim to see the success level of the chosen algorithms in validation process simultaneously with the utilized software. Additionally, we aim to improve innovative approach for decision-makers and stakeholders about which renewable resource is the most suitable for an exact region by taking care of different variables at the same time.
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  • 90
    Publication Date: 2016-08-09
    Description: To quickly and precisely extract the parameters for solar cell models, inspired by simplified bird mating optimizer (SBMO), a new optimization technology referred to as population classification evolution (PCE) is proposed. PCE divides the population into two groups, elite and ordinary, to reach a better compromise between exploitation and exploration. For the evolution of elite individuals, we adopt the idea of parthenogenesis in nature to afford a fast exploitation. For the evolution of ordinary individuals, we adopt an effective differential evolution strategy and a random movement of small probability is added to strengthen the ability to jump out of a local optimum, which affords a fast exploration. The proposed PCE is first estimated on 13 classic benchmark functions. The experimental results demonstrate that PCE yields the best results on 11 functions by comparing it with six evolutional algorithms. Then, PCE is applied to extract the parameters for solar cell models, that is, the single diode and the double diode. The experimental analyses demonstrate that the proposed PCE is superior when comparing it with other optimization algorithms for parameter identification. Moreover, PCE is tested using three different sources of data with good accuracy.
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  • 91
    Publication Date: 2016-08-09
    Description: We have studied the p-type hydrogenated silicon oxide (:H) films prepared in the amorphous-to-microcrystalline transition region as a window layer in a-Si:H/a-:H multijunction solar cells. By increasing the -to- flow ratio () from 10 to 167, the :H(p) films remained amorphous and exhibited an increased hydrogen content from 10.2% to 12.2%. Compared to the amorphous :H(p) film prepared at low , the :H(p) film deposited at of 167 exhibited a higher bandgap of 2.04 eV and a higher conductivity of 1.15 × 10−5 S/cm. With the employment of :H(p) films prepared by increasing from 10 to 167 in a-Si:H single-junction cell, the FF improved from 65% to 70% and the efficiency increased from 7.4% to 8.7%, owing to the enhanced optoelectrical properties of :H(p) and the improved p/i interface. However, the cell that employed :H(p) film with over 175 degraded the p/i interface and degraded the cell performance, which were arising from the onset of crystallization in the window layer. Compared to the cell using standard a-:H(p), the a-Si:H/a-:H tandem cells employing :H(p) deposited with of 167 showed an improved efficiency from 9.3% to 10.3%, with of 1.60 V, of 9.3 mA/cm2, and FF of 68.9%.
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  • 92
    Publication Date: 2016-08-09
    Description: Subpicosecond transient absorption spectroscopy is a powerful tool used to clarify the exciton and carrier dynamics within the organic solar cells (OSCs). In this review article, we introduce a method to determine the absolute numbers of the excitons and carriers against delay time (t) only from the photoinduced absorption (PIA) and electrochemically induced absorption (EIA) spectra. Application of this method to rr-P3HT-, PTB7-, and SMDPPEH-based OSCs revealed common aspects of the carrier formation dynamics. First, the temporal evolution of the numbers of the excitons and carriers indicates that the late decay component of exciton does not contribute to the carrier formation process. This is probably because the late component has not enough excess energy to separate into the electron and hole across the donor/acceptor (D/A) interface. Secondly, the spectroscopy revealed that the exciton-to-carrier conversion process is insensitive to temperature. This observation, together with the fast carrier formation time in OSCs, is consistent with the hot exciton picture.
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  • 93
    Publication Date: 2015-10-20
    Description: Concentrating characteristics of the sunlight have an important effect on the optical-thermal conversion efficiency of solar concentrator and the application of the receiver. In this paper, radiation flux in the focal plane and the receiver with three focal lengths has been investigated based on Monte Carlo ray-tracing method. At the same time, based on the equal area-height and equal area-diameter methods to design four different shape receivers and numerical simulation of radiation flux distribution characteristics have also been investigated. The results show that the radiation flux in the focal plane increases with decreasing of the focal length and the diameter of the light spot increases with increasing of the focal length. The function of the position with a maximum of radiation flux has been obtained according to the numerical results. The results also show that the radiation flux distribution of cylindrical receiver has the best performance in all four receivers. The results can provide a reference for future design and application of concentrating solar power.
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  • 94
    Publication Date: 2015-10-20
    Description: A theoretical analytical method for optical properties of cavity absorber was proposed in this paper and the optical design software TracePro was used to analyze the optical properties of triangular cavity absorber. It was found that the optimal optical properties could be achieved with appropriate aperture width, depth-to-width ratio, and offset distance from focus of triangular cavity absorber. Based on the results of orthogonal experiment, the optimized triangular cavity absorber was designed. Results showed that the standard deviation of irradiance and optical efficiency of optimized designed cavity absorber were 30528 W/m2 and 89.23%, respectively. Therefore, this study could offer some valuable references for designing the parabolic trough solar concentrator in the future.
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  • 95
    Publication Date: 2015-10-27
    Description: Development of a new concept of glazed PVT collector based on temperature resistant polysiloxane encapsulation material is presented together with the results from experimental testing and modelling. Performance and economic analysis in 4 different European climates has been done to derive the competitive price of the PVT collector concepts with main focus on the glazed PVT collector under development. Results have shown that specific market price 400 to 500 EUR/m2 for the glazed PVT collector should not be exceeded in order to become competitive with conventional combination of photothermal and photovoltaic collectors.
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  • 96
    Publication Date: 2015-10-28
    Description: Outdoor experimentation of solar cells is essential to maximize their performance and to assess utilization requirements and limits. More generally tests with direct exposure to the sun are useful to understand the behavior of components and new materials for solar applications in real working conditions. Insolation and ambient factors are uncontrollable but can be monitored to know the environmental situation of the solar exposure experiment. A parallel characterization of the photocells can be performed in laboratory under controllable and reproducible conditions. A methodology to execute solar exposure tests is proposed and practically applied on photovoltaic cells for a solar cogeneration system. The cells are measured with concentrated solar light obtained utilizing a large Fresnel lens mounted on a sun tracker. Outdoor measurements monitor the effects of the exposure of two multijunction photovoltaic cells to focused sunlight. The main result is the continuous acquisition of the - (voltage-current) curve for the cells in different conditions of solar concentration and temperature of exercise to assess their behavior. The research investigates electrical power extracted, efficiency, temperatures reached, and possible damages of the photovoltaic cell.
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  • 97
    Publication Date: 2015-10-19
    Description: TiO2 nanotube arrays (TNAs) are fabricated on quartz substrate by anodizing E-beam evaporated Ti films. E-beam evaporated Ti films are directly anodized at various anodizing voltages ranging from 20 to 45 V and their morphological, wetting, and photocatalytic properties are examined. The photocatalytic activity of the prepared TNAs is evaluated by the photodecomposition of methylene blue under UV illumination. The TNAs prepared at an anodizing voltage of 30 V have a high roughness of 30.1 nm and a low water contact angle of 7.5°, resulting in a high photocatalytic performance. The surface roughness of the TNAs is found to correlate inversely with the water contact angle. High roughness (i.e., high surface area), which leads to high hydrophilicity, is desirable for effective photocatalytic activity.
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  • 98
    Publication Date: 2015-12-22
    Description: There are various conducting polymer blends which are used as hole transporting layers (HTL) in organic photovoltaic devices (OPV). The electrical performance of these conducting polymer blends depends crucially on its surface compositions and morphology. In this paper, we studied poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate) or PEDOT:PSS as an example of the HTL conducting polymer blends used in OPV. We have investigated the effect of annealing PEDOT:PSS in different atmospheres such as vacuum, N2, and air at different temperatures. It was found that the component ratio of the polymer blend is changing with annealing temperature and atmosphere. PSS/PEDOT ratio was found to have clear influence on the electrical performance of the material. In practice, we found that annealing can be used as a method to control component ratio of the HTL conducting polymer blend to achieve better electrical performance in OPV devices. The component ratio changes of the polymer with annealing were understood by X-ray photoelectron spectroscopy (XPS). Annealing in N2 atmosphere at 220°C for 1 hour gave best electrical performance for the polymer and the PSS/PEDOT ratio at that condition was close to 1.1, while the initial ratio was 2.5. Optimizing HTL layer by simple conductivity measurement does not guarantee best performance in OPV since surface property changes during annealing might affect the deposition of successive active layers on top and thus final device. Thus we have optimized annealing condition of the HTL layer according to the OPV performance itself.
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  • 99
    Publication Date: 2015-12-22
    Description: A new simple moving voltage average (SMVA) technique with fixed step direct control incremental conductance method is introduced to reduce solar photovoltaic voltage () oscillation under nonuniform solar irradiation conditions. To evaluate and validate the performance of the proposed SMVA method in comparison with the conventional fixed step direct control incremental conductance method under extreme conditions, different scenarios were simulated. Simulation results show that in most cases SMVA gives better results with more stability as compared to traditional fixed step direct control INC with faster tracking system along with reduction in sustained oscillations and possesses fast steady state response and robustness. The steady state oscillations are almost eliminated because of extremely small around maximum power (MP), which verify that the proposed method is suitable for standalone PV system under extreme weather conditions not only in terms of bus voltage stability but also in overall system efficiency.
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  • 100
    Publication Date: 2016-06-08
    Description: Here we report a facile, efficient, and catalyst-free method to realize C-C cross-coupling of aryl chlorides and inert arenes under UV light irradiation. The aryl radical upon homolytic cleavage of C-Cl bond initiated the nucleophilic substitution reaction with inert arenes to give biaryl products. This mild reaction mode can also be applied to other synthetic reactions, such as the construction of C-N bonds and trifluoromethylated compounds.
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