ALBERT

Description: Field relationships and structural studies combined with in situ U–Th–Pb dating of monazite from Las Chacritas pluton (LCP), Sierra de Humaya, provide insight into the emplacement of peraluminous magmas triggered by lateral shortening of the host rock and magmatic stoping at a mid-crustal level of a retro-arc zone in a convergent orogen. Modal and chemical compositions indicate that the LCP is composed of two main igneous units of peraluminous granitoids. The predominant two-mica granitoids were generated by interaction of crustal rocks with mafic or mafic-derived magmas and/or crystal-rich magmas that entrained residual phases, whereas less abundant leucocratic granitoids may have been originated by partial melting of metasedimentary rocks. The calculated crystallization age of 474 ± 4 Ma is consistent with Ordovician ages (477–470 Ma) of the high-grade metamorphic rocks, indicating concomitant magmatism and metamorphism during the Famatinian orogeny. The LCP was emplaced in the middle crust at a maximum depth of ~14.5 km, where attendant fracturing and ductile deformation were active. Field evidence shows strong temporal and spatial relationships between host rock ductile deformation and the emplacement of the pluton such as folding and strike deflection of the host rock layering and folded concordant leucocratic sheets with magmatic fabrics. This suggests that material transfer processes like lateral wall rock displacement (lateral shortening) was a viable mechanism for the emplacement of the LCP. However, cross-sectional restoration and field evidence such as wall rock xenoliths and intrusive truncations of the host rock foliation and fold traces suggest that magmatic stoping was a complementary mechanism to create the necessary space for the emplacement of the LCP. This work supports previous studies showing that participation of multiple material transfer processes are the rule rather than the exception in the emplacement of plutons.

Description: The Alanya Massif, which is located to the south of central Taurides in Turkey, presents a typical nappe pile consisting of thrust sheets with contrasting metamorphic histories. In two thrust sheets, Sugözü and Gündoğmuş nappes, HP metamorphism under eclogite (550–567 °C/14–18 kbar) and blueschist facies (435–480 °C/11–13 kbar) conditions have been recognized, respectively. Whereas the rest of the Massif underwent MP metamorphism under greenschist to amphibolite facies (525–555 °C/6.5–7.5 kbar) conditions. Eclogite facies metamorphism in Sugözü nappe, which consists of homogeneous garnet–glaucophane–phengite schists with eclogite lenses is dated at 84.8 ± 0.8, 84.7 ± 1.5 and 82 ± 3 Ma (Santonian–Campanian) by 40 Ar/ 39 Ar phengite, U/Pb zircon and rutile dating methods, respectively. Similarly, phengites in Gündoğmuş nappe representing an accretionary complex yield 82–80 Ma (Campanian) ages for blueschist facies metamorphism. During the exhumation, the retrograde overprint of the HP units under greenschist–amphibolite facies conditions and tectonic juxtaposition with the Barrovian units occurred during Campanian (75–78 Ma). Petrological and geochronological data clearly indicate a similar Late Cretaceous tectonometamorphic evolution for both Alanya (84–75 Ma) and Bitlis (84–72 Ma) Massifs. They form part of a single continental sliver ( Alanya – Bitlis microcontinent ), which was rifted from the southern part of the Anatolide–Tauride platform. The P – T – t coherence between two Massifs suggests that both Massifs have been derived from the closure of the same ocean ( Alanya – Bitlis Ocean ) located to the south of the Anatolide–Tauride block by a northward subduction. The boundary separating the autochthonous Tauride platform to the north from both the Alanya and Bitlis Massifs to the south represents a suture zone, the Pamphylian – Alanya – Bitlis suture .

Description: The Indosinian orogeny is recorded by Triassic angular unconformities in Vietnam and South China and by widely occurring granitoids in the Yunkai-Nanling and the Xuefengshan belts of South China. The Longtan pluton in the northwestern part of the Xuefengshan belt is a typical high-K, calc-alkaline, I-type granitoid, which can shed light on the relationship between the Indosinian tectonic and magmatic activity in the region. Three precise zircon U–Pb ages yielded a mean of 218 ± 0.8 Ma, which is taken as the age of crystallization. The pluton consists of both granodiorite (64.59–68.01 % SiO 2 and 3.25–4.22 % K 2 O) and granite (70.49–71.80 % SiO 2 and 4.07–4.70 % K 2 O). The granodiorites are characterized by relatively high Mg# (54–57), low contents of Na 2 O (3.2–4.3 wt%), low abundances of incompatible elements (LILE, Nb and P), high initial 87 Sr/ 86 Sr (0.7175–0.7184) and negative ε Nd ( t ) (−9.98 to −9.72). REE patterns show moderate fractionation ((La/Yb) cn  = 8.07–18.80) with negative Eu anomalies (Eu/Eu* = 0.62–0.86). Compared with the granodiorite, the granite has a wider range of Mg# (49–59), lower contents of Na 2 O (2.8–4.2 wt%), higher initial 87 Sr/ 86 Sr (0.7232–0.7243) and more negative ε Nd ( t ) (−12.07 to −11.24) values. REE patterns are relatively flat ((La/Yb) cn  = 14.73–29.37) with smaller negative Eu anomalies (Eu/Eu* = 0.48–0.63). The granodiorite has lower K 2 O/Na 2 O and Al 2 O 3 /(MgO + FeO Tot ) values than the granite. Based on major and trace element geochemistry and Sr–Nd isotopes, we interpret the Longtan granodioritic magma to have been derived by partial melting of interlayered Proterozoic metabasaltic to metatonalitic source rocks, whereas the granite was probably derived from a mixture of Proterozoic metagraywackes and metaigneous rocks. Field, petrographic and geochemical evidence indicate that partial melting and fractional crystallization were the dominant mechanism in the evolution of the pluton. The Longtan granodiorites and granites are petrologically and geochemically similar to typical Indosinian varieties and are considered to have been produced in a similar manner. The Indosinian granitoids in the region show a magmatic peak age of ~238 Ma from the Yunkai-Nanling belt in the southeast and a magmatic peak age of ~218 Ma of the Xuefengshan belt to the northwest. These early and late magmatic episodes of the Indosinian granitoids also display slight variations of regular compositions, ε Nd ( t ) values and T DM ages. Thus, we propose a syncollisional extension model that Indosinian granitoids were generated by decompressional partial melting of crustal materials triggered by two extensions during collision of the Indochina and South China blocks. The Longtan pluton in the northwesternmost part of the orogenic belt marks the termination of the Indosinian magmatism and orogenesis.

Description: The granitoids and related polymetallic mineralization in the Zhejiang Province at the southeast margin of the Yangtze Block in China provide an important window to evaluate metallogeny associated with convergent margin magmatism. Here, we present geochronological, geochemical, and isotopic data from the granitic rocks of west Zhejiang, to constrain the timing of transformation of the tectonic setting of this region from volcanic arc to intra-plate during Late Mesozoic and its bearing on regional metallogeny. The granitic rocks in west Zhejiang can be geochemically subdivided into two groups. The first group is characterized by relatively steep rare earth element (REE) patterns with slight Eu anomalies, high Sr, low Yb, and negative Nb–Ta–Ti (NTT) anomalies, indicating a volcanic arc environment with a thickened crust in a convergent setting. The second group is featured by flat REE patterns with prominent negative Eu anomalies, low Sr, high Yb, and weak NTT anomalies, suggesting an intra-plate extensional environment with a thin crust. The geochronology of granitic rocks in west Zhejiang, combined with ages of regional tectonic basins and nappe structures, constrains the timing of the tectonic transformation to be in the range from 150 to 140 Ma. Sr–Nd isotopic data and a positive correlation displayed by oxygen fugacity ( f O 2 ), and La/Sm and Ba/Th ratios (proxies of subducted sediments and slab dehydration fluids) suggest that the high oxygen fugacity is probably related to the melting of subducted sediments and slab dehydration. From 180 to 80 Ma, due to the increasing dip angle of the subducted Izanagi Plate, the volcanic arc belt migrated oceanward, leaving most of the interior of Zhejiang Province under an intra-plate environment where insufficient subducted components and upwelling mantle generated reduced magmas which were not favorable for Cu–Mo mineralization. Our model provides a plausible explanation for the absence of Cu–Mo porphyry deposits in the adjacent region of Zhejiang, Jiangxi, and Anhui provinces (Zhe-Gan-Wan region) after 140 Ma.

Description: The Northern Tyrrhenian Sea is located on the collisional zone between the Alpine Corsica and the Northern Apennines and is a key area for gaining a better understanding of the complex relationships between these two systems. The knowledge of the wide offshore part of this zone, located between Corsica (France) and mainland Italy, is based primarily on the analysis of several seismic profiles tied to the outcropping geology and unpublished preliminary reports of few offshore wells. The here presented study of two offshore wells provides a revision of the sedimentology, biostratigraphy and petrography of the thick, mainly siliciclastic, Tertiary successions (about 3,600 m) composing the Elba–Pianosa Ridge (EPR), a structural/morphological high separating the Tuscan Shelf to the east from the Corsica Basin to the west. A comparison with similar deposits cropping out in the surrounding onshore areas (Northern Apennines, Corsica, Tuscan Archipelago, Piedmont Tertiary Basin) provides additional constraints for refinement of the complex geodynamic and regional setting in which the EPR evolved.

Description: The Cameros Basin is a part of the Mesozoic Iberian Rift. It is an extensional basin formed during the late Jurassic and early Cretaceous, in the Mesozoic Iberian Rift context, and it was inverted in the Cenozoic as a result of the Alpine contraction. This work aims to reconstruct the tectono-stratigraphic evolution of the basin during the Mesozoic, using new and revised field, geophysical and subsurface data. The construction of a basin-wide balanced section with partial restorations herein offers new insights into the geometry of the syn-rift deposits. Field data, seismic lines and oil well data were used to identify the main structures of the basin and the basin-forming mechanisms. Mapping and cross-sectional data indicate the marked thickness variation of the depositional sequences across the basin, suggesting that the extension of the depositional area varied during the syn-rift stage and that the depocentres migrated towards the north. From field observation and seismic line interpretation, an onlap of the depositional sequences to the north, over the marine Jurassic substratum, can be deduced. In the last few decades, the structure and geometry of the basin have been strongly debated. The structure and geometry of the basin infill reconstructed herein strongly support the interpretation of the Cameros Basin as an extensional-ramp synclinal basin formed on a blind south-dipping extensional ramp. The gradual hanging-wall displacement to the south shifted the depocentres to the north over time, thus increasing the basin in size northwards, with onlap geometry on the pre-rift substratum. The basin was inverted by means of a main thrust located in a detachment located in the Upper Triassic beds (Keuper), which branched in depth with the Mesozoic extensional fault flat. The reconstruction of the tectono-stratigraphic evolution of the Cameros Basin proposed herein represents a synthesis and an integration of previous studies of the structure and geometry of the basin. This study can be used as the basis for future basin-scale research and for modelling the ancient petroleum system of the basin.

Description: From salt mine galleries and well data it is known that thick rock salt layers can contain anhydrite and carbonate layers with thicknesses on the millimetre to tens of metre scale. The relatively thick Zechstein 3 anhydrite–carbonate layer in the northern Netherlands has been studied previously using 3-D seismic data. Observations from geophysical well logs in this study reveal the presence of thin sulphate layers on the sub-seismic scale imbedded in the Zechstein 2 (Z2) salt. Core samples, thin sections, seismic data and geochemical measurements were used to determine the mineralogy and origin of one of these Z2 sulphate layers. Bromine analyses show that they mark a freshening event in the Z2 salt, which can be correlated over large distances in the northern Netherlands. Their core-calibrated log signature indicates that the Z2 sulphate layers consist either of pure anhydrite or of anhydrite and polyhalite. The mineralogy and thickness of the sulphate layers are interpreted to vary between synsedimentary morphologic lows (thin anhydrite–polyhalite couplets) and highs (thicker anhydrite layers). Such a combination of core observations and well log analysis is a powerful tool to detect lateral trends in evaporite mineralogy and to reconstruct the environmental setting of their formation. Salt internal geometries can further be used to distinguish between different deformation mechanisms. In our study area, the distribution of sulphate layers within the Z2 salt indicates that subjacent salt dissolution was not the dominant process leading to salt-related deformation.

Description: After more than a decade of multidisciplinary studies of the Central American subduction zone mainly in the framework of two large research programmes, the US MARGINS program and the German Collaborative Research Center SFB 574, we here review and interpret the data pertinent to quantify the cycling of mineral-bound volatiles (H 2 O, CO 2 , Cl, S) through this subduction system. For input-flux calculations, we divide the Middle America Trench into four segments differing in convergence rate and slab lithological profiles, use the latest evidence for mantle serpentinization of the Cocos slab approaching the trench, and for the first time explicitly include subduction erosion of forearc basement. Resulting input fluxes are 40–62 (53) Tg/Ma/m H 2 O, 7.8–11.4 (9.3) Tg/Ma/m CO 2 , 1.3–1.9 (1.6) Tg/Ma/m Cl, and 1.3–2.1 (1.6) Tg/Ma/m S (bracketed are mean values for entire trench length). Output by cold seeps on the forearc amounts to 0.625–1.25 Tg/Ma/m H 2 O partly derived from the slab sediments as determined by geochemical analyses of fluids and carbonates. The major volatile output occurs at the Central American volcanic arc that is divided into ten arc segments by dextral strike-slip tectonics. Based on volcanic edifice and widespread tephra volumes as well as calculated parental magma masses needed to form observed evolved compositions, we determine long-term (10 5 years) average magma and K 2 O fluxes for each of the ten segments as 32–242 (106) Tg/Ma/m magma and 0.28–2.91 (1.38) Tg/Ma/m K 2 O (bracketed are mean values for entire Central American volcanic arc length). Volatile/K 2 O concentration ratios derived from melt inclusion analyses and petrologic modelling then allow to calculate volatile fluxes as 1.02–14.3 (6.2) Tg/Ma/m H 2 O, 0.02–0.45 (0.17) Tg/Ma/m CO 2 , and 0.07–0.34 (0.22) Tg/Ma/m Cl. The same approach yields long-term sulfur fluxes of 0.12–1.08 (0.54) Tg/Ma/m while present-day open-vent SO 2 -flux monitoring yields 0.06–2.37 (0.83) Tg/Ma/m S. Input–output comparisons show that the arc water fluxes only account for up to 40 % of the input even if we include an “invisible” plutonic component constrained by crustal growth. With 20–30 % of the H 2 O input transferred into the deeper mantle as suggested by petrologic modeling, there remains a deficiency of, say, 30–40 % in the water budget. At least some of this water is transferred into two upper-plate regions of low seismic velocity and electrical resistivity whose sizes vary along arc: one region widely envelopes the melt ascent paths from slab top to arc and the other extends obliquely from the slab below the forearc to below the arc. Whether these reservoirs are transient or steady remains unknown.

Description: The volcano Cotopaxi in South America is 5,897 m high and is one of the highest active volcanoes of the world and the second highest volcano in the Andes after the Chimborazo (6,310 m). In Ecuador, there are more than 20 volcanoes contributing to the spectacular mountain range diving this country between the western and eastern lowlands. There have been more than 50 reports of volcanic activity at Cotopaxi since 1738, among which those from the years 1744, 1768, and 1877 are the largest. During the 1877 eruption, the whole summit glacier collapsed and a huge mudflow spread out for more than 100 km and flooded the city of Latacunga. Five years prior to this catastrophic event, the German geologist Wilhelm Reiss from the University of Heidelberg ascended Cotopaxi for the first time together with his supporter Angel M. Escobar from Columbia.

Description: Clinopyroxenes in some fresh anhydrous spinel peridotite mantle xenoliths from the northern Massif Central (France) and Lower Silesia (Poland), analysed for a range of incompatible trace elements by laser ablation inductively coupled plasma mass spectrometry, show unusually strong negative anomalies in Hf and Zr relative to adjacent elements Sm and Nd, on primitive mantle-normalised diagrams. Similar Zr–Hf anomalies have only rarely been reported from clinopyroxene in spinel peridotite mantle xenoliths worldwide, and most are not as strong as the examples reported here. Low Hf contents give rise to a wide range of Lu/Hf ratios, which over geological time would result in highly radiogenic εHf values, decoupling them from εNd ratios. The high 176 Lu/ 177 Hf could in theory produce an isochronous relationship with 176 Hf/ 177 Hf over time; an errorchron is shown by clinopyroxene from mantle xenoliths from the northern Massif Central. However, in a review of the literature, we show that most mantle spinel peridotites do not show such high Lu/Hf ratios in their constituent clinopyroxenes, because they lack the distinctive Zr–Hf anomaly, and this limits the usefulness of the application of the Lu–Hf system of dating to garnet-free mantle rocks. Nevertheless, some mantle xenoliths from Poland or the Czech Republic may be amenable to Hf-isotope dating in the future.

Description: The surface sediments of two mud mounds (“Mound 11” and “Mound 12”) offshore southwest Costa Rica contain abundant authigenic carbonate concretions dominated by high-Mg calcite (14–20 mol-% MgCO 3 ). Pore fluid geochemical profiles (sulfate, sulfide, methane, alkalinity, Ca and Mg) indicate recent carbonate precipitation within the zone of anaerobic oxidation of methane (AOM) at variable depths. The current location of the authigenic carbonate concretions is, however, not related to the present location of the AOM zone, suggesting mineral precipitation under past geochemical conditions as well as changes in the flow rates of upward migrating fluids. Stable oxygen and carbon isotope analysis of authigenic carbonate concretions yielded δ 18 O carbonate values ranging between 34.0 and 37.7 ‰ Vienna standard mean ocean water (VSMOW) and δ 13 C carbonate values from −52.2 to −14.2 ‰ Vienna Pee Dee belemnite (VPDB). Assuming that no temperature changes occurred during mineral formation, the authigenic carbonate concretions have been formed at in situ temperature of 4–5 °C. The δ 18 O carbonate values suggest mineral formation from seawater-derived pore fluid (δ 18 O porefluid  = 0 ‰ VSMOW) for Mound 12 carbonate concretions but also the presence of an emanating diagenetic fluid (δ 18 O porefluid  ≈5 ‰) in Mound 11. A positive correlation between δ 13 C carbonate and δ 18 O carbonate is observed, indicating the admixing of two different sources of dissolved carbon and oxygen in the sediments of the two mounds. The carbon of these sources are (1) marine bicarbonate (δ 13 C porefluid  ≈0 ‰) and (2) bicarbonate which formed during the AOM (δ 13 C porefluid  ≈−70 ‰). Furthermore, the δ 18 O porefluid composition, with values up to +4.7 ‰ Vienna standard mean ocean water (VSMOW), is interpreted to be affected by the presence of emanating, freshened and boron-enriched fluids. Earlier, it has been shown that the origin of 18 O-enriched fluids are deep diagenetic processes as it was indicated by the presence of methane with thermogenic signature (δ 13 C CH4  = −38 ‰). A combination of present geochemical data with geophysical observations indicates that Mounds 11 and 12 represent a single fluid system interconnected by deep-seated fault(s).

Description: The nitrogen concentrations [N] and isotopic compositions of ultramafic mantle rocks that represent various dehydration stages and metamorphic conditions during the subduction cycle were investigated to assess the role of such rocks in deep-Earth N cycling. The samples analyzed record low-grade serpentinization on the seafloor and/or in the forearc wedge (low-grade serpentinites from Monte Nero/Italy and Erro Tobbio/Italy) and two successive stages of metamorphic dehydration at increasing pressures and temperatures (high-pressure (HP) serpentinites from Erro Tobbio/Italy and chlorite harzburgites from Cerro del Almirez/Spain) to allow for the determination of dehydration effects in ultramafic rocks on the N budget. In low-grade serpentinites, δ 15 N air values (−3.8 to +3.5 ‰) and [N] (1.3–4.5 μg/g) are elevated compared to the pristine depleted MORB mantle (δ 15 N air  ~ −5 ‰, [N] = 0.27 ± 0.16 μg/g), indicating input from sedimentary organic sources, at the outer rise during slab bending and/or in the forearc mantle wedge during hydration by slab-derived fluids. Both HP serpentinites and chlorite harzburgites have δ 15 N air values and [N] overlapping with low-grade serpentinites, indicating no significant loss of N during metamorphic dehydration and retention of N to depths of 60–70 km. The best estimate for the δ 15 N air of ultramafic rocks recycled into the mantle is +3 ± 2 ‰. The global N subduction input flux in serpentinized oceanic mantle rocks was calculated as 2.3 × 10 8  mol N 2 /year, assuming a thickness of serpentinized slab mantle of 500 m. This is at least one order of magnitude smaller than the N fluxes calculated for sediments and altered oceanic crust. Calculated global input fluxes for a range of representative subducting sections of unmetamorphosed and HP-metamorphosed slabs, all incorporating serpentinized slab mantle, range from 1.1 × 10 10 to 3.9 × 10 10  mol N 2 /year. The best estimate for the δ 15 N air of the subducting slab is +4 ± 1 ‰, supporting models that invoke recycling of subducted N in mantle plumes and consistent with general models for the volatile evolution on Earth. Estimates of the efficiency of arc return of subducted N are complicated further by the possibility that mantle wedge hydrated in forearcs, then dragged to beneath volcanic fronts, is capable of conveying significant amounts of N to subarc depths.

Description: Here we present the first systematic investigation of volatile geochemistry along the Southern Volcanic Zone (SVZ) of Chile. Holocene olivine-hosted melt inclusions in the most mafic tephras sampled from 16 volcanoes along the volcanic front of the SVZ between 33°S and 43°S were analysed for pre-eruptive sulphur, chlorine, and major element contents. These results are combined with trace element compositions of the host whole rocks. The highest fractionation-corrected gas contents occur in the least-degassed melt inclusions from small monogenetic cones of Los Hornitos, Cabeza de Vaca, and Apagado from both the transitional and the southern-central SVZ, reaching ~3,000 μg/g S and 1,400 μg/g Cl, while the lowest abundances of ~1,100 μg/g S and ~600 μg/g Cl were found in the central SVZ at Volcán Lonquimay, Volcán Llaima, and Volcán Villarrica. Chlorine co-varies with trace element indicators for the degree of melting and/or source enrichment, such that the lowest Cl contents are found in high-degree melts from the most depleted mantle sources. The size of the volcanic edifices correlates inversely with Cl abundances in the melt. This could reflect more extensive degassing during ascent through the complex magma plumbing systems beneath the stratovolcanoes or greater dilution during larger degrees of melting of more depleted sources, or a combination of these factors. Compared to other subduction zones, the SVZ melt inclusions exhibit Cl and S abundances in the same range as most of those from the Central American and those from the Marianas arcs.

Description: Llaima and Villarrica are two of the most active volcanoes in the Chilean Southern Volcanic Zone and presently show contrasting types of activity. Llaima is a closed vent edifice with fumarolic activity, while Villarrica has an open vent with a lava lake, continuous degassing and tremor activity. This study is focused on characterizing the relationships between volcanic and seismic activity in the months before and after the 2010 M8.8 Maule earthquake, which was located in NNW direction from the volcanoes. Time series for tremors, long-period and volcano-tectonic events were obtained from the catalogue of the Volcanic Observatory of the Southern Andes (OVDAS) and from the SFB 574 temporary volcanic network. An increase in the amount of tremor activity, long-period events and degassing rates was observed at Villarrica weeks before the mainshock and continued at a high level also after it. This increase in activity is interpreted to be caused by enhanced magma influx at depth and may be unrelated to the Maule event. In Llaima, an increase in the volcano-tectonic activity was observed directly after the earthquake. The simultaneous post-earthquake activity at both volcanoes is consistent with a structural adjustment response. Since this enhanced activity lasted for more than a year, we suggest that it is related to a medium-term change in the static stress. Thus, the Maule earthquake may have affected both volcanoes, but did not trigger eruptions, from which we assume that none of the volcanoes were in a critical state.

Description: Characteristics of cold seeps at different geologic settings are the subject of this review primarily based on results of the Research Consortium SFB 574. Criteria are drawn from examples on the erosive convergent margin off Costa Rica, the accretionary margin off Chile supplemented by examples from the transform margin of the Golf of Cadiz and the convergent Hikurangi margin off New Zealand. Others are from well-studied passive margins of the Black Sea, the Golf of Mexico, the eastern Mediterranean Sea and the South China Sea. Seeps at all settings transport water and dissolved compounds to the ocean through the seafloor by different forcing mechanism and from different depths of the submerged geosphere (10s of meters to 10s of km). The compounds sustain oasis-type ecosystems by providing bioactive reductants sulfide, methane and hydrogen. Hereby, the interaction between fluid composition, flux rates and biota results in a diagnostic hydrocarbon–metazoan–microbe–carbonate association; currently, well over 100 active sites are known. The single most important reaction is microbially mediated anaerobic oxidation of methane with secondary reactions involving S-biogeochemistry and carbonate mineral precipitation. Seep fluids and their seafloor manifestations provide clues as to source depth, fluid–sediment/rock interaction during ascent, lifetime and cyclicity of seepage events but less so on the magnitude of return flow. At erosive margins, Cl-depleted and B-enriched fluids from clay dehydration provide criteria for source depth and temperature. The upward material flow generates mud volcanoes at the seafloor above the projected location of dehydration at depth. At accretionary margins, fluids are derived from more shallow depths by compaction of sediments as they ride on the incoming oceanic plate; they are emitted through thrust faults. At highly sedimented margins, organic-rich and evaporite-containing strata (when present) determine the final fluid composition, by emitting characteristically gas hydrate-derived methane, brine-associated non-methane hydrocarbons or leached elements and their isotopes (Li, δ 7 Li, B, Ba) from host sediments. Smectite–illite transformation and associated Cl-depletion from release of interlayer water is a pervasive process at these margins. Rare earth element pattern in conjunction with redox-sensitive metals retained in seep carbonates indicate whether or not they precipitated in contact with oxic bottom water or suboxic fluids; clear environmental characterization, though, currently remains inconclusive. More deeply sourced fluids as in transform margins may be characterized by their 87 Sr/ 86 Sr ratios from interaction with oceanic crustal rocks below. Quantification of flow and reliable estimates of total volatile output from fore-arcs remain a challenge to seep research, as does understanding the role of geologically derived methane in the global methane cycle.

Description: Subduction zones of continental, transitional, and oceanic settings, relative to the nature of the overriding plate, are compared in terms of trace element compositions of mafic to intermediate arc rocks, in order to evaluate the relationship between subduction parameters and the presence of subduction fluids. The continental Chilean Southern Volcanic Zone (SVZ) and the transitional to oceanic Central American Volcanic Arc (CAVA) show increasing degrees of melting with increasing involvement of slab fluids, as is typical for hydrous flux melting beneath arc volcanoes. At the SVZ, the central segment with the thinnest continental crust/lithosphere erupted the highest-degree melts from the most depleted sources, similar to the oceanic-like Nicaraguan segment of the CAVA. The northern part of the SVZ, located on the thickest continental crust/lithosphere, exhibits features more similar to Costa Rica situated on the Caribbean Large Igneous Province, with lower degrees of melting from more enriched source materials. The composition of the slab fluids is characteristic for each arc system, with a particularly pronounced enrichment in Pb at the SVZ and in Ba at the CAVA. A direct compositional relationship between the arc rocks and the corresponding marine sediments that are subducted at the trenches clearly shows that the compositional signature of the lavas erupted in the different arcs carries an inherited signal from the subducted sediments.

Description: The Central American isthmus hosts a highly variable Moho structure due to the diverse origin and composition of the crustal basement and the influence of large-scale neotectonic processes. Gravity data from the combined geopotential model EGM2008 were interpreted via forward modelling to outline the three-dimensional lithospheric density structure along the Middle American Trench, as well as the segmentation of the oceanic Cocos and Nazca plates and the overriding Caribbean plate. In this work, results for the depth of the Moho obtained from the density model are presented. The Quaternary volcanic arc correlates with a maximum Moho depth of 44 km in western Guatemala. To the south-east of the continental shelf, the Caribbean plate shows Moho depths between 20 and 12 km whereas to the north, values as shallow as 8 km are observed at the Cayman trough. For the oceanic Cocos plate, depths between 16 and 21 km are obtained for the Moho along the Cocos ridge, contrasting with values between 15 and 12 km for the seamount segment and 8 and 11 km for the segments of the crust that are not affected by the Galapagos hot-spot track.

Description: Methane (CH 4 ) concentrations and CH 4 stable carbon isotopic composition ( \( \delta^{13} {\text{C}}_{{{\text{CH}}_{4} }} \) ) were investigated in the water column within Jaco Scar. It is one of several scars formed by massive slides resulting from the subduction of seamounts offshore Costa Rica, a process that can open up structural and stratigraphical pathways for migrating CH 4 . The release of large amounts of CH 4 into the adjacent water column was discovered at the outcropping lowermost sedimentary sequence of the hanging wall in the northwest corner of Jaco Scar, where concentrations reached up to 1,500 nmol L −1 . There CH 4 -rich fluids seeping from the sedimentary sequence stimulate both growth and activity of a dense chemosynthetic community. Additional point sources supplying CH 4 at lower concentrations were identified in density layers above and below the main plume from light carbon isotope ratios. The injected CH 4 is most likely a mixture of microbial and thermogenic CH 4 as suggested by \( \delta^{13} {\text{C}}_{{{\text{CH}}_{4} }} \) values between −50 and −62 ‰ Vienna Pee Dee Belemnite. This CH 4 spreads along isopycnal surfaces throughout the whole area of the scar, and the concentrations decrease due to mixing with ocean water and microbial oxidation. The supply of CH 4 appears to be persistent as repeatedly high CH 4 concentrations were found within the scar over 6 years. The maximum CH 4 concentration and average excess CH 4 concentration at Jaco Scar indicate that CH 4 seepage from scars might be as significant as seepage from other tectonic structures in the marine realm. Hence, taking into account the global abundance of scars, such structures might constitute a substantial, hitherto unconsidered contribution to natural CH 4 sources at the seafloor.

Description: The lithostratigraphy of the Mekece–Iznik Corridor, the Geyve–Pamukova, and the Iznik basins on the southern branch of the North Anatolian Fault System (NAFS-SB) was investigated in detail. The intra-basin deposits carried by Sakarya River and the drainage systems in the northern and southern elevated blocks of the Iznik and Geyve–Pamukova Basins have been classified based on their lithofacies characteristics. The Geyve–Pamukova basin, which has developed with a NNE–SSW-trending transtensional strain, was formed as a lazy Z-shaped and releasing bend or pure strike-slip, pull-apart basin that is related to simple-shear, right-lateral strike-slip faulting. The Iznik basin was formed by a right-lateral strike-slip faulting kinematics and NNE–SSW-trending transtension as a result of the step-over of the northeast-trending Dırazali fault from the southern edge to the NW-trending Gürle fault, and the western step-over of this fault to the E–W-trending Umurbey fault. This strike-slip setting is also supported by the NW–SE-trending right-lateral oblique normal Orhangazi fault on the northern edge of the basin. According to this, the Iznik basin can be described as a more advanced stage of a large-scale, pull-apart basin compared with a lazy Z-shaped and releasing bend or transtensional strain. Furthermore, it is defined as the former stage of an extreme or rhomboid-type transtensional pull-apart basin.

Description: Seafloor methane emission from the Quepos Slide on the submarine segment of the Costa Rica fore-arc margin was estimated by extrapolating flux measurements from individual seeps to the total area covered by bacterial mats. This approach is based on the combination of detailed mapping to determine the abundance of seeps and the application of a numerical model to estimate the amount of benthic methane fluxes. Model results suggest that the majority of the studied seeps transport rather limited amount of methane (on average: ~177 μmol cm −2  a −1 ) into the water column due to moderate upward advection, allowing for intense anaerobic oxidation of methane (AOM; on average: 53 % of the methane flux is consumed). Depth-integrated AOM rates (56–1,538 μmol CH 4 cm −2  a −1 ) are comparable with values reported from other active seep sites. The overall amount of dissolved methane released into the water column from the entire area covered by bacterial mats on the Quepos Slide is estimated to be about 0.28 × 10 6  mol a −1 . This conservative estimate which relies on rather accurate determinations of seafloor methane fluxes emphasizes the potential importance of submarine slides as sites of natural methane seepage; however, at present the global extent of methane seepage from submarine slides is largely unknown.

Description: The Lonquimay volcanic complex (LVC) in the high Southern Andes comprises a stratocone and NE-trending flank-cone alignments. Numerous effusive and explosive volcanic eruptions characterize its post-glacial magmatic activity. Our tephrostratigraphic record, pre-dating the four historically documented eruptions, comprises 22 dated pyroclastic deposits that are used to constrain repose time distribution and eruption probability of the LVC magmatic system. Statistical examination of the stratigraphy-based eruption time series yields probabilities of 20–50 % for at least one explosive (VEI ≥ 3) eruption within the next 100 years as of 2011. The tephra deposits are subdivided into three petrographic groups: a felsic group (Lonquimay colored-pumice tephra, LCPT), an intermediate population (Lonquimay gray pumice tephra, LGPT), and a mafic member (Lonquimay dark scoria tephra, LDST). The distribution of these petrographic groups through the LVC tephrostratigraphy is linked to the observed changes in repose times. LDST-deposits as well as deposits compositionally zoned from LCPT to LGPT dominate the lower part of the stratigraphy for which recurrence times are short (RT mean  = 417 ± 169a). Deposits younger than 6,000 b2k (years before 2000 AD) have dominantly LCPT and minor LDST compositions, no longer contain LGPT, and repose times are significantly longer (RT mean  = 1,350 ± 310a). We interpret the change in eruption regime to result from a rearrangement in the magma storage and plumbing system. Thermobarometric calculations based on cpx–liquid equilibria and amphibole compositions reveal three distinct magma storage levels: the mafic LDST derive from mid crustal storage ( P mean  = 476 ± 95 MPa, T mean  = 1,073 ± 24 °C), felsic LCPT mainly erupted from upper-crustal level ( P mean  = 86 ± 49 MPa, T mean  = 936 ± 24 °C), whereas LGPT samples yield intermediate storage depths ( P mean  = 239 ± 100 MPa, T mean  = 1,013 ± 17 °C). Magma contributions from this intermediate reservoir are restricted to 〉6,000 b2k when the Lonquimay plumbing system was in a regime of short repose times; disappearance of the intermediate reservoir coincides with the change to longer repose times between eruptions.

Description: The continental shelf and slope of southern Central Chile have been subject to a number of international as well as Chilean research campaigns over the last 30 years. This work summarizes the geologic setting of the southern Central Chilean Continental shelf (33°S–43°S) using recently published geophysical, seismological, sedimentological and bio-geochemical data. Additionally, unpublished data such as reflection seismic profiles, swath bathymetry and observations on biota that allow further insights into the evolution of this continental platform are integrated. The outcome is an overview of the current knowledge about the geology of the southern Central Chilean shelf and upper slope. We observe both patches of reduced as well as high recent sedimentation on the shelf and upper slope, due to local redistribution of fluvial input, mainly governed by bottom currents and submarine canyons and highly productive upwelling zones. Shelf basins show highly variable thickness of Oligocene-Quaternary sedimentary units that are dissected by the marine continuations of upper plate faults known from land. Seismic velocity studies indicate that a paleo-accretionary complex that is sandwiched between the present, relatively small active accretionary prism and the continental crust forms the bulk of the continental margin of southern Central Chile.

Description: We present for the first time a self-consistent methodology connecting volcanological field data to global climate model estimates for a regional time series of explosive volcanic events. Using the petrologic method, we estimated SO 2 emissions from 36 detected Plinian volcanic eruptions occurring at the Central American Volcanic Arc (CAVA) during the past 200,000 years. Together with simple parametrized relationships collected from past studies, we derive estimates of global maximum volcanic aerosol optical depth (AOD) and radiative forcing (RF) describing the effect of each eruption on radiation reaching the Earth’s surface. In parallel, AOD and RF time series for selected CAVA eruptions are simulated with the global aerosol model MAECHAM5-HAM, which shows a relationship between stratospheric SO 2 injection and maximum global mean AOD that is linear for smaller volcanic eruptions (〈5 Mt SO 2 ) and nonlinear for larger ones (≥5 Mt SO 2 ) and is qualitatively and quantitatively consistent with the relationship used in the simple parametrized approximation. Potential climate impacts of the selected CAVA eruptions are estimated using an earth system model of intermediate complexity by RF time series derived by (1) directly from the global aerosol model and (2) from the simple parametrized approximation assuming a 12-month exponential decay of global AOD. We find that while the maximum AOD and RF values are consistent between the two methods, their temporal evolutions are significantly different. As a result, simulated global maximum temperature anomalies and the duration of the temperature response depend on which RF time series is used, varying between 2 and 3 K and 60 and 90 years for the largest eruption of the CAVA dataset. Comparing the recurrence time of eruptions, based on the CAVA dataset, with the duration of climate impacts, based on the model results, we conclude that cumulative impacts due to successive eruptions are unlikely. The methodology and results presented here can be used to calculate approximate volcanic forcings and potential climate impacts from sulfur emissions, sulfate aerosol or AOD data for any eruption that injects sulfur into the tropical stratosphere.

Description: The Berriasian Wealden Shale provides the favourable situation of possessing immature to overmature source rock intervals due to differential subsidence within the Lower Saxony Basin. Hydrocarbon generation kinetics and petroleum physical properties have been investigated on four immature Wealden Shale samples situated in different depth intervals and following the PhaseKinetics approach of di Primio and Horsfield (AAPG Bull 90(7):1031–1058, 2006 ). Kinetic parameters and phase prediction were applied to a thermally calibrated 1D model of the geodynamic evolution at the location of an overmature well. The immature source rocks of all depth intervals comprise kerogen type I being derived from the lacustrine algae Botryococcus braunii . Bulk kinetics of the lower three depth intervals (sample 2–4) can be described by one single activation energy  E a , typical for homogeneous, lacustrine organic matter (OM), whereas sample 1 from the uppermost interval shows a slightly broader E a distribution which hints to a more heterogeneous, less stable OM, but still of lacustrine origin. Predicted physical properties of the generated petroleum fluids are characteristic of variably waxy, black oil possessing GOR’s below 100 Sm 3 /Sm 3 and saturations pressures below 150 bar. Petroleum fluids from the more heterogeneous OM-containing sample 1 can always be described by slightly higher values. Based on the occurrence of paraffinic, free hydrocarbons in the uppermost horizon of the overmature well and gas/condensate in the lower 3 depth intervals, two scenarios have been discussed. From the first and least realistic scenario assuming no expulsion from the source rock, it can be deduced that phase separation in the course of uplift can only have occurred in the uppermost interval containing the slightly less stable OM but not in the lower intervals being composed of a more stable OM. Therefore and taking secondary cracking into account, all depth intervals should contain gas/condensate. The free hydrocarbons in the upper horizon are interpreted as impregnation from migrated hydrocarbons. The second scenario assumes nearly complete expulsion due to fracturing by the so-called generation overpressure (Mann et al. in Petroleum and basin evolution. Springer, Berlin, 1997 ). The expelled petroleum might migrate into lower pressurised source rock horizons and reach bubble-point pressures leading to the exsolution of gas and “precipitation” of very high molecular weight bitumen unable to migrate. Subsequent burial of the latter in the course of the basin evolution would lead to secondary cracking and remaining pyrobitumen explaining the high amounts of pyrobitumen in the overmature well Ex-B and relatively enhanced TOC contents at such high maturity levels.

Description: The physical and chemical evolution of the Earth is driven by geodynamic cycles that are global in scale, operating over 4.57 Ga of Earth’s history. Some processes are truly cyclic, e.g., the Wilson Cycle, while others are irreversible (e.g., core formation). Heat and mass transfer between the lowermost mantle (e.g., core-mantle boundary) and the surface drives these global geodynamic processes. Subduction of lithospheric plates transfers cool fractionated material into the lower mantle and leads indirectly to the formation of new oceanic lithosphere, while the rise of thermochemical plumes recycles the remnants of these plates back to the surface, driven by heat transfer across the core–mantle boundary. These global geodynamic cycles are responsible for hotspot volcanism, the formation of continental crust, collisional orogenies, continental rifting, subduction zone processes (arcs, accretionary prisms), and ore deposits. Each of these presents opportunities for investigation by continental scientific drilling. In addition, these cycles affect other processes that are targets of continental scientific drilling: the origin and evolution of life and an oxygenated atmosphere, the impact of large volcanic eruptions on climate, and geological hazards such as earthquakes and volcanic eruptions. In this paper, we present the scientific rationale for continental scientific drilling to study global geodynamic processes, review past successes in this realm that were sponsored in part by ICDP, and suggest potential new targets for drilling campaigns that focus on solid earth evolution. This paper builds on discussions at the 2013 ICDP Science Meeting on the future of continental scientific drilling, held in Potsdam in November 2013.

Description: A deep drilling campaign was performed at Lake Van (Turkey) to enhance the understanding of the paleoenvironmental conditions of the Middle East. Cores were collected, and the sediments are mainly composed of clayey silts and tephra deposits. Spectral gamma ray data were acquired (0–210 m below lake floor), and the uranium data were used for cyclostratigraphic studies to estimate the sedimentation rates and the time of deposition. Detection and analysis of climate cycles require continuous sedimentation and cannot be applied to these sediments which include numerous tephra layers. Therefore, these layers were removed, and a synthetic log was created (cumulative thickness of the tephra ≈50 m; remaining lacustrine sediments ≈160 m). High amplitudes were detected and correlated to Milanković cycles. Their evolution was analyzed using the sliding window technique. The sedimentation rates varied from 22 to 33 cm/ka in the upper section. The sediments between the lake floor and a depth of 210 m were deposited over a period of 587 ka. Our results agree with core interpretations (e.g., correlation of total organic carbon with marine isotope stages) which suggest a time span of deposition of 600 ka. High-frequency cycles were detected and correlated with interstadials from the North Greenland δ 18 O record for the past 75 ka. The two datasets agreed closely. We conclude that climate signals, even on sub-Milanković scale, are imprinted in uranium of these sediments, and cyclostratigraphic methods are applicable if event layers are subtracted from the sediment record.

Description: The Kashafrud Formation was deposited in the extensional Kopeh-Dagh Basin during the Late Bajocian to Bathonian (Middle Jurassic) and is potentially the most important siliciclastic unit from NE Iran for petroleum geology. This extensional setting allowed the accumulation of about 1,700 m of siliciclastic sediments during a limited period of time (Upper Bajocian–Bathonian). Here, we present a detailed facies analysis combined with magnetic susceptibility (MS) results focusing on the exceptional record of the Pol-e-Gazi section in the southeastern part of the basin. MS is classically interpreted as related to the amount of detrital input. The amount of these detrital inputs and then the MS being classically influenced by sea-level changes, climate changes and tectonic activity. Facies analysis reveals that the studied rocks were deposited in shallow marine, slope to pro-delta settings. A major transgressive–regressive cycle is recorded in this formation, including fluvial-dominated delta to turbiditic pro-delta settings (transgressive phase), followed by siliciclastic to mixed siliciclastic and carbonate shoreface rocks (regressive phase). During the transgressive phase, hyperpycnal currents were feeding the basin. These hyperpycnal currents are interpreted as related to important tectonic variations, in relation to significant uplift of the hinterland during opening of the basin. This tectonic activity was responsible for stronger erosion, providing a higher amount of siliciclastic input into the basin, leading to a high MS signal. During the regressive phase, the tectonic activity strongly decreased. Furthermore, the depositional setting changed to a wave- to tide-dominated, mixed carbonate–siliciclastic setting. Because of the absence of strong tectonic variations, bulk MS was controlled by other factors such as sea-level and climatic changes. Fluctuations in carbonate production, possibly related to sea-level variations, influenced the MS of the siliciclastic/carbonate cycles. Carbonate intervals are characterized by a strong decrease of MS values indicates a gradual reduction of detrital influx. Therefore, the intensity of tectonic movement is thought to be the dominant factor in controlling sediment supply, changes in accommodation space and modes of deposition throughout the Middle Jurassic sedimentary succession in the Pol-e-Gazi section and possibly in the Kopeh-Dagh Basin in general.

Description: The Borborema Province is the western part of a major Brasiliano belt that extends from Brazil through NW Africa in pre-drift reconstructions. This province resulted from convergence and collision among the West African, Congo-São Francisco, and Amazonian cratons about 600 Ma. This study focuses on the Pernambuco–Alagoas (PEAL) domain, which is a complex of magmatic, migmatitic, and metamorphic rocks, located in the southern part of the Borborema Province. U–Pb geochronology and Sm–Nd data for metasedimentary sequences (Rio Una, Inhapi) of the PEAL domain and a sample from a sequence of the Transversal Zone domain suggest that their deposition occurred during a Cryogenian extensional event, within the interval 850–631 Ma (or slightly younger). This extensional event occurred in the PEAL, Transversal Zone, and Sergipano domains before the onset of the Brasiliano collision and was followed by syn- and post-collisional magmatism. The Rio Una sequence and the sequence from Transversal Zone domain were deposited over a Rhyacian (ca. 2.0–2.2) basement having a juvenile Palaeoproterozoic Nd signature, whereas the Inhapi sequence was deposited over an Early Neoproterozoic (Tonian) basement. The deposition of the studied sequences is coeval with metasedimentary sequences to the north and south in other domains of the Borborema Province. However, differences in Nd isotopic signatures between the sequences from PEAL, Transversal Zone, and Sergipano domains suggest that they were formed in distinct basins. Metasedimentary sequences from the PEAL domain have Meso- and Palaeoproterozoic T DM model ages. These data suggest that the orogens where the metasedimentary sequences are located have a strong ensialic component. T DM model ages of ca. 1.0 Ga and εNd (0.6 Ga) values around zero recorded in granites from the southern part of the PEAL, suggesting that juvenile material was accreted to the southern part of the PEAL domain crust during the Tonian. The migmatites from the PEAL domain have a wide range of T DM ages along with a wide range of εNd (0.6 Ga) values. The transition between the northern and southern parts of the PEAL domain denotes the approximate northern margin of a Late Mesoproterozoic to Early Neoproterozoic rift.

Description: A fault system southeast of Eisenstadt was investigated with high-resolution geophysics using electric resistivity tomography, seismics and gravimetry. The St. Margarethen Fault separates the Neogene succession of the Eisenstadt Basin from the north south-trending Rust Range, which belongs to the Austroalpine frame. The interpretation of profiles down to a depth of 350 m derived from reflection and refraction seismics combined with the density model along the Oslip road section clearly reveals a listric fault, which dips westward towards the Eisenstadt Basin. Bed thickness of growth-strata regularly increases from west to east, and normal fault drags visible in the seismic profile west of the St. Margarethen Fault allow for interpreting this structure as a hanging-wall syncline. Thickness distribution of Neogene deposits reveals that the Eisenstadt Basin can be interpreted as a half-graben bounded by the listric St. Margarethen normal fault, which developed at the western flank of Rust Range. The subsidence of the Eisenstadt Basin during Lower to Middle Sarmatian times was accompanied by concurrent updoming of the Rust Range of at least 70 m. For the mechanism of the updoming of the Rust Range footwall uplift during hanging wall subsidence is inferred.

Description: Retrogressed eclogites are hosted within the Variscan low- to medium-grade metamorphic complex near Giuncana, north-central Sardinia. These rocks are medium to fine grained with garnet and amphibole as the most abundant mineral phases along with clinopyroxene, plagioclase, quartz, biotite, chlorite, epidote, ilmenite, rutile and titanite. Four stages of mineralogical re-equilibration have been distinguished. The stage I is characterized by the occurrence of omphacite, epidote, quartz, amphibole, rutile and ilmenite in garnet poikiloblasts. The stage II is characterized by two types of symplectitic microstructures: (1) amphibole + quartz symplectite and (2) clinopyroxene + plagioclase ± amphibole symplectite. The first symplectite type replaces omphacite included in garnet, whereas the second one is widespread in the matrix. Biotite droplets and/or lamellae intimately growing with fine-grained plagioclase resemble biotite + plagioclase symplectite after phengite. The stage III is characterized by the widespread formation of amphibole: (1) as zoned porphyroblasts in the matrix, (2) as corona-type microstructure replacing garnet. Subordinate plagioclase (oligoclase) is also present in the amphibole corona. The stage IV is characterized by the local formation of biotite replacing garnet, actinolite, chlorite, albite and titanite. P – T pseudosections calculated with Perple_X give P – T conditions 580 〈  T  〈 660 °C, 1.3 〈  P  〈 1.8 GPa for the stage I. After the stage I, pressure decrease and temperature increase led to the breakdown of omphacite with the formation of clinopyroxene + plagioclase ± amphibole symplectite at ~1.25–1.40 GPa and 650–710 °C (stage II). P – T conditions of the amphibolite-facies stage III have been defined at 600–670 °C, P  = 0.65–0.95 GPa. P – T conditions of the latest stage IV are in the range of greenschist facies. The P – T path of the retrogressed eclogite hosted in the medium-grade micaschist and paragneiss of Giuncana recalls the P – T trajectory of retrogressed eclogite hosted in the migmatite complex of northern Sardinia. The eclogites from Giuncana do not preserve the prograde segment of the P – T path, but, similarly to the other Sardinian eclogites, they record a slight increase in temperature, though slighter, during exhumation. This suggests that the thermal flow responsible for the amphibolitic-granulitic event post-dating the eclogitic stage recorded in the Giuncana eclogite may be tentatively referred to the slab break-off also responsible for the production of the Mg–K igneous suite in Corsica.

Description: The Wadi Hamama area is a volcanogenic Zn–Cu–Au–Ag prospect. It is hosted by a Neoproterozoic bimodal-mafic sequence, which comprises basalt, dacite and rhyolite along with volcaniclastic rocks. The rocks have a low-K tholeiitic affinity and are enriched in large ion lithophile elements over high field strength elements, which indicated their formation in an intra-oceanic island arc tectonic setting. The area was intruded by a tonalite–trondhjemite body, which has an intra-oceanic island arc affinity and later by diorite, which has a cordilleran-margin geochemical affinity. These rock units were intruded by post-tectonic granite dykes, which have a within-plate geochemical signature. There is a quartz-carbonate horizon extending along the contact between the basalt and the volcaniclastic rocks, mainly banded and lapilli tuffs. This horizon is of exhalative origin and is underlain by a mushroom-shaped alteration zone extending from the horizon down to the massive basalt. The footwall alteration is characterized by a silica-rich core surrounded by a thick chlorite sheath. Both the quartz-carbonate horizon and the footwall-altered rocks enclose historical trenches and pits. Sulfide-rich core samples are enriched in Zn, relative to Cu, and in Ag, which indicates the low-temperature nature of the hydrothermal system. The prospect was affected by supergene processes, which led to the widespread occurrence of secondary copper minerals and gold enrichment relative to the leached base metals, especially Zn. The prospect formed through a limited rifting of an intra-oceanic island arc which resulted in the formation of a small-scale volcanogenic Zn–Cu–Ag–Au prospect.

Description: The relationships between tectonics and magmatic activity in the Alps are still debated. Despite an active subduction since the Late Cretaceous, no arc-related magmatism is recorded prior of the Middle Eocene. The emplacement of plutons along the Insubric Fault in a short time span (~34–28 Ma) has been generally interpreted in terms of the slab break-off model. The Tertiary magmatism, however, is also characterized by the occurrence of widespread calcalkaline dikes not necessarily intruded along the Insubric Fault. The geochemical features of dikes vary along the Alps belt and are interpreted in terms of mantle source heterogeneity and degree of crustal contamination. U–Pb zircon dating of studied dikes indicates intrusion ages in the 42- to 34-Ma time interval. These data provide evidence for a pre-Oligocene magmatic activity that was not solely limited to the Adamello batholith. Moreover, it appears that dikes rejuvenate from SE to NW, in an opposite direction with respect to the Alpine subduction polarity. Thus, a more complex geodynamic scenario than the slab break-off model must be envisaged. The absence of arc magmatism prior to the Middle Eocene can be explained by the low-angle subduction of the Tethyan slab that confined the mantle partial melting zone away from the orogenic wedge. The onset of the Apennines subduction at 55–50 Ma caused the Alpine slab to retreat. The partial melting zone progressively migrated beneath the orogenic wedge and finally reached the axial belt in the Late Eocene, when the Alpine collision was completed. Only at this stage, slab break-off occurred and promoted the intrusion of the Periadriatic plutons.

Description: The Cotiella Massif in the south-central Pyrenees hosts upper Cretaceous gravity-driven extensional faults which were developed in the Bay of Biscay–Pyrenean paleorift margin of the Atlantic Ocean. They accommodate up to 6 km of post-rift carbonates above relict upper Triassic salt. Subsequent Pyrenean contractional deformation preserved the main extensional features, but most of the upper Triassic salt was expulsed and then dissolved, leaving little indications of the original salt volume. Nonetheless, several distinctive salt-related features are still recognizable both at outcrop and at basin scale, providing an exposed analogue for salt-floored extensional basins developed on passive margins. Based on field research, we re-interpret the tectonic evolution of the area and suggest that passive diapirs were coeval with gravity-driven extension during the development of the Cotiella basin. The given interpretations are supported with detailed geological maps, original structural data, cross sections and outcrop photographs. The discovery of previously unknown post-rift salt structures in the Cotiella Massif is an extra element to consider in the paleogeographic reconstructions of the upper Cretaceous passive margin of the Bay of Biscay–Pyrenean realm and consequently helps in our understanding of the evolution of current Atlantic-type margins.

Description: The Guevgueli Ophiolite Complex near Demir Kapija (Eastern Vardar Ophiolitic Unit) was studied for the age and facies of the overlying sediments. Cherts in direct contact with basalts are dated to late Bathonian–early Callovian with radiolarians. The post-obduction sequence, here informally named the Demir Kapija group, is composed of polymictic conglomerate, probably Kimmeridgian in age, and a more than 350-m thick carbonate succession. The carbonate succession consists of hemipelagic, slope and platform margin facies and contains algae and benthic foraminifers indicative of the Tithonian age. These new data support the previously proposed palaeogeographical connection between the Guevgueli and South Apuseni ophiolite complexes.

Description: Lode gold mineralization at the El-Sid mine area is associated with the ca. 600 Ma Fawakhir granite intrusion, which cuts the ~737 Ma ophiolite nappes in the Central Eastern Desert of Egypt. The mineralized quartz veins are hosted by ~E- and NE-trending fault/fracture sets cutting the western boundary of the intrusion and sheared ophiolites. The results of electron microprobe analyses of gold-associated hydrothermal sulfide and silicate minerals suggest that Au was mobilized alongside Ni, Co, Cr and As from the adjacent ophiolitic serpentinite. After granite emplacement, hydrothermal fluids interacted with the sheared serpentinite, leaching metals and re-depositing them in the faults/fractures and adjacent wall rock in a cyclic process. Low-salinity aqueous-carbonic fluids with significant quantities of volatile species (CO 2 , CH 4 , and N 2  ± H 2 S) leached and transported Au from deep to shallow crustal levels. Carbon dioxide had a buffering effect on the Au-bearing hydrothermal solution, maintaining its pH within a narrow near-neutral range, where elevated gold concentration was transported by complexation with reduced magmatic sulfur in a reducing environment. Gold deposition along fault/fracture conduits in the Fawakhir granite and adjacent serpentinite resulted from interplay of pressure drop, fluctuations in oxygen and sulfur fugacities, and exsolution of the volatile phases. Infiltration of meteoric water may have contributed to the formation of the late stage gold-sulfide mineralization that formed at shallower levels during terrane uplift. Sulfidation of the Fe-rich magmatic minerals was, on the other hand, the overriding process in the wall rock as evidenced by abundant disseminated sulfides with gold inclusions. Considering the structural control by regional shear zones (fluid conduits) and the voluminous granitic and ophiolitic rocks (metal sources), a high tonnage gold deposit amenable to open pit mining at the El-Sid mine area is very likely.

Description: The Makeng Fe deposit is located in the southwestern Fujian district, South China. The Sm–Nd isochron ages of seven samples of pure garnet and five of pure magnetite separates from the Makeng ores yielded an isochron age of 157 ± 15 Ma. Laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) zircon U–Pb dating of the nearby exposed the Dayang–Juzhou (DJ) porphyritic biotite granite and fine-grained syenogranite yielded 206 Pb/ 238 U ages of 140.2 ± 1.1 and 140.1 ± 1.0 Ma, respectively. These results suggest that the intrusion of the DJ granite and the Makeng skarn alterations and Fe mineralization are contemporaneous. The DJ granite exhibits geochemical characteristics of A-type granites, including high values of Na 2 O + K 2 O (8.13–8.92 wt%), FeO t /MgO (3.4–21.5), and Ga/Al (2.64–3.45 × 10 −4 ), and low Al 2 O 3 (10.71–13.29 wt%) value. Chondrite-normalized rare earth element patterns are characterized by obviously negative Eu anomalies (δEu = 0.02–0.28) and primitive-mantle normalized spidergrams show the enrichment in high field strength element and depleting in Sr, Ti, Ba, and Eu. The geochemical characteristics of DJ granite suggest that the granite was derived from partial melting of the Paleoproterozoic metasedimentary rocks of the Cathaysia basement. And some underplating of mafic magma in the lower tholeiitic crust and/or depleted mantle might be involved and provide the heat source for the partial melting. The DJ granite also fits the spatiotemporal distribution of the Jurassic–Cretaceous coastward migration of both extensional and arc-related magmatism and fills the A-type granites gap in the early stage of the early Cretaceous (145–125 Ma). Therefore, it is suggested that the late Jurassic and early Cretaceous magmatism in southwestern Fujian district were generated in an extensional environment responding to the slab rollback and concomitant retreating arc system of the paleo-Pacific plate within the South China Block. And the Fe metallogeny in southwestern Fujian district is genetically linked with the magmatism during this period.

Description: The Lunpola Basin in the central Tibet is the highest petroliferous basin in the world. The basin is a Cenozoic lacustrine rift basin with widespread oil shale depositions, which provide a valuable example for understanding the mechanisms of organic accumulation. Thirty-five samples of oil shale and mudstone were collected from one of the organic-rich oil shale intervals in the Lunpola Basin to discuss the controlling factors of organic enrichment. In the investigated oil shale interval, many redox proxies, including V/(V + Ni) ratios, Mo–U covariations, and pyrite framboid size distribution suggest anoxic conditions. However, the almost consistent variation patterns of TOC, P and Mo contents indicate that organic matter accumulation was controlled mainly by primary productivity. The relatively low Sr/Ba (average 0.74) and Sr/Cu ratios (average 4.75) suggest a warm–humid climate during the oil shale deposition. These conditions are suitable for living of organisms, which would raise the initial productivity of lake and in turn could have led to the oxygen-depleted conditions. The detrital input together with fast sedimentary rate during the oil shale deposition would result in dilution of organic matter.

Description: The Cambrian Tamdroust and Bab n’Ali Volcanic Complexes represent two magmatic episodes developed in the latest Ediacaran–Cambrian Atlas Rift of Morocco. Their rifting pulses were accompanied by accumulation of volcanosedimentary edifices (dominated by effusive lava flows in the former and explosive acidic aprons in the latter) associated with active tilting and uplift. Sealing of their peneplaned horst-and-graben palaeotopographies led to the onset of distinct onlapping geometries and angular discordances capping eroded basements ranging from the Ediacaran Ouarzazate Supergroup to the Cambrian Asrir Formation. Previous interpretations of these discordances as pull-apart or compressive events are revised here and reinterpreted in an extensional (rifting) context associated with active volcanism. The record of erosive unconformities, stratigraphic gaps, condensed beds and onlapping patterns across the traditional “lower–middle Cambrian” (or Cambrian Series 2–3) transition of the Atlas Rift must be taken into consideration for global chronostratigraphic correlation based on their trilobite content.

Description: The availability of a deep borehole in northeastern Alberta provides an unprecedented opportunity to study the in situ metamorphic craton rocks. This borehole reaches a depth of 2.4 km, with 1.8 km in the crystalline rocks, and is the only known borehole allowing access into the deeper rocks of the metamorphic Canadian Shield. In 2011, a zero-offset vertical seismic profile (VSP) was acquired to assist in the interpretation of seismic reflection data and geophysical logs. Three sets of upgoing tube waves interpreted from the raw profile correspond to the small-scale fluctuations in the borehole diameters and fracture zone in the crystalline rocks. A comparison between sonic log velocities and VSP velocities reveals a zone with increased velocity that could be due to the change in rock composition and texture in the basement rocks. The final processed profile is used to generate corridor stacks for differentiating between primary reflections and multiples in the seismic reflection profile. Analysis of the zero-offset VSP verifies existing log interpretation on the presence of fractures and the possible lithological changes in the metamorphic rocks of the Canadian Shield.

Description: Microfossil and stable isotope data (δ 13 C, δ 18 O) from deep-water sediments of Late Miocene age in the Mediterranean region have revealed a stepwise restriction of the Mediterranean prior to the Messinian Salinity Crisis which was modulated by a cyclicity responding to orbital precession. Very little is known with regard to the effects of these changes on shallow water environments of carbonate platforms and ramps. This work is based on a geological section on Crete (Greece) exposing sediments of early Messinian age, which documents the coeval response of pelagic and neritic systems to oceanographic changes. We discuss a dataset of planktic and benthic foraminifera assemblages in conjunction with size measurements ( n  = 6,777) and isotope analyses (δ 18 O, δ 13 C) of the planktic foraminifera Orbulina universa with regard to reef growth patterns. The planktic foraminifera fauna displays pronounced cyclical abundance changes of warm, oligotrophic ( O. universa ) and cold, meso- to eu-trophic taxa (globigerinids, neogloboquadrinids). This cyclicity corresponds to lithological changes from laminated to homogeneous marls on the precessional frequency band. In beds rich in mesotrophic foraminifera, O. universa is rare and the test is ~50 % smaller than average. Growth and size of O. universa is affected by various environmental factors, including temperature, trophic resources, illumination and O 2 content of ambient water. Explaining size variability by water temperature implies a change of ~11 °C over one precessional cycle. This estimate is in disagreement with growth patterns and stable isotope data of displaced reef corals ( Porites , Tarbellastraea ) documenting almost constant sea-surface temperatures, but substantial evaporation. Therefore, moderate temperature changes in a context of intense evaporation (high salinity) and water column destabilization associated with upward mixing of colder water masses with higher nutrient concentrations and low O 2 content better fits size variation of O. universa . From the presence of Halimeda bioherms intercalated with the sapropel cycles, we infer cyclic photic zone anoxia and at least some sections with sapropel couplets to have formed in the neritic zone. We also suggest further testing of stunted growth of O. universa as a proxy for enhanced nutrient availability in future palaeoceanographic studies.

Description: We have investigated the Coulomb stress change due to the 1983 Charazeh earthquake and its triggering effect on the 1990 Rudbar earthquake. Two stress increase lobes and two stress decrease lobes with N-S and NE-SW striking are detected, respectively. These lobes appear to be similar in size with the ones resulting from an equal length/width ratio of the Manjil thrust fault. The western section of the Kabateh segment is located in the increased Coulomb stress lobe and the eastern one in the decreased Coulomb stress lobe. The Coulomb stress change indicates that the 1983 main shock did not affect the Kelishom and Kashachal strike-slip faults. In the map view, we find that the 1990 Rudbar earthquake is located in the stress decrease lobe with 〈0.1 bar. The cross-sectional view of the calculated Coulomb stress change shows that the Rudbar main shock lies in the decreased Coulomb stress lobe. Also, we find that the low slip azimuth of the Manjil thrust fault, which associates with the negative normal stress and low shear stress, reduced the Coulomb stress change and inhibited the failure on the adjacent area. Therefore, we conclude that the 1983 Charazeh earthquake did not trigger the 1990 Rudbar destructive earthquake. We perceive that the events before and after the Charazeh main shock have not characteristic spatial distribution patterns and the seismicity after the main shock is not consistent with the Coulomb stress change. Therefore, the 1983 main shock, unlike the 1990 Rudbar earthquake, did not affect the seismicity patterns.

Description: The Carnic Alps represent the best exposed Paleozoic succession within the Alpine domain being fossiliferous, mostly non-metamorphic and largely complete. This study focuses on the area around Mt. Pizzul, because the bedrocks record well the basin dynamics and most of the units are conodont bearing. Our aims were to contribute to the procedure of formalization of the lithostratigraphic units and to understand the depositional and deformation history of the study area. The area has been mapped, tectonic overprint constrained and the successions described, measured and dated. As a second-order aim, we discuss these data to infer the relations with other parts of the Carnic basin and to recognize the global controls on sedimentation. The depositional evolution can be sketched as follows: pre-Hirnantian ramp-type margin; Hirnantian glacioeustatic-related deposits and unconformity; pelagic deposition in a ramp-type margin (Přídolí–Eifelian); slope formation and differentiation in buildup, foreslope and pelagic environments (Eifelian–Frasnian); transgression and reef drowning (Frasnian–Visean); probable subaerial exposures likely during in uppermost Famennian and Visean times; and turbidite deposition (Visean). Global controls or deposits suggesting a global control are documented, including the Boda Event, the Hirnantian glaciation, the Middle Devonian reef growth, the Kačák Event, and the high-frequency sea-level fluctuations around the Devonian–Carboniferous boundary. The drowning of the buildups here and elsewhere in the Carnic Alps started during the Frasnian, unlike observed globally. This suggests that local tectonics lead to progressive deepening up to the transition to turbidite deposition.

Description: Recent results of research from a regional geological survey have demonstrated that the Neoproterozoic Nanhuan strata in the Jiangnan sub-basin in the Nanhua rift in South China are built up of “wedge-shaped strata”, which rest transgressively on the metamorphic basement. These strata are grouped, as indicated by our sedimentary facies analysis, into the following four depositional successions (with ten related sedimentary facies associations): (1) continental volcanic depositional succession; (2) continental siliciclastic depositional succession; (3) marine siliciclastic depositional succession; and (4) glacial depositional succession. Compared with the Hunan-Guangxi sub-basin and the Northern Zhejiang sub-basin, the sedimentary processes in the Jiangnan sub-basin are dominated by continental rather than marine facies. However, similar sedimentary successions with identical facies trends can be recognized in all these sub-basins. All the Neoproterozoic basin fills in South China are characterized by a deepening water trend leading from continental to fully marine facies, recording the evolution of a typical rift basin related to the break-up of Rodinia. The crystalline zircons from a rhyolite sample taken from the base part of the first succession in the Jiangnan sub-basin give a mean SHRIMP U–Pb age of 803 ± 9 Ma. The occurrence of the ca. 803 Ma volcanic rocks and the volcaniclastic rocks marks the onset of a new phase of depositional cycles in the Jiangnan sub-basin.

Description: The structural evolution of the Sanandaj–Sirjan zone is the result of the convergence of the Iranian microcontinent and the Afro-Arabian continent. The study area at Khabr in the SE Sanandaj–Sirjan zone, in the hinterland of the Zagros orogen, consists of Paleozoic, Mesozoic and Cenozoic rocks. In this area, deformation phases were distinguished in different rock units based on structural and stratigraphical evidence, and the deformational events are divided into two stages: (1) a Late Triassic event and (2) a Late Cretaceous to Miocene event. The Late Triassic deformation event caused regional metamorphism in the Paleozoic units. These units are overlain by unmetamorphosed Jurassic clastic sequences. Fabrics and structural evidence confirm that the F 1 folding recumbent and refolded folds were synchronous with the metamorphism of the Paleozoic units and terminated in the Early Jurassic. The time table of the orogenic phases shows that this deformation event is related to the Cimmerian orogenic phase. From a geodynamic point of view, the early Cimmerian deformation in the southeastern Iranian margin suggests that the SE Sanandaj–Sirjan zone was an active margin at that time. The early Cimmerian discordance recorded the onset of a contractional component related to the oblique subduction of Neo-Tethys beneath the central Iranian microcontinent. Structures related to the Late Cretaceous to Miocene deformation phase are observed in Jurassic to Oligocene units, which contain moderately inclined and plunging folds. Comparing these folds with domains of deformation generated in models of transpression shows that the folding was caused by a combination of contractional and dip-slip components of movement, eventually resulting in the formation of a thrust system. The Khabr thrust systems consist of five sheets of oblique thrusts, duplex structures and shear zones. The shear zones generally strike E–W and dip moderately N (30°–40°). The occurrence of asymmetric folds with hinges that are either parallel to strike or plunge down dip demonstrates an oblique-slip component in these thrust shear zones. The stretching lineation in the mylonites within the shear zones is defined by the long axes of ellipsoidal grains of quartz, calcite, plagioclase and garnet. In general, stretching lineations trend from N40°W to N80°W with an intermediate (35°) plunge. The geometry of foliation and lineation within these shear zones shows the effect of dip- and oblique-slip shearing. Deformation continued with strike-slip faulting becoming important during the last stages of deformation from the Miocene to the present day. The results of this study demonstrate that the evolution of the SE Sanandaj–Sirjan zone, from Late Triassic to Miocene, is compatible with an inclined dextral transpression along this zone.

Description: Detrital heavy mineral analysis coupled with a regional geological review provide key elements to re-evaluate the distribution of the Rhodope metamorphic zone (SE Europe) in the region and its role in determining the evolution of the Thrace basin. We focus on the Eocene–Oligocene sedimentary successions exposed in the southern Thrace basin margin to determine the dispersal pathways of eroded crustal elements, of both oceanic and continental origins, as well as their different contributions through time. Lithological aspects and tectonic data coupled with geochemistry and geochronology of metamorphic terranes exposed in the area point to a common origin of tectonic units exposed in NW Turkey (Biga Peninsula) with those of NE Greece and SE Bulgaria (Rhodope region). The entire region displays (1) common extensional signatures, consisting of comparable granitoid intrusion ages, and a NE-SW sense of shear (2) matching zircon age populations between the metapelitic and metamafic rocks of the Circum-Rhodope Belt (NE Greece) and those of the Çamlica–Kemer complex and Çetmi mélange exposed in NW Turkey. Detrital heavy mineral abundances from Eocene–Oligocene sandstones of the southern Thrace basin demonstrate the influence of two main sediment sources mostly of ultramafic/ophiolitic and low- to medium-grade metamorphic lithologies, plus a third, volcanic source limited to the late Eocene–Oligocene. Detrital Cr-spinel chemistry is used to understand the origin of the ultramafic material and to discriminate the numerous ultramafic sources exposed in the region. Compositional and stratigraphic data indicate a major influence of the metapelitic source in the eastern part (Gallipoli Peninsula) during the initial stages of sedimentation with increasing contributions from metamafic sources through time. On the other hand, the western and more external part of the southern Thrace margin (Gökçeada, Samothraki and Limnos) displays compositional signatures according to a mixed provenance from the metapelitic and metamafic sources of the Circum-Rhodope Belt (Çamlıca–Kemer complex and Çetmi mélange). Tectonic restoration and compositional signatures provide constraints on the Palaeogene palaeogeography of this sector of the central-eastern Mediterranean region.

Description: The present study deals with heavy mineral analysis of late Early Miocene marine sediments recovered in the McMurdo Sound region (Ross Sea, Antarctica) during the ANDRILL—SMS Project in 2007. The main objective is to investigate how heavy mineral assemblages reflect different source rocks and hence different provenance areas. These data contribute to a better understanding of East Antarctica ice dynamics in the Ross Sea sector during the Early Miocene (17.6–20.2 Ma), a time of long-term global warming and sea level rise. The AND-2A drill core recovered several stratigraphic intervals that span from Early Miocene to Pleistocene and it collected a variety of terrigenous lithologies. The heavy mineral assemblages of the lower 650-m-thick sedimentary succession were analyzed through SEM observations and SEM–EDS microanalyses on heavy mineral grains. The heavy mineral analysis shows that the sediments are a mix of detritus dominated by McMurdo Volcanic Group sources most likely located in the present-day Mount Morning area (Proto-Mount Morning) with minor contribution from Transantarctic Mountains source rocks located west of the drill site. The heavy mineral assemblages in Interval 1 indicate that between 20.2 and 20.1 Ma, the grounding line of the ice sheet advanced to a position near the present-day Mount Morning volcanic center. During deposition of Interval 2 (20.1–19.3 Ma), the ice sheet most likely experienced a dynamic behavior with interval of ice advance alternating with periods of ice retreat, while Interval 3 (19.3–18.7 Ma) records further retreat to open water conditions. A dynamic behavior is noted in Interval 4 (18.7–17.6 Ma) with a decreasing contribution of materials derived from the basalts of the Mount Morning volcanic center located to the south of the drill site and a consequent increasing contribution of materials derived from the Transantarctic Mountains to the west of the drill site.

Description: Teisseyre–Tornquist Zone (TTZ) corresponds to a crustal boundary between the Precambrian East European Platform (EEP) and the Palaeozoic West European Platform. Although the zone has been controlling Phanerozoic evolution of large parts of Central Europe, its course, geometry and origin are still poorly constrained. Deep reflection seismic profile POLCRUST-01, recently acquired in SE Poland, for the first time allowed a precise comparison of the Ediacaran and later tectonic patterns to the deep crustal features of the TTZ and adjacent areas. The TTZ corresponds to the subvertical Tomaszów Fault separating the Radom–Kraśnik Elevation, composed of the typical EEP crust, from the Biłgoraj–Narol Block (BNB) in the SW, with a thinned crystalline basement showing affinities to the EEP crust. The BNB is a part of the larger Caledonian Łysogóry Terrane as evidenced by its Lower Palaeozoic stratigraphy and gravity data. Thus, for the first time, the proximal Baltican affinity of this unit has been documented unambiguously. The Łysogóry Terrane is delimited from the SW by the subvertical Cieszanów Fault Zone, corresponding to the Holy Cross Suture. The adjacent Małopolska Terrane is characterized by a distinct Early Palaeozoic stratigraphy, and lower-middle crust exhibiting SW-dipping reflective packages interpreted as NE-verging thrust and shear zones of a Neoproterozoic orogen. The observations from the POLCRUST-01 profile and regional comparisons indicate that the TTZ is a major Caledonian transcurrent zone between Poland and East Romania. In central Poland, the TTZ likely forms a narrow subvertical contact between the EEP and a proximal Kuiavia Terrane, as constrained by the deep refraction seismic data. To the NW, the zone extends towards the Pomeranian part of the Caledonide fold-and-thrust belt related to the Avalonia–Baltica collision zone (Thor Suture). South-east of Poland the TTZ corresponds to the Rava Ruska Fault Zone established as a Caledonian suture separating adjacent terrane, probably of a Baltican affinity. The East Romanian part of the TTZ conforms with the Sfântu Gheorghe Fault separating reworked EEP crust of the Pre-Dobrogean Depression from the North Dobrogea unit bearing a strong Variscan and Cimmerian overprint.

Description: Incorporating PVT properties and compositional evolution of oil inclusions into reservoir engineering simulator protocols can enhance understanding of oil accumulation, reservoir charge history, and migration events. Microthermometry and volumetric analysis have proven to be useful tools in compositional reconstitution and PT studies of oil inclusions and were used to determine composition, thermodynamic conditions, physical properties, and gas-to-oil ratios of heavy oil samples from Asmari carbonate reservoir in Kuh-e-Mond heavy oil field in Iran. PVT properties were predicted using a PVT black-oil model, and an acceptable agreement was observed between the experiments and the simulations. Homogenization temperatures were determined using microthermometry techniques in dolomite and calcite cements of the Asmari Formation, as well. Based on the homogenization temperature data, the undersaturated hydrocarbon mixture prior to formation of the gas cap migrated with a higher gas-to-oil ratio from a source rock. According to the oil inclusion data, the onset of carbonate cementation occurred at temperatures above 45 °C and that cementation was progressive through burial diagenesis. PVT black-oil simulator results showed that the reservoir pressure and temperature were set at 100 bar and 54 °C during the initial stages of oil migration. Compositional modeling implies that primary and secondary cracking in source rocks were responsible for retention of heavy components and migration of miscible three-phase flow during hydrocarbon evolution. The PT evolution of the petroleum inclusions indicates changes in thermodynamic properties and mobility due to phenomena such as cracking, mixing, or/and transport at various stages of oil migration.

Description: The evolution of drainage systems in and around active orogens may be strongly affected by climatic or tectonic processes. Information on the drainage evolution is stored in the sediments of the foreland depocentres. We investigated the provenance of two key deposits adjacent to the Central Alps, the Pliocene Sundgau gravels and the Pleistocene Höhere Deckenschotter by applying detrital thermochronology. Combined with provenance information from Rhine Graben deposits, we propose a reconstruction of the north Alpine drainage system since the middle Pliocene and discuss potential controlling mechanisms. Our data show that the Rhine Graben received detritus from the Alpine realm already during the Pliocene, indicating two different river systems—the proto-Rhine and the Aare–Doubs—draining the Alpine realm toward the North Sea and Mediterranean Sea. The investigated sediments contain detritus from two central Alpine sources, one showing a regional exhumational equilibrium and the other characterized by increasing exhumation rates. Discharge of the latter source ceased after ~2 Ma, reflecting a northward shift of the main Alpine drainage divide. Between ~2.0 and 1.2 Ma, the drainage system was affected by a major change, which we explain as resulting from a change in the Alpine stress field leading to tectonic exhumation and topography reduction in the area of the southern Aar massif. Generally, it seems that between ~4 and 1.2 Ma, the drainage system was mainly controlled by tectonic processes, despite first glaciations that already affected the north-Alpine foreland by ~2 Ma. The drainage system only seems to have reacted to the late Cenozoic climate changes after ~1.2 Ma, i.e., at the time of the most intense Alpine glaciation. At that time, the course of the Rhine River shifted toward the area of the Hegau volcanics, and the size of the Rhine River catchment became strongly reduced.

Description: Species diversity and how it is structured on a continental scale is influenced by stochastic, ecological, and evolutionary driving forces, but hypotheses on determining factors have been mainly examined for terrestrial and marine organisms. The extant diversity of African freshwater mollusks is in general well assessed to facilitate conservation strategies and because of the medical importance of several taxa as intermediate hosts for tropical parasites. This historical accumulation of knowledge has, however, not resulted in substantial macroecological studies on the spatial distribution of freshwater mollusks. Here, we use continental distribution data and a recently developed method of random and cohesive allocation of species distribution ranges to test the relative importance of various factors in shaping species richness of Bivalvia and Gastropoda. We show that the mid-domain effect, that is, a hump-shaped richness gradient in a geographically bounded system despite the absence of environmental gradients, plays a minor role in determining species richness of freshwater mollusks in sub-Saharan Africa. The western branch of the East African Rift System was included as dispersal barrier in richness models, but these simulation results did not fit observed diversity patterns significantly better than models where this effect was not included, which suggests that the rift has played a more complex role in generating diversity patterns. Present-day precipitation and temperature explain richness patterns better than Eemian climatic condition. Therefore, the availability of water and energy for primary productivity during the past does not influence current species richness patterns much, and observed diversity patterns appear to be in equilibrium with contemporary climate. The availability of surface waters was the best predictor of bivalve and gastropod richness. Our data indicate that habitat diversity causes the observed species–area relationship, and hence, that environmental heterogeneity is a principal driver of freshwater mollusk richness on a continental scale.

Description: We give an interpretive review of the geological evolution of the Nysa-Morava Zone (NMZ)—a Late Cenozoic tectonically active region of the NE Bohemian Massif located at its contact with the Western Carpathians’ orogenic front. This crustal domain, delimited by generally NW–SE-striking fault system, is characterised by Oligo-Miocene and Plio-Pleistocene volcanic activity, regionally anomalous, weak historical and present-day seismicity and increased CO 2 flux. The NMZ hosts several elongated, mostly NW–SE-trending, graben-like sedimentary basins (Upper Morava Basin System), which are filled by more than 300-m-thick succession of clastic fluvial/lacustrine sediments of Pliocene–Quaternary age. Based on geometric relations, basin architecture, coincidence of seismicity with CO 2 escape and sparse focal mechanism data, a model is proposed, which explains this active domain as a transfer zone developed between major WNW–ESE and NW–SE faults in a right-lateral transpressional setting. It is suggested that slow horizontal slip at these faults resulted in local permutations of the largest and medium stress directions and formation of transtensional crustal domains in the NMZ. Moreover, relation of the NMZ to the Alpine–Carpathian system and sedimentary grabens in its foreland is discussed. The absence of Paleogene and Lower Miocene deposits suggests that subsidence in the NMZ was commenced later than in the European Cenozoic Rift System (ECRIS), which is in agreement with later thrusting in Western Carpathians at ~17 Ma. The quantitative contrasts to the ECRIS in terms of faulting and subsidence rates are explained by the absence of lithospheric/crustal thinning in the NMZ.

Description: Molybdenum (Mo) exploration activity in China has increased tremendously over the past decade, and China is now known to have the largest Mo reserves in the world. The Tianshan–Xingmeng orogenic belt, the second largest Mo metallogenic belt, possesses over 8.2 Mt of Mo reserves. Porphyry Mo deposits contain 99 % of the Mo reserves in the Tianshan–Xingmeng orogenic belt; other Mo deposits contain 1 % of the Mo reserves. Five subtypes of the porphyry Mo deposits can be distinguished by deposit associations, such as Mo, Mo–Cu, Mo–W, Mo–Pb–Zn–Ag, and Cu–Mo deposits. These porphyry Mo deposits are formed at different stages: during the Ordovician, Devonian, Carboniferous, Late Permian, Triassic, Jurassic, and Cretaceous Periods. The polystage porphyry Mo mineralizations indicate that polystage tectonic–magmatic activity occurred in the orogenic belt. The Ordovician–Carboniferous porphyry Cu–Mo deposits are formed in an island-arc setting; the Late Permian porphyry Mo deposits are formed in a syn-collisional tectonic setting; and the Triassic porphyry Mo deposits are formed in a syn-collisional to post-collisional tectonic setting. The Ordovician–Triassic porphyry deposits are related to the Paleo-Asian Ocean tectonic system. The Jurassic porphyry Mo deposits are formed at the eastern margin of the Asian continent and are associated with a Paleo-Pacific plate-subduction tectonic setting. Cretaceous porphyry Mo deposits are formed in a lithospheric thinning setting and are related to the rollback of the Paleo-Pacific subduction plate.

Description: Core U1359 collected from the continental rise off Wilkes Land, east Antarctica, is analyzed for the clay mineralogy and carbon content. The temporal variation of the clay mineralogical data shows a dominance of illite with chlorite, smectite and kaolinite in decreasing concentration. Clay mineral illite is negatively correlated with smectite which shows enrichment during 6.2–6.8, 5.5–5.8, 4.5 and 2.5 Ma. The mineralogical analyses on the silt size fraction (2–53 μm) of some selected samples were also carried out. The combined result of both the size fractions shows the presence of chlorite and illite in both size fractions, smectite and kaolinite only in clay size fraction (〈2 μm) and similarity in the crystallinity and chemistry of illite in both fractions. Similar nature of illite in both fractions suggests negligible role of sorting probably due to the deposition from the waxing ice sheet. During times of ice growth, nearby cratonic east Antarctica shield provided biotite-rich sediments to the depositional site. On the other hand, the presence of smectite, only in the clay size fraction, suggests the effective role of sorting probably due to the deposition from distal source in ice retreat condition. During times of ice retreat, smectite-rich sediment derived from Ross Orogen is transported to the core site through surface or bottom water currents. Poor crystallinity of illite due to degradation further corroborates the ice retreat condition. The ice sheet proximal sediments of U1359 show that in the eastern part of Wilkes Land, the ‘warming’ was initiated during late Miocene.

Description: The Ohře(Eger) rift in the Bohemian Massif, which represents part of the Cenozoic Central European Volcanic Province, contains abundant mantle xenoliths of spinel peridotite. Petrography, geothermometry, mineral compositions and whole-rock and clinopyroxene trace element compositions of xenolith suites from four localities in the central part České Středohoří Volcanic complex (CSVC) and one locality in the eastern continuation (northern Bohemia) of the rift system display important differences that reveal small-scale compositional heterogeneity of the mantle. The xenoliths from the CSVC are mostly harzburgite that experienced high degrees of partial melting from ~17 to 21 %. However, xenoliths from one locality, Medvědický vrch, are predominantly fertile lherzolite. Subsequent pervasive metasomatism produced enrichments in light rare earth elements, large-ion lithophile elements, and U and Th, except for xenoliths from Medvědický vrch, which show marked depletions in all these elements. Such composition most likely reflects refertilization of the source rock by depleted melts. The trace element characteristics of the CSVC xenoliths indicate metasomatism of a depleted protolith by silicate melt at high melt/rock ratios. In contrast, harzburgite xenoliths from northern Bohemia experienced metasomatism at low melt/rock ratios by more evolved, alkaline and carbonate-rich melts.

Description: Here, we propose an alternative physical model, based on the concept of criticality, for the explanation of the observed magnetic signals prior to the M6.0 Parkfield and the M5.4 Alum Rock earthquakes. Motivated by an analogous experience from major earthquakes in Greece, where both magnetic field variations and seismic electric signals were also recorded few weeks before the main shock, we suggest that in all these cases, similar dynamic processes characterized by critical behaviour should govern the corresponding pre-focal areas when the relevant precursory signals emerged.

Description: Shear-wave splitting measurements from local and teleseismic earthquakes are used to investigate the seismic anisotropy in the upper mantle beneath the Rwenzori region of the East African Rift system. At most stations, shear-wave splitting parameters obtained from individual earthquakes exhibit only minor variations with backazimuth. We therefore employ a joint inversion of SKS waveforms to derive hypothetical one-layer parameters. The corresponding fast polarizations are generally rift parallel and the average delay time is about 1 s. Shear phases from local events within the crust are characterized by an average delay time of 0.04 s. Delay times from local mantle earthquakes are in the range of 0.2 s. This observation suggests that the dominant source region for seismic anisotropy beneath the rift is located within the mantle. We use finite-frequency waveform modeling to test different models of anisotropy within the lithosphere/asthenosphere system of the rift. The results show that the rift-parallel fast polarizations are consistent with horizontal transverse isotropy (HTI anisotropy) caused by rift-parallel magmatic intrusions or lenses located within the lithospheric mantle—as it would be expected during the early stages of continental rifting. Furthermore, the short-scale spatial variations in the fast polarizations observed in the southern part of the study area can be explained by effects due to sedimentary basins of low isotropic velocity in combination with a shift in the orientation of anisotropic fabrics in the upper mantle. A uniform anisotropic layer in relation to large-scale asthenospheric mantle flow is less consistent with the observed splitting parameters.

Description: Continuous surface cores of cold-seep carbonates were recovered offshore Pacific Nicaragua and Costa Rica from 800 to 1,500-m water depths (Meteor 66/3) in order to decipher their evolution and methane enriched fluid emanation in contrasting geological settings. Cores from the mounds Iguana, Perezoso, Baula V and from the Jaco Scarp escarpment were used for a multi-method approach. For both settings aragonite was revealed as dominant authigenic carbonate phase in vein fillings and matrix cementation, followed by Mg-calcite as second most abundant. This common precipitation process of CaCO 3 polymorphs could be ascribed as indirectly driven by chemical changes of the advecting pore water due to anaerobic oxidation of methane. A more direct influence of seep-related microbial activity on the authigenic mineral assemblage in both settings is probably reflected by the observed minor amounts of dolomite and a dolomite-like CaMg carbonate (MgCO 3  ~ 42 %). δ 13 C data of Jaco Scarp samples are significantly lower (−43 to −56 ‰ PDB) than for mound samples (−22 to −36 ‰ PDB), indicating differences in fluid composition and origin. Noteworthy, δ 18 O values of Scarp samples correlate most closely with the ocean signature at their time of formation. Documenting the archive potential, a high resolution case study of a mound core implies at least 40 changes in fluid supply within a time interval of approximately 14 ky. As most striking difference, the age data indicate a late-stage downward-progressing cementation front for all three mound cap structures (approx. 2–5 cm/ky), but a significantly faster upward carbonate buildup in the bulging sediments on top of the scarp environment (approx. 120 cm/ky). The latter data set leads to the hypothesis of chemoherm carbonate emplacement in accord with reported sedimentation rates until decompression of the advective fluid system, probably caused by the Jaco Scarp landslide and dating this to approximately 13,000 years ago.

Description: The Southern Gemericum basement in the Inner Western Carpathians experienced a polyphase regional deformation. Differences in the pre-Alpine and Alpine events have been constantly discussed. To address this, monazites from metapelites and acid metavolcanic rocks were dated using the Th–U–Pb electron microprobe method. Three monazite generations, such as Precambrian, Early Paleozoic, and Alpine, have been recognized in the greenschist facies pelites and acid metavolcanic rocks of the Southern Gemericum basement. Both inherited magmatic monazite grains in metavolcanites and rare relics of detrital monazites within the polyphase monazite grains in metapelites yielded the Precambrian age in the time span of 550–660 Ma. They prove the provenance and derivation from deeper crustal Cadomian fragments. High-Y magmatic monazites of Early Paleozoic age (444 ± 13 and 477 ± 7 Ma) have been recorded in the acid metavolcanites and their metavolcaniclastics. These ages roughly fit within the previously published magmatic zircon age determinations (at 494 ± 1.7 and 464 ± 1.7 Ma) that clearly indicate two-phase volcanic activity in the Early Paleozoic Southern Gemericum basin. The Early Paleozoic magmatic monazites were partly overprinted by the low-Y Alpine monazites (133 ± 5 and 184 ± 16 Ma) at their rims. In Al-rich metapelites, the newly formed low-Y monazites of Alpine age commonly occur, reflecting the polystage compression geodynamic evolution with three distinct peaks at 100 ± 8, 133 ± 5, and 190 ± 16 Ma, respectively. No data as the evidence of the pre-Alpine metamorphic events were observed in metapelites. Only some monazites yield the age indications for the Permian extensional thermal re-heating (260–290 Ma). The monazite age data from the Southern Gemericum basement indicate the strong overprinting due to the polyphase Alpine deformation at least in the greenschist facies conditions.

Description: The Variscan orogenic collage consists of three subduction-collision systems (Rheno-Hercynian, Saxo-Thuringian and Massif Central-Moldanubian). Devonian to early Carboniferous marine strata are widespread not only in the individual foreland fold and thrust belts, but also in post-tectonic basins within these foreland belts and on the Cadomian crust of peri-Gondwanan microcontinental fragments, which represent the upper plates of the subduction/collision zones. These marine basins preclude high elevations in the respective areas and also in their neighbourhood. Widespread late Carboniferous intra-montane basins with their coal-bearing sequences are likewise incompatible with high and dry plateaus. While narrow belts with high elevations remain possible along active margins within the orogen, comparison of the Variscides with the Himalaya/Tibetan plateau is unfounded. Plausible reasons for the scarcity of high Variscan relief include subduction of oceanic and even continental crust, subduction erosion, orogen-parallel extension and—most important—lithospheric thinning accompanied by high heat flow and magmatism. In many areas, timing and areal array of magmatism and HT metamorphism are not compatible with a model of tectonic thickening and subsequent gravitational collapse. It is suggested, instead, that lithospheric thinning and heating are due to mantle activities caused by the Tethys rift. The lower and middle crust were thermally softened and rendered unfit for stacking and isostatic uplift: in terms of topography, the Variscides represent a failed orogen. The HT regime also explains the abundance of granitoids and HT/LP metamorphic rocks typical of the Variscides. Melting in the HT regime extracted mafic components from Variscan and Cadomian crust as well as from Cadomian metasomatized lithospheric mantle, thus mimicking subduction-related magmatism. The onset of the HT regime at c. 340 Ma may also have triggered the final ascent of HP/UHP felsic metamorphic rocks.

Description: The aim of this article is to inform about the spatial distribution of the lignite qualitative parameters and total lignite reserves in the Czech Part of the Vienna Basin—The South Moravian Lignite Coalfield (SMLC). The total reserves were estimated on the basis of several composed variant digital models of individual seams in four partial area of SMLC. Calculations of the reserves resulted from the identified spatial distribution of chemical-technological parameters obtained from the thousands analysis of samples taken from more than 4,000 exploration works. The basic model of the deposit was so-called geological model characterising genetic evolution of the deposit and defines the spatial positions of the coal seams. Subsequently developed variant economical models spatially define the selected areas by the quality of lignite expressed by the limits of ash yield. Based on the created models, it was found that in the past just 3–7 % (depending on the variant model) of the total lignite reserves SMLC had been extracted. The presented geological reserves are currently using the existing mining technologies only partially mineable.

Description: We present the results of paleomagnetic study of Ediacaran sedimentary successions from the Southern Urals. The analysis of the sedimentary rocks of the Krivaya Luka, Kurgashlya and Bakeevo Formations reveal stable mid-temperature and high-temperature remanence components. Mid-temperature components were acquired during Devonian (Bakeevo Formation) and Late Carboniferous–Early Permian remagnetization events. The high-temperature components in Kurgashlya and Bakeevo Formations are interpreted to be primary, because they are supported by a positive conglomerate test (Bakeevo Formation) and magnetostratigraphic pattern (Kurgashlya Formation). The high-temperature component in the Krivaya Luka Formation is interpreted to be a Late Ediacaran overprint. Our new paleomagnetic poles together with some previously published Ediacaran poles from Baltica and Laurentia are used herein to produce a series of paleogeographic reconstructions of the opening of the Iapetus Ocean.

Description: Ultramafic rocks and gabbros are exposed in the southern Puna (NW Argentina) in tectonic association with continental arc-related Ordovician (volcano) sedimentary successions and granitoids. The origin of this mafic rock suite has been debated for three decades as either representing an Ordovician terrane suture, primitive Ordovician arc-related rocks or relics of the pre-Ordovician basement in tectonic contact with the Ordovician retro-arc basin successions. We present the first U–Pb ages of primary and inherited zircon from gabbros of this mafic–ultramafic assemblage. LA-ICP-MS analyses on cores and rims of these zircon grains yielded a concordia age of 543.4 ± 7.2 Ma for the gabbroic rocks. Other analysed zircons have Mesoproterozoic, and Early Ediacaran core and rim ages indicating that the magmas also assimilated Meso- and Neoproterozoic crustal material prior to final crystallization. The mafic rocks witnessed higher metamorphic grade than associated Ordovician rocks, which are unmetamorphosed or only affected by anchimetamorphism. The gabbros are mostly tholeiitic and enriched in Zr, Th, as well as other incompatible elements and have εNd t =540Ma ranging from 1.3 to 7.4 with most of the values between 5 and 7. 147 Sm/ 144 Nd ratios show evidence of weak crustal contamination. The mafic rocks do not reveal any affinity to mid-ocean ridge basalts in their geochemistry but point instead to an emplacement in an active plate margin arc environment. Chromites from ultramafic rocks show typical Ti, Al, Cr#, Fe 3+ abundances found in magmatic arc rocks. The formation of the gabbros and the associated ultramafic rocks in the southern Argentine Puna is related to the evolution of the margin of the Pampia terrane, including the Puncoviscana basin, during the Late Neoproterozoic and earliest Cambrian. In contrast to previous interpretations, the rocks predate the Ordovician evolution of the Central proto-Andean active margin. Consequently, interpretations assuming these rocks to represent an oceanic terrane suture of Ordovician age have to be dismissed as much as all palaeotectonic models that define Ordovician terranes in the Central Andes based on assumption that the ultramafic rocks and gabbros exposed in the southern Puna mark plate boundaries.

Description: Authigenic carbonates and seep biota are archives of seepage history and record paleo-environmental conditions at seep sites. We obtained the timing of past methane release events at the northeastern slope of the South China Sea based on U/Th dating of seep carbonates and seep bivalve fragments from three sites located at 22°02′–22°09′N, 118°43′–118°52′E (water depths from 473 to 785 m). Also, we were able to reconstruct the paleo-bottom water temperatures by calculating the equilibrium temperature using the ages, the corresponding past δ 18 O of seawater (δ 18 O sw ) and the δ 18 O of the selected samples formed in contact with bottom seawater with negligible deep fluid influence. A criterion consists of mineralogy, redox-sensitive trace elements and U/Th-isotope systematics is proposed to identify whether the samples were formed from pore water or have been influenced by deep fluid. Our results show that all methane release events occurred between 11.5 ± 0.2 and 144.5 ± 12.7 ka, when sea level was about 62–104 m lower than today. Enhanced methane release during low sea-level stands seems to be modulated by reduced hydrostatic pressure, increased incision of canyons and increased sediment loads. The calculated past bottom water temperature at one site (Site 3; water depth: 767–771 m) during low sea-level stands 11.5 and 65 ka ago ranges from 3.3 to 4.0 °C, i.e., 1.3 to 2.2 °C colder than at present. The reliability of δ 18 O of seep carbonates and bivalve shells as a proxy for bottom water temperatures is critically assessed in light of 18 O-enriched fluids that might be emitted from gas hydrate and/or clay dehydration. Our approach provides for the first time an independent estimate of past bottom water temperatures of the upper continental slope of the South China Sea.

Description: This is the first detailed report and analyses of deformation from the W part of the Deccan large igneous province (DLIP), Maharashtra, India. This deformation, related to the India–Seychelles rifting during Late Cretaceous–Early Paleocene, was studied, and the paleostress tensors were deduced. Near N–S trending shear zones, lineaments, and faults were already reported without significant detail. An E–W extension was envisaged by the previous workers to explain the India–Seychelles rift at ~64 Ma. The direction of extension, however, does not match with their N–S brittle shear zones and also those faults (sub-vertical, ~NE–SW/~NW–SE, and few ~N–S) we report and emphasize in this work. Slickenside-bearing fault planes, brittle shear zones, and extension fractures in meso-scale enabled us to estimate the paleostress tensors (directions and relative magnitudes). The field study was complemented by remote sensing lineament analyses to map dykes and shear zones. Dykes emplaced along pre-existing ~N–S to ~NE–SW/~NW–SE shears/fractures. This information was used to derive regional paleostress trends. A ~NW–SE/NE–SW minimum compressive stress in the oldest Kalsubai Subgroup and a ~N–S direction for the younger Lonavala, Wai, and Salsette Subgroups were deciphered. Thus, a ~NW/NE to ~N–S extension is put forward that refutes the popular view of E–W India–Seychelles extension. Paleostress analyses indicate that this is an oblique rifted margin. Field criteria suggest only ~NE–SW and ~NW–SE, with some ~N–S strike-slip faults/brittle shear zones. We refer this deformation zone as the "Western Deccan Strike-slip Zone" (WDSZ). The observed deformation was matched with offshore tectonics deciphered mainly from faults interpreted on seismic profiles and from magnetic seafloor spreading anomalies. These geophysical findings too indicate oblique rifting in this part of the W Indian passive margin. We argue that the Seychelles microcontinent separated from India only after much of the DLIP erupted. Further studies of magma-rich passive margins with respect to timing and architecture of deformation and emplacement of volcanics are required.

Description: In Sweden, knowledge of the location and timing of glacially induced faulting and seismicity is critical to effective engineering of a long-term nuclear disposal facility. To improve understanding and modeling of the complex ice-induced and tectonic stresses associated with glacially induced faulting, field studies detailing the location and timing of movement of such structures are required. Although the fault has not been confirmed in the bedrock, multi-proxy surficial geologic evidence indicates that the recently discovered scarp in Bollnäs is such a structure. Machine-excavated trenches across the scarp reveal landsliding down the scarp and, in one location, faulted and vertically offset fine-grained glacial sediments. The presence of water-escape structures in trenches excavated on a topographic high strongly suggests a co-seismic origin derived from earthquake magnitudes 〉5.5. Numerous landslides in till exist in the region as well. Four slopes with landslides were examined in detail, and the factors of safety for these slopes indicate stable conditions and suggest a seismic trigger. Basal radiocarbon dates from peat bogs located stratigraphically above the landslides provide minimum limiting ages for the co-seismic landslides. The oldest date indicates sliding prior to 10,180 calendar years before the present. The proposed Bollnäs Fault is 400 km south of the so called Lapland Fault Province. To date, it is the southernmost confirmed glacially induced fault in Sweden. The results of this study are consistent with existing modeling results that indicate fault instability in this region of central Sweden following deglaciation.

Description: In this paper, we present a sedimentary and structural analysis that together with maps, sections and new Ar/Ar data enable to describe the tectono-sedimentary evolution of the Mauléon hyper-extended rift basin exposed in the W-Pyrenees. Hyper-extension processes that ultimately resulted in exhuming mantle rocks are the result of the subsequent development of two diachronous detachment systems related to two evolutional stages of rifting. An initial Late Aptian Early Albian crustal thinning phase is first recorded by the development of a crustal necking zone controlled by the north-vergent Southern Mauléon Detachment system. During a subsequent exhumation phase, active faulting migrates to the north with the emplacement of the Northern Mauléon detachment system that exhumed north section thinned continental crust and mantle rocks. This diachronous crustal thinning and exhumation processes are also recorded by the diachronous deposition of syn-tectonic sedimentary tracts above the two supra-detachment sub-basins. Syn-tectonic sedimentary tracts record the progressive exhumation of footwall rocks along detachment systems. Tectonic migration from the southern to the northern Mauléon Detachment system is recorded by the coeval deposition of “sag” deposits above the necking zone basin and of syn-tectonic tracts above exhumed rocks north section. Located on a hanging-wall situation related to the Mauléon hyper-extension structures, the Arzacq Basin also records a major crustal thinning phase as shown by its subsidence evolution so as by deep seismic images. The absence of major top-basement structures and its overall sag morphology suggest that crustal thinning processes occurred by decoupled extension of lower crustal levels contrasting with the Southern Mauléon Detachment system. Reconciling observations from the Mauléon and Arzacq Basins, we finally propose in this paper that they were the result of one and the same asymmetric crustal thinning and exhumation processes, where extension is accommodated into the upper crust in the Mauléon Basin (lower plate basin) and relayed in ductile lower crust below the Arzacq Basin (upper plate basin).

Description: Based on an N–S-oriented crustal-scale cross section running east of the Rhine Valley in Vorarlberg, western Austria, we address the Alpine nappe stack and discuss the boundary between Central and Eastern Alps. For our cross section, we used surface geology, drillings and reinterpreted seismic lines, together with published sections. The general architecture of the examined area can be described as a typical foreland fold-and-thrust belt, comprising the tectonic units of the Subalpine Molasse, (Ultra-)Helvetic, Penninic and Austroalpine nappes. These units overthrusted the autochthonous Molasse along the south-dipping listric Alpine basal thrust. The European Basement, together with its autochthonous cover, dips gently towards the south and is dissected by normal faults and trough structures. The seismic data clearly show an offset not only of the top of the European Basement, but also of the Mesozoic cover and the Lower Marine Molasse. This indicates an activity of the structures as normal faults after the sedimentation of the Lower Marine Molasse. The Subalpine Molasse is multiply stacked, forming a triangle zone at the boundary with the foreland Molasse. The shortening within the Subalpine Molasse amounts to approximately 45 km (~67 %), as deduced from our cross section with the Lower Marine Molasse as a reference. The hinterland-dipping duplex structure of the Helvetic nappes is deduced from surface and borehole data. There are at least two Helvetic nappes needed to fill the available space between the Molasse below and the Northpenninic above. This is in line with the westerly located NRP20-East transect (Schmid et al., Tectonics 15(5):1047–1048, 1996 ; Schmid et al., The TRANSMED Atlas: the Mediterranean Region from Crust to Mantle, 2004 ), where the two Helvetic nappes are separated by the Säntis thrust. Yet in contrast to the Helvetic nappes in the NRP20-East transect, both of our Helvetic nappes comprise Cretaceous and Jurassic strata. This change is explained by an eastward down-stepping of the Säntis thrust along a pre-existing, approximately N–S striking lateral ramp bounding an inverted Jurassic graben structure below the Rhine Valley. This causes the Säntis thrust to detach the base Cretaceous west of the Rhine Valley and the base Jurassic units east of it. This graben-controlled change in detachment level leads to the formation of quite different nappe stacks on either side of the Rhine Valley and a “fault-controlled” appearance of the boundary between the Central and Eastern Alps.

Description: Several proxy data indicate an aridification of the East African climate during the Neogene, which might be influenced by the orographic changes of the East African Rift System (EARS) induced by tectonic forcing during the last 20 million years. To investigate the impact of the orography and especially of the rifts, the regional climate model CCLM is used, covering the EARS with Lake Victoria in the centre of the model domain. CCLM is driven by the ERA-Interim reanalysis and applied with a double-nesting method resulting in a very high spatial resolution of 7 km. The resolution clearly shows the shoulders and rifts of the western and eastern branch of the EARS and the Rwenzoris within the western branch. To analyse the orographic influence on climate, a new technique of modifying the orography is used in this sensitivity study. The shoulders of the branches are lowered and the rifts are elevated, resulting in a smoothed orography structure with less altitude difference between the shoulders and rifts. The changes in 2 m-temperature are very local and associated with the changes in the orography. The vertically integrated moisture transport is characterised by less vortices, and its zonal component is increased over the branches. The resulting amount of precipitation is mainly decreased west of the western branch and increased in the rift of the western branch. In the eastern branch, however, the changes in the amount of precipitation are not significant. The changes in the precipitation and temperature patterns lead to a shift of biomes towards a vegetation coverage characterised by more humid conditions in the northern part of the model domain and more arid conditions in the South. Thus, the aridification found in the proxy data can be attributed to the orographic changes of the rifts only in the northern model domain.

Description: In the Western Alps, the Money Complex of the Gran Paradiso Massif, metamorphosed under blueschist facies during the Alpine cycle, is considered to be Permo-Carboniferous in age, but no palaeontological or radiometric data constrain this interpretation. A revision of the lithostratigraphy of the Money Complex allows recognizing a polygenic (graphite-rich) and a monogenic (graphite-poor) meta-sedimentary formation. Detrital zircon U–Pb geochronology in both meta-sedimentary formations shows that (i) the main population is Cambrian and Ordovician in age, (ii) the youngest grains are Silurian and Lower Devonian, and (iii) Carboniferous zircon grains are lacking. A careful study of the age distributions in the Alps suggests that potential source for the detrital material in the Money Complex is the Briançonnais basement. Late Carboniferous magmatism is widespread in the Helvetic Zone of the Alps. Permian magmatism is dominant in the Briançonnais, the Austroalpine and the Southalpine basements. The lack of Carboniferous zircons in the Money Complex suggests that the detritus was not shed from the Helvetic zone, which was separated from the Money basin by the Zone Houillère basin, where the main drainage pattern was developed from south to north and where the depocenters migrated northwards from the Upper Missisippian to Upper Pennsylvanian. We suggest that the Money Complex may had been located to the east of the main river drainage inside the Zone Houillère basin or alternatively may represent a small basin, located on the east of the Zone Houillère.

Description: The Precambrian basement of Egypt is part of the Red Sea Mountains and represents the north-western part of the Arabian–Nubian Shield (ANS). Five volcanic sections are exposed in the Egyptian basement complex, namely El Kharaza, Monqul, Abu Had, Mellaha and Abu Marwa. They are located in the north Eastern Desert (ED) of Egypt and were selected for petrological and geochemical studies as they represent the Dokhan volcanics. The volcanics divide into two main pulses, and each pulse was frequently accompanied by deposition of immature molasse type sediments, which represent a thick sequence of the Hammamat group in the north ED. Compositionally, the rocks form a continuum from basaltic andesite, andesite, dacite (lower succession) to rhyodacite and rhyolite (upper succession), with no apparent compositional gaps. These high-K calc-alkaline rocks have strong affinities to subduction-related rocks with enriched LILEs (Rb, Ba, K, Th, Ce) relative to high field strength elements (Nb, Zr, P, Ti) and negative Nb anomalies relative to NMORB. The lower succession displays geochemical characteristics of adakitic rocks with SiO 2 〉53 wt%, Al 2 O 3 〉15 wt%, MgO 〉2.5 wt%, Mg# 〉49, Sr 〉650 ppm, Y 〈17 ppm, Yb 〈2 ppm, Ni 〉25 ppm, Cr 〉50 ppm and Sr/Y 〉42.4. They also have low Nb, Rb and Zr compared to the coexisting calc-alkaline rhyodacites and rhyolites. The highly fractionated rhyolitic rocks have strong negative Eu anomalies and possess the geochemical characteristics of A-type suites. Trace element geochemical signatures indicate a magma source consistent with post-collisional suites that retain destructive plate signatures associated with subduction zones. The adakitic rocks in the northern ANS are generated through partial melting of delaminated mafic lower crust interacting with overlying mantle-derived magma. The Dokhan volcanics were likely generated by a combination of processes, including partial melting, crystal fractionation and assimilation.

Description: The present study is dealing with the emplacement and deformation of diorite and quartz diorite exposed along new road cuts between Agios Nikolaos and Sitia (Uppermost Unit, eastern Crete). Mingling of both melt types is indicated by enclaves of diorite inside quartz diorite and vice versa. The diorite and quartz diorite intruded into coarse-grained white marble, which is in lateral contact to, but also forms the roof of, the intrusive body. Evidence for contact metamorphism is indicated by increasing grain size of calcite in the marble with decreasing distance from the diorite. U–Pb (TIMS) dating of zircons, separated from quartz diorite, yielded a concordant age at 74.0 ± 0.25 Ma, which is interpreted as emplacement age. As this age is close to published K–Ar cooling ages of hornblende and biotite, the melt should have intruded and cooled down rapidly at upper structural levels, which is not common for granitoids of the Uppermost Unit of Crete. Upper crustal melt emplacement is also documented by stoped blocks and by the lack of any ductile (viscous) deformation. The diorite and quartz diorite, however, are affected by strong post-Oligocene brittle faulting. Paleostress analysis, based on these faults, revealed a change in stress field from N–S and NNW–SSE shortening by thrusting (convergence between African and European plates) to NNE–SSW and NE–SW shortening accommodated by strike-slip (SW-ward extrusion of the Anatolian microplate). Calcite-twin density indicates high differential stress (260 ± 20 MPa) related to these phases of crustal shortening.

Description: An important part of the pre-Mesozoic basement of the Alps is the product of orogenic processes occurred in Ordovician times. Most of the geological constrains for this reconstruction have been obtained by the study of the Strona-Ceneri zone in the Southern Alps, where Alpine overprint was weak. The erosion of late Pan-African belts delivered large amounts of greywackes and pelites into subduction zones along Gondwana. The sediments were subducted and accreted to form wide complexes. As a result of the large sediment input, subduction retreated and the mantle-derived magmas intruded the base of the fertile “mud pile.” This initiated substantial anatexis to produce peraluminous magmas, which intruded and extruded syntectonically. Thereby, the predominantly steeply structured subduction–accretion complex provided ideal pathways for the uprising magmas, and down-thrusting host rocks to result in an isostatically stable crust. The SE Australian Lachlan fold belt is interpreted as an upper crustal analog of the Strona-Ceneri zone. Based on the combination of their geology, a crustal profile through an Alaskan type of orogen is drawn.

Description: Well data and core samples from the Late Paleozoic Halle Volcanic Complex (HVC) have been used to describe the geometry of the rhyolitic porphyritic laccoliths and their margins. The HVC formed between 301 and 292 Ma in the intramontane Saale basin, and it comprises mainly rhyolitic subvolcanic bodies (~300 km 3 ) as well as minor lava flows and volcaniclastic deposits. The major HVC laccolith units display aspect ratios ranging between 0.04 and 0.07, and they are separated by tilted and deformed Carboniferous–Permian host sediments. For the margin of the Landsberg laccolith, a major coarsely porphyritic unit of the HVC, an exceptional data set of 63 wells concentrated in an area of 10 km 2 reaching to depth of 710 m exists. It was used to explore the 3D geometry and textures, and to deduce an intrusion model. For a 3D visualization of the Landsberg laccolith margin, Geological Object Computer Aided Design; Paradigm ® software (GOCAD) was used. Curve objects have been derived from the intrusion–host contacts. Automated GOCAD ® methods for 3D modelling failed. As a result, manual refinement was essential. A major finding of the 3D modelling is the presence of prolate sediment rafts, up to 1,400 m in length and up to 500 m in thickness, surrounded by Landsberg rhyolite. The sedimentary rafts dip away from the laccolith centre. The engulfing laccolith sheets reach thickness of 100–300 m. For other HVC laccolith units (Löbejün, Petersberg, Brachstedt), well data reveal vertical rhyolite/sediment contacts or magma lobes fingering into the host sediments. HVC laccolith contact textures include small-scale shearing of the intruding magma and of the host sediment. In addition, internal shear zones have been detected inside the rhyolite bodies. The present study suggests that the emplacement of successive magma sheets was an important process during laccolith growth in the HVC.

Description: Elephant Island, located in the vicinity of the present-day active boundary of the South Shetland Block and the Antarctic and Scotia plates, is a region of particular interest for understanding the past and present geodynamic evolution of the southern Scotia Arc. Lineament from different data sources, field-measured fractures and geomorphological evidences have been analysed in this context. The lineaments extracted from aerial photographs (1,624), from a DEM (348) and from RADARSAT-2 satellite data (1,365) indicate four dominant lineament sets with NE–SW, NW–SE, N–S and W–E strikes. All data sources identified similar lineament families, but differences in the frequency distributions and subsequently on the dominant orientations were observed. The measurements direct of fractures were obtained from 23 sites in the field at which 278 planes were measured. Fracture planes indicate main modes trending in the NNE–SSW and NNW–SSE directions and a secondary mode in the E–W. The major trends of the fracture measurements and the lineaments display a good correlation in the E–W direction. However, there is an angular variation in the azimuth values of the NNE–SSE and NNW–SSE fractures with respect to the N–S, NE–SW and NW–SE orientations of the lineaments of approximately 20°. This trend deviation may be due to the fact that mapped lineaments are composed of small fracture sets that may be related to shear fractures that cannot be distinguished at the aerial photograph or radar satellite data scales. Submerged sea-floor morphological feature orientations match the studied morphostructures on the island and the main tectonic structures in this part of the Scotia Arc. A linkage of the main lineament families to the tectonic stages from the Oligocene to the present has been proposed, taking into account the information of the orientation and sense of movement of the fractures and stresses in the Elephant Island region.

Description: Alkaline basaltic volcanism has been taking place in the Carpathian–Pannonian region since 11 Ma and the last eruptions occurred only at 100–500 ka. It resulted in scattered low-magma volume volcanic fields located mostly at the margins of the Pannonian basin. Many of the basalts have compositions close to those of the primitive magmas and therefore can be used to constrain the conditions of the magma generation. Low-degree (2–3 %) melting could occur in the convective asthenosphere within the garnet–spinel transition zone. Melting started at about 100 km depth and continued usually up to the base of the lithosphere. Thus, the final melting pressure could indicate the ambient lithosphere–asthenosphere boundary. The asthenospheric mantle source regions of the basalts were heterogeneous, presumably in small scale, and included either some water or pyroxenite/eclogite lithology in addition to the fertile to slightly depleted peridotite. Based on the prevailing estimated mantle potential temperature (1,300–1,400 °C) along with the number of further observations, we exclude the existence of mantle plume or plume fingers beneath this region. Instead, we propose that plate tectonic processes controlled the magma generation. The Pannonian basin acted as a thin spot after the 20–12 Ma syn-rift phase and provided suction in the sublithospheric mantle, generating asthenospheric flow from below the adjoining thick lithospheric domains. A near-vertical upwelling along the steep lithosphere–asthenosphere boundary beneath the western and northern margins of the Pannonian basin could result in decompressional melting producing low-volume melts. The youngest basalt volcanic field (Perşani) in the region is inferred to have been formed due to the dragging effect of the descending lithospheric slab beneath the Vrancea zone that could result in narrow rupture at the base of the lithosphere. Continuation of the basaltic volcanism cannot be excluded as inferred from the still fusible condition of the asthenospheric mantle. This is reinforced by the detected low-velocity seismic anomalies in the upper mantle beneath the volcanic fields.

Description: The pre-Neogene Tauride fold-and-thrust belt, comprising Cretaceous ophiolites and metamorphic rocks and non-metamorphic carbonate thrust slices in southern Turkey, is flanked and overlain by Neogene sedimentary basins. These include poorly studied intra-montane basins including the Yalvaç Basin. In this paper, we study the stratigraphy, sedimentology and structure of the Yalvaç Basin, which has a Middle Miocene and younger stratigraphy. Our results show that the basin formed as a result of multi-directional extension, with NE–SW to E–W extension dominating over subordinate NW–SE to N–S extension. We show that faults bounding the modern basin also governed basin formation, with proximal facies close to the basin margins grading upwards and basinwards into lacustrine deposits representing the local depocentre. The Yalvac Basin was a local basin, but a similar, contemporaneous history recently reconstructed from the Altınapa Basin, ~100 km to the south, shows that multi-directional extension dominated by E–W extension was a regional phenomenon. Extension is still active today, and we conclude that this tectonic regime in the study area has prevailed since Middle Miocene times. Previously documented E–W shortening in the Isparta Angle along the Aksu Thrust, ~100 km to the southwest of our study area, is synchronous with the extensional history documented here, and E–W extension to its east shows that Anatolian westwards push is likely not the cause. Synchronous E–W shortening in the heart and E–W extension in the east of the Isparta Angle may be explained by an eastwards-dipping subduction zone previously documented with seismic tomography and earthquake hypocentres. We suggest that this slab surfaces along the Aksu thrust and creates E–W overriding plate extension in the east of the Isparta Angle. Neogene and modern Anatolian geodynamics may thus have been driven by an Aegean, Antalya and Cyprus slab segment that each had their own specific evolution.

Description: The Vivero fault is crustal-scale extensional shear zone parallel to the Variscan orogen in the Iberian massif belt with an associated dip-slip movement toward the hinterland. To constrain the timing of the extension accommodated by this structure, we performed zircon U–Pb LA-ICP-MS geochronology in several deformed plutons: some of them emplaced syntectonically. The different crystallization ages obtained indicate that the fault was active at least between 303 ± 2 and 287 ± 3 Ma, implying a minimum tectonic activity of 16 ± 5 Ma along the fault. The onset of the faulting is established to have occurred later than 314 ± 2 Ma. The geochronological data confirm that the Vivero fault postdates the main Variscan deformation events in the NW of the Iberian massif and that the extension direction of the Late Carboniferous–Early Permian crustal-scale extensional shear zones along the Ibero-Armorican Arc was consistently perpendicular to the general arcuate trend of the belt in SW Europe.

Description: The annually laminated oil shale from the Eocene maar lake at Messel (Federal State of Hessen, Germany) provides unique paleoenvironmental data for a time interval of ~640 ka during the Paleogene greenhouse phase. As a consequence of orbitally controlled changes in the vegetation in the vicinity of the lake, the lacustrine laminites can now be astronomically tuned. Dating is based on the short eccentricity amplitude modulations of the regional pollen rain and their correlation to the astronomical La2010a/La2010d solutions in combination with a revised 40 Ar/ 39 Ar age of a basalt fragment from a lapilli tuff section below the first lacustrine sediments. Depending on different newly suggested ages for the Fish Canyon sanidine used as monitor for neutron irradiation, the age for the eruption at Messel is between 48.27 ± 0.22 and 48.11 ± 0.22 Ma. This allows for the first time the exact correlation of a Paleogene lacustrine sequence to the marine record in Central Europe. The Messel oil shale becomes now slightly older than previously assumed and includes the Ypresian/Lutetian boundary that moves the base of the European Land Mammal Age Geiseltalian (MP 11) into the Lower Eocene. This opens a window for establishing an independent chronostratigraphic framework for Paleogene terrestrial records and their correlation to the marine realm. Furthermore, the study reveals that higher amounts of pollen from “wet” and thermophilous plants indicate less seasonal and more balanced precipitation and slightly higher temperatures during a well-expressed eccentricity minimum.

Description: Geochronological U–Pb (LA-ICP-MS), geochemical and isotopic data from metavolcanic felsic rocks of the Canigó and Cap de Creus massifs in the Eastern Pyrenees provide evidence of an Ediacaran magmatic event lasting 30 Ma in NE Iberia. These data also constrain the age of the Late Neoproterozoic succession in the Cap de Creus massif, where depositional ages range from 577 to 558 Ma, and in the Canigó massif, where the data (575–568 Ma) represent minimum ages. The geochemistry of the felsic rocks indicates that they were formed in a back-arc environment and they record a fragment of a long-lived subduction-related magmatic arc (620–520 Ma) in the active northern Gondwana margin. The homogeneity shown by all these crustal fragments along this margin suggests that the individualization of the Pyrenean basement from the Iberian Massif started later, probably during its transition from an active to a passive margin in Cambro–Ordovician times.

Description: The Zr-in-rutile thermometer is well established for the determination of metamorphic temperatures, particularly in high-grade metamorphic terrains, and for sedimentary provenance studies. The robustness of the rutile thermometry has not been tested on hydrothermal systems. Unlike quartz, a common hydrothermal mineral with abundant fluid inclusions, it is difficult to find fluid inclusions in rutile that are suitable for fluid-inclusion microthermometry. Here, we report fluid-inclusion microthermometric measurements in rutile from the auriferous quartz–kaolinite–hematite vein that typifies the gold deposit of Mil Oitavas in the southern Serra do Espinhaço, Minas Gerais, Brazil. Primary fluid inclusions in the rutile record moderately saline (10–12 wt% NaCl equivalent), aqueous–carbonic fluids with a total homogenization temperature of ~250 °C, which were likely trapped at about 300 °C and 2.0 kbar. This temperature is approximately 200 °C lower than that predicted by the Zr-in-rutile thermometer. For hydrothermal conditions of relatively low temperature, direct measurements of homogenization temperatures in rutile-hosted fluid inclusions should be preferred to the Zr-in-rutile thermometer.

Description: Mantle xenoliths in Oligocene–Miocene alkaline lavas in Lower Silesia (SW Poland) and adjacent part of Upper Lusatia (SE Germany) are samples of the subcontinental lithospheric mantle at the time of culmination of rifting in the Eger Rift (Bohemian Massif, Central Europe). The xenoliths come from the spinel mantle facies and show that two major lithologies occur in the area: A—highly magnesian (olivine Fo 90.5–92.0) harzburgites, and B—less magnesian (olivine Fo 84.0–90.0) harzburgites. The protolith of group A was clinopyroxene-free harzburgite being the residue after extensive melting. It was affected by chromatographic carbonatite/silicate melt metasomatism, with the carbonatite metasomatism only recorded in distal parts of the chromatographic systems. The B harzburgites were penetratively metasomatised by percolating alkaline silicate melts at the time of volcanism. That metasomatism was mostly anhydrous and typically cryptic; it lowered the Mg/(Mg + Fe) ratio of olivine and orthopyroxene in the peridotites subjected to melt percolation and led in places to dissolution of clinopyroxene. The mostly harzburgitic subcontinental mantle lithospheric domain beneath Lower Silesia and Upper Lusatia differs from the lherzolitic/harzburgitic ones located to W and SW beneath other parts of European Variscan orogen.

Description: Drill core is critical for robust and high-resolution reconstructions of Earth’s climate record, as well demonstrated from both marine successions and modern long-lived lake systems. Deep-time climate reconstructions increasingly require core-based data, but some facies, notably red beds and evaporites, have garnered less attention for both paleoclimatic and geochronologic analyses. Here, we highlight studies from the Rebecca K. Bounds (RKB) core, a nearly continuous, 〉1.6 km drill core extending from the Cretaceous to the Mississippian, recovered from the US Midcontinent by Amoco Production Company in 1988, and serendipitously made available for academic research. Recent research conducted on this core illustrates the potential to recover high-resolution data for geochronologic and climatic reconstructions from both the fine-grained red bed strata, which largely represent paleo-loess deposits, and associated evaporite strata. In this case, availability of core was instrumental for (1) accessing a continuous vertical section that establishes unambiguous superposition key to both magnetostratigraphic and paleoclimatic analyses, and (2) providing pristine sample material from friable, soluble, and/or lithofacies and mineralogical species otherwise poorly preserved in surface exposures. The potential for high-resolution paleoclimatic reconstruction from coring of deep-time loess strata in particular remains severely underutilized.

Description: Zircon crystals have been separated from gneisses and metagranitoids of the Pollino area (southern Apennines) in order to unravel the origin of these crustal slices within the ophiolite-bearing Frido Unit. The morphology of the zircon has been investigated by SEM, and the internal structure was revealed by cathodoluminescence. Data obtained by U/Pb dating have been used to deduce the age and significance of the different crystallization stages of zircon, connected to the evolutionary stages of the continental crust (Late Paleozoic–Early Mesozoic). Zircons in gneisses are characterized by inherited cores of magmatic origin, bordered by metamorphic rims. Inherited zircons generally show Paleoproterozoic to Ordovician ages, indicating the provenance of the sedimentary protolith from different sources. The exclusive presence of Late Neoproterozoic zircon cores in leucocratic gneisses may suggest a different magmatic source possibly connected to Pan-African events. Late Carboniferous–Early Permian ages are found mainly in zircon rims of metamorphic origin. These are similar to the emplacement ages of protolith of the metagranites in the middle crust portion. Late Carboniferous–Early Permian metamorphism and magmatism testify the extensional collapse of the Hercynian belt, recorded in European, particularly, in the Corsica–Sardinia block and in Calabria. Late Permian–Triassic ages have been detected in zircon rims from gneisses and metagranitoids. These younger ages appear related to deformation and emplacement of albite–quartz veins in both lithologies, and are related to an extensional episode predating the Middle Triassic to Middle Jurassic rifting in the Tethyan domain, followed by Middle to Late Jurassic spreading.

Description: This study presents laser step-heating 40 Ar/ 39 Ar age determinations of basaltic lava samples from Tamu Massif, the oldest and largest edifice of the submarine Shatsky Rise in the northwest Pacific and Earth’s proposed largest volcano. The rocks were recovered during Integrated Ocean Drilling Program Expedition 324, which cored 160 m into the igneous basement near the summit of Tamu Massif. The analyzed lavas cover all three major stratigraphic groups penetrated at this site and confirm a Late Jurassic/Early Cretaceous age for the onset of Shatsky Rise volcanism. Lavas analyzed from the lower and middle section of the hole yield plateau ages between 144.4 ± 1.0 and 143.1 ± 3.3 Ma with overlapping analytical errors (2σ), whereas a sample from the uppermost lava group produced a significantly younger age of 133.9 ± 2.3 Ma suggesting a late or rejuvenated phase of volcanism. The new geochronological data infer minimum (average) melt production rates of 0.63–0.84 km 3 /a over a time interval of 3–4 million years consistent with the presence of a mantle plume.

Description: In palaeoseismological trench studies, precise correlation of sedimentary units between fault blocks has an unquestionable value for accurately inferring the amounts of coseismic displacement and hence for assessing seismic hazard. A methodology based on laser analysis of particle size and mineralogic composition by X-ray diffraction is proposed in order to strengthen the correlation of sedimentary units in a trench excavated across the Concud Fault (central Iberian Chain, Spain). The surveyed sediments show sharp and multiple lateral facies changes, as well as inconsistent optically stimulated luminescence (OSL) ages. The results reinforce the correlation based on field inspection of lithologic and sedimentologic features. Moreover, they allow interpretation of rejuvenation of OSL ages of samples in the upthrown fault block, which has been attributed to partial erosion of sedimentary units, as evidenced by their smaller thickness and erosive boundaries. The correlated units are then used to estimate coseismic displacements for three palaeoseismic events.

Description: Palinspastic map reconstructions and plate motion studies reveal that switches in subduction polarity and the opening of slab gaps beneath the Alps and Dinarides were triggered by slab tearing and involved widespread intracrustal and crust–mantle decoupling during Adria–Europe collision. In particular, the switch from south-directed European subduction to north-directed “wrong-way” Adriatic subduction beneath the Eastern Alps was preconditioned by two slab-tearing events that were continuous in Cenozoic time: (1) late Eocene to early Oligocene rupturing of the oppositely dipping European and Adriatic slabs; these ruptures nucleated along a trench–trench transfer fault connecting the Alps and Dinarides; (2) Oligocene to Miocene steepening and tearing of the remaining European slab under the Eastern Alps and western Carpathians, while subduction of European lithosphere continued beneath the Western and Central Alps. Following the first event, post-late Eocene NW motion of the Adriatic Plate with respect to Europe opened a gap along the Alps–Dinarides transfer fault which was filled with upwelling asthenosphere. The resulting thermal erosion of the lithosphere led to the present slab gap beneath the northern Dinarides. This upwelling also weakened the upper plate of the easternmost part of the Alpine orogen and induced widespread crust–mantle decoupling, thus facilitating Pannonian extension and roll-back subduction of the Carpathian oceanic embayment. The second slab-tearing event triggered uplift and peneplainization in the Eastern Alps while opening a second slab gap, still present between the Eastern and Central Alps, that was partly filled by northward counterclockwise subduction of previously unsubducted Adriatic continental lithosphere. In Miocene time, Adriatic subduction thus jumped westward from the Dinarides into the heart of the Alpine orogen, where northward indentation and wedging of Adriatic crust led to rapid exhumation and orogen-parallel escape of decoupled Eastern Alpine crust toward the Pannonian Basin. The plate reconstructions presented here suggest that Miocene subduction and indentation of Adriatic lithosphere in the Eastern Alps were driven primarily by the northward push of the African Plate and possibly enhanced by neutral buoyancy of the slab itself, which included dense lower crust of the Adriatic continental margin.

Description: The Batang Group (BTG) volcanic rocks in the Zhiduo area, with NW-trending outcrops along the northeastern margin of the Qiangtang terrane (northern Tibet), are mainly composed of volcaniclastic rocks, dacite and rhyolite. Major and trace element, Sr and Nd isotope, zircon U–Pb and Hf isotope data are presented for the BTG dacites. Laser ablation inductively coupled plasma mass spectrometry zircon U–Pb dating constrains the timing of volcanic eruption as Late Triassic (221 ± 1 Ma). Major and trace element geochemistry shows that the BTG volcanic rocks are classified as calc-alkaline series. All samples are enriched in large-ion lithophile elements and light rare earth elements with negative–slightly positive Eu anomalies (Eu/Eu* = 0.47–1.15), and depleted in high field strength elements and heavy rare earth elements. In addition, these rocks possess less radiogenic Sr [( 87 Sr/ 86 Sr) i  = 0.7047–0.7078], much radiogenic Nd (ε Nd ( t ) = −4.2 to −1.3) and Hf (ε Hf ( t ) = 4.0–6.6) isotopes, suggesting that they probably originated from partial melting of a crustal source containing a mantle-derived juvenile component. The inferred magma was assimilated by crustal materials during ascending and experienced significant fractional crystallization. By combining previously published and the new data, we propose that the BTG volcanic rocks were genetically related to southwestward subduction of the Ganzi–Litang ocean (a branch of Paleo-Tethys) in the northeastern margin of the Qiangtang terrane. Given the coeval arc-affinity magmatic rocks in the region, we envisage that the Ganzi–Litang ocean may extend from the Zhongdian arc through the Yidun terrane to the Zhiduo area, probably even further northwest to the Tuotuohe area.

Description: The Cenozoic Urumieh–Dokhtar magmatic belt (UDMB) extends for over 2,000 km from northwest to southeast Iran and is characterized by dominantly calc-alkaline volcanic, pyroclastic, and intrusive rocks. The UDMB hosts numerous porphyry-type Cu ± Mo deposits, mostly distributed in two separate areas, one known as the Kerman copper belt (KCB) in the south, and the other, here referred to as the Arasbaran Metallogenic Zone (AMZ), in the north, of the UDMB. The two areas are represented by two world-class Cu–Mo deposits, Sarcheshmeh (1,200 Mt of ore at 0.69 % Cu and 300 ppm Mo) and Sungun (〉500 Mt of ore at 0.69 % Cu and ~250 ppm Mo), respectively. Chronology data were obtained for the Sungun, Haftcheshmeh, Kighal, and Niaz deposits in the AMZ. The Sungun deposit is associated with a suite of porphyritic granodiorite to monzodiorite stocks and late dykes intruding older andesitic lavas and limestones. SHRIMP zircon U–Pb data indicate that the host andesites were emplaced at 27.65 ± 0.51 Ma (±0.2σ). The main Sungun porphyritic intrusion crystallized at 20.69 ± 0.37 (±0.2σ) Ma. The Haftcheshmeh deposit is associated with a porphyritic granodiorite body intruding an older gabbro-diorite intrusion. Primary magmatic hornblende from the gabbro-diorite host rock yielded a 40 Ar/ 39 Ar plateau age of 27.47 ± 0.17 Ma. The main porphyritic intrusion crystallized at 19.46 ± 0.39 Ma. The Kighal porphyry system is associated with a porphyritic monzonite body intruding into older andesitic and dacitic lavas, and the Niaz porphyry system is associated with a porphyritic granodiorite stock cutting through an older monzodiorite intrusion. For the Kighal and Niaz, secondary biotite concentrates collected from potassic alteration zones in the parent porphyritic bodies yielded plateau ages of 20.1 ± 1.8 and 22.14 ± 0.13 Ma, respectively. The timing of the porphyritic intrusions and the associated mineralizations in the AMZ is considerably older than that in KCB in southern UDMB (14–7 Ma). There is evidence that the AMZ formed on a separate arc related to the southern lesser Caucasus subduction zone. The arc extends from northwest Iran to Armenia and Azerbaijan to the north. Similar deposits of the same age have been discovered in Armenia, exemplified by Kajaran and Dastakert.

Description: Based on detailed analyses of cores covering the lagoon of Rasdhoo Atoll, Maldives, six carbonate facies, one soil, and one peat facies have been identified. The abundance of carbonate and rare opaque grains was quantified with a point counter. X-ray diffractometry was used to measure mineralogical composition of samples. The statistical delineation of facies using cluster analysis was based on point count, mineralogical, and textural analyses. In decreasing abundance, the six carbonate facies are classified as mollusk–coral–algal floatstone to rudstone (30 %), mollusk–coral–red algae rudstone (23 %), mollusk–coral–algal wackestone to floatstone (23 %), mollusk–coral wackestone (13 %), mollusk–coral mudstone to wackestone (9 %), and mollusk mudstone (2 %). The carbonate facies represent lagoonal background sedimentation, mostly consisting of fine sediments, and event sedimentation depositing transported coarse-grained reefal components. Fifty-seven carbonate samples and one peat sample were dated radiometrically, covering the Holocene transgression from 10 kyrs BP until today. Comparing the sediment accumulation data of the lagoon with two local sea-level curves, three systems tracts can be identified: (1) a lowstand systems tract characterized by karst and soil deposition 〉10 kyrs BP, (2) a transgressive systems tract with peat and carbonate separated by hiatus 10–6.5 kyrs BP, and (3) a highstand systems tract dominated by carbonate sedimentation 6.5–0 kyrs BP and further divided into three stages (6.5–3, 3–1, and 1–0 kyrs BP). During the Holocene transgression, sedimentation rates increased continuously to a maximum of 1.4 m/kyr during 3–1 kyrs BP. Modern (1–0 kyrs BP) mean sedimentation rates average 0.6 m/kyr. A simple calculation suggests that two processes (background sedimentation and sand apron progradation) will probably fill up the accommodation space of the lagoon during the Holocene highstand, but these processes will not suffice to fill the larger atoll lagoons of the archipelago.

Description: Holocene slackwater deposits along the river channels were used to study the magnitude and frequency of the palaeofloods that occurred prior to gauged and historical data sets all over the world. Palaeohydrological investigations along the Shanxi-Shaanxi Gorge of the middle Yellow River, China, identified palaeoflood slackwater deposits (SWDs) at several sites along the cliffs bordering the river channel. The SWDs are intercalated within Holocene eolian loess-soil profiles and clastic slope deposits. The palaeoflood SWDs were differentiated from eolian loess and soil by the sedimentary criteria and analytical results including magnetic susceptibility and particle-size distribution, similar to the flood SWDs in 2012, which indicated that these well-sorted palaeoflood SWD beds were deposited from the suspended sediment load in floodwaters. They have recorded the extraordinary palaeoflood events which occurred between 3200 and 3000 a BP as dated by the optically stimulated luminescence method in combination with pedostratigraphic correlations with the previously studied Holocene pedo-stratigraphy in the Yellow River drainage basin. Manning slope-area calculations estimate the peak discharged for these palaeoflood events to range from 43,290 to 49,830 m 3 /s. The drainage area of the study site is 489,900 km 2 . It is 2.0–2.5 times the largest gauged flood (21,000 m 3 /s) that has ever occurred since 1934. These events also occurred on Yellow River tributaries, including the Weihe, Jinghe and Qishuihe Rivers. These flood events are therefore considered to be a regional expression of known climatic events in the northern hemisphere and demonstrate Holocene climatic instability. This study provides important data in understanding the interactions between regional hydro-climatic systems and global change in semiarid and subhumid regions.

Description: Spinel peridotite xenoliths in 4.1 Ma basanite lava at Kozákov volcano vary in equilibration temperature from 675 to 1,135 °C and provide a continuous sample of lithospheric mantle from the Moho to a depth of ~82 km. The sub-Kozákov mantle is layered, consisting of an upper equigranular layer (UEL) from 32 to 45 km, an intermediate protogranular layer (PGL) from 45 to 66 km, and a lower equigranular layer (LEL) below 66 km. Relative to primitive mantle, all three layers are depleted in major incompatible elements and heavy rare earth elements, with the UEL being most depleted among the three layers, consisting of harzburgite and having experienced 〉15 % fractional melting. In contrast, the PGL and LEL experienced 〈10–15 % melting and consist of lherzolite; the PGL and LEL overlap in major element composition, with the PGL displaying a decreasing degree of depletion with depth. Subsequent metasomatism by silicate melt led to cryptic enrichments in large-ion lithophile elements, light REE, and high field strength elements over all the layers and, locally, modal enrichment in orthopyroxene. Metasomatism is accompanied by elevated whole-rock Li contents (1.2–3.6 ppm) and isotopically light δ 7 Li (−0.8 to −5.8 ‰). Lithium contents and δ 7 Li show no strong correlation with rock type or depth, although values of δ 7 Li are 〈−3.0 ‰ in the PGL and 〉−3.5 ‰ in the UEL and LEL. The layered structure and geochemical characteristics of sub-Kozákov lithospheric mantle are the product of Variscan or pre-Variscan melting, Variscan tectonics, and Neogene volcanism and metasomatism.

Description: Early- to mid-Cretaceous flood-basalt suites of the northeast Canadian High Arctic assigned to a High Arctic Large Igneous Province (HALIP) were studied for their whole-rock geochemistry and Sr–Nd isotopes. Data from basalt flows within the upper Albian to lower Cenomanian Hassel Formation of northeast Ellesmere Island are compared with former published data and new inductively coupled plasma mass spectrometry data of the stratigraphic equivalent Strand Fiord basalts and the older, late Hauterivian to Aptian Isachsen basalts from Axel Heiberg Island. The transitional to mildly alkaline aphyric Hassel basalts, with ocean island basalt (OIB)-like geochemical signatures in parts, have an Ar–Ar whole-rock age of on average 96.4 ± 1.6 Ma. They represent two geochemically different flow units without a fractional crystallization relationship: the high-phosphorous (HP) and low-phosphorous (LP) basalts. The Hassel HP basalts differ from the LP basalts by additionally higher Ba, K, Rb, Th and LREE contents, a pronounced positive Eu anomaly (Eu/Eu* = 1.74–1.76), as well as lower Ta, Nb, Zr and Hf concentrations. The Nd and Sr isotope ratios of the Hassel HP basalts [ ε Nd ( t ) of −1.3 to −1.4, 87 Sr/ 86 Sr( t ) of 0.70706–0.70707] and the LP basalts [ ε Nd ( t ) of 4.5–4.9, 87 Sr/ 86 Sr( t ) of 0.7038–0.7040] indicate an origin from different mantle sources. The geochemically similar tholeiitic Isachsen (ca. 130–113 Ma) and Strand Fiord basalts (ca. 105–95 Ma) are also incompatible element enriched relative to the primitive mantle, however, with negative Sr–P anomalies as well as partially negative K, Ta and Nb anomalies. In terms of incompatible element ratios (Zr/Nb, Nb/Th), several mantle components are involved in the formation of the flood-basalt suites: a component with primitive mantle composition, an OIB-like component (probably subducted and recycled oceanic crust) and an enriched lithospheric component. The latter component, probably metasomatized subcontinental lithospheric mantle, has contributed mainly to the Isachsen, Strand Fiord and Hassel HP basalts. In the Sr–Nd isotope system, the enriched lithospheric component is characterized by hypothetical values of ε Nd ( t ) of approximately −4, and 87 Sr/ 86 Sr( t ) of approximately 0.7083. The HALIP-related flood-basalt suites of the Canadian High Arctic are interpreted to be part of a continental rift zone that was active during the opening of the Amerasia Basin of the Arctic Ocean and the development of the oceanic Alpha-Mendeleev Ridge into a Large Igneous Province.

Description: Natural gases from Middle Cambrian and Carboniferous-Lower Permian reservoirs of the onshore Polish Baltic region were studied for their molecular and stable isotope compositions. The following gas species were analysed: 12,13 C in CH 4 , C 2 H 6 , C 3 H 8 , n -C 4 H 10 , i -C 4 H 10 and CO 2 , 1,2 H in CH 4 , 14,15 N in N 2 , and stable isotopes of all noble gases. Due to significantly different geological settings and genetic types of source rocks of Eastern and Western Pomerania, the molecular and isotopic compositions of natural gases of these two regions exhibit distinct differences. Hydrocarbon gases associated with oil accumulated in the Middle Cambrian reservoir of Eastern Pomerania were generated during low-temperature thermogenic processes from a single source rock containing Type-II kerogen at one phase of petroleum generation. Non-associated hydrocarbon gases accumulated in the Carboniferous (Mississippian and Pennsylvanian)-Lower Permian (Rotliegend) reservoirs of Western Pomerania originated during at least two phases of gas generation by thermogenic processes from mainly Type-III kerogen and a small component of mixed Type-III/II kerogen. Noble gases are in general heavily enriched in radiogenic and nucleogenic isotopes such as 4 He, 40 Ar and 21 Ne accumulated in the reservoirs. Weak contributions of mantle-derived He and Ne are observed. Radiogenic 4 He/ 40 Ar ratios are higher than the average production rate ratio of about 5 for radiogenic 4 He/ 40 Ar in crustal materials, which might have been caused by a selective supply of 4 He that is lighter than 40 Ar from crustal rocks, or (U + Th)/K ratio might be higher than the average in crustal block. Carbon dioxide from gases of both the Western and Eastern Pomerania were mainly generated during thermogenic processes of transformation of organic matter, although gases of Western Pomerania can contain an endogenic component. Molecular nitrogen from the Eastern Pomeranian natural gases was mainly generated during low-temperature thermal transformation of organic matter and derived from NH 3 and NH 4 of crustal fluid, whereas molecular nitrogen from Western Pomeranian natural gases contains a significant component from the destruction of organic matter at a higher maturity level which may have been caused by a high heat flux from the volcanic activity during late Pennsylvanian–early Rotliegend ages, and has a bigger component release from NH 4 -rich illites.

Description: Compared to the well-documented Cenozoic magmatic and metamorphic rocks of the Cyclades, Aegean Sea, Greece, the geodynamic context of older meta-igneous rocks occurring in the marble–schist sequences and mélanges of the Cycladic Blueschist Unit is as yet not fully understood. Here, we report O–Hf isotopic compositions of zircons ranging in age from ca. 320 Ma to ca. 80 Ma from metamorphic rocks exposed on the islands of Andros, Ios, Sifnos, and Syros with special emphasis on Triassic source rocks. Ion microprobe (SHRIMP II) single spot oxygen isotope analysis of pre-Cretaceous zircons from various felsic gneisses and meta-gabbros representing both the marble–schist sequences and the mélanges of the study area yielded a large range in δ 18 O values, varying from 2.7 ‰ to 10.1 ‰ VSMOW, with one outlier at −0.4 %. Initial ε Hf values (−12.5 to +15.7) suggest diverse sources for melts formed between Late Carboniferous to Late Cretaceous time that record derivation from mantle and reworked older continental crust. In particular, variable δ 18 O and ε Hf ( t ) values for Triassic igneous zircons suggest that magmatism of this age is more likely rift- than subduction-related. The significant crustal component in 160  Ma meta-gabbros from Andros implies that some Jurassic gabbroic rocks of the Hellenides are not part of SSZ-type (supra-subduction zone) ophiolites that are common elsewhere along the margin of the Pelagonian zone.