ALBERT

Description: 〈p〉Publication date: August 2019〈/p〉 〈p〉〈b〉Source:〈/b〉 Solar Energy, Volume 188〈/p〉 〈p〉Author(s): Naser Abdi, Yaser Abdi, Zahra Alemipour〈/p〉

Description: 〈p〉Publication date: August 2019〈/p〉 〈p〉〈b〉Source:〈/b〉 Solar Energy, Volume 188〈/p〉 〈p〉Author(s): Smajil Halilovic, Jamie M. Bright, Wiebke Herzberg, Sven Killinger〈/p〉 〈div xml:lang="en"〉 〈h5〉Abstract〈/h5〉 〈div〉〈p〉Knowledge of horizontal solar irradiance is crucial for the nowcasting and forecasting of generated photovoltaic (PV) power. High quality irradiance measurement devices, however, are typically not collocated with PV systems. The lack of measurements can be compensated by numerical weather models or satellite-derived products, but they provide only limited temporal and spatial resolutions. Another possibility is to directly use PV systems as irradiance sensors, since the measured PV power is a good indicator of incoming solar irradiance. The challenging part in this procedure is the computation of the global horizontal irradiance 〈math xmlns:mml="http://www.w3.org/1998/Math/MathML" altimg="si233.svg"〉〈mrow〉〈msub〉〈mrow〉〈mi〉G〈/mi〉〈/mrow〉〈mrow〉〈mi〉h〈/mi〉〈/mrow〉〈/msub〉〈/mrow〉〈/math〉 from the global tilted irradiance 〈math xmlns:mml="http://www.w3.org/1998/Math/MathML" altimg="si234.svg"〉〈mrow〉〈msub〉〈mrow〉〈mi〉G〈/mi〉〈/mrow〉〈mrow〉〈mi〉c〈/mi〉〈/mrow〉〈/msub〉〈/mrow〉〈/math〉, because a combination of decomposition and transposition models is not analytically invertible. Hence, the majority of existing solutions to this problem are numerical procedures. In this paper, an analytical approach to compute 〈math xmlns:mml="http://www.w3.org/1998/Math/MathML" altimg="si235.svg"〉〈mrow〉〈msub〉〈mrow〉〈mi〉G〈/mi〉〈/mrow〉〈mrow〉〈mi〉h〈/mi〉〈/mrow〉〈/msub〉〈/mrow〉〈/math〉 from 〈math xmlns:mml="http://www.w3.org/1998/Math/MathML" altimg="si236.svg"〉〈mrow〉〈msub〉〈mrow〉〈mi〉G〈/mi〉〈/mrow〉〈mrow〉〈mi〉c〈/mi〉〈/mrow〉〈/msub〉〈/mrow〉〈/math〉 is presented. The comparison of the proposed approach with one of the existing iterative (numerical) approaches shows promising results. When applied to 1-min data at four different locations, the new approach outperforms the iterative procedure by up to 9% in terms of the relative root mean square error (rRMSE) for east/west module’s orientations, and performs slightly better with the south orientation. Moreover, the new approach provides results in less than 1 s, whereas the iterative procedure requires more than 20 min for a one year of data. An open source R-script of the new approach is also publicly available and provided as supplementary material.〈/p〉〈/div〉 〈/div〉

Description: 〈p〉Publication date: 5 January 2020〈/p〉 〈p〉〈b〉Source:〈/b〉 Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, Volume 224〈/p〉 〈p〉Author(s): Hayam M. Lotfy, Sarah S. Saleh, Christine M. El-Maraghy〈/p〉 〈div xml:lang="en"〉 〈h5〉Abstract〈/h5〉 〈div〉〈p〉An analytical investigation was carried out to study the treatment and amplification of the spectral signals produced by critical concentrations with high accuracy and precision using two advanced approaches. The factorized-spectrum approach was applied through two novel methods which were: absorptivity centering technique via both: factorized zero order absorption spectrum (ACT-FSD〈sup〉0〈/sup〉〈sub〉∆A〈/sub〉) and factorized ratio spectrum (ACT-FSR〈sub〉∆P〈/sub〉). The proposed methods were found to be linear in the ranges of (15–100 μg/mL) and (3–40 μg/mL) for ASP and MTO, respectively. Those methods were compared to the methods following the geometrical standard addition approach: ratio H-point standard addition method (RHPSAM) and geometrical induced amplitude modulation (GIAM). The approaches were applied for the determination of the minor component metoclopramide in its mixture with the major component aspirin in the challengeable ratio of (1,90) respectively in a white multicomponent system. The results obtained from the proposed approaches were statistically compared with each other. The methods were validated according to ICH guidelines where the results were found to be within the acceptable limits. The methods were found to be accurate and reliable for the determination of metoclopramide critical concentration besides aspirin concentration. The results of single factor ANOVA analysis indicated that there is no significant difference among the developed methods. These methods provided simple resolution of this binary combination from synthetic mixtures and pharmaceutical preparation and can be conveniently adopted for routine quality control analysis.〈/p〉〈/div〉 〈/div〉 〈div xml:lang="en"〉 〈h5〉Graphical abstract〈/h5〉 〈div〉〈p〉〈figure〉〈img src="https://ars.els-cdn.com/content/image/1-s2.0-S1386142519307292-ga1.jpg" width="325" alt="Unlabelled Image" title="Unlabelled Image"〉〈/figure〉〈/p〉〈/div〉 〈/div〉

Description: 〈p〉Publication date: 5 December 2019〈/p〉 〈p〉〈b〉Source:〈/b〉 Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, Volume 223〈/p〉 〈p〉Author(s): Rui Zhang, Yun Liu, Lin Kong, Xian-Yun Xu〈/p〉 〈div xml:lang="en"〉 〈h5〉Abstract〈/h5〉 〈div〉〈p〉In this study, a two photon absorbing (TPA) material consisting silver nanoparticles and triphenylamine-thiol derivative (TBS) has been prepared through interfacial coordination effect according to soft-hard-acid-base principle. The interfacial structure and morphology of the hybrid are researched in detail. Linear and nonlinear optical properties of the hybrid are studied. Upon interfacial coordination, the hybrid shows red-shifted UV–Vis absorption, causing from enhanced electronic drawing strength due to existence of Ag atom. The results also indicate that the surface Plasmon resonance (SPR) effect of Ag nanoparticles (~6 nm) brings about enhancement in single photon fluorescence emission and two photon absorption. Compared with free TBS, Ag-TBS hybrids show higher TPA cross-section (δ), which is 8784 GM for TBS and up to 103876 GM for Ag-TBS hybrid, showing ~12 fold increase. Due to excellent TPA property, the hybrids have good application in the field of optical power limiting and its limiting threshold is 0.49 J/cm〈sup〉−2〈/sup〉. This type of interfacial coordination induced hybrid provides a promising strategy to regulate linear optical properties and optimize nonlinear performance.〈/p〉〈/div〉 〈/div〉 〈div xml:lang="en"〉 〈h5〉Graphical abstract〈/h5〉 〈div〉〈p〉A thiol-Ag nanohybrid has been prepared through interfacial coordination effect and self-assembly process to optimize the TPA performance.〈figure〉〈img src="https://ars.els-cdn.com/content/image/1-s2.0-S1386142519307280-ga1.jpg" width="500" alt="Unlabelled Image" title="Unlabelled Image"〉〈/figure〉〈/p〉〈/div〉 〈/div〉

Description: 〈p〉Publication date: 5 December 2019〈/p〉 〈p〉〈b〉Source:〈/b〉 Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, Volume 223〈/p〉 〈p〉Author(s): Qiujuan Ma, Chunyan Wang, Yu Bai, Junhong Xu, Juan Zhang, Zhengkai Li, Xiaoyu Guo〈/p〉 〈div xml:lang="en"〉 〈h5〉Abstract〈/h5〉 〈div〉〈p〉Hypochlorous acid (HClO) is an important reactive oxygen species (ROS) and plays a significant role in living organisms. Highly selective and lysosome-targetable probes for sensing hypochlorous acid are rare. In this article, we designed and prepared a new lysosome-targeting and ratiometric fluorescent probe for monitoring the levels of hypochlorous acid. 4-Aminonaphthalimide was chosen as the fluorescent group and (2-aminoethyl) thiourea group was used as a specific recognition group for HClO. A morpholine unit was employed as a lysosome-targeting group. In the absence of HClO the probe underwent intramolecular charge transfer (ICT) and showed a green emission. When excess HClO is present, the ICT process was interrupted which caused a 57 nm blue-shift of fluorescence emission from 533 nm to 476 nm. The ratiometric fluorescent probe showed outstanding selectivity toward HClO over other various bioactive species. Furthermore, the ratiometric fluorescent probe exhibited rapid response time and ability of working in a wide pH range. The linear response of I〈sub〉476nm〈/sub〉/I〈sub〉533nm〈/sub〉 toward HClO was obtained in a concentration range of HClO from 1.0 × 10〈sup〉−6〈/sup〉 to 1.0 × 10〈sup〉−4〈/sup〉 mol·L〈sup〉−1〈/sup〉. The detection limit was estimated to be 8.0 × 10〈sup〉−7〈/sup〉 mol·L〈sup〉−1〈/sup〉 for HClO. Moreover, the probe showed a perfect lysosome-targeting ability, and has been successfully used to the confocal imaging of HClO in lysosomes of HepG2 cells with little cell toxicity. All of such good properties illustrated that it could be applied to determine HClO at lysosomes in living cells.〈/p〉〈/div〉 〈/div〉 〈div xml:lang="en"〉 〈h5〉Graphical abstract〈/h5〉 〈div〉〈p〉〈figure〉〈img src="https://ars.els-cdn.com/content/image/1-s2.0-S1386142519307243-ga1.jpg" width="158" alt="Unlabelled Image" title="Unlabelled Image"〉〈/figure〉〈/p〉〈/div〉 〈/div〉

Description: 〈p〉Publication date: 5 January 2020〈/p〉 〈p〉〈b〉Source:〈/b〉 Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, Volume 224〈/p〉 〈p〉Author(s): Markéta Paloncýová, Gustav Aniander, Emma Larsson, Stefan Knippenberg〈/p〉 〈div xml:lang="en"〉 〈h5〉Abstract〈/h5〉 〈div〉〈p〉Visualization of membrane domains like lipid rafts in natural or artificial membranes is a crucial task for cell biology. For this purpose, fluorescence microscopy is often used. Since fluorescing probes in lipid membranes partition specifically in e.g. local liquid disordered or liquid ordered environments, the consequent changes in their orientation and location are both theoretically and experimentally of interest. Here we focused on a liquid disordered membrane phase and performed molecular dynamics (MD) simulations of the indocarbocyanine DiD probes by varying the length of the attached alkyl tails and also the length of the cyanine backbone. From the probed compounds in a DOPC lipid bilayer at ambient temperature, a varying orientation of the transition dipole moment was observed, which is crucial for fluorescence microscopy and which, through photoselection, was found to be surprisingly more effective for asymmetric probes than for the symmetric ones. Furthermore, we observed that the orientation of the probes was dependent on the tail length; with the methyls or propyls attached, DiD oriented with its tails facing the water, contrary to the ones with longer tails. With advanced hybrid QM/MM calculations we show that the different local environment for differently oriented probes affected the one-photon absorption spectra, that was blue-shifted for the short-tailed DiD with respect to the DiDs with longer tails. We show here that the presented probes can be successfully used for fluorescence microscopy and we believe that the described properties bring further insight for the experimental use of these probes.〈/p〉〈/div〉 〈/div〉 〈div xml:lang="en"〉 〈h5〉Graphical abstract〈/h5〉 〈div〉〈p〉〈figure〉〈img src="https://ars.els-cdn.com/content/image/1-s2.0-S138614251930719X-ga1.jpg" width="417" alt="Unlabelled Image" title="Unlabelled Image"〉〈/figure〉〈/p〉〈/div〉 〈/div〉