ALBERT

Description: Biocides used in film protection products leaching from facades are known to be a potential threat to the environment. This study identifies individual sources and entry pathways in a small-scale urban area. We investigate emissions of commonly used biocides (terbutryn, diuron, and octylisothiazolinone – OIT) and some of their transformation products (TPs; diuron-desmethyl, terbumeton, terbuthylazine-2-hydroxy, and terbutryn-desethyl) from a 2 ha residential area 13 years after construction has ended. Sampling utilizes existing urban water infrastructure representative for decentralized storm water management in central and northern Europe and applies a two-step approach to (a) determine the occurrence of biocides above water quality limits (i.e., predicted no-effect concentration, PNEC) and (b) identify source areas and characterize entry pathways into surface and groundwater. Monitoring focuses on the analysis of selected biocides and TPs by liquid chromatography–mass spectrometry/mass spectrometry (LC-MS/MS) in water samples taken from facades, rainwater pipes, drainage, and storm water infiltration systems. In standing water in a swale, we found high concentrations of diuron (174 ng L−1) and terbutryn (40 ng L−1) above PNEC for surface water. We confirmed expected sources, i.e., facades. Sampling of rain downpipes from flat roofs identified additional sources of all biocides and two TPs of terbutryn and one TP of diuron. Diuron and terbutryn were found in three drainage pipes representing different entry pathways of biocides. In one drainage pipe collecting road runoff, only diuron-desmethyl and terbutryn-desethyl were detected. In two other drainage pipes collecting infiltrated water through soil, terbuthylazine-2-hydroxy was additionally detected. One of the pipes collecting infiltrated water through soil concentration showed the highest concentrations of terbutryn and two of its TPs (terbutryn-desethyl and terbuthylazine-2-hydroxy). This suggests a high leaching potential of terbutryn. The applied two-step approach determined sources and pathways of biocide and their TPs. This study contributes to expanding knowledge on their entry and distribution and, thus, eventually towards reducing emissions.

Description: Recent advances in soil moisture remote sensing have produced satellite data sets with improved soil moisture mapping under vegetation and with higher spatial and temporal resolutions. In this study, we evaluate the potential of a new, experimental version of the Advanced Scatterometer (ASCAT) soil water index data set for multiple objective calibrations of a conceptual hydrologic model. The analysis is performed in 213 catchments in Austria for the period 2000–2014. An HBV (Hydrologiska Byråns Vattenbalansavdelning)-type hydrologic model is calibrated based on runoff data, ASCAT soil moisture data, and Moderate Resolution Imaging Spectroradiometer (MODIS) snow cover data for various calibration variants. Results show that the inclusion of soil moisture data in the calibration mainly improves the soil moisture simulations, the inclusion of snow data mainly improves the snow simulations, and the inclusion of both of them improves both soil moisture and snow simulations to almost the same extent. The snow data are more efficient at improving snow simulations than the soil moisture data are at improving soil moisture simulations. The improvements of both runoff and soil moisture model efficiencies are larger in low elevation and agricultural catchments than in others. The calibrated snow-related parameters are strongly affected by including snow data and, to a lesser extent, by soil moisture data. In contrast, the soil-related parameters are only affected by the inclusion of soil moisture data. The results indicate that the use of multiple remote sensing products in hydrological modeling can improve the representation of hydrological fluxes and prediction of runoff hydrographs at the catchment scale.

Description: Crop yield is reduced by heat and water stress and even more when these conditions co-occur. Yet, compound effects of air temperature and water availability on crop heat stress are poorly quantified. Existing crop models, by relying at least partially on empirical functions, cannot account for the feedbacks of plant traits and response to heat and water stress on canopy temperature. We developed a fully mechanistic model, coupling crop energy and water balances, to determine canopy temperature as a function of plant traits, stochastic environmental conditions, and irrigation applications. While general, the model was parameterized for wheat. Canopy temperature largely followed air temperature under well-watered conditions. But, when soil water potential was more negative than −0.14 MPa, further reductions in soil water availability led to a rapid rise in canopy temperature – up to 10 ∘C warmer than air at soil water potential of −0.62 MPa. More intermittent precipitation led to higher canopy temperatures and longer periods of potentially damaging crop canopy temperatures. Irrigation applications aimed at keeping crops under well-watered conditions could reduce canopy temperature but in most cases were unable to maintain it below the threshold temperature for potential heat damage; the benefits of irrigation in terms of reduction of canopy temperature decreased as average air temperature increased. Hence, irrigation is only a partial solution to adapt to warmer and drier climates.

Description: The MARINE (Model of Anticipation of Runoff and INundations for Extreme events) hydrological model is a distributed model dedicated to flash flood simulation. Recent developments of the MARINE model are explored in this work. On one hand, transfers of water through the subsurface, formerly relying on water height, now take place in a homogeneous soil column based on the soil saturation degree (SSF model). On the other hand, the soil column is divided into two layers, which represent, respectively, the upper soil layer and the deep weathered rocks (SSF–DWF model). The aim of the present work is to assess the accuracy of these new representations for the simulation of soil moisture during flash flood events. An exploration of the various products available in the literature for soil moisture estimation is performed. The efficiency of the models for soil saturation degree simulation is estimated with respect to several products either at the local scale or spatially distributed: (i) the gridded soil moisture product provided by the operational modeling chain SAFRAN-ISBA-MODCOU; (ii) the gridded soil moisture product provided by the LDAS-Monde assimilation chain, which is based on the ISBA-A-gs land surface model and assimilating satellite derived data; (iii) the upper soil water content hourly measurements taken from the SMOSMANIA observation network; and (iv) the Soil Water Index provided by the Copernicus Global Land Service (CGLS), which is derived from Sentinel-1 C-SAR and ASCAT satellite data. The case study is performed over two French Mediterranean catchments impacted by flash flood events over the 2017–2019 period. The local comparison of the MARINE outputs with the SMOSMANIA measurements, as well as the comparison at the basin scale of the MARINE outputs with the gridded LDAS-Monde and CGLS data, lead to the following conclusion: both the dynamics and the amplitudes of the soil saturation degree simulated with the SSF and SSF–DWF models are better correlated with both the SMOSMANIA measurements and the LDAS-Monde data than the outputs of the base model. Finally, the soil saturation degree simulated by the two-layers model for the deep layer is compared to the soil saturation degree provided by the LDAS-Monde product at corresponding depths. In conclusion, the developments presented for the representation of subsurface flow in the MARINE model enhance the soil saturation degree simulation during flash floods with respect to both gridded data and local soil moisture measurements.

Description: Compound dry and hot conditions frequently cause large impacts on ecosystems and societies worldwide. A suite of indices is available for the assessment of droughts and heatwaves, yet there is no index available for incorporating the joint variability of dry and hot conditions at the sub-monthly scale. Here we introduce a daily-scale index, called the standardized compound drought and heat index (SCDHI), to assess compound dry-hot conditions. The SCDHI is based on a daily drought index (the standardized antecedent precipitation evapotranspiration index – SAPEI), the daily-scale standardized temperature index (STI), and a joint probability distribution method. The new index is verified against real-world compound dry and hot events and associated observed vegetation impacts in China. The SCDHI can not only capture compound dry and hot events at both monthly and sub-monthly scales, but is also a good indicator for associated vegetation impacts. Using the SCDHI, we quantify the frequency, severity, duration, and intensity of compound dry-hot events during the historical period and assess the ability of climate models to reproduce these characteristics in China. We find that compound events whose severity is at least light and which last longer than 2 weeks generally persisted for 20–35 d in China. Southern China suffered from compound events most frequently, and the most severe compound events were mainly detected in this region. Climate models generally overestimate the frequency, duration, severity, and intensity of compound events in China, especially for western regions, which can be attributed to a too strong dependence between the SAPEI and STI in those models. The SCDHI provides a new tool to quantify sub-monthly characteristics of compound dry and hot events and to monitor their initiation, development, and decay. This is important information for decision-makers and stakeholders to release early and timely warnings.

Description: Unconventional sources of data that enhance our understanding of internal interactions between socio-economic and hydrological processes are central to modeling human–water systems. Participatory modeling (PM) departs from conventional modeling tools by informing and conceptualizing human–water systems through stakeholder engagement. However, the implementation of many PM processes remains biased, particularly in regions where marginalized communities are present. Many PM processes are not cognizant of differentiation and diversity within a society and tend to treat communities as homogeneous units with similar capabilities, needs, and interests. This undifferentiation leads to the exclusion of key actors, many of whom are associated with marginalized communities. In this study, a participatory model-building framework (PMBF), aiming to ensure the inclusiveness of marginalized stakeholders – who (1) have low literacy, (2) are comparatively powerless, and/or (3) are associated with a marginalized language – in participatory modeling, is proposed. The adopted approach employs interdisciplinary storylines to inform and conceptualize human–water systems. The suggested method is underpinned by the multi-level perspective (MLP) framework, which was developed by Geels et al. (2002) to conceptualize socio-technical transitions and modified in this study to accommodate the development of interdisciplinary storylines. A case study was conducted in Atitlán Basin, Guatemala, to understand the relationships that govern the lake's cultural eutrophication problem. This research integrated key stakeholders from the Indigenous Mayan community, associated with diverse literacy ranges, and emerging from three different marginalized linguistic backgrounds (Kaqchikel, Tz'utujil, and K'iche'), in the PM activity. The proposed approach facilitated the participation of marginalized stakeholders. Moreover, it (1) helped develop an understanding of mechanisms governing the eutrophication of the lake, (2) initiated a dialogue between Indigenous Peoples and non-Indigenous stakeholders, and (3) extracted potential solutions targeting the system's leverage points. The participatory model-building activity generated three submodules: (1) agriculture, (2) tourism, and (3) environmental awareness. Each submodule contained socioculturally specific mechanisms associated with nutrient discharge to Lake Atitlán. The delineation of such nuanced relationships helps develop well-targeted policies and best management practices (BMPs). Additionally, the suggested process helped decrease the impact of power imbalances in water resources management and empowered community-based decision-making.

Description: With the increasing frequency and severity of fire, there is an increasing desire to better manage fuels and minimize, as much as possible, the impacts of fire on soils and other natural resources. Piling and/or burning slash is one method of managing fuels and reducing the risk and consequences of wildfire, but the repercussions to the soil, although very localized, can be significant and often irreversible. In an effort to provide a tool to better understand the impact of fire on soils, this study outlines the improvements to and the in situ validation of a nonequilibrium model for simulating the coupled interactions and transport of heat, moisture and water vapor during fires. Improvements to the model eliminate the following two important (but heretofore universally overlooked) inconsistencies: one that describes the relationship between evaporation and condensation in the parameterization of the nonequilibrium vapor source term, and the other that is the incorrect use of the apparent thermal conductivity in the soil heat flow equation. The first of these made a small enhancement in the stability and performance of the model. The second is an important improvement in the physics underpinning the model but had less of an impact on the model's performance and stability than the first. This study also (a) develops a general heating function that describes the energy input to the soil surface by the fire and (b) discusses the complexities and difficulties of formulating the upper boundary condition from a surface energy balance approach. The model validation uses (in situ temperature, soil moisture and heat flux) data obtained in a 2004 experimental slash pile burn. Important temperature-dependent corrections to the instruments used for measuring soil heat flux and moisture are also discussed and assessed. Despite any possible ambiguities in the calibration of the sensors or the simplicity of the parameterization of the surface heating function, the difficulties and complexities of formulating the upper boundary condition and the obvious complexities of the dynamic response of the soil's temperature and heat flux, the model produced at least a very credible, if not surprisingly good, simulation of the observed data. This study then continues with a discussion and sensitivity analysis of some important feedbacks (some of which are well known and others that are more hypothetical) that are not included in the present (or any extant) model, but that undoubtedly are dynamically influencing the physical properties of the soil in situ during the fire and, thereby, modulating the behavior of the soil temperature and moisture. This paper concludes with a list of possible future observational and modeling studies and how they would advance the research and findings discussed here.

Description: Acquiring in situ data of tidal flooding is key for the successful restoration planning of intertidal wetlands such as salt marshes and mangroves. However, monitoring spatially explicit inundation time series and tidal currents can be costly and technically challenging. With the increasing availability of low-cost sensors and data loggers, customized solutions can now be designed to monitor intertidal hydrodynamics with direct applications for restoration and management. In this study, we present the design, calibration, and application of the “Mini Buoy”, a low-cost underwater float containing an acceleration data logger for monitoring tidal inundation characteristics and current velocities derived from single-axis equilibrium acceleration (i.e. logger tilt). The acceleration output of the Mini Buoys was calibrated against water-level and current-velocity data in the hypertidal Bay of Fundy, Canada, and in a tidally reconnected former aquaculture pond complex in North Sumatra, Indonesia. Key parameters, such as submersion time and current velocities during submergence, can be determined over several months using the Mini Buoy. An open-source application was developed to generate ecologically meaningful hydrological information from the Mini Buoy data for mangrove restoration planning. We present this specific SE Asian mangrove restoration application alongside a flexible concept design for the Mini Buoy to be customized for research and management of intertidal wetlands worldwide.

Description: Spatiotemporally continuous estimates of the hydrologic cycle are often generated through hydrologic modeling, reanalysis, or remote sensing (RS) methods and are commonly applied as a supplement to, or a substitute for, in situ measurements when observational data are sparse or unavailable. This study compares estimates of precipitation (P), actual evapotranspiration (ET), runoff (R), snow water equivalent (SWE), and soil moisture (SM) from 87 unique data sets generated by 47 hydrologic models, reanalysis data sets, and remote sensing products across the conterminous United States (CONUS). Uncertainty between hydrologic component estimates was shown to be high in the western CONUS, with median uncertainty (measured as the coefficient of variation) ranging from 11 % to 21 % for P, 14 % to 26 % for ET, 28 % to 82 % for R, 76 % to 84 % for SWE, and 36 % to 96 % for SM. Uncertainty between estimates was lower in the eastern CONUS, with medians ranging from 5 % to 14 % for P, 13 % to 22 % for ET, 28 % to 82 % for R, 53 % to 63 % for SWE, and 42 % to 83 % for SM. Interannual trends in estimates from 1982 to 2010 show common disagreement in R, SWE, and SM. Correlating fluxes and stores against remote-sensing-derived products show poor overall correlation in the western CONUS for ET and SM estimates. Study results show that disagreement between estimates can be substantial, sometimes exceeding the magnitude of the measurements themselves. The authors conclude that multimodel ensembles are not only useful but are in fact a necessity for accurately representing uncertainty in research results. Spatial biases of model disagreement values in the western United States show that targeted research efforts in arid and semiarid water-limited regions are warranted, with the greatest emphasis on storage and runoff components, to better describe complexities of the terrestrial hydrologic system and reconcile model disagreement.

Description: Irrigated agriculture is threatened by soil salinity in numerous arid and semi-arid areas of the world, chiefly caused by the use of highly salinity irrigation water, compounded by excessive evapotranspiration. Given this threat, efficient field assessment methods are needed to monitor the dynamics of soil salinity in salt-affected irrigated lands and evaluate the performance of management strategies. In this study, we report on the results of an irrigation experiment with the main objective of evaluating time-lapse inversion of electromagnetic induction (EMI) data and hydrological modelling in field assessment of soil salinity dynamics. Four experimental plots were established and irrigated 12 times during a 2-month period, with water at four different salinity levels (1, 4, 8 and 12 dS m−1) using a drip irrigation system. Time-lapse apparent electrical conductivity (σa) data were collected four times during the experiment period using the CMD Mini-Explorer. Prior to inversion of time-lapse σa data, a numerical experiment was performed by 2D simulations of the water and solute infiltration and redistribution process in synthetic transects, generated by using the statistical distribution of the hydraulic properties in the study area. These simulations gave known spatio-temporal distribution of water contents and solute concentrations and thus of bulk electrical conductivity (σb), which in turn were used to obtain known structures of apparent electrical conductivity, σa. These synthetic distributions were used for a preliminary understanding of how the physical context may influence the EMI-based σa readings carried out in the monitored transects as well as being used to optimize the smoothing parameter to be used in the inversion of σa readings. With this prior information at hand, we inverted the time-lapse field σa data and interpreted the results in terms of concentration distributions over time. The proposed approach, using preliminary hydrological simulations to understand the potential role of the variability of the physical system to be monitored by EMI, may actually allow for a better choice of the inversion parameters and interpretation of EMI readings, thus increasing the potentiality of using the electromagnetic induction technique for rapid and non-invasive investigation of spatio-temporal variability in soil salinity over large areas.