Publication Date:
2019
Description:
〈p〉Publication date: 5 January 2020〈/p〉
〈p〉〈b〉Source:〈/b〉 Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, Volume 224〈/p〉
〈p〉Author(s): Aiqing Feng, Fangru Jiang, Guiyuan Huang, Peilian Liu〈/p〉
〈div xml:lang="en"〉
〈h5〉Abstract〈/h5〉
〈div〉〈p〉Anionic surfactants were widespread used in car cleaning agents, household detergents, agricultural and industrial processes, and considered as a major source of environmental pollutant. Therefore, it is necessary to develop a fast, simple, highly selective and sensitive probe for the detection of anionic surfactants. Here, we synthesized two aggregation induced emission (AIE)-active molecules 4,4′,4″,4‴-(ethene-1,1,2,2-tetrayltetrakis(benzene-4,1-diyl))tetrakis (1-(4-bromobenzyl)pyridin-1-ium) bromide (〈strong〉TPE〈/strong〉-〈strong〉Br〈/strong〉) and 4,4′,4″,4‴-(ethene-1,1,2,2-trayltetrakis(benzene-4,1-diyl))tetrakis(1-methylpyridin-1-ium)iodide (〈strong〉TPE〈/strong〉-〈strong〉I〈/strong〉), which were then applied as fluorescence probes for detecting sodium dodecyl sulfate (SDS) with high selectivity and sensitivity. In the presence of SDS, a multi-fold fluorescence emission intensity enhancement was observed in both two probes (〈strong〉TPE〈/strong〉-〈strong〉Br〈/strong〉 and 〈strong〉TPE〈/strong〉-〈strong〉I〈/strong〉) due to the electrostatic self-assembly of AIE molecular. The limits of detection are 71.5 and 120 nM for 〈strong〉TPE〈/strong〉-〈strong〉Br〈/strong〉 and 〈strong〉TPE〈/strong〉-〈strong〉I〈/strong〉, respectively. This study may provide a new strategy for environmental monitoring by AIE-based fluorescent probe.〈/p〉〈/div〉
〈/div〉
〈div xml:lang="en"〉
〈h5〉Graphical abstract〈/h5〉
〈div〉〈p〉Two cationic fluorescent probes (〈strong〉TPE-Br〈/strong〉 and 〈strong〉TPE-I〈/strong〉) were designed and synthesized for detecting sodium dodecyl sulfonate (SDS) with high selectivity and sensitivity. In the presence of SDS, a multi-fold fluorescence emission intensity enhancement was observed in the both of two probes due to the electrostatic self-assembly of AIE molecular.〈figure〉〈img src="https://ars.els-cdn.com/content/image/1-s2.0-S1386142519308364-ga1.jpg" width="404" alt="Unlabelled Image" title="Unlabelled Image"〉〈/figure〉〈/p〉〈/div〉
〈/div〉
Print ISSN:
1386-1425
Electronic ISSN:
1873-3557
Topics:
Chemistry and Pharmacology
,
Physics
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