ALBERT

Beschreibung: A satellite-based global analysis of high-resolution (0.25o) ocean surface turbulent latent and sensible heat fluxes was developed by the Objectively Analyzed air-sea Fluxes (OAFlux) project. Resolving air-sea flux down to the order to 0.25o is critical for the description of the air-sea interaction on mesoscale scales. In this study, we evaluate the high-resolution product in depicting air-sea exchange in the eddy-rich Gulf Stream region. Two approaches were used for evaluation, one is point-to-point validation based on six moored buoys in the region, and another is basin-scale analysis in terms of wavenumber spectra and probability density functions (PDFs). An intercomparison is also carried out between OAFlux-0.25o, OAFlux-1o, and four atmospheric reanalyses. Results indicate that OAFlux-0.25 o is able to depict sharp oceanic fronts and has the best performance among the six participating products in comparison with buoy measurements. The mean OAFlux-0.25 o differences in latent and sensible heat flux with respect to the buoy are 7.6 Wm -2 (7.7%) with root-mean-square (RMS) difference of 44.9 Wm -2 , and 0.0 Wm -2 with RMS difference of 19.4 Wm -2 , respectively. Large differences are primarily due to mismatch in SST between gridded data and point measurements when strong spatial gradients are presented. The wavenumber spectra and decorrelation length scale analysis indicate OAFlux-0.25 o depicts eddy variability much better than OAFlux-1 o and the four reanalyses; however, its capability in detecting eddies with smaller scale still needs to be improved. Among the four reanalyses, CFSR stands out as the best in comparison with OAFlux-0.25°.

Beschreibung: Breaking waves and Langmuir circulation are two important turbulent processes in the wind-driven upper ocean. To investigate their roles in generating turbulence in the surface boundary layer of a coastal ocean, a Large Eddy Simulation (LES) model is used to simulate the turbulence measurements collected at the Marthad's Vineyard Coastal Observatoryd's Air-Sea Interaction Tower, during the Coupled Boundary Layers and Air-Sea Transfer (CBLAST) experiment in 2003. The model provides reasonable predictions for the vertical profiles of vertical velocity variance, turbulent kinetic energy (TKE), energy dissipation rates and heat flux. It shows breaking waves dominating turbulence generation near the ocean surface and turbulent large eddies characteristic of Langmuir circulation deeper in the water column. Diagnostic analysis of TKE budget in the model shows a dominant balance between turbulent transport and dissipation near the surface and a dominant balance between shear production and dissipation at deeper depths. Although the Stokes production is a significant term in the TKE budget balance near the surface, it is smaller than shear production. The turbulent transport is large in the near-surface zone and is still significant in the region affected by Langmuir circulation. These results are in agreement with a conclusion inferred from a recent analysis of the near-surface turbulence measurements at the CBLAST site.

Beschreibung: A Gulf of Mexico performance evaluation and comparison of coastal circulation and wave models was executed through harmonic analyses of tidal simulations, hindcasts of Hurricane Ike (2008) and Rita (2005), and a benchmarking study. Three unstructured coastal circulation models (ADCIRC, FVCOM, and SELFE) validated with similar skill on a new common Gulf scale mesh (ULLR) with identical frictional parameterization and forcing for the tidal validation and hurricane hindcasts. Coupled circulation and wave models, SWAN+ADCIRC and WWMII+SELFE, along with FVCOM loosely coupled with SWAN, also validated with similar skill. NOAA's official operational forecast storm surge model (SLOSH) was implemented on local and Gulf scale meshes with the same wind stress and pressure forcing used by the unstructured models for hindcasts of Ike and Rita. SLOSH's local meshes failed to capture regional processes such as Ike's forerunner and the results from the Gulf scale mesh further suggest shortcomings may be due to a combination of poor mesh resolution, missing internal physics such as tides and nonlinear advection, and SLOSH's internal frictional parameterization. In addition, these models were benchmarked to assess and compare execution speed and scalability for a prototypical operational simulation. It was apparent that a higher number of computational cores are needed for the unstructured models to meet similar operational implementation requirements to SLOSH, and that some of them could benefit from improved parallelization and faster execution speed.

Beschreibung: Pairs of moorings equipped with current profilers were deployed at each end of the Dardanelles Strait and remained in place for over 13 months. Current observations were able to resolve well the exchange flow and volume fluxes. Volume fluxes showed distinct temporal variability in upper and lower layers, especially evident on synoptic time scales. The synoptic flux variability in the upper layer was coherent with the local atmospheric forcing and the bottom pressure anomaly gradient, while the flux variations in the lower layer were related to the bottom pressure anomaly gradient. Estimated volume flux values were often two or more times larger than their respective annual means. Annual upper-layer flux means were 25.66·10 -3 and 36.68·10 -3 Sv, whereas the lower-layer averages were 14.02·10 -3 and 31.67·10 -3 Sv for the Marmara and Aegean sections, respectively. The fluxes also showed that there was a net low-salinity water outflow to the Aegean Sea, and that they varied weakly on longer time scales (monthly to seasonal). High-salinity water fluxes (≥ 39 psu) were used to calculate strait-averaged vertical eddy diffusivities which ranged between 10 -4 and 10 -2 m 2 s -1 . Additionally, microstructure observations were used to evaluate vertical eddy diffusivities. These estimates indicated that mixing in the strait varied spatially and temporarily, and it was dependent on complex strait geometry, exchange flow status, and partially on meteorological conditions. Large values of eddy diffusivities, with a depth-averaged mean of 1.3·10 -2 m 2 s -1 , and vigorous mixing were found in the Nara Pass, the narrowest section in the Dardanelles Strait.

Beschreibung: In this paper, simulated variability of the Atlantic Multidecadal Oscillation (AMO) and the Atlantic Meridional Overturning Circulation (AMOC) and their relationship have been investigated. For the first time, climate models of the Coupled Model Intercomparison Project phase 5 (CMIP5) provided to the Intergovernmental Panel on Climate Change Fifth Assessment Report (IPCC-AR5) in historical simulations have been used for this purpose. The models show the most energetic variability on the multidecadal timescale band both with respect to the AMO and AMOC, but with a large model spread in both amplitude and frequency. The relationship between the AMO and AMOC in most of the models resembles the delayed advective oscillation proposed for the AMOC on multidecadal timescales. A speed up (slow down) of the AMOC is in favor of generating a warm (cold) phase of the AMO by the anomalous northward (southward) heat transport in the upper ocean, which reversely leads to a weakening (strengthening) of the AMOC through changes in the meridional density gradient after a delayed time of ocean adjustment. This suggests that on multidecadal timescales the AMO and AMOC are related and interact with each other.

Beschreibung: Atmospheric boundary layer rolls and their impact on upper ocean circulation were investigated using a combination of two high-resolution data sources: (1) data from the Advanced Synthetic Aperture Radar (ASAR) onboard ENVISAT with a spatial sampling of approximately 500m×500m, and (2) continuous observations taken at the research platform FINO 1 with two-minutes temporal sampling at eight heights between 33 and 100m. The parallel analysis of instantaneous image data in combination with the FINO 1 time series enabled us to quantify both the spatial and temporal dynamics of mesoscale and submesoscale wind variations. The influence of these variations with different temporal and spatial scales on the hydrodynamics of the German Bight was addressed using outputs from a three-dimensional circulation model. It was demonstrated that while the coupling between wind and tidal forcing triggered substantial responses at mesoscales, the response of surface currents and sea surface temperature to the atmospheric boundary layer rolls appeared relatively weak. However, these ocean surface responses closely follow the surface footprint of the atmospheric boundary layer rolls, the signatures of which become more pronounced in the absence of strong tidal flows.

Beschreibung: State estimation techniques have been well established in open ocean systems; however they are less often used in coastal applications due to non-linearity. Using 4D-variational data assimilation in a triple one-way nested system, we investigate the processes that control coastal dynamics for a test case along the western coast of Oahu, Hawaii. All available observations are combined with the model dynamics for 13 months. Over this time, the residual error between the model and observations was improved by nearly 30% in the surface temperature and 34% in the along-shore ADCP currents. The barotropic and baroclinic tides are found dominate the local circulation; however, island and atmospheric interaction generates an island wake effect that is important to the sub-tidal dynamics of the region. The baroclinic tides exhibit well defined energy paths, and the initial condition corrections, despite altering the density waveguide, have little influence on the propagation of the baroclinic energy, which is controlled by the propagation of baroclinic tides generated outside of the domain. We find the larger-scale, advected dynamics control the local surface circulation through boundary condition adjustment, accounting for 45% of the total corrections made via data assimilation system. The initial conditions controls little of the evolution of this local, coastal flow and has a short persistence. The wind-stress control vector is important in the central region of the domain inducing flow toward the lee of the island. Our results reveal that coastal studies may not be initial value problems, rather they are forced problems that require a knowledge of the large-scale energy propagated into the region.

Beschreibung: The effects of solar radiation diurnal cycle on intraseasonal mixed layer variability in the tropical Indian Ocean during boreal wintertime Madden-Julian Oscillation (MJO) events are examined using the HYbrid Coordinate Ocean Model. Two parallel experiments, the main run and the experimental run, are performed for the period of 2005-2011 with daily atmospheric forcing except that an idealized hourly shortwave radiation diurnal cycle is included in the main run. The results show that the diurnal cycle of solar radiation generally warms the Indian Ocean sea surface temperature (SST) north of 10°S, particularly during the calm phase of the MJO when sea surface wind is weak, mixed layer is thin, and the SST diurnal cycle amplitude ( dSST ) is large. The diurnal cycle enhances the MJO-forced intraseasonal SST variability by about 20% in key regions like the Seychelles–Chagos Thermocline Ridge (SCTR; 55°-70°E, 12°-4°S) and the central equatorial Indian Ocean (CEIO; 65°-95°E, 3°S-3°N) primarily through nonlinear rectification. The model also well reproduced the upper-ocean variations monitored by the CINDY/DYNAMO field campaign between September-November 2011. During this period, dSST reaches 0.7°C in the CEIO region, and intraseasonal SST variability is significantly amplified. In the SCTR region where mean easterly winds are strong during this period, diurnal SST variation and its impact on intraseasonal ocean variability are much weaker. In both regions, the diurnal cycle also has large impact on the upward surface turbulent heat flux Q T and induces diurnal variation of Q T with a peak-to-peak difference of O (10 W m -2 ).

Beschreibung: The horizontal and vertical flux of particulate material in the nearshore of southern Lake Michigan (0 – 40 m) was estimated with the naturally occurring radionuclide 234 Th. Horizontal fluxes of 234 Th supplemented apparent vertical fluxes of 234 Th in the water column (based on local 234 Th/ 238 U disequilibria) by a factor of 7 to 14, reinforcing the importance of lateral transport in coastal environments. Calculated onshore transport of particulate material across the 40 m isobath was as high as 1.1 × 10 6 kg km -1 d -1 , and exceeds estimates of terrigenous (riverine and bluff erosion) loading. Estimates of onshore flux of organic carbon exceeded areal primary productivity by as much as ~ 300 %, and should be considered in nearshore carbon budgets. Bottom tethered sediment traps (placed 5 m above the bottom) measured sedimentation rates that were approximately 1 order of magnitude lower than 234 Th derived mass fluxes from the water column and ~ 2 orders of magnitude lower than 234 Th derived mass fluxes to the lakebed. We ascribe this difference to under-collecting by the sediment trap either because of trap hydrodynamics or flux occurring below the trap capture plane. Cross-shore fluxes showed a periodicity of ~ 4 days and correlated strongly with a topographic vorticity wave that is present throughout the year in southern Lake Michigan. The impact of this wave (as a driver of bidirectional cross-shore flux) on biogeochemical cycling and both nearshore and offshore food webs has not yet been explicitly considered.

Beschreibung: Time series (1990-2011) of sea ice thickness observed by moored sonars in the Transpolar Drift in Fram Strait are examined. Contrasting the post 2007 years against the 1990s, three remarkable changes in the monthly ice thickness distributions are highlighted: 1) The thickness of old level ice (modal thickness) is reduced by 32 percent, 2) the old ice modal peak width is reduced by 25 percent, and 3) the fraction of (ridged) ice thicker than 5 m is reduced by 50 percent. The combined effect on the mean ice thickness is a reduction from an annual average of 3.0 m during the 1990s to 2.2 m during 2008-2011. Most of the thinning took place after 2005-2006. While the old ice modal thickness and peak width show signs of recovery after 2008, the decreasing trend in fraction of ridged ice and mean ice thickness persists until the end of the record in 2011. The ice observed in Fram Strait carries an integrated signal of Arctic change due to the advection of ice from many sites in the Arctic. Based on concurrence in timing, we conclude that much of the thinning quantified here is reflecting recent change in the age composition of the Arctic ice cover towards younger ice. The old level ice remains thin, and as such the ice cover remains preconditioned for new summers of very low sea ice extent.

Beschreibung: Hydrographic observations, ocean state estimates, and ocean objective analyses are combined to investigate the decadal variations of the North Equatorial Current (NEC) in the Pacific at 137°E during the last three decades (1975-2005). Observations show that the decadal NEC transport has three maxima around 1980/1981, 1994/1995, and 2004/2005 and two minima around 1989/1990 and 1999/2000, respectively. Associated with these maxima/minima, the sea surface height (SSH) falls/rises and the subsurface isopycnals shoal/deepen in the southern part of NEC, resulting in westward/eastward zonal velocity anomalies. Results from the ocean state estimates and ocean objective analyses show good agreement with observations. Further analysis indicates that the observed zonal velocity anomalies at 137°E are part of the cyclonic/anticyclonic gyre anomalies formed in the tropical northwestern Pacific east of the Philippines, coinciding with the tropical gyre. Results from a 1½ layer reduced gravity model suggest that these oceanic variations are mainly controlled by the decadal wind forcing in the tropical western Pacific and can be attributed to both local Ekman dynamics and baroclinic Rossby wave propagation.

Beschreibung: Based on observations and ocean reanalysis, this study analyzes the variability of salinity and its related ocean dynamics in the equatorial Indian Ocean (IO). The results show significant interannual variability of salinity associated with the Indian Ocean Dipole (IOD) mode in the boreal fall. During the positive phase of IOD (pIOD), when anomalous easterly winds prevail, westward advection along the equator strengthens in summer, while the eastward advection associated with the Yoshida-Wyrtki Jet weakens in fall. Analysis of salinity budget indicates that salinity anomalies are mainly due to advection, of which zonal component is dominant. As zonal current anomalies are symmetric with respect to the equator, the equatorward large northern IO zonal salinity gradient is more important than the current anomalies in determining the asymmetric distribution of low-salinity advection. During the mature phase of pIOD, low-salinity water is advected westward, which in turn shoals the surface mixed layer, thereby providing a favorable condition for warmer sea-surface temperature in the western equatorial IO. During the decay phase of pIOD, low-salinity water is advected across the equator to the southwestern IO. When pIOD concurs along with El Niño, the strengthened off-equatorial anticyclonic circulations, which is associated with El Niño, advect low-salinity water poleward after the decay phase.

Beschreibung: Homogenous liquid precursor for ZrC – SiC was prepared by blending of Zr ( OC 4 H 9 ) 4 and Poly[(methylsilylene)acetylene]. This precursor could be cured at 250°C and converted into binary ZrC – SiC composite ceramics upon heat treatment at 1700°C. The pyrolysis mechanism and optimal molar ratio of the precursor were investigated by XRD. The morphology and elements analyses were conducted by SEM and corresponding energy-dispersive spectrometer. The evolution of carbon during ceramization was studied by Raman spectroscopy. The results showed that the precursor samples heat treated at 900°C consisted of t- ZrO 2 (main phase) and m- ZrO 2 (minor phase). The higher temperature induced phase transformation and t- ZrO 2 converted into m- ZrO 2 . Further heating led to the formation of ZrC and SiC due to the carbothermal reduction, and the ceramic sample changed from compact to porous due to the generation of carbon oxides. With the increasing molar ratios of C / Zr , the residual oxides in 1700°C ceramic samples converted into ZrC and almost pure ZrC – SiC composite ceramics could be obtained in ZS-3 sample. The Zr , Si , and C elements were well distributed in the obtained ceramics powders and particles with a distribution of 100 ~ 300 nm consisted of well-crystallized ZrC and SiC phases.

Beschreibung: Ce -doped BaTiO 3 -based ceramics were prepared and studied to satisfy ultra-broad temperature stability (from −55°C to 300°C, capacitance variation rate based on C 20°C is within ±15%). The sample with 0.6 mol% CeO 2 succeeds to achieve this performance with a remarkably high ceiling temperature of 300°C. Meanwhile, the sample has good dielectric and electrical properties at room temperature (ε r  = 1667, tanδ = 1.478%, ρ V  = 5.9 × 10 12  Ω·cm). Ce ion can substitute for Ti ion as Ce 4+ or Ba ion as Ce 3+ . The substitution decreases the spontaneous polarization of BaTiO 3 , and then weakens the ferroelectricity of BaTiO 3 . As a result, the temperature stability of samples is improved obviously. Besides, CeO 2 addition promotes the formation of exaggerated grains, which are consisting of Ba 6 Ti 17 O 40 .

Beschreibung: This study aims to optimize quantitative X-ray diffraction (XRD) mineralogical analysis of the minority phases in clinker. The proposed method consists of applying Rietveld quantitative refinement to the XRD patterns for both clinker and the insoluble residue remaining after it is attacked with methanol and salicylic acid (Takashima method). The method was tested with industrial clinker and the same material after modifying its mineralogy by refiring at 1500°C followed by slow cooling. The findings showed that the C 4 AF / C 3 A ratios for quickly and gradually cooled clinker were much higher when the clinker diffractograms were refined with the Rietveld procedure than when the proposed method was used. The proportion of C 3 A found with the proposed method was ≈2.8-fold higher than when Rietveld only was applied to the diffractograms for clinkers. Taken together, the refinement data for the two materials (clinker and Takashima residua) revealed that Rietveld quantitative XRD applied to clinker underestimates the low C 3 A content. These findings are supported by postsulfate attack durability studies conducted on cements prepared with the two clinkers.

Beschreibung: The effect of increasing poling fields on the properties of (1− x )BZT– x BCT compositions across the morphotropic phase boundary (MPB) is studied using large signal polarization and strain, small signal permittivity and piezoelectric coefficient, and XRD measurements. Successive poling causes charge carrier migration inducing an internal bias field, which becomes large with respect to the coercive field resulting in biased ferroelectric and ferroelastic switching. Improvements in piezoelectric coefficient of 9% are significantly smaller in the tetragonal 60BCT composition compared with the improvement of approximately 50% in the rhombohedral 40BCT and MPB 50BCT compositions. While the properties continue to change with increased poling fields, the remnant ferroelastic domain texture parallel to the field direction, as observed from XRD, stays approximately constant. The improvement in overall domain alignment leading to largely enhanced intrinsic piezoelectricity originates from the alignment of 180° domains and possibly non-180° domains in grains with orientations inclined to the electric field. As a result, poling is most effective in BZT–BCT materials that have low coercive fields, show low distortions and possess more polarization orientations, such as compositions in the rhombohedral phase field or near the MPB.

Beschreibung: The defect chemistry-modulated dielectric properties of dense yttria-doped zirconia ceramics prepared by conventional sintering (at 1350°C–1500°C) and electric field-assisted flash sintering (55 V/cm at 900°C) were studied by impedance spectroscopy. While the bulk dielectric properties from both sets of samples showed only small and insignificant changes in conductivity and permittivity, respectively, a huge increase of these properties was measured for the grain boundaries in the flash sintered specimens. A close analysis of these results suggests that flash sintering reduced grain-boundary thickness (by about 30%), while increasing the concentration of oxygen vacancies near these interfaces (by about 49%). The underlying mechanism proposed is electric field-assisted generation and accommodation of defects in the space-charge layers adjacent to the grain surface. The changes in measured permittivity are attributed to the boundary thickness effect on capacitance, while conductivity involved variations in its defect density-dependent intrinsic value, accounting for changes also observed in grain-boundary relaxation frequencies. Therefore, in terms of modifications to the specific dielectric properties of these materials, the overall consequence of flash sintering was to considerably lower the semi-blocking character of the grain boundaries.

Beschreibung: This article presents a detailed study on the nanoscaled interface between microelongated gold particles (GP) and biphase leucite/feldspar glass-ceramic matrix. The glass-ceramic composite with a nonuniform GP distribution was processed through hot-pressing under vacuum using a commercial dental ceramic furnace for glass-ceramic dental crown manufacturing. Heat treatments at 900°C, 1100°C, and 1300°C were conducted, and microstructural features along the interface were used to verify the chemical reactions between GP and glass-ceramic matrix. It was observed that the amorphous glass-ceramic matrix had nanoscaled biphase structures, and the distributed nanoscaled amorphous leucite phase was attracted to GP during hot-pressing, and was more reactive with GP than the feldspar phase. The thickness of the interfacial phase formed through chemical reactions between GP and glass-ceramic matrix is around 30 nm. The chemically bonded interface has contributed significantly toward the substantial improvements in both strength and toughness of the GP-reinforced glass-ceramic matrix composite. Characterization techniques, including X-ray diffraction and field-emission scanning electron Microscopy, incorporating X-ray microanalysis using energy dispersive spectrometry, have been employed in this study.

Beschreibung: Recent investigations have revealed the great potential of Raman spectroscopy for the characterization of clinker minerals and commercial Portland cements. The usefulness of this technique for the identification of anhydrous, hydrated, and carbonated phases in cement-based materials has been demonstrated. In the present work, the application of micro-Raman spectroscopy for the characterization of the main clinker phases of calcium aluminate cements and calcium sulfoaluminate cement is explored. The main stable hydrated phases as well as several important carbonated phases are investigated. Raman measurements on the following phases are reported: (i) pure, unhydrated phases: CA, C 12 A 7 , CA 2 , C 2 AS, cubic- C 3 A , C 4 AF, and C 4 A 3 ; (ii) hydrated phases: ettringite, monosulfoaluminate, and hydrogarnet ( C 3 AH 6 ); (iii) carboaluminate phases: hemicarboaluminate and monocarboaluminate. The present results, which are discussed in terms of the internal vibrational modes of the aluminate, carbonate, and sulfate molecular groups as well as stretching O–H vibrations, show the ability of Raman spectroscopy to identify the main hydrated and unhydrated phases in the aluminate and sulfoaluminate cements. The Raman spectra obtained in this work provide an extended database to the existing data published in the literature.

Beschreibung: Acmite ( NaFeSi 2 O 6 ) films were formed on steel coupons via solvothermal reaction of silica, sodium hydroxide, and 1, 4-butanediol in an autoclave under autogenous pressure. Systematic variation in processing variables led to homogenous coatings comprised of pinacoidal acmite grains with an average grain size of ~33 μm. The coatings were produced on the steel coupons from reactant conditions of 0.635 m SiO 2 , 2.546 m NaOH , and 3.087 m 1,4-butanediol for 72 h at 240°C.

Beschreibung: Submarine canyons that cut into the continental shelf are regions of enhanced upwelling. The depth of upwelling and flux through the canyons determines their role in exchange between the shelf and the open ocean. Scaling analyses that relate these quantities to the strength of the flow, stratification, Coriolis parameter and topographic shape parameters allow their estimation in the absence of a full numerical simulation or a detailed field study. Here we add the effect of the continental shelf slope to the scaling of the depth of upwelling, upwelling flux, and deep water stretching. The scaling is then tested using a three-dimensional primitive equation model over 18 distinct geometries. The impact of the continental shelf is significant for real canyons with changes in the depth of upwelling of up to 11% and of the flux of upwelling of up to 70%. The numerical simulations clearly show three types of canyon upwelling, a symmetric time-dependent flux, the dominant advection-driven flux and a new flux that appears to be related to internal waves. They also suggest that the canyon width is more important than the upstream canyon shape in determining the strength of the flow across the canyon.

Beschreibung: A 50:50 vol% MgO – Y 2 O 3 nanocomposite with ~150 nm grain size was prepared in an attempt to make 3–5 μm infrared-transmitting windows with increased durability and thermal shock resistance. Flexure strength of the composite at 21°C is 679 MPa for 0.88 cm 2 under load. Hardness is consistent with that of the constituents with similar grain size. For 3-mm-thick material at 4.85 μm, the total scatter loss is 1.5%, forward scatter is 0.2%, and absorptance is 1.8%. Optical scatter below 2 μm is 100%. Variable intensity OH absorption (~6% absorptance) is observed near 3 μm. The refractive index is ~0.4% below the volume-fraction-weighted average of those of the constituents. Thermal expansion is equal to the volume-fraction-weighted average of expansion of the constituents. Specific heat capacity is equal to the mass-fraction-weighted average of heat capacities of the constituents. Thermal conductivity lies between those of the constituents up to 1200 K. Elastic constants lie between those of the constituents. The Hasselman mild thermal shock resistance parameter for the composite is twice as great as that of common 3–5 μm window materials, but half as great as that of c -plane sapphire.

Beschreibung: In this work, novel Y 2 Si 2 O 7 / ZrO 2 composites were developed for structural and coating applications by taking advantage of their unique properties, such as good damage tolerance, tunable mechanical properties, and superior wear resistance. The γ- Y 2 Si 2 O 7 / ZrO 2 composites showed improved mechanical properties compared to the γ- Y 2 Si 2 O 7 matrix material, that is, the Young's modulus was enhanced from 155 to 188 GPa (121%) and the flexural strength from 135 to 254 MPa (181%); when the amount of ZrO 2 was increased from 0 to 50 vol%, the γ- Y 2 Si 2 O 7 / ZrO 2 composites also presented relatively high facture toughness (〉1.7 MPa·m 1/2 ), but this exhibited an inverse relationship with the ZrO 2 content. The composition–mechanical property–tribology relationships of the Y 2 Si 2 O 7 / ZrO 2 composites were elucidated. The wear resistance of the composites is not only influenced by the applied load, hardness, strength, toughness, and rigidity but also effectively depends on micromechanical stability properties of the microstructures. The easy growth of subcritical microcracks in Y 2 Si 2 O 7 grains and at grain boundaries significantly contributes to the macroscopic fracture toughness, but promotes the pull-out of individual grains, thus resulting in a lack of correlation between the wear rate and the macroscopic fracture toughness of the composites.

Beschreibung: The as-prepared BiFeO 3 ceramic shows a piezoelectric d 33 coefficient of −14 pC/N, that is, an obvious ferroelectric self-poling phenomenon. The temperature gradient between the two surfaces of BiFeO 3 ceramic was intentionally enlarged when BiFeO 3 was prepared with a rapid liquid sintering method. This temperature gradient and the corresponding thermal strain can introduce defect dipoles through separating bismuth vacancies from oxygen vacancies. A mass of these dipoles introduce a macroscopic internal electric field ( E in ) which downward poles BiFeO 3 ceramic during its cooling down process. As expected, an E in of 〉10 kV/cm is confirmed by the asymmetrical polarization/strain versus electric field curves.

Beschreibung: The effect of Ba content on the stress sensitivity of the antiferroelectric to ferroelectric phase transition in ( Pb 0.94− x La 0.04 Ba x )[( Zr 0.60 Sn 0.40 ) 0.84 Ti 0.16 ] O 3 ceramics is investigated through monitoring electric field-induced polarization and longitudinal strain under compressive prestresses. It is found that incorporation of Ba significantly suppresses the stress sensitivity of the phase transition, as manifested by slight decreases under prestresses up to 100 MPa in the maximum polarization ( P m ) and longitudinal strain ( x m ). The energy storage density is even increased under the mechanical confinement in compositions x  = 0.02 and 0.04. X-ray diffraction, transmission electron microscopy, and dielectric measurements indicate that the suppressed stress sensitivity is associated with the disruption of micrometersized antiferroelectric domains into nanodomains and the transition from antiferroelectric to relaxor behavior.

Beschreibung: Powders and nanoceramics composed of composites of CoFe 2 O 4 , CoFe 2 , and a small amount of FeO were prepared by heating CoFe 2 O 4 powder in reducing atmosphere and by sintering the product of reducing reaction at 350°C via spark plasma sintering technology. In the powders, increase in the molar ratios of CoFe 2 : CoFe 2 O 4 and a great change in magnetic parameters were observed with the change in heating temperature from 300°C to 400°C, and the dominance of dipole interaction over exchange coupling in the interparticle interactions was confirmed by the steps in magnetic hysteresis loops and the negative Henkel plots. However, in the nanoceramics, significant enhancement in exchange coupling was found when the sintering temperature was raised to 500°C and 650°C, which was confirmed by both the positivity of Henkel plot and the single-phase style of the magnetic hysteresis loop.

Beschreibung: Gas adsorption porosity measurement of geopolymers (GPs) is required for quantitative understanding of such mesoporous structures, but the complex nature of the GP system makes analysis difficult. Previous results in the literature are often ambiguous or contradictory. A systematic investigation of metakaolin GP gas adsorption results was conducted to optimize the use of this measurement technique and verify that results match known theory about GP structure. It was found that GP undergoes structural change upon degassing at 100°C or higher. If and only if this change is prevented by degassing at a lower temperature could it be shown that specific surface area and total gas adsorption increases with both increasing curing temperature and decreased Si : Al ratio. This observation is consistent with previous suggestions of increased zeolitic character under these conditions, where previous gas adsorption investigations had not observed this expected relationship. Hydrogen physisorption is proposed as a substitute technique for micropore isotherms in GPs due to the difficulty of removing trace gasses from GPs and the measurement effect of such gasses at high vacuum. A hydrogen physisorption isotherm qualitatively resembled an equivalent nitrogen micropore isotherm.

Beschreibung: In this work, the role of europium doping of glasses formulated in the ternary system ZnO – CdO – TeO 2 is described. The Eu -doped oxide glasses were prepared by the conventional melt-quenching method and by using three different compositions. Structural studies reveal that there exists a good affinity between Cd and some rare earth (RE) ions to form the crystalline phase. The X-ray diffraction (XRD) diagrams display that the structure of these glasses is amorphous and with the increase in CdO content and the compatibility of Eu 3+ , there is a tendency to form nanocrystals of CdTe 2 O 5 . The scanning electron microscopic (SEM) observation of their microstructure confirms the presence of phase separation. Differential thermal analysis (DTA) of these glasses showed small exothermic peaks noted around 450°C for the V2 glass and 480°C for V1 and V3 glasses, which could be attributed to the formation of these crystals. The infrared spectra showed a main absorption band around 800–600 cm −1 corresponding to the Te – O stretching mode in TeO 4 and TeO 3 groups. By optical absorption (OA), the band gap ( E g ) for each glass was determined; these values were 3.27, 3.14, and 3.3 eV for the V1–V3 glasses, respectively. Furthermore, the presence of Eu 3+ was detected in the 370–470 nm short-range wavelengths. The photoluminescence (PL) experiments of the glasses showed light emission due to the following transitions: 5D0 → 7F1, 5D0 → 7F2, 5D0 → 7F3, and 5D0 → 7F4.

Beschreibung: The conductivity of nominal CaWO 4 , CaW 0.99 Ta 0.01 O 4–δ , 0.7( CaWO 4 )–0.3( La 0.99 Ca 0.01 NbO 4–δ ), and Ca 0.9 La 0.1 WO 4+δ has been studied by means of a.c. impedance measurements. Proton conductivity was observed for CaW 0.99 Ta 0.01 O 4–δ , which displayed exothermic hydration with enthalpy and entropy of –82 kJ/mol and –120 J/molK, respectively. The proton mobility in CaW 0.99 Ta 0.01 O 4–δ was low, with enthalpy and preexponential factor of mobility of 82 kJ/mol and 0.7 cm 2 K/Vs. The high enthalpy of mobility is interpreted to reflect association between the acceptor dopant and protonic defects, whereas the low preexponential factor of mobility may reflect a lower proton concentration than assumed. Rietveld refinement indicated low solubilities of La on Ca -site and Ta on W-site. Proton conductivity was also observed in undoped CaWO 4 , however, not in Ca 0.9 La 0.1 WO 4+δ . The conductivity of 0.7( CaWO 4 )–0.3( La 0.99 Ca 0.01 NbO 4–δ ) behaved much like that of undoped LaNbO 4 , likely due to a very low acceptor dopant concentration.

Beschreibung: A new lead-free BNT-based piezoelectric ceramics of (1 −  x ) Bi 0.5 Na 0.5 TiO 3 – x Bi ( Al 0.5 Ga 0.5 ) O 3 ( x  = 0, 0.02, 0.03, 0.04, and 0.05) were synthesized using a conventional ceramic fabrication method. Their structures and electrical properties were investigated. All the samples show a typical ferroelectric P ( E ) loops and S ( E ) curves at room temperature. The optimal properties are obtained at the composition of the x  = 0.03. The substitution of Bi ( Al 0.5 Ga 0.5 ) O 3 enhances piezoelectric constant and increases Curie temperature from 58 pC/N and 310°C of pure BNT to 93 pC/N and 325°C of the x  = 0.03. The temperature-dependent P ( E ) loops and S ( E ) curves of 0.97BNT–0.03BAG indicate that phase transition from ferroelectric to antiferroelectric takes place over a very wide temperature region from 80°C to 180°C. The results show that the introduction of BAG improves the electrical properties of BNT.

Beschreibung: The Northwestern Mediterranean Sea (NWMS) is one of the most productive areas of the Mediterranean Sea. The NWMS pelagic planktonic ecosystem is strongly influenced by hydrodynamics, in particular winter deep convection. Here we investigate the response of this ecosystem and associated carbon cycle to oceanic and atmospheric winter conditions interannual variability. For that we developed a tridimensional coupled physical-biogeochemical model, ran annual simulations forced by XXth climate conditions and performed statistical and budget analysis. Our coupled model reproduces correctly the seasonal evolution of the NWMS pelagic planktonic ecosystem. It however overestimates the contribution of nanophytoplankton to the total phytoplanktonic biomass and GPP, underestimates the bacteria biomass and represents the spring bloom with one month delay. Our results confirm that the control of phytoplanktonic development and bacteria growth by the phosphorus availability is a marked specificity of the NWMS, that is temporally reduced by deep convection. They confirm the relevance of the Behrenfeld [2010] hypothesis in explaining the bloom dynamics. The variability of the winter atmospheric conditions induces differences of vertical mixing and water temperature that propagate into the whole NWMS ecosystem through a chain of relationships. The high frequency filtering associated with averaging diagnostics explains that this variability seems weak at the NWMS scale. However for most of the variables and processes, differences induced by the winter atmospheric variability are significant at the annual scale. Net metabolism and deep carbon export are systematically positive and show larger variabilities related respectively to the water temperature and convection intensity.

Beschreibung: Frontal meanderings are generally difficult to predict. In this study, we demonstrate through an exercise with the Iceland-Faeroe Front (IFF) that satisfactory predictions may be achieved with the aid of hydrodynamic instability analysis. As discovered earlier on, underlying the IFF meandering is a convective instability in the western boundary region followed by an absolute instability in the interior; correspondingly the disturbance growth reveals a switch of pattern from spatial amplification to temporal amplification. To successfully forecast the meandering, the two instability processes must be faithfully reproduced. This sets stringent constraints for the tunable model parameters, e.g., boundary relaxation, temporal relaxation, eddy diffusivity, etc. By analyzing the instability dispersion properties, these parameters can be rather accurately set, and their respective ranges of sensitivity estimated. It is shown that too much relaxation inhibits the front from varying; on the other hand, too little relaxation may have the model completely skip the spatial growth phase, leading to a meandering way more upstream along the front. Generally speaking, dissipation/diffusion tends to stabilize the simulation, but unrealistically large dissipation/diffusion could trigger a spurious absolute instability, and hence a premature meandering intrusion. The belief that taking in more data will improve the forecast does not need to be true; it depends on whether the model setup admits the two instabilities. This study may help relieve modelers from the laborious and tedious work of parameter tuning; it also provides us criteria to distinguish a physically relevant forecast from numerical artifacts

Beschreibung: In this paper we assess the risk of future coastal flooding in the Severn Estuary, examining the contribution from low probability extreme sea level rise scenarios resulting from the possibility of increased rates of ice sheet mass loss in the coming century. A simple asymmetric probability distribution is constructed to include sea level rise scenarios of up to 1.9 m by 2100, based on recent assessments of future sea level rise in the UK. A regular sampling procedure, sampling every 1 mm, is used to increase the boundary water levels associated with a current 1:200 year event to force a two-dimensional hydrodynamic model of coastal inundation to examine the influence of sea level rise on inundation of the Somerset Levels region. From the resulting ensemble of predictions an estimation of risk (conditioned upon the hazard and the probability of occurrence) by 2100 is established. The results indicate that although the likelihood of extreme sea level rise due to rapid ice sheet mass loss is low, the resulting hazard can be large, resulting in a significant (29.7%) increase to the projected risk. These findings clearly demonstrate that uncertainty in future sea level rise, mostly associated with the rate of ice sheet mass loss, is a vital component of coastal flood risk, and therefore, needs to be accounted for by decision makers when considering mitigation policies related to coastal flooding.

Beschreibung: The in-situ data in the Deepwater Navigation Channel (DNC), Yangtze River Estuary (YRE), China, in the dry season 2009, shows spring tides associated with greater maximum velocities, more mixing, less stratification, and diffused fluid mud; whereas neap tides are associated with smaller maximum velocities, greater stratification, inhibited mixing, and stratified fluid muds. The balance of salt flux indicates the seaward salt transport is dominated by fluvial flows, and the landward salt transport is generated by compensation flows during spring tides, but shear effects during neap tidal cycles. The balance of suspended sediment flux illustrates the offshore sediment transport is dominated by fluvial flows as well, but the onshore transport is induced by tidal-pumping effects on spring tides, and shear effects on neaps. The suspended sediment transport is strongly affected by the salinity distribution and salinity-gradient-induced stratification in the DNC. The spring-neap asymmetry is generated by the estuarine gravitational circulation during low-flow conditions; while the flood-ebb asymmetric stratification within a tidal cycle is due to the semidiurnal-tidally movement of the salt front.

Beschreibung: In recent years the latitudinal position of the Subtropical Front (STF) has emerged as a key parameter in the global climate. A poleward positioned front is thought to allow a greater salt flux from the Indian to the Atlantic Ocean and so drive a stronger Atlantic Meridional Overturning Circulation. Here, the common view that the STF aligns with the zero windstress curl (WSC) is challenged. Based on the STF climatologies of Orsi [1995], Belkin and Gordon [1996], and Graham and De Boer [submitted], and on satellite scatterometry winds, we find that the zero WSC contour lies on average ~10º, ~8º, and ~5º poleward of the front for the three climatologies, respectively. The circulation in the region between the Subtropical gyres and the zero WSC contour is not forced by the WSC but rather by the strong bottom pressure torque that is a result of the interaction of the Antarctic Circumpolar Current with the ocean floor topography. The actual control of the position of the STF is crucially dependent on whether the front is regarded as simply a surface water mass boundary or a dynamical front. For the Agulhas Leakage problem the southern boundary of the so-called Super Gyre may be the most relevant property but this cannot easily be identified in observations.

Beschreibung: The M 2 tidal circulation in Algeciras Bay (Strait of Gibraltar) is analyzed using a 3-D, nonlinear, baroclinic, hydrodynamic model, in conjunction with observed data series. Results show the influence of the density-stratification on the vertical structure of the M 2 currents in Algeciras Bay, although its tidal dynamics shows major differences with respect to the Strait of Gibraltar. Whereas the M 2 currents in the Strait present mainly barotropic behaviour, the baroclinic effects prevail in Algeciras Bay. A notable finding is the presence of a tidal M 2 counter-current system between the upper Atlantic and the lower Mediterranean water layers within the Bay, with amplitudes of up to 25 cm s -1 . The interface between the two layers oscillates in anti-phase relation with respect to the free-surface elevation, with amplitudes of almost 20 m. The presence of the submarine Algeciras Canyon was found to be determinant in the three-dimensional structure of tidal currents within the Bay, strengthening the baroclinic tidal regime of currents. This situation has quantitative consequences for the flow exchange processes between Algeciras Bay and the outer Strait, with rates 20 times higher than those obtained when considering only the barotropic behaviour, as well as inflow/outflow lateral recirculation volumes during half a tidal cycle that account for more than 20% of the net accumulated volume. This flow exchange system was found to be affected by the nonlinear interaction processes between the first baroclinic period of resonance of Algeciras Bay and the M 2 tide.

Beschreibung: Impacts of submesoscale processes on transport are investigated numerically in an energetic mesoscale flow with an ocean model run at two horizontal resolutions, 1 km and 5 km. The focus is the northwestern Gulf of Mexico, where the Loop Current eddies are surrounded by smaller vortices. By increasing the horizontal resolution, the number and strength of submesoscale eddies and vorticity filaments within the mixed layer increase dramatically, and with them the vertical velocities. Inside the coherent eddies and at their peripheries increased vertical velocities for increasing resolution are associated to near inertial motions and they are not limited to the mixed layer, but are found at all depths. Horizontal velocities, on the contrary, are similar. Lagrangian isobaric tracers are deployed close to the surface and at 100 m, and three dimensional, neutrally buoyant particles are released close to the surface, at the base of the mixed layer and at 100 m. The modeled horizontal dispersion curves for each deployment depth are independent of the kind of particles and of horizontal resolution. Close to the ocean surface, however, convergence zones, generated by submesoscale ageostrophic motions and resolved at 1 km resolution, influence the details of the tracer distributions. Vertical dispersion increases by several folds for increasing resolution at all depths explored, with the largest differences found close to the surface. Therefore submesoscales processes play a fundamental role in driving vertical transport in eddy dominated flows, both within and below the mixed layer, for times comparable to the Eulerian time scale.

Beschreibung: The 2011 Tohoku tsunami devastated the northeastern Japan coasts and caused localized damage to coastal infrastructure across the Pacific. The tsunami resulted in strong currents around the Hawaiian Islands that led to closure of harbor and marinas for up to 38 hours after its arrival. We utilize a non-hydrostatic model to reconstruct the tsunami event from the seismic source for elucidation of the physical processes and inference of coastal hazards. A number of tide gauges, bottom pressure sensors, and ADCPs provided point measurements for validation and assessment of the model results in Hawaii. Spectral analysis of the computed surface elevation and current reveals complex flow patterns due to multi-scale resonance. Standing waves with 33 to 75 min period develop along the island chains, while oscillations of 27 min or shorter are primarily confined to an island or an island group with interconnected shelves. Standing edge waves with periods 16 min or shorter, which are able to form nodes on the reefs and inside harbors, are the main driving force of the observed coastal currents. Resonance and constructive interference of the oscillation modes provide an explanation of the impacts observed in Hawaii with implications for emergency management in Pacific island communities.

Beschreibung: This study characterizes the seasonal cycle of the Catalan inner-shelf circulation using observations and complementary numerical results. The relation between seasonal circulation and forcing mechanisms is explored through the depth-averaged momentum balance, for the period between May 2010 and April 2011 when velocity observations were partially available. The monthly-mean along-shelf flow is mainly controlled by the along-shelf pressure gradient and by surface and bottom stresses. During summer, fall and winter, the along-shelf momentum balance is dominated by the barotropic pressure gradient and local winds. During spring, both wind stress and pressure gradient act in the same direction and are compensated by bottom stress. In the cross-shelf direction the dominant forces are in geostrophic balance, consistent with dynamic altimetry data.

Beschreibung: The Southern Ocean Subtropical Front (STF) is thought to play a key role in the global climate system. Theory suggests that the latitude of the STF regulates the volume of saline Agulhas Leakage into the Atlantic Ocean from the Indian. Here we use satellite sea surface temperature (SST) and height (SSH) data to study the physical characteristics of the STF water mass boundary. We find that the strong currents in this region do not align with the surface water mass boundary. Therefore we provide a new climatology for these currents which we define as the Dynamical STF (DSTF). The DSTF is the eastward extension of the western boundary current in each basin and marks the southern boundary of the subtropical gyre circulations. It is a deep water mass boundary. At the centre of each basin it merges with the Sub-Antarctic Front. The DSTF is characterised by strong SST and SSH gradients, and has no seasonal cycle. On the eastern side of basins the STF surface water mass boundary coincides with a separate region of enhanced temperature gradients which we call the Subtropical Frontal Zone (STFZ). The STFZ is comprised of multiple SST fronts and has a large seasonal cycle. There are no strong SSH gradients in the STFZ. Separating the DSTF and STFZ is a band of weak SST gradients. Given the clear separation of these features as well as stark contrast in characteristics and seasonal cycles it is counterproductive and misleading to refer to them both as the STF.

Beschreibung: A time-dependent, 1D coupled ice-ocean model is used to quantify the impact of ocean stratification on the Arctic ice cover. The model results show that the ice growth during winter equals the ice melt in summer for areas with a well-developed cold halocline layer (CHL), provided that the initial ice thickness is around 3 m, while thinner initial ice thickness results in net growth. Areas with weak salt stratification can have a negative annual thickness change irrespective of the initial ice thickness and are thus dependent on ice import in order to remain ice-covered. The model results also show that ocean stratification is mostly important for ice-thickness development during the growing season. Areas with weak stratification have an ocean heat flux up to 8 Wm -2 reaching the ice during the growing season, while areas with a CHL have an average of about 0.7 Wm -2 . In the extreme area north of Svalbard, the ocean heat fluxes are typically around 25 Wm -2 but can be up to 400 Wm -2 during the initial adjustment, when the warm Atlantic water has direct contact with the ice. A general outcome of the study is that, depending on ocean stratification, the ice cover of Arctic Ocean can be divided into one part with net ice growth (the major part) and another part with net ice melt (mainly in the Nansen Basin).

Beschreibung: : A three-dimensional wave-current-sediment coupled numerical model with wetting and drying process is developed to understand hydrodynamics and sediment transport dynamics in the Deepwater Navigation Channel (DNC), the North Passage of the Yangtze River Estuary (YRE), China. The model results are in good agreement with observed data, and statistics show good model skill scores and correlation coefficients. The model well reproduces the spring-neap variation between a well-mixed estuary and a highly-stratified estuary. Model results indicate that the estuarine gravitational circulation plays the most important role in the estuarine turbidity maximum (ETM) formation in the DNC. The upstream non-local sediment intrusion through the spill-over-mechanism is a major source of sediment trapping in the North Passage after the morphological changes. Numerical studies are conducted to show scenarios in the YRE under the effects of different forcings (river-discharges, waves, and winds). Between these study cases, surface-wave-breaking relieves the sediment trapping and bottom-wave-current-interaction aggravates the bed erosion and elevates the SSC in the ETM; the former and the latter have the least and largest influence on the suspended sediment transport in the DNC. The wind effects have a greater influence on sediment trapping than the river-discharges, and the steady-northwesterly-wind condition favours the siltation in the DNC most. The significance of density-driven turbidity current is also assessed, which can enhance the saline-water intrusion and suppress the turbulent mixing in the bottom boundary layer.

Beschreibung: The Arctic Ocean is changing rapidly but there are no longterm time series observations on the state of the phytoplankton community that could allow a link to be made from physical/chemical pressures to the impact on marine ecosystems. Here, we test the idea that space-for-time (SFT) substitution might predict temporal change in the Canada Basin premised on differences in the present state of phytoplankton in other geographic zones, specifically the ratio in the abundance of picophytoplankton to nanophytoplankton (Pico:Nano). We compared the change in Pico:Nano observed in the Canada Basin from 2004 to 2012 to the different average states of this ratio in 26 other ocean ecological regions. Our results show that as upper ocean nitrate concentration changed in the Canada Basin from year to year, the concomitant change in Pico:Nano was statistically commensurate with the difference that this ratio exhibits between Longhurst ecological provinces in relation to nitrate concentration. Lower average concentration of nitrate in the upper water column is associated with a higher value of Pico:Nano, a result consistent with resource control of phytoplankton size structure in the ocean. We suggest that SFT substitution allows an explanation of temporal progression from spatial pattern as a test of mechanism, but such statistical prediction is not necessarily a projection of future states.

Beschreibung: Particle aggregation plays an important role in many marine biogeochemical processes such as determining the vertical flux of particulate material and trace metal scavenging. Models of particle aggregation vary in complexity and in this paper I compare the behavior of a detailed size-spectrum model with that of a series of simple, two size-class models with different representations of aggregation, all of which have appeared in the literature. The simplest model uses a first-order representation of aggregation kinetics, while two other models have non-linear representations of aggregation. The simplest model is unable to reproduce the dynamic or steady-state behavior of the size-spectrum model. Results from the two non-linear size-class models show better agreement with the behavior of the size-spectrum model. I find that the mode of aggregation and the dependence of aggregation on particle size are crucial for understanding the differences between the models.

Beschreibung: This study investigates how the quality of sea surface temperature (SST) observations made by drifting buoys (drifters) and ships for 1996-2010 can be improved through retrospective quality control (QC) against a reference field. The observations used are a blend of delayed mode data taken from the International Comprehensive Ocean-Atmosphere Data Set (versions 2.0 and 2.5) and real time data obtained from the Global Telecommunication System. A comparison of drifter and ship measurements on a platform-by-platform basis to high quality SST estimates from the ATSR Reprocessing for Climate (ARC) project reveals drifter observations are generally of good quality but frequently suffer from gross errors, whilst ship observations are generally of worse quality and show a diverse range of measurement errors. QC procedures are developed which similarly assess drifter and ship SST observations through comparison with the Met Office Operational SST and Sea Ice Analysis (OSTIA). These procedures make use of seasonal background error variance estimates now available for OSTIA. Drifter observations displaying some commonly observed gross errors are flagged and ship callsigns whose observations are deemed unreliable are blacklisted. Validation of the QC outcomes against ARC and Argo demonstrates that this retrospective QC improves the quality of drifter and ship observations, though some limitations are discussed.

Beschreibung: Observations of the spatially dependent velocity field over movable bedforms subjected to slightly skewed and asymmetric regular wave forcing were collected. The dynamics between the ripple elements is dominated by coherent vortices, characterized by the swirling strength, and evidenced in the temporal and spectral characterization. Within the boundary layer, spectral energy in the second harmonic (3 f 0 ) is amplified at the ripple slopes and is consistent with the location of the expected strongest pressure gradients. First- and second-moment velocity statistics were used to address the spatial variability of the intra-ripple hydrodynamics. Estimates of displacement and momentum thicknesses (δ* and δ mom ), are smaller than suggested by the higher harmonics, but consistently highlight areas of adverse and favorable pressure gradients. Shear stress and roughness estimates were inferred by fitting a logarithmic model to first- and second-moment statistics of the velocity field. The maximum Shields parameter was observed to peak at the stoss slope of asymmetric ripples during the strongest and shorter half-wave period (onshore). First-moment roughness estimates are similar in magnitude to bedload parameterizations provided by Li et al . [1997], and about a factor of 3 larger than second-moment estimates. Assessment of the vertical transfer of horizontal momentum derived using a Reynolds decomposition, suggests that stresses inferred from the logarithmic law using first-moment velocity statistics appropriately reproduce the mean momentum transfer for the longer and weaker offshore half-wave period.

Beschreibung: The tidal regime in the Bohai Sea, China, is investigated using observations and an established numerical tidal model. The area has recently experienced rapid coastline changes due to natural developments of the Yellow River delta and large-scale anthropogenic land reclamation. These morphological changes are not reflected in most global bathymetric databases and are thus rarely incorporated into investigations of the Bohai Sea. It is shown that there have indeed been significant changes in the tidal regime in the Bohai Sea over the last 35 years, with M 2 amplitudes changing up to 20 cm in some parts. The model captures some of these changes when the appropriate bathymetries are used. Furthermore, the simulations show that the tides in the Bohai Sea have become more sensitive to future sea level rise and the way in which it is implemented in the model (i.e. whether or not flood defenses are included).These sensitivity changes are due to the recent coastal developments.

Beschreibung: We investigate the temporal variability and trends of pH and of the aragonite saturation state, Ω arag , in the southern California Current System on the basis of a 6 year timeseries from Santa Monica Bay, using bi-weekly observations of dissolved inorganic carbon and combined calculated and measured alkalinity. Median values of pH and Ω arag in the upper 20 m are comparable to observations from the subtropical gyres, but the temporal variability is at least a factor of 5 larger, primarily driven by short-term upwelling events and mesoscale processes. Ω arag and pH decrease rapidly with depth, such that the saturation horizon is reached already at 130 m, on average, but it occasionally shoals to as low as 30 m. No statistically significant linear trends emerge in the upper 100 m, but Ω arag and pH decrease, on average, at rates of -0.009 ± 0.006 yr -1 and -0.004 ± 0.003 yr -1 in the 100 to 250 m depth range. These are somewhat larger, but not statistically different from the expected trends based on the recent increase in atmospheric CO 2 . About half of the variability in the deseasonalized data can be explained by the El Niño Southern Oscillation (ENSO), with warm phases (El Niño) being associated with above normal pH and Ω arag . The observed variability and trend in Ω arag and pH is well captured by a multiple linear regression model on the basis of a small number of readily observable independent variables. This permits the estimation of these variables for related sites in the region.

Beschreibung: We studied ancient enamels on gilded copper from a collection of archeological horse harness pendants of the Museo Instituto Valencia de Don Juan (Madrid, Spain) to test the benefits of a new, nondestructive analytical methodology based on chemometric analysis (i.e., Principal Component Analysis, PCA) on micro-ATR-FTIR spectral data and chemical quantification using SEM-EDS. The novelty of this approach was threefold: (i) PCA allowed the discrimination of the different harness pendants of known origin and attributed to the 14th and 15th centuries according to the chemical complex composition, nanostructure, glass weathering, and/or coloring mechanisms of each colored enamel, separately (i.e., red, purple, blue, and white), (ii) it is a cheap, easily available and nondestructive methodology that enables us to (iii) draw archeological conclusions about the quality of the manufacturing process, reassess the chronology of these objects and attempt to attribute them to different workshops according to the different traditional recipes identified. In particular, the enamels were made of alkali and/or alkaline earth lead-glass with a wide range of chemical compounds in the form of pigments or opacifiers. Two types of coloring mechanisms were identified, colloidal particles such as copper-ruby for red enamels, and ionic mechanisms such as Fe (II) and Co (II) to achieve a blue pigments; Mn (III) in the purple pigment; and two kind of white enamels were identified, i.e., tin oxide as an opacifier and uranium oxide. In addition, we established the reason for the poor state of conservation of some of the enamels by means of the identification of depolymerization and ion exchanges, well-known harmful effects of glass weathering, and finally a chronology was assigned for some of these pieces according to the enamel composition.

Beschreibung: Novel glass-ceramics with embedded thermoelectric Bi 2 Se 3 crystals were prepared from glass matrices in the Ge 20 Se 100− x Bi x ( x  = 5, 10, 12 mol%) system. Based on DSC results performed at different heating rates, characteristic activation energies ( E c ) and Avrami exponents ( n ) were obtained and analyzed by using Kissinger's relation, Ozawa's method, Augis–Bennett approximation and Matusita–Sakka theory. XRD results showed that pure Bi 2 Se 3 crystalline phase precipitated upon annealing at different temperatures for various time. The crystal size and crystalline fraction in the samples could be tuned by controlling the annealing time.

Beschreibung: In the present investigations nano size high alumina cements (HAC) were prepared by very effective co-melt precursor sintering technique from their metal nitrate precursors. The prime cementing phases observed were CA, CA 2 , and C 12 A 7 . The addition of nano structured cements in refractory castables has improved the thermo-chemical-mechanical properties to a significant extent. Each batch of low cement castables (LCC) was prepared from calcined Chinese bauxite, HAC, and superfine additives. The effect of HAC in bauxite castable with the additives similar to Silicon Carbide, reactive alumina, and micro-fine silica on the sinterability and properties of these castables was investigated. Physical properties such as apparent porosity and bulk density, mechanical properties such as hot modulus of rupture (HMOR), cold and hot modulus of rupture (CMOR), and cold crushing strength (CCS) of hydrated and sintered castables were studied. The sintered castables were also characterized for their solid phase compositions and microstructure using X-ray diffraction (XRD) and FE-SEM, respectively. In the castables new phases such as mullite, α-alumina were formed at the expense of bauxite and silica. Solid solution of mullite formed at high temperature acts as a bonding phase and is accounted for high HMOR, CMOR, and CCS values. These excellent properties of such castables may enable their uses in various applications such as refractory lining for fabrication of steel, aluminium, copper, glass, cement, chemicals, and ceramics.

Beschreibung: Zn 2 GeO 4 ceramic materials were synthesized by the solid-state method. Zn 2 GeO 4 powders were investigated with X-ray powder diffraction (XRD) and high-resolution transmission electron microscopy (HRTEM). Oxygen defects in the Zn 2 GeO 4 ceramics were investigated by photoluminescence, Raman, and EDS spectra. Conductivity of Zn 2 GeO 4 was 0.18 S/cm at low temperature of 773 K, and its activation energy was 0.49 eV. The results showed that Zn 2 GeO 4 was a promising low-temperature electrolyte with high conductivity.

Beschreibung: This article details the influence of zirconium doping on the piezoelectric properties and relaxor characteristics of 94( Bi 1/2 Na 1/2 ) TiO 3 –6 Ba ( Zr x Ti 1− x ) O 3 (BNT–6BZT) bulk ceramics. Neutron diffraction measurements of BNT–6BZT doped with 0%–15% Zr revealed an electric-field-induced transition of the average crystal structure from pseudo-cubic to rhombohedral/tetragonal symmetries across the entire compositional range. The addition of Zr up to 10% stabilizes this transition, resulting in saturated polarization hysteresis loops with a maximum polarization of 40 μC/cm 2 at 5.5 kV/mm, while corresponding strain hysteresis measurements yield a maximum strain of 0.3%. With further Zr addition, the ferroelectric order is progressively destabilized and typical relaxor characteristics such as double peaks in the current density loops are observed. In the strain hysteresis, this destabilization leads to an increase of the maximum strain by 0.05%. These changes to the physical behavior caused by Zr addition are consistent with a reduction of the transition temperature T F-R , above which the field-induced transformation from the relaxor to ferroelectric state becomes reversible.

Beschreibung: Precursor glasses for the ferroelectric barium bismuth titanate ( BaBi 4 Ti 4 O 15 ) (BBiT) have been prepared by the melt-quench technique in the SiO 2 – K 2 O – BaO – Bi 2 O 3 – TiO 2 (SKBBT) glass system with and without Eu 2 O 3 doping. BBiT glass–ceramic (GC) nanocomposites have been derived from these glasses by controlled heat treatment. The structural properties of the GCs have been investigated using X-ray diffraction (XRD), electron microscopy (FE-SEM, TEM), and FT-IR reflectance spectroscopy. FE-SEM images show the formation of randomly oriented hexagonal rod-shaped crystals of 200–400 nm and TEM images show 10–20 nm crystallites. FT-IR spectra exhibit the characteristic bands of BBiT at 480, 585, and 680 cm −1 . The activation energy of crystallization ( E c ) varies from 295 to 307 kJ/mol. The dielectric constants (ε r ) of glass and GC nanocomposites increase with an increase in frequency up to 3.0 MHz and then decrease up to 5.0 MHz. Heat-treated GCs show higher ε r values, in the range 25–55, compared to the precursor glasses (20–37). Dielectric losses (tan δ) for all the samples increase from 0.005 to 1.0 with an increase in frequency from 100 Hz to 5.0 MHz. Excitation spectra were recorded by monitoring emission at 613 nm corresponding to the 5 D 0 → 7 F 2 transition. An intense 466 nm excitation band corresponding to the 7 F 0 → 5 D 2 transition was observed. Emission spectra were then recorded by exciting the glass samples at 466 nm. Longer heat-treatment times led to a 15-fold increase in the intensity of the red emission at 612 nm, attributed to the segregation of Eu 3+ ions into the low phonon energy BBiT crystallites. The hardness (3.8–5.1 GPa) and fracture toughness (1.8–3.5 MPam 0.5 ) values obtained in the GCs are high and suitable for structural applications.

Beschreibung: Carbon doping is known to be very effective for enhancing the high-field properties of magnesium diboride, MgB 2 , but not for the low-field properties. Here, we report that both the high- and the low-field properties can be improved simultaneously without doping by increasing the initial magnesium partial pressure, by simply reducing the size of the magnesium particles. It is shown that in situ processed bulk MgB 2 sintered with fine magnesium powders has superior superconducting properties compared with a bulk sample fabricated using coarse magnesium lumps. The change in the lattice parameters was almost negligible; however, a clear increase in lattice strain can be observed for the sample sintered with fine magnesium powders. The increase in the lattice strain results in an enhancement of the high-field properties. Furthermore, it has also been found that the low-field critical current density is not reduced, but rather slightly increased for the fine magnesium powder sample. This is due to a closer linkage among the grains that drastically improves grain connectivity. These findings demonstrate that the initial growth mechanism of MgB 2 is very crucial for its superior superconducting properties, and it especially indicates the importance of magnesium vapor pressure.

Beschreibung: Revisiting classic phase diagrams and chemical phase relations in the solid state of a very well-studied oxide system, such as the lithium aluminosilicate (LAS) system, can open a new window for the design of new advanced materials with improved properties. Crystal chemistry and phase equilibria are used to demonstrate the ability to design materials with particular desired properties in the alumina-rich corner of the LAS phase diagram. The experimental results demonstrate the alumina and β-eucryptite solid-state compatibility.

Beschreibung: This work reports the crystallization, microstructure, and surface composition of Cu In 0.7 Ga 0.3 Se 2 (CIGS) thin films grown by femtosecond pulsed laser deposition at different annealing temperatures. The structural and optical properties of the CIGS films were characterized by X-ray diffraction, Raman scattering, UV-visible spectroscopy, and Hall effect measurement. The results indicate that binary crystals of CuS e initially formed on the as-deposited film, but then completely turned into a quaternary chalcopyrite structure after annealing at 400°C. Phase transformation significantly affects the surface morphology, Hall properties, and band gap. Transmission electron microscopy further revealed that an interface between the Mo substrate and CIGS crystallites contains an amorphous layer even at the high temperature of 500°C. For the application of photovoltaic devices, we also report on the photoresponse of both as-deposited and annealed films as demonstrated by preliminary tests.

Beschreibung: Reactive sintering of 3 Ti : Sn :2 C and 3Ti:Sn:2C:0.6Fe powder mixtures is studied in the temperature range 510°C–1200°C under argon. It is demonstrated that the recently discovered Ti 3 SnC 2 phase is formed, provided that Fe is added to a 3 Ti : Sn :2 C reactant mixture within the synthesis conditions used. Using dilatometric and X-Ray diffraction analyses, the formation mechanism of Ti 3 SnC 2 is discussed. Results show that at low temperature (about 510°C), tin is consumed to form Fe x Sn y intermetallics. At high temperature (about 1060°C), tin is newly available to form Ti 3 SnC 2 due to the melting of Fe x Sn y . Then, the intermediate phases, TiC and Ti 2 SnC , and/or Ti 5 Sn 3 , TiC , C , and Ti are dissolved in the ( Fe  +  Sn ) liquid phase and Ti 3 SnC 2 very likely precipitate from the melt. The second part of the study deals with the optimization of the Fe content in the initial 3Ti:Sn:2C reactant powder mixture to synthesize samples with larger Ti 3 SnC 2 content by hot isostatic pressing.

Beschreibung: The effects of non-stoichiometry on the microstructure, oxygen vacancies, and piezoelectric properties of ( Na 0.5 K 0.5 ) x NbO 3 (NK x N, where x  =   0.98, 1.00, 1.01, and 1.02) ceramics doped with sintering aid CuTa 2 O 6 (CT) doping were investigated. X-ray diffraction (XRD) patterns indicated that a secondary phase formed in CT-doped NK x N (NK x NCT) ceramics with x  〈   1.00 and that a pure phase was obtained with x  ≥   1.00. The grain size of NK x NCT ceramics increased with increasing x value due to the formation of a liquid phase. The internal bias field, activation energy, and Raman analysis for NK x NCT ceramics showed that the number of induced oxygen vacancies increased with decreasing x value. The high mechanical quality factor ( Q m ) value obtained for NK x NCT ceramics did not correspond to a higher concentration of oxygen vacancies, illustrating that the suitable compensation (excess Na and K ) is more important than the concentration of oxygen vacancies to obtain the ceramics with high Q m values. The NK x NCT ceramics with x  =   1.01 exhibited excellent piezoelectric properties, with k p and Q m values of 39.9% and 2,070, respectively.

Beschreibung: Low-temperature sintering of β-spodumene ceramics with low coefficient of thermal expansion (CTE) was attained using Li 2 O – GeO 2 sintering additive. Single-phase β-spodumene ceramics could be synthesized by heat treatment at 1000°C using highly pure and fine amorphous silica, α-alumina, and lithium carbonate powders mixture via the solid-state reaction route. The mixture was calcined at 950°C, finely pulverized, compacted, and finally sintered with or without the sintering additive at 800°C–1400°C for 2 h. The relative density reached 98% for the sample sintered with 3 mass% Li 2 O – GeO 2 additive at 1000°C. Its Young's modulus was 167 GPa and flexural strength was 115 MPa. Its CTE (from R.T. to 800°C) was 0.7 × 10 −6  K −1 and dielectric constant was 6.8 with loss tangent of 0.9% at 5 MHz. These properties were excellent or comparative compared with those previously reported for the samples sintered at around 1300°C–1400°C via melt-quenching routes. As a result, β-spodumene ceramics with single phase and sufficient properties were obtained at about 300°C lower sintering temperature by adding Li 2 O – GeO 2 sintering additive via the conventional solid-state reaction route. These results suggest that β-spodumene ceramics sintered with Li 2 O – GeO 2 sintering additive has a potential use as LTCC for multichip modules.

Beschreibung: Pyrochlore-structured lanthanide stannate ceramic ( Ln 2 Sn 2 O 7 ) has been synthesized via a new complex precipitation method. A suite of characterization techniques, including FTIR, Raman, X-ray, and electron diffraction as well as nitrogen sorption were employed to investigate the structural evolution of the synthesized and calcined powder. Raman, XRD, and selected area electron diffraction results confirm the presence of the pyrochlore structure after calcination of the powder above 1200°C. TEM imaging shows fine crystallites gradually increased in size from approximately 100 nm to about 500 nm with higher calcination temperatures. Grain growth and powder densification upon increasing the calcination temperature was confirmed by nitrogen sorption results. This aqueous synthetic method provides a simple pathway for the preparation of homogeneous lanthanide stannate ceramics.

Beschreibung: A new framework for simulating the El Niño/Southern Oscillation (ENSO) using a generalized linear model (GLM) is provided. The GLM provides a versatile and computationally inexpensive method for investigating ENSO dynamics, by conditioning an ENSO index on an arbitrary set of input variables. Here, the system state (El Niño/neutral/La Niña) at previous times is combined with the first few principal components of SST and thermocline depth. Despite having relatively few degrees of freedom, the model accurately reproduces 20th century SST time series, seasonal variance, power spectra and autocorrelation functions for both the eastern and western Pacific. The GLM also has good overall forecast skill, especially at sub-yearly lead times; performance is competitive with models currently used for operational ENSO forecasting. The model is then used to examine changes to El Niño/La Niña statistics under CO 2 increases, by using the GLM to represent simulations run with the NCAR Community Climate System Model, versions 3.5 and 4. GLM simulations of 21st century CCSM4 changes to El Niño/La Niña magnitudes show insignificant results, despite a slight increase in El Niño persistence. GLM fits conditioned on millennial stabilized CCSM3.5 simulations with varying CO 2 levels, however, show a weakening and shortening of El Niño events as CO 2 concentration increases, while La Niña events become markedly stronger and do not change significantly in length. The reduction in El Niño persistence in CCSM3.5 is consistent with previous results showing that at higher CO 2 levels, a stronger seasonal cycle creates a Southern Hemisphere ‘seasonal footprint’ leading to more efficient El Niño termination.

Beschreibung: Measurements near the edge of fast ice in Freemansundet, Svalbard, reveal mixing processes associated with tidal advection of a sharp front in salinity, including possible supercooling induced by double diffusion in a fully turbulent water column. The front translated back and forth with the semidiurnal tide between an area of mobile (drifting) ice in Storfjorden proper, and the narrow sound covered by fast ice. Water on each side of the front was near its salinity-determined freezing temperature. Instruments deployed about 400 m into the sound from the fast ice edge measured current, temperature, conductivity, and turbulence quantities through several tidal cycles. Turbulence data illustrate that as the steep horizontal salinity (density) gradient advected past the measurement site, vertical shear near the fast-ice base induced marked flood/ebb asymmetry in turbulent mixing. As fresher water entered the sound on the flood phase, inward transport of denser water near the upper boundary was retarded, leading to statically unstable conditions and enhanced turbulence. The opposite occurred during ebb tide, as denser water under-ran lighter. Transient episodes of supercooling accompanied frontal passage on both flood and ebb phases. The most likely explanation for a zone of supercooled water within the strongly mixed frontal region is that during mixing of fresher, slightly warmer (but still at freezing) water from outside with saltier, colder water in the sound, the former constituent lost heat faster than gaining salt. This interpretation (differing turbulent diffusivities for heat and salt) challenges strict application of Reynolds analogy for highly turbulent shear flow.

Beschreibung: The detection of long-term trends in geophysical time series is a key issue in climate change studies. This detection is affected by many factors: the size of the trend to be detected, the length of the available datasets, and the noise properties. Although the noise auto-correlation observed in geophysical time series does not bias the trend estimate, it affects the estimation of its uncertainty and consequently the ability to detect, or not, a significant trend. Ignoring the noise auto-correlation level typically leads to an over-detection of significant trends. Satellite time series have been providing remote observations of the sea surface for several decades. Due to satellite lifetime, usually between 5 and 10 years, these time series do not cover the same period and are acquired by different sensors with different characteristics. These differences lead to unknown level shifts (biases) between the datasets, which affect the trend detection. In this work, we develop a generic framework to detect and evaluate linear trends and level shifts in multi-sensor time series of satellite chlorophyll-a concentrations, as provided by the MERIS and SeaWiFS ocean color missions. We also discuss the optimization of the observation networks, in terms of needed time overlap between successive time series in order to reduce the uncertainty on the detection of long-term trends. For the incoming Sentinel-3 - OLCI mission that should be launched at the end of 2014, we propose a global map of the duration of this future time series necessary to actually enhance the trend detection performed with the joint SeaWiFS-MERIS analysis.

Beschreibung: The effects of exopolymers on the particle size distributions (PSD) of suspended cohesive sediments were investigated in laboratory using four abundant clay minerals, kaolinite, illite, Na-montmorillonite, and Ca-montmorillonite, and two exopolymers, xanthan and guar, at six different exopolymer to clay ratios (E/C) (i.e., 0, 1, 2, 5, 10, and 20 wt.%) to represent the compositional variability of cohesive sediments in natural waters. Results show that the clay-exopolymer suspensions possess multimodal PSD. Statistical deconvolution of the PSD curves indicates that the suspensions consist of four discrete particle groups, primary particles, flocculi, microflocs, and macroflocs, all of which exhibit a unimodal lognormal distribution. Furthermore, such deconvolution quantifies the mean size and fraction of each particle group, leading to a more quantitative understanding of PSD kinetics of these sediments. Both clay surface charges and exopolymer polarity as well as the E/C affect the PSD kinetics. While neutral guar causes flocculation for all four clay minerals, anionic xanthan only induces flocculation for kaolinite with very low surface charges, but not for the other three clay minerals with relatively high charges. The fraction of each particle group also varies with the E/C, and such complex changes depend upon the interfacial interactions between clay particles and exopolymer molecules. For each exopolymer, critical E/C exist that can lead to a maximum or minimum fraction of microflocs or macroflocs. The role of exopolymer bridging, Coulomb force, and hydrogen bond in affecting the PSD kinetics of cohesive sediments is also discussed.

Beschreibung: Ceramics have played a crucial role in the development of fission based nuclear power, in glass & glass composite high level wasteforms, in composite cements to encapsulate intermediate level wastes (ILW) and also for oxide nuclear fuels based on UO 2 and PuO 2 /UO 2 mixed oxides. They are also used as porous filters with the ability to absorb radionuclides (RN) from air and liquids and are playing a key role in the cleanup at Fukushima. Non-oxides also find current fission applications including in graphite moderators and B 4 C control rods. Ceramics will continue to be significant in the near-term expansion of nuclear power via next-step developments of fuels with inert matrices or based on thoria and in wasteforms using alternative composite cements or single or multiphase ceramics that can host Pu & other difficult RN. Longer term advances for Generation IV reactors, which will operate at higher temperatures & with higher fuel burn-up require innovative fuel developments potentially via carbides & nitrides or composite fuel systems. Novel non-thermal (cement-like) and thermal techniques are currently being developed to treat some of the difficult legacy wastes. Non-thermally derived wasteforms developed from geopolymers, composite cements, hydroceramics, and phosphate-bonded ceramics and thermally derived wasteforms made by Hot Isostatic Pressing and fluidized bed steam reforming (FBSR) as well as vitrification techniques based on cold crucible melting (CCM), Joule-heater in-container melting and plasma melting (PM) are described. Future developments in waste treatment will be based on separation technologies for partitioning individual RN along with design & construction of RN-containing ceramic targets for inducing transmutation reactions. Near demonstration actinide-hosting ceramic wasteforms including multiphase Synroc systems are described. Opportunities also exist for ceramics in structural applications in Generation IV reactors such as composite SiC / SiC and C / C for fuel cladding and control rods and MAX phases and ultrahigh-temperature ceramics (UHTCs) may find near core fuel coating and cladding applications. Uses of ceramics in fusion reactor systems will be both functional (ceramic superconductors in magnet systems for plasma control and in Li silicate breeder blankets in tokamaks) and structural including as sapphire diagnostic windows, graphite diverters, and plasma facing C and UHTCs. In all these cases, performance is limited by poorly understood radiation damage and interface controlled processes, which demands a combined modeling/experimental approach.

Beschreibung: ABSTRACT Heat and water mass transports tagged by water type in a bay were investigated using daily outputs from a high-resolution land–sea coupled model. The modeled circulation and water property distribution were similar to those reported by observations. In this paper, the heat angle is introduced to accurately define the roles of the lateral heat flux ( LF ) into the bay and the net surface heat flux on temperature changes in the bay water. As a result, ocean phenomena in the bay can be categorized by using the heat angle in an intensive LF regime on short-period timescales and a gradual LF regime on intra-seasonal timescales. Our close examination revealed that the velocity fields can be classified into three flow patterns: a twin vortex accompanied by positive LF , a clockwise flow with negative LF , and an anticlockwise flow with both LF s. These patterns occur in both intensive and gradual LF regimes. Intensive wind-driven LF forced by atmospheric disturbances was often observed from summer to autumn in 2008 accompanying the intrusion of southern subtropical Tsugaru warm water that was colder than the deep bay water ( LF 〈 0) and subarctic Oyashio water that was warmer than the surface bay water ( LF 〉 0), but both were hardly found in 2009. This thermal contrast affects the interannual difference in the stratification inherent in the bay. Our integrated analysis method is useful for prompt and robust understanding of the thermal and dynamic states in a bay based on ocean simulation data.

Beschreibung: The promotion of zircon ( ZrSiO 4 ) crystallization by ZnO from a zirconium-based frit glaze was studied and the possible mechanism was discussed. X-ray diffraction was used to analyze the relative quantities of zircon and other transitional crystals in the samples. The results show that ZnO can significantly decrease the crystallization temperature of zirconium-based glaze, depress the formation of Ca 2 ZrSi 4 O 12 , and promote the devitrification of transitional crystals t - ZrO 2 and Ca 2 ZnSi 2 O 7 , as well as lead to the formation of more zircon than the ZnO -free glaze. It was also found that zircon not only can form from the interaction between t - ZrO 2 and SiO 2 but also can devitrify directly from the glass phase of zirconium-based glaze.

Beschreibung: Barium-substituted CsAlSi 2 O 6 pollucites, Cs x Ba (1− x )/2 AlSi 2 O 6 , and barium- and iron-substituted pollucites, Cs x Ba (1− x )/2 Al x Fe 1− x Si 2 O 6 and Cs x Ba 1− x Al x Fe 1− x Si 2 O 6 were synthesized with 1 ≥  x ≥ 0.7 using a hydrothermal synthesis procedure. Rietveld analysis of X-ray diffraction data confirmed the substitution of Ba for Cs and Fe for Al , respectively. The crystallographic analysis also describes the effects of three different types of pollucite substitutions on the pollucite unit cell: Ba 2+ for Cs 1+ cation results in little effect on cell dimensions, intermediate concentrations of Ba 2+ and Fe 3+ substitution result in net minor expansion due to Fe 3+ addition, and large Ba and Fe substitutions result in overall framework contraction. Elemental analysis combined with microscopy further supports the phase purity of these new phases. These materials can be used to study the stability of CsAlSi 2 O 6 as a durable ceramic waste form, which could accommodate with time Cs and its decay product, Ba . Furthermore, success in iron substitution for aluminum into the pollucite lattice predicts that redox charge compensation for Cs cation decay is possible.

Beschreibung: Nitrogen-doped mullite fibers were first synthesized through the nitridation of Al 2 O 3 – SiO 2 gel fibers in NH 3 . The results showed that nitrogen take-up began at 800°C, reached the maximum at 900°C, and then decreased with increasing temperature. The ceramic fibers nitridated at 900°C were essentially amorphous, but contained a small amount of nano-sized Al – Si spinel crystals. Mullite was formed after nitridation at 1200°C, accompanied by crystallization of χ- SiAlON and δ- Al 2 O 3 . The incorporation of nitrogen resulted in the formation of a variety of nitrogen-containing crystalline phases. The grain size of the mullite fibers can be adjusted by changing of the nitrogen content.

Beschreibung: The solubility limit of Ca in 99.99% pure α- Al 2 O 3 (alumina) was measured using a wavelength dispersive spectrometer mounted on a scanning electron microscope. Al 2 O 3 samples were equilibrated at a concentration which ensured saturation of the Al 2 O 3 grains with Ca , and were quenched in water from 1600°C. The results were compared with those from samples which were furnace cooled from 1600°C. For the quenched samples, the Ca solubility limit was found to be 51 ± 1 ppm, which is significantly larger than the solubility limit for samples which were furnace cooled (26 ± 1 ppm).

Beschreibung: The possibility of developing large solid oxide fuel cell (SOFC) stacks based upon 25 cm 2 ceramic oxide anode-supported cells is investigated. Planar fuel cells comprising strontium titanate-based anode support impregnated with active catalysts were prepared using a combination of deposition techniques. The fuel cell tests performed in a semisealed rig have shown power densities of 185 mW cm −2 at 850°C using humidified hydrogen as fuel and air as oxidant. The structure and evolution of the catalytically active impregnated materials-10 mol% Gd -doped CeO 2 and nickel- are analysed using electron microscopy at the end of the fuel cell test, revealing that a ceria and nickel layer surrounds the titanate backbone grains while ~50–150 nm spherical-like nickel particles uniformly decorate this top layer.

Beschreibung: Structural and dielectric properties of (1− x ) BaTiO 3 – x Bi ( Mg 1/2 Ti 1/2 ) O 3 ( x  = 0.1–0.5) were investigated to understand the binary system and utilize it for high-voltage, high energy density capacitors. The solubility limit for Bi ( Mg 1/2 Ti 1/2 ) O 3 in a BaTiO 3 perovskite was between x  = 0.4 and x  = 0.5. A phase with pseudocubic symmetry was formed for x  = 0.1–0.4; a secondary phase developed at x  = 0.5. Dielectric measurements showed highly diffusive and dispersive relaxor-like characteristics from 10 to 40 mol% of Bi ( Mg 1/2 Ti 1/2 ) O 3 . These compositions also showed high relative permittivity with low-temperature coefficients of permittivity over a wide range of temperatures −100°C–600°C. Relaxation behavior was quantitatively investigated using the Vogel–Fulcher model, which revealed the activation energy of 0.17–0.22 eV. Prototyped multilayer capacitors of 18 mm × 17 mm × 4 mm dimensions with a capacitance of 12.5 nF at 1 kHz were successfully constructed and demonstrated multiple charge–discharge characteristics up to 10 kV.

Beschreibung: K 3 Gd ( PO 4 ) 2 : RE 3+ (RE = Eu, Tb) are prepared by solid-state reaction and their photoluminescence (PL) properties are investigated under UV and VUV excitation, respectively. The obtained experimental data show that no energy transfer happens among the activator ions Tb 3+ or Eu 3+ under UV excitation. Under 147-nm excitation, the strongest emission intensity of K 3 Gd ( PO 4 ) 2 : RE 3+ (RE = Eu, Tb) is obtained when the activator ions Tb 3+ or Eu 3+ concentration is 0.8 mol, the integrate emission intensity of K 3 Gd 0.2 (PO 4 ) 2 :0.8Tb 3+ is about 204% of commercial phosphor Zn 1.96 SiO 4 :0.04 Mn 2+ with chromaticity coordinates of (0.340, 0.561) and the decay time of about 5.09 ms under 147-nm excitation. We analyze the experimental data and propose a possible energy-transfer mechanism under 147-nm excitation.

Beschreibung: The 0.72 Bi ( Fe 1− x Al x ) O 3 –0.28 BaTiO 3 ( x  = 0, 0.01, 0.03, 0.05, and 0.07, abbreviated as BFA x – BT ) lead-free high-temperature ceramics were prepared by the conventional ceramic processing. Systematic investigation on the microstructures, crystalline structures, dielectric and piezoelectric properties, and high-temperature stability of piezoelectric properties was carried out. The crystalline structures of BFA x –BT ceramics evolve from rhombohedral structure with x 〈  0.01 to the coexistence of rhombohedral structure and pseudocubic phases with x  ≈ 0.01, finally to pseudocubic phases when x 〉  0.03. Remarkably high-temperature stability with near-zero temperature coefficient of piezoelectric properties ( TCk p ), together with improved piezoelectric properties has been achieved for x  = 0.01 BFA x –BT ceramics. The BFA x –BT( x  = 0.01) ceramics simultaneously show the excellent piezoelectric properties of d 33  = 151 pC/N, k p  = 0.31 and super-high-temperature stability of T d  = 420°C, TCk p  = 1 × 10 −4 . It is considered that the observed strong piezoelectricity and remarkably high-temperature stability should be ascribed to the phase coexistence of rhombohedral and pseudocubic phases. The rhombohedral phases have a positive TCk p value and the pseudocubic phases possess a negative TCk p value. Thus, the TCk p value of BFA x –BT ceramics can be tuned by composition of x .

Beschreibung: [1]  Basic constraints on the dense water formation rate and circulation resulting from cooling around an island are discussed. The domain under consideration consists of an island surrounded by a shelf, a continental slope, and a stratified ocean. Atmospheric cooling over the shelf forms a dense water that penetrates down the sloping bottom into the stratified basin. Strong azimuthal flows are generated over the sloping bottom as a result of thermal wind. Thermally direct and indirect mean overturning cells are also forced over the slope as a result of bands of convergent and divergence Reynolds stresses associated with the jets. The Coriolis force associated with the net mass flux into the downwelling region over the slope is balanced by these nonlinear terms, giving rise to a fundamentally different momentum budget than arises in semi-enclosed marginal seas subject to cooling. A similar momentum balance is found for cases with canyons and ridges around the island provided that the terms are considered in a coordinate system that follows the topography. Both eddy fluxes and the mean overturning cells are important for the radial heat flux, although the eddy fluxes typically dominate. The properties of the dense water formed over the shelf (temperature, diapycnal mass flux) are predicted well by application of baroclinic instability theory and simple heat and mass budgets. It is shown that each of these quantities depends only on a nondimensional number derived from environmental parameters such as the shelf depth, Coriolis parameter, offshore temperature field, and atmospheric forcing.

Beschreibung: The Pacific Decadal Oscillation (PDO) has been shown to have significant climatic and environmental impacts across the Pan-Pacific basin; however, there are no records of PDO activity from the South China Sea (SCS), the largest marginal sea in the northwest Pacific Ocean. This study suggests that a series of geochemical profiles obtained from a modern coral in the northern SCS records annual PDO activity dating back to 1853. These geochemical data are significantly correlated with the PDO index, and their patterns of variation closely match those of the PDO index over the last century. The relationship between the PDO and coral geochemistry may be related to the influence of the PDO on rainfall on Hainan Island. Rainfall patterns influence the volume of terrestrial runoff, which, in turn, is a primary determinant of δ 18 O and Δδ 18 O values in coral; however, coral δ 13 C values are also influenced by the 13 C Suess effect. The results indicate that Sr/Ca ratios in coral are affected by a combination of sea surface temperature and terrestrial runoff.

Beschreibung: [1]  The attenuation of downward planar irradiance can be quantified by , the diffuse attenuation coefficient calculated from the surface to the depth where the irradiance E d at wavelength λ falls to 10% of its surface value. Theoretical studies by Gordon [1989], Limnol. Oceanogr. 34, 1389-1409 and Lee et al . [ 2005a], J. Geophys. Res. 110, C02016 suggest that can be derived from the absorption coefficient, a ( λ ) and the backscattering coefficient, b b ( λ ), using equations incorporating either the solar zenith angle ( θ a ) or the subsurface distribution function ( D 0 ) and empirical coefficients derived by radiative transfer modelling. These results have not, however, been validated against in situ measurements. We have therefore assessed the performance of both models using measurements of a ( λ ), b b ( λ ) and for 100 stations in UK coastal waters. Best results were obtained from the Lee et al . [2005] model, for which over 90% of the predicted values in the 440 nm to 665 nm range were within +/- 0.1 m -1 of those measured in situ. A strong linear relationship ( R 2  〉 0.95, mean relative difference 5.4%) was found between at 490 nm and the reciprocal of the depth of the mid-point of the euphotic zone ( z 10% , PAR). This allowed ( z 10% , PAR) to be predicted from measured values of a (490 nm), b b (490 nm) and θ a , using the Lee et al . model as an intermediate step, with an RMS error of 1.25 m over the 2.5 m to 25.0 m range covered by our data set.

Beschreibung: [1]  The role of asymmetric tidal mixing (ATM) in subtidal estuarine dynamics is investigated using a series of generic numerical experiments that simulate narrow estuaries under different stratification and external forcing conditions. The focus is on quantifying the characteristics of ATM-induced flow and its contributions to stratification and salt transport. The flow induced by ATM has a two-layer vertical structure in periodically stratified estuaries, similar to that of the density-driven flow. It has a three-layer vertical structure in the central regime of weakly stratified estuaries, and a reverse two-layer structure in highly stratified estuaries. The changes in vertical distribution of ATM-induced flows result from the influence of stratification on the covariance of eddy viscosity and vertical shear. Such covariance represents the driving force of ATM-induced flow in the tidally averaged momentum equation. Compared to density-driven flow, ATM-induced flow dominates in periodically stratified estuaries with strong tides, has the same order of magnitude in weakly stratified estuaries with moderate tides, and is less important in highly stratified estuaries with weak tides. In contrast to density-driven flow that always increases estuarine stratification and transports salt landward, the ATM-induced flow exhibits different behaviors because of its varying vertical structure. In estuaries with strong tides, ATM-induced flow tends to enhance stratification and to transport salt landward, similar to density-driven flow. In estuaries with weak tides, ATM-induced flow tends to reduce stratification and to transport salt seaward.

Beschreibung: We examine the basin-wide trends in sea ice circulation and drift speed, and highlight the changes between 1982-2009 in connection to local winds, multiyear sea ice coverage, ice export, and the thinning of the ice cover. The polarity of the Arctic Oscillation (AO) is used as a backdrop for summarizing the variance and shifts in decadal drift patterns. The 28-year circulation fields show a net strengthening of the Beaufort Gyre and the Transpolar Drift, especially during the last decade. The imprint of the Arctic Dipole Anomaly on mean summer circulation is evident (2001-2009) and enhances summer ice area export at the Fram Strait. Between 2001 and 2009, the large spatially averaged trends in drift speeds (winter: +23.6%/decade, summer: +17.7%/decade) are not explained by the much smaller trends in wind speeds (winter: 1.46%/decade, summer: -3.42%/decade). Notably, positive trends in drift speed are found in regions with reduced multiyear sea ice coverage. Over 90% of the area of the Arctic Ocean has positive trends in drift speed and negative trends in multiyear sea ice coverage. The increased responsiveness of ice drift to geostrophic wind is consistent with a thinner and weaker seasonal ice cover and suggests large-scale changes in the air-ice-ocean momentum balance. The retrieved mean ocean current field from decadal-scale average ice motion captures a steady drift from Siberia to the Fram Strait, an inflow north of the Bering Strait, and a westward drift along coastal Alaska. This mean current is comparable to the geostrophic current from satellite-derived dynamic topography.

Beschreibung: Owing to the widespread presence of electromagnetic interferences, it is necessary to develop new materials with excellent high-temperature electromagnetic wave (EM) absorption properties. In the present work, ZnO is infiltrated into porous ZrSiO 4 substrates to form ZnO / ZrSiO 4 composite ceramics using sol-gel process. The doping of aluminum results in the improvement of electrical conductivity and the significant change in the morphology of ZnO . With the increase in environment temperature during measurement, the permittivity of the composite ceramics increases first and then decreases dramatically, which is attributed to the change in conductive loss. The electrical conductivity increases with increasing measurement temperature. However, the concentration of oxygen vacancies decreases under air atmosphere when the measurement temperature increases continuously, which results in the reduction in conductivity. Therefore, permittivities of the undoped and doped ceramics measured at 673 K are higher than the ones at the other temperatures. The composite ceramics maintain a relatively high EM absorption coefficient, low reflection coefficient (RC), and wide effective absorption bandwidth at environment temperatures up to 773 K. As a result, we conclude that the ZnO / ZrSiO 4 composite ceramics exhibit a promising prospect as a kind of high-temperature EM absorbing material.

Beschreibung: [0001] textured alumina ceramics with a fine grain size were fabricated between 1400°C and 1600°C via templated grain growth (TGG) using fine alumina platelets (~0.6 and ~3 μm diameter) aligned by tape casting in either a 50 nm α- Al 2 O 3 matrix powder, or in a seeded boehmite sol. The 3 μm templates could be readily aligned by tape casting in both matrices (orientation parameters r  = 0.27 and 0.18, respectively), whereas 0.6 μm diameter templates were well aligned in the seeded boehmite sol only ( r  = 0.29). Improved alignment in boehmite sols is attributed to inorganic gelation, resulting in a strongly pseudo-plastic rheology that preserves template alignment against the influence of Brownian motion. The in situ formation of fine α- Al 2 O 3 matrix after transformation in the seeded boehmite system results in a higher driving force for TGG and improves texture development. The combination of 3 μm templates with a seeded boehmite matrix results in extremely high texture qualities (texture fraction f  = 0.97–0.99, r  = 0.17) while maintaining a relatively fine grain size (5–10 μm in diameter and 1.5–3 μm in thickness). Although undoped samples can be fully textured at 1600°C, adding as little as ~0.25 wt% CaO / SiO 2 dopant improves TGG kinetics and yields full texture at 1400°C.

Beschreibung: [1]  We present a data-assimilated model of ocean's phosphorus cycle that is constrained by climatological phosphate, temperature, salinity, sea-surface height, sea-surface heat and freshwater fluxes, as well as CFC-11 and natural Δ 14 C. Export production is estimated to be 5.8 ± 2.0 × 10 12  mol P/year of which 26 ± 6% originates in the Southern Ocean (SO) south of 40°S. The biological pump efficiency, defined as the proportion of the ocean's phosphate inventory that is regenerated, is 39 ± 7%. Dividing the SO south of 40°S into a subantarctic zone (SANTZ) and an antarctic zone (ANTZ) separated by the latitude of maximum Ekman divergence, we estimate that the SANTZ and ANTZ account respectively for 23 ± 5% and 3 ± 1% of global export production, 17 ± 4% and 3 ± 1% of the regenerated nutrient inventory, and 31 ± 1% and 43 ± 5% of the preformed nutrient inventory. Idealized SO nutrient depletion experiments reveal a large-scale transfer of nutrients into circumpolar and deep waters, and from the preformed to the regenerated pool. In accord with the concept of the biogeochemical divide, we find that nutrient drawdown in the ANTZ is more effective than in the SANTZ for increasing the efficiency of the biological pump, while having a smaller impact on production in regions north of 40°S. Complete SO nutrient drawdown would allow the biological pump to operate at 94% efficiency by short circuiting the transport of nutrients in northward Ekman currents leading to a trapping of nutrients in circumpolar and deep waters that would decrease production outside the SO by approximately 44% while increasing it in the SO by more than 725%.

Beschreibung: Yttria partially stabilized zirconia Y-PSZ/glass-ceramic composites were prepared by reaction sintering using powder mixtures of a SiO 2 – Al 2 O 3 – ZnO – CaO – ZrO 2 – TiO 2 -based glass and yttria partially stabilized zirconia (Y-PSZ). The glass crystallized during sintering at temperatures of 1173, 1273, and 1373 K to give a glass-ceramic matrix for high-temperature protecting coatings. With the increasing firing time, the added zirconia reacted with the base glass and a glass-ceramic material with dispersed zircon particles was prepared in situ . Furthermore, the added zirconia changed the crystallization behavior of the base glass, affecting the shape, amount, and distribution of zircon in the microstructure. The bipyramid-like zircon grains with imbedded residual zirconia particles turned out to have two growth mechanisms: the inward growth and the outward growth, and its rapid growth was mainly dominated by the later one. For comparison, the referenced glass-ceramic was prepared by sintering using exclusive glass granules and its crystallization behavior at 1173–1373 K was examined as well. Scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS), transmission electron microscopy (TEM), and X-ray diffraction (XRD) were used to characterize the crystallization behavior of the base glass and the phase evolution of the Y-PSZ/glass-ceramic composites.

Beschreibung: In this study, we present the preparation of a bulk material with a composition of 80 GeTe 2 –20 Ga 2 Te 3 by combining mechanosynthesis and sintering. This composition cannot be prepared by conventional melt/quenching technique. The progressive evolution of the powder during ball-milling is followed by X-ray Diffraction (XRD) and Differential Scanning Calorimetry analysis. The final powder obtained is highly crystalline, but a glass transition temperature ( T g ) is observed, indicating the presence of some amorphous phase remaining, allowing for its efficient sintering. By hot-pressing, a dense bulk material with a fine microstructure and a high electrical conductivity is obtained. The synthesis method described represents a simple and cost-effective way to produce tellurium-based materials of desired dimension with potential applications for optical storage or thermoelectric devices.

Beschreibung: [1]  We have developed, validated, and applied a synthetic method to monitor the off-equatorial eastward currents in the central tropical Atlantic. This method combines high-density expendable bathythermograph (XBT) temperature data along the AX08 transect with altimetric sea level anomalies (SLAs) to estimate dynamic height fields from which the mean properties of the North Equatorial Countercurrent (NECC), the North Equatorial Undercurrent (NEUC) and the South Equatorial Undercurrent (SEUC), and their variability can be estimated on seasonal to interannual timescales. On seasonal to interannual timescales, the synthetic method is well suited for reconstructions of the NECC variability, reproduces the variability of the NEUC with considerable skill, and less efficiently describes variations of the SEUC, which is located in a region of low SLA variability. A positive correlation is found between interannual variations of the NECC transport and two indices based on an interhemispheric sea surface temperature (SST) gradient and southeasterly wind stress in the central tropical Atlantic. The NEUC is correlated on interannual timescales with SSTs and meridional wind stress in the Gulf of Guinea and zonal equatorial wind stress. This study shows that both altimetry and XBT data can be effectively combined for near-real-time inference of the dynamic and thermodynamic properties of the tropical Atlantic current system.

Beschreibung: Revealing and understanding the microscopic origins of the macroscopic properties of aluminosilicate glasses is important for the design of new glasses with optimized properties. In this work, we study the composition-structure-property relationships in 20 MgO / CaO sodium aluminosilicate glasses upon Al 2 O 3 -for- SiO 2 and MgO -for- CaO substitutions. We find that some properties (density, molar volume, Young's modulus, and shear modulus) are linear through the investigated range of Al 2 O 3 compositions, while others (refractive index, coefficient of thermal expansion, Vickers hardness, isokom temperatures, and liquid fragility index) exhibit a change in the slope around the composition with [ Al 2 O 3 ] = [ Na 2 O ], which is especially pronounced for the glasses containing MgO . We discuss these phenomena based on structural information obtained by NMR spectroscopy and topological considerations.

Beschreibung: In this article the changes on the surface of the 45S5 bioglass submitted to an enrichment with calcium ions were investigated. The method employed was the immersion of bioglass in calcium molten salt bath at 450°C. Changes in composition were probed by different techniques of chemical analysis. The use of SEM-EDS allowed estimating the thickness modified, as being about 10 μm. X-ray photoelectron spectroscopy enabled to infer over the structural changes on the surface of 45S5 bioactive glass. The entry of calcium in the vitreous network promoted the phase separation of microdomains rich in silica and phosphate on the surface of the glass. The formation of immiscibility region was attributed a depolymerization of silica network and also, to a possible migration of phosphate species from the bulk. The results of this study indicate a great change in the surface properties of this biomaterial. In addition, the method proposed in this study proved to be very promising in the possibility of designing the surface of bioactive glasses, to modulate the desired properties, keeping the bulk unchanged.

Beschreibung: [1]  Parameterizations of near-bed sediment processes are commonly associated with the poor predictive skill of coastal sediment transport models. We implement a two-dimensional Reynolds-Averaged Navier-Stokes (RANS) model to directly assess these parameterizations by reproducing measurements obtained in large-scale wave flume experiments. A sediment transport model has been coupled to wave hydrodynamics and turbulence, and numerical experiments provide temporal and spatial variations of free surface, flow velocity, sediment concentration and turbulence quantities. Model-data comparisons enable the direct assessment of how key suspension processes are represented and of the inherent variability of the sediment transport model. We focus on the different processes occurring above rippled beds versus dynamically flat beds. Numerical results show that increasing roughness alone is not sufficient to have good predictive capability above steep ripples. Some parameterization of the vortex entrainment process is necessary and a simple modification, which leads to constant sediment diffusivity above steep-rippled beds, is sufficient to obtain good predictions of wave-averaged suspended concentrations. Model-data comparisons for the turbulent kinetic energy are also presented and highlight the need to account for the effect of vortex entrainment on near-bed turbulence and transfer of momentum.

Beschreibung: The meridional heat flux required to balance the heat lost by ocean to atmosphere at high latitudes must be accomplished by some mechanism other than mean advection and the heat flux by eddies crossing the Antarctic Circumpolar Current (ACC) may be a candidate. In this study, the positions of the main ACC fronts are determined basing on 23 XBT transects collected from 1994 to 2010 and are compared to those detected through satellite altimetry. Then cold core anomalies in XBT sections are identified and altimetry is used to follow the spatial-temporal evolution of these cold, low sea level anomalies. Mean values of main parameters, such as speed (0.35 Km/h), lifetime (79 weeks) and diameter (105 Km), are estimated. Moreover, estimations of rotational speed (0.9÷76.8 cm/s), ocean surface layer heat content along temperature sections and eddy Available Heat Anomaly (mean value -9.74*10 9 Jm -2 ) give a wider description of the detected eddies. In our study area, the spawning of eddies is found to occur downstream of the Southeast Indian Ridge and in correspondence of the Polar Front (PF) when regarding to the ACC frontal structure The contribution of eddies to the global heat budget is linked to their ability to cross the ACC fronts but also to the capacity of keeping partially unaltered the properties of water inside them. Analysis of the relation between the translation and rotational speeds shows that a typical eddy may effectively be a significant part (0.8%) of the net meridional heat transport across the PF with a mean heat content/anomaly of -7.65*10 19 J.

Beschreibung: Recent dramatic changes of freshwater systems in high latitudes will allow Submarine Fresh Groundwater Discharge (SFGD) to play a more important role in the coastal environment; especially in that SFGD will directly effect heat flux. Toyama Bay, along the central western Japan coast, is a suitable and representative case study area to estimate SFGD flux using hydrographic properties since multiple high-flow rate SFGD sites exist there. Salinities averaged over the water column (depth range 10–100 m) measured during research cruises in June 2003 and May 2005 show lower levels in the eastern than the western area in this bay. Together with monthly hydrographic properties over a 10-year period (1987-1998), the low salinity water mass in the eastern area exists consistently but distinctly and varies systematically, as does nutrient flux, affected by SFGD more than riverine input. SFGD fluxes in June 2003 (1 x 10 8 m 3 month -1 ) and May 2005 (〈1 x 10 8 m 3 month -1 ) were estimated using a box model, which is divided into a shallow box (0 – 40 m) and a deeper box (40 – 100 m). The monthly flux ratio between the SFGD and the river inputs is 13% in June, comparable to higher values reported in other global studies. Our results demonstrate that the box model analysis, based on hydrographic observations in coastal areas, is an efficient approach that can be used to estimate SFGD fluxes between the land and ocean.

Beschreibung: Time series measurements of temperature, salinity and surface meteorological parameters recorded at 8°N, 90°E in the southern central Bay of Bengal (BoB) from a Research Moored Array for African-Asian-Australian Monsoon Analysis and predication (RAMA) buoy are used to document temperature inversions and their influence on the mixed layer heat budget during the winters, defined as October to March, of 2006-07 (W67) and 2007-08 (W78). There is a marked difference in the frequency and amplitude of temperature inversion between these two winters, with variations much stronger in W78 compared to W67. The formation of temperature inversions is favored by the existence of thick barrier layers, which are also more prominent in W78 compared to W67. Inversions occur when heating in the barrier layer below the mixed layer by penetrative shortwave radiation is greater than heating of the mixed layer by net surface heat flux and horizontal advection. Our analysis further demonstrates that intraseasonal and year-to-year variability in the frequency and magnitude of temperature inversions during winter have substantial influence on mixed layer temperature through the modulation of vertical heat flux at the base of mixed layer.

Beschreibung: Lanthanum hexaaluminate is a promising competitor to establish yttria partially stabilized zirconia as a thermal barrier coating material for Ni -based superalloy due to its relative low intrinsic thermal conductivity and low sinterability at temperatures exceeding 1100°C. Sr 2+ and Ti 4+ were selected as two dopants to partially substitute the La 3+ and Al 3+ in LaMgAl 11 O 19 , respectively. The variation in thermal conductivity with Sr 2+ and Ti 4+ fractions was analyzed based on structure information provided by X-ray diffraction and Raman spectroscopy. The average crystal size of LaMgAl 11 O 19 sintered at 1600°C for 10 min by spark plasma sintering is in nanoscale. The fully dense La 1− x Sr x MgAl 11− x Ti x O 19 solid solution showed a minimum thermal conductivity value (λ = 1.12 W/(m K) −1 , T  = 1273 K) at the composition of La 0.5 Sr 0.5 MgAl 10.5 Ti 0.5 O 19 ,which possibly reduces from the enhanced phonon scattering due to mass and strain fluctuations at the Ln 3+ and B 3+ sites.

Beschreibung: Aqueous 3Y-TZP inks with solid contents of 22 and 27 vol% were used for fabricating three-dimensional ceramic components by the direct ink-jet printing process (DIP). The DIP fabrication was realized using a thermal ink-jet (TIJ) printing system. Despite the different physical properties of the inks, both inks were successfully ejected and deposited. To define the optimum window of the ink properties required for a stable printing operation, both ceramic inks as well as a typical TIJ ink were characterized in terms of particle size distribution, zeta potential, viscosity, surface tension, and the inverse Ohnesorge number ( Oh −1 ). Moreover, single drops of all inks were deposited and analyzed by scanning electron microscopy (SEM) to examine the form and integrity of the ejected drops. Demonstration objects (a base with curved channels and a sample molar tooth) were DIP fabricated using both of the ceramic inks. These objects show the potentials of the DIP process for ceramics manufacturing particularly by using TIJ printing systems.

Beschreibung: Spherical granules of aluminum nitride (AlN) with an average particle size of about 50 μm were produced from aqueous suspensions using an AlN powder surface treated against hydrolysis with aluminum dihydrogenphosphate [Al(H 2 PO 4 ) 3 ]. Two different amounts of Al(H 2 PO 4 ) 3 were tested and the effects of surface treatment and aging time were evaluated by various techniques (XRD, TG-DTA, zeta potential and pH measurements). The treated powder exhibited antihydrolytic property and good dispersing behavior, enabling the preparation of low-viscosity and high-concentration aqueous AlN slurries for freeze granulation. The spherical AlN granules were sintered in a boron nitride (BN) powder bed followed by ultrasonic washing of the AlN granulates/BN mixture to remove BN. The sintered spherical AlN granules present excellent crystallinity and high sphericity as observed from SEM micrographs.

Beschreibung: Near-infrared (NIR) quantum cutting involving the emission of two NIR photons for each visible photon absorbed is realized from Eu 2+ /Yb 3+ codoped chalcohalide glasses. Excitation, emission and decay spectra are measured to prove the occurrence of cooperative energy transfer (ET) from Eu 2+ to Yb 3+ . The maximum ET efficiency obtained is as high as 85%. The ET from Eu 2+ to Yb 3+ is followed by dipole-dipole interaction. The possible mechanism of ET is discussed.

Beschreibung: Well-crystallized pure BiFeO 3 nanopowders were successfully synthesized at the temperature as low as 120°C by an ethanol-assisted hydrothermal process. In this synthesis, the composition of the solvent played important roles in the formation of pure BiFeO 3 . The BiFeO 3 nanopowders synthesized with 4:3 ethanol/water ratio mainly consists of cubic structures with size from 50 to 150 nm. Zero-field-cooled (ZFC) and field-cooled (FC) magnetization measurements indicated that pure BiFeO 3 nanopowders showed a spin-glass transition below the freezing temperature. Moreover, the BiFeO 3 nanopowders exhibited ferromagnetic order at room temperature.

Beschreibung: Nanoparticles of Co 0.6 Zn 0.4 Fe 2 O 4 , with narrow size distribution, regular morphology, and high saturation magnetization, have been synthesized. The synthesis, involved a very rapid mixing of reducible metal cations with sodium borohydride, is carried out in a colloid mill and followed by a separate hydrothermal process. The microstructure and magnetic properties of the synthesized nanoparticles are characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and vibrating sample magnetometer (VSM). The effects of different synthesis conditions (synthesis temperature and reaction time) on the characteristics of the ferrite nanoparticles are discussed. The changes in cation contribution are revealed by the Raman study. The magnetic measurements explore that all the as-synthesized samples are superparamagnetic in nature. The corresponding superparamagnetic behavior is explained by paramagnetic Langevin theory. Note that, the superparamagnetic Co 0.6 Zn 0.4 Fe 2 O 4 ferrite nanoparticle, with excellent performance, can be synthesized at 160°C for a short reaction time (4 h).

Beschreibung: We show that multilayer green tapes constituted from sandwiched layers of NiO–zirconia anode and cubic zirconia electrolyte can be sintered below 1000°C in a few seconds under the influence of a DC electric field. The sintering yields a dense electrolyte layer with minor closed porosity, and an anode layer with open porosity, and, most importantly, a multilayer that is largely devoid of defects and delamination.