Publikationsdatum:
2014-12-31
Beschreibung:
Combined synthesis experiments and first-principles calculations show that MgSiO 3 -perovskite with minor Al or Fe does not incorporate significant OH under lower mantle conditions. Perovskite, stishovite, and residual melt were synthesized from natural Bamble enstatite samples (Mg/(Fe + Mg) = 0.89 and 0.93; Al 2 O 3 〈 0.1 wt% with 35 and 2065 ppm wt H 2 O, respectively) in the laser-heated diamond anvil cell at 1600–2000 K and 25–65 GPa. Combined Fourier transform infrared (FTIR) spectroscopy, x-ray diffraction, and ex-situ transmission electron microscopy (TEM) analysis demonstrates little difference in the resulting perovskite as a function of initial water content. Four distinct OH vibrational stretching bands are evident upon cooling below 100 K (3576, 3378, 3274, and 3078 cm −1 ), suggesting 4 potential bonding sites for OH in perovskite with a maximum water content of 220 ppm wt H 2 O, and likely no more than 10 ppm wt H 2 O. Complementary, Fe-free, first-principles calculations predict multiple potential bonding sites for hydrogen in perovskite, each with significant solution enthalpy (0.2 eV/defect). We calculate that perovskite can dissolve less than 37 ppm wt H 2 O (400 ppm H/Si) at the top of the lower mantle, decreasing to 31 ppm wt H 2 O (340 ppm H/Si) at 125 GPa and 3000 K in the absence of a melt or fluid phase. We propose that these results resolve a long-standing debate of the perovskite melting curve and explain the order of magnitude increase in viscosity from upper to lower mantle.
Print ISSN:
0148-0227
Thema:
Geologie und Paläontologie
,
Physik
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