Publication Date:
2016-07-15
Description:
Selective recovery of lithium from four kinds of cathode materials, manganese-type, cobalt-type, nickel-type, and ternary-type, of spent lithium ion battery was investigated. In all cathode materials, leaching of lithium was improved by adding sodium persulfate (Na 2 S 2 O 8 ) as an oxidant in the leaching solution, while the leaching of other metal ions (manganese, cobalt, and nickel) was significantly suppressed. Optimum leaching conditions, such as pH, temperature, amount of Na 2 S 2 O 8 , and solid/liquid ratio, for the selective leaching of lithium were determined for all cathode materials. Recovery of lithium from the leachate as lithium carbonate (Li 2 CO 3 ) was then successfully achieved by adding sodium carbonate (Na 2 CO 3 ) to the leachate. Optimum recovery conditions, such as pH, temperature, and amount of Na 2 CO 3 , for the recovery of lithium as Li 2 CO 3 were determined for all cases. Purification of Li 2 CO 3 was achieved by lixiviation in all systems, with purities of the Li 2 CO 3 higher than 99.4%, which is almost satisfactory for the battery-grade purity of lithium.
Print ISSN:
1047-4838
Electronic ISSN:
1543-1851
Topics:
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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